BI TP NHM OXI

Mt s phn ng kh lin quan n: * O2 2Cu + 2H2SO4 + O2 2CuSO4 + 2H2O 2Cu2O + Cu2S 6Cu + SO2 4FeS2 + 11O2 2Fe2O3 + 8SO2 2Fe(OH)2 + 1/2O2 + H2O 2Fe(OH)3 H2S + O2 S + H2O (trng xanh) (nu ) H2S + 3/2 O2 SO2 + H2O 2Fe(OH)2 + O2 Fe2O3 + 2H2O * H2O2, O3 H2O2 + KNO2 H2O + KNO3 H2O2 + Ag2O 2Ag + H2O + O2 H2O2 + 2KI I2 + 2KOH O3 + 2Ag Ag2O + O2 2KI + O3 + H2O I2 + 2KOH + O2 2KMnO4 + 5H2O2 + 3H2SO4 2MnSO4 + 5O2 + K2SO4 + 8H2O *S 3S + 2KClO3 3SO2 + 2KCl S + 2H2SO4 (c) 3SO2 + 2H2O S + 2H2SO4 (c) 3SO2 + 2H2O 3S + 6NaOH 2Na2S + Na2SO3 + 3H2O S + 2HNO3 H2SO4 + 2NO S + 6HNO3 H2SO4 + 6NO2 + 2H2O * H2S 2NO + 2H2S 2S + N2 + 2H2O H2S + 4Cl2 + 4H2O H2SO4 + 8Cl2 H2SO3 + 2H2S 3S + 3H2O H2S + Cl2 S + 2HCl I2 + H2S S + 2HI 2H2S + 2K 2KHS + H2 2H2S + SO2 3S + 2H2O 2H2S + 4Ag + O2 2Ag2S + 2H2O H2S + 2FeCl3 2FeCl2 + 2HCl + S CuS, PbS + H2SO4 : khng phn ng H2S + H2SO4 () SO2 + S + 2H2O H2S + CuSO4 CuS + H2SO4 2KMnO4 + 5H2S + 3H2SO4 2MnSO4 + 5S + K2SO4 + 8H2O * SO2 SO2 + NO2 SO3 + NO SO2 + 2H2O + Cl2 H2SO4 + 2HCl boxit ,500 C SO2 + 2H2O + Br2 H2SO4 + 2HBr SO2 + 2CO 2CO2 + S SO2 + 2Mg 2MgO + S SO2 + 2FeCl3 + 2H2O 2FeCl2 + H2SO4 + 2HCl SO2 + 6HI 2H2O + H2S + 3I2 5SO2 + 2KMnO4 + 2H2O K2SO4 + 2MnSO4 + 2H2O * SO3 SO3 + 2KI K2SO3 + I2 3SO3 + 2NH3 3SO2 + N2 + 2H2O * H2SO3 H2SO3 + O2 H2SO4 4K2SO3 3K2SO4 + K2S H2SO3 + I2 + H2O H2SO4 + 2HI NaHSO3 + NaClO NaHSO4 + NaCl H2SO3 + 2H2S 3S + 3H2O * H2SO4 H2SO4 () + 8HI 4I2 + H2S + 4H2O 2H2SO4 + C 2SO2 + CO2 + 2H2O H2SO4 () + 2HBr Br2 + SO2 + 2H2O 2H2SO4 + S 3SO2 + 2H2O 6H2SO4 (,n) + 2Fe Fe2(SO4)3 + 3SO2 + 6H2O 5H2SO4 + 2P 2H3PO4 + 5SO2 + 2H2O 2H2SO4 () + Zn ZnSO4 + SO2 + 2H2O 4H2SO4 (,n) + 2FeO Fe2(SO4)3 + SO2 + 4H2O 4H2SO4 () + 3Zn 3ZnSO4 + S + 4H2O 4H2SO4(,n) + 2Fe(OH)2Fe2(SO4)3 + SO2 + 6H2O 5H2SO4 () + 4Zn 4ZnSO4 + H2S + 4H2O H2SO4 (,n) + H2S SO2 + S + 2H2O 2H2SO4 () + Cu CuSO4 + SO2 + 2H2O K2Cr2O7 + 12FeSO4 + 11H2SO4 Cr2(SO4)3 + 6Fe2(SO4)3 + K2SO4 + S + 11H2O
o

PHN I : BI TP S , CHUI PHN NG a/ A + B D (mi trng thi) D+EA+G A + O2 E F+GX VO E + G + Br2 X + Y E + O2 F 400 C X + K2SO3 H + E + G
2 5 o

b/ A + B C (mi trng thi) C + O2 E + H2O B + O2 E

C + Cl2 F + B Dd F + H FeCl2 +C C + G T (en) + HNO3

c/ A + C D D + E A + H2 O A+BE D + KMnO4 + H2O G + H + F A + F D + H2O E + KMnO4 + F A + G + H + H2O d/ FeS H2S Na2S FeS Fe2(SO4)3 FeCl3 Fe(OH)3 e/ FeS2 SO2 S H2S SO2 SO3 SO2 H2SO4 BaSO4 SO2 NaHSO3 f/ FeS H2S S NO2; H2S H2SO4 CuSO4; H2S SO2 HBr + O2 + O2 + H 2O 1:2 1:1 g/ X A B C D BaSO4 + Al , 2:3 1:3 C E BaSO4 h/ MnO2 Cl2 S SO2 H2SO4 CO2 K2CO3 KNO3 i/ NaCl NaOH NaCl Cl2 S H2S H2SO4 S; Cl2 FeCl3 Fe2(SO4)3 ; FeCl3 S j/ KMnO4 Cl2 NaCl Cl2 FeCl3 Fe2(SO4)3 Fe(NO3)3 H2SO4 NaHSO4 Na2SO4 k/ Zn ZnS H2S SO2 H2SO4 Fe2(SO4)3 FeCl3 SO2 S Al2S3 l/ FeS2 SO2 SO3 H2SO4 SO2 Na2SO3 Na2SO4 NaCl NaNO3 HBr AgBr m/ Ca(NO3)2 CuS Cu(NO3)2 Cu(OH)2 CuO Cu CuCl2 n/ ZnS H2S S SO2 SO3 H2SO4 HCl Cl2 KClO3 O2 S H2S SO2 Na2SO3 Na2SO4 NaCl Cl2 o/ ZnS SO2 H2SO4 Fe2(SO4)3 Fe(OH)3 Fe2O3 FeFeS FeSO4Fe2(SO4)3 H2S S SO2 KHSO3 K2SO3 K2SO4 KOH KClO Cl2 CaOCl2 p/ FeS H2S SO2 NaHSO3 Na2SO3 SO2 H2SO4 K2SO4 KCl KOH KClO3 O2 S ZnS SO2 SO3 BaSO4 PHN II : BI TON 1. un nng hon ton hn hp bt gm st v lu hunh. em ho tan cht rn sau phn ng trong dung dch HCl d thy c 4,48 lit kh thot ra. Nu em ht lng kh ny cho vo dung dch Pb(NO3)2 d th cn li 2,24 lit kh. Cc th tch u o ktc. Tnh % khi lng ca st v lu hunh trong hn hp u v tnh khi lng kt ta to thnh trong dung dch Pb(NO3)2? 2. Cho sn phm to thnh khi nung hn hp 5,6 gam st v 1,6 gam bt lu hunh vo 500 ml dung dch HCl th c 1 hn hp kh bay ra v mt dung dch A (hiu sut phn ng 100%). a) Tnh thnh phn phn trm th tch hn hp kh to thnh? b) trung ho HCl cn d trong dung dch A phi dng 125 ml dung dch NaOH 0,1 M. Tnh nng mol ca dung dch HCl? 3. Cho 6,45 gam mt hn hp gm lu hunh v 1 kim loi M ( ho tr 2) vo mt bnh kn khng cha Oxi. Nung bnh cho n khi phn ng hon ton thu c hn hp B. Cho hn hp B tc dng vi dung dch HCl d thu oc kh C v 1,6 gam cht rn D khng tan. Cho kh C i t t qua 1 dung dch Pb(CH3COO)2 c kt ta cn nng 11,95 g. Xc nh kim loi M v tnh khi lng M v lu hunh trong hn hp ban u? 4. Mt hn hp X gm bt lu hunh v mt kim loi M ho tr 2 c khi lng l 25,9 g. Cho X vo 1 bnh kn khng cha khng kh. Thc hin phn ng gia M v S ( phn ng hon ton) thu c cht rn A. khi cho A tc dng vi dung dch HCl d, A tan ht to ra hn hp kh B c V=6,72 lit (kc) v t khi i vi Hiro bng 11,666. Xc nh thnh phn hn hp kh B, tn kim loi M v khi lng S v M trong hn hp X?

5. Mt hn hp Y gm Zn v lu hunh; Cho M v S phn ng hon ton vi nhau to ra cht rn C. Khi cho C tc dng vi dung dch HCl d th cn li 1 cht rn D khng tan cn nng 6 gam v thu c 4,48 lit kh E c t khi ca E i vi hiro l 17. Tnh khi lng Y? 6. Mt hn hp Z gm km v lu hunh; nung nng hn hp trong bnh kn khng c oxi thu c cht rn F. Khi cho F tc dng vi dung dch HCl d li mt cht rn G khng tan cn nng 1,6 gam v to ra 8,96 lit hn hp kh (kc) c t khi i vi hiro bng 17. Tnh khi lng hn hp Z v hiu sut phn ng gia M v S? 7. Tnh khi lng cc cht thu c sau phn ng trong cc trng hp sau: a) Dn 2,24 lit kh hirosunfua vo 300 ml dung dch NaOH 1M b) Dn 13,44 lit SO2 vo 200 ml dung dch NaOH 2M c) Dn 0,672 lit SO2 vo 1 lit dung dch Ca(OH)2 0.02 M 8. Dn 12, 8 gam SO2 vo 50 ml dung dch NaOH 25% ( d= 1,28 gam /ml). Mui no c to thnh? Tnh C% ca n trong dung dch thu c? 9. t chy hon ton 8,96 lit H2S (ktc) ri ho tan tt c sn phm sinh ra vo 80 ml dung dch NaOH 25% ( d= 1,28 g/ml). Tnh nng phn trm ca cc cht trong dung dch thu c? 10. Mt hn hp X gm 2mui sunfit v hirosunfit ca cng mt kim loi kim - Cho 43,6 gam hn hp X tc dng vi dung dch H2SO4 long d. Cht kh A sinh ra lm mt mu va 400 ml dung dch KMnO4 0,3M 2KMnO4 + 5SO2 +2 H2O 2MnSO4 + 2KHSO4 + H2SO4 - Mt khc, 43,6 gam hn hp X cng tc dng va vi 100 ml dung dch NaOH 1M. a) Xc nh tn kim loi kim? % khi lng mi mui trong hn hp X? b) Cho ton b kh A sinh ra hp th vo 500 gam dung dch Ba(OH)2 6,84%. Tnh nng phn trm ca dung dch thu c? c) Tnh khi lng dung dch Ba(OH)2 6,84% ti thiu dng hp thu ton b lng kh A ni trn? 11. Dn V lit (kc) kh CO2 qua dung dch c cha 0,1 mol Ca(OH)2 thu c 6 gam kt ta. Lc b kt ta, ly dung dch nc lc un nng li thu c kt ta na. Tnh V? 12. Cho 16,8 lit kh CO2 (ktc) hp th hon ton vo 600 ml dung dch NaOH 2M thu c dung dch X. Nu cho mt lng d dung dch BaCl2 vo dung dch X th thu oc lng kt ta bao nhiu? 13. Dn V lit kh CO2 (kc) hp th vo dung dch c cha 0,5 mol Ca(OH)2 thy c 25 gam kt ta. Tnh V? 14.* 11,2 lit (kc) hn hp kh A gm clo v oxi tc dng ht vi 16,98 gam hn hp B gm magi v nhm to ra 42,34 gam hn hp clorua v oxit ca 2 kim loi. Tnh thnh phn phn trm v th tch ca tng cht trong hn hp A? thnh phn phn trm v khi lng ca tng cht trong hn hp B? 15.* Ho tan hon ton mt lng bt st vo dung dch HNO3 thu c mui st (III) nitrat v hn hp kh gm 0,015 mol N2O v 0,01 mol NO. Tnh khi lng st ho tan? 16.* Cho 11 gam hn hp st v nhm vo dung dch H2SO4 c nng thu c 10,08 lit kh SO2 (kc). Tnh thnh phn phn trm khi lng ca mi kim loi trong hn hp? 17.* Ho tan hon ton a gam FexOy bng dung dch H2SO4 thu c b gam mt mui v c 168 ml kh SO2 (kc) duy nht thot ra. Tnh tr s a, b v cng thc FexOy? 18.* m gam bt st ngoi khng kh, sau mt thi gian bin thnh hn hp M c khi lng 12 gam gm: Fe, FeO, Fe3O4, Fe2O3. Ho tan hon ton M vo dung dch H2SO4 c thu oc 3,36 lit SO2 duy nht (kc). Tnh gi tr m? 19.* Ho tan hon ton 11,9 g hn hp kim loi Al, Zn bng dd H2SO4 c nng thu c dd X; 7,616 lit SO2 (kc) v 0,64 g lu hunh. Tnh tng khi lng mui trong X? 20.* Hn hp kh A gm clo v oxi. A phn ng ht vi 1 hn hp gm 4,80 gam magi v 8,10 gam nhm to ra 37,05 gam hn hp cc mui clorua v oxit ca 2 kim loi. Xc nh thnh phn phn trm theo khi lng v theo th tch ca hn hp A?