BI TP TNG HP HU C Cu 1: Cho cc cht: HOCH2CHO, CH4O , HOCH2CH2OH, C2H5OCH=CH2 , HCOOC2H3 , p-H3CC6H4OH lng (p-crezol), OHC-CH2COCH3. S cht tc dng c vi Na l: A. 3 B. 4 C. 5 D.

2 Cu 2: Chn pht biu khng ng A. Hiro ha (Ni, t0) hon ton cht bo lng thu c cht bo rn. B. Trong cng nghip, mt lng ln cht bo dng iu ch x phng v glixerol. C. X phng ho cht bo th tng s mol mui natri to thnh gp 2 ln s mol cht bo phn ng. D. Thu phn hon ton cht bo lun thu c glixerol. Cu 3: Dng brom v nc c th nhn bit c my cht ring bit sau: stiren, phenol (lng), benzen, nc, axit fomic A. 3 B. 4 C. 5 D. 2 H 2O CuO Ag 2O 2 Cu 4: Cho s sau: X Cl Y Z T G (axit acrylic). Cc cht X v Z l: A. C3H6 v CH2 = CH - CH2OH. B. C2H6 v CH2 = CH - CHO. C. C3H8 v CH3 - CH2 - CH2 - OH. D. C3H6 v CH2 = CH - CHO. Cu 5: Hy cho bit s sp xp no sau y ng vi chiu tng dn v nhit si ca cc cht? A. ru metylic < ru etylic < metyl amin < axit fomic B. metyl amin < ru metylic < ru etylic < axit fomic C. axit fomic < metyl amin < ru metylic < ru etylic D. ru metylic < axit fomic < metyl amin < ruetylic Cu6: Cho s chuyn ho sau: HCl HCHO / H + , t 0 Axetilen X Y Z + T + nha novolac X, Y, Z, T ln lt l: A. Benzen, phenylclorua, natriphenolat, phenol. B. Etilen, benzen, phenylclorua, phenol. C. Vinylclorua, benzen, phenyl clorua, phenol. D. Xiclohexan, benzen, phenylclorua, natriphenolat. Cu7: Cho cc cht sau: (1) CH3-CO-O-C2H5; (2) CH2=CH-CO-O-CH3 ; (3)C6H5-CO-O-CH=CH2; (4) CH2=C(CH3)-O-CO-CH3 (5) C6H5O-CO-CH3 (6) CH3-CO-O-CH2-C6H5. Hy cho bit cht no khi cho tc dng vi NaOH un nng khng thu c ancol? A. (1) (2) (3) (4) B. (3) (4) (5) C. (1) (3) (4) (6) D. (3) (4) (5) (6). Cu8: Trong cc cht sau: CH4(1); C2H6(2); C2H2(3); C3H8(4); Butan(5); Benzen(6) cht no c th dng iu ch trc tip etilen? A. 1,3,4 B. 2,3,4,5 C. 1,3,4,5 D. Ch c 3. Cu9: C bao nhiu amin bc ba c cng CTPT C6H15N A.3 cht B.4 cht C.7 cht D. 8 cht Cu 10: C s chuyn ho sau:
X1 CH3CHO X2 X4 X3

X1, X2, X3, X4 ln lt c th l: A. C2H5OH ; C2H2 ; CH3COOH ; CO2. B. C2H5OH ; C2H4 ; CH3COOH ; CH3COONH4 C. CH3COONa, CH3COOH ; C2H5OH ; CH3COOC2H5. D. C2H4 ; C2H5OH ; CO2 ; CH3COOH. Cu 11: Cho s dng: X Y Z. Cho cc cht sau y: etilen, etyl clorua, ancol etylic. S s nhiu nht th hin mi quan h gia cc cht trn l A. 3 B. 4 C. 5 D. 6 Cu 12: Cho cc cht sau: propyl clorua, anlyl clorua, phenyl clorua, natri phenolat, anilin, mui natri ca axit amino axetic, ancol benzylic. S cht tc dng c vi dung dch NaOH long khi un nng l A. 3. B. 4. C. 2. D. 1. Cu 13: Trong s cc loi t sau: t tm, t visco, t nilon-6,6, t axetat, t capron, t enang. Nhng loi t no thuc loi t nhn to l: A. T nilon 6,6 v t capron. B. T tm v t enang. C. T visco v t nilon-6,6. D. T visco v t axetat. Cu 14: Hp cht thm X, c cng thc phn t C8H8O2 va c kh nng tc dng vi Na, va c kh nng tc dng vi NaOH v lm qu tm chuyn mu hng. S ng phn cu to ca X l A. 4. B. 5. C. 6. D. 3.

Cu 15: Cho cc cng thc phn t sau: C3H7Cl , C3H8O v C3H9N. Hy cho bit s sp xp no sau y theo chiu tng dn s lng ng phn ng vi cc cng thc phn t ? A. C3H7Cl < C3H8O < C3H9N. B. C3H8O < C3H9N < C3H7Cl. C. C3H8O < C3H7Cl < C3H9N. D. C3H7Cl < C3H9N < C3H8O. Cu 16: Cho cc cht: amoniac (1); anilin (2); p-nitroanilin (3); p-metylanilin (4); metylamin (5); imetylamin (6). Hy chn s sp xp cc cht trn theo th t lc baz tng dn A. (3) < (2) < (4) < (1) < (5) < (6). B. (2) > (3) > (4) > (1) > (5) > (6). C. (2) < (3) < (4) < (1) < (5) < (6) . D. (3) < (1) < (4) <(2) < (5) < (6). Cu 17: Cho cc cht sau: axetilen, axit fomic, fomanehit, phenyl fomat, glucoz, anehit axetic, metyl axetat, mantoz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l A. 8. B. 7. C. 5. D. 6. Cu 18: Trong dy bin ho sau C2H6 C2H5Cl C2H5OH CH3CHO CH3COOH CH3COOC2H5 C2H5OH S phn ng oxi ho kh l: A. 2 B. 3 C. 4 D. 6 Cu 19: Cho cc hp cht hu c: (1) ankan; (2) ancol no, n chc, mch h (3) xicloankan; (4) ete no, n chc, mch h; (5) anken; (6) ancol khng no (c mt lin kt i C=C), mch h; (7) ankin; (8) anehit v este no, n chc, mch h; (9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc. Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l: A. (1), (3), (5), (6), (8). B. (3), (4), (6), (7), (10). C. (3), (5), (6), (8), (9). D. (2), (3), (5), (7), (9). Cu 20: Cho cac cht : (1) axit picric; (2) cumen; (3) xiclohexanol; (4) 1,2-ihiroxi-4-metylbenzen; (5) 4metylphenol; (6) -naphtol. Cac cht thuc loai phenol la: A. (1), (3), (5), (6) B. (1), (2), (4), (6) C. (1), (2), (4), (5) D. (1), (4), (5), (6) Cu 21: Trong cc polime c cng s mt xch sau y, polime no c khi lng phn t ln nht ? A. Poli(vinyl axetat) B. Thu tinh hu c C. Poli stiren D. T capron Cu 22: Trong s cc cht: phenylamoni clorua, natri phenolat, vinyl clorua, anlyl clorua, benzyl clorua, phenyl clorua, phenyl benzoat, t nilon-6, propyl clorua, ancol benzylic, alanin, tripeptit Gly-Gly-Val, mcrezol, s cht phn ng c vi dung dch NaOH long, un nng l: A. 8 B. 10 C. 9 D. 7 Cu 23: S ng phn cu to ca amin ng vi cng thc phn t C4H11N tc dng vi dung dch hn hp HCl v NaNO2 sinh ra cht kh l: A. 7 B. 8 C. 4 D. 5 Cu 24: Cho C2H3Cl3 tc dng vi dung dch NaOH d, un nng, thu c cht hu c X. Cht X, Y, Z tham gia phn ng theo s sau: X Y Z Phenyl axetat . Cc cht X, Y, Z ln lt l: A. Axit axetic, axetyl clorua, anhirit axetic B. 2-Hiroxietanal, 2-cloetanal, axetyl clorua C. Natri axetat, axit axetic, benzophenon D. Natri axetat, axit axetic, anhirit axetic Cu 25: Qu trnh no sau y khng ph hp vi quy tc to ra sn phm chnh: A. benzen brombenzen p-brom nitrobenzen. B. buten-1 2-clobutan butanol-2. C. benzen nitrobenzen o-brom nitrobenzen. D. propanol-1 propen propanol-2 Cu 26: Cho dy cc hp cht sau: phenol(1), etanol( 2), nc( 3), axit etanoic(4), axit clohiric( 5), axit metanoic( 6), axit oxalic(7), ancol proylic( 8). Th t tng dn tnh axit l: A. ( 8),( 2),( 3),(1),(7),( 4),(6),( 5) B. ( 8),( 2),( 1),(3),(4),( 6),(7),( 5) C. ( 3),( 8),( 2),(1),(4),( 6),(7),( 5) D. ( 8),( 2),( 3),(1),(4),( 6),(7),( 5) Cu 27: Polime no di y c iu ch bng phng php trng ngng: A. T nilon-6 t axit -aminocaproic B. T capron t caprolactam C. Poli(metyl metacrylat) D. T nitron Cu 28: Trong s cc cht: axetyl clorua, anhirit axetic, axit nitric, brom, kali hiroxit, axit axectic, anehit fomic. S cht phn ng c vi phenol l: A. 7. B. 4. C. 5. D. 6. Cu 29: Cho cc polime sau: nha rezol (1), nha bakelit (2), xenluloz (3) , amiloz (4), amilopectin (5), cao su thin nhin (6), cao su lu ha (7). Nhng polime cu trc mng khng gian l: A. (2), (7). B. (5), (7). C. (2), (6), (7). D. (2), (5), (7).

Cu 30: Trong s cc cht: clobenzen, toluen, nitrobenzen, anilin, phenol, axit benzoic, benzanehit, naphtalen, p-xilen, cumen, p-crezol,s cht tham gia phn ng th nhn thm d hn so vi benzen l: A. 7. B. 9. C. 8. D. 6. Cu 30: Trong s cc cht: anehit axetic, anehit fomic, anehit oxalic, axeton, axit fomic, natri fomat, etyl fomat. C bao nhiu cht tha mn iu kin sau: Khi cho tc dng vi lng d dung dch AgNO3/NH3, sn phm mui thu c cho tc dng vi dung dch NaOH hoc vi dung dch H2SO4 un nng u c kh v c thot ra: A. 3. B. 5. C. 4. D. 2. Cu 31: Trong s cc cu sau: a) Cc cht: amoniac, etylamin, hiro, ancol metylic u kh c ng (II) oxit khi nung nng. b) Propen v xiclopropan khi cng brom u cho cng mt sn phm. c) Cc cht rn: km hiroxit, bc oxit, bc clorua u tan c trong dung dch amoniac m c. d) Khi cho dung dch natri stearat vo dung dch canxi hirocacbonat c kt ta to thnh. e) Stiren v toluen u c kh nng lm mt mu dung dch thuc tm. S cu ng l A. 3. B. 5. C. 4. D. 2. Cu 33: X, Y, Z c cng cng thc phn t C3H6O2. Bit: X lm tan vi; Y khng tc dng c vi NaOH nhng tc dng vi Na v tham gia phn ng trng bc. Khi oxi ha Y vi xc tc thch hp thu c hp cht a chc. Z khng tham gia phn ng trng bc; khng tc dng vi NaOH nhng tc dng vi Na. X, Y, Z ln lt l: A. C2H5COOH; HO-CH2-CH2-CHO; CH3-CO-CH2OH B. C2H5COOH; CH3-CH(OH)-CHO; CH3COOCH3 C.C2H5COOH;CH3-CH(OH)-CHO;CH3-CO-CH2OHD.HCOOCH2CH3;HO-CH2-CH2-CHO;CH3COCH2OH Cu 34:Cho cc cht: CH2ClCOOH (a); CH3-COOH (b); C6H5OH (c); CO2 (d); H2SO4 (e). Tnh axit ca cc cht gim theo trt t: A. e > b > d > c > a B. e > a > b > d > c C. e > b > a > d > c D. e > a > b > c > d H 2O CuO Ag 2O 2 Cu 35: Cho s sau: X Cl Y Z T G (axit acrylic). Cc cht X v Z l: A. C3H6 v CH2 = CH - CH2OH. B. C2H6 v CH2 = CH - CHO. C. C3H8 v CH3 - CH2 - CH2 - OH. D. C3H6 v CH2 = CH - CHO. Cu 36: Xc nh pht biu no di y l khng ng? A. C th phn bit da tht v da gi (lm t PVC) bng cch t chy v hp th sn phm chy vo dung dch AgNO3/HNO3. B. C th phn bit glixerol v lng trng trng bng phn ng mu vi dung dch HNO3 c. C. C th phn bit fructoz v axit fomic bng phn ng trng gng. D. C th phn bit du m ng thc vt v du m bi trn my bng dung dch NaOH nng. Cu 37: Vi cc cht: butan, buta-1,3-dien, propilen, but-2-in, axetilen, metylaxetilen, isobutan, xiclopropan, isobutilen , anlen. Chn pht biu ng v cc cht trn: A. C 7 cht tham gia phn ng cng hidro B. C 3 cht tc dng dung dch AgNO3/NH3 to KT mu vng C. C 8 cht lm mt mu nc brom. D. C 8 cht lm mt mu tm ca dung dch KMnO4 Cu 38: Cho cc pht biu sau: (1) glucoz c phn ng thu phn to ancol etylic (2) mantoz v saccaroz c lin kt glicozit (3) mantoz v fructoz c kh nng lm mt mu dung dch nc Br2 (4) tinh bt v xenluloz l ng phn ca nhau (5) mantoz v fructoz c kh nng tham gia trng gng. Cc pht biu khng ng l: A. 1, 3, 4, 5. B. 2, 5. C. 1, 3, 4. D. 3, 4, 5. Cu 39: Dy cc gm cc polime tng hp l: A. Polipropilen; poli(vinylclorua); visco; nilon-6. B. Polietilen; polistiren; nilon-6; poli(vinylclorua). C. Poli(vinyl clorua); polietilen; t axetat; polistiren. D. Nilon-6; polietilen; protin; polistiren. Cu 40: Trong cc polime sau : (1) poli(metyl metacrylat) ; (2) t capron ; (3) nilon-6,6 ; (4) poli(etylenterephtalat) ; (5) poli(vinylclorua) ; (6) poli(vinyl axetat). Cc polime c th tng hp bng phn ng trng hp l : A. (1), (2) , (4), (6) B. (2), (3), (4) . C. (1), (2), (3), (5) D. (1), (2) ,(5), (6) Cu 41:S hp cht ng vi cng thc phn t C4H11NO3 u tc dng c vi dung dch NaOH v dung dch HCl( khi tc dng vi dung dch NaOH d ch to ra mt mui v c duy nht) l: A. 6 B. 5 C. 3 D. 4 Cu 42: Cho s sau:

Cumen

+O2(kk) H2SO4

(X)

+HCN long

(Y)

+H2O/H3O+

(Z)

Cc cht X, Z ln lt l. A. CH3COCH3, CH3CH(OH)COOH B. CH3COCH3, (CH3)2C(OH)COOH C. C6H5OH, HOC6H4NH2 D. C6H5OH, HOC6H4COOH Cu 43: Khng nh no sau y khng ng? A. Dung dch natri phenolat lm qu tm ha xanh B. Lng trng trng gp HNO3 to thnh hp cht c mu vng. C. Phn ng cng H2 (xt Ni, t0) vo hirocacbon khng lm thay i mch cacbon ca hirocacbon. D. ng saccaroz gp Cu(OH)2 to thnh hp cht mu xanh lam. Cu 44: Cho s : +O2, xt,t0 +NaOH +CuO +Br 2 Xiclopropan X1 X2 X3 X4 X4 c cng thc cu to l: A. HOOC-CH2-COOH B. CH3-CH(OH)-COOH C. CH3-CO-COOH D. CH2=CH-COOH Cu 45: C s sau : tho mn s trn: a 1 Cu 46: Cho s :
C3H6O
+H2

xt

+H2SO4

+H2

170 C

xt

C3H8

. Bao nhiu cht c cng thc C3H6O d 4

A3 CH4 C2H6O CH4

b 3
A1 C2H2 A4 A6

c 2
A2 A5 A4

Bit A1, A4 u c kh nng phn ng c vi AgNO3 /NH3. A2, A5, A6 ln lt l : a CH3COOH; C3H8; C2H4. b C4H4; CH3COONa; CH3COOC2H3. c CH3COONH4; CH3COONa; CH3CHO. d C4H6;CH3COONa; CH3COOC2H3. Cu 47: Cho 5 cht sau : (1) CH3-CHCl2 .(2) CH3-COO-CH=CH2 (3) CH3-COO-CH2-CH=CH2 (4) CH3CH2CH(OH)Cl. (5)CH3-COOCH3 . Cht thu phn trong mi trng kim to sn phm c phn ng trng gng: a 3, 5 b 1, 2, 4 c 1, 2 d 2 Cu 48: Cho cc cht : ancol etylic ; glixerol ; axit focmic ; axit acrylic; phenol ; anehit axetic; axeton. t a l s cht c p vi Na ; b l s cht c p vi NaOH ; c l s cht c p vi dd Br2 ; d l s cht c p vi AgNO3 / NH3 ; e l s cht c p vi Cu(OH)2 trong iu kin thng ; Gi tr ca a,b,c,d,e ln lt l: a 5, 3, 3, 2, 1. b 5, 3, 4, 2, 3. c 5, 3, 3, 2, 3. d 5, 3, 4, 2, 2. Cu 49: Cho cc cht sau : axetilen, axit fomic, fomanehit, phenyl fomat, glucz, anehit axetic, metyl axetat, mantz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l A. 8 B. 7 C. 5 D. 6 Cu 50: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2(anilin), C6H5OH (phenol), C6H6(benzen), CH3CHO. S cht trong dy phn ng c vi nc brom l: A. 5 B. 6 C. 7 D. 8 Cu 51:Pht biu no sau y l sai: (1)Du thc vt thuc loi lipit. (4)X phng c iu ch t Protein. (2)Tinh bt thuc loi Gluxit. (5)Cao su thin nhin thuc loi du thc vt. (3)Lng trng trng l loi cht bo. A.Ch c 4. B.Ch c 3,4,5. C.Ch c 5. D.Ch c 1 ,4. Cu 52. Trong s cc cht: phenylamoni clorua, natri phenolat, vinyl clorua, anlyl clorua, benzyl clorua, phenyl clorua, phenyl benzoat, t nilon-6, propyl clorua, ancol benzylic, alanin, tripeptit Gly-Gly-Val, mcrezol, s cht phn ng c vi dung dch NaOH long, un nng l: A. 8 B. 10 C. 9 D. 7 Cu 53. Cho C2H3Cl3 tc dng vi dung dch NaOH d, un nng, thu c cht hu c X. Cht X, Y, Z tham gia phn ng theo s sau: X Y Z Phenyl axetat . Cc cht X, Y, Z ln lt l: A. Axit axetic, axetyl clorua, anhirit axetic B. 2-Hiroxietanal, 2-cloetanal, axetyl clorua

C. Natri axetat, axit axetic, benzophenon D. Natri axetat, axit axetic, anhirit axetic Cu 54. Trong s cc cht: iot, photpho trng, photpho , lu hunh, cao su thin nhin, cht bo, naphtalen, alanin, brom,s cht d tan trong benzen l: A. 8 B. 7 C. 6 D. 5 Cu 55: Cho dy cht: phenyl clorua, anlyl clorua, benzyl clorua, natri phenolat, protein, lipit, tinh bt, amoni axetat. S cht trong dy khng tc dng vi dung dch NaOH long nhit thng cng nh khi un nng l A. 5 B. 3 C. 2 D. 1 Cu 56: Cho dy Cht: CH3OH, C6H12O6, CH4, C2H2, C2H4, CH2Cl2, HCOOH. S cht trong dy ch bng mt phn ng trc tip iu ch HCHO l. A. 2 B. 3 C. 1 D. 4 Cu57: iu ch cao su buna ngi ta c th thc hin theo cc s bin ha sau: 30% 80% 50% 80% C2H6 hs C2H4 hs C2H5OH hs Buta-1,3-ien hs Caosubuna Tnh khi lng etan cn ly c th iu ch c 5,4 kg cao su buna theo s trn? A. 46,875kg B. 62,50 kg C. 15,625kg D. 31,25 kg.