IN PHN

PHN 1: MT S DNG TON THNG GP DNG 1: IN PHN NNG CHY HP CHT CA KIM LOI Cu 1: in phn mui clorua nng chy ca kim loi kim R thu c 0,896 lt kh (ktc) anot v 3,12 gam kim loi R catot. R l: A. Li B. Na C. K D. Rb Cu 2: in phn nng chy Al2O3 trong 24 gi, vi cng dng in 100000A, hiu sut qu trnh in phn 90% s thu c lng Al l: A. 0,201 tn B. 0,603 tn C. 0,725 tn D. 0,895 tn DNG 2: IN PHN C H2O B KH HAY B OXH MT HAY C 2 IN CC. Cu 1: in phn (vi in cc tr) dung dch NaOH a% vi cng dng in 19,3A, sau 60 pht thu c 100 gam dung dch X c nng 24%. Gi tr a l: A. 22,54 B. 24 C. 25,66 D. 21,246 Cu 2: in phn 500 ml dung dch NaCl 1M (vi in cc tr, mng ngn xp) cho ti khi catot thot ra 0,56 lt kh X (ktc) th ngng in phn. Nu coi th tch dung dch sau in phn khng thay i so vi ban u th gi tr pH ca dung dch ny l: A. 7 B. 10 C. 12 D. 13 Cu 3: in phn 0,5 lt dung dch AgNO3 aM, vi I = 2A, sau t giy thy khi lng cactot thay i 2,16 gam, thu c dung dch X (khng to c kt ta vi dung dch NaCl) v gii phng V (ml) kh (ktc) anot. Gi tr a, t, V ln lt l: A. 0,04; 965; 112 C. 0,04; 1930; 125,7 B. 0,04; 1158; 112 D. 0,02; 965; 168 Cu 4: Tin hnh in phn hon ton 1 lt dung dch X cha Cu(NO 3)2 a(M) v AgNO3 b(M) thy khi lng catot tng 16,8 gam v gii phng 1,344 lt kh (ktc) bn anot. Gi tr a v b ln lt l: A. 0,04 v 0,08 B. 0,05 v 0,1 C. 0,06 v 0,12 D. 0,08 v 0,12 Cu 5: in phn (vi in cc tr, cng dng in 20A) 300ml dung dch CuSO 4 0,05M; sau 193 giy thu c V (ml) kh Y (ktc). Gi tr ca V l: A. 448 B. 336 C. 224 D. 168 DNG 3: BI TON IN PHN DUNG DCH TUY CHA NHIU ION KIM LOI NHNG CH 1 ION KIM LOI B KH Cu 1: in phn vi bnh in phn c mng ngn v in cc tr 1 dung dch c cha 23,4 gam NaCl v 27 gam CuCl2 ha tan. Sau 120 pht in phn (vi cng dng in 5,1A) th ngng in phn, ly dung dch sau in phn tc dng vi V (ml) dung dch HCl 1,2M th trung ha va . Gi tr V l A. 150 B. 240 C. 300 D. 360 Cu 2: in phn 100 ml dung dch X cha (Na2SO4, CuSO4, H2SO4) pH = 1, vi in cc tr, Sau mt thi gian in phn, ly in cc ra khi dung dch, thy khi lng dung dch gim 0,64 gam v dung dch c mu xanh nht, th tch coi nh khng i. Nng mol ion H+ c trong dung dch sau in phn l: A. 0,016 B. 0,026 C. 0,01 D. 0,02 DNG 4: IN PHN NHIU BNH IN PHN MC NI TIP Cu 1: Cho 2 bnh in phn mc ni tip. Bnh in phn 1 ha tan 0,3725 gam RCl (R l kim loi kim) trong nc. Bnh in phn 2 cha dung dch CuSO 4. Sau mt thi gian
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IN PHN
in phn thy catot bnh in phn 2 c 0,16 gam kim loi bm vo, cn bnh in phn 1 thy cha V (lt) dung dch mt cht tan pH = 13. Gi tr V A. 0,05 B. 0,075 C. 0,1 D. 0,01 Cu 2: Mc ni tip 2 bnh in phn. Bnh in phn 1 cha dung dch mui clorua ca kim loi R ha tr II, bnh in phn 2 cha dung dch AgNO3. Sau 3 pht 13 giy in phn th catot bnh in phn 1 thu c 1,6 gam kim loi; cn catot bnh in phn 2 thu c 5,4 gam kim loi. Bit sau in phn trong mi bnh vn cn dung dch mui. Kim loi R l: A. Mg B. Zn C. Ni D. Cu [Ti liu tham kho: Mt s kinh nghim v phng php gii ton trc nghim ha hc 12 phn V C Quan Hn Thnh]

PHN 2: THI CC NM
Cu 1: (C 2007) Trong cng nghip, natri hiroxit c sn xut bng phng php A. in phn dung dch NaNO3, khng c mng ngn in cc. B. in phn dung dch NaCl, c mng ngn in cc. C. in phn dung dch NaCl, khng c mng ngn in cc. D. in phn NaCl nng chy. Cu 2: (C 2007) Hai kim loi c th c iu ch bng phng php in phn dung dch l A. Mg v Zn. B. Na v Fe. C. Al v Mg. D. Cu v Ag Cu 3: (C 2010) in phn dung dch CuSO4 vi anot bng ng (anot tan) v in phn dung dch CuSO4 vi anot bng graphit (in cc tr) u c c im chung l A. catot xy ra s oxi ho: 2H2O + 2e 2OH + H2. B. anot xy ra s kh: 2H2O O2 + 4H+ + 4e. C. anot xy ra s oxi ho: Cu2+ + 2e. Cu D. catot xy ra s kh: Cu2+ + 2e Cu. Cu 4: (C 2011) in phn 500 ml dung dch CuSO4 O,2M (in cc tr) cho n khi catot thu
c 3,2 gam kim loi th th tch kh (ktc) thu c anot l: A. 3,36 lt B. 1,12 lt C. 0,56 lt D. 2,24 lt

Cu 5: (C 2012) Tin hnh in phn (vi in cc tr) V lt dung dch CuCl2 0,5M. Khi dng in phn thu c dung dch X v 1,68 lt kh Cl2 (ktc) duy nht anot. Ton b dung dch X tc dng va vi 12,6 gam Fe. Gi tr ca V l A. 0,60. B. 0,15. C. 0,45. D. 0,80. Cu 6: (HKA 2007)in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,32 gam Cu catt v mt lng kh X ant. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH ( nhit thng). Sau phn ng, nng NaOH cn li l 0,05M (gi thit th tch dung dch khng thay i). Nng ban u ca dung dch NaOH l (cho Cu = 64) A. 0,15M. B. 0,2M. C. 0,1M. D. 0,05M. Cu 7: (HKA 2008)Khi in phn NaCl nng chy (in cc tr), ti catt xy ra A. s kh ion Cl-. B. s oxi ho ion Cl-. C. s oxi ho ion Na+. D. s kh ion Na+. Cu 8:( HKA 2009) Dy cc kim loi u c th c iu ch bng phng php in phn dung dch mui ca chng l:
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IN PHN
A. Fe, Cu, Ag. B. Mg, Zn, Cu. C. Al, Fe, Cr. D. Ba, Ag, Au.

Cu 9: (HKA 2010) Phn ng in phn dung dch CuCl2 (vi in cc tr) v phn ng n mn in ho xy ra khi nhng hp kim Zn-Cu vo dung dch HCl c c im l: A. Phn ng cc m c s tham gia ca kim loi hoc ion kim loi. B. Phn ng xy ra lun km theo s pht sinh dng in. C. u sinh ra Cu cc m. D. Phn ng cc dng u l s oxi ho Cl. Cu 10: (HKA 2010) in phn (vi in cc tr) mt dung dch gm NaCl v CuSO4 c cng s mol, n khi catot xut hin bt kh th dng in phn. Trong c qu trnh in phn trn, sn phm thu c anot l A. kh Cl2 v H2. B. kh Cl2 v O2. C. kh H2 v O2. D. ch c kh Cl2. Cu 11: (HKA 2010) in phn (in cc tr) dung dch X cha 0,2 mol CuSO4 v 0,12 mol NaCl bng dng in c cng 2A. Th tch kh (ktc) thot ra anot sau 9650 giy in phn l A. 1,792 lt. B. 2,240 lt. C. 2,912 lt. D. 1,344 lt. Cu 12: (HKA 2011) in phn dung dch gm 7,45 gam KCl v 28,2 gam Cu(NO3)2 (in cc tr, mng ngn xp) n khi khi lng dung dch gim i 10,75 gam th ngng in phn (gi thit lng nc bay hi khng ng k). Tt c cc cht tan trong dung dch sau in phn l A. KNO3, HNO3 v Cu(NO3)2. C. KNO3 v Cu(NO3)2. B. KNO3, KCl v KOH. D. KNO3 v KOH.

Cu 13: (HKA 2011) Ho tan 13,68 gam mui MSO4 vo nc c dung dch X. in phn X (vi in cc tr, cng dng in khng i) trong thi gian t giy, c y gam kim loi M duy nht catot v 0,035 mol kh anot. Cn nu thi gian in phn l 2t giy th tng s mol kh thu c c hai in cc l 0,1245 mol. Gi tr ca y l A. 4,788. B. 4,480. C. 1,680. D. 3,920. Cu 14: (HKA 2011) Khi in phn dung dch NaCl (cc m bng st, cc dng bng than ch, c mng ngn xp) th: A. cc m xy ra qu trnh oxi ho H2O v cc dng xy ra qu trnh kh ion Cl. B. cc dng xy ra qu trnh oxi ho ion Na+ v cc m xy ra qu trnh kh ion Cl . C. cc m xy ra qu trnh kh H2O v cc dng xy ra qu trnh oxi ho ion Cl. D. cc m xy ra qu trnh kh ion Na+ v cc dng xy ra qu trnh oxi ho ion Cl. Cu 15: (HKA 2012) in phn 150 ml dung dch AgNO3 1M vi in cc tr trong t gi, cng dng in khng i 2,68A (hiu sut qu trnh in phn l 100%), thu c cht rn X, dung dch Y v kh Z. Cho 12,6 gam Fe vo Y, sau khi cc phn ng kt thc thu c 14,5 gam hn hp kim loi v kh NO (sn phm kh duy nht ca N+5). Gi tr ca t l

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IN PHN
A. 0.8. B. 0,3. C. 1,0. D. 1,2.

Cu 16: (HKA 2012) Dy cc kim loi u c th c iu ch bng phng php in phn dung dch mui (vi in cc tr) l: A. Ni, Cu, Ag. B. Li, Ag, Sn. C. Ca, Zn, Cu. D. Al, Fe, Cr.

Cu 17: (HKB 2007) in phn dung dch cha a mol CuSO4 v b mol NaCl (vi in cc tr, c mng ngn xp). dung dch sau in phn lm phenolphtalein chuyn sang mu hng th iu kin ca a v b l (bit ion SO42- khng b in phn trong dung dch)
A. b > 2a.

B. b = 2a.

C. b < 2a.

D. 2b = a.

Cu 18: (HKB 2009) in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl2 0,1M v NaCl 0,5M (in cc tr, hiu sut in phn 100%) vi cng dng in 5A trong 3860 giy. Dung dch thu c sau in phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l
A. 4,05.

B. 2,70.

C. 1,35.

D. 5,40.

Cu 19: (HKB 2009) in phn nng chy Al2O3 vi anot than ch (hiu sut in phn 100%) thu c m kg Al catot v 67,2 m3 ( ktc) hn hp kh X c t khi so vi hiro bng 16. Ly 2,24 lt ( ktc) hn hp kh X sc vo dung dch nc vi trong (d) thu c 2 gam kt ta. Gi tr ca m l
A. 108,0.

B. 75,6.

C. 54,0.

D. 67,5.

Cu 20: (HKB 2010) in phn (vi in cc tr) 200 ml dung dch CuSO4 nng x mol/l, sau mt thi gian thu c dung dch Y vn cn mu xanh, c khi lng gim 8 gam so vi dung dch ban u. Cho 16,8 gam bt st vo Y, sau khi cc phn ng xy ra hon ton, thu c 12,4 gam kim loi. Gi tr ca x l
A. 1,50.

B. 3,25.

C. 2,25.

D. 1,25.

Cu 21: (HKB 2012) in phn dung dch hn hp gm 0,1 mol FeCl3, 0,2 mol CuCl2 v 0,1 mol HCl (in cc tr). Khi catot bt u thot kh th anot thu c V lt kh (ktc). Bit hiu sut ca qu trnh in phn l 100%. Gi tr ca V l:
A. 5,60.

B. 11,20.

C. 22,40.

D. 4,48.

Ngi son: Ti polime