N TP CHNG 7

A-L THUYT Cu 1: Vit cu hnh e ca Fe, Fe2+, Fe3+; Cr, Cr3+. Xc nh v tr ca Fe v Cr trong BTH
V d 1: Cu hnh electron ca ion Cr3+ l: A. [Ar]3d5. B. [Ar]3d4. C. [Ar]3d3. D.[Ar]3d2. V d 2: Cc s oxi ho c trng ca crom l: A. +2; +4, +6. B. +2, +3, +6. C. +1, +2, +4, +6. D.+3, +4, +6. V d 3: Cu hnh electron no sau y l ca ion Fe? A. [Ar] 4s23d6. B. [Ar]3d64s2. C. [Ar]3d8. D. [Ar]3d74s1. 2+ V d 4: Cu hnh electron no sau y l ca ion Fe ? A. [Ar]3d6. B. [Ar]3d5. C. [Ar]3d4. D.[Ar]3d3. V d 5: Cu hnh electron no sau y l ca ion Fe3+? A. [Ar]3d6. B. [Ar]3d5. C. [Ar]3d4. D.[Ar]3d3. V d 6: St nm th 26 trong bng tun hon, cu hnh electron ca ion Fe3+ A. 1s2 2s2 2p6 3s2 3p6 3d4 4s2 B. 1s2 2s2 2p6 3s2 3p6 3d5 4s1 2 2 6 2 6 5 C.1s 2s 2p 3s 3p 3d D.1s2 2s2 2p6 3s2 3p6 3d5 4s2 Cu 2: Trnh by tnh cht ha hc ca Fe? Hp cht Fe (II); Hp cht Fe (III)? K ra cc loi qung cha st quan trng? V d 7: Kim loi no sau y tc dng vi axit HCl long v kh clo khng cho cng loi mui clorua kim loi A. Zn B. Cu C. Fe D. Al V d 8: Fe c th tan trong dung dch cht no sau y? A. AlCl3 B. FeCl3 C. FeCl2 D. MgCl2 V d 9: Trong cc phn ng ho hc cho di y, phn ng no khng ng? A.Fe + 2HCl FeCl2 + H2 B. Fe + CuSO4 FeSO4 + Cu C. Fe + Cl2 FeCl2 D. Fe + H2O FeO + H2 V d 10: Hai dung dch u phn ng c vi kim loi Fe l A. CuSO4 v ZnCl2. B. CuSO4 v HCl. C. ZnCl2 v FeCl3. D. HCl v AlCl3. V d 11: Cho st phn ng vi dung dch HNO3 c, nng thu c mt cht kh mu nu . Cht kh l A. NO2. B. N2O. C. NH3. D. N2. V d 12: Cho phn ng: a Fe + b HNO3 c Fe(NO3)3 + d NO + e H2O Cc h s a, b, c, d, e l nhng s nguyn, n gin nht. Th tng (a+b) bng A. 3. B. 6. C. 4. D. 5. V d 13: Phn ng ho hc no sau y xy ra? A. Cu2+ + 2Ag Cu + 2Ag+ B. Cu + Pb2+ Cu2+ + Pb C. Cu + 2Fe3+ Cu2+ + 2Fe2+ D. Cu + 2Fe3+ Cu2+ + 2Fe V d 14: Cp cht khng xy ra phn ng ho hc l A. Cu + dung dch FeCl3. B. Fe + dung dch HCl. C. Fe + dung dch FeCl3. D. Cu + dung dch FeCl2. V d 15: Cht c tnh oxi ho nhng khng c tnh kh l A. Fe. B. Fe2O3. C. FeCl2. D. FeO. V d 16: Dung dch mui FeCl3 khng tc dng vi kim loi no di y? A. Zn B. Fe C. Cu D. Ag V d 17: Khi nung nng Fe vi cht no sau y th to ra hp cht st (II) A. S B. Dung dch HNO3 C. O2 D. Cl2 V d 18: Phn ng no di y khng th xy ra (1) Fe + MgSO4Mg + FeSO4 (2) Fe + 2HCl FeCl2+ H2 (3) Fe + 6HNO3 , ngui Fe(NO3)3 + 3NO2 + 3H2O (4) 2Fe + 3Cl22FeCl3 A. (1),(2) B. (1),(3) C. (3),(4) D. (2),(3) V d 19: Nhn nh no sau y sai? A. St tan c trong dung dch CuSO4 B. St tan c trong dung dch FeCl3 C. St tan c trong dung dch FeCl2 D. ng tan c trong dung dch FeCl3

V d 20: Cho bt Fe vo dung dch HNO3 long, phn ng kt thc thy c bt Fe cn d. Dung dch thu c sau phn ng l: A. Fe(NO3)3 B. Fe(NO3)3, HNO3 C. Fe(NO3)2 D. Fe(NO3)2, Fe(NO3)3 V d 21: Nu cho dung dch NaOH vo dung dch FeCl3 th xut hin A. kt ta mu trng hi xanh. B. kt ta mu trng hi xanh, sau chuyn dn sang mu nu . C. kt ta mu xanh lam. D. kt ta mu nu . V d 22: T qung Fe2O3 c th iu ch ra st bng phng php A. Thy luyn. B. in phn. C. Nhit luyn. D.Mt phng php khc. V d 23: Kim loi phn ng c vi dung dch st (II) clorua l A. Pb. B. Fe. C. Zn. D. Cu. V d 24: kh ion Fe3+ trong dung dch thnh ion Fe2+ c th dng mt lng d A. kim loi Mg. B. kim loi Cu. C. kim loi Ba. D. kim loi Ag. V d 25: Cho hn hp Fe v Cu d vo dung dch HNO3 thy thot ra kh NO. Mui thu c trong dung dch sau phn ng l : A. Fe(NO3)3 B. Fe(NO3)3 v Cu(NO3)2 C. Fe(NO3)2 v Cu(NO3)2 D. Cu(NO3)2 V d 26: Phn hy Fe(OH)3 nhit cao n khi lng khng i, thu c cht rn l A. FeO. B. Fe2O3. C. Fe3O4. D. Fe(OH)2. V d 27: Dy gm hai cht ch c tnh oxi ho l A. Fe(NO3)2, FeCl3. B. Fe(OH)2, FeO. C. Fe2O3, Fe2(SO4)3. D. FeO, Fe2O3. X Y V d 28: Cho s chuyn ho: Fe Fe(OH)3 (mi mi tn ng vi mt phn ng). Hai cht FeCl3 X, Y ln lt l A. HCl, NaOH. B. HCl, Al(OH)3. C. NaCl, Cu(OH)2. D.Cl2, NaOH. V d 29: Hp cht st (II) sunfat c cng thc l A. FeSO4. B. Fe(OH)3. C. Fe2O3. D.Fe2(SO4)3. Cu 3: Trnh by khi nim gang? Nguyn tc sn xut v cc phn ng ha hc xy ra trong qu trnh luyn qung thnh gang? Trnh by khi nim thp? Nguyn tc sn xut? V d 30: Qung c hm lng st ln nht l A. manhetit B. xierit C. hematit D. pirit V d 31: Cu no ng trong s cc cu sau? A. Gang l hp kim ca st vi cacbon, trong cacbon chim 5-10% khi lng. B. Thp l hp kim ca st vi cacbon, trong cacbon chim 2-5%khi lng. C. Nguyn tc sn xut gang l kh qung st bng cc cht khnh CO, H2, Al D. Nguyn tc sn xut thp l oxi ho cc tp cht (C, Si, Mn, S,P) thnh oxit, nhm gimhm lng ca chng. V d 32: Trong cc pht biu sau, pht biu no khng ng? A. Hm lng C trong gang nhiu hn trong thp B. Gang l hp cht ca Fe C C. Gang l hp kim Fe C v mt s nguyn t khc D. Gang trng cha t C hn gang xm V d 33: C th dng dung dch no sau y ho tan hon ton mt mu gang? A. Dung dch HCl. B. Dung dch H2SO4 long. C. Dung dch NaOH. D. Dung dch HNO3 c nng. Cu 4: Trnh by tnh cht ha hc ca Cr? Hp cht Cr(III)? Hp cht Cr(VI)? Khi no dd cromat chuyn thnh mu da cam v dd icromat chuyn thnh mu vng V d 34: Nh t t dung dch H2SO4 long vo dung dch K2CrO4 th mu ca dung dch chuyn t A. khng mu sang mu vng. B. mu da cam sang muvng. C. khng mu sang mu da cam. D. mu vng sang mu dacam. V d 35: Oxit lng tnh l A. Cr2O3. B. MgO. C. CrO. D. CaO. V d 36: Cho phn ng : NaCrO2 + Br2 + NaOH Na2CrO4 + NaBr +H2O Khi cn bng phn ng trn, h s ca NaCrO2 l A. 1. B. 2. C. 3. D. 4. V d 37: Cp kim loi no sau y bn trong khng kh v nc do c mng oxit bo v? A. Fe v Al. B. Fe v Cr. C. Mn v Cr. D. Al v Cr. V d 38: Khi so snh trong cng mt iu kin th Cr l kim loi c tnh kh mnh hn A. Fe. B. K. C. Na. D. Ca.

B- BI TP Dng 1: Mt kim loi tc dng vi mt mui

V d 1: Nhng 10 gam thanh st vo dd CuSO4, sau mt thi gian ly thanh st ra ra sch, sy kh thy khi lng tng 1,6 gam. Khi lng ca Cu bm vo thanh st v khi lng thanh st sau phn ng l A. 3,2 gam v 9,4 gam B. 6,4 gam v 11,6 gam C. 12,8 gam v 11,6 gam D. 19,2 gam v 9,4 gam V du 2: Ha tan 2,8 gam bt st trong 120 ml dung dch AgNO3 1M. Khi lng cht rn thu c l A. 5,40 gam. B. 10,80 gam. C. 2,16 gam. D. 7,56 gam. V du 3: Ngm mt inh st nng 4g trong dung dch CuSO4, sau mt thi gian ly inh st ra, sy kh, cn nng 4,2857g. Khi lng st tham gia phn ng l A. 1,9990g B. 1,9999g C. 0,3999g D. 2,1000g

Dng 2: Bi tp st v cc oxit ca st, oxit ca ng tc dng vi cht kh CO hoc H2

V d 4: kh hon ton 17,6 gam hn hp Fe, FeO, Fe3O4, Fe2O3 n st cn va 2,24 lt kh CO(ktc). Khi lng st thu c l A. 15 gam. B. 16 gam. C. 17 gam. D. 18 gam. V d 5: Kh hon ton 6,4 gam hn hp CuO v Fe2O3 bng kh H2 thy to ra 1,8 gam nc. Khi lng hn hp kim loi thu c l A. 4,5 gam B. 4,8 gam C. 4,9 gam D. 5,2 gam V d 6: Kh a gam mt oxit st bng 1,12 lt kh CO (ktc) nhit cao, thu c 0,84 gam st v hn hp kh Y cha 0,88 gam CO2 a) Cng thc ca oxit st v % V CO 2 trong Y l A. FeO v 40 % B. Fe2O3 v 60 % C. Fe3O4 v 40 % D. Fe2O3 v 40% b) ha tan a gam oxit trn cn dng V ml dung dch HCl 2M. Gi tr ca V l A. 10 ml. B. 20 ml. C. 40 ml. D. 30 ml. V d 7: Ha tn 10 gam hn hp bt Fe v Fe2O3 bng dd HCl thu c 1,12 lt kh (ktc) v dung dch A. Cho dung dch A tc dng vi NaOH d, thu c kt ta. Nung kt ta trong khng kh n khi lng khng i c cht rn c khi lng l: A. 11,2 gam. B. 12,4 gam. C. 15,2 gam. D. 10,9 gam. V d 8: Kh hon ton 0,1 mol FexOy bng kh CO nhit cao thy to ra 0,3 mol CO2. Cng thc oxit st l A. FeO B. Fe3O4 C. Fe2O3 D. khngxc nh c V d 9: Cho kh CO kh hon ton n Fe mt hn hp gm: FeO,Fe2O3, Fe3O4 thy c 4,48 lt CO2 (ktc) thot ra. Th tch CO (ktc) tham gia phn ng l A. 1,12 lt. B. 2,24 lt. C. 3,36 lt. D.4,48 lt.

Dng 3: Bi tp oxit kim loi tc dng vi dd H2SO4 long

V d 10: Bit 2,3 gam hh gm MgO, CuO v FeO tc dng va vi 100 ml dd H2SO4 0,2M. Khi lng mui thu c l A. 3,6 gam. B. 3,7 gam. C. 3,8 gam. D. 3,9 gam. V d 11: Cho 32g hn hp gm MgO, Fe2O3, CuO tc dng va vi 300ml dung dch H2SO4 2M. Khi lng mui thu c l A. 60g B. 80g C. 85g D. 90g

Dng 4: Bi tp kim loi tc dng vi axit

V d 12: Hn hp X gm Cu v Fe, trong Cu chim 43,24% v khi lng, Cho 14,8 gam X tc dng ht vi dd HCl thy c V lt kh(ktc) bay ra. Gi tr ca V l A. 1,12 lt. B. 2,24 lt. C. 4,48 lt. D. 3,36 lt. V d 13: Cho 7,68 gam Cu tc dng vi dd HNO3 long thy c kh V lt NO thot ra (ktc). Gi tr ca V l A. 1,792 lt. B. 1,344 lt. C. 1.12 lt. D. 2,688 lt. V d 14: Cho 19,2 gam kim loi M tc dng vi dd HNO3 long, d thu c 4,48 lt kh duy nht NO (ktc). Kim loi M l A. Mg. B. Cu. C. Fe. D. Zn. V d 15: Ha tan 8,4 gam mt kim loi M trong dd HCl d, thu c 6,72 lt kh (ktc). Kim loi M l A. Mg. B. Fe. C. Zn. D. Al. V d 16: Cho m gam hh Al v Fe phn ng hon ton vi dd HNO3 long thu c 2,24 lt kh NO duy nht (ktc). Mt khc cho m gam hh ny phn ng vi dd HCl thu c 2,80 lt kh H2 (ktc). Gi tr ca m l A. 8,30. B. 4,15. C. 4,50. D. 6,95.

V d 17: Ha tan 3,04 gam hh bt kim loi Fe v Cu trong d HNO3 long, thu c 0,896 lt kh NO duy nht (ktc). %Fe v %Cu l A. 36,84% v 63,16%. B. 63,16% v 36,84% C. 50% v 50%. D. 25% v 75%. V d 18: Cho 2,52 gam mt kim loi tc dng vi dd H2SO4 long, thu c 6,84 gam mui sunfat. Kim loi l A. Mg. B. Zn. C. Fe. D. Al. V d 19: Cn iu ch 6,72 lt H2 (ktc) t Fe v dung dch HCl hoc dung dch H2SO4 long. Chn axit no s mol cn ly nh hn ? A. HCl B. H2SO4 longC. Hai axit u nh nhau D. Khng xc nh c V d 20: Cho 8g hn hp kim loi Mg v Fe tc dng ht vi dung dch HCl thy thot ra 5,6 lt H2 (ktc). Khi lng mui to ra trong dung dch l A. 22,25g B. 22,75g C. 24,45g D. 25,75g V d 21 : Cho 10 gam hn hp gm Fe v Cu tc dng vi dung dch H2SO4 long (d). Sau phn ng thu c 2,24 lt kh hiro ( ktc), dung dch X v m gam cht rn khng tan. Gi tr ca m l A. 6,4 gam. B. 3,4 gam. C. 5,6 gam. D. 4,4 gam. V d 22: Cho 13,5 gam hn hp cc kim loi Al, Cr, Fe tc dng vi lng d dung dch H2SO4 long nng (trong iu kin khng c khng kh), thu c dung dch X v 7,84 lt kh H2 ( ktc). C cn dung dch X (trong iu kin khng c khng kh) c m gam mui khan. Gi tr ca m l A. 42,6. B. 45,5. C. 48,8. D. 47,1. V d 23: Cho 7,68 gam Cu tc dng ht vi dung dch HNO 3 long thy c kh NO thot ra. Khi lng mui nitrat sinh ra trong dung dch l: A. 22,65 gam. B. 21,65 gam. C. 21, 56 gam. D. 22,56 gam. V d 24: 20 gam hn hp gm Cu v Fe tan trong dd HNO3 c, ngui d th thu c 4,48 lt kh NO2 (sp kh duy nht) ktc. % v khi lng ca Fe c trong hn hp l A. 68% B. 64% C. 36% D. 32%

Dng 5: Bi tp v Crom v hp cht

V d 25: Khi lung K2Cr2O7 cn dng oxi ho ht 0,6 mol FeSO4 trong dung dch c H2SO4 long lm mi trng l (Cho O = 16, K = 39, Cr = 52) A. 29,4 gam B. 59,2 gam. C. 24,9 gam. D. 29,6 gam V d 26: Mun iu ch 6,72 lt kh clo (kc) th khi lung K2Cr2O7 ti thiu cn dng tc dng vi dung dch HCl c, d l (Cho O = 16, K= 39, Cr = 52) A. 29,4 gam B. 27,4 gam. C. 24,9 gam. D. 26,4 gam V d 27: Khi lng bt nhm cn dng thu c 78 gam crom t Cr2O3 bng phn ng nhit nhm (gi s hiu sut phn ng l 100%) l A. 13,5 gam B. 27,0 gam. C. 54,0 gam. D. 40,5 gam

Dng 6: Bi tp tng hp
V d 28: Cho 100 gam hp kim gm c Fe, Cr v Al tc dng vi lng d dd NaOH thu c 6,72 lt kh (ktc). Ly phn rn khng tan cho tc dng vi lng d dd axit HCl (khi khng c khng kh) thu c 38,08 lt kh (ktc). %mAl; %mFe; %mAl ln lt l A. 86,8%; 7,8% v 5,4%. C. 20%; 30%; 50%. C. 40%; 30% v 30%. D. 7,8%; 5,4% v 86,8%.

Dng 7: Bi tp lin quan n luyn qung thnh gang

V d 29: Cho a tn qung manhetit cha 80% Fe3O4 c th sn xut c 800 tn gang c hm lng st 95%. Bit trong qu trnh sn xut, lng st b hao ht l 1%. Gi tr ca a l A. 1255 tn B. 1325,163 tn C. 1000 tn. D. 2000 tn V d 30: Y l mt loi qung manhetit cha 69,6% Fe3O4. Khi lng st ti a c th iu ch t 1 tn Y l A. 0,504 tn. B. 0,405 tn. C. 0,304 tn. D. 0,404 tn.