S Gio dc v o to thanh ho chnh thc

K thi chn hc sinh gii tnh Nm hc 2006-2007 Mn thi: Ha hc - Lp: 9 THCS Ngy thi: 28/03/2007. Thi gian: 150 pht (khng k thi gian giao thi) thi ny c 1 trang gm 4 cu.

Cu 1. (6,5 im)
1. Khi cho bt nhm tc dng vi dung dch NaOH un nng thu c dung dch X1 v kh X2. Thm vo X1 mt t tinh th NH4Cl ri tip tc un nng thy to thnh kt ta X3 v c kh X4 thot ra. Xc nh X1, X2 , X3 , X4. Vit phng trnh ho hc biu din cc phn ng xy ra. 2. Xc nh cc cht A, B, C, D, E, F, H v hon thnh s bin ha sau:
+ NaOH

C
+HCl

+E H +F
Bit rng H l thnh phn chnh ca dng np cho cc bnh cha chy(dp

phn; B l kh
+ NaOH

A B
t0

+NaOH

tt la). 3. a. Bng phng php ha hc hy tch SO2 ra khi hn hp gm cc kh SO2 , SO3 , O2. b. Bng phng php ha hc hy tch ring tng kim loi ra khi hn hp gm Mg, Al, Fe, Cu. 4. C 5 cht rn: BaCl2 , Na2SO4 , CaCO3 , Na2CO3 , CaSO4.2H2O ng trong 5 l ring bit. Hy t chn 2 cht dng lm thuc th nhn bit cc cht rn ng trong mi l. Cu 2: (5,5 im) 1. Vit cng thc cu to cc ng phn ng vi cng thc phn t: C 2H4O2 , C3H8O, C5H10 . 2. Cht A c cng thc phn t C4H6. Xc nh cng thc cu to ca A, B, C, D v hon thnh phng trnh ha hc biu din cc phn ng theo s :
+Cl2 dd NaOH +H2 H2SO4

t0,xt,p

A
1:1

C
Ni,t0

D
1700C

Cao su

3. Hn hp kh gm CO, CO2, C2H4 v C2H2. Trnh by phng php dng tch tng kh ra khi hn hp

Cu3: (4,0 im)

C hai dung dch; H2SO4 (dung dch A), v NaOH (dung dch B). Trn 0,2 lt dung dch A vi 0,3 lt dung dch B c 0,5 lt dung dch C. Ly 20 ml dung dch C, thm mt t qu tm vo, thy c mu xanh. Sau thm t t dung dch HCl 0,05M ti khi qu tm i thnh mu tm thy ht 40 ml dung dch axit. Trn 0,3 lt A vi 0,2 lt B c 0,5 lt dung dch D. Ly 20 ml dung dch D, thm mt t qu tm vo thy c mu . Sau thm t t dung dch NaOH 0,1M ti khi qu tm i thnh mu tm thy ht 80 ml dung dch NaOH. a. Tnh nng mol/l ca 2 dung dch A v B. b. Trn VB lt dung dch NaOH vo VA lt dung dch H2SO4 trn ta thu c dung dch E. Ly V ml dung dch E cho tc dng vi 100 ml dung dch BaCl2 0,15 M c kt ta F. Mt khc ly V ml dung dch E cho tc dng vi 100 ml dung dch AlCl3 1M c kt ta G. Nung F hoc G nhit cao n khi lng khng i th u thu c 3,262gam cht rn. Tnh t l VB:VA

Cu 4: (4,0 im)
t chy hon ton 3,24 gam hn hp X gm hai cht hu c A v B khc dy ng ng v cng loi hp cht, trong A hn B mt nguyn t cacbon, ngi ta ch thu c nc v 9,24 gam CO2. Bit t khi hi ca X i vi H2 l 13,5. a. Tm cng thc cu to ca A, B v tnh thnh phn trm theo khi lng ca mi cht trong hn hp X. b. T B vit s phn ng iu ch CH3COOCH3 v CH3COO CH -- CH3 CH3 (Cho: O=16, H=1, C=12, Ca=40, Ba=137, Na=23, S=32, Cl=35,5 )

--------------------------------------------- Ht ----------------------------------------------Lu : Hc sinh c s dng my tnh thng thng, khng c s dng bt k ti liu g (k c bng tun hon cc nguyn t ha hc). H v tn: .............................................S bo danh:.................................................... S Gio dc v o to Hng dn chm bi Thi Thanh ha hc sinh gii lp 9 THCS Nm hc 2006

2007

Mn :

Ho hc
Thang im 6,5 1,5

p n Cu 1: 1. Cc phng trnh ha hc:

2Al + 2NaOH + 2H2O ..................................................................... NaOH + NH4Cl NaCl + NH3 + H2O NaAlO2 + NH4Cl + H2O Al(OH)3 ------------------------------------NaAlO2 +

3H2 0,5

0,5
+NH3 + NaCl

=> Dung dch X1 cha NaOH d v NaAlO2 - Kh A2 l H2. - Kt ta A3 l Al(OH)3 Kh A4

................................................................

0,5 l NH3. 1,5

2. Cc phng trnh ha hc:

t MgCO3 MgO + CO2 CO2 + NaOH NaHCO3 CO2 + 2NaOH Na2CO3 + H2O NaHCO3 + NaOH Na2CO3 H2O ......................................................................... Na2CO3 + HCl NaHCO3 + NaCl NaHCO3 + Ca(OH)2 CaCO3 + NaOH + H2O Na2CO3 + CaCl2 CaCO3 2NaCl ........................................................................
0

+ 0,5

0,5

=> B l CO2 , A l mui cacbonnat d b nhit phn nh MgCO3, 0,5 BaCO3..., C l NaHCO3 , D l Na2CO3 , E l Ca(OH)2 , F l mui tan ca canxi nh CaCl2, Ca(NO3)2 ..., H l CaCO3. ..............................................................................

3. a. Cho hn hp qua dd NaOH d, cn li O2:

SO2 + 2NaOH Na2SO3 + H2O SO3 + 2NaOH Na2SO4 + H2O

2,0 0,5 0,25 0,25 1,5

+ 0,25

dung dch thu c tc dng vi H2SO4 long:

Na2SO3 + H2SO4 Na2SO4 + H2O + SO2.

b. Ho tan hn hp trong dd NaOH d, Al tan theo phn ng:

2Al + 2NaOH + 2H2O 3H2. ................................................................... NaAlO2 + CO2 + 2H2O Al(OH)3 + NaHCO3 2NaAlO2

- Lc tch c Fe, Mg, Cu khng tan. Thi CO2 d vo nc lc: - Lc tch kt ta Al(OH)3, nung n khi lng khng i thu c Al2O3, in phn nng chy thu c Al:
t 2Al(OH)3 Al2O3 + 3H2O
0

2Al2O3 3O2

dpnc 4Al .....................................................................................

0,25

- Ho tan hn hp 3 kim loi trong dd HCl d, tch c Cu khng tan v dung dch hai mui:
Mg + 2HCl MgCl2 + H2 Fe + 2HCl FeCl2 + H2

- Cho dd NaOH d vo dung dch 2 mui :

MgCl2 + 2NaOH Mg(OH)2 + 2NaCl FeCl2 + 2NaOH Fe(OH)2 2NaCl ............................................................................... +

0,25

- Lc kt ta v nung nhit cao:

Mg(OH)2 MgO + H2O t0 4Fe(OH)2 + O2 2Fe2O3 + 4H2O
t Fe2O3 + 3CO 2Fe + 3CO2
0

- Thi CO d vo hn hp 2 oxit nung nhit cao: MgO + CO khng phn ng 0,5 - Ho tan hn hp ( ngui) sau khi nung vo H 2SO4 c ngui d, MgO tan cn Fe khng tan c tch ra:
......................................................................................... MgO + H2SO4 (c ngui) MgSO4 + H2O MgSO4 +2NaOH d Mg(OH)2 + Na2SO4 Mg(OH)2 + 2HCl MgCl2 + 2H2O dpnc Mg + Cl2 MgCl2

- Tin hnh cc phn ng vi dung dch cn li thu c Mg:

0,25

4. - Ho tan cc cht trong nc d, phn bit hai nhm cht:

1.5

- Nhm 1 gm cc cht khng tan: CaCO3 , CaSO4.2H2O. Dng dd HCl nhn c cc cht nhm 1 (Vit 0,5 PTHH). ........................................................................... 0,5

- Nhm 2 gm cc cht tan l BaCl2 , Na2SO4 , Na2CO3 . Dng dd HCl nhn Na2CO3. ........................................................................... - Dng Na2CO3 mi tm ; nhn c BaCl2 . Cn li Na2SO4.
Na2CO3 +2HCl 2NaCl + CO2 + H2O Na2CO3 + BaCl2 BaCO3 2NaCl .......................................................................................

0,5

Cu 2: 1. Cc ng phn

+ C2H4O2: CH3COOH , HCOOCH3 , CHO. ........................................................ + C3H8O: CH3CH2CH2OH , CH3CH(OH) CH3 , CH3-OCH2CH3 ...................................... 0,5 +C5H10: CH2= CHCH2CH2CH3 , CH2= CH-CH(CH3)CH3 , CH2= C(CH3) CH2CH3 , CH3-CH=CH-CH2CH3 , CH3CH=C(CH3)2 . .......................................................................

5,5 1,5 CH2(OH) 0,5 0,5

2. Theo ra cng thc cu to ca cc cht l :

A: CH2=CH-CH=CH2 , C: CH2OH-CH=CH-CH2OH. CH2OH ..............................

2,0
B: CH2Cl-CH=CH-CH2Cl D: CH2OH-CH2- CH2- 1,0

Phng trnh ha hc:

1,4 CH2=CH-CH=CH2 + Cl2 CH2Cl-CH=CH-CH2Cl toc CH2Cl-CH=CH-CH2Cl + 2NaOH CH2OH-CH=CH-CH2OH.+2NaCl o Ni ,t c CH2OH-CH=CH-CH2OH. + H2 CH2OH-CH2- CH2-CH2OH 0 170 C , H 2 SO4 dac CH2OH-CH2- CH2-CH2OH CH2=CH-CH=CH2 0 t , xt , p nCH2=CH-CH=CH2 (-CH2-CH=CH-CH2-)n

1,0 2,0

3. - Dn hn hp kh qua dung dch Ca(OH)2d ; CO2 c gi li: - Nhit phn CaCO3 thu c CO2:
CO2 CO2 + Ca(OH)2 CaCO3 + H2O
0

t CaCO3 ................................................................................

CaO

+ 0,5

- Dn hn hp kh cn li qua dung dch Ag2O d trong NH3 ; lc tch thu c kt ta v hn hp kh CO , C2H4 v NH3: - Cho kt ta tc dng vi dd H2SO4 long d thu c C2H2 :
t C2Ag2 + H2SO4 C2H2 + Ag2SO4 ..........................................................
0

NH 3 C2H2 + Ag2O C2Ag2 + H2O

0,75

- Dn hn hp CO, C2H4 v NH3 qua dd H2SO4 long d, un nng; thu c CO: - Chng ct dung dch thu c C2H5OH. Tch nc t ru thu c C2H4.
CH3CH2OH
170 C , H 2 SO4 dac
0

2NH3 + H2SO4 (NH4)2SO4 d .dH 2 SO4 C2H4 + H2O CH3CH2OH

0,75
C2H4 +

H2O ...............................................................

Cu 3 . a. PTHH: + Ln th nghim 1: 2NaOH + H2SO4 Na2SO4 + 2H2O V qu tm ha xanh, chng t NaOH d. Thm HCl:
(2) .................................... HCl + NaOH

4,0 1,5
(1) NaCl + H2O 0,5

+ ln th nghim 2: phn ng (1) xy ra, sau qu ha 0,25 chng t H2SO4 d. Thm NaOH: 2NaOH + H2SO4 Na2SO4 + 2H2O
(3) ..............................................

+ t x, y ln lt l nng mol/l ca dung dch A v dd B: T (1), (2),(3) ta c:

0, 05.40 500 . = 0,05 (I) 1000 20 0, 2 y 0,1.80 500 0,3x = = 0,1 (II) 2 1000.2 20

0,3y - 2.0,2x =

0,75

Gii h (I,II) ta c: x = 0,7 mol/l , y = mol/l .................................................. b. V dung dch E to kt ta vi AlCl3 , chng t NaOH cn d.
AlCl3 + 3NaOH Al(OH)3 + 3NaCl t0 2Al(OH)3 Al2O3 + 3H2O Na2SO4 + BaCl2 BaSO4 + 2NaCl (6) ............................................... (4) (5)

1,1 2,5

0,5

Ta c n(BaCl2) = 0,1.0,15 = 0,015 mol n(BaSO4) =

3, 262 = 0,014mol < 0,015 233 0, 014 = 0, 7

=> n(H2SO4) = n(Na2SO4) = n(BaSO4) = 0,014mol . Vy VA = 0,02 lt n(Al2O3) =

3, 262 =0,032 102

0,75 mol v n(AlCl3) = 0,1.1 = 0,1 mol.

................... + Xt 2 trng hp c th xy ra: - Trng hp 1: Sau phn ng vi H2SO4 , NaOH d nhng thiu so vi AlCl3 ( p (4): n(NaOH) p trung ho axit = 2.0,014 = 0,028 mol 0,75 n(NaOH p (4) = 3n(Al(OH)3) = 6n(Al2O3) = 6.0,032 = 0,192 mol. tng s mol NaOH bng 0,028 + 0,192 = 0,22 mol Th tch dung dch NaOH 1,1 mol/l l
0, 22 = 0,2 lt . T l VB:VA = 1,1

0,2:0,02 =10 ..... - Trng hp 2: Sau (4) NaOH vn d v ho tan mt phn Al(OH)3: Al(OH)3 + NaOH NaAlO2 + 2H2O (7) Tng s mol NaOH p (3,4,7) l: 0,028 + 3.0,1 + 0,1 - 2.0,032 = 0,5

0,364 mol Th tch dung dch NaOH 1,1 mol/l l

0,364 0,33 lt 1,1

=> T l VB:VA = 0,33:0,02 = 16,5 Cu 4. a. Theo ra: MX= 13,5.2 = 27 => MB < MX < MA. - MB < 27 => B l CH4 (M = 16) hoc C2H2 26). ............................................... - V A,B khc dy ng ng v cng loi hp cht nn: * Khi B l CH4 (x mol) th A l C2H4(y mol) :
t CH4 + 2O2 CO2 + 2H2O t0 C2H4 + 3O2 2CO2 2H2O ......................................................................
0

4,0 2,5 (M = 0,75

0,5

T cc pthh v ra: mX = 16x + 28y =3,24 n CO = x + 2y = 0,21 Gii phng trnh i s: x = 0,15 , y = 0,03
2

0,25

mCH 4 = 16.0,15 = 2,4 gam. => 74,07% ; %m C 2 H 4 = 25,93% ...................................... * Khi B l C2H2 th A l C3H6 hoc C3H8. + Khi A l C3H6: cng thc cu to ca A l CH3-CH=CH2 hoc CH2CH2 C H2 t PTHH t chy: 2C2H2 + 5O2 4CO2 + 2H2O
0

T cc pthh v ra: mX = 26x + 42y =3,24 n CO = 2x + 3y = 0,21 Gii ph trnh i s: y = 0,17, x = - 0,15 loi ............................... + Khi A l C3H8: cng thc cu to ca A l CH3-CH2- CH3 . t PTHH t chy: 2C2H2 + 5O2 4CO2 + 2H2O
2 0

t 2C3H6 + 9O2 6CO2 + 6H2O

0,5

=>

T cc pthh v ra: mX = 26x + 44y =3,24

2

t C3H8 + 5O2 3CO2 + 4H2O

0,5

n CO = 2x + 3y = 0,21 Gii ph trnh i s: x < 0 => loi VyB l CH4 v A l . ....................................................................... b. * S iu ch CH3COOCH3 t CH4 :
+ CH4 CHCH CH2=CH2 CH3COOH ............................................... + CH4 CH3Cl CH3OH CH3COOCH3 C2H5OH

C 2H4 1,5
0,75

* S iu ch CH3COOCH(CH3)2 t CH4 :

+ CH4 CHCH CH2=CH2 C2H5OH CH3COOH +C2H5OH CH2=CH-CH=CH2 CH3CH2CH2CH3 CH3CH=CH2 (CH3)2CHOH CH3COOCH(CH3)2 .................................................................................... .........................

0,75

Ch khi chm thi: - Trong cc phng trnh ha hc nu vit sai cng thc ha hc th khng cho im, nu khng vit iu kin phn ng hoc khng cn bng phng trnh hockhng ghi trng thi cc cht phn ng hoc c ba th cho 1/2 s im ca phng trnh . - Nu lm cc cch khc m ng vn cho im ti a ng vi mi , cu ca ra. thi hc sinh gii - lp 9 THCS
Mn : Ho hc - Thi gian : 150 pht

Cu 1 : (6 im) 1- Cho bit tng s ht proton, ntron, electron trong 2 nguyn t ca nguyn t A v B l 78, trong s ht mang in nhiu hn s ht khng mang in l 26 ht. S ht mang in ca A nhiu hn s ht mang in ca B l 28 ht. Hi A, B l nguyn t g ? Cho bit in tch ht nhn ca mt s nguyn t sau : ZN = 7 ; ZNa = 11; ZCa = 20 ; ZFe = 26 ; ZCu = 29 ; ZC = 6 ; ZS = 16. 2 - Hp cht ca A v D khi ho tan trong nc cho mt dung dch c tnh kim. Hp cht ca B v D khi ho tan trong nc cho dung dch E c tnh axit yu. Hp cht A, B, D khng tan trong nc nhng tan trong dung dch E. Xc nh hp cht to bi A v D; B v D; A,B,D. Vit phng trnh phn ng. 3 - Mt s nguyn nhn ca s hnh thnh canxicacbonat trong thch nh cc hang ng vi tu thuc vo thc t v canxihirocacbonat l : a, Cht kt tinh v c th si bt kh. b, C th tan v khng bn. c, D bay hi v c th chy ra. d, Cht kt tinh v khng tan.

Cu 2 : (4 im) 1 - Tm cc cht A,B,C,D,E (hp cht ca Cu) trong s sau v vit phng trnh ho hc : A B B C C A D
Cu

2 - Ch dng thm nc hy nhn bit 4 cht rn : Na2O, Al2O3, Fe2O3, Al cha trong cc l ring bit. Vit cc phng trnh phn ng. Cu 3 : (4 im) Cho 27,4 g Ba vo 400 g dung dch CuSO4 3,2 % thu c kh A, kt ta B v dung dch C. a, Tnh th tch kh A (ktc). b, Nung kt ta B nhit cao n khi lng khng i th thu c bao nhiu gam cht rn ? c, Tnh nng phn trm ca cht tan trong dung dch C. Cu 4 : (6 im) A l hn hp gm ru Etylic v 2 axit hu c k tip nhau c dng CnH2n+1COOH v Cn+1H2n+3COOH. Cho 1/2 hn hp A tc dng ht vi Na thot ra 3,92 lt H2 (ktc). t 1/2 hn hp A chy hon ton, sn phm chy c hp th ht vo dung dch Ba(OH)2 d th c 147,75g kt ta v khi lng bnh Ba(OH)2 tng 50,1 g . a, Tm cng thc 2 axit trn . b, Tm thnh phn hn hp A.
Hng dn chm thi hc sinh gii mn Ho hc 9

Cu 1 : (6 im) 1 - (3 im)

Gi Z, N, E v Z', N', E' l s ht proton, ntron, electron ca hai nguyn t A, B. Ta c cc phng trnh : im) Z + N + E + Z' + N' + E' = 78 . hay : im) (2Z - 2Z' ) hay : im) Ly (1) + (2) sau kt hp vi (3) ta c : Z = 20 v Z' = 6 im) Vy cc nguyn t l : A l Ca ; B l C . im) 2 - (2 im) Hp cht ca A v D ho tan trong nc cho mt dung dch c tnh kim : Hp cht ca A v D l CaO . im) Hp cht ca B v D khi tan trong nc cho dung dch E c tnh axit yu : Hp cht ca B v D l CO2 . Vy hp cht l CaCO3 . PTHH : CaO + H2O Ca(OH)2 (r) (l) (dd) CO2 + H2O (k) (l) H2CO3 (dd)

(0,5

(2Z + 2Z' ) + (N + N') (2Z + 2Z' ) - (N + N') = 28 = 14

= 78 = 26

(1) (2)

(0,5 im) (0,5

(Z - Z' )

(3)

(0,5 (0,5 (0,5

(0,25

(0,25 im) (0,5 im)

Hp cht A, B, D khng tan trong nc nhng tan trong dung dch E.

(1 Ca(HCO3)2 (dd) im)

CaCO3 + CO2 + H2O (r) (k) (l) 3 - (1 im)

Do Ca(HCO3)2 c th tan c d b phn hu cho CO2. Do cu tr (1 im) Cu 2 : (4 im) 1 - (2 im) Chn (0,5 im) Vit ng cc phng trnh : im) Hc sinh lm ng theo s khc vn cho im ti a . A - Cu(OH)2 (1) Cu(OH)2 (5) CuCl2 CuCl2 (6) Cu(NO3)2 B- CuCl2 (2) Cu(NO3)2 (7) Cu(OH)2
CuCl2 + 2 H2O 2AgCl + Cu(NO3)2

li

ng

b.

ng

cht,

ph

hp

vi

yu

cu

bi. (1,5

C - Cu(NO3)2 (3)

D- CuO CuO (8) CuSO4

Cu

E - CuSO4 (4)

(1) Cu(OH)2 + 2 HCl (2) CuCl2 + 2AgNO3 (3) 2Cu(NO3)2

t0 2CuO + 4 NO2 + O2 Cu + H2O 2AgCl + Cu(NO3)2

(4) CuO + H2 (5) CuCl2 + 2AgNO3 (7) Cu(OH)2 + H2SO4

t0

(6) Cu(NO3)2 + 2 NaOH

Cu(OH)2 + 2 NaNO3 CuSO4 + 2H2O

(8) Fe + CuSO4 FeSO4 + Cu . Cc cht trong PTHH phi ghi y trng thi cht mi cho im ti a. 2 - Ly mt t mi cht rn cho vo tng ng nghim cha nc. Cht rn no tan l Na2O

Na2O + H2O 2NaOH (r) (l) (dd) * Ly mt t mi cht rn cn li cho vo tng ng nghim cha dung dch NaOH thu c trn : Cht no tan v c bt kh thot ra l Al . 2Al + 2NaOH + 2H2O 2NaAlO2 + 3H2 (r) (dd) (l) (dd) (k) Cht no ch tan l Al2O3 Al2O3 + 2NaOH 2NaAlO2 + H2O (r) (dd) (dd) Cht no khng tan l Fe2O3 . Nhn bit c mi cht 0,5 im. Cu 3 : (4 im) Cc phng trnh ghi y trng thi cht mi cho im ti a . PTHH : Ba + 2H2O Ba(OH)2 + H2 Ba(OH)2 + CuSO4 BaSO4 + Cu(OH)2 t0 BaSO4 BaSO4 t0 Cu(OH)2 CuO + H2O (1) (2) (1 im) (3) (0,5 im) (l)

nBa = nCuSO VH
im)
4

27,4 = 0,2 mol 137

= 100.160 = 0,08 mol

400.3,2

T (1) ta c:
2

= VA = 0,2 x22,4 = 4,48 lt .

(0,5

T (2) v (3) cht rn gm BaSO4 v CuO v Ba(OH)2 d nn:

nBaSO

nCu(OH)

= nCuO = 0,08 mol

m cht rn = 0,08.233 + 0,08. 80 = 25,04 (g) im) Trong dung dch C ch cn Ba(OH)2 mdd = 400 + 27,4 - 0,2 . 2 - 0,08 .233 - 0,08 .98 = 400,52 (g) C% Ba(OH)2 =
(0,2 0,08).171 .100% 5,12 % 400,52

(1

(1 im)

Cu 4: (6 im) im vit ng cc phng trnh ho hc l 1,5 im.

3,92

nH

= 22,4 = 0,175 (mol)

PT phn ng : 2C2H5OH + 2Na 2C2H5ONa + H2 2CnH2n+1 COOH +2Na 2CnH Bin lun theo tr s trung bnh . Tng s mol 3 cht trong 1/2 hn hp = 0,175.2= 0,35 (mol) (0,5 im) C2H6O + 3O2 CxH2xO2 + t0 2CO2 + 3H2O t0 (4) (5)
147,75 = 0,75 (mol) 197
2n+1

(1) (2) (3)

COONa + H2

2Cn+1H2n+3 COOH +2Na 2Cn+1H2n+3COONa + H2

3x 2 O2 xCO2 + xH2O 2

Cht kt ta l BaCO3 nBaCO3 =

PT : CO2 + Ba(OH)2 BaCO3 + H2O (6) Theo PT (6) ta c : nCO2 = nBaCO3 = 0,75 (mol)
mCO2 = 0,75 x44 = 33(g)

(0,5

im)
mH2O = m tng - mCO2 mH2O = 50,1 - 33 = 17,1 (g)

 nH2O =

17,1 = 0,95 (mol) 18

(0,5

im) T PT (4) ta thy ngay : S mol ru C2H5OH = 0,95 - 0,75 = 0,2 ( mol) im) Theo PT (4) ta thy s mol CO2 to ra l nCO2 = 2.nC2H5OH = 2.0,2 = 0,4 (mol) Suy ra : 2 a xt chy to ra 0,75 - 0,4 = 0,35 (mol CO2) im) T PT (4) ta thy nH2O = 3.nC2H5OH = 3.0,2 = 0,6 (mol) Suy ra 2 axit chy to ra : 0,95 - 0,6 = 0,35 mol H2O im) Vi s mol 2axit = 0,35 - 0,2 = 0,15 x = 0,35 : 0,15 = 2,33 (x l s mol trung bnh gia n+1 v n+2) 2 axit l CH3COOH v C2H5COOH. Theo phng trnh t chy ta c : n2 axit = 0,15mol = a + b . nCO2 sinh ra = 2a + 3 b = 0,35 . Gii ra ta c : a = 0,1; b = 0,05 . Vy hn hp c 0,2 mol CH3COOH l 12 g v 0,10 mol C2H5COOH l 7,4g ( 1im) Hc sinh lm cch khc ng vn cho im ti a. C = 12 ; H= 1 ; S = 32 ; Cu = 64 ; O = 16 ; Ba = 137. Th sinh c s dng my tnh v h thng tun hon khi lm bi. ( thi gm 2 trang, p n gm 4 trang ) Ti liu tham kho: (0,5 im) Gi s mol CH3COOH, C2H5COOH trong 1/2 A l a, b . (0,5 (0,5 (0,5

- 150 cu hi trc nghim v 350 bi tp Ho hc chn lc dng cho hc sinh THCS. - Bi dng ho hc THCS . - thi HS gii Ho hc cc tnh nm 1998 .

thi hc sinh gii

Mn thi: Ho hc Thi gian lm bi: 150 pht

bi

Cu 1 (4,5 im): Mt hn hp gm Al, Fe, Cu c chia lm 3 phn A, B, C u nhau a/ - Phn A tc dng vi dung dch NaOH d - Phn B tc dng vi dung dch HCl d - Phn C tc dng vi dung dch HNO3 c d Trnh by hin tng ho hc xy ra b/ Gn lc kt ta cc phn trn, thu c cc dng dch A, B, C - Cho dung dch HCl vo A cho n d - Cho dung dch NaOH vo B cho n d - Cho dung dch NaOH vo C cho n d Trnh by hin tng ho hc xy ra Cu 2 (3 im) a/ Gii thch v sao dng bng nhm khng dng ng dung dch kim mnh. b/ t hai cc trn a cn. Rt dung dch H2SO4 long vo hai cc, lng axt hai cc bng nhau, cn v tr thng bng. Cho mu Km vo mt cc v mu St vo cc kia. Khi lng ca hai mu nh nhau. Cn s v tr no sau khi kt thc phn ng ? Cu 3: (3 im) a/ Cho cc nguyn liu Fe3O4, KMnO4, HCl. - Hy vit cc phng trnh phn ng iu ch FeCl3 b/ Vit cc phn ng c th iu ch FeCl3 Cu 4: (4 im) Hn hp Mg, Fe c khi lng m gam c ho tan hon ton bi dung dch HCl. Dung dch thu c tc dng vi dung dch NaOH d. Kt ta sinh ra sau phn ng em nung trong khng kh n khi lng khng i gim i a gam so vi trc khi nung. a/ Xc nh % v khi lng mi kim loi theo m, a

b/ p dng vi m = 8g a = 2,8g Cu 5: (5,5 im) Ngi ta t chy mt hidrcacbon no bng O2 d ri dn sn phm chy i ln lt qua H2SO4 c ri n 350ml dung dch NaOH 2M thu c dung dch A. Khi thm BaCl2 d vo dung dch A thy tc ra 39,4gam kt ta BaCO3 cn lng H2SO4 tng thm 10,8gam. Hi hir cc bon trn l cht no ?

p n v hng dn chm thi Mn thi: ho hc Thi gian lm bi: 150 pht Cu 1: (4,5) a/ Khi cho A tc dng vi dung dch NaOH d th c bt khi H2 thot ra khi dung dch lin tc kim loi b ho tan ht l Al, cn Fe, Cu khng tan. 2Al + 2H2O NaAlO2 + H2 - Khi cho B tc dng vi dung dch HCl d cn bt kh H2 thot ra khi dung dch lin tc. Kim loi b tan ht l Fe, Al cn Cu khng tan 2Al + 6HCl 2AlCl3 + 3H2 Fe + 2HCl FeCl2 + H2 - Khi cho C tc dng vi dung dch HNO3 c d th c kh mu nu thot ra khi dung dch. Kim loi b ho tan ht l Cu, cn Al, Fe khng ho tan. Cu + 4HNO3 Cu(NO3)2 + 2NO2 + 2H2O b/ Gn lc kt ta cc phn trn th dung dch A thu c (2,25 cha NaAlO2 v NaOH d; dung dch B cha: FeCl2, AlCl3, HCl d; dung dch C cha Cu(NO3)2, HNO3 d. - Cho dung dch HCl vo dung dch A xy ra phn ng: HCl + NaOH NaCl + H2O ng thi xut hin kt ta mu trng: NaAlO2 + HCl + H2O Al(OH)3 + NaCl n mt lc no kt ta dn tan thu c dung dch trong sut khi HCl dng d. Al(OH)3 + 3HCl AlCl3 + 3H2O - Khi cho dung dch NaOH vo dung dch B xy ra phn ng NaOH + HCl NaCl + H2O ng thi kt ta trng xut hin FeCl2 + 2NaOH Fe(OH)2 + 2NaCl 0,75 ) 0,75 0,75 0,75 2,25 0,75

AlCl3 + 3NaOH Fe(OH)3 + 3NaCl n mt lc no kt ta tan dn nhng vn cn kt ta trng hi xanh khi NaOH dng d (v Fe(OH)2 c mu trng xanh) Al(OH)3 + NaOH NaAlO2 + 2H2O - Khi cho dung dch NaOH vo dung dch C xy ra phn ng NaOH + HNO3 NaNO3 + H2O ng thi kt ta xanh xut hin Cu(NO3)2 + 2NaOH Cu(OH)2 + 2NaNO3 Cu 2: (3) - Khng th dng nhm ng dung dch kim mnh, chng hn nc vi trong l do: + Trc ht lp Al2O3 b ph hu v Al2O3 l mt hp cht lng tnh Al2O3 + Ca(OH)2 Ca(AlO2)2 + H2O + Sau khi lp Al2O3 b ho tan, Al phn ng vi nc mnh 2Al + 6H2O 2Al(OH)3 + 3H2 + S ph hu Al xy ra lin tc bi v Al(OH)3sinh ra n u lp tc b ho tan ngay bi Ca(OH)2, do Al(OH)3 l hp cht lng tnh 2Al(OH)3 + Ca(OH)2 Ca(AlO2)2 + 4H2O Phn ng ch dng li khi no ht nhm hoc ht nc vi trong b/ * Trng hp axt hoc d Cn s nghing v cc cho km vo nu a xt hoc d Phng trnh phn ng ho hc l: Zn + H2SO4 ZnSO4 + H2 65g ag 2g 2a g 65 1 0,4 1 0,3 0,3 0,4

0,75

Fe + H2SO4 FeSO4 + H2

56g ag V

2g 2a g 56 2a 2a g > g cho nn cn s nghing v cc cho 56 65

0,4

ming st. * Nu a xt thiu th lng H2 c tnh theo lng axit. Do lng axit bng nhau nn lng H2 thot ra hai cc bng nhau. Cn vn v tr cn bng sau khi kt thc phn ng 0,3 1 Cu 3: (3) a/ Trc ht iu ch Cl2 16HCl + 2KMnO4 - Dng HCl ho tan Fe3O4 Fe3O4 + 8HCl FeCl2 + 2FeCl3 + 4H2O - Cho kh Cl2 thu c trn sc vo dung dch cha FeCl2, FeCl3 2FeCl2 + Cl2 2FeCl3 b/ Cc phn ng iu ch Cch 1: Cch 2: Cch 3: Cch 4: Cch 5: Cch 6: 2Fe + 3Cl2 0,5 2KCl + 2MnCl2 + 5Cl2 + 8H2O 0,5 0,5

t0

t0

2FeCl3 0,25

0,25

Fe2O3 + 6HCl 2FeCl3 + 3H2O Fe(OH)3 + 3HCl

FeCl3 + 3H2O

0,25 0,25 0,25 0,25 0,3

Fe2(SO4)3 + 3BaCl2 3BaSO4 + 2FeCl3 Fe(NO3)3 + 3HCl FeCl3 + 3HNO3 2FeCl2 + Cl2 2FeCl3

Cu 4: (4) Do lng HCl d nn Mg, Fe c ho tan ht Mg + 2HCl MgCl2 + H2 (1) Fe + 2HCl FeCl2 + H2 (2)

Dung dch thu c trn khi tc dng vi dung dch NaOH d th ton b 0,3 cc kation kim loi c kt ta di dng hyrxit. FeCl2 + 2NaOH 2NaCl + Fe(OH)2 MgCl2 + 2NaOH NaCl + Mg(OH)2 (4) Khi em nung kt ta trong khng kh n khi lng khng i xy ra cc phn ng 0,4 Mg(OH)2 MgO + H2O (5) (6) 4Fe(OH)2 + O2 2Fe2O3 + 4H2O thit ta c phng trnh 24x + 56y = m (*) Mt khc theo nh lut bo ton suy ra s phn t gam Mg(OH)2 l x; s phn t gam Fe(OH)2 l y. 0,5 Khi nung khi lng cc cht rn gim mt lng 18x + 18y y .32= a (**) 4 0,5 (3)

Gi s trong hn hp ban u c x mol Mg v y mol Fe, theo gi

Gii h phng trnh gm (*) v (**) c x.6 + 56 y.6 = 6m 24 x.8+ 10 y.8 = 8a 18 256y = 6m - 8a y = Vy khi lng Fe = 6m 8a 256 0,25 0,5 0,25

6m 8a .56 256

Kt qu % v khi lng ca Fe (6m 8a)56 .100 % = % 256 .m % v khi lng ca Mg 100% - % = % 0,25 0,25

b/ p dng bng s: %Fe : % = (6.8 8.2,8).56 .100 % = 70 % 256 .8 0,25 0,25 1,5

% Mg : % = 100% - 70% = 30% Cu 5: (5,5) - Sn phm chy khi t Hir cac bon bng kh O2 l CO2; H2O; O2 d. Khi dn sn phm chy i qua H2SO4 c th ton b H2O b gi li (do H2SO4 c ht nc mnh), do vy lng H2SO4 tng 10,8gam, chnh bng lng nc to thnh ( mH O = 10,8gam), kh cn li l CO2, O2 d
2

tip tc qua dung dch NaOH, xy ra phn ng gia CO2 v NaOH CO2 + 2NaOH Na2CO3 + H2O CO2 + NaOH NAHCO3 (2) 0,25 2 0,5 (1) 0,5

Tu thuc vo s mol ca CO2 v NaOH m c th to ra mui trung ho Na2CO3 ln mui axit NaHCO3) * Trng hp 1: NaOH d, sn phm ca phn ng gia CO2 v NaOH ch

l mui trung ho. Dung dch A gm Na2CO3 + H2O Khi phn ng vi dung dch BaCl2, ton b mui gc cacbonat b chuyn thnh kt ta BaCO3. Na2CO3 + BaCl2 BaCO3 + 2NaCl Ta c: V:
2

(3)

0,5

nBaCO = nCO
3

nBaCO =
3

39 ,4 = 0,2(mol ) 197 0,5

nCO = 0,2 (mol) 10 ,8 = 0,6(mol ) Trong khi: nH O = 18

2

Suy ra: T s

nCO 0,2 1 = = khng tn ti hir cc bon no no nh vy v nH O 0,6 3

2 2

t s nh nht l 0,5 * Trng hp 2:

1 CH4 chy 2 2,0

- Nh vy NaOH khng d. Ngha l NaOH phn ng ht. ng thi to ra c mui axt v mui trung ho (c phn ng (1) v (2) u xy ra, lng CO2 phn ng hon ton, lng CO2 b gi li hon ton) 0,25 - Theo phng trnh (1)
2 3

n NaOH ban u = 0,35 . 2 = 0.7 (mol)

3

nNaOH = 2. nNa CO = 2 . nBaCO = 2 . 0,2 = 0,4 (mol) nCO (1) = 0,2 (mol)
2

(*)

0,25

Lng NaOH cn li: 0,7 - 0,4 = 0,3 (mol). Tham gia phn ng (2) 0,25 - Theo phng trnh (2): nCO = n NaOH = 0,3 (mol) (**)
2

0,25 - Vy t (*), (**) lng kh CO2 to thnh trong phn ng chy l nCO = 0,2 + 0,3 = 0,5 (mol)
2

0,25

Gi CTHH hir cc bon no l CnH2n+2 (n 1) Phn ng chy; CnH2n+2 + Do ; 3n + 1 O2 n CO2 + (n + 1)H2O 2 0,25 0,25

n 0,5 = n= 5 n + 1 0,6

Vy hir cc bon cn tm c cng thc ho hc C5H12 0,25 Ch : Nu hc sinh lm cch khc ng vn cho im ti a

S GD&T Thanh Ho chnh thc nm 2008

S bo danh: ................

k thi chn hsg cp tnh Ngy thi: 28 thng 3 Mn thi: Ho Hc Lp: 9 THCS Thi gian lm bi: 150 pht (khng k
Nguyn liu

thi gian giao ) Cu 1. (5,0 im)

Sn phm

1.
E, F, G

A, B, C

Gang c sn xut t qung st trong l cao theo s : a. Em hy cho bit tn, cng thc ho hc(nu c) ca cc cht: A, B, C, D, E, F, H, G, I.
H

b. Nu qung st em dng l manhetit th phn ng xy ra trong l cao nh th no?

I

2. a. Khi ta thi mnh mt lung khng kh vo bp ci ang chy, c th xy ra hin tng g? b. V sao cc vin than t ong c ch to nhiu l xuyn dc, cn khi nhm bp than t ong ngi ta thng p thm mt ng khi cao ln ming l? 3. C cc cht: KMnO4, MnO2, dung dch HCl c. Nu khi lng cc cht KMnO4 v MnO2 bng nhau, em s chn cht no c th iu ch c nhiu kh clo hn? Nu s mol ca KMnO4 v MnO2 bng nhau, em s chn cht no c th iu ch c nhiu kh clo hn? Nu mun iu ch mt th tch kh clo nht nh, em s chn KMnO 4 hay MnO2 tit kim c axit clohiric? Hy bin ln trn c s ca nhng phn ng ho hc i vi mi s la chn trn. Cu 2. (6,0 im) 1. A, B, D, F, G, H, I l cc cht hu c tho mn cc s phn ng sau: t , xt , xt A B+C ; B + C t ; D + E t ; F + O2 D F t , xt G + E , xt t F + G t ; H + NaOH I+F ; G+L I + H + E C Xc nh A, B, D, F, G, H, I, L. Vit phng trnh ho hc biu din s phn ng trn. 2. Vit cng thc cu to cc ng phn ca A ng vi cng thc phn t C5H12. Xc nh cng thc cu to ng ca A bit rng khi A
0 0 0 0 0 0

tc dng vi clo(askt) theo t l 1 : 1 v s mol to ra mt sn phm duy nht. 3. T nguyn liu chnh l vi, than , cc cht v c v iu kin cn thit. Vit s phn ng iu ch cc ru CH3OH; C2H5OH; CH3 CH2 CH2OH v cc axit tng ng. Cu 3. (5,0 im) Cho hn hp gm MgO, Al2O3 v mt oxit ca kim loi ho tr II km hot ng. Ly 16,2 gam A cho vo ng s nung nng ri cho mt lung kh H2 i qua cho n phn ng hon ton. Lng hi nc thot ra c hp th bng 15,3 gam dung dch H2SO4 90%, thu c dung dch H2SO4 85%. Cht rn cn li trong ng em ho tan trong HCl vi lng va , thu c dung dch B v 3,2 gam cht rn khng tan. Cho dung dch B tc dng vi 0,82 lt dung dch NaOH 1M, lc ly kt ta, sy kh v nung nng n khi lng khng i, c 6,08 gam cht rn. Xc nh tn kim loi ho tr II v thnh phn % khi lng ca A. Cu 4. (4,0 im) Cho 2 hn hp kh A1 v A2 iu kin thng, mi hn hp gm H2 v mt hircacbon mch h bt k. Khi t chy 6 gam hn hp A1 to ra 17,6 gam CO2, mt khc 6 gam A1 lm mt mu c 32 gam brm trong dung dch. Hn hp A2(cha H2 d) C t khi hi i vi H2 l 3. Cho A2 qua ng ng Ni nung nng(gi thit hiu sut 100%), to ra hn hp B c t khi so vi H2 l 4,5. 1. Tnh thnh phn % th tch cc kh trong A1 v A2. 2. Tm cng thc phn t ca hai hircacbon trong A1 v A2. Cho bit: H = 1, C = 12, O = 16, Mg = 24, Al = 27, S = 32, Fe = 56, Cu = 64, Zn = 65.

S GD&T Thanh Ho chnh thc

S bo danh ........................... .....

k thi chn hsg cp Tnh Nm hc: 2008 - 2009 Mn thi: Ho Hc THCS Ngy thi: 28 03 2009 Thi gian lm bi: 150 pht (khng k thi gian giao )

Cu 1: (7,0 im) 1/ Vit 17 PTHH (c bn cht khc nhau) biu din cc phn ng xy ra iu ch mui. 2/ Vit cc PTHH theo s Kh D sau: + Na + O , du + ddHCl du A B C
2

Dd H Kt ta F

Bit A gm Mg v Cu. 3/ Trong thnh phn kh thi ca mt nh my c cha cc kh CO2; SO2 v Cl2. Em hy xut mt phng php loi b cc kh ny trc khi thi ra mi trng. 4/ C 6 l mt nhn c cha cc kh: H2; CO2; CH4 v H2; CO2 v C2H4; H2 v C2H4; CH4 v CO2. M t qu trnh nhn ra ho cht trong tng l bng phng php ho hc. Cu 2: (5,0 im) 1/ Bng phng php ho hc hy tch tng cht ring bit ra khi hn hp gm ru etylic v axit axetic. 2/ T ru etylic vit cc PTP iu ch poly etilen, axit axetic v cao su buna. 3/ Mt hp cht hu c A (cha cacbon, hiro, oxi) c phn t khi bng 60 .v.C. a/ Xc nh CTPT ca A. b/ Vit CTCT ca A, bit rng A c kh nng tc dng vi Na kim loi v dung dch NaOH. Vit PTHH biu din cc phn ng xy ra. Cu 3: (4,0 im) t chy hon ton hn hp cha 2 hiro cacbon A, B. Sn phm thu c ln lt cho qua bnh (1) ng H2SO4 c, khi lng bnh tng 3,24 gam, bnh (2) ng dung dch Ca(OH)2 d, to thnh 16 gam cht rn. Xc nh CTPT ca cc hiro cacbon. Bit rng s mol ca A, B c trong hn hp bng nhau v s mol CO2 c to ra t phn ng chy ca A v B bng nhau. Cu 4: (4,0 im) Cho 1,36 gam hn hp gm Fe v Mg vo 400ml dung dch CuSO 4 nng a (mol/lit). Sau khi phn ng xong thu c 1,84 gam cht rn B v dung dch C. Them NaOH d vo dung dch C c kt ta. Sy, nung kt ta trong khng kh n khi lng khng i, cn c 1,2 gam cht rn D. a/ Vit PTHH biu din cc phn ng c th xy ra. b/ Tnh thnh phn % theo khi lng ca 2 kim loi trong A. Tnh a.
(Cho: H = 1, C = 12, O = 16, Na = 23, Mg = 24, S = 32, Ca = 40, Fe = 56, Cu = 64) .......................................................Ht............................................................... ...

S GD&T Ngh An chnh thc

k thi chn hsg cp Tnh Nm hc: 2008 - 2009

S bo danh ........................... .....

Mn thi: Ho Hc THCS Ngy thi: 20 03 2009 Thi gian lm bi: 150 pht (khng k thi gian giao )

Cu 1: (4,5 im) 1/ T KMnO4 ; NH4HCO3 ; Fe ; MnO2 ; NaHSO3 ; BaS v cc dung dch Ba(OH)2 ; HCl c c th iu ch c nhng kh g? Vit phng trnh ho hc. Khi iu ch cc kh trn thng c ln hi nc, lm kh tt c cc kh ch bng mt s ho cht th chn cht no trong s cc cht sau y: CaO ; CaCl 2 khan ; H2SO4 c ; P2O5 ; NaOH rn. 2/ Vit cc phng trnh ho hc ca cc phn ng xy ra trong cc th nghim sau: a/ Cho hn hp NaHCO3 v NaHSO3 vo dung dch Ba(OH)2 d. b/ Cho st d vo dung dch H2SO4 c nng c dung dch A. Cho A vo dung dch NaOH d c kt ta B. Lc kt ta B nung ngoi khng kh n khi lng khng i. Cu 2: (4,0 im) 1/ Da vo c im cu to phn t. Vit cng thc cu to c th c ca cc cht c cng thc phn t C4H6. 2/ Cho hn hp X gm Ca v CaC2 vo nc d c hn hp kh Y. Cho hn hp kh Y qua bnh cha Ni nung nng c hn hp kh Z gm 4 cht. Cho hn hp kh Z qua bnh ng dung dch Br2 d, ri t chy hon ton hn hp kh thot ra khi bnh. Vit cc phng trnh ho hc xy ra trong cc th nghim trn. Cu 3: (4,0 im) Chia 26,88 gam MX2 thnh 2 phn bng nhau. - Cho phn 1 vo 500ml dung dch NaOH d thu c 5,88 gam M(OH)2 kt ta v dung dch D. - Cho phn 2 vo 360ml dung dch AgNO 3 1M c dung dch B v 22,56 gam AgX kt ta. Cho thanh Al vo dung dch B thu c dung dch E, khi lng thanh Al sau khi ly ra cn li tng ln m gam so vi ban u (ton b kim loi thot ra bm vo thanh Al). Cho dung dch D vo dung dch E c 6,24 gam kt ta. a/ Xc nh MX2 v gi tr m? b/ Tnh nng mol ca dung dch NaOH dng. (Bit cc phn ng xy ra hon ton) Cu 4: (4,5 im) Chia 17 gam hn hp rn X gm: MxOy ; CuO v Al2O3 thnh 2 phn bng nhau. - Ho tan phn 1 vo dung dch NaOH d, cn li 7,48 gam hn hp rn A. - Dn 4,928 lt kh CO (ktc) vo phn 2 nung nng c hn hp rn B v hn hp kh C, c t khi i vi hiro l 18. Ho tan B vo dung dch HCl d cn li 3,2 gam Cu. a/ Vit cc phng trnh ho hc xy ra. b/ Tnh % v khi lng ca mi nguyn t c trong hn hp X. Cc phn ng xy ra hon ton. c/ ho tan hon ton A phi dng ht 12,5 gam dung dch H2SO4 98%, nng. Xc nh kim loi M v cng thc ca MxOy. Bit: MxOy + H2SO4 e, nng ----> M2(SO4)3 + SO2 + H2O. MxOy b kh v khng tan trong dung dch NaOH. Cu 5: (3,0 im) t chy hon ton V lit hn hp kh gm a gam hiro cacbon A v b gam hiro cacbon B (mch h). Ch thu c 35,2 gam CO2 v 16 gam H2O. Nu thm vo V lt

X mt lng a/2 gam A c hn hp kh Y, t chy hon ton Y ch thu c 48,4 gam CO2 v 23,4 gam H2O. Xc nh cng thc phn t A, B. Cho: H = 1; C = 12; O = 16; Mg = 24; Al = 27; S = 32; Cl = 35,5; Ca = 40; Fe = 56; Cu = 64; Br = 80; Ag = 108. ...........................................................Ht.............................................................

S GD&T tha thin hu chnh thc 2009

S bo danh ........................... .....

k thi chn hsg cp Tnh Nm hc: 2008 -

Mn thi: Ho Hc THCS Ngy thi: 20 03 2009 Thi gian lm bi: 150 pht (khng k thi gian giao )

Cu 1: (2,0 im) 1. Trong phng th nghim ta thng iu ch kh CO2 t CaCO3 v dung dch HCl (dng bnh kp), do kh CO2 thu c cn b ln mt t kh hiro clorua v hi nc. Hy trnh by phng php ho hc thu c kh CO2 tinh khit. Vit cc phng trnh phn ng ho hc xy ra. 2. Bng phng php no c th phn bit c 3 cht bt: BaCO3 ; MgCO3 ; Na2CO3. Vit cc phng trnh phn ng ho hc xy ra. Cu 2: (2,0 im) 1. Polime X cha 38,4% cacbon; 56,8% clo v cn li l hiro v khi lng. Xc nh cng thc phn t, vit cng thc cu to ca X v gi tn, cho bit trong thc t X dng lm g? 2. T metan v cc cht v c cn thit khc. Hy vit cc phng trnh phn ng ho hc (ghi r iu kin) iu ch X ni trn. Cu 3: (2,5 im) 1. Ho tan 7 gam mt kim loi R trong 200 gam dung dch HCl va , thu c 206,75 gam dung dch A. Xc nh kim loi R. 2. Mt hn hp X gm 2 hirocacbon mch h C xH2x v CyH2y. Bit 9,1 gam X lm mt mu va ht 40 gam brom trong dung dch. Xc nh cng thc phn t ca 2 hirocacbon . Bit trong X thnh phn th tch ca cht c phn t khi nh nm trong khong t 65% n 75%. Cu 4: (1,5 im) Ho tan ht hn hp X gm oxit ca mt kim loi c ho tr II v mui cacbonat ca kim loi bng H2SO4 long va , sau phn ng thu c sn phm gm kh Y v dung dch Z. Bit lng kh Y bng 44% lng X. em c cn dung dch Z thu c mt lng mui khan bng 168% lng X. Hi kim loi ho tr II ni trn l kim loi g? Tnh thnh phn phn trm ca mi cht trong hn hp X. Cu 5: (2,0 im) t chy hon ton mt lng cht hu c A cn 6,72 lt oxi (ktc). Cho ton b sn phm to thnh (ch gm CO2, H2O) vo mt lng nc vi trong, sau khi kt thc phn ng thu c 10 gam kt ta v 200 ml dung dch mui c nng 0,5M, khi lng dung dch mui ny nng hn khi lng nc vi trong em dng l 8,6 gam. Hy xc nh cng thc phn t hp cht hu c A. Bit 40 < MA < 74.

Cho: H = 1; C = 12; O = 16; S = 32; Cl = 35,5; Ca = 40; Br = 80. ---------------------------------Ht---------------------------------- Th sinh c s dng bng h thng tun hon cc nguyn t ho hc, bng tnh tan. - Gim th coi thi khng gii thch g thm. H v tn th sinh: ..............................................................................................S bo danh: ......................

Cu 1 : (1,5 ) 1, iu ch v thu kh ccbonc t phn ng gia CaCO3 vi dung dch a xt H2SO4 long, iu ch v thu kh hyr t phn ng gia km vi dung dch Axt HCl. Dng c no di y c th iu ch v thu c tng kh trn: ---------------------------------------------------------------------------------------------------------(b) (a ) (c )

thi hs gii khi 9 - THCS mn ho - thi gian 150 phT

(d ) 2, Khi cho lung kh Hyr (c d) i qua ng nghim cha Al2O3 , FeO , CuO , MgO nung nng n phn ng xy ra hon ton. Cht rn cn li trong ng nghim gm: A. Al, Fe , Cu , Mg B. Al2O3 , Fe , Cu , MgO . C. Al2O3 , Fe , Cu , Mg D. Al , Fe , Cu , MgO

Hy chn phng n ng . Cu 2 : (4 ) 1, Trn bao b 1 loi phn bn NPK c ghi k hiu: 20 : 10 : 10 - K hiu ny c ngha g ? - Hy tnh t l hm lng cc nguyn t N,P,K trong loi phn bn trn . 2 , Cho cc kh sau: O2 , H2S , NH3 , CO2 , H2 . Trong phng th nghim , khi iu ch cc kh trnT mun thu li cc kh vo l sch v kh , phi t l nh th no ? V sao ? Hy v hnh minh ho . 3, Vit cc phng trnh ho hc khc nhau thc hin phn ng theo s sau : FeCl2 + ? NaCl + ? . Cu 3 : (6) Ho tan 19,5 gam FeCl3 v 27,36 gam Al2 (SO4 )3 vo 200gam dung dch H2SO4 9,8 % c dung dch A , sau ho tan tip 77,6 gam NaOH nguyn cht vo dung dch A thy xut hin kt ta B v c dung dch C . Lc ly kt ta B . a / Nung B n khi lng khng i hy tnh khi lng cht rn thu c . b / Thm nc vo dung dch C c dung dch D c khi lng l 400 gam . Tnh khi lng nc cn thm vo v nng phn trm ca cc cht tan trong dung dch D . 1 c / Cn thm bao nhiu ml dung dch HCl 2M vo dung dch D c kt ta ln nht Cu 4 : ( 8,5 ) 1, Vit cc phng trnh ho hc hon thnh s phn ng sau : C6H12 CaCO3 CaO CaC2 C2H2 C6H6 C6H5Br C6H6Cl6 C6H5NO2 2, t chy 0,282 gam hp cht hu c X v cho cc cht sinh ra i qua cc bnh ng CaCl2 v KOH thy bnh CaCl2 tng thm 0,194 gam cn bnh KOH tng 0,8 gam. Mt khc t chy 0,186 gam cht sinh ra 22,4 ml kh nit ( o iu kin tiu chun ). Hp cht hu c X c cng thc phn t l cng thc no sau y: (Bit phn t hp cht hu c c 1 nguyn t ni t) A. C6H5N B . C6H7N C, C2H5N D, Tt c u sai. Gii thch cho s la chn.

3, KCl c iu ch t qung Sin vi nit l hn hp gm ch yu c KCl v NaCl . Hy nu phng php tch ring KCl s 1: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao ) Cu 1: (5,5 im) 1. Cho nhng cht sau: Na2O, Na, NaOH, Na2CO3, AgCl, NaCl. a. Hy sp xp cc cht trn thnh hai dy bin ha? b. Vit cc PTHH ca cc phn ng trong mi dy bin ha? 2. Nu hin tng v vit PTHH biu din cc phn ng trong cc trng hp sau: a. Cho kim loi Bari vo tng dung dch: NaHCO3, NH4Cl, Al(NO3)3. b. Cho kim loi ng vo dung dch H2SO4 96% v un nng. 3. Vit 4 PTHH th hin 4 cch khc nhau iu ch kh clo. 4. Cho hn hp bt gm Al; Fe; Cu. Trnh by phng php tch tng kim loi ra khi hn hp trn? 5. Vit cng thc cu to c th c ca cc cht ng vi cng thc phn t sau: C3H8O; C4H8; C3H6O2 Cu 2: (2,5 im) Chn 2 cht v c tho mn cht R trong s sau: A B C R R R R X Y Z Vit cc PTHH minh ho: Cu 3: (2,0 im) A l thnh phn chnh ca kh bn ao, E l ru Etylic, G v H l cc polime. Xc nh cng thc cu to ca A, B, C, D, E, F, G, H v hon thnh cc phng trnh ho hc th hin theo s bin ho sau (ghi r cc iu kin nu c). C +Y F (TH:t0,p,xt) G 0 0 + X, (t ,xt) (xt) (t ,xt) , H SO dd C , LLN A 1500 E t B CH3COOC2H5 0 +Y, (t ,xt) +X (t0,xt) D ( t0,xt ) C (TH:t0,p,xt) H Cu 4: (5,0 im) Ho tan 7,8 gam hn hp gm 2 kim loi: Mg v Al vo bnh ng dung dch HCl va , sau phn ng ny khi lng bnh tng thm 7 gam. a/ Tnh thnh phn % theo khi lng mi kim loi trong hn hp. b/ Cho 7,8 gam hn hp kim loi trn vo 400 ml dung dch CuSO 4 1M, sau phn ng thu c cht rn A. Tnh khi lng cht rn A v nng
0 0 2 4

mol/lit ca cc dung dch sau phn ng (coi nh th tch dung dch thay i khng ng k). Cu 5: (5,0 im) Hn hp A gm 2 axit cacboxylic no, n chc c khi lng phn t hn km nhau 28 vC. Ly m gam hn hp A cho phn ng vi Na d, thu c 3,36 lit kh H2 (ktc). Mt khc t chy hon ton m gam hn hp A, dn ton b sn phm qua bnh 1 cha P2O5, sau qua bnh 2 cha 470,25 gam dung dch Ba(OH)2 20%. Sau phn ng khi lng bnh 1 (cha P2O5) tng 14,4 gam, bnh 2 c dung dch B v khng c kh i ra khi bnh 2. a/ Tnh m gam? b/ Xc nh cng thc cu to ca mi axit. c/ Tnh s gam mi axit trong hn hp ban u. d/ Tnh nng % ca cht tan trong dung dch B. s 2:
Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian

giao ) Cu I: (7,0 im) 1/ Nu hin tng c th xy ra v vit cc PTHH biu din cc phn ng: a. Sc kh CO2 t t vo dung dch nc vi. b. MnO2 + 4HCl c, nng. c. K + dd FeCl3 d. dd Ca(OH) 2 + dd NaHCO3 2/ Ch dng Ba(OH)2 c th phn bit 6 dung dch sau y khng? Vit PTHH minh ho. NH4Cl, (NH4)2SO4, Na2SO4, AlCl3 , FeCl2, NaCl. 3/ Xc nh cc cht A, B, C, D, E, F, M v hon thnh cc phng trnh ho hc theo s sau: (Bit M l kim loi) NaOH A + C +HCl(d d) + F, kk, t0
( dd )

H ,t D + M + CO ,t M.
2 0 0

+ Fe,t0

+ Cl2 ,t0

t E D
0

+ Cl2,t0

+ NaOH(dd)

B 4/ Hon thnh s bin ho sau (ghi r iu kin nu c) ( 3) ( 4) B C Cao su buna

(2)

CaC2 ( 1 ) A chnh ca kh bn ao)

(5)

Bit G (thnh phn

( 6) (7) (8 ) (9) D Ru etylic E F G

5/ C 4 l mt nhn cha ring bit cc kh CO2, CH4, C2H4 v C2H2. Bng phng php ho hc hy nhn bit cc nm trong mi l. Vit phng trnh ho hc minh ho (nu c). Cu II: (3,0 im) Cho 3,16 gam hn hp A gm Fe v Mg vo 250 ml dung dch Cu(NO3)2 khuy u hn hp cho n khi phn ng kt thc thu c dung dch B v 3,84 gam cht rn D. Thm vo dung dch B mt lng NaOH d ri lc kt ta em nung nhit cao n khi lng khng i c 1,4 gam rn E gm 2 oxit. a/ Tnh % theo khi lng mi kim loi trong hn hp A. b/ Tnh nng mol/lit ca dung dch Cu(NO3)2. Cu III: (5,0 im) Hn hp A c khi lng 8,14 gam gm CuO, Al2O3 v mt oxit ca st. Cho H2 d qua A nung nng, sau khi phn ng xong thu c 1,44 gam H2O. Ho tan hon ton A cn dng 170 ml dung dch H2SO4 long 1M, c dung dch B. Cho B tc dng vi dung dch NaOH d, lc ly kt ta em nung trong khng kh n khi lng khng i, c 5,2 gam cht rn. Xc nh cng thc ca oxit st v khi lng ca tng oxit trong A. Cu IV: (5,0 im) Hn hp X gm mt axit no, n chc, mch h A v mt ru no, n chc, mch h B c phn t khi bng nhau. Chia m gam hn hp X thnh 2 phn bng nhau. t chy ht phn 1 ri cho ton b sn phm chy hp th hon ton vo 110 ml dung dch Ba(OH)2 1M thu c 19,7 gam kt ta. Cho phn 2 tc dng vi Na thu c 420 ml kh H2 (ktc). a/ Vit cc phng trnh phn ng xy ra. b/ Tm CTPT ca A, B. Vit cc ng phn ca A, B. c/ Tnh m.

s 3: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I: (8,0 im) 1/ Vit PTHH biu din phn ng khi: a/ Cho Na vo dung dch Al2(SO4)3 b/ Cho K vo dung dch FeSO4 c/ Ho tan Fe3O4 vo dung dch H2SO4 long. d/ Nung nng Al vi Fe2O3 to ra hn hp Al2O3 v FexOy. 2/ Bng phng php ho hc hy nhn bit 4 kim loi di dng bt: Mg, Al, Fe, Ag, ng trong 4 l mt nhn. Vit PTHH minh ho. 3/ Cht rn A mu xanh lam tan c trong nc to thnh dung dch, khi cho thm NaOH vo dung dch to ra kt ta B mu xanh lam m. Khi nung nng cht B b ho en. Nu sau tip tc nung nng sn phm trong dng kh H2 th to ra cht rn C mu . Cht rn C tc dng vi mt axit v c c li to ra cht A ban u. Hy cho bit cht A l cht no v vit tt c cc PTHH xy ra. 4/ A, B, D, F, G, H, I l cc cht hu c tho mn cc s phn ng sau:

, xt , xt ; D + E t ; F + O2 t F G+E t , xt t F + G ; H + NaOH I+F ; G+L I + C H + E Xc nh A, B, D, F, G, H, I, L. Vit phng trnh ho hc biu din s phn ng trn. 5/ Bng phng php ho hc hy nu cch phn bit 5 cht kh sau: CO, NO, C2H2, SO2 v CO2. Cu II: (3,0 im) C V1 lit dung dch a xit HCl cha 9,125 gam cht tan (dd A) v c V 2 lit dung dch axit HCl cha 5,475 gam cht tan (dd B). Trn V1 lit dd A vo V2 lit dd B thu c dd C c V = 2 lit. a/ Tnh nng mol/lit ca dung dch C. b/ Tnh nng mol/lit ca dung dch A v B. Bit CM (A) CM (B) = 0,4 M Cu III: (4,0 im) Cho 14,8 gam hn hp gm kim loi ho tr II, oxit v mui sunfat ca kim loi , tan vo dung dch H2SO4 long d th thu c dung dch A v thot ra 4,48 lt kh ( ktc). Cho dung dch NaOH d vo dung dch A, c kt ta B. Nung kt ta B nhit cao n khi lng khng i c 14 gam cht rn. Mt khc cho 14,8 gam hn hp trn vo 0,2 lit dung dch CuSO4 2M th sau khi ng kt thc, ta tch b cht rn ri em chng kh dung dch th cn li 62 gam. a/ Tnh thnh phn % theo khi lng ca cc cht c trong hn hp ban u. b/ Xc nh kim loi . Cu 5: (5,0 im) hirat ho (loi H2O) hon ton 26,5 gam hn hp X gm 2 ru no, n chc A, B c 17,5 gam hn hp 2 anken. Bit anken c khi lng phn t ln c t khi i vi oxi nh hn 2. a/ Xc nh CTPT ca A, B v thnh phn % ca mi cht trong hn hp X. b/ Xc nh cc cht A, B, C, D, E, F v vit cc PTHH minh ho. Na CO Cl , AS , xt Ca ( OH ) NaOH NaOH , xtCaO ,t C2H6 + A + B O C + D + E + F
0 0 0 0 0 0 2 2 2 2 3 0

t A B+C

, xt B + C t D

(Cho: H = 1, C = 12, O = 16, Mg = 24, S = 32, Cl = 35,5, Na = 23, Cu = 64, Fe = 56).

s 4: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao ) Cu I: (8,0 im) 1/ C cc phn ng sau:

 Kh A MnO2 + HCl c Kh B Na2SO3 + H2SO4 (l) FeS + HCl Kh C NH4HCO3 + NaOHd Kh D Na2CO3 + H2SO4 (l) Kh E a. Xc nh cc kh A, B, C, D, E. b. Cho A tc dng C, B tc dng vi dung dch A, B tc dung vi C, A tc dung dch NaOH iu kin thng, E tc dng dung dch NaOH. Vit cc PTHH xy ra. c. C 3 bnh kh A, B, E mt nhn. Bng phng php ho hc hy phn bit cc kh. 2/ Mt hn hp X gm cc cht: Na2O, NaHCO3, NH4Cl, BaCl2 c s mol mi cht bng nhau. Ho tan hn hp X vo nc, ri un nh thu c kh Y, dung dch Z v kt ta M. Xc nh cc cht trong Y, Z, M v vit phng trnh phn ng minh ho. 3/ T than , vi v cc cht v c cn thit khc. Hy vit cc phng trnh iu ch poli vinyl clrua, poli etilen, axit axtic, cao su buna. (ghi r cc iu kin) 4/ C cc cht ng ring bit trong cc l mt nhn gm: Ru etylic, axit axtic, benzen, dung dch NaOH, dung dch H2SO4, dung dch Ba(OH)2. Bng phng php ho hc hy phn bit cc cht ng trong mi l trn. Cu II. (3,0 im) Ho tan hn hp M gm Fe v Zn trong 500 ml dung dch HCl 0,4M thu c dung dch A v 1,792 lit H2 (ktc). C cn A thu c 10,52 gam mui khan. 1. Tnh % khi lng mi kim loi trong M. 2. Tnh th tch NaOH 0,5M cn dng trung ho axt d. Cu III.(4,0 im) Cho 4,8 gam bt magi vo 400 ml dung dch gm AgNO3 0,2M v Cu(NO3)2 0,5M. Khuy u dung dch cho n khi phn ng xy ra hon ton, thu c cht rn A, dung dch B. a/ Tnh khi lng cht rn A. b/ Tnh nng mol/lit cc cht trong dung dch B. Cu IV: (5,0 im) t chy hon ton 17,25 gam mt ru no, n chc A thu c 33 gam CO2 v 20,25 gam H2O. 1/ Xc nh cng thc phn t, cng thc cu to ca A. 2/ Hn hp X gm A v B l ng ng ca nhau. Cho 11,7 gam hn hp X tc dng vi Na d thu c 3,36 lit H2 ( ktc). Xc nh cng thc cu to ca B v tnh thnh phn % theo khi lng ca A v B trong X. 3/ t chy hon ton hn hp X ri cho ton b sn phm chy i qua bnh ng dung dch Ba(OH)2 d th thu c 118,2 gam kt ta. Tnh khi lng X em t chy.

.............................................................Ht............................................ ....................... (Cho: H = 1, C = 12, N = 14, O = 16, Mg = 24, S = 32, Cl = 35,5, Ca = 40, Cu = 64, Fe = 56, Ag = 108, Zn = 65). s 5: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao ) Cu I. (8,0 im) 1/ t chy cacbon trong oxi nhit cao c hn hp kh A. Cho A tc dng vi FeO nung nng c kh B v hn hp cht rn C. Cho B tc dng vi dung dch nc vi trong thu c kt ta K v dung dch D, un si D li thu c kt ta K. Cho C tan trong dung dch HCl, thu c kh v dung dch E. Cho E tc dng vi dung dch NaOH d c kt ta hiroxit F. Nung F trong khng kh ti khi lng khng i thu c cht rn G. Xc nh cc cht A, B, C, D, K, E, F. Vit cc PTHH xy ra. 2/ Hy dng mt ho cht phn bit cc dung dch ring bit sau: NH4Cl, NaNO3, MgCl2, FeCl2, FeCl3, AgNO3, AlCl3. Vit PTHH minh ho. 3/ Vit cc PTHH theo s bin ho sau: 1 2 3 4 5 6 Fe FeCl2 FeCl3 Fe(OH)3 Fe2O3 Fe2(SO4)3 Fe(NO3)3
7 13 14 15
8 9 10 11 12 Fe(OH)2 FeO Fe FeCl3 FeCl2 Fe(NO3)2 4/ T kh thin nhin, cc cht v c v iu kin cn thit vit cc phng trnh phn ng iu ch axtilen, ru etylic, axit axtic, poli vinyl clorua (PVC), cao su buna. Cu II. (3,0 im) Cho 18,6 gam hn hp 2 kim loi l R c ho tr II v Zn tc dng vi dung dch HCl d. Khi phn ng kt thc thu c dung dch 2 mui v 6,72 lt kh ( ktc). Bit rng trong hn hp ban u t l s mol R : Zn l 1 : 2. a/ Vit cc phng trnh phn ng xy ra. b/ Tnh khi lng mi mui thu c sau phn ng v tnh th tch dung dch HCl 1,5M ti thiu cn dng. c/ Xc nh kim loi R Cu III. (4,0 im) Cho 2,3 gam bt A gm Al, Fe, Cu tc dng hon ton vi 40 ml dung dch CuSO4 1M thu c dung dch B v hn hp D gm 2 kim loi. Cho dung dch NaOH tc dng t t vi dung dch B cho n khi thu c kt ta ln nht, nung kt ta trong khng kh n khi lng khng i thu

c 1,82 gam hn hp 2 oxit. Cho D tc dng hon ton vi dung dch AgNO3 d, thu c 12,96 gam Ag. Tnh s gam mi kim loi trong A. Cu IV: (5,0 im) Hn hp kh A gm C2H2 v H2 c khi lng 5,8 gam v c th tch l 11,2 lt ( ktc). Dn hn hp A qua ng ng Ni nung nng, thu c hn hp kh B. Cho B qua bnh ng dung dch Br2 d, thu c hn hp kh thot ra X. t chy hon ton X ri cho ton b sn phm vo bnh cha dung dch Ca(OH)2 d thu c 24 gam kt ta v khi lng bnh tng ln 17,4 gam. a/ Xc nh th tch ca tng kh trong hn hp A ( ktc). b/ Tnh tng khi lng ca bnh ng dung dch brm. c/ Tnh thnh phn % v s mol cc kh trong hn hp B. .............................................................Ht............................................ ....................... (Cho: H = 1, C = 12, N = 14, O = 16, Mg = 24, Al = 27, S = 32, Cl = 35,5, Ca = 40, Cu = 64, Fe = 56, Ag = 108, Zn = 65). s 6: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I: (8,0 im) 1/ t hn hp C v S trong Oxi d thu c hn hp A. - Cho 1/2 A li qua dung dch NaOH thu c dung dich B v kh C. - Cho kh C qua hn hp cha CuO, MgO nung nng thu c cht rn D v kh E. - Cho kh E li qua dung dch Ca(OH)2 thu c kt ta F v dung dch G thm dung dch KOH vo G li thy c kt ta F xut hin. un nng G cng thy kt ta F. Cho 1/2 kh A cn li qua xc tc, nung nng thu c kh M. Dn M qua dung dch BaCl2 thy c kt ta N. Xc nh thnh phn A, B, C, D, E, F, G, M, N v vit tt c cc phn ng xy ra. 2/ Vit cc phng trnh ho hc th hin theo s bin ho sau (ghi r iu kin).
(1 )

FeCl2
(9) ( 10 )

(2)

Fe(NO3)2

(3)

Fe(OH)2
( 11)

(4)

Fe
(5)

(8) ( 6)

Fe2O3

3/ C 5 mu kim loi Ba, Mg, Fe, Al, Ag nu ch dng dung dch H2SO4 long c th nhn bit c nhng kim loi no. Vit cc PTHH minh ho. 4/ Hon thnh cc phng trnh phn ng theo s bin ho sau (ghi r iu kin) NaOH D + E
men gim Xt : CaO, T
0

FeCl3

Fe(NO3)3

(7)

Fe(OH)3

+O2

,Clorofin CO2 ASKT A Lenmen B

c CH4 1500 F
0

+ H2 O

XT XT, T 0
H , Ni ,t C4H6 + C4H10
2 0

Crcking,T 0

Xc nh cc cht A, B, D, E, F trong mi phng trnh. 5/ Cho mt hir cacbon A, t chy hon ton 1 mol A cn 6 mol oxi. Xc nh cng thc phn t, vit cng thc cu to v gi tn A. Bit A th kh. Cu 2: (3,0 im) Cho m (gam) mt kim loi M ho tr II vo V lt dung dch CuSO 4 0,2 M ti khi phn ng hon ton tch c 38,65 gam cht rn A. - Cho 7,73 (gam) A tc dng vi dung dch HCl d thot ra 1,12 lt kh ( ktc). - Cho 23,19 (gam) A tc dng vi dung dch AgNO 3 d thu c 77,76 (gam) cht rn. Tm V, xc inh kim loi M v tnh khi lng m (gam) dng. Cu 3: (5,0 im) Hn hp bt A gm Fe v Mg c khi lng 2,72g c chia thnh 2 phn bng nhau. Phn 1: Cho vo 400ml dung dch CuSO4 a(M) ch cho phn ng xong thu c 1,84g cht rn B v dung dch C. Cho dung dch NaOH d vo dung dch C thu c kt ta. Sy nung kt ta trong khng kh n khi lng khng i cn c 1,2g cht rn D. Tnh thnh phn % theo khi lng ca mi kim loi trong hn hp A v tr s a? Phn 2: Cho tc dng vi V(ml) dung dch AgNO3 0,1M. Sau khi phn ng xong thu c cht rn E c khi lng 3,36g. Tnh thnh phn % theo khi lng cc cht trong cht rn E? Tnh V? Cu 4: (4,0 im) t chy hon ton hn hp (A) gm 2 hircacbon (X), (Y) mch h, cng dy ng ng. Hp th ton b sn phm vo 4,5 lt dung dch Ca(OH) 2 0,02M, thu c kt ta v khi lng dung dch tng 3,78 gam. Cho dung dch Ba(OH)2 d vo dung dch thu c, kt ta li tng thm, tng khi lng kt ta 2 ln l 18,85 gam. T khi hi ca hn hp (A) i vi Heli nh hn 10. Hy xc nh cng thc cu to ca (X), (Y). Bit rng s mol ca (X) bng 60% tng s mol ca (X), (Y) c trong hn hp (A). Cc phn ng xy ra hon ton.

s 7: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I (8,0 im) 1/ Hn hp A gm Fe3O4, Al, Al2O3, Fe. Cho A tan trong dung dch NaOH d, thu c cht rn B, dung dch C v kh D. Cho kh D d tc dng vi A nung nng c cht rn A1. Dung dch C cho tc dng vi dung dch H2SO4 long d c dung dch C1. Cht rn A1 tc dng vi dung dch H2SO4 c nng (va ) thu c dung dch E v kh F. Cho E tc dng vi bt Fe d c dung dch H. Vit cc PTHH xy ra. 2/ Cho hn hp gm: Al2O3, CuO, CuCl2, AlCl3. Bng phng php ho hc hy tch cc cht trn ra khi hn hp. Vit cc PTHH trong qu trnh tch cc cht.

3/ C 4 l mt nhn cha ring bit cc kh CO2, CH4, C2H4 v C2H2. Bng phng php ho hc hy nhn bit cc nm trong mi l. Vit phng trnh ho hc minh ho (nu c). 4/ Cho mt ru no X, t chy hon ton mt mol X cn 3 mol oxi. Xc nh cng thc phn t, vit cng thc cu to v gi tn X. 5/ Vit cng thc cu to cc ng phn ng vi cng thc phn t: C3H6O2, C3H8O, C3H6, C5H10 6/ Cht A c cng thc phn t C4H6. Xc nh cng thc cu to ca A, B, C, D v hon thnh phng trnh ha hc biu din cc phn ng theo s : A
+Cl2 1:1

dd NaOH

+H2 Ni,t0

H2SO4 1700C

t0,xt,p

Cao su

Cu II (5,0 im) Cho hn hp gm MgO, Al2O3 v mt oxit ca kim loi ho tr II km hot ng. Ly 16,2 gam A cho vo ng s nung nng ri cho mt lung kh H2 i qua cho n phn ng hon ton. Lng hi nc thot ra c hp th bng 15,3 gam dung dch H2SO4 90%, thu c dung dch H2SO4 85%. Cht rn cn li trong ng em ho tan trong HCl vi lng va , thu c dung dch B v 3,2 gam cht rn khng tan. Cho dung dch B tc dng vi 0,82 lt dung dch NaOH 1M, lc ly kt ta, sy kh v nung nng n khi lng khng i, c 6,08 gam cht rn. Xc nh tn kim loi ho tr II v thnh phn % khi lng ca A. Cu III. (3,0 im) a/ Cho 13,8 gam cht A l mui cacbonat ca kim loi kim vo 110 ml dung dch HCl 2M. Sau phn ng thu c dung dch B (dung dch B lm giy qu chuyn thnh mu ) v th tch kh thot ra V 1 vt qu 2016 ml.Vit PTHH xy ra, tm A v tnh th tch kh thot ra V1. b/ Ho tan 13,8 gam cht A trn vo nc, va khuy, va thm tng git dung dch HCl 1M cho ti 180 ml dung dch axit, th thu c V2 lit kh. Vit PTHH xy ra v tnh V2. (Bit th tch cc kh u o ktc) Cu III. (4,0 im) Hn hp kh X gm mt ankan v mt anken. Cho 6,72 (l) hn hp X qua bnh nc brom d thy c 16(g) brm tham gia phn ng. Bit 11,2 (l) hn hp X nng 21,66(g). a, Tm cng thc phn t ca ankan v anken. b, t chy hon ton 6,72 (l) hn hp X v cho tt c sn phm chy hp th vo dung dch NaOH (d), sau thm BaCl2 d th thu c bao nhiu (g) cht kt ta? (Bit th tch cc kh u c o ktc) c, T anken trn hy vit phng trnh phn ng iu ch glyxrin (C3H5(OH)3).
.............................................................Ht.............................................................. ..... (Cho: H = 1, C = 12, O = 16, Mg = 24, S = 32, Cl = 35,5, Cu = 64, Fe = 56, Ag = 108, Ba = 137).

 s 8: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I. (8,0 im) 1/ Hn hp A gm BaO, FeO, Al2O3. Ho tan A trong lng nc d c dd D v phn khng tan B. Sc kh CO2 d vo D, phn ng to kt ta. Cho kh CO d i qua B nung nng c cht rn E. Cho E tc dng vi dd NaOH d, thy tan mt phn v cn li cht rn G. Ho tan ht G trong lng d H2SO4 long ri cho dd thu c tc dng vi dd NaOH d, lc kt ta nung ngoi khng kh n khi lng khng i thu c cht rn Z. Gii thch th nghim trn bng cc phng trnh ho hc. 2/ Ch dng phenol phtalein hy nhn bit 5 dung dch: Na2SO4, H2SO4, NaOH, BaCl2, MgCl2. 3/ Hn hp A gm CuO, CuCl2, Al2O3, AlCl3. Bng phng php ho hc hy tch ring tng cht ra khi hn hp A m khng lm thay i khi lng ca chng. 4/ a, Xc nh cc cht t A1 n A11 v vit cc phng trnh phn ng sau: A1 + A2 A4 A3 + A3 + A5 A7 A6 + A6 + A8 + A9 A10 0 t A10 A11 + A8 0 t A11 + A4 A1 + A8 Bit A3 l mui st Clorua, nu ly 1,27 gam A3 tc dng vi dd AgNO3 d thu c 2,87 gam kt ta. b, Vit tt c cc ng phn c th c ng vi cng thc phn t: C3H6O2; C4H10O v C4H8. 5/ Cho mt ru no X, t chy hon ton mt mol X cn 3 mol oxi. Xc nh cng thc phn t, vit cng thc cu to v gi tn X. Cu II. (3,0 im) Ho tan hon ton 1,64 gam hn hp A gm Al v Fe trong 250 ml dung dch HCl 1M c dung dch B. Thm 100 gam dung dch NaOH 12% vo B, sau khi phn ng xy ra hon ton, lc ly kt ta thu c ri em nung kt ta ngoi khng kh n khi lng khng i th thu c 0,8 gam cht rn. Tnh thnh phn % theo khi lng mi kim loi trong A. Cu III. (4,0 im) Ho tan a(g) hn hp Na2CO3 v KHCO3 vo nc c 400ml dung dch A. Cho t t 100ml dung dch HCl 1,5M vo dung dch A thu c dung dch B v 1,008l kh (ktc). Cho B tc dng vi dung dch Ba(OH)2 d thu c 29,55g kt ta. a. Tnh A. b. Tnh nng mi mui trong dung dch A. c. Nu tin hnh cho t t dung dch A trn vo bnh ng 100ml dung dch HCl 1,5M. Tnh th tch kh CO2(ktc) c to ra. Cu IV. (5,0 im)

Cho 6,72 lt (ktc) hn hp kh A gm 2 hirocacbon mch h. Chia lm 2 phn bng nhau: Dn phn 1 qua dung dch Br2 d, khi lng dung dch tng a gam, lng Br2 phn ng ht 32 gam khng c kh thot ra khi dung dch. t chy phn 2 v cho sn phm chy qua bnh ng P2O5. Sau cho qua KOH rn. Sau th nghim bnh ng P2O5 tng b gam v bnh ng KOH tng 17,6 gam. a/ Tm cng thc phn t ca 2 hirocacbon. b/ Tnh % V cc kh trong A. c/ Tnh cc gi tr a, b.

s 9: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I (8,0 im) 1, Xc nh cc cht A, B, C, D, E, F, H v hon thnh s bin ha sau:
+ NaOH

C
+HCl

+E H +F
Bit rng H l thnh phn chnh ca dng np cho cc bnh cha chy(dp

phn; B l kh
+ NaOH

A B
t0

+NaOH

tt la). 2, A, B, D, F, G, H, I l cc cht hu c tho mn cc s phn ng sau: 0 0 0 t0 , xt , xt , xt A B+C ; B + C t ; D + E t ; F + O2 t D F G + E 0 t , xt t0 F + G ; H + NaOH I+F ; G+L I + C H + E Xc nh A, B, D, F, G, H, I, L. Vit phng trnh ho hc biu din s phn ng trn. 3, Vit cng thc cu to cc ng phn ca A ng vi cng thc phn t C 5H12. Xc nh cng thc cu to ng ca A bit rng khi A tc dng vi clo(askt) theo t l 1 : 1 v s mol to ra mt sn phm duy nht. 4, T nguyn liu chnh l vi, than , cc cht v c v iu kin cn thit. Vit s phn ng iu ch cc ru CH3OH; C2H5OH; CH3 CH2 CH2OH v cc axit tng ng. 5, C cc cht: KMnO4, MnO2, dung dch HCl c. Nu khi lng cc cht KMnO4 v MnO2 bng nhau, em s chn cht no c th iu ch c nhiu kh clo hn? Nu s mol ca KMnO4 v MnO2 bng nhau, em s chn cht no c th iu ch c nhiu kh clo hn? Nu mun iu ch mt th tch kh clo nht nh, em s chn KMnO4 hay MnO2 tit kim c axit clohiric? Hy bin ln trn c s ca nhng phn ng ho hc i vi mi s la chn trn.

Cu II (2,0 im) Cho m(g) CuO vo 160ml dung dch axt HCl 1M thu c dung dch A (th tch khng i). Ngi ta cho vo dd A mt inh st c d, sau khi phn ng xong ly inh st ra lm kh v cn thy khi lng khng i. 1. Gii thch v sao thy khi lng khng i. 2.Tnh gi tr m(g) v nng CM ca cht trong A. Cu III (5,0 im) Cho 9,86g hn hp gm Mg v Zn vo 1 cc cha 430ml dung dch H2SO4 1M long. Sau khi phn ng hon ton, thm tip vo cc 1,2 lit dung dch hn hp gm Ba(OH)2 0,05M v NaOH 0,7M, khuy u cho phn ng hon ton, ri lc ly kt ta v nung nng n khi lng khng i th thu c 26,08g cht rn. Tnh khi lng mi kim loi trong hn hp u. Cu IV (5,0 im) Hn hp kh A gm hiro, mt parafin v 2 olefin l ng ng lin tip. Cho 560 ml A i qua ng cha bt Ni nung nng c 448 ml hn hp kh A1 li qua bnh nc brom thy nc brom nht mu mt phn v khi lng bnh nc brom tng thm 0,343 gam. Hn hp kh A2 i ra khi bnh nc brom chim th tch 291,2 ml v c t khi i vi khng kh bng 1,313. Xc nh cng thc phn t ca cc hirocacbon v tnh thnh phn % th tch mi kh trong hn hp A. Gi thit cc phn ng xy ra hon ton, cc olefin phn ng vi tc bng nhau (ngha l t l vi thnh phn % th tch ca chng) v cc th tch kh o ktc.

.............................................................Ht............................................ .......................
Cho: H = 1, C = 12, O = 16, Mg = 24, S = 32, Cl = 35,5, Ca = 40, Cu = 64, Fe = 56, Ag = 108, Ba =137.

s 10: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I. (6,0 im) 1/ Khi cho bt nhm tc dng vi dung dch NaOH un nng thu c dung dch X1 v kh X2.Thm vo X1 mt t tinh th NH4Cl ri tip tc un nng thy to thnh kt ta X3 v c kh X4 thot ra.Xc nh X1, X2, X3, X4 .Vit phng trnh ho hc biu din cc phn ng xy ra. 2/ Xc nh cc cht A , B , C , D , E , F , G , H v hon thnh s bin ho sau C (Bit rng C l thnh phn chnh ca phn)
(2) +G +H (3)

(9) (8)

(7)

(1)

(6)

+ H2 O

+ G (4)

+H

(5)

D
3/ a, Bng phng php ho hc hy tch SO2 ra khi hn hp gm cc kh SO2 ,SO3 , O2. b, Bng phng php ho hc hy tch ring tng kim loi ra khi hn hp gm Mg, Al, Fe, Cu. 4/ C 5 cht rn: BaCl2 ,Na2SO4 ,CaCO3 ,Na2CO3 ,CaSO4.2H2O ng trong nm l ring bit. Hy t chn 02 cht dng lm thuc th nhn bit cc cht rn ng trong mi l. Cu II (4,0 im) 1/ Vit cng thc cu to cc ng phn ng vi cng thc phn t: C2H4O2, C3H8O, C5H10. 2/ Cht A c cng thc phn t C4H6. Xc nh cng thc cu to ca A, B, C, D v hon thnh phng trnh ho hc biu din cc phn ng theo s . Cl (1:1) H , Ni ,t SO , dd ,170 C Xt , P ,t A + B ddNaOH C + D H A Cao su 3/ Hn hp kh gm CO ,CO2 ,C2H4 v C2H2.Trnh by phng php dng tch tng cht kh ra khi hn hp. Cu III (5,0 im) Khi thm t t v khuy u 0,8 lit dd HCl 0,5 M vo dd cha 35g hn hp A gm 2 mui Na2CO3 v K2CO3 th c 2,24 lit kh CO2 thot ra ( ktc) v dd D. Thm dd Ca(OH)2 c d vo dd D thu c kt ta B. a/ Tnh khi lng mi mui trong hn hp A v khi lng kt ta B. b/ Thm m (g) NaHCO3 vo hn hp A c hn hp A/. Tin hnh th nghim tng t nh trn, th tch dd HCl 0,5M thm vo vn l 0,8 lit, dd thu c l dd D/. Khi thm Ca(OH)2 d vo dd D/ c kt ta B/ nng 30 g. Tnh V (lit) kh CO2 thot ra ( ktc) v m (g). Cu IV (5,0 im) C 2 dung dch axit hu c, no n chc A, B. Trn 1 lt A vi 3 lt B ta c 4 lt dung dch D. trung ho 10 ml dung dch D cn 7,5 ml dung dch NaOH v to ra 1,335 gam mui. Ngc li trn 3 lt A vi 1 lt B ta c 4 lt E. trung ho 10 ml dung dch E cn 12,5 ml dung dch NaOH trn v to ra c 2,085 gam mui. a/ Xc nh CTPT ca cc axit A, B. Bit rng s nguyn t cacbon trong mi phn t axit nh hn 5. b/ Tnh nng mol ca dung dch NaOH.
2 2 o 2 4 0 0

.............................................................Ht............................................ .......................
Cho: H = 1, C = 12, O = 16, Na = 23, K = 39, Cl = 35,5, Ca = 40.

s 11: Mn thi: Ho Hc

Thi gian lm bi: 150 pht (khng k thi gian giao ) Cu I (1,5 im) Nu hin tng xy ra khi . 1/ Nhng thanh kim loa Mg vo dd CuSO4. 2/ Nhng thanh kim loa Ag vo dd CuCl2. 3/ Nhng mt mu kim loi K vo dd CuCl2. 4/ Cho t t dd HCl cho n d vo dd hn hp gm Na2CO3 v NaHCO3. Cu II (2,0 im) Hy dng mt cht phn bit cc dd ring bit sau: NH4Cl, NaNO3, MgCl2, FeCl2, FeCl3, AgNO3, AlCl3. Cu III (3,0 im) 1/ Nu phng php lm sch kh O2 c ln kh CO2 v SO2. 2/ Trnh by phng php iu ch: FeCl2, H2SiO3, BaSO4 t hn hp BaCO3, FeO, SiO2. Cu IV (2,0 im) Nung nng Cu trong khng kh c cht rn A. Cho A tan trong dd H2SO4 c nng, d c dd B, kh C. Cho kh C tc dng vi dd KOH c dd D. Dung dch D va tc dng vi BaCl2 va tc dng vi NaOH. Pha long B cho tc dng vi NaOH d thy xut hin kt ta E. Nung E n khi lng khng i c cht rn F, cho mt dng kh hir d i qua F c cht rn mu . Xc nh A, B, C, D, E, F v vit cc PTHH xy ra. Cu V (3,0 im) Dung dch A l dd H2SO4, dung dch B l dd NaOH. Trn A v B theo t l VA:VB = 3:2 c dd X c cha A d, trung ho 1 lt dd X cn dng 40 gam dd KOH 28%. Trn A v B theo t l th tch VA:VB = 2:3 th thu c dd Y c cha B d, trung ho 1 lt dd Y cn dng 29,2 gam dd HCl 25%. Tnh nng mol/lit ca A v B. Cu VI (4,5 im) Ho tan 5,94g hn hp 2 mui clorua ca 2 kim loi A v B (A, B l 2 kim loi thuc phn nhm chnh nhm II) vo nc, c 100ml dung dch X. Ngi ta cho dung dch X tc dng va vi dung dch AgNO3 th thu c 17,22g kt ta. Lc kt ta thu c dung dch Y c th tch l 200ml. C cn dung dch Y thu c m(g) hn hp mui khan. a/ Tnh m? b/ Xc nh CTHH ca 2 mui clorua. Bit t l KLNT A so vi B l 5:3 v trong mui ban u c t l s phn t A i vi s phn t mui B l 1:3. c/ Tnh nng mol/l ca cc mui trong dung dch X. Cu VII (4,0 im) A l hn hp gm ru Etylic v 2 axit hu c k tip nhau c dng CnH2n+1COOH v Cn+1H2n+3COOH. Cho 1/2 hn hp A tc dng ht vi Na thot ra 3,92 lt H2 (ktc). t 1/2 hn hp A chy hon ton, sn phm

chy c hp th ht vo dung dch Ba(OH)2 d th c 147,75g kt ta v khi lng bnh Ba(OH)2 tng 50,1 g. a, Tm cng thc 2 axit trn. b, Tm thnh phn hn hp A. .............................................................Ht............................................ .......................
Cho: H = 1, C = 12, O = 16, Na = 23, S = 32, Cl = 35,5, K = 39, N = 14, Fe = 56, Ag = 108, Ba =137.

s 12: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I. (6,0 im) 1/ Nu hin tng xy ra v vit cc phng trnh phn ng. a/ Khi cho Na vo dung dch MgCl2, NH4Cl. b/ Cho Ba vo dung dch Na2CO3, Na2SO4. 2. a/ Ch dng thm mt ho cht, nu cch phn bit cc Oxit: K 2O, Al2O3, CaO, MgO. b/ Ch dng thm Cu v mt mui tu hy nhn bit cc ho cht b mt nhn trong cc l ng ring bit tng dung dch sau: HCl, HNO3, H2SO4, H3PO4. 3/ Tch ring tng kim loi sau y ra khi hn hp bt gm: Al, Fe, Cu. 4/ Xc nh cc cht A,B,C,D,E,F,M v hon thnh cc phng trnh ho hc theo s sau:

+HCl( d d )
H ,t D + M + CO ,t M.
2 0 0

NaOH A + C
( dd )

+ F,kk,t0
t E D
0

+ Fe,t0

+ Cl2 ,t0

+ Cl2 ,t0 B

+ NaOH( dd )

Cu II. (5,0 im) 1/ Vit cng thc cu to cc ng phn ng vi cng thc phn t: C3H6O2 ,C3H8O ,C3H6 ,C5H10 2/ Cht A c cng thc phn t C2H6. Xc nh cng thc cu to ca cc cht B,C,D,E,F v hon thnh cc phng trnh ho hc theo s phn ng sau: Na CO Cl , ASKT O , XT Ca ( OH ) NaOH NaOH , Xt:CaO ,t C2H6 + B + C + D + E + F + CH4
2 2 2 2 3 0

3/ t chy 1 lt hn hp gm 2 Hir cacbon th kh thu c 1,6 lt kh CO2 v 1,4 lt hi nc. Cc th tch o cng iu kin nhit v p sut. Xc nh 2 cht v thnh phn % v s mol ca mi cht trong hn hp. 4/ Bng phng php ho hc hy nu cch phn bit 4 cht kh sau: CH 4 ,C2H2 , SO2 v CO2. Cu III. (5,0 im) Ho tan 8,48g hn hp gm Na 2CO3 v MgO (thnh phn mi cht trong hn hp c th thay i t 0 100%) vo mt lng dung dch H2SO4 long v d 25% (so vi lng axt cn ho tan) ta thu c mt lng kh B v mt dung dch C. 1/ Nu cho ton b kh B hp th ht vo 225 ml dung dch Ba(OH)2 0,2M, ta thu c 3,94g kt ta. Hy tnh thnh phn, phn trm v khi lng cc cht trong hn hp A. 2/ Cho dung dch C phn ng vi 390 ml dung dch Ba(OH)2 0,2M, ta thu c kt ta D. a/ Tnh gi tr khi lng nh nht ca kt ta D v thnh phn % v khi lng ca hn hp A. b/ Tnh gi tr khi lng ln nht ca kt ta D v thnh phn % v khi lng ca hn hp A. Cu III. (4,0 im) trung ho 14,8 gam 2 axit hu c no, n chc cn dng 400ml dung dch NaOH nng 0,5M. a/ Tnh s mol mi axit trong hn hp, bit rng s mol ca 2 axit bng nhau. b/ Nu em c cn dung dch trung ho th thu c bao nhiu gam mui khan? c/ Xc nh CTPT ca 2 axit ni trn.

.............................................................Ht............................................ .......................
Cho: H = 1, C = 12, O = 16, Mg = 24, S = 32, Cl = 35,5, Ca = 40, Cu = 64, Fe = 56, Na = 23, Ba =137.

s 13:
Mn thi: Ho Hc Thi gian: 150 pht
Cu I (5,0 im) 1/ Nu hin tng xy ra v vit phng trnh phn ng gii thch khi cho Ca vo: a/ Dung dch NaOH b/ Dung dch MgCl2 2/ Trnh by cch tch cc cht Al2O3, Fe2O3, SiO2 ra khi hn hp bt ca chng. 3. a/ C 5 mu kim loi Ba; Mg; Fe; Al; Ag. Nu ch dng dung dch H2SO4 long c th nhn bit c nhng kim loi no? Vit cc phng trnh phn ng. b/ Hy nhn bit mi dung dch ng trong 5 l ring bit sau: HNO 3; Ca(OH)2; NaOH; HCl; NH3

4/ Xc nh B, C, D, E, M, X, Z. Gii thch v hon thnh cc phng trnh ho hc th hin theo s bin ho sau: B + HCl +X+Z M +Z + NaOH D +Y+Z t0 E pnc M.

C Cu II (5,0 im) 1/ Vit cng thc cu to cc ng phn ng vi cng thc phn t : C2H4O2; C4H10O; C4H8. 2/ A l thnh phn chnh ca kh bn ao, E l ru Etylic, G v H l cc polime. Xc nh cng thc cu to ca A, B, C, D, E, F, G, H v hon thnh cc phng trnh ho hc th hin theo s bin ho sau (ghi r cc iu kin nu c). C +Y F (TH:t0,p,xt) G 0 0 + X, (t ,xt) (xt) (t ,xt) 0 1500 C , LLN A E B 0 +Y, (t ,xt) +X (t0,xt) D (t0,xt) C (TH:t0,p,xt) H 3/ Mt cacbua hir c th cng hp vi mt hoc hai phn t clo khi to ra i clo hoc tetra clorua hir cacbon tng ng c t l khi lng gia tetra v i clorua hir cacbon l 1,568/1. Hy cho bit cng thc phn t ca cacbua hir v vit tt c cc ng phn ng vi cng thc phn t . 4/ C 4 l mt nhn cha ring bit cc kh CO 2 ,CH4 ,C2H4 v C2H2. Bng phng php ho hc hy nhn bit cc nm trong mi l. Vit phng trnh ho hc minh ho (nu c) Cu III (5,0 im) Ho tan ht 4,52g hn hp 2 mui cacbonat ca 2 kim loi A v B k tip nhau trong phn nhm chnh nhm II bng dung dch HCl 0,5M. Sau phn ng thu c dung dch C v 1,12 lt kh CO2 (o ktc). 1/ Xc nh tn v k hiu hai nguyn t kim loi trn. 2/ Tnh tng khi lng ca mui to thnh trong dung dch C. 3/ Ton b lng kh CO2 thu c trn c hp th hon ton bi 200 ml dung dch Ba(OH)2.Tnh nng mol/lt ca dung dch Ba(OH)2 : a/ Thu c 1,97g kt ta. b/ Thu c lng kt ta nh nht v ln nht. Cu IV (5,0 im) Trn m1 gam mt ru n chc v m2 gam mt axit n chc ri chia hn hp thnh 3 phn bng nhau. - Cho phn 1 tc dng ht vi Na thy thot ra 3,36 lt H2 ( ktc) - t chy hon ton phn 2 thu c 39,6 gam CO2. - un nng phn 3 vi H2SO4 c th thu c 10,2 gam este. Hiu sut phn ng este ho l 100%. t chy 5,1 gam este th thu c 11 gam CO2 v 4,5 gam H2O. a/ Xc nh cng thc phn t ca ru v axit b/ Tnh m1 v m2.

s 14: Mn thi: Ho Hc

Thi gian lm bi: 150 pht (khng k thi gian giao ) Cu I ( 6,0 im ) 1/ Gii thch hin tng v vit phng trnh phn ng minh ho khi cho. a/ T t n d dung dch NaOH vo dung dch AlCl3 b/ T t dng kh CO2 n d vo cc ng dung dch Ca(OH)2 c/ T t n d dung dch HCl vo dung dch NaAlO2 d/ T t n d dung dch AgNO3 vo ng nghim ng bt Fe 2/ C 6 l ho cht b bong mt nhn ng ring bit 6 dung dch khng mu sau y: Na2CO3, NH4Cl, MgCl2, AlCl3, FeSO4 v Fe2(SO4)3. Bng phng php ho hc ch dng mt thuc th lm th no nhn bit c l no ng dung dch g? 3/ Cho hn hp mui KCl, MgCl2, BaSO4, BaCO3. Hy nu cch tch ring tng mui ra khi hn hp. 4/ Hon thnh cc PTHH theo s bin ho sau: 1 2 3 4 5 6 Fe FeCl2 FeCl3 Fe(OH)3 Fe2O3 Fe2(SO4)3 Fe(NO3)3
7 13 14 15
8 9 10 11 12 Fe(OH)2 FeO Fe FeCl3 FeCl2 Fe(NO3)2 Cu II (4,0 im) 1/ Trnh by phng php ho hc phn bit cc cht sau y cha trong cc l mt nhn: ru etylic, axt axtic, dung dch glucz v benzen. 2/ T kh thin nhin, cc cht v c v iu kin cn thit vit cc phng trnh phn ng iu ch axtilen, ru etylic, axit axtic, poli vinyl clorua (PVC), cao su buna. 3/ Cho mt ru no X, t chy hon ton mt mol X cn 3 mol oxi. Xc nh cng thc phn t, vit cng thc cu to v gi tn X. 4/ Bng phng php ho hc hy tch ring CO2 v C2H6 ra khi hn hp kh CO2, C2H2, C2H4 v C2H6. Cu III (5,0 im) Ha tan 1,97g hn hp Zn, Mg, Fe trong 1 lng va dung dch HCl thu c 1,008l kh ktc v dung dch A. Chia A thnh 2 phn khng bng nhau. Phn 1 cho kt ta hon ton vi 1 lng va dung dch xt, cn 300ml dd NaOH 0,06M. un nng trong khng kh, lc kt ta v nung n khi lng khng i thu c 0,562g cht rn. Phn 2 cho phn ng vi NaOH d ri tin hnh ging nh phn 1 th thu c cht rn c khi lng a (g). Tnh khi lng tng kim loi trong hn hp v gi tr ca a. Cu IV (5,0 im) Mt hn hp gm 2 ankan c khi lng l 10,2 gam. t chy hon ton hn hp ankan ny cn dng 25,8 lt O2 (ktc). a/ Tm tng s mol ca 2 ankan. b/ Tm khi lng CO2 v H2O to thnh.

c/ Tm cng thc phn t ca ankan bit rng phn t khi mi ankan khng qu 60. d/ Tnh khi lng ca mi ankan trong hn hp. .............................................................Ht............................................ .......................
Cho: H = 1, C = 12, O = 16, Mg = 24, Cl = 35,5 , Zn = 65, Fe = 56, Na = 23.

s 15:
Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I (6,0 im) 1/ Cho BaO vo dung dch H 2SO4 long, sau khi phn ng xy ra hon ton thu c kt ta A v dung dch B. Cho nhm d vo dung dch B thu c kh E v dung dch D. Ly dung dch D cho tc dng vi dung dch Na2CO3 thu c kt ta F. Xc nh cc cht A, B, C, D, F. Vit cc phng trnh phn ng xy ra. 2/ Hon thnh dy bin ho sau (ghi r iu kin nu c)

FeSO4 Fe (1) Fe (5) (7)

(2)

Fe(OH)2

(3)

Fe2O3

(4)

(8) Fe 2(SO4)3

(9) (6)

(10) Fe(OH)3

Fe3O4

3/ c 4 l mt nhn ng 4 dung dch: BaCl2, FeCl3, MgCl2 v AlCl3. Bng phng php ho hc hy phn bit cc dung dch trong cc l trn v vit cc phng trnh phn ng xy ra. 4/ Trnh by phng php tch: K, Ba, Al t hn hp bt gm K2O, BaO, Al2O3 sao cho khi lng tng kim loi khng thay i. Cu II (5,0 im) 1/ C 3 hp cht hu c c cng thc phn t nh sau: CH2O2, C2H4O2, C3H6O2. Hy vit cng thc cu to c th c ng vi 3 cng thc phn t trn. 2/ Hon thnh s bin ho sau (ghi r iu kin nu c) ( 3) ( 4) B C Cao su buna
(2)

CaC2

(1)

A
(5)
( 6) (7) (8 ) (9) D Ru etylic E F G

Bit G (thnh phn chnh ca kh bn ao) 3/ Bng phng php ho hc hy phn bit cc dung dch ng trong cc l mt nhn cha ring bit cc dung dch: CH3COOH, HCOOH, C2H5OH, C6H6.

4/ Hy xc nh cng thc cu to c th c ca cc hp cht hu c ng vi cng thc tng qut: CXHYOZ khi x 2. Bit rng cc hp cht u tc dng c vi kali v khng phi l hp cht a chc. 5/ Cho mt hir cacbon A, t chy hon ton 1 mol A cn 6 mol oxi. Xc nh cng thc phn t, vit cng thc cu to v gi tn A. Bit A th kh . Cu III (5,0 im) Ho tan hon ton 3,18g hn hp gm Mg, Al, Fe bng mt lng va dung dch HCl thu c 2,24 lt kh ( ktc) v dung dch A. Chia dung dch A lm 2 phn. Phn 1: Cho tc dng vi 100 ml dung dch NaOH 0,5M th thu c lng kt ta ln nht. Lc ly kt ta em nung trong khng kh nhit cao n khi lng khng i thu c 1,255g cht rn. Phn 2: Cho tc dng vi dung dch NaOH d ri tin hnh th nghim nh phn 1 th thu c b gam cht rn. Tnh khi lng tng kim loi trong hn hp v tnh b? (gi s cc phn ng xy ra hon ton) Cu IV (4,0 im) Hn hp X gm mt axt no, n chc ,mch h A v mt ru no, n chc, mch h B c phn t khi bng nhau. Chia m gam X thnh 2 phn bng nhau. t chy ht phn 1 ri cho ton b sn phm chy hp th hon ton vo 44 ml dung dch Ba(OH)2 1M. Thu c 7,88g kt ta. Cho phn 2 tc dng ht vi Na thu dc 168 ml kh H2 ( ktc) 1/ Vit cc phng trnh phn ng xy ra. 2/ Tm cng thc phn t ca A, B. Vit cc ng phn ca A, B v gi tn. 3/ Tnh m? (Cho: H = 1; C = 12; O = 16; Mg = 24; Fe = 56; Ba = 137)

s 16: Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I (6,0 im) 1/ Nhit phn mt lng MgCO3 trong mt thi gian, c cht rn A v kh B. Cho kh B hp th hon ton vo dung dch NaOH thu c dung dch C. Dung dch C c kh nng tc dng c vi BaCl2 v KOH.Cho A tc dng vi dung dch HCl d li thu c kh B v mt lng dung dch D. C cn dung dch D c mui khan E. in phn nng chy E c kim loi M. Vit cc phng trnh phn ng xy ra trong th nghim trn v xc nh cc cht A, B, C, D, E, M. 2/ a, Ch c nc v kh CO2 hy phn bit 5 cht bt trng sau y: NaCl, Na2CO3, Na2SO4, BaCO3, BaSO4. b, Khng c dng thm mt ho cht no khc, hy nhn bit 5 l b mt nhn sau y: NaHCO3, KHSO4, K2CO3, Mg(HCO3)2, Ba(HCO3)2. 3/ Hon thnh cc phng trnh phn ng theo s bin ho sau (ghi r iu kin nu c)

BaCO3
(2) (3)

Ba
(7)

(1)

Ba(OH)2
(4)

(8)

(9)

BaCl2
(5)

(6)

BaCO3

BaO Ba(HCO3)2

4/ Bng phng php ho hc hy tch ring tng kim loi ra khi hn hp gm: Ag, Au, Al. Cu II (5,0 im) 1/ Vit cc cng thc cu to thu gn ca cc ng phn c cng cng thc phn t ca cc hp cht hu c sau: C4H8, C4H10O, C3H6O2. 2/ Hn hp X gm mt ankan v mt ankin c t l phn t khi tng ng l 22:13. t chy hon ton 0,2 mol hn hp X, thu c 22g CO2 v 9g H2O. Xc nh cng thc phn t ca ankan v ankin trn. 3/ Hon thnh cc phng trnh phn ng theo s bin ho sau (ghi r iu kin nu c) NaOH D + E
men gim Xt : CaO, T
0

+O2 CO2 A B 1500 c F

ASKT ,Clorofin Lenmen
0

CH4

+ H2 O

XT XT, T 0
H , Ni ,t C4H6 + C4H10
2 0

Crcking,T 0

Xc nh cc cht A, B, D, E, F trong mi phng trnh. 4/ Hy nhn bit cc l mt nhn ng cc cht lng: CH 3COOH, HCl, C2H5OH, NaOH v C6H6 bng phng php ho hc. Cu III (4,0 im) Cho hn hp cha 0,2 mol Cu v 0,1 mol Fe3O4 vo 400 ml dung dch HCl 2M. Sau khi phn ng kt thc thu c dung dch A v cn li a gam cht rn B khng tan. Cho dung dch A tc dng vi dung dch NaOH d ri un nng trong khng kh. Cho cc phn ng xy ra hon ton. Lc ly kt ta, nung n khi lng khng i thu c b gam cht rn C. Vit cc phng trnh phn ng xy ra v tnh gi tr a v b. Cu IV (5,0 im) Cho hn hp A gm 2 cht hu c no n chc cha cc nguyn t C, H, O. Tc dng va vi 40 ml dung dch NaOH 1M, thu c mt mui v mt ru. un nng ru (va thu c) vi H2SO4 c 1700 C th to ra c 336 ml mt hir cacbon ( ktc). Nu t chy hon ton lng A nh trn ri cho sn phm hp th ht vo bnh ng CaO th thy khi lng bnh tng thm 6,82g. Tm cng thc cu to ca 2 hp cht trong A v tnh % v s mol ca 2 cht c trong A. Bit: Cc phn ng xy ra hon ton v hn hp A gm mt ru + mt este cng gc ru hoc mt axt + mt este cng gc axt.

s 17: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I (5,0 im)

1/ Vit cng thc ca cc axt hoc baz tng ng vi cc oxt axit v oxt baz trong s cc oxt sau: CaO, SO2, CO, Fe2O3, Mn2O7, Cl2O, NO, R2On (R l kim loi). 2/ Vit cc phng trnh ho hc theo s chuyn ho sau. O2 ,V2O5 KOH KOH t0 FeS2 + O2 A + A + B C D + E 3/ Vit cc phng trnh ho hc theo s phn ng sau . (1) ( 2) ( 3) CO2 Tinh bt Glucz Ru etylic. Gi tn cc phn ng (1), (2), (3). 4/ C 6 l mt nhn ng ring bit 6 dung dch sau: H 2SO4, NaCl, NaOH, Ba(OH)2, BaCl2, HCl. Ch dng qu tm hy nhn bit cc dung dch ng trong mi l trn. Cu II (4,0 im) 1/ a/ Cho m (g) Na vo 200ml dung dch AlCl3 0,1M, thu c 0,39g kt ta. Tnh m (g) dng b/ Dn V (lt) kh CO2 (o ktc) vo 200ml dung dch Ca(OH)2 1M, thu c 10g kt ta. Tnh V (lt) CO2 dng. 2/ Cho 7,8g hn hp kim loi l R ho tr II v Al tc dng vi dung dch H 2SO4 (long d). Khi phn ng kt thc thu c dung dch 2 mui v 8,96 lt kh (ktc). a/ Vit cc phng trnh phn ng ho hc xy ra. b/ Tnh khi lng mui thu c sau th nghim v tnh th tch dung dch H2SO4 2M ti thiu dng. c/ Xc nh R bit rng trong hn hp ban u t l s mol R : Al l 1 : 2. Cu III (2,0 im) 1/ Cho 1 lt cn 920 tc dng vi Na (d).Tnh th tch H2 thu c ktc. Bit khi lng ring ca ru etylc l 0,8 g/ml, ca nc l 1g/ml. 2/ Cho 12,8g dung dch ru A (trong nc) c nng 71,875 % tc dng vi Na (d) thu c 5,6 lt kh ( ktc). Xc nh cng thc cu to ca ru A. Bit phn t khi ca A nng gp 46 ln phn t khi ca hir. Cu IV (4,0 im) C 2 kim loi R v M, mi kim loi ch c mt ho tr. Cho kh CO d i qua ng s nung nng cha hn hp A gm 2 Oxt ca 2 kim loi trn n khi phn ng hon ton th cn li cht rn A1 trong ng v kh A2 i ra khi ng. Dn kh A2 vo cc ng lng d dung dch Ba(OH)2 thu c 2,955g kt ta. Cho A1 tc dng vi dung dch H2SO4 10% va th khng c kh thot ra. Cn li 0,96g cht rn khng tan v to ra dung dch A3 c nng 11,243%. a/ Xc nh kim loi R, M v cng thc ca cc O xt dng. b/ Xc nh thnh phn % theo khi lng ca mi cht trong hn hp A nu bit rng khi ho tan ht A vo dung dch HCl th nng % ca 2 mui trong dung dch l bng nhau. Cu V (5,0 im) t chy hon ton a gam hp cht hu c B (c to bi 2 loi nguyn t) ri hp th ht sn phm chy (gm CO2 v hi nc) bng cch dn hn hp ln lt i qua bnh 1 ng dung dch NaOH, bnh 2 ng dung dch H 2SO4 c. Sau th nghim thy khi lng cc bnh 1 v 2 tng thm tng ng l 24,16g v 8,64g. Lng Oxi tiu tn ng bng lng Oxi to ra khi nhit phn hon ton 252,8g KMnO4. a/ Tnh a v xc nh cng thc phn t ca B. b/ Khi cho B tc dng vi Clo ch to ra hn hp 2 dn xut ca B c cng khi lng mol bng 141g. Vit cng thc cu to ca B v ca cc dn xut Clo. ...........Ht..........

H = 1; C = 12; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Mn = 55; Cu =64; Ba=137

s 18: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I (3,0 im) 1/ Trong ht nhn nguyn t ca nguyn t A c s prton bng 13, v nguyn t ca nguyn t B c 3 lp electron , lp ngoi cng c 7 electron. - V s cu to nguyn t ca cc nguyn t A v B. - Hy m t qu trnh to thnh phn t c to ra t cc nguyn t ca nguyn t A v B. 2/ Vit cng thc cu to ca cc cht ng vi cng thc phn t C4H8. 3/ Tnh s nguyn t oxi c trong 4,4g CO2. Cu II (1,0 im) D on hin tng xy ra v vit phng trnh ho hc minh ho. 1/ Cho t t dung dch HCl vo dung dch Na2CO3. 2/ Cho Cu vo dung dch FeCl3. 3/ Cho Fe vo dung dch CuSO4. 4/ Sc kh CO2 vo nc vi trong n d. Cu III (3,0 im) 1/ Mt hp cht cha Ag, Cu, Fe. Ch c dng dung dch ca mt cht bng cch no c th tch c Ag tinh khit t hp kim trn sao cho khi lng Ag khng thay i. 2/ Khng c dng thm bt k ho cht no khc .Hy nhn bit 5 dung dch sau y ng trong 5 l ring bit b mt nhn: NaHCO3, KHSO4, Mg(HCO3)2, K2CO3, Ba(HCO3)2. Cu IV (3,0 im) 1/ Hon thnh cc phng trnh ho hc theo dy bin ho sau. a/ CaC2 CH = CH CH2 = CH2 CH3 CH2 OH CH3 COOH CH COONa CH CH Cl 3 4 3 b/ CH3 COOH CH COOC H CH3 CH2 OH CH3 CH2 ONa 3 2 5 2/ Vit phng trnh ho hc ca axtilen vi H2, HCl, dung dch Brm v vi Ag2O trong mi trng NH3 (hoc AgNO3 trong mi trng NH3). Cu V (5,0 im) Nung a(g) hn hp A gm MgCO3, Fe2O3 v CaCO3 nhit cao n khi lng khng i, thu c cht rn B c khi lng bng 60% khi lng hn hp A. Mt khc ho tan hon ton a(g) hn hp A trong dung dch HCl thu c kh C v dung dch D. Cho dung dch D tc dng vi NaOH d, lc ly kt ta, nung n khi lng khng i, c 12,92g hn hp 2 Oxt. Cho kh C hp th hon ton vo 2 lt dung dch Ba(OH) 2 0,075M, sau khi phn ng xong, lc ly dung dch, thm nc vi trong kt ta ht cc ion trong dung dch thu c 14,85g kt ta. 1/ Tnh th tch kh C ktc. 2/ Tnh % khi lng cc cht trong hn hp A.

Cu VI (5,0 im) 1/ Ru A c cng thc: CnH2n + 1OH, trong phn t Ru B hn Ru A mt nhm CH2. Cho 11g hn hp 2 ru trn tc dng vi Na th thu c 3,36 lt H2 ( ktc). a/ Xc nh cng thc phn t, vit cng thc cu to ca 2 ru. b/ Tnh khi lng ca mi ru trong hn hp. 2/ Vit cc phng trnh phn ng theo s sau. (1) ( 2) ( 3) ( 4) (5) Etilen Ru etylic Axt axtic Etyl axtat Natri axtat ( 6) (7) (8 ) Mtan Axtilen Vinyl clorua Poli vinyl clorua. ...........Ht.......... (Cho: H = 1; C = 12; O = 16; Na = 23; Mg = 24; Cl = 35,5; Ca = 40; Fe = 56; Cu =64; Ba = 137)

s 19: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I (7,0 im) 1/ Nhit phn mt lng MgCO3 trong mt thi gian, c cht rn A v kh B. Cho kh B hp th hon ton vo dung dch NaOH thu c dung dch C. Dung dch C c kh nng tc dng c vi dung dch (BaCl2 v KOH). Cho A tc dng vi dung dch HCl d li thu c kh B v mt dung dch D. C cn dung dch D c mui khan E. in phn nng chy E c kim loi M . Vit cc phng trnh phn ng xy ra trong th nghim trn v xc nh A, B, C, D, E, M. 2/ Ch c dng thm 2 loi ho cht t chn. Bng phng php ho hc hy nhn bit 5 cht bt ng ring bit trong 5 l mt nhn gm: Mg(OH)2, Zn(OH)2, BaCl2, Na2CO3, NaOH. 3/ Bng phng php ho hc hy tch ring tng cht ra khi hn hp gm Mg, Al, Fe, Cu. 4/ Vit cc phng trnh ho hc th hin theo s chuyn ho sau. (1) ( 2) ( 3) ( 4) (5) ( 6) CaCO3 CaO CaC2 C2H2 C2H4 C2H5OH CH3COOH (7) (8 ) (9) (10 ) CH3COONa CH4 CO2 Ba(HCO3)2. 5/ Ch c dng hai thuc th bn ngoi nhn bit 4 cht sau ng trong cc l b mt nhn: axit axetic, benzen, ng glucoz, ru etylic. Cu II (4,0 im) 1/ Hn hp X gm 2 kim loi A v B c t l khi lng l 1:1. Trong 33,6g hn hp X ny s mol 2 kim loi A, B khc nhau 0,0375 mol. Bit hiu MA MB = 8 (g) a/ Xc nh A, B trong hn hp X. b/ Ly mt na lng X dng trn cho tc dng vi lng d dung dch HCl. Tnh lng mui thu c. 2/ t chy hon ton 10,08 lit hn hp kh gm C 2H6 v CH4 thu c 14,56 lt kh CO2 (Cc th tch kh o ktc).

a/ Tm thnh phn % theo th tch ca mi cht trong hn hp. b/ Dn ton b sn phm chy trn i qua dung dch Ba(OH)2 d, thu c a(g) cht kt ta. Tm a. Cu III (5,0 im) Ha tan 1,97g hn hp Zn, Mg, Fe trong 1 lng va dung dch HCl thu c 1,008l kh ktc v dung dch A. Chia A thnh 2 phn khng bng nhau. - Phn 1 cho kt ta hon ton vi 1 lng va dung dch xt, cn 300ml dd NaOH 0,06M. un nng trong khng kh, lc kt ta v nung n khi lng khng i thu c 0,562g cht rn. - Phn 2 cho phn ng vi NaOH d ri tin hnh ging nh phn 1 th thu c cht rn c khi lng a (g). Tnh khi lng tng kim loi trong hn hp v gi tr ca a. Cu IV (4,0 im) Trung ho 13,4g hn hp X gm 2 axt no, n chc, mch h bng mt lng dung dch KOH va , c cn dung dch sau phn ng thu c 21g hn hp mui khan. 1/ Tm tng s mol hn hp X. 2/ Cn bao nhiu lt kh oxi ktc t chy hon ton hn hp X. 3/ Xc nh cng thc cu to ca mi axt v tnh khi lng tng axt trong hn hp X. Bit rng 2 axit trn l ng ng k tip. (Cho: H = 1 ; C = 12 ; O = 16 ; Mg = 24 ; Cl = 35,5 ; K = 39 ; Fe = 56 ; Cu = 64 ; Zn = 65)

s 19: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao ) Cu I (6,0 im) 1/ Nu cc hin tng xy ra v vit phng trnh ho hc minh ho khi. a/ Cho t t dung dch HCl n d vo dung dch NaAlO2. b/ Cho t t dung dch NaOH n d vo dung dch AlCl3. c/ Cho t t dung dch NH3 n d vo dung dch AlCl3. d/ Cho t t kh CO2 vo dung dch NaAlO2. 2/ khng dng thm ho cht no khc, hy nhn bit 5 l b mt nhn sau y: NaHSO4, KHCO3, Mg(HCO3)2, Na2CO3, Ba(HCO3)2. 3/ Bng phng php ho hc hy tch 3 mui KCl, AlCl3, FeCl3 ra khi nhau trong hn hp dung dch gm cc dung dch trn. 4/ Nhit phn mt lng MgCO3 trong mt thi gian thu c mt cht rn A v kh B. Cho kh B hp th hon ton vo dung dch NaOH thu c dung dch C. Dung dch C c kh nng tc dng c vi BaCl2 v KOH.

Cho A tc dng vi dung dch HCl d li thu c kh B v mt dung dch D. C cn dung dch D c mui khan E. in phn nng chy E c kim loi M. Xc nh A, B, C, D, E, M v Vit cc phng trnh phn ng xy ra trong th nghim trn. Cu II (5,0 im) 1/ Nung 29,4g Cu(OH)2 nhit cao thu c CuO, cn cht rn B thu c sau phn ng c 25,8g. Tnh s nguyn t oxi c trong B. 2/ t chy hon ton mt hir cacbon(X), thu c 6,72 lt CO2 v 5,4g H2O. Bit 1 lt kh (X) nng 1,26g (th tch cc kh u o iu kin tiu chun). a/ Xc nh cng thc phn t ca hir cacbon(X). b/ Vit cc phng trnh iu ch poli etilen; ru etylic; axt axtic t (X) v ghi r iu kin. 3/ a - Vit cng thc cu to c th c ca C4H8, C2H4O2, C3H8O. b - C cc cht kh sau C2H6, C2H2, C2H4, CO2, N2, O2. Bng phng php ho hc hy phn bit cc cht trn. Cu III (4,0 im) Cho 200ml dung dch gm (MgCl2 0,3M; AlCl3 0,45M; HCl 0,55M) tc dng hon ton vi V(lit) dung dch C cha (NaOH 0,02M ; v Ba(OH)2 0,01M). Hy tnh V(lit) thu c lng kt ta ln nht v nh nht. Tnh lng kt ta Gi s khi Mg(OH)2 kt ta th Al(OH)3 tan trong kim khng ng k) Cu IV (5,0 im) t chy hon ton 3,24 gam hn hp X gm 2 cht hu c (A) v (B) khc dy ng ng, trong (A) hn (B) mt nguyn t cacbon, ngi ta ch thu c H2O v 9,24 gam CO2. Bit t khi hi ca X i vi H2 l dX/H2 = 13,5. Tm cng thc ca (A), (B) v tnh thnh phn % theo khi lng ca mi cht trong X.
(Cho: H = 1 ; C = 12 ; O = 16 ; Na = 23, Mg = 24 ; Cl = 35,5 ; Al = 27 ; Ba = 137 ; Cu = 64)

s 20: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I: (6,0 im) 1/ Ho tan hn hp gm Na2CO3 v KHCO3 vo nc c dung dch A. Dung dch B l axit HCl.

a/ Cho t t dung dch axit HCl vo dung dch A n khi khng thy du hiu ca phn ng. b/ Cho t t dung dch axit HCl vo dung dch A th thu c dung dch C v kh E. Cho dung dch Ba(OH)2 vo dung dch C th thy c kt ta trng xut hin. c/ Cho t t dung dch A vo dung dch axit HCl th thy c kh thot ra. Hy vit cc PTHH xy ra trong cc th nghim trn. 2/ C mt ming Na ngoi khng kh m trong mt thi gian bin thnh sn phm A. Cho A tan trong nc c dung dch B. Cho dung dch B ln lt vo cc dung dch NaHSO4, NaHCO3, CaCl2, (NH4)2SO4, AlCl3. Vit cc phng trnh phn ng v gii thch qu trnh th nghim. 3/ Bng phng php ho hc hy tch ring tng cht ra khi hn hp ca chng gm Al2O3; Fe2O3; SiO2.
4/ Ch c nc v kh CO2 hy trnh by cch phn bit 5 cht bt mu trng sau: NaCl, Na2CO3, Na2SO4, BaCO3, BaSO4. Vit phng trnh ho hc minh ho.

5/ Hon thnh cc phng trnh phn ng theo s bin ho sau (ghi r iu kin nu c). K2CO3
(2) (3)

K KNO2

(1)

KOH
(4)

(8)

(9)

KCl
(5)

(6)

KNO3

(7)

KHCO3 Cu II (5,0 im) 1/ Vit cng thc cu to cc ng phn ng vi cng thc phn t: C3H6O2, C3H8O, C3H6, C5H10 2/ Cht A c cng thc phn t C2H6 .Xc nh cng thc cu to ca cc cht B, C, D, E, F v hon thnh cc phng trnh ho hc theo s phn ng sau: Na 2CO3 Cl 2 , ASKT O2 , XT Ca ( OH ) 2 NaOH NaOH , Xt:CaO ,t 0 C2H6 + B + C + D + E + F + CH4 3/ t chy 1 lt hn hp gm 2 Hir cacbon th kh thu c 1,6 lt kh CO2 v 1,4 lt hi nc. Cc th tch o cng iu kin nhit v p sut. Xc nh 2 cht v thnh phn % v s mol ca mi cht trong hn hp. 4/ Bng phng php ho hc hy nu cch phn bit 5 cht kh sau: CO, NO, C 2H2, SO2 v CO2. Cu III (4,0 im) Khi cho a gam Fe vo trong 400 ml dung dch HCl, sau khi phn ng kt thc em c cn dung dch thu c 6,2 gam cht rn X. Nu cho hn hp gm a gam Fe v b gam Mg vo trong 400 ml dung dch HCl th sau phn ng kt thc thu c 896 ml H2 (ktc) v c cn dung dch th thu c 6,68 gam cht rn Y. Tnh a, b, nng mol ca dung dch HCl v thnh phn khi lng cc cht trong X, Y (gi s Mg khng phn ng vi nc v khi phn ng vi axit Mg phn ng trc, ht Mg mi n Fe. Cho bit cc phn ng u xy ra hon ton). Cu IV (5,0 im) 1/ Hn hp kh X gm mt hircacbon A mch h v H 2. t chy hon ton 8 gam X thu c 22 gam kh CO2. Mt khc 8 gam X tc dng va vi 250 ml dung dch Br2 1M. Xc nh CTPT ca A v tnh thnh phn % v th tch ca mi cht trong X.

2/ Hn hp kh Y gm mt hircacbon B mch h v H 2 c t khi so vi mtan bng 0,5. Nung nng hn hp Y c bt Ni lm xc tc n phn ng hon ton thu c hn hp kh Z c t khi so vi oxi bng 0,5. Xc nh CTPT ca B, Tnh thnh phn % theo th tch ca mi cht trong hn hp Y.

(Cho: H = 1; C = 12; O = 16; Fe = 56; Mg = 24; Br = 80; Cl = 35,5)

s 21: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I: (6,0 im) 1/ Ho tan hn hp gm Na2CO3 v KHCO3 vo nc c dung dch A. Dung dch B l axit HCl. a/ Cho t t dung dch axit HCl vo dung dch A n khi khng thy du hiu ca phn ng. b/ Cho t t dung dch axit HCl vo dung dch A th thu c dung dch C v kh E. Cho dung dch Ba(OH)2 vo dung dch C th thy c kt ta trng xut hin. c/ Cho t t dung dch A vo dung dch axit HCl th thy c kh thot ra. Hy vit cc PTHH xy ra trong cc th nghim trn. 2/ C mt ming Na ngoi khng kh m trong mt thi gian bin thnh sn phm A. Cho A tan trong nc c dung dch B. Cho dung dch B ln lt vo cc dung dch NaHSO4, NaHCO3, CaCl2, (NH4)2SO4, AlCl3. Vit cc phng trnh phn ng v gii thch qu trnh th nghim. 3/ Bng phng php ho hc hy tch ring tng cht ra khi hn hp ca chng gm Al2O3; Fe2O3; SiO2.
4/ Ch c nc v kh CO2 hy trnh by cch phn bit 5 cht bt mu trng sau: NaCl, Na2CO3, Na2SO4, BaCO3, BaSO4. Vit phng trnh ho hc minh ho.

5/ Vit cc phng trnh ho hc th hin theo s bin ho sau (ghi r iu kin).

(1)

FeCl2
(9) (10)

(2)

Fe(NO3)2

(3)

Fe(OH)2
(11)

(4)

Fe
(5)

(8) (6)

Fe2O3

Cu II (5,0 im) 1/ Vit cng thc cu to cc ng phn ng vi cng thc phn t: C3H6O2, C3H8O, C3H6, C5H10 2/ Cht A c cng thc phn t C2H6 .Xc nh cng thc cu to ca cc cht B, C, D, E, F v hon thnh cc phng trnh ho hc theo s phn ng sau: 0 + Cl , ASKT + NaOH C llN t 0 t 0 Al4C3 CH4 1500 C2H2 Pd C2H4 Ni C2H6 2 B C Na 2CO3 O2 , XT Ca ( OH ) 2 NaOH , Xt:CaO ,t 0 C + D + E + F + CH4 3/ Bng phng php ho hc hy nu cch phn bit 5 cht kh sau: CO, NO, C 2H2, SO2 v CO2. 4/ t chy hon ton m gam hn hp X gm CH4, C2H4 v C2H2 thu c 39,6 gam CO2 v 14,4 gam H2O. Mt khc cho 2,24 lit hn hp X ( ktc) i t t qua nc Br2 d

FeCl3

Fe(NO3)3

(7)

Fe(OH)3

thy c 19,2 gam Br2 tham gia phn ng. Tnh m v thnh phn % v th tch ca mi kh trong X.

Cu III (4,0 im) Hn hp A gm 2 kim loi Al v Mg, cho 1,29 gam A vo 200 ml dung dch CuSO4. Sau khi phn ng xy ra hon ton thu c 3,47 gam cht rn B v dung dch C, lc ly dung dch C ri thm dung dch BaCl2 d vo thu c 11,65 gam kt ta. a/ Tnh nng mol/lit ca dung dch CuSO4. b/ Tnh khi lng tng kim loi trong hn hp A. c/ Nu cho dung dch NaOH vo dung dch C thu c kt ta D, ly kt ta D em nung ngoi khng kh n khi lng khng i c m gam cht rn. Tm khong xc nh ca m. Cu IV (5,0 im) 1/ Dung dch A l hn hp ca ru etylic v nc. Cho 20,2 gam dung dch A tc dng vi kim loi Na d, thu c 5,6 lt kh (o ktc). a/ Tnh ru ca dung dch A, bit khi lng ring ca ru l 0,8 g/ml. b/ Nu dng ru etylic tinh khit th cn bao nhiu gam thu c th tch kh ni trn. 2/ t chy 6,9 gam hp cht hu c A c cng thc CnH2n + 2O (n 1, nguyn) vi 10,08 lt kh O2 (ktc), lng O2 ny l va cho phn ng. Sn phm thu c gm 8,1 gam H2O v mt lng CO2 bng mt lng CO2 thu c khi cho 31,8 gam Na2CO3 tc dng vi dung dch H2SO4 d. Tm CTPT v CTCT ca A.

s 22: Mn thi: Ho Hc Thi gian lm bi: 150 pht (khng k thi gian giao )
Cu I (6,0 im) 1/ Nu cc hin tng xy ra v vit phng trnh ho hc minh ho khi. a/ Cho t t dung dch HCl n d vo dung dch NaAlO2. b/ Cho t t dung dch NaOH n d vo dung dch AlCl3. c/ Cho t t dung dch NH3 n d vo dung dch AlCl3. d/ Cho t t kh CO2 vo dung dch NaAlO2. 2/ khng dng thm ho cht no khc, hy nhn bit 5 l b mt nhn sau y: NaHSO4, KHCO3, Mg(HCO3)2, Na2CO3, Ba(HCO3)2. 3/ Bng phng php ho hc hy tch 3 mui KCl, AlCl3, FeCl3 ra khi nhau trong hn hp dung dch gm cc dung dch trn. 4/ Nhit phn mt lng MgCO3 trong mt thi gian thu c mt cht rn A v kh B. Cho kh B hp th hon ton vo dung dch NaOH thu c dung dch C. Dung dch C c kh nng tc dng c vi BaCl2 v KOH. Cho A tc dng vi dung dch HCl d li thu c kh B v mt dung dch D. C cn dung dch D c mui khan E. in phn nng chy E c kim loi M. Xc nh A, B, C, D, E, M v Vit cc phng trnh phn ng xy ra trong th nghim trn.
5/ Vit cc phng trnh ho hc theo s chuyn ho sau.

Cu II (5,0 im) 1/ Nung 29,4g Cu(OH)2 nhit cao thu c CuO, cn cht rn B thu c sau phn ng c 25,8g. Tnh s nguyn t oxi c trong B. 2/ t chy hon ton mt hir cacbon(X), thu c 6,72 lt CO2 v 5,4g H2O. Bit 1 lt kh (X) nng 1,26g (th tch cc kh u o iu kin tiu chun). a/ Xc nh cng thc phn t ca hir cacbon(X). b/ Vit cc phng trnh iu ch poli vinyl clorua; poli etilen; ru etylic; axt axtic t (X) v ghi r iu kin (nu c). 3/ a - Vit cng thc cu to c th c ca C4H8, C2H4O2, C3H8O. b - C cc cht kh sau C2H6, C2H2, C2H4, CO2, N2, O2. Bng phng php ho hc hy phn bit cc cht trn. Cu III (4,0 im) Cho 8,12 gam mt oxit ca kim loi M vo ng s trn, di, nung nng ri cho dng kh CO i chm qua ng kh hon ton lng oxit thnh kim loi. Kh c to thnh trong phn ng i ra khi ng s c hp th ht vo bnh ng lng d dung dch Ba(OH)2, thy to thnh 27,58 gam kt ta trng. Cho ton b lng kim loi va thu c trn tc dng ht vi dung dch HCl, thu c 2,532 lt kh H2 (ktc). Xc nh kim loi M v cng thc oxit ca n. Cu IV (5,0 im) Dn 1,68 lt hn hp kh X gm CH4, C2H4 v H2 i qua mt bnh cha dung dch nc Br2, nhn thy dung dch b nht mu mt phn v khi lng dung dch tng thm 0,42 gam. a/ Xc nh % th tch cc kh trong hn hp X, bit rng 0,7 lt hn hp kh ny nng 0,4875 gam. b/ t chy hon ton 1,68 lt kh X ri hp th ton b sn phm to thnh bng 1 lt dung dch Ca(OH)2 0,05M (khi lng ring l 1,025 g/ml). Tnh C% ca cc cht trong dung dch sau th nghim. Bit rng cc phn ng xy ra hon ton, cc th tch kh u o ktc. (Cho: H = 1; C = 12; O = 16; Fe = 56; Mg = 24; Ca = 40; Cu = 64; Br = 80; Cl = 35,5)

O2 ,V2O5 KOH KOH t FeS2 + O2 A + A + B C D + E

0