9.

Chuyn bi tp v O-S

1.11a Cu 31: Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh (gm 20% th tch O2 v 80% th tch N2) n
khi cc phn ng xy ra hon ton, thu c mt cht rn duy nht v hn hp kh Y c thnh phn th tch: 84,8% N2, 14% SO2, cn li
l O2. Phn trm khi lng ca FeS trong hn hp X l
A.59,46%.
B. 42,31%.
C. 26,83%.
D. 19,64%.
2.11a Cu 60: Ho tan hn hp bt gm m gam Cu v 4,64 gam Fe3O4 vo dung dch H2SO4 (long, rt d), sau khi cc phn ng kt thc
ch thu c dung dch X. Dung dch X lm mt mu va 100 ml dung dch KMnO4 0,1M. Gi tr ca m l
A.0,96.
B. 1,24.
C. 3,2.
D. 0,64.
3.10a Cu 2: Thc hin cc th nghim sau:
(I) Sc kh SO2 vo dung dch KMnO4. (II) Sc kh SO2 vo dung dch H2S. (III) Sc hn hp kh NO2 v O2 vo nc.
(IV) Cho MnO2 vo dung dch HCl c, nng. (V) Cho Fe2O3 vo dung dch H2SO4 c, nng. (VI) Cho SiO2 vo dung dch HF.
S th nghim c phn ng oxi ho - kh xy ra l
A.6.
B. 5.
C. 4.
D. 3.
4.10a Cu 21: Ho tan hon ton 8,94 gam hn hp gm Na, K v Ba vo nc, thu c dung dch X v 2,688 lt kh H2 (ktc). Dung dch
Y gm HCl v H2SO4, t l mol tng ng l 4 : 1. Trung ho dung dch X bi dung dch Y, tng khi lng cc mui c to ra l
A.13,70 gam.
B. 12,78 gam.
C. 18,46 gam.
D. 14,62 gam.
5.10a Cu 39: Cho x mol Fe tan hon ton trong dung dch cha y mol H2SO4 (t l x : y = 2 : 5), thu c mt sn phm kh duy nht v
dung dch ch cha mui sunfat. S mol electron do lng Fe trn nhng khi b ho tan l
A.2x.
B. 3x.
C. 2y.
D. y.
6.09a Cu 21: Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung dch H2SO4 10%, thu c 2,24 lt kh H2 (
ktc). Khi lng dung dch thu c sau phn ng l
A.101,68 gam.
B. 88,20 gam.
C. 101,48 gam.
D. 97,80 gam.
7.07a Cu 32: Ho tan 5,6 gam Fe bng dung dch H2SO4 long (d), thu c dung dch X. Dung dch X phn ng va vi V ml dung
dch KMnO4 0,5M. Gi tr ca V l (cho Fe = 56)
A.80.
B. 40.
C. 20.
D. 60.
8.07a Cu 45: Ho tan hon ton 2,81 gam hn hp gm Fe2O3, MgO, ZnO trong 500 ml axit H2SO4 0,1M (va ). Sau phn ng, hn
hp mui sunfat khan thu c khi c cn dung dch c khi lng l
A.6,81 gam.
B. 4,81 gam.
C. 3,81 gam.
D. 5,81 gam.
9.Cd11Cu 10: Ho tan hon ton hn hp X gm 0,2 mol Fe v 0,2 mol Fe2O3 vo dung dch axit H2SO4 long (d), thu c 2,24 lt kh
(ktc) v dung dch Y. Cho lng d dung dch NaOH vo dung dch Y, sau khi phn ng xy ra hon ton thu c m gam kt ta. Gi
tr nh nht ca m l
A.57,4.
B. 59,1.
C. 60,8.
D. 54,0.
10.Cd11Cu 15: Cho cc cht: KBr, S, SiO2, P, Na3PO4, FeO, Cu v Fe2O3. Trong cc cht trn, s cht c th b oxi ha bi dung dch axit
H2SO4 c, nng l
A.4.
B. 5.
C. 7.
D. 6.
11.10cdCu 5: Cho phn ng: Na2SO3 + KMnO4 + NaHSO4 Na2SO4 + MnSO4 + K2SO4 + H2O. Tng h s ca cc cht (l nhng s
nguyn, ti gin) trong phng trnh phn ng l
A.23.
B. 27.
C. 47.
D. 31.
12.10cd Cu 19: Nguyn t S ng vai tr va l cht kh, va l cht oxi ho trong phn ng no sau y?
to
to
A. S + 2Na
Na2S.
B. S + 6HNO3 (c)
H2SO4 + 6NO2 + 2H2O.
to

t
C. 4S + 6NaOH(c)
2Na2S + Na2S2O3 + 3H2O.
D. S + 3F2
SF6.
13.10cd Cu 27: Cho 0,015 mol mt loi hp cht oleum vo nc thu c 200 ml dung dch X. trung ho 100 ml dung dch X cn
dng 200 ml dung dch NaOH 0,15M. Phn trm v khi lng ca nguyn t lu hunh trong oleum trn l
A.32,65%.
B. 35,95%.
C. 37,86%.
D. 23,97%.
14.09cd Cu 32: t chy hon ton 7,2 gam kim loi M (c ho tr hai khng i trong hp cht) trong hn hp kh Cl2 v O2. Sau phn
ng thu c 23,0 gam cht rn v th tch hn hp kh phn ng l 5,6 lt ( ktc). Kim loi M l
A.Mg.
B. Ca.
C. Be.
D. Cu.
o hp khng xy ra phn ng ha hc l
15.Cd08Cu 5: Trng
t
A. 3O2 + 2H2S
2H2O + 2SO2.
B. FeCl2 + H2S
FeS + 2HCl.
C. O3 + 2KI + H2O
2KOH + I2 + O2.
D. Cl2 + 2NaOH
NaCl + NaClO + H2O
16.Cd08Cu 34: X l kim loi thuc phn nhm chnh nhm II (hay nhm IIA). Cho 1,7 gam hn hp gm kim loi X v Zn tc dng vi
lng d dung dch HCl, sinh ra 0,672 lt kh H2 ( ktc). Mt khc, khi cho 1,9 gam X tc dng vi lng d dung dch H2SO4 long, th
th tch kh hiro sinh ra cha n 1,12 lt ( ktc). Kim loi X l
A.Ba.
B. Ca.
C. Sr.
D. Mg.
Fe(OH)2 +ddY Fe2(SO4)3 +ddZ BaSO4
NaOH +ddX
17.Cd08Cu 36: Cho s chuyn ho (mi mi tn l mt phng trnh phn ng):
Cc dd (dung dch) X, Y, Z ln lt l:
A. FeCl3, H2SO4 (c, nng), Ba(NO3)2.
B. FeCl3, H2SO4 (c, nng), BaCl2.
C. FeCl2, H2SO4 (c, nng), BaCl2.
D. FeCl2, H2SO4 (long), Ba(NO3)2.
18.Cd08Cu 38: Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh), thu c hn hp rn
M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn li mt phn khng tan G. t chy hon ton X v
G cn va V lt kh O2 ( ktc). Gi tr ca V l
A.2,80.
B. 3,36.
C. 3,08.
D. 4,48.

19.Cd08Cu 41: Ha tan hon ton Fe3O4 trong dung dch H2SO4 long (d) c dung dch X1. Cho lng d bt Fe vo dung dch X1
(trong iu kin khng c khng kh) n khi phn ng xy ra hon ton, thu c dung dch X2 cha cht tan l
A. Fe2(SO4)3 v H2SO4.
B. FeSO4.
C. Fe2(SO4)3.
D. FeSO4 v H2SO4.
20.Cd08Cu 44: Ho tan ht 7,74 gam hn hp bt Mg, Al bng 500 ml dung dch hn hp HCl 1M v H2SO4 0,28M thu c dung dch
X v 8,736 lt kh H2 ( ktc). C cn dung dch X thu c lng mui khan l
A.38,93 gam.
B. 103,85 gam.
C. 25,95 gam.
D. 77,86 gam.
21.Cd08Cu 54: Cho 13,5 gam hn hp cc kim loi Al, Cr, Fe tc dng vi lng d dung dch H2SO4 long nng (trong iu kin khng
c khng kh), thu c dung dch X v 7,84 lt kh H2 ( ktc). C cn dung dch X (trong iu kin khng c khng kh) c m gam
mui khan. Gi tr ca m l
A.42,6.
B. 45,5.
C. 48,8.
D. 47,1.
22.Cd07Cu 1: Khi ha tan hiroxit kim loi M(OH)2 bng mt lng va dung dch H2SO4 20% thu c dung dch mui trung ho c
nng 27,21%. Kim loi M l
A.Cu.
B. Zn.
C. Fe.
D. Mg.
23.Cd07Cu 3: SO2 lun th hin tnh kh trong cc phn ng vi
A. H2S, O2, nc Br2.
B. dung dch NaOH, O2, dung dch KMnO4.
C. dung dch KOH, CaO, nc Br2.
D. O2, nc Br2, dung dch
KMnO4.
24.Cd07Cu 18: Cho mt mu hp kim Na-Ba tc dng vi nc (d), thu c dung dch X v 3,36 lt H2 ( ktc). Th tch dung dch axit
H2SO4 2M cn dng trung ho dung dch X l
A. 150ml.
B. 75ml.
C. 60ml.
D. 30ml.
25.Cd07Cu 27: Ha tan hon ton 3,22 gam hn hp X gm Fe, Mg v Zn bng mt lng va dung dch H2SO4 long, thu c 1,344
lt hiro ( ktc) v dung dch cha m gam mui. Gi tr ca m l
A.9,52.
B. 10,27.
C. 8,98.
D. 7,25.
26.Cd07Cu 48: Cho hn hp X gm Mg v Fe vo dung dch axit H2SO4 c, nng n khi cc phn ng xy ra hon ton, thu c dung
dch Y v mt phn Fe khng tan. Cht tan c trong dung dch Y l
A. MgSO4 v FeSO4.
B. MgSO4.
C. MgSO4 v Fe2(SO4)3. D. MgSO4, Fe2(SO4)3 v
FeSO4.
27.11b Cu 55: Ho tan 25 gam hn hp X gm FeSO4 v Fe2(SO4)3 vo nc, thu c 150 ml dung dch Y. Thm H2SO4 (d) vo 20 ml
dung dch Y ri chun ton b dung dch ny bng dung dch KMnO4 0,1M th dng ht 30 ml dung dch chun. Phn trm khi lng
FeSO4 trong hn hp X l
A.68,4%.
B. 9,12%.
C. 31,6%.
D. 13,68%.
28.10bCu 4: Phng php loi b tp cht HCl c ln trong kh H2S l: Cho hn hp kh li t t qua mt lng d dung dch
A.Pb(NO3)2.
B. NaHS.
C. AgNO3.
D. NaOH.
29.10b Cu 7: Kh hon ton m gam oxit MxOy cn va 17,92 lt kh CO (ktc), thu c a gam kim loi M. Ho tan ht a gam M bng
dung dch H2SO4 c nng (d), thu c 20,16 lt kh SO2 (sn phm kh duy nht, ktc). Oxit MxOy l
A.Cr2O3.
B. FeO.
C. Fe3O4.
D. CrO.
30.10b Cu 20: Ho tan hon ton 2,44 gam hn hp bt X gm FexOy v Cu bng dung dch H2SO4 c nng (d). Sau phn ng thu c
0,504 lt kh SO2 (sn phm kh duy nht, ktc) v dung dch cha 6,6 gam hn hp mui sunfat. Phn trm khi lng ca Cu trong X
l
A.39,34%.
B. 65,57%.
C. 26,23%.
D. 13,11%.
31.10b Cu 25: Cho dung dch X cha KMnO4 v H2SO4 (long) ln lt vo cc dung dch: FeCl2, FeSO4, CuSO4, MgSO4, H2S, HCl
(c). S trng hp c xy ra phn ng oxi ho - kh l
A.3.
B. 5.
C. 4.
D. 6.
32.10b Cu 36: t chy hon ton m gam FeS2 bng mt lng O2 va , thu c kh X. Hp th ht X vo 1 lt dung dch cha
Ba(OH)2 0,15M v KOH 0,1M, thu c dung dch Y v 21,7 gam kt ta. Cho Y vo dung dch NaOH, thy xut hin thm kt ta. Gi
tr ca m l
A.23,2.
B. 12,6.
C. 18,0.
D. 24,0.
33.10b Cu 42: Cho cc cp cht vi t l s mol tng ng nh sau:
(a) Fe3O4 v Cu (1:1); (b) Sn v Zn (2:1); (c) Zn v Cu (1:1); (d) Fe2(SO4)3 v Cu (1:1);
(e) FeCl2 v Cu (2:1); (g) FeCl3 v Cu (1:1). S cp cht tan hon ton trong mt lng d dung dch HCl long nng l
A.4.
B. 2.
C. 3.
D. 5
34.09b Cu 4: Ho tan m gam hn hp gm Al, Fe vo dung dch H2SO4 long (d). Sau khi cc phn ng xy ra hon ton, thu c dung
dch X. Cho dung dch Ba(OH)2 (d) vo dung dch X, thu c kt ta Y. Nung Y trong khng kh n khi lng khng i, thu c
cht rn Z l
A. hn hp gm BaSO4 v FeO. B. hn hp gm Al2O3 v Fe2O3. C. hn hp gm BaSO4 v Fe2O3. D. Fe2O3.
35.09b Cu 12: C cc th nghim sau: (I) Nhng thanh st vo dung dch H2SO4 long, ngui. (II) Sc kh SO2 vo nc brom. (III) Sc
kh CO2 vo nc Gia-ven. (IV) Nhng l nhm vo dung dch H2SO4 c, ngui. S th nghim xy ra phn ng ho hc l
A. 2.
B. 1.
C. 3.
D. 4.
36.09b Cu 34: Ha tan hon ton 20,88 gam mt oxit st bng dung dch H2SO4 c, nng thu c dung dch X v 3,248 lt kh SO2 (sn
phm kh duy nht, ktc). C cn dung dch X, thu c m gam mui sunfat khan. Gi tr ca m l
A. 52,2.
B. 54,0.
C. 58,0.
D. 48,4.
37.09b Cu 46: ng dng no sau y khng phi ca ozon?
A. Ty trng tinh bt, du n.
B. Cha su rng.
C. iu ch oxi trong phng th nghim.
D. St trng nc sinh hot.

38.07bCu 4: Trong phn ng t chy CuFeS2 to ra sn phm CuO, Fe2O3 v SO2 th mt phn t CuFeS2 s
A. nhn 13 electron.
B. nhn 12 electron.
C. nhng 13 electron.
D. nhng 12 electron.
39.07b Cu 10: Cho 6,72 gam Fe vo dung dch cha 0,3 mol H2SO4 c, nng (gi thit SO2 l sn phm kh duy nht). Sau khi phn ng
xy ra hon ton, thu c (cho Fe = 56)
A. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4.
B. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d.
C. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4.
D. 0,12 mol FeSO4.
40.07b Cu 48: Cho 0,01 mol mt hp cht ca st tc dng ht vi H2SO4 c nng (d), thot ra 0,112 lt ( ktc) kh SO2 (l sn phm
kh duy nht). Cng thc ca hp cht st l
A. FeS.
B. FeS2.
C. FeO
D. FeCO3.

41.12A Dy cht no sau y u th hin tnh oxi ha khi phn ng vi SO2?

A. H2S, O2, nc brom.
B. O2, nc brom, dung dch KMnO4.
C. Dung dch NaOH, O2, dung dch KMnO4.
D. Dung dch BaCl2, CaO, nc brom.
42.12A Ha tan hon ton 2,43 gam hn hp gm Mg v Zn vo mt lng va dung dch H2SO4 long, sau
phn ng thu c 1,12 lt H2 (ktc) v dung dch X. Khi lng mui trong dung dch X l
A. 5,83 gam.
B. 7,33 gam.
C. 4,83 gam.
D. 7,23 gam.
43.12B Cho cc cht ring bit sau: FeSO4, AgNO3, Na2SO3, H2S, HI, Fe3O4, Fe2O3 tc dng vi dung dch
H2SO4 c, nng. S trng hp xy ra phn ng oxi ho - kh l
A. 6.
B. 3.
C. 4.
D. 5.
44.12B Cho cc cht sau: FeCO3, Fe3O4, FeS, Fe(OH)2. Nu ho tan cng s mol mi cht vo dung dch H2SO4
c, nng (d) th cht to ra s mol kh ln nht l
A. Fe3O4.
B. Fe(OH)2.
C. FeS.
D. FeCO3.
45.12B t 16,2 gam hn hp X gm Al v Fe trong kh Cl2 thu c hn hp cht rn Y. Cho Y vo nc d,
thu c dung dch Z v 2,4 gam kim loi. Dung dch Z tc dng c vi ti a 0,21 mol KMnO4 trong dung
dch H2SO4 (khng to ra SO2). Phn trm khi lng ca Fe trong hn hp X l
A. 72,91%.
B. 64,00%.
C. 66,67%.
D. 37,33%.
46.12B Mt mu kh thi c sc vo dung dch CuSO4, thy xut hin kt ta mu en. Hin tng ny do
cht no c trong kh thi gy ra?
A. H2S.
B. NO2.
C. SO2.
D. CO2.
47.Cd12Hn hp X gm Na, Al v Fe (vi t l s mol gia Na v Al tng ng l 2 : 1). Cho X tc dng vi
H2O (d) thu c cht rn Y v V lt kh. Cho ton b Y tc dng vi dung dch H2SO4 long (d) thu c
0,25V lt kh. Bit cc kh o cng iu kin, cc phn ng u xy ra hon ton. T l s mol ca Fe v Al
trong X tng ng l
A. 1 : 2.
B. 5 : 8.
C. 5 : 16.
D. 16 : 5.
2+
2+
48.Cd12Cho dy gm cc phn t v ion : Zn, S, FeO, SO2, Fe , Cu , HCl. Tng s phn t v ion trong dy
va c tnh oxi ha, va c tnh kh l
A. 7
B. 4
C. 6
D. 5
49.Cd12Oxi ha hon ton m gam kim loi X cn va 0,25m gam kh O2. X l kim loi no sau y?
A. Al.
B. Fe.
C. Cu.
D. Ca.