Trng THPT K Thut L Thy-Qung Bnh

ng cp t duy ca ngi hc Ha!

CC DNG BI TP AMINO AXIT

Dng 1: L thuyt tng hp
Cu 1: Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi dung dch HCl l A. X, Y, Z, T B. X, Y, T. C. X, Y, Z. D. Y, Z, T. Cu 2:C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch phenolphtalein. B. nc brom. C. dung dch NaOH. D. giy qu tm. Cu 3: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l: A. anilin, metyl amin, amoniac. B. amoni clorua, metyl amin, natri hiroxit. C. anilin, amoniac, natri hiroxit. D. metyl amin, amoniac, natri axetat. Cu 4: Pht biu khng ng l: A. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO2 li thu c axit axetic. B. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung dch HCl li thu c phenol. C. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH li thu c anilin. D. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to ra cho tc dng vi dung dch NaOH li thu c natri phenolat. Cu 5: Cho cc cht: etyl axetat, anilin, ancol (ru) etylic, axit acrylic, phenol, phenylamoni clorua, ancol (ru) benzylic, p-crezol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l A. 3. B. 5. C. 6. D. 4. Cu 6: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. giy qu tm. B. nc brom. C. dung dch NaOH. D. dung dch phenolphtalein. Cu 7: Pht biu khng ng l: A. Trong dung dch, H2N-CH2-COOH cn tn ti dng ion lng cc H3N -CH2-COO B. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt. C. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl. D. Hp cht H2 N-CH2-COOH3N-CH3 l este ca glyxin (hay glixin). Cu 8: C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoni clorua), H2N-CH2-CH2-CH(NH2 )-COOH, ClH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa. S lng cc dung dch c pH < 7 l A. 2. B. 3. C. 5. D. 4. Cu 9:un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l: A. H2N-CH2-COOH, H2N-CH2-CH2 -COOH. B. H3N-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl-. + + C. H3N -CH2-COOHCl , H3 N -CH(CH3)-COOHCl . D. H2N-CH2-COOH, H2N-CH(CH3)-COOH. Cu 10 Cho dy cc cht: CH4, C2H2, C2H4 , C2 H5OH, CH2=CH-COOH, C6H5 NH2 (anilin), C6H5OH (phenol), C6H6 (benzen). S cht trong dy phn ng c vi nc brom l A. 6. B. 8. C. 7. D. 5. Cu 11 : Cho dy cc cht: C6H5OH (phenol), C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2. S cht trong dy tc dng c vi dung dch HCl l: A. 5. B. 2. C. 3. D. 4. Cu 12: Cho dy cc cht: CH4, C2H2, C 2H4, C 2H5 OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6 (benzen). S cht trong dy phn ng c vi nc brom l A. 6. B. 8. C. 7. D. 5. Cu 13: Cho dy cc cht: phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy phn ng c vi NaOH (trong dung dch) l A. 3. B. 2. C. 1. D. 4. Cu 14: Cho dy cc cht: C6H5OH (phenol), C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2. S cht trong dy tc dng c vi dung dch HCl l A. 4. B. 2. C. 3. D. 5. Cu 15: Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l : A. Cu(OH)2 trong mi trng kim. B. dung dch NaCl. C. dung dch HCl. D. dung dch NaOH.
o

Cu 16: Cho tng cht H2NCH2COOH, CH3COOH, CH3COOCH3 ln lt tc dng vi dung dch NaOH (t ) v
o

vi dung dch HCl (t ). S phn ng xy ra l:

Gio vin: Nguyn Cao Chung

-1-

D: 0973904885

Trng THPT K Thut L Thy-Qung Bnh ng cp t duy ca ngi hc Ha! A. 3. B. 5. C. 6. D. 4. Cu 17: C ba dung dch: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol etylic, benzen, anilin ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l dung dch HCl th nhn bit c ti a bao nhiu ng nghim? A. 5. B. 6. C. 3. D. 4. Cu 18: Pht biu no sau y l ng? A. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam. B. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh. C. Benzen lm mt mu nc brom nhit thng. D. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni. Cu 19: Cht X c cng thc phn t C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l A. metyl aminoaxetat. B. axit -aminopropionic. C. axit -aminopropionic. D. amoni acrylat. Cu 20: Dy ch cha nhng amino axit c s nhm amino v s nhm cacboxyl bng nhau l A. Gly, Ala, Glu, Tyr B. Gly, Val, Tyr, Ala C. Gly, Val , Lys, Ala D. Gly, Ala, Glu, Lys Cu 21: Cho 29.8 gam hn hp 2 amin n chc k tip tc dng ht vi dung dch HCl, lm kh dung dch thu c 51.7 gam mui khan. Cng thc phn t 2 amin l A. CH5N v C2H7N B. C2H7N v C3 H9N D. C3H7N v C4H9 N C. C3H9N v C4H11N Cu 22: ng vi cng thc phn t C2H7O2N c bao nhiu cht va phn ng c vi dung dch NaOH, va phn ng c vi dung dch HCl? A. 1. B. 3. C. 4. D. 2. Cu 123: S amin thm bc mt ng vi cng thc phn t C7H9N l A. 3. B. 5. C. 2. D. 4. Cu 24: C bao nhiu tripeptit (mch h) khc loi m khi thu phn hon ton u thu c 3 aminoaxit: glyxin, alanin v phenylalanin? A. 3 B. 9 C. 4 D. 6 Cu 25: Pht biu ng l A. Khi thu phn n cng cc protein n gin s cho hn hp cc -aminoaxit B. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc mu xanh m C. Enzim amilaza xc tc cho phn ng thu phn xenluloz thnh mantoz D. Axit nucleic l polieste ca axit photphoric v glucoz Cu 26: Cc dung dch phn ng c vi Cu(OH)2 nhit thng l A. glixeron, axit axetic, glucoz B. lng trng trng, fructoz, axeton C. anhit axetic, saccaroz, axit axetic D. fructoz, axit acrylic, ancol etylic Cu 27. Cho cc cht sau: phenol, kh sunfur, toluen, ancol benzylic, isopren, axit metacrylic, vinyl axetat, phenyl amin, axit benzoic. S cht phn ng c vi dung dch nc brom nhit thng l A. 6. B. 5. C. 4. D. 3. Cu 28. Dy gm cc cht u c kh nng lm i mu dung dch qu tm l A. CH3NH2, C2H5NH2, HCOOH B. C6H5NH2 , C2H5 NH2, HCOOH C. CH3NH2, C2H5NH2, H2N-CH2-COOH D. CH3NH2, C6H5OH, HCOOH Cu 29. Cho cc cht C4H10O,C4H9Cl,C4H10,C4H11N. S ng phn cu to ca cc cht gim theo th t l A. C4H11N, C4H10O, C4H9Cl, C4H10 B. C4H10O, C4H9Cl, C4H11N, C4H10 C. C4H10O, C4H9Cl, C4H10, C4H11N. D. C4H10O, C4H11 N, C4H10, C4H9Cl Cu 30. Cho s sau: 0 KOH du X (C4H9O2N) NaOH X1 HCl X2 CH3OH, HCl khan X3 H2N-CH2COOK ,t Vy X2 l: A. H2N-CH2-COOH B. ClH3N-CH2COOH C. H2N-CH2-COONa D. H2N-CH2-COOC2H5 Cu 31. Cho cc cht lng C2H5OH, C6H5OH, C6H5NH2, cc dung dch C6H5ONa, NaOH, CH3COOH, HCl. Cho cc cht trn tc dng vi nhau tng i mt iu kin thch hp. S cp cht xy ra phn ng ho hc l A. 9 B. 10 C. 11 D. 8 Cu 32: Cho 6 th nghim sau (phn ng xy ra hon ton) - Cho etyl amin tc dng vi lng d dd {NaNO2 + HCl} - Cho etyl amin tc dng vi CH3I theo t l mol 1:1 - Cho nitrobenzen tc dng vi hn hp {Fe + dd HCl} d - Cho NH3 d tc dng vi C2H5I Gio vin: Nguyn Cao Chung -2D: 0973904885

Trng THPT K Thut L Thy-Qung Bnh ng cp t duy ca ngi hc Ha! - Cho anilin tc dng vi dd HCl d - Thu phn hon ton protein n gin S th nghim thu c amin l: A. 3 B. 2 C. 4 D. 5 Cu 33: Khi vit ng phn ca C4 H11N v C4H10O mt HS nhn xt: 1. S ng phn ca C4H10O nhiu hn s ng phn C4H11N. 2. C4H11N c 3 ng phn amin bc I. 3. C4H11N c 3 ng phn amin bc II. 5. C4H10O c 7 ng phn ancol no v ete no. 4. C4H11N c 1 ng phn amin bc III. Nhn xt ng gm: A. 1, 2, 3, 4. B. 2, 3, 4. C. 3, 4, 5. D. 2, 3, 4, 5. Cu 34: C7H9N c s ng phn cha nhn thm l A. 6. B. 5. C. 4. D. 3. Cu 35: S ng phn cu to amino axit c CTPT C4H9 O2N l A. 5. B. 2. C. 3. D. 4. Cu 36. Cho glyxin tc dng vi axit glutamic to ra ipeptit mch h. S lng ipeptit c th to ra l: A. 1 B. 4 C. 3 D. 2 Cu 37: Chn cu sai A. Oligopeptit gm cc peptit c t 2 n 10 gc -amino axit. B. Lin kt ca nhm CO vi nhm NH gia 2 n v -amino axit c gi l lin kt peptit. C. Polipeptit gm cc peptit c t 10 n 50 gc -amino axit. D. Peptit l nhng hp cht cha t 2 n 50 gc -amino axit lin kt vi nhau bng cc lin kt peptit. Cu 38: Cho cc hp hu c thuc: Ankaien. Anken. Ankin. Ancol khng no (c 1 lin kt i) mch h, hai chc. Anehit no, mch h, hai chc. Axit khng no (c 1 lin kt i), mch h, n chc. Amino axit (c mt nhm chc amino v 2 nhm chc cacboxyl), no, mch h. Tng s cc loi hp cht hu c trn tho mn cng thc CnH2n-2OxNy (x, y thuc nguyn) l A. 4 B. 5 C. 3 D. 2 Cu 39: Cho cc cht A (C4H10), B (C4H9Cl), C (C4 H10O), D (C4H11N). Nguyn nhn gy ra s tng s lng cc ng phn t A n D l do A. ha tr ca cc nguyn t th tng lm tng th t lin kt trong phn t. B. m in khc nhau ca cc nguyn t. C. cc bon c th to nhiu kiu lin kt khc nhau. D. khi lng phn t khc nhau. Cu 40: Cho cc cht A (C4H10), B (C4 H9Cl), C (C4H10O), D (C4H11N). S lng cc ng phn ca A, B, C, D tng ng l A. 2; 4; 6; 8. B. 2; 3 ; 5; 7. C. 2; 4; 7; 8. D. 2; 4; 5; 7.

Dng 2: Amino axit tc dng vi axit hoc baz

Cu 1: Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc va vi 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l A. 8 v 1,0. B. 8 v 1,5. C. 7 v 1,0. D. 7 v 1,5. Cu 2: a) Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung dch Y cha (m+30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha (m+36,5) gam mui. Gi tr ca m l A. 112,2 B. 165,6 C. 123,8 D. 171,0 b) Hn hp X gm glyxin v Lysin. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung dch Y cha (m+22) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha (m + 51,1) gam mui. Gi tr ca m l : A. 112,2 g B. 103,4 g C. 123,8 g D. 171,0 g Cu 3: Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. H2NC2H3(COOH)2. B. H2NC3H5(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH Cu 4: Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l : A. C4H10O2N2. B. C5 H9O4N. C. C4H8O4N2. D. C5H11 O2N. Cu 5: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l: A. H2NC4 H8COOH. B. H2NC3 H6COOH. C. H2NC2H4COOH. D. H2NCH2COOH. Cu 6: -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui Gio vin: Nguyn Cao Chung -3D: 0973904885

Trng THPT K Thut L Thy-Qung Bnh ng cp t duy ca ngi hc Ha! khan. Cng thc cu to thu gn ca X l :(cho H = 1, C = 12, N = 14, O = 16, Cl = 35,5) A. H2NCH2COOH. B. H2NCH2CH2COOH. C. CH3CH2CH(NH2)COOH. D. CH3CH(NH2)COOH Cu 7: -amino axit X cha mt nhm NH2. Cho 10,3 g X tc dng vi axit HCl (d), thu c 13,95 g mui khan. CTCT thu gn ca X l B. H2NCH2 CH2COOH. A. CH3CH2CH(NH2)COOH. C. CH3CH(NH2)COOH. `D. H2NCH2COOH. Cu 8: Cho mt -amino axit X c mch cacbon khng phn nhnh. - Ly 0,01mol X phn ng va vi dd HCl thu c 1,835g mui. - Ly 2,94g X phn ng va vi dd NaOH thu c 3,82g mui. Xc nh CTCT ca X? A. CH3CH2CH(NH2)COOH. B. HOOCCH2CH2CH(NH2)COOH. C. HCOOCH2CH(NH2)CH2COOH. D. HOOCCH2CH2CH2CH(NH2)COOH. Cu 9: X l mt amino axit no ch cha 1 nhm NH2 v 1 nhm COOH. Cho 15,1 g X tc dng vi HCl d thu c 18,75 g mui. CTCT ca X l A. H2N-CH2-COOH. B. CH3-CH(NH2)-COOH. C. C6H5-CH(NH2)-COOH. D. C3H7-CH(NH2)-COOH. Cu 10: Trung ho 1 mol -amino axit X cn 1 mol HCl to ra mui Y c hm lng clo l 28,286% v khi lng. CTCT ca X l A. H2N-CH2-CH(NH2)-COOH. B. H2N-CH2 -COOH. C. CH3-CH(NH2 )-COOH. D. H2N-CH2-CH2-COOH. Cu 11: Hp cht Y l 1 - amino axit. Cho 0,02 mol Y tc dng va vi 80 ml dd HCl 0,25M. Sau c cn c 3,67 gam mui. Mt khc trung ho 1,47 gam Y bng 1 lng va dd NaOH, c cn dd thu c 1,91 gam mui. Bit Y c cu to mch khng nhnh. CTCT ca Y l: A. H2N CH2 CH2 COOH B. CH3 CH(NH2) COOH C. HOOC CH2 CH2 CH(NH2) COOH D. HOOC CH2 CH(NH2) COOH Cu 12: Amino axit X mch khng nhnh cha a nhm COOH v b nhm NH2. Khi cho 1 mol X tc dng ht vi dd NaOH thu c 144 gam mui. CTPT ca X l: A. C3H7 NO2 B. C4H7NO4 C. C4H6N2 O2 D. C5H7 NO2 Cu 13: Cht A c phn trm khi lng cc nguyn t C,H, O, N ln lt l 32,00%, 6,67%, 42,66%, 18,67%. T khi hi ca A so vi khng kh nh hn 3. A va tc dng vi dd NaOH va tc dng vi dd HCl. CTCT ca A l: A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 14: Cht A c phn trm cc nguyn t C,H, N, O ln lt l 40,45%, 7,86%, 15,73%, cn li l O. Khi lng mol phn t ca A nh hn 100g/mol. A va tc dng vi dd NaOH va tc dng vi dd HCl, c ngun gc t thin nhin. Cng thc cu to ca A l: A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2 N-CH2-COOH D. H2N-(CH2)3-COOH Cu 15: un 100ml dung dch mt aminoaxit 0,2M tc dng va vi 80ml dd NaOH 0,25M. Sau phn ng ngi ta chng kh dung dch thu c 2,5g mui khan. Mt khc, li ly 100g dung dch aminoaxit ni trn c nng 20,6% phn ng va vi 400ml dung dch HCl 0,5M. CTPT ca aminoaxit: A. H2NCH2 COOH B. H2NCH2CH2COOH C. H2N(CH2)3COOH D. a v c ng Cu 16: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l A. H2NC4 H8COOH. B. H2NC3 H6COOH. C. H2NC2H4COOH. D. H2NCH2COOH. Cu 17: Hp cht hu c X ch cha hai loi nhm chc amino v cacboxyl. Cho 100ml dung dch X 0,3M phn ng va vi 48ml dd NaOH 1,25M. Sau em c cn dung dch thu c c 5,31g mui khan. Bt X c mch cacbon khng phn nhnh v nhm NH2 v tr alpha. CTCT ca X: A. CH3CH(NH2)COOH B. CH3C(NH2)(COOH)2 C. CH3CH2C(NH2)(COOH)2 D. CH3CH2CH(NH2)COOH Cu 18:un nng 100 ml dung dch amino axit 0,2 M tc dng va vi 80 ml dung dch NaOH 0,25 M hoc vi 80 ml dung dch HCl 0,5 M. Cng thc phn t ca amino axit l: A. (H2N)2C2H3 -COOH B. H2N-C2H3 (COOH)2 C. (H2N)2C2H2(COOH)2 D. H2N-C2H4-COOH Cu 19: Cho 15 gam hn hp 3 amino axit tc dng va vi dung dch HCl 1,2 M th thu c 18,504 gam mui .Vy th tch dung dch HCl phi dng l: A. 0,8 lt B. 0, 08 lt C. 0,4 lt D. 0,04 lt

Gio vin: Nguyn Cao Chung

-4-

D: 0973904885

Trng THPT K Thut L Thy-Qung Bnh ng cp t duy ca ngi hc Ha! Cu 20: X l mt amino axit no ch cha mt nhm COOH v 1 nhm NH2. Cho 2,06 gam X phn ng va vi NaOH, c cn dung dch sau phn ng thu c 2,5 g mui. Vy cng thc ca X l: A. H2N-CH2-COOH B. CH3 -CH(NH2)COOH D. C3H7CH(NH2)COOH. C. CH3 -CH(NH2)CH2COOH Cu 21: Cho 22,15 g mui gm CH2NH2 COONa v CH2NH2CH2 COONa tc dng va vi 250 ml dung dch H2SO4 1M. Sau phn ng c cn dung dch th lng cht rn thu c l : A. 46,65 g B. 45,66 g C. 65,46 g D. Kt qu khc Cu 22: Cho 4,41 g mt aminoaxit X tc dng vi dung dch NaOH d cho ra 5,73 g mui. Mt khc cng lng X nh trn nu cho tc dng vi dung dch HCl d thu c 5,505 g mui clorua. Xc nh CTCT ca X. A. HOOC-CH2CH2CH(NH2)COOH B. CH3CH(NH2)COOH D. C A v B C. HOOCCH2CH(NH2)CH2COOH Cu 23: Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l A. C4H10O2N2. B. C5 H9O4N. C. C4H8O4N2. D. C5H11 O2N. Cu 24: Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. H2NC2H3(COOH)2. B. H2NC3H5(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH Cu 25: Cho 2.46 gam hn hp gm HCOOH, CH3COOH, C6H5OH, H2NCH2COOH tc dng va vi 40 ml dung dch NaOH 1M. Tng khi lng mui khan thu c sau khi phn ng l A. 3.52 gam B. 6.45 gam C. 8.42 gam D. 3.34 gam Cu 26: Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l C. 0,70. D. 0,55. A. 0,50. B. 0,65. Cu 27. Amino axit mch khng phn nhnh X cha a nhm -COOH v b nhm -NH2. Khi cho 1mol X tc dng ht vi axit HCl thu c 169,5 gam mui. Cho 1 mol X tc dng ht vi dung dch NaOH thu c 177 gam mui.CTPT ca X l A. C4H7NO4 B. C3H7NO2 C. C4H6N2O2 D. C5H7NO2 Cu 28. Cho 0,1 mol -amino axit X tc dng va vi 50 ml dung dch HCl 2M. Trong mt th nghim khc, cho 26,7 gam X vo dung dch HCl d, sau c cn cn thn dung dch thu c 37,65 gam mui khan. Vy X l: B. Axit glutamic. C. Valin. D. Glyxin. A. Alanin. Cu 29. Hp cht X cha vng benzen, c cng thc phn t CxHyN. Khi cho X tc dng vi dung dch HCl thu c mui Y c cng thc dng RNH3Cl (R l gc hirocacbon). Phn trm khi lng ca nit trong X l 13,084%. S ng phn cu to ca X tha mn cc iu kin trn l A. 3. B. 4. C. 5. D. 6. Cu 30: Cho 25,65 gam mui gm H2NCH2COONa v H2NCH2CH2COONa tc dng va vi 250 ml dung dch H2SO41M. Sau phn ng c cn dung dch th khi lng mui do H2NCH2COONa to thnh l: A. 29,25 gam B. 18,6 gam C. 37,9 gam D. 12,4 gam Cu 31: Cho 0,02 mol cht X (X l mt -aminoaxit) phn ng va ht vi 160ml dd HCl 0,125 M th to ra 3,67g mui. Mt khc, 4,41g X khi tc dng vi mt lng NaOH va th to ra 5,73g mui khan. Bit X c mch cacbon khng phn nhnh. Vy cng thc cu to ca X l : B. CH3-CH2-CH(NH2 )-COOH A. HOOC-CH(NH2)-CH(NH2)-COOH. C. HOOC-CH2-CH2-CH(NH2 )-COOH. D. CH3-CH2 -CH2-CH(NH2)-COOH Cu 32: Cho 0,02 mol amino axit X tc dng va vi 200ml dung dch HCl 0,1M c 3,67gam mui khan. Mt khc 0,02mol X tc dng va vi 40gam dung dch NaOH 4%. S cng thc cu to ca X l: A. 2. B. 3. C. 4. D. 5. Cu 33: Cht X l mt aminoaxit. Cho 100ml dung dch X 0,02M phn ng va ht vi 160ml dung dch NaOH 0,25M. C cn dung dch sau phn ng ny th c 3,82g mui khan. Mt khc X tc dng vi HCl theo t l 1:1. Cng thc phn t ca X l: A. C3H7NO2 B. C4 H7NO4 C. C5H11NO4 D. C5H9 NO4 Cu 34: Cho m gam hn hp X gm axit glutamic v alanin tc dng vi dung dch HCl d. Sau phn ng lm bay hi cn thn dung dch thu c (m + 11,68) gam mui khan. Nu cho m gam hn hp X tc dng vi dung dch KOH va , sau phn ng lm bay hi cn thn dung dch thu c (m + 19) gam mui khan. Gi tr ca m l: A. 38,92 gam B. 35,4 gam C. 36,6 gam D. 38,61 gam Cu 35: Dung dch X cha 0,01 mol ClH3N-CH2-COOH, 0,02 mol CH3-CH(NH2)COOH; 0,05 mol HCOOC6 H5. Cho dung dch X tc dng vi 160 ml dung dch KOH 1M un nng phn ng xy ra hon ton. C cn dung dch sau phn ng thu c m gam cht rn khan. Gi tr ca m l: A. 12,535 gam B. 16,335 gam C. 8,615 gam D. 14,515 gam Gio vin: Nguyn Cao Chung -5D: 0973904885

Trng THPT K Thut L Thy-Qung Bnh ng cp t duy ca ngi hc Ha! Cu 36: Hn hp X gm 2 amino axit no, mch h. Ly 8,9 gam X cho tc dng vi dung dch HCl d c a gam mui, cng lng 8,9 gam X khi tc dng vi dung dch NaOH d th lng mui thu c l (a 1,45) gam. Hai amino axit l A. NH2C4H8COOH v NH2 C3H6COOH. B. NH2CH2COOH v NH2C2H4COOH. C. NH2C2H4COOH v NH2 C3H6COOH. D. NH2CH2COOH v NH2C3 H6COOH. Cu 37: -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l (cho H = 1, C = 12, N = 14, O = 16, Cl = 35,5) D. CH3CH(NH2)COOH. A. H2NCH2COOH. B. H2NCH2CH2COOH. C. CH3CH2CH(NH2)COOH. Cu 38: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l A. H2NC4 H8COOH. B. H2NC3 H6COOH. C. H2NC2H4COOH. D. H2NCH2COOH. Cu 39 :Hp cht A l mt -amino axit. Cho 0,01 mol A tc dng va vi 80 ml dung dch HCl 0,125M, sau c cn cn thn thu c 1,835 gam mui. Mt khc, khi trung ho 2,94 gam A bng dung dch NaOH va th c 3,82 gam mui. Hy: a. Xc nh cng thc cu to v gi tn A, bit A c cu to mch khng phn nhnh. b. Vit phng trnh phn ng ca A vi dung dch NaNO2 vi s c mt ca axit clohiric. b. Phn ng ca A vi NaNO2 v HCl : Cu 40: Bit A l mt aminoaxit 1/ C 0,01 mol A p va vi 80 ml dd HCl 0,125M, sau em c cn dd th thu c 1,835 gam mui khan. Tnh KLPT ca A? 2/ Trung ha 2,94 gam A bng NaOH va sau c cn c 3,82 gam mui khan. Tm CTCT v tn ca A bit nhm amino v tr ? Cu 41: Hp cht hu c A c 15,7303%N v 35,9551%O v khi lng. A tc dng vi HCl ch to ra R(O)z-NH3Cl (R l gc hidrocacbon). Xc nh CTCT ca A. Bit A tham gia phn ng trng ngng. Cu 42: Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Mt khc cho 0,01 mol A tc dng va vi dung dch HCl sau c cn cn thn thu c 1,835 gam mui. Cng thc ca X l : A. H2NC2H3(COOH)2. B. H2NC3H5(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH. Cu 43: Cho m1 gam -amino axit A (c tng s nhm chc khng vt qu 4) tc dng va vi 100 ml dung dch HCl 1M, sau c cn cn thn thu c 18,35 gam mui khan. Mt khc, khi trung ho m2 gam A bng 160ml dung dch NaOH 1,25M th c 19,1 gam mui khan. a. Xc nh cng thc cu to v gi tn A, bit A c cu to mch khng phn nhnh? b. Gi tn theo danh php thay th Cu 44. Cho dung dch X c cha 0,01 mol Glixin, 0,02 mol ClH3N-CH2-COOH v 0,03 mol phenyl fomat tc dng vi 150 ml dung dch NaOH 1M un nng c dung dch Y. C cn dung dch Y thu c cht rn khan c khi lng l A. 9,6 gam B. 6,12 gam C. 11,2 gam D. 11,93 gam Cu 45. Cho 17,8 gam hn hp hai amino axit no cha mt chc -COOH v mt chc -NH2 (t l khi lng phn t ca chng l 1,373) tc dng vi 110 ml dung dch HCl 2M, c dung dch A. tc dng ht cc cht trong dung dch A cn dng 140 ml dung dch KOH 3M. Phn trm s mol mi amino axit trong hn hp ban u bng A. 25% v 75%. B. 50% v 50%. C. 20% v 80%. D. 40% v 60%. Cu 46 : Cho m gam hn hp X gm axit glutamic v valin tc dng vi dung dch HCl (d), sau phn ng hon ton lm bay hi cn thn dung dch, thu c (m + 9,125) gam mui khan. Nu cho m gam X tc dng vi dung dch NaOH (d), kt thc phn ng to ra (m + 7,7) gam mui. Gi tr ca m l A. 26,40. B. 39,60. C. 33,75. D. 32,25. Dng 3: Amino axit tc dng vi axit hoc baz sau ly sn phm thu c tc dng vi baz hoc axit Cu 1: Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l : A. 0,50. B. 0,65. C. 0,70. D. 0,55. Cu 2: 0,01 mol amino axit Y phn ng va vi 0,01 mol HCl c cht Z. Cht Z phn ng va vi 0,02 mol NaOH. Cng thc ca Y c dng l A. H2NR(COOH)2. B. H2NRCOOH. C. (H2N)2RCOOH. D. (H2N)2R(COOH)2. Cu 3 : Mt amino axit A c cha 2 nhm chc amin, mt nhm chc axit. 100ml dd c cha A vi nng 1M phn ng va vi 100ml dd HCl aM c dd X, dd X phn ng va vi 100ml dd NaOH bM. Gi tr ca a, b ln lt l A. 2, 1. B. 1, 2. C. 2, 2. D. 2, 3. Cu 3: Cho 0,2 mol amino axit X phn ng va vi 100 ml dung dch HCl 2M thu c dung dch A.Cho dung dch A phn ng va vi dung dch NaOH, sau phn ng c cn sn phm thu c 33,9g mui. X c tn gi l: A. glixin B. alanin C. valin D. axit glutamic Gio vin: Nguyn Cao Chung -6D: 0973904885

Trng THPT K Thut L Thy-Qung Bnh ng cp t duy ca ngi hc Ha! Cu 4: X l 1 amino axit c cng thc tng qut dng H2N R COOH. Cho 8,9 gam X tc dng vi 200 ml dd HCl 1M thu c dd Y. phn ng ht vi cc cht trong dd Y cn dng 300 ml dd NaOH 1M. CTCT ng ca X l: A. H2N CH2 COOH B. H2N CH2 CH2 COOH D. CH3 CH2 CH(NH2) COOH C. CH3 CH(NH2) COOH Cu 5: A l mt -amino axit mch cacbon khng phn nhnh. Cho 0,1 mol A vo dung dch cha 0,25 mol HCl (d), c dung dch B. phn ng ht vi dd B, cn va 300 ml dd NaOH 1,5 M un nng. Nu c cn dung dch sau cng, th c 33,725 g cht rn khan. A l: A. Glixin B. Alanin C. axit glutamic D. axit -amino butiric Cu 6: Cho 0,1 mol amino axit phn ng va vi 200 ml dung dch HCl 0,5M, thu c dung dch X. Cho dd NaOH 0,5M vo dung dch X th thy cn dng va ht 600ml.Xc nh s nhm chc amino -NH2 v cacboxyl COOH ? Cu 7. X l mt -amino axit c cha vng thm v mt nhm NH2 trong phn t. Bit 50 ml dung dch X phn ng va vi 80 ml dung dch HCl 0,5M, dung dch thu c phn ng va vi 50 ml dung dch NaOH 1,6M. Mt khc nu trung ha 250 ml dung dch X bng lng va KOH ri em c cn thu c 40,6 gam mui. CTCT ca X l: A. C6H5-CH(CH3)-CH(NH2)COOH B. C6H5-CH(NH2)-CH2COOH C. C6H5-CH(NH2)-COOH D. C6H5-CH2CH(NH2)COOH Cu 8: Cho 0,1 mol alanin phn ng vi 100 ml dung dch HCl 1,5M thu c dung dch A. Cho A tc dng va vi dung dch NaOH thu c dung dch B, lm bay hi dung dch B thu c bao nhiu gam cht rn khan? A. 14,025 gam B. 8,775 gam C. 11,10 gam D. 19,875 gam Cu 9: Cho 0,15 mol hn hp X gm hai aminoaxit : R(NH2)(COOH)2 v R(NH2)2(COOH) vo 200 ml dung dch HCl 1,0 M, thu c dung dch Y. Y tc dng va ht vi 400 ml dung dch NaOH 1,0 M. S mol ca R(NH2 )(COOH)2 trong 0,15 mol X l : A. 0,1 mol B. 0,125 mol . C. 0,075 mol D. 0,05 mol Cu 10. Cho 27,15 gam tyrosin tc dng vi 225 ml dung dch HCl 1M thu c dung dch X. Cho X tc dng vi 600 ml dung dch NaOH 1M thu c dung dch Y. Tng khi lng cht rn khan thu c khi c cn cn thn dung dch Y l A. 40,9125 gam. B. 49,9125 gam. C. 52,6125 gam. D. 46,9125 gam. Cu 11: Ly 0,3 mol hn hp X gm H2NC3H5(COOH)2 v H2NCH2COOH cho vo 400ml dung dch HCl 1M th thu c dung dch Y. Y tc dng va vi 800ml dung dch NaOH 1M nthu c dung dch Z. Lm bay hi Z thu c m gam cht rn khan, gi tr ca m l? A. 52,2 gam B. 55,2 gam C. 28,8 gam D. 31,8 gam Cu 12: Cho m gam hn hp X gm hai -aminoaxit cng s mol, u no mch h, c 1 nhm amino v 1 nhm cacboxyl tc dng vi dd cha 0,44 mol HCl c dd Y. Y td va ht vi dd cha 0,84 mol KOH. t chy hon ton m gam X ri hp th sn phm chy bng dd KOH d thy khi lng bnh tng 65,6 g. CTCT 2 cht trong X l A. H2NCH(C2H5 )COOH v H2NCH(CH3 )COOH B. H2NCH2COOH v H2NCH(CH3)COOH C. H2NCH(C2H5)COOH v H2NCH2 CH2 COOH D. H2NCH2 COOH v H2NCH(C2 H5)COOH Cu 13: Cho -aminoaxit X ch cha mt chc NH2 tc dng vi 200ml dung dch NaOH 1M thu c dung dch Y. Dung dch Y phn ng va vi 500ml dung dch HCl 1M thu c dung dch Z. C cn cn thn dung dch Z thu c 49,35 gam cht rn khan. X l A. Valin. B. Lysin. C. Glyxin. D. Alanin. Cu 14: Cho 20,15 gam hn hp X gm glyxin v alanin phn ng vi 200 ml dung dch HCl 1M, thu c dung dch Y. Dung dch Y phn ng va vi 450 ml dung dch NaOH 1M. Thnh phn % v khi lng ca glyxin trong hn hp X l A. 55,83%. B. 53,58%. C. 44,17%. D. 47,41%. Cu 15:Cho dung dch cha 0,01 mol mt aminoaxit A tc dng va vi 100ml dung dch HCl 0,1M thu c dung dch X , tc dng ht vi dung dch X cn ti thiu 300ml NaOH 0,1M, c cn dung dch sau phn ng thu c 2,845 gam cht rn. A l: A. Lysin. B. Axit glutamic. C. Tyrosin. D. Alanin. Cu 16: Cho 0,12 mol alanin tc dng va vi dung dch HCl thu c dung dch X. Thm vo dung dch X 300 ml dung dch NaOH 1M thu c dung dch Y. C cn dung dch Y thu c m gam cht rn khan. Bit khi c cn khng xy ra phn ng ho hc. Gi tr ca m l: A. 17,70 gam B. 22,74 gam C. 20,10 gam D. 23,14 gam Cu 17: Cho 19,2 gam hn hp gm hai amino axit no cha mt chc axit v mt chc amin (t l khi lng phn t ca chng l 1,373) tc dng vi 110 ml dung dch HCl 2M, c dung dch A. tc dng ht vi cc cht trong dung dch A cn dng 140 ml dung dch KOH 3M. Phn trm s mol ca mi aminoaxit trong hn hp ban u bng: A. 25% v 75%. B. 20% v 80%. C. 50% v 50%. D. 40% v 60%. Cu 18: Cho 13,35 g hn hp X gm CH2 NH2CH2COOH v CH3CHNH2 COOH tc dng vi V ml dung dch NaOH 1M thu c dung dch Y. Bit dung dch Y tc dng va vi 250 ml dung dch HCl 1M. Gi tr ca V l : A. 100 ml B. 150 ml C. 200 ml D. 250 ml

Gio vin: Nguyn Cao Chung

-7-

D: 0973904885

Trng THPT K Thut L Thy-Qung Bnh ng cp t duy ca ngi hc Ha! Cu 19: Cho 20,15 g hn hp X gm (CH2NH2COOH v CH3 CHNH2COOH) tc dng vi 200 ml dung dch HCl 1M thu c dung dch Y. Y tc dng va vi 450 ml dung dch NaOH. Phn trm khi lng ca mi cht trong X l: A. 55,83 % v 44,17 % B. 53,58 % v 46,42 % C. 58,53 % v 41,47 % D. 52,59 % v 47,41% Cu 20 : Ly 20 ml amino axit X c 1 nhm -NH2 phn ng vi 100 ml dung dch HCl 0,1M thu c dung dch Y .Cho dung dch Y phn ng va vi 300 ml dung dch NaOH 0,1M. Mt khc trung ha ht 250 ml X bi KOH sau phn ng c cn sn phm thu c 26,125 g mui. Xc nh cng thc CT ca X ? Cu 21: Ly m gam hn hp X gm hai amino axit c 1 nhm -NH2 v 1 nhm -COOH phn ng vi 55 ml dung dch HCl 2M thu c dung dch Y . tc dng ht vi cc cht trong dung dch Y cn dng 70 ml dung dch KOH 3M. Mt t chy hon ton m(g) X v cho sn phm chy qua dd KOH d th khi lng bnh ny tng thm 14,85 gam .Bit t l phn t khi gia hai amino axit l 1,187. Xc nh cng thc CT ca X ? Cu 22 : Cho hn hp A gm ( 0,15 mol axit glutamic v 0,1 mol glyxin ) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dd X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l A. 0,80. B. 0,60. C. 0,75. D. 0,65. Cu 23: Cho m gam aminoaxt ( trong phn t ch cha mt nhm NH2 v mt nhm COOH), tc dng vi 110ml dd HCl 2M c dd X. phn ng ht vi cc cht trong dd X cn 200 gam dd NaOH 8,4% c dd Y, c can dd Y th c 32,27 gam cht rn. Cng thc phn t ca aminoaxt trn l: A. NH2CH2COOH B. NH2 C2H2COOH C. NH2C2H4COOH D. NH2C3H6COOH Cu 24: Hn hp X gm 2 aminoaxit (H2N)2R1COOH v H2NR2(COOH)2 c s mol bng nhau tc dng vi 550ml dung dch HCl 1M thu c dung dch Y. Y tc dng va vi 1 lt dung dch NaOH 1M. Vy khi to thnh dung dch Y th? A. HCl v aminoaxit va B. HCl d 0,1 mol C. HCl d 0,3 mol D. HCl d 0,25 mol Cu 25: Hn hp M gm hai cht CH3COOH v NH2CH2COOH. trung ho m gam hn hp M cn 100ml dung dch HCl 1M. Ton b sn phm thu c sau phn ng li tc dng va vi 300ml dung dch NaOH 1M. Thnh phn phn trm theo khi lng ca cc cht CH3COOH v NH2CH2 COOH trong hn hp M ln lt l ; A. 61,54 v 38,46. B. 72,80 v 27,20. C. 44,44 v 55,56 D. 40 v 60. Cu 26: X l axit , iaminobutiric. Cho dung dch cha 0,25 mol X tc dng vi 400 ml dung dch NaOH 1M, sau cho vo dung dch thu c 800ml dung dch HCl 1M v sau khi phn ng kt thc c cn dung dch s thu c bao nhiu gam cht rn khan : A. 47,75 gam B. 74,7 gam C. 35 gam D. 56,525 gam Dng 4: Este ca amino axit v mui ca aminoaxit vi axit (v c ,hu c) hoc vi (NH3 ,amin ) Cng thc CnH2n+1NO2 c cc ng phn sau : - Amino axit , este aminoaxit , mui to ra t axit hu c khng no vi NH3 hoc amin no v ngc li ; hp cht nitro - NO2 V d: C3H7NO2 c cc p sau: CH2 = CHCOONH4 ; H2N COOCH2 CH3 ; H2N CH2 COOCH3 ; H2NCH(CH3 )COOH H2NC2H4COOH ; HCOONH3CH = CH2 ; CH3-CH2 - CH2 -NO2 ; CH3-CH(CH3)-NO2 Cu 1: (K) l hp cht hu c c CTPT l: C5H11NO2. un (K) vi dd NaOH thu c hp cht c CTPT l C2H4 O2NNa v hp cht hu c (L). Cho hi (L) qua CuO/to thu c mt cht hu c (M) c kh nng tham gia phn ng trng bc. CTCT ca (K) l A. CH2=CH-COONH3-C2H5. B. NH2-CH2-COO-CH2-CH2-CH3. C. NH2-CH2-COO-CH(CH3)2. D. H2N-CH2-CH2-COO-C2H5. Cu 2: Cho 8,9 g mt hp cht hu c X c CTPT C3H7 O2N phn ng vi 100 ml dd NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dd thu c 11,7 g cht rn. CTCT thu gn ca X l B. H2NCH2 COOCH3. A. H2NCH2CH2COOH. C. CH2=CHCOONH4. D. HCOOH3NCH=CH2. Cu 3: t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 (cc kh o ktc) v 3,15 g H2O. Khi X tc dng vi dd NaOH thu c sn phm c mui H2N-CH2COONa. CTCT thu gn ca X l A. H2N-CH2-COO-C3H7. B. H2N-CH2 -COO-C2H5. C. H2N-CH2-CH2-COOH. D. H2N-CH2-COO-CH3. Cu 4: Cho hn hp X gm 2 cht hu c c cng cng thc phn t C3H10N2O2 tc dng va vi dung dch NaOH v un nng thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m) hn km nhau mt nguyn t C . T khi hi ca Z i vi H2 bng 13,75 .C cn dung dch Y thu c khi lng mui khan l: A. 16,5 gam B. 20,1 gam C. 8,9 gam D. 15,7 gam Gi : 2 cht l: NH2CH2CH2COONH4 v NH2CH2COONH3 CH3 Cu 5: a) Hp cht X c CTPT trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt Gio vin: Nguyn Cao Chung -8D: 0973904885

Trng THPT K Thut L Thy-Qung Bnh ng cp t duy ca ngi hc Ha! bng 40,449%; 7,865% v 15,73%, cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dd NaOH (un nng) thu c 4,85 mui khan. CTCT thu gn ca X l: A. CH2 = CHCOONH4 B. H2N COOCH2 CH3 D. H2NC2H4COOH C. H2N CH2 COOCH3 b) Khi cho 10,6 gam X c cng thc phn t C3 H10N2O2 phn ng vi mt lng va dd NaOH (un nng) thu c 8,3 gam mui khan v kh Y bc 1 lm xanh qu m.CTCT thu gn ca X l: A. NH2COONH2(CH3)2 B. NH2CH2CH2COONH4 C. NH2COONH3CH2 CH3 D. NH2CH2COONH3CH3 Cu 6: a) Este A c iu ch t amino axit B v ancol metylic. t chy hon ton 0,1 mol A thu c 1,12 lt N2 (ktc), 13,2 gam CO2 v 6,3 gam H2O. Bit t khi ca A so vi H2 l 44,5. CTCT ca A l: A. H2N CH2 COOH B. H2N CH2 CH2 COOCH3 D. CH2 CH = C(NH2) COOCH3 C. CH3 CH(NH2) COOCH3 b) Este A c iu ch t amino axit B v ancol metylic. t chy hon ton 8,9 gam A thu c 1,12 lt N2 (ktc), 13,2 gam CO2 v 6,3 gam H2O. Bit t khi ca A so vi H2 l 44,5. CTCT ca A l: A. H2N CH2 COOH B. H2N CH2 CH2 COOCH3 C. CH3 CH(NH2) COOCH3 D. CH2 CH = C(NH2) COOCH3 Cu 7: Mt HCHC X c t l khi lng C:H:O:N = 9: 1,75: 8: 3,5 tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 v mi trng hp ch to mt mui duy nht. Mt ng phn Y ca X cng tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 nhng ng phn ny c kh nng lm mt mu dd Br2. Cng thc phn t ca X v cng thc cu to ca X, Y ln lt l: A. C3H7O2N; H2N-C2H4 -COOH; H2 N-CH2-COO-CH3 B. C3H7O2N; H2N-C2H4-COOH; CH2=CH-COONH4 C. C2H5O2N; H2N-CH2 -COOH; CH3-CH2-NO2 D. C3H5O2N; H2N-C2H2-COOH; CHC-COONH4 Cu 8: (X) l HCHC c thnh phn v khi lng phn t l 52,18%C, 9,40%H, 27,35%O, cn li l N. Khi un nng vi dd NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t0 thu c cht hu c (Z) c kh nng tham gia phn ng trng gng. Cng thc cu to ca X l: A. CH3(CH2)4NO2 B. NH2-CH2COO-CH2 -CH2-CH3 C. NH-CH2-COO=CH(CH2)3 D. H2N-CH2-CH2-COOC2H5 Cu 9: Thc hin phn ng este gia amino axit X v ancol CH3OH thu c este Y c t khi hi so vi khng kh bng 3,069. CTCT ca X: A. H2N-CH2-COOH B. H2N-CH2-CH2-COOH D. H2N-(CH2)3-COOH C. CH2 -CH(NH2)-COOH Cu 10: Cht X c cng thc phn t C4H10O2NCl. un nng X vi dung dch NaOH thu c cc sn phm NaCl, H2NCH2- COONa, v ru Y. Cng thc cu to ca X l: A. CH3-CH2-COO-CH2-NH3Cl B.CH3-CH2-OOC- CH2-NH3Cl C. CH3 -COO-CH2-CH2-NH3Cl D.CH3- CH- COO-CH2-Cl NH2 Cu 11: Cc cht X, Y, Z c cng CTPT C2H5O2 N. X tc dng c c vi HCl v Na2O. Y tc dng c vi H mi sinh to ra Y1 . Y1 tc dng vi H2SO4 to ra mui Y2. Y2 tc dng vi NaOH ti to li Y1. Z tc dng vi NaOH to ra mt mui v kh NH3. CTCT ng ca X, Y, Z l : A. X (HCOOCH2NH2), Y (CH3COONH4), Z (CH2NH2COOH) B. X (CH3COONH4), Y (HCOOCH2NH2), Z (CH2 NH2COOH) C. X (CH3COONH4), Y (CH2NH2COOH), Z (HCOOCH2NH2) D. X (CH2 NH2COOH), Y (CH3CH2NO2), Z (CH3 COONH4) Cu 12: Cho 12,55 gam mui CH3CH(NH3Cl)COOH tc dng vi 150 ml dung dch Ba(OH)2 1M. C cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l : A. 15,65 g B. 26,05 g C. 34,6 g D. Kt qu khc Cu 13: (A) l mt hp cht hu c c CTPT C5H11O2N. un (A) vi dung dch NaOH thu c mt hp cht c CTPT C2H4O2NNa v cht hu c (B). Cho hi qua CuO/t0 thu c cht hu c (D) c kh nng cho phn ng trng gng. CTCT ca A l : A. CH2 = CH - COONH3 - C2H5 B. CH3 (CH2)4NO2 C. H2N- CH2 - CH2 - COOC2H5 D. NH2 - CH2COO - CH2 - CH2 - CH3 Cu 14: Cht hu c A c mt nhm amino, 1 chc este. Hm lng oxi trong A l 31,07 %. X phng ha m gam cht A c ancol, cho hi ancol i qua CuO d, to thu andehit B. Cho B phn ng vi dd AgNO3/NH3 thu c 16,2 gam Ag v mt mui hu c. Gi tr ca m l A. 3,3375 gam B. 7,725 gam C. 6,675 gam D. 3,8625 gam Gio vin: Nguyn Cao Chung -9D: 0973904885

Trng THPT K Thut L Thy-Qung Bnh ng cp t duy ca ngi hc Ha! Cu 15: Cht hu c M c mt nhm amino, mt chc este. Hm lng oxi trong M l 35,96 %. X phng ha a gam cht M c ancol. Cho ton b hi ancol i qua CuO d, to thu andehit Z. Cho Z phn ng vi dung dch AgNO3/NH3 d, thu c 16,2 gam Ag. Gi tr ca a l: ( hiu sut phn ng 100%) A. 7,725 gam B. 3,3375 gam C. 3,8625 gam D. 6,675 gam Cu 16: Hai ng phn X, Y trong c 1 cht lng v 1 cht rn c thnh phn 40,45%C, 7,86%H, 15,73%N cn li l oxi. Khi cho cht lng bay hi thu c cht hi c t khi so vi khng kh l 3,069. Khi phn ng vi NaOH, X cho mui C3H6 O2NNa, Y cho mui C2H4O2NNa.Cng thc cu to v trng thi ca X, Y l A. X l cht lng CH3-CH(NH2)-COOH, Y l cht rn NH2 -CH2COOCH3 B. X l cht rn CH2(NH2)-CH2COOH, Y l cht lng NH2-CH2OOCCH3 C. X l cht lng CH2(NH2)-CH2COOH, Y l cht rn NH2-CH2OOCCH3 D. X l cht rn CH3-CH(NH2)-COOH, Y l cht lng NH2 -CH2COOCH3. Cu 17: X l este to bi -amino axit Y (cha 1 nhm -COOH v 1 nhm -NH2) vi ru n chc Z. Thy phn hon ton 0,1 mol X trong 200 ml dung dch NaOH 1M, c cn dung dch thu c 13,7 gam cht rn v 4,6 gam ru Z. Vy cng thc ca X l: A. CH3-CH(NH2)-COOC2H5 B. CH3-CH(NH2)-COOCH3 C. H2N-CH2-COOC2H5 D. H2N-CH2-COOCH2-CH=CH2 Cu 18: Mt hp cht X (c khi lng phn t bng 103). Cho 51,50 gam X phn ng ht vi 500 ml dung dch NaOH 1,20M, thu c dung dch Y trong c mui ca aminaxit, ancol (c khi lng phn t ln hn khi lng phn t O2), C cn Y thu m gam cht rn. Gi tr m l A. 52,50 B. 26,25 C. 48,50 D. 24,25 Cu 19: Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. un 25,75 gam X vi 300 ml dung dch NaOH 1M, sau phn ng hon ton thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l A. 27,75 gam B. 26,25 gam C. 29,75 gam D. 24,25 gam Cu 20. a) A l este ca axit glutamic , khng tc dng vi Na . Thy phn han ton mt lng cht A trong 100ml dung dch NaOH 1M ri c cn , thu c mt ru B v cht rn khan C . un nng lng ru B trn vi H2SO4 c 1700C thu c 0,672 lt lfin (kc) vi hiu sut phn ng l 75% . Cho ton b cht rn C tc dng vi dung dch HCl d ri c cn , thu c cht rn khan D. Khi lng cht rn D l : A . 10,85gam B . 7,34 gam C . 9,52 gam D .5,88gam b) Este X c iu ch t aminoaxit glutamic v ancol etylic. Cho 0,1 mol X vo 200 ml dung dch NaOH 1,5M, sau khi phn ng xy ra hon ton, c cn cn thn dung dch thu c cht rn G. Cho ton b cht rn G vo dung dch HCl d, sau c cn cn thn li thu c m gam cht rn E. Gi tr ca m l: A. 26,4 g. B. 18,35 g C. 30,05 g D. 35,9 g Cu 21: Cht X c cng thc phn t C4H9 O2N Bit: X + NaOH Y + CH4O Y + HCl (d) Z + NaCl Cng thc cu to ca X v Z ln lt l A. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH. B. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH. B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH. C. H2NCH2COOC2H5 v ClH3NCH2COOH. Cu 22. Cht hu c X c 1 nhm amino, 1 chc este. Hm lng N c trong X l 15,73%. X phng ho m gam X thu c hi ancol Z, cho Zqua CuO d thu c andehit Y ( phn ng hon ton), cho Y phn ng hon ton AgNO3/NH3d thu c 16,2 gam Ag . gi tr m l. A.7,725 B.6,675 C.3,3375 D .5,625 Cu 23: X l este to bi -amino axit Y (cha 1 nhm -COOH v 1 nhm -NH2) vi ancol n chc Z. Thy phn hon ton 0,1 mol X trong 200 ml dung dch NaOH 1M, c cn dung dch thu c 13,7 gam cht rn v 4,6 gam ancol Z. Vy cng thc ca X l: A. CH3-CH(NH2)-COOC2H5 B. CH3-CH(NH2)-COOCH3 C. H2N-CH2-COOC2H5 D. H2N-CH2-COOCH2-CH=CH2 Cu 24: Cht X c cng thc phn t C8H15O4N. T X, thc hin bin ha sau: C8 H15O4N + NaOH tC NaOOC-(CH)2CH(NH2 )COONa + CH4 O + C2H6O Hy cho bit, X c th c bao nhiu cng thc cu to? A. 4. A. 1. C. 3. D. 2. Cu 25: Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc hirocacbon), phn trm khi lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ha thnh anehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l: A. 2,67 B. 4,45 C. 5,34 D. 3,56

Gio vin: Nguyn Cao Chung

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Trng THPT K Thut L Thy-Qung Bnh

ng cp t duy ca ngi hc Ha!

Dng 5: t chy aminoaxit

Cu 1: Dng 16,8 lt khng kh ktc (O2 chin 20% v N2 chim 80% th tch) t chy hon ton 3,21 gam hn hp A gm 2 aminoaxt k tip nhau c cng thc tng qut CnH2n+1O2N. Hn hp thu c sau phn ng em lm kh c hn hp kh B, cho B qua dd Ca(OH)2 d thu 9,5gam kt ta. a) Tm CTCT v khi lng ca 2 aminoaxt. b) Nu cho kh B vo bnh dung tch 16,8 lt, nhit 136,50C th p sut trong bnh l bao nhiu ? Cho bit aminoaxt khi t chy to kh N2 . Cu 2 : t chy hon ton 8,7 gam aminoaxit A (axit n chc)th thu c 0,3 mol CO2 v 0,25 mol H2O v 1,12 lt (kc) ca N2 . Xc nh cng thc cu to ca A? Cu 3: t chy 0,2 mol hp cht A thuc loi tp chc, thu c 26,4 gam kh CO2; 12,6 gam hi H2O v 2,24 lt kh N2 (ktc). Nu t chy 1 mol A cn 3,75 mol O2. Xc nh cng thc phn t ca A. Cu 4: t chy hon ton 17,8 gam hp cht amino axit X c ly t thin nhin ngi ta thu c 13,44 lt kh CO2, 12,6 gam nc v 1,12 lt N2. Mt khc, khi cho 0,1 mol X phn ng ht vi hn hp NaNO2 v HCl, ngi ta c 2,24 lt kh N2. Cc cht kh u o iu kin tiu chun. Cng thc cu to ca X l: B. H2NCH2COOH A. H2NCH(C2H5)COOH C. H2NCH(CH3)COOH D. H2NCH2CH2COOH Cu 5: :t chy hon ton 45,1 gam hn hp X gm CH3CH(NH2)COOH v CH3COONH3CH3 thu c CO2, H2O v N2 c tng khi lng l 109,9 gam. Phn trm khi lng mi cht trong hn hp X ln lt l : A. 39,47% v 60,53% B. 35,52% v 64,48%. C. 59,20% v 40,80% D. 49,33% v 50,67% Cu 6: t chy hon ton 0,25 mol hn hp X gm aminoaxit H2NR(COOH)x v mt axit no, h ,n chc, thu c 0,6 mol CO2 v 0,675 mol nc. Mt khc, 0,2 mol X phn ng va vi dung dch cha a mol HCl. Gi tr ca a l : A. 0,2 mol B. 0,25 mol C. 0,12 mol D. 0,1 mol Cu 7. Aminoaxit X (ch cha amin bc 1) c cng thc CxHyO2N. t chy hon ton 0,1 mol X ri cho ton b sn phm chy hp th vo bnh ng dung dch NaOH c thy khi lng bnh tng thm 25,7 g. S cng thc cu to ca X l: A. 3. B. 4. C. 5. D. 6. Cu 8: Hn hp X gm 2 amino axit no bc 1 Y v Z. Y cha 2 nhm axit, mt nhm amino; Z cha mt nhm axit, mt nhm amino. MY/MZ = 1,96. t chy 1mol Y hoc 1 mol Z th s mol CO2 thu c nh hn 6. Cng thc cu to ca hai amino axit l: A. H2NCH2 CH(COOH) CH2 COOH v H2 NCH2 COOH B. H2NCH2 CH(COOH) CH2 COOH v H2N [CH2]2 COOH C. H2N CH(COOH) CH2 COOH v H2NCH2 COOH D. H2N CH(COOH) CH2 COOH v H2N [CH2]2 COOH Cu 9: Mt amino axit (X) c cng thc tng qut NH2RCOOH. t chy hon ton a mol X thu c 6,729 (l) CO2 (ktc) v 6,75 g H2 O. CTCT ca X l : A. CH2NH2 COOH B. CH2NH2CH2 COOH C. CH3CH(NH2)COOH D. C B v C Cu 10: Xc nh th tch O2 (ktc) cn t chy ht 22,455 g hn hp X gm (CH3 CH(NH2)COOH v CH3COOCNH3CH3). Bit sn phm chy c hp th ht vo bnh ng dung dch NaOH th khi lng bnh tng 85,655 g. A. 44,24 (l) B. 42,8275 (l) C. 128,4825 (l) D. Kt qu khc Cu 11: t chy hon ton 45,1 gam hn hp X gm CH3CH(NH2)COOH v CH3COONH3CH3 thu c CO2, H2O v N2 c tng khi lng l 109,9 gam. Phn trm khi lng mi cht trong hn hp X ln lt l A. 39,47% v 60,53% B. 35,52% v 64,48%. C. 59,20% v 40,80% D. 49,33% v 50,67% Cu 12: Amino axit (Y) c cng thc dng NCxHy(COOH)m. Ly mt lng axit aminoaxetic (X) v 3,82g (Y). Hai cht (X) v (Y) c cng s mol. t chy hon ton lng (X) v (Y) trn, th tch kh oxi cn dng t chy ht (Y) nhiu hn t chy ht (X) l 1,344 lt (ktc). CTCT thu gn ca (Y) l A. CH3NHCH2COOH. B. H2NCH2CH2COOH. C. N(CH2COOH)3. D. NC4H8 (COOH)2. Cu 13: Ly m gam hn hp X gm hai amino axit c 1 nhm -NH2 v 1 nhm -COOH phn ng vi 55 ml dung dch HCl 2M thu c dung dch Y . tc dng ht vi cc cht trong dung dch Y cn dng 70 ml dung dch KOH 3M. Mt t chy hon ton m(g) X v cho sn phm chy qua dd KOH d th khi lng bnh ny tng thm 14,85 gam .Bit t l phn t khi gia hai amino axit l 1,187. Cng thc phn t ca X : A. C2H5 NO2 v C3H7NO2 B. C2H5NO2 v C4H9NO2 C. C2 H5NO2 v C5H11NO2 D. C3H7NO2 v C4H9NO2 Cu 14: Khi thy phn mt protein (X) thu c hn hp gm 2 aminoaxit no k tip nhau trong dy ng ng. Bit mi cht u cha mt nhm NH2 v mt nhm COOH. t chy hon ton 0,2 mol hn hp 2 aminoaxit ri cho sn phm chy qua bnh ng dung dch NaOH d, thy khi lng bnh tng 32,8 gam. Cng thc cu to ca 2 aminoaxit l Gio vin: Nguyn Cao Chung

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Trng THPT K Thut L Thy-Qung Bnh A. H2NCH(CH3)COOH, C2H5CH(NH2)COOH. C. H2NCH(CH3)COOH, H2N(CH2)3COOH.

ng cp t duy ca ngi hc Ha! B. H2NCH2COOH, H2NCH(CH3)COOH. D. H2NCH2COOH, H2 NCH2CH2COOH.

Dng 6: Peptit v protein

S peptit ng phn c to thnh t n n v amino axit khc nhau l n! (cng CTPT) C 2 n v amino axit th tch 1 phn t H2O Vy c n n v amino axit th tch (n - 1) phn t H2 O Mt phn t dipepit s cng 1 phn t H2O Vy c 1peptit c n n v amino axit s cng (n-1) phn t H2O Mt phn t dipepit s cng 2 phn t NaOH to ra 1 phn t H2O Vy c 1peptit c n n v amino axit s cng n phn t NaOH to ra 1 phn t H2O Mt phn t dipepit s cng 2 phn t HCl v 1 phn t H2O to sn phm mui Vy c 1peptit c n n v amino axit s cng n phn t HCl v (n-1) phn t H2O to sn phm mui Cu 1: Khi thy phn 500 g protein A thu c 170 g alanin. Nu phn t khi ca A l 50000 vC th s mt xch alanin trong phn t ca A l A. 190. B. 191. C. 192. D. 193. Cu 2: Cng thc no sau y ca tripeptit (A) tha iu kin sau: + Thy phn hon ton 1 mol A th thu c cc - amino axit l: 3 mol Glyxin , 1 mol Alanin, 1 mol Valin. + Thy phn khng hon ton A, ngoi thu c cc amino axit th cn thu c 2 i peptit: Ala-Gly ; Gly- Ala v Gly-Gly-Val. A. Ala-Gly-Gly-Gly-Val. B. Gly-Gly-Ala-Gly-Val. C. Gly-Ala-Gly-Gly-Val. D. Gly-Ala-Gly-Val-Gly. Cu 3: Thu phn khng hon ton tetra peptit (X), ngoi cc - amino axit cn thu c cc i petit: Gly-Ala; Phe-Va; Ala-Phe. Cu to no sau y l ng ca X. A. Val-Phe-Gly-Ala. B. Ala-Val-Phe-Gly. C. Gly-Ala-Val-Phe D. Gly-Ala-Phe Val. Cu 4: Khi thy phn hon ton 1 polipeptit ta thu c cc aminoaxit X,Y,Z,E,F. Cn khi thy phn mt phn th thu c cc i v tripeptit XE, ZY, EZ, YF , EZY. Hy la chn th t ng ca cc aminoaxit to thnh polipeptit cho trn. A. X-Z-Y-E-F; B. X-E-Y-Z-F C. X-E-Z-Y-F D. X-Z-Y-E-F Cu 5: Thu phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) v 1 mol Phenylalanin (Phe). Thu phn khng hon ton X thu c ipeptit Val-Phe v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l A. Gly-Phe-Gly-Ala-Val B. Gly-Ala-Val-Val-Phe C. Gly-Ala-Val-Phe-Gly D. Val-Phe-Gly-Ala-Gly Cu 6 : ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm NH2 v mt nhm COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2 O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 120. B. 60. C. 30. D. 45. Cu 7: Ly 14,6g mt ipeptit to ra t glixin v alanin cho tc dng va vi dung dch HCl 1M. Th tch dung dch HCl tham gia phn ng: A. 0,1 lit B. 0,2 lt C. 0,3 lt D. 0,4 lt Cu 8 : Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vC th s mt xch alanin c trong phn t X l A. 328. B. 453. C. 479. D. 382. Cu 9: Khi thy phn hon ton 0,1 mol tripeptit mch h X thu c alanin .t chy hon ton lng alanin ny ly sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l: A. 120. B. 90. C. 30. D. 45. Cu 10: Khi thy phn m (gam) protein A thu c 17,8 g alanin. Hy tnh m ? Cu 11: Bradikinin c tc dng lm gim huyt p, l mt nonapeptit c cng thc l : Arg Pro Pro Gly-Phe-Ser-Pro-Phe-Arg. Khi thy phn khng hon ton peptit ny c th thu c bao nhiu tri peptit m thnh phn c cha phenyl alanin ( phe). A.3 B.4 C.5 D.6 Cu 12. a) X v Y ln lt l cc tripeptit v tetrapeptit c to thnh t cng mt amino axit no mch h, c mt nhm -COOH v mt nhm -NH2. t chy hon ton 0,1 mol Y thu c sn phm gm CO2, H2O, N2, trong tng khi lng ca CO2 v H2O l 47,8 gam. Nu t chy hon ton 0,3 mol X cn bao nhiu mol O2? Gio vin: Nguyn Cao Chung - 12 D: 0973904885

Trng THPT K Thut L Thy-Qung Bnh ng cp t duy ca ngi hc Ha! A. 2,8 mol B. 2,025 mol C. 3,375 mol D. 1,875 mol b)Tripeptit mch h X v tetrapeptit mch h Y u c to ra t mt amino axit no, mch h c 1 nhm COOH v 1 nhm NH2. t chy hon ton 0,1 mol X thu c sn phm gm CO2, H2O, N2 trong tng khi lng CO2 , H2O l 36,3 gam. Nu t chy hon ton 0,2 mol Y cn s mol O2 l: A. 1,875 B. 1,8 C. 2,8 D. 3,375 Cu 13: Cho mt ipeptit Y c cng thc phn t C6 H12N2O3. S ng phn peptit ca Y (ch cha gc -amino axit) mch h l A. 6. B. 7. C. 5. D. 4. Cu 14: a) X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m (gam) hn hp cha X v Y c t l s mol ca X v Y tng ng l 1:3 vi dung dch NaOH va . Phn ng hon ton thu c dung dch T. C cn cn thn dung dch T thu c 23,745 gam cht rn khan. Gi tr ca m l A. 19,455. B. 68,1. C. 17,025. D. 78,4 b) X l tetrapeptit c cng thc Gly Ala Val Gly. Y l tripeptit c cng thc Gly Val Ala. un m gam hn hp A gm X, Y c t l mol tng ng l 4:3 vi dung dch KOH va sau khi phn ng xy ra hon ton c cn dung dch thu c 257,36g cht rn khan. Gi tr ca m l: A. 150,88 gam B. 155,44 gam C. 167,38 gam D. 212,12 gam c) X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m gam hn hp X v Y c t l s mol nX : nY = 1 : 3 vi 780 ml dung dch NaOH 1M (va ), sau khi phn ng kt thc thu c dung dch Z. C cn dung dch thu c 94,98 gam mui. m c gi tr l : A.. 68,1 gam. B. 64,86 gam. C.. 77,04 gam. D.. 65,13 gam. Cu 15: Tn gi cho peptit A. alanylglyxylalanyl.

H2N-CH-CO-NH-CH2-CO-NH-CH-COOH CH3 CH3

B. glixylalanylglyxin. C. glixylalanylglyxin. D. alanylglixylalanin.

Cu 16: X l mt tetrapeptit cu to t mt amino axit (A) no, mch h c 1 nhm COOH; 1 nhm NH2. Trong A %N = 15,73% (v khi lng). Thy phn m gam X trong mi trng axit thu c 41,58 gam tripeptit; 25,6 gam ipeptit v 92,56 gam A. Gi tr ca m l: A. 149 gam B. 161 gam C. 143,45 gam D. 159 gam Cu 17: Thy phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin, 1 mol alanin v 1 mol valin. Khi thy phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly, Gly-Ala v tripeptit Gly-Gly-Val. Vy trt t cu to cc amino axit trong pentapeptit A l: A. Val-Gly-Gly-Gly-Ala. B. Gly-Ala-Gly-Gly-Val. C. Ala-Gly-Val-Gly-Gly. D. Gly-Gly-Val-Gly-Ala. Cu 18 a) : Thu phn hon ton 150 gam hn hp cc ipeptit thu c 159 gam cc aminoaxit. Bit rng cc ipeptit c to bi cc aminoaxit ch cha mt nguyn t N trong phn t. Nu ly 1/10 khi lng aminoaxit thu c tc dng vi HCl d th lng mui thu c l: A. 19,55 gam B. 20,375 gam C. 23,2 gam D. 20,735 gam b) Thy phn hon ton 60 gam hn hp hai ipetit thu c 63,6 gam hn hp X gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho 1/10 hn hp X tc dng vi dung dch HCl (d), c cn cn thn dung dch, th lng mui khan thu c l : A. 7,09 gam. B. 16,30 gam C. 8,15 gam D. 7,82 gam. Cu 19: X l mt tripeptit c to thnh t 1 aminoaxit no, mch h c 1 nhm -COOH v 1 nhm -NH2 .t chy hon ton 0,3 mol X cn 2,025 mol O2 thu c sn phm gm CO2 ,H2O , N2. Vy cng thc ca amino axit to nn X l A. H2NC2H4COOH B. H2NC3H6COOH C. H2N-COOH D. H2NCH2COOH Cu 20: X l tetrapeptit (mch h) c to bi amino axit Y no , mch h , c mt nhm -COOH v mt nhm -NH2. t chy hon ton 0,1 mol X thu c sn phm gm CO2, H2O, N2, trong tng khi lng ca CO2 v H2O l 97,4 gam. S CTCT tho mn Y l: A. 2 B. 1 C. 3 D. 5 Cu 21: Vi xc tc men thch hp cht h c G b thu phn hon ton cho hai aminoaxit thin nhin X v Y vi t l s mol ca cc cht trong phn ng nh sau: 1 mol G + 2 mol H2O 2 mol X + 1 mol Y Thu phn hon ton 20,3 gam G thu c m1 gam X v m2 gam Y. t chy hon ton m2 gam Y cn 8,4 lt O2 kc thu c 13,2 gam CO2, 6,3 gam H2O v 1,23 lt N2 270C, 1 atm. Y c cng thc phn t trng vi cng thc n gin nht. X, Y v gi tr m1, m2 l. A. NH2-CH2-COOH (15gam), CH2(NH2)-CH2-COOH; (8,95 gam). B. NH2-CH2-CH2-COOH (15gam), CH3-CH(NH2)-COOH; (8,9 gam). C. NH2-CH2-COOH (15gam), CH3-CH(NH2)-COOH, (8,9 gam). D. NH2-CH2-COOH (15,5gam), CH3-CH(NH2)-COOH; (8,9 gam). Gio vin: Nguyn Cao Chung - 13 D: 0973904885

Trng THPT K Thut L Thy-Qung Bnh Cu 22: Thu phn hon ton peptit:
H2N CH 2 CO NH CH CH 2 CO NH CH CH 2 CO NH CH 2 COOH C 6H 5

ng cp t duy ca ngi hc Ha!

COOH

thu c cc aminoaxit A. H2N-CH2-COOH; HOOC-CH(NH2)-COOH v C6H5-CH(NH2)-COOH. B. H2N-CH2-COOH; H2N-CH2-CH(NH2)-COOH v C6H5-CH(NH2 )-COOH. C. H2N-CH2-COOH; HOOC-CH2 -CH(NH2)-COOH v C6H5-CH2-CH(NH2)-COOH. D. H2N-CH2-COOH; H2N-CH(CH2-COOH)-CO-NH2 v H2N-CH(CH2 -C6H5)-COOH Cu 23: Phn t khi ca mt pentapeptit bng 373. Bit pentapeptit ny c to nn t mt amino axit m trong phn t ch c cha mt nhm amino v mt nhm cacboxyl. Phn t khi ca amino axit ny l A. 60,6. B. 57,0. C. 75,0. D. 89,0. Cu 24: X l tetrapeptit c cng thc Gly Ala Val Gly. Y l tripeptit c cng thc Gly Val Ala. un m gam hn hp A gm X, Y c t l mol tng ng l 4:3 vi dung dch KOH va sau khi phn ng xy ra hon ton c cn dung dch thu c 257,36g cht rn khan. Gi tr ca m l: A. 167,38 gam B. 150,88 gam C. 212,12 gam D. 155,44 gam Cu 25: Nu thu phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu c ti a bao nhiu ipeptit khc nhau? A. 4. B. 2. C. 3. D. 1. Cu 26: ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm NH2 v mt nhm COOH).t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton m (g) X ,lng CO2 sinh ra c hp th hon ton vo 600 ml dd hn hp gm NaOH 0,1M v Ba(OH)2 0,2M sinh ra 11,82g kt ta. Tnh gi tr ca m l: A. 1,6 v 6,4 gam B. 1,6 C. 6,4 D. 8 Cu 27: Trong fibroin khi lng gc glyxyl chim 50%. Khi lng glyxin m cc con tm c to nn 1kg t l. A. 646,55. B. 500. C. 386,66. D. 556,5. ... Cu 28: Khi thu phn hon ton 0,1 mol peptit A mch h (A to bi cc amino axit c mt nhm amino v mt nhm cacboxylic) bng lng dung dch NaOH gp i lng cn phn ng, c cn dung dch thu c hn hp cht rn tng so vi khi lng A l 78,2gam. S lin kt peptit trong A l: D. 18 A. 10 B. 20 C. 9 Cu 29. Cho 0,1 mol mt peptit X ch c to thnh t mt -aminoaxit Y (ch cha 1 nhm amino v mt nhm cacboxyl ) tc dng vi dung dch HCl va , sau phn ng thu c khi lng mui tng so vi ban u l 30,9 gam. Mt khc t chy 0,1 mol X ri sc sn phm chy vo nc vi trong d thu c 180 gam kt ta. Tn gi ca Y l. A. Glyxin. B. Alanin. C. Valin. D. Lysin. Cu 30: Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin; 1 mol alanin v 1mol valin. Khi thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly; Gly-Ala v tripeptit Gly-Gly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l A. Gly, Val. B. Ala, Val. C. Gly, Gly. D. Ala, Gly. Cu 31: Khi thy phn khng hon ton mt peptit A c khi lng phn t 293 g/mol v cha 14,3% N (theo khi lng) thu c 2 peptit B v C. Mu 0,472 gam peptit B khi em un nng, phn ng hon ton vi 18 ml dung dch HCl 0,222 M. Mu 0,666 gam peptit C khi un nng, phn ng hon ton vi 14,7 ml dung dch NaOH 1,6% (khi lng ring l 1,022 g/ml). Cu to c th c ca A l: A. Ala-Phe-Gly hoc Gly-Phe-Ala B. Phe-Gly-Ala hoc Ala-Gly-Phe C. Phe-Ala-Gly hoc Gly-Ala-Phe D. Phe-Ala-Gly hoc Ala-Gly-Phe Cu 32: Pht biu no sau y ng A. Phn t peptit mch h c s lin kt peptit bao gi cng nhiu hn s gc -amino axit B. Phn t peptit mch h to bi n gc -amino axit c cha (n 1) lin kt peptit C. Cc peptit u c phn ng vi Cu(OH)2 to thnh phc cht c mu tm c trng D. Phn t tripeptit c ba lin kt peptit Cu 33: Cho 15 gam glyxin tc dng va vi 8,9 gam alanin thu c m gam hn hp tripeptit mch h. Gi tr ca m l A. 22,10 gam B. 23,9 gam C. 20,3 gam D. 18,5 gam Cu 34: X v Y ln lt l cc tripeptit v hexapeptit c to thnh t cng mt amino axit no mch h, c mt nhm COOH v mt nhm -NH2. t chy hon ton 0,1 mol X bng O2 va thu c sn phm gm CO2, H2O, N2, c tng khi lng l 40,5 gam. Nu cho 0,15 mol Y cho tc dng hon ton vi NaOH (ly d 20% so vi lng cn thit), sau phn ng c cn dung dch th thu c bao nhiu gam cht rn? A. 87,3 gam B. 9,99 gam C. 107,1 gam D. 94,5 gam Cu 35: Ly 8,76 g mt ipeptit to ra t glyxin v alanin cho tc dng va vi dung dch HCl 1M. Th tch dung dch HCl tham gia phn ng l: A. 0,1 lt B. 0,06 lt C. 0,24 lt D. 0,12 lt Gio vin: Nguyn Cao Chung - 14 D: 0973904885

Trng THPT K Thut L Thy-Qung Bnh ng cp t duy ca ngi hc Ha! Cu 49: Trong hp cht sau y c my lin kt peptit? H2N-CH2-CO-NH-CH-CO-NH-CH-CO-NH-CH2-CH2-CO-HN-CH2 -COOH CH3 C6H5 A. 4. B. 3. C. 1. D. 2. Cu 50: Thy phn hon ton 1 mol oligopeptit X mch h thu c 2 mol Gly, 1 mol Ala, 1 mol Val, 1 mol Tyr. Mt khc, nu thy phn khng hon ton thi thu c sn phn c cha Gly-Val, Val-Gly. S cng thc cu to ph hp ca X l. A. 4 B. 1 C. 2 D. 6 Cu 51. Mt peptit X khi thu phn hon ton ch thu c alanin. Bit phn trm khi lng N trong X bng 18,767%. Khi lng mui thu c khi cho 0,5 mol X tc dng vi dung dch KOH d l A. 317,5 gam B. 315,7 gam C. 371,5 gam D. 375,1 gam Cu 52: Hn hp M gm mt peptit X v mt peptit Y (chng cu to t 1 loi aminoaxit, tng s nhm CONH trong 2 phn t l 5) vi t l s mol nX : nY = 1:3 .Khi thy phn hon ton m gam M thu c 81 gam glixin v 42,72 gam alanin. m c gi tr l A. 104,28 gam B. 109,5 gam C. 116,28 gam D. 110,28 gam Cu 53: Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin; 1 mol alanin v 1mol valin. Khi thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly; Gly-Ala v tripeptit Gly-Gly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l: A. Gly, Gly. B. Ala, Val. C. Ala, Gly. D. Gly, Val. Cu 54: Thc hin tng hp tetra peptit t 5,0 mol glixin 4,0 mol alanin v 7,0 mol axit -2-aminobutanoic. Bit phn ng xy ra hon ton, khi lng tetrapeptit thu c l A. 1236 gam. B. 1164 gam C. 1452 gam D. 1308 gam Cu 55: Khi thy phn mt octanpetit X c cng thc cu to l Gly-Phe-Tyr-Lys-Gly-Phe-Tyr th thu c bao nhiu tripeptit c cha Gly? A. 3. B. 4. C. 5. D. 6. Cu 56: X l mt tetrapeptit. Cho m gam X tc dng va vi 0,3 mol NaOH thu c 34,95g mui. Phn t khi ca X c gi tr l: A. 324 B. 432 C. 234 D. 342 Cu 57: Tripeptit M v tetrapeptit Q u c to ra t mt amino axit X mch h, phn t c mt nhm -NH2. Phn trm khi lng ca N trong X l 18,667%. Thu phn khng hon ton m gam hn hp M, Q (t l mol 1 : 1) trong mi trng axit thu c 0,945 gam M ; 4,62 gam ipeptit v 3,75 gam X. Gi tr ca m l B. 58,725. C. 5,580. D. 9,315. A. 8,389. Cu 58: Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32 gam AlaAla v 27,72 gam Ala-Ala-Ala. Gi tr ca m l A. 90,6. B. 111,74. C. 81,54. D. 66,44. Cu 59: Khi thy phn khng hon ton pentapeptit Ala-Gly-Val-Gly-Ala c ti a bao nhiu tripeptit khc nhau? A. 1. B. 4. C. 3. D. 2. Cu 60: Thy phn 25,6 gam polipeptit X thu c 15 gam glyxin v 17,8 gam alanin. Cng thc cu to ca mt xch c bn phn t X l : A. [-NHCH2CO-NHCH(CH3)-CO-] B. [-NHCH2CO-NHCH(CH3)-CO-NHCH2CO-] C. [-NHCH2CO-NHCH(CH3)-CO-NHCH(CH3)CO-] D. [-NHCH2CO-NHCH(CH3)-CO-NHCH(CH3)CO-NHCH2CO-] Cu 61. X l tetrapeptit AlaGlyValAla, Y l tripeptit ValGlyVal. un nng m gam hn hp X v Y c t l s mol nX : nY = 1:3 vi 1560 ml dung dch NaOH 1M (dng d gp 2 ln lng cn thit) , sau khi phn ng kt thc thu c dung dch Z. C cn dung dch thu c 126,18 gam cht rn khan. m c gi tr l : A. 68,1 gam B. 75,6 gam C. 66,7 gam D. 78,4 gam Cu 62 : Cho cc cu sau: (1). Peptit l hp cht c hnh thnh t 2 n 50 gc amino axit. (2). Tt c cc peptit u phn ng mu biure. (3). T 3 - amino axit ch c th to ra 3 tripeptit khc nhau. (4). Khi un nng nung dch peptit vi dung dch kim, sn phm s c phn ng mu biure. S nhn xt ng l: A. 1 B. 2 C. 3 D. 4 Cu 63 : Cho cc pht biu sau: (1). Phn t ipeptit c hai lin kt peptit. (2). Phn t tripeptit c 3 lin kt peptit. (3). S lkt peptit trong pt peptit mch h c n gc - amino axit l n -1. (4). C 3 -amino axit khc nhau, c th to ra 6 peptit khc nhau c y cc gc -amino axit . S nhn nh ng l: A. 1 B.2 C.3 D.4

Gio vin: Nguyn Cao Chung

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D: 0973904885

Trng THPT K Thut L Thy-Qung Bnh ng cp t duy ca ngi hc Ha! Cu 64: Thc hin phn ng trng ngng hn hp gm glixin v alanin. S ipeptit c to ra r glixin v alanin l: A. 2 B. 3 C. 4 D. 5 Cu 65: : X l mt Tetrapeptit cu to t Aminoacid A, trong phn t A c 1 nhm (-NH2 ) + 1 nhm (-COOH) no ,mch h.Trong A Oxi chim 42,67% khi lng . Thy phn m gam X trong mi trng acid th thu c 28,35(g) trpeptit; 79,2(g) ipeptit v 101,25(g) A. Gi tr ca m l? A. 184,5. B. 258,3. C. 405,9. D. 202,95. Cu 66: Thy phn hon ton 143,45 gam hn hp A gm hai tetrapeptit thu c 159,74 gam hn hp X gm cc Aminoacid (cc Aminoacid ch cha 1nhm COOH v 1 nhm NH2 ) . Cho tan b X tc dng vi dung dch HCl d,sau c cn dung dch th nhn c m(gam) mui khan. Khi lng nc phn ng v gi tr ca m ln lt bng? A. 8,145(g) v 203,78(g). B. 32,58(g) v 10,15(g). C. 16,2(g) v 203,78(g) B. 16,29(g) v 203,78(g). Cu 67: X l mt Hexapeptit cu to t mt Aminoacid H2N-CnH2n -COOH (Y).Trong Y c tng % khi lng Oxi v Nito l 61,33%. Thy phn ht m(g) X trong mi trng acid thu c 30,3(g) petapeptit, 19,8(g) ieptit v 37,5(g) Y. Gi tr ca m l : A. 69 gam. B. 84 gam. C. 100 gam. D. 78 gam. Cu 68 : Thy phn 14(g) mt Polipeptit(X) vi hiu sut t 80%,th thu c 14,04(g) mt - aminoacid (Y). Xc nh Cng thc cu to ca Y? B. H2NCH(CH3)COOH. C. H2NCH2COOH D. H2NCH(C2H5)COOH A. H2N(CH2)2COOH. Cu 69: Xc nh Phn t khi gn ng ca mt Polipeptit cha 0,32% S trong phn t. Gi s trong phn t ch c 2 nguyn t S? A. 20.000(vC) B.10.000(vC). C. 15.000(vC). D. 45.000(vC Cu 70 : un nng alanin thu c mt s peptit trong c peptit A c phn trm khi lng nit l 18,54%. Khi lng phn t ca A l : A. 231. B. 160. C. 373. D. 302. Cu 71: Khi thy phn hon ton 55,95 gam mt peptit X thu c 66,75 gam alanin (amino axit duy nht). X l : A. tripeptit. B. tetrapeptit. C. pentapeptit. D. ipeptit. Cu 72 : Khi thy phn hon ton 65 gam mt peptit X thu c 22,25 gam alanin v 56,25 gam glyxin. X l : A. tripeptthu c. B. tetrapeptit. C. pentapeptit. D. ipeptit. Cu 73 :Thu phn hon ton 500 gam mt oligopeptit X (cha t 2 n 10 gc -amino axit) thu c 178 gam amino axit Y v 412 gam amino axit Z. Bit phn t khi ca Y l 89. Phn t khi ca Z l : A. 103. B. 75. C. 117. D. 147. Cu 74: Tripeptit X c cng thc sau : H2NCH2 CONHCH(CH3)CONHCH(CH3)COOH . Thy phn hon ton 0,1 mol X trong 400 ml dung dch NaOH 1M. Khi lng cht rn thu c khi c cn dung dch sau phn ng l : A. 28,6 gam. B. 22,2 gam. C. 35,9 gam. D. 31,9 gam.

Gio vin: Nguyn Cao Chung

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D: 0973904885