S GIO DC V O TO

BNH PHC

K THI TUYN SINH VO LP 10 THPT CHUYN

NM HC 2009-2010
Mn: Ho hc

chnh thc
Thi gian: 120 pht (khng k thi gian giao )
( thi ny c 1 trang)

Cu 1:(3im)
1. Ho tan hn hp gm BaO, Al2O3, FeO trong mt lng nc d, thu c dung dch A
v cht rn B. Sc kh CO2 d vo dung dch A, phn ng to kt ta. Cho kh CO d i
qua phn B un nng thu c cht rn C. Cho C tc dng vi dung dch NaOH d, thy
tan mt phn cn li cht rn D. Ho tan ht D trong lng d dung dch H2SO4 long ri
cho dung dch thu c tc dng vi dung dch KMnO4. Xc nh thnh phn cc cht c
trong A, B, C, D v vit cc phng trnh phn ng xy ra.
2. C dung dch FeSO4 ln tp cht l CuSO4. Trnh by phng php ho hc c th
loi b tp cht CuSO4 khi dung dch FeSO4. Gii thch v vit cc phng trnh phn ng
xy ra.
3. C 5 kh sau ng ring bit trong cc bnh khng c nhn: O 2, O3, N2, Cl2 v NH3 . Hy
nhn bit cc kh bng phng php ho hc. Vit cc phng trnh phn ng dng.
Cu 2: (2,75 im)
1. Xc nh cc cht hu c ng vi mi ch ci A, B, C, D v vit cc phng trnh phn
ng (ghi r iu kin) thc hin dy chuyn ho sau:
CH3COONa CH4 A B C D Caosu Buna.
2. C 3 l mt nhn, mi l ng mt trong cc cht kh sau: etilen, metan, CO. Trnh by
phng php ho hc nhn bit chng. Vit cc phng trnh phn ng.
3. C hn hp gm ru etylic v axit axetic. Trnh by phng php ho hc c th
tch ring mi cht. Vit cc phng trnh phn ng.
Cu 3: (2,75 im)
Ho tan hon ton 6,93 gam hn hp gm Zn, Fe v Al trong dung dch H2SO4
long thu c kh X v dung dch Y. Cho kh X i qua vi sng, sau cho i qua 32 gam
CuO t nng, cui cng cho qua H2SO4 c. Sau th nghim khi lng bnh ng H2SO4
c tng thm 2,97 gam. Dung dch Y cho tc dng vi dung dch NaOH d, nng trong
khng kh. Lc ly kt ta, ri nung n khi lng khng i, thu c 2,4 gam cht rn.
Hy vit cc phng trnh phn ng xy ra v tnh thnh phn phn trm mi kim
loi trong hn hp u, bit rng cc phn ng u c hiu sut l 100%.
Cu 4: (1,5 im)
t chy hon ton 7,12 gam cht hu c A ngi ta dng va ht 6,72 lt kh
oxi. Sn phm ca phn ng thu c gm 5,04 gam nc v 6,272 lt hn hp kh N2 v
CO2 (cc th tch u o iu kin tiu chun). Bit t khi hi ca cht A i vi hiro l
44,5.
a. Xc nh cng thc phn t ca cht A.
b. Vit cng thc cu to ca A, bit rng A l este ca ru metylic (CH3OH).
(Cho bit: H = 1; O = 16; C = 12; N = 14; Fe = 56; Zn = 65; Al = 27; Cu = 64)
Ht

S GIO DC V O TO
Bnh Phc

K THI TUYN SINH VO LP 10 - THPT CHUYN

Nm hc 2009-2010
Hng dn chm thi chnh thc
Mn: Ho hc

Cu

Ni dung
1.
Ho tan hn hp vo nc d c cc phn ng:
BaO + H2O Ba(OH)2
Ba(OH)2 + Al2O3 Ba(AlO2)2 + H2O
Dung dch A thu c l: Ba(AlO2)2
Cht rn B gm: FeO v Al2O3 d (v C tan mt phn trong d d NaOH)
Sc kh CO2 vo d.d A c phn ng:
Ba(AlO2)2 + 2CO2 + 4H2O 2 Al(OH)3 + Ba(HCO3)2
Cho kh CO d qua B nung nng c phn ng:
FeO + CO Fe + CO2
Cht rn C gm : Fe v Al2O3
Cho C tc dng vi dung dch NaOH d:
2NaOH + Al2O3 2NaAlO2 + H2O
Cht rn D l Fe
Cho D tc dung vi H2SO4 sau cho tc dng vi KMnO4
Fe + H2SO4 FeSO4 + H2
10FeSO4 + 2KMnO4 + 8H2SO4 2MnSO4 + 5Fe2(SO4)3 + K2SO4 + 8H2O

2.
V tnh kh ca st mnh hn ng. Ta thm bt st (d ) dung dch cha
tp cht st s kh ht mui CuSO4 (Cu2+) thnh Cu khng tan . Sau
lc dung dch loi b phn cht rn, ta thu c dung dch FeSO4 tinh
khit

Fe + CuSO4
FeSO4 + Cu
3.
Ly mi kh mt t em th nghim.
-Dng giy qu tm t a vo 5 bnh cha kh, nhn ra Kh NH3 lm
qu ho xanh.
- Nhn ra Cl2 l kh lm qu chuyn mu sau mt mu

Cl2 + H2O
HCl + HClO
- Dng giy tm dung dch KI v h tinh bt nhn ra O3 l kh lm giy
ho xanh
2KI + O3 + H2O
2KOH + I2 +O2
I2 + tinh bt c mu xanh
2 kh cn li a tn m vo nhn ra O2 lm tn m bng sng, N2 lm
m tt.
1.
Hon thnh s ho hc:

im
3,0
1,5
0,25
0,25

0,25
0,25
0,125
0,125
0,25
0,5
0,25
0,25
1,0
0,125
0,125
0,125
0,125
0,25
0,125
0,125
2,75
1,25
2

CaO
CH3COONa + NaOH
CH4 + Na2CO3
1500
2CH4
C2H2 +3H2
Pd
C2H2 + H2
C 2 H4
H SO t
C2H4 + H2O
C2H5OH

Al O

2C2H5OH
CH2=CH-CH=CH2 + H2 +2H2O
450
0

2 3
0

Na

xt, t
n CH2=CH-CH=CH2
(-CH2-CH=CH-CH2-)n
(Nu hc sinh chn cc cht A, B, C, D khc m vn thc hin 4
phng trnh ng vn cho im ti a)
2.
Cho ln lt cc kh qua dung dch nc brom nhn ra etilen lm nc
brom t mu vng da cam chuyn sang khng mu.
CH2=CH2 + Br2 BrCH2-CH2Br
t metan v oxit cacbon, dn sn phm i qua CuSO4 khan, nu sn
phm lm chuyn CuSO4 khan thnh mu xanh (CuSO4. 5 H2O ) th cht
kh em t l metan (sn phm c H2O).
CH4 + 2O2 CO2 + 2H2O
CO + O2 CO2
Kh cn li l CO.
3.
Trung ho hn hp bng dung dch NaOH
CH3COOH + NaOH CH3COONa + H2O
Chng ct dung dch, cho hi r u ngng t thu dc ru etylic, Cho
dung dch H2SO4 long tc dng vi cht cn li
2CH3COONa + H2SO4 2CH3COOH + Na2 SO4
Chng ct dung dch ln na ta thu c CH3COOH

1. Cc phn ng xy ra:
Zn + H2SO4 = ZnSO4 + H2
(1)
Fe + H2SO4 = FeSO4 + H2
(2)
2Al + 3H2SO4 = Al2( SO4)3 +3 H2 (3)
CaO +H2O = Ca(OH)2
(4)
t
H2 + CuO
(5)
Cu + H2O
Hi nc c hp th bng H2SO4 c .
Cc phn ng ca dung dch Y vi d d NaOH:
ZnSO4 + 2NaOH = Zn(OH)2 + Na2SO4
Zn(OH)2 + 2NaOH = Na2(Zn(OH)4)
FeSO4 + 2NaOH = Fe(OH)2 + Na2SO4
4Fe(OH)2 + O2 + 2H2O = 4Fe(OH)3
Al2(SO4)3 + 6NaOH = 2Al(OH)3 + 3Na2SO4
Al(OH)3 + NaOH =NaAlO2 + 2H2O
Nung k t ta:
2Fe(OH)3 = Fe2O3 + 3H2O
2.Tnh thnh phn %:
Gi x ,y, z ln lt l s mol ca Zn, Fe v Al trong hn hp u ta c :
65x + 56y + 27 z = 6,93
S mol nc to thnh l: 2,97: 18 = 0,165 mol
S mol CuO dng cho phn ng l : 32: 80 = 0,4 mol
0

0,25
0,25
0,125
0,25
0,25
0,125

0,75
0.125
0,25
0,125
0,25
0,75
0.25
0,25
0,25
2,75
1,75
0,125
0,125
0,125
0,125
0,125

0,125
0,25
0,125
0,25
0,125
0,125
0,125
1,0
0,25
3

( H2 phn ng ht)
Vy theo phn ng 1,2,3 ta c : x+ y + 1,5 z = 0,165
Cht rn thu c sau khi nung ch c Fe2O3 nn
y:2 = 2,4:160 => y= 0,03 ( mol Fe); x= 0,06 ( mol Zn), z= 0.05 (mol Al)
Thnh phn phn trm cc kim loi trong hn hp u l:
65.0, 06.100
= 56, 28%
6,93
56.0, 03.100
% Fe =
= 24, 24%
6,93
% Al = 19, 48%
% Zn =

0,125

0,25
0,125
0,125
0,125
1,5

a.
Theo nh lut bo ton khi lng, ta c khi lng N2 v CO2 l:
7,12 + 32.6,72: 22,4 -5,04 = 11,68 (g)
Gi s mol N2 l x , s mol CO2 l y ta c:
x+y = 6,272: 22,4 = 0,28
28x + 44y = 11,68
=.>> x= 0,004, y = 0,24
Vy trong 7,12 gam cht hu c A cha lng C l: 0,24. 12 = 2,88 gam
lng H l: 2.5,04: 18 = 0,56 gam, lng N l: 0,004 .28 =1,12 gam,
lng O l: 7,12 -2,88-0,56-1,12=2,56 gam.
MA = 44,5.2= 89
Trong 1 mol cht A s mol cc nguyn t ln lt l:
2,88.89
:12 = 3
7,12
0,56.89
nH =
=7
7,12
1,12.89
nN =
:14 = 1
7,12
2,56.89
nO =
:16 = 2
7,12

1,25
0,125
0,125
0.25
0,25
0,25

nC =

=> CTPT ca A l: C3H7NO2

0,25

b) CTCT ca A:
O
H2N CH2 C

0,25

O CH3