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Anehit qua cc nm thi i hc

Nm 2007 - Khi A Cu 1: Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 2,24 lt kh NO (sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16) A. CH3CHO. B. HCHO. C. CH3CH2CHO. D. CH2 = CHCHO Cu 2: Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l (cho Na = 23, Ag = 108) A. HCHO. B. CH3CHO. C. OHC-CHO. D. CH3CH(OH)CHO Cu 3: Dy gm cc cht u tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3, l: A. anehit axetic, butin-1, etilen. B. anehit axetic, axetilen, butin-2. C. axit fomic, vinylaxetilen, propin. D. anehit fomic, axetilen, etilen. Cu 4: Cho cc cht: HCN, H2, dung dch KMnO4, dung dch Br2. S cht phn ng c vi (CH3)2CO l A. 2. B. 4. C. 1. D. 3. Nm 2007 - Khi B Cu 5: t chy hon ton a mol mt anehit X (mch h) to ra b mol CO2 v c mol H2O (bit b = a + c). Trong phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit A. khng no c mt ni i, n chc. B. no, n chc. C. khng no c hai ni i, n chc. D. no, hai chc. Cu 6: Khi oxi ha hon ton 2,2 gam mt anehit n chc thu c 3 gam axit tng ng. Cng thc ca anehit l (cho H = 1, C = 12, O = 16) A. C2H5CHO. B. CH3CHO C. HCHO. D. C2H3CHO Cu 7: Oxi ho 4,48 lt C2H4 ( ktc) bng O2 (xc tc PdCl2, CuCl2), thu c cht X n chc. Ton b lng cht X trn cho tc dng vi HCN (d) th c 7,1 gam CH3CH(CN)OH (xianohirin). Hiu sut qu trnh to CH3CH(CN)OH t C2H4 l (cho H = 1, C = 12, N = 14, O = 16) A. 50%. B. 60%. C. 70%. D. 80%. Nm 2008 - Khi A Cu 8: Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dung dch HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l A. C3H7CHO. B. C4H9CHO. C. HCHO. D. C2H5CHO Cu 9: un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z; cho Z tc dng vi Na sinh ra H2 c s mol bng s mol Z phn ng. Cht X l anehit A. khng no (cha mt ni i C=C), hai chc. B. no, hai chc. C. khng no (cha mt ni i C=C), n chc. D. no, n chc. Cu 10: S ng phn xeton ng vi cng thc phn t C5H10O l A. 3. B. 5. C. 6. D. 4.

Chuyn ho hu c n thi i hc 2007 - 2012

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Nm 2008 - Khi B Cu 11: Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H6O v c cc tnh cht: X, Z u phn ng vi nc brom; X, Y, Z u phn ng vi H2 nhng ch c Z khng b thay i nhm chc; cht Y ch tc dng vi brom khi c mt CH3COOH. Cc cht X, Y, Z ln lt l: A. C2H5CHO, (CH3)2CO, CH2=CH-CH2OH. B. C2H5CHO, CH2=CH-O-CH3, (CH3)2CO. C. CH2=CH-CH2OH, C2H5CHO, (CH3)2CO. D. (CH3)2CO, C2H5CHO, CH2=CH-CH2OH. Nm 2009 - Khi A Cu 12: Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam H2O v 7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l A. 46,15%. B. 35,00%. C. 53,85%. D. 65,00%. Cu 13: Dy gm cc cht u iu ch trc tip (bng mt phn ng) to ra anehit axetic l: A. CH3COOH, C2H2, C2H4. B. C2H5OH, C2H4, C2H2. C. C2H5OH, C2H2, CH3COOC2H5. D. HCOOC2H3, C2H2, CH3COOH Cu 14: Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO 3 trong NH3, thu c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, to) th 0,125 mol X phn ng ht vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l A. CnH2n(CHO)2 (n 0). B. CnH2n+1CHO (n 0). C. CnH2n-1CHO (n 2). D. CnH2n-3CHO (n 2). Nm 2009 - Khi B Cu 15: t chy hon ton mt hp cht hu c X, thu c 0,351 gam H2O v 0,4368 lt kh CO2 ( ktc). Bit X c phn ng vi Cu(OH)2 trong mi trng kim khi un nng. Cht X l A. C2H5CHO. B. CH2=CH-CH2-OH. C. CH3COCH3. D. O=CH-CH=O. Cu 16: Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca X v Y tng ng l A. HOCH2CH2CHO v HOCH2CH2CH2CHO. B. HOCH2CHO v HOCH2CH2CHO. C. HCOOCH3 v HCOOCH2CH3. D. HOCH(CH3)CHO v HOOCCH2CHO. Cu 17: Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l A. 10,5. B. 8,8. C. 24,8. D. 17,8. Cu 18: t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X tc dng c vi Na, tham gia phn ng trng bc v phn ng cng Br2 theo t l mol 1 : 1. Cng thc cu to ca X l A. HOOC-CH=CH-COOH. B. HO-CH2-CH2-CH2-CHO. C. HO-CH2-CH=CH-CHO. D. HO-CH2-CH2-CH=CH-CHO. Nm 2010 - Khi A Cu 19: Axeton c iu ch bng cch oxi ho cumen nh oxi, sau thu phn trong dung dch H 2SO4 long. thu c 145 gam axeton th lng cumen cn dng (gi s hiu sut qu trnh iu ch t 75%) l A. 400 gam. B. 600 gam. C. 300 gam. D. 500 gam. Cu 20: Cho m gam hn hp etanal v propanal phn ng hon ton vi lng d dung dch AgNO3 trong NH3, thu c 43,2 gam kt ta v dung dch cha 17,5 gam mui amoni ca hai axit hu c. Gi tr ca m l A. 9,5. B. 10,9. C. 14,3. D. 10,2 Cu 21: Hiro ho cht hu c X thu c (CH3)2CHCH(OH)CH3. Cht X c tn thay th l A. metyl isopropyl xeton. B. 2-metylbutan-3-on.
Chuyn ho hu c n thi i hc 2007 - 2012

Bin son GV Phm Khc Tun Mobile: 0972 98 4422 C. 3-metylbutan-2-ol.

D. 3-metylbutan-2-on.

Nm 2010 - Khi B Cu 22: Cho hn hp M gm anehit X (no, n chc, mch h) v hirocacbon Y, c tng s mol l 0,2 (s mol ca X nh hn ca Y). t chy hon ton M, thu c 8,96 lt kh CO2 (ktc) v 7,2 gam H2O. Hirocacbon Y l A. C3H6. B. C2H4. C. CH4. D. C2H2. Cu 23: Cho phn ng: 2 C6H5-CHO + KOH C6H5-COOK + C6H5-CH2-OH Phn ng ny chng t C6H5-CHO A. ch th hin tnh oxi ho. B. khng th hin tnh kh v tnh oxi ho. C. va th hin tnh oxi ho, va th hin tnh kh. D. ch th hin tnh kh. Nm 2011 - Khi A Cu 24: t chy hon ton anehit X, thu c th tch kh CO2 bng th tch hi nc (trong cng iu kin nhit , p sut). Khi cho 0,01 mol X tc dng vi mt lng d dung dch AgNO3 trong NH3 th thu c 0,04 mol Ag. X l A. anehit fomic. B. anehit axetic. C. anehit khng no, mch h, hai chc. D. anehit no, mch h, hai chc. Cu 25: X, Y, Z l cc hp cht mch h, bn c cng cng thc phn t C 3H6O. X tc dng c vi Na v khng c phn ng trng bc. Y khng tc dng c vi Na nhng c phn ng trng bc. Z khng tc dng c vi Na v khng c phn ng trng bc. Cc cht X, Y, Z ln lt l: A. CH3-CO- CH3, CH3- CH2-CHO, CH2=CH- CH2-OH. B. CH3- CH2-CHO, CH3-CO- CH3, CH2=CH- CH2-OH. C. CH2=CH- CH2-OH, CH3-CO- CH3, CH3- CH2-CHO. D. CH2=CH- CH2-OH, CH3- CH2-CHO, CH3-CO- CH3. Cu 25: Pht biu no sau y v anehit v xeton l sai? A. Axeton khng phn ng c vi nc brom. B. Anehit fomic tc dng vi H2O to thnh sn phm khng bn. C. Hiro xianua cng vo nhm cacbonyl to thnh sn phm khng bn. D. Axetanehit phn ng c vi nc brom Nm 2011 - Khi B Cu 26: Hn hp M gm mt anehit v mt ankin (c cng s nguyn t cacbon). t chy hon ton x mol hn hp M, thu c 3x mol CO2 v 1,8x mol H2O. Phn trm s mol ca anehit trong hn hp M l A. 50%. B. 40%. C. 30%. D. 20%. Cu 27: hiro ho hon ton 0,025 mol hn hp X gm hai anehit c khi lng 1,64 gam, cn 1,12 lt H 2 (ktc). Mt khc, khi cho cng lng X trn phn ng vi mt lng d dung dch AgNO 3 trong NH3 th thu c 8,64 gam Ag. Cng thc cu to ca hai anehit trong X l A. CH2=C(CH3)-CHO v OHC-CHO. B. OHC-CH2-CHO v OHC-CHO. C. CH2=CH-CHO v OHC-CH2-CHO. D. H-CHO v OHC-CH2-CHO. Cu 28: Hn hp X gm hai anehit n chc Y v Z (bit phn t khi ca Y nh hn ca Z). Cho 1,89 gam X tc dng vi mt lng d dung dch AgNO3 trong NH3, sau khi cc phn ng kt thc, thu c 18,36 gam Ag v dung dch E. Cho ton b E tc dng vi dung dch HCl (d), thu c 0,784 lt CO2 (ktc). Tn ca Z l A. anehit axetic. B. anehit acrylic. C. anehit propionic. D. anehit butiric Cu 29: X l hn hp gm H2 v hi ca hai anehit (no, n chc, mch h, phn t u c s nguyn t C nh hn 4), c t khi so vi heli l 4,7. un nng 2 mol X (xc tc Ni), c hn hp Y c t khi hi so vi heli l 9,4. Thu ly ton b cc ancol trong Y ri cho tc dng vi Na (d), c V lt H2 (ktc). Gi tr ln nht ca V l A. 13,44. B. 5,6. C. 11,2. D. 22,4

Chuyn ho hu c n thi i hc 2007 - 2012

Bin son GV Phm Khc Tun Mobile: 0972 98 4422

Nm 2012- Khi A Cu 30: Hirat ha 5,2 gam axetilen vi xc tc HgSO4 trong mi trng axit, un nng. Cho ton b cc cht hu c sau phn ng vo mt lng d dung dch AgNO3 trong NH3 thu c 44,16 gam kt ta. Hiu sut phn ng hirat ha axetilen l A. 80%. B. 70%. C. 92%. D. 60%. Nm 2012 - Khi B Cu 31: Cho 0,125 mol anehit mch h X phn ng vi lng d dung dch AgNO3 trong NH3 thu c 27 gam Ag. Mt khc, hiro ho hon ton 0,25 mol X cn va 0,5 mol H2. Dy ng ng ca X c cng thc chung l A. CnH2n+1CHO (n 0). B. CnH2n-1CHO (n 2). H CHO C. Cn 2n-3 (n 2). D. CnH2n(CHO)2 (n 0).

Chuyn ho hu c n thi i hc 2007 - 2012