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CACBOHIDRAT QUA CC NM THI I HC

Nm 2007 Khi A Cu 1: Cho m gam tinh bt ln men thnh ancol (ru) etylic vi hiu sut 81%. Ton b lng CO2 sinh ra c hp th hon ton vo dung dch Ca(OH)2, thu c 550 gam kt ta v dung dch X. un k dung dch X thu thm c 100 gam kt ta. Gi tr ca m l (cho H = 1, C = 12, O = 16, Ca = 40) A. 550. B. 810. C. 650. D. 750 Cu 2: chng minh trong phn t ca glucoz c nhiu nhm hiroxyl, ngi ta cho dung dch glucoz phn ng vi A. kim loi Na. B. AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. C. Cu(OH)2 trong NaOH, un nng. D. Cu(OH)2 nhit thng. Nm 2007 Khi B Cu 3: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc axit sunfuric c, nng. c 29,7 kg xenluloz trinitrat, cn dng dung dch cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l (cho H = 1, C =12, N = 14, O = 16) A. 30 kg. B. 42 kg. C. 21 kg. D. 10 kg Cu 4: Pht biu khng ng l A. Dung dch mantoz tc dng vi Cu(OH)2 khi un nng cho kt ta Cu2O. B. Sn phm thy phn xenluloz (xc tc H+, to) c th tham gia phn ng trng gng. C. Thy phn (xc tc H+, to) saccaroz cng nh mantoz u cho cng mt monosaccarit. D. Dung dch fructoz ho tan c Cu(OH)2 Nm 2008 Khi A Cu 5: Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia phn ng A. thy phn. B. trng gng. C. trng ngng. D. ho tan Cu(OH)2. Cu 6: Gluxit (cacbohirat) ch cha hai gc glucoz trong phn t l A. tinh bt. B. mantoz. C. xenluloz. D. saccaroz. Cu 7: Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l A. 1,44 gam. B. 2,25 gam. C. 1,80 gam. D. 1,82 gam Nm 2008 Khi B Cu 8: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol) etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l 0,8 g/ml) A. 6,0 kg. B. 5,4 kg. C. 5,0 kg. D. 4,5 kg. Cu 9: Th tch dung dch HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20 %) A. 70 lt. B. 49 lt. C. 81 lt. D. 55 lt. Cu 10: Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (mantoz). S cht trong dy tham gia c phn ng trng gng l A. 5. B. 3. C. 6. D. 4. Nm 2009 Khi A Cu 11: Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht vo dung dch nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi khi lng dung dch nc vi trong ban u. Gi tr ca m l
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A. 20,0. B. 30,0. C. 13,5. Cu 12: Cacbohirat nht thit phi cha nhm chc ca A. ancol. B. xeton. C. amin. Cu 13: Dy gm cc dung dch u tham gia phn ng trng bc l: A. Glucoz, mantoz, axit fomic, anehit axetic. B. Fructoz, mantoz, glixerol, anehit axetic. C. Glucoz, glixerol, mantoz, axit fomic. D. Glucoz, fructoz, mantoz, saccaroz.

D. 15,0. D. anehit.

Nm 2009 Khi B Cu 14: Cho mt s tnh cht: c dng si (1); tan trong nc (2); tan trong nc Svayde (3); phn ng vi axit nitric c (xc tc axit sunfuric c) (4); tham gia phn ng trng bc (5); b thu phn trong dung dch axit un nng (6). Cc tnh cht ca xenluloz l: A. (3), (4), (5) v (6). B. (1), (3), (4) v (6). C. (1), (2), (3) v (4). D. (2), (3), (4) v (5). Cu 15: Pht biu no sau y l ng? A. Saccaroz lm mt mu nc brom. B. Glucoz b kh bi dung dch AgNO3 trong NH3. C. Xenluloz c cu trc mch phn nhnh. D. Amilopectin c cu trc mch phn nhnh Cu 16: Pht biu no sau y khng ng? A. Glucoz tn ti dng mch h v dng mch vng. B. dng mch h, glucoz c 5 nhm OH k nhau. C. Khi glucoz dng vng th tt c cc nhm OH u to ete vi CH3OH. D. Glucoz tc dng c vi nc brom Nm 2010 Khi A Cu 16: Mt phn t saccaroz c A. mt gc -glucoz v mt gc -fructoz. B. mt gc -glucoz v mt gc -fructoz. C. hai gc -glucoz. D. mt gc -glucoz v mt gc -fructoz Cu 17: T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic (hiu sut 80%). Oxi ho 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X. trung ho hn hp X cn 720 ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l A. 20%. B. 10%. C. 80%. D. 90%. Nm 2010 Khi B Cu 18: Cc dung dch phn ng c vi Cu(OH)2 nhit thng l: A. lng trng trng, fructoz, axeton. B. anehit axetic, saccaroz, axit axetic. C. fructoz, axit acrylic, ancol etylic. D. glixerol, axit axetic, glucoz. Cu 19: Cht X c cc c im sau: phn t c nhiu nhm -OH, c v ngt, ho tan Cu(OH) 2 nhit thng, phn t c lin kt glicozit, lm mt mu nc brom. Cht X l A. xenluloz. B. mantoz. C. glucoz . D. s accaroz Nm 2011 Khi A Cu 20: Xenluloz trinitrat c iu ch t phn ng gia axit nitric vi xenluloz (hiu sut phn ng 60% tnh theo xenluloz). Nu dng 2 tn xenluloz th khi lng xenluloz trinitrat iu ch c l A. 3,67 tn. B. 2,97 tn. C. 1,10 tn. D. 2,20 tn
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Cu 21: Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut ton b qu trnh l 90%. Hp th ton b lng CO2 sinh ra khi ln men m gam tinh bt vo nc vi trong, thu c 330 gam kt ta v dung dch X. Bit khi lng X gim i so vi khi lng nc vi trong ban u l 132 gam. Gi tr ca m l A. 324. B. 405. C. 297. D. 486. Nm 2011 Khi B Cu22: Cho cc pht biu sau v cacbohirat: (a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc. (b) Tinh bt v xenluloz u l polisaccarit. (c) Trong dung dch, glucoz v saccaroz u ho tan Cu(OH)2, to phc mu xanh lam. (d) Khi thu phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit, ch thu c mt loi monosaccarit duy nht. (e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3 trong NH3 thu c Ag. (g) Glucoz v saccaroz u tc dng vi H2 (xc tc Ni, un nng) to sobitol. S pht biu ng l A. 5. B. 6. C. 4. D. 3. Cu 23: Thu phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c dung dch X (hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt lng d dung dch AgNO3 trong NH3 th lng Ag thu c l A. 0,090 mol. B. 0,095 mol. C. 0,06 mol. D. 0,12 mol. Cu 24: Cho cc pht biu sau: (a) C th dng nc brom phn bit glucoz v fructoz. (b) Trong mi trng axit, glucoz v fructoz c th chuyn ho ln nhau. (c) C th phn bit glucoz v fructoz bng phn ng vi dung dch AgNO3 trong NH3. (d) Trong dung dch, glucoz v fructoz u ho tan Cu(OH)2 nhit thng cho dung dch mu xanh lam. (e) Trong dung dch, fructoz tn ti ch yu dng mch h. (g) Trong dung dch, glucoz tn ti ch yu dng vng 6 cnh (dng v ). S pht biu ng l A. 4. B. 3. C. 5. D. 2. Nm 2012 Khi A Cu25: Cho s phn ng : ctc (a) X + H2O x Y (b) Y + AgNO3 + NH3 + H2O amoni gluconat + Ag + NH4NO3 ctc (c) Y x E + Z anh sang X+G (d) Z + H2O chat diepluc X, Y, Z ln lt l: A. Tinh bt, glucoz, etanol. B. Tinh bt, glucoz, cacbon ioxit. C. Xenluloz, saccaroz, cacbon ioxit. D. Xenluloz, fructoz, cacbon ioxit. Cu 26: Cho cc pht biu sau: (a) t chy hon ton este no, n chc, mch h lun thu c s mol CO2 bng s mol H2O. (b) Trong hp cht hu c nht thit phi c cacbon v hiro. (c) Nhng hp cht hu c c thnh phn nguyn t ging nhau, thnh phn phn t hn km nhau mt hay nhiu nhm CH2 l ng ng ca nhau. (d) Dung dch glucoz b kh bi AgNO3 trong NH3 to ra Ag. (e) Saccaroz ch c cu to mch vng.
Chuyn ho hu c n thi i hc 2007 - 2012

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S pht biu ng l A. 4. B. 5. C. 3. Cu 27: Cho cc pht biu sau v cacbohirat: (a) Tt c cc cacbohirat u c phn ng thy phn. (b) Thy phn hon ton tinh bt thu c glucoz. (c) Glucoz, fructoz v mantoz u c phn ng trng bc. (d) Glucoz lm mt mu nc brom. S pht biu ng l: A. 3. B. 4. C. 1.

D. 2.

D. 2.

Nm 2012 Khi B Cu 28: Th nghim no sau y chng t trong phn t glucoz c 5 nhm hiroxyl? A. Cho glucoz tc dng vi Cu(OH)2. B. Tin hnh phn ng to este ca glucoz vi anhirit axetic. C. Thc hin phn ng trng bc. D. Kh hon ton glucoz thnh hexan. Cu 29: iu ch 53,46 kg xenluloz trinitrat (hiu sut 60%) cn dng t nht V lt axit nitric 94,5% (D = 1,5 g/ml) phn ng vi xenluloz d. Gi tr ca V l A. 24. B. 40. C. 36. D. 60. Cu 30: Thy phn hn hp gm 0,01 mol saccaroz v 0,02 mol mantoz trong mi trng axit, vi hiu sut u l 60% theo mi cht, thu c dung dch X. Trung ha dung dch X, thu c dung dch Y, sau cho ton b Y tc dng vi lng d dung dch AgNO3 trong NH3, thu c m gam Ag. Gi tr ca m l A. 7,776. B. 6,480. C. 8,208. D. 9,504.

Chuyn ho hu c n thi i hc 2007 - 2012