B GD & T

GII THI TUYN SINH I HC 2009

Mn thi : HO, khi B - M : 637

Cho bit khi lng nguyn t (theo vC) ca cc nguyn t :

H = 1; C = 12; N = 14; O = 16; F = 19 ; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5;
K = 39; Ca = 40; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108 ; I = 127 ; Ba = 137 ;
Au = 197
PHN CHUNG CHO TT C TH SINH: (40 cu, t cu 1 n cu 40)
Cu 1 : Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO 3)2 0,2M v H2SO4 0,25M. Sau khi
cc phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh
duy nht, ktc). Gi tr ca m v V ln lt l
A. 17,8 v 4,48.
B. 17,8 v 2,24.
C. 10,8 v 4,48.
D. 10,8 v 2,24.
-nCu2+ = 0,16; nNO3- = 0,32 ; nH+ = 0,4. Kim loi d mui Fe2+
3Fe + 2NO3- + 8H+ 3Fe2+ + 2NO + 4H2O (1)
Fe + Cu2+ Fe2+ + Cu (2)
0,15 ----0,4 ------------ 0,1
0,16 0,16 ------- 0,16
m 0,15.56 (1) + mtng(2) = 0,6m m = 17,8 g v V = 0,1.22,4 = 2,24 lt

p n B

Cu 2: C cc th nghim sau:
(I) Nhng thanh st vo dung dch H2SO4 long, ngui.
(II) Sc kh SO2 vo nc brom.
(III) Sc kh CO2 vo nc Gia-ven.
(IV) Nhng l nhm vo dung dch H2SO4 c, ngui.
S th nghim xy ra phn ng ha hc l
A. 4.
B. 3.
C. 1.

-(IV) khng xy ra (Al th ng trong dd H2SO4 c, ngui.)

D. 2.

p n B

Cu 3: Dy gm cc cht u c kh nng tham gia phn ng trng hp l:

A. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua.
B. buta-1,3-ien; cumen; etilen; trans-but-2-en.
C. stiren; clobenzen; isopren; but-1-en.
D. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen.

-Monome phi c lin kt bi : A. CF2=CF2, CH2=CH-CH3, C6H5CH=CH2, CH2=CH-Cl

p n A

Cu 4: t chy hon ton mt hp cht hu c X, thu c 0,351 gam H2O v 0,4368 lt kh CO2 (
ktc). Bit X c phn ng vi Cu(OH)2 trong mi trng kim khi un nng. Cht X l
A. CH3COCH3.
B. O=CH-CH=O.
C. CH2=CH-CH2-OH.
D. C2H5CHO.
-nCO2 = nH2O = 0,197. X tc dng vi Cu(OH)2,t0 andehit no n chc

p n D

Cu 5: Cho cc nguyn t: K (Z = 19), N (Z = 7), Si (Z = 14), Mg (Z = 12). Dy gm cc nguyn t c

sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l:
A. N, Si, Mg, K.
B. Mg, K, Si, N.
C. K, Mg, N, Si.
D. K, Mg, Si, N.
-Th t bn knh nguyn t gim nhm IA>IIA>IIA>IVA>VA...
Vy, K(IA)>Mg(IIA)>Si(IVA)>N(VA)

p n D

Cu 6: Pht biu no sau y l ng?

A. Trng hp stiren thu c poli (phenol-fomanehit).
B. Trng ngng buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N.
C. Poli (etylen terephtalat) c iu ch bng phn ng trng ngng cc monome tng ng.
D. T visco l t tng hp.
-P: nHOCH2-CH2OH + nHOOCC6H4COOH [-CH2-CH2OOC-C6H4-COO-]n + 2nH2O

p n C

Cu 7: Cho 61,2 gam hn hp X gm Cu v Fe3O4 tc dng vi dung dch HNO3 long, un nng v
khuy u. Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht,
ktc), dung dch Y v cn li 2,4 gam kim loi. C cn dung dch Y, thu c m gam mui khan. Gi tr
ca m l
A. 151,5.
B. 97,5.
C. 137,1.
D. 108,9.
Kim loi cn li l Cu vy to mui Fe2+

GV: Nguyn Kim Chin

-Nhn: N+5 + 3e N+2 v Fe3O4 + 2e 3Fe2+ . cho: Cu Cu2+ + 2e

0,450,15
y -- 2y
3y
x-------- 2x
64x + 232y = 61, 32 - 2,4 x = 0, 375

y = 0,15 m = 0,375.188 + 0,15.3.180 = 151,5 (g)

2x = 2y + 0,45

p n A

Cu 8: Khi nhit phn hon ton tng mui X, Y th u to ra s mol kh nh hn s mol mui tng
ng. t mt lng nh tinh th Y trn n kh khng mu, thy ngn la c mu vng. Hai mui X, Y
ln lt l:
A. KMnO4, NaNO3. B. Cu(NO3)2, NaNO3. C. CaCO3, NaNO3. D. NaNO3, KNO3.
-n

Kh

<n

X v Y

loi B v C. Y t0 to la vng mui ca Na. Vy, A

p n A

Cu 9: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X
thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc). t chy
hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z
trong hn hp X ln lt l
A. HOOC-CH2-COOH v 70,87%.
B. HOOC-COOH v 60,00%.
C. HOOC-CH2-COOH v 54,88%.
D. HOOC-COOH v 42,86%.
- RCOOH + Na RCOONa + H2 ;
R(COOH)2 + 2Na R(COONa)2 + H2
X
x/2
y
y
nH2 = x/2+y = 0,02(1) , nCO2 = nx + ny = 0,06 (2) 1,5 <n < 3. Vy n = 2 (CH3COOH v HOOC-COOH)
0,1.90
.100 = 42, 86(%)
Thay vo (1), (2) x = 0,02 , y = 0,01 %HOOC - COOH =
0,1.90 + 0,2.60

p n D

Cu 10: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l:

A. CH3CHO, C2H5OH, HCOOH, CH3COOH.
B. CH3COOH, HCOOH, C2H5OH, CH3CHO.
C. HCOOH, CH3COOH, C2H5OH, CH3CHO
D. CH3COOH, C2H5OH, HCOOH, CH3CHO.
t0si : CH3CHO < C2H5OH < HCOOH < CH3COOH.

p n A

Cu 11: Cho dung dch cha 6,03 gam hn hp gm hai mui NaX v NaY (X, Y l hai nguyn t c
trong t nhin, hai chu k lin tip thuc nhm VIIA, s hiu nguyn t ZX < ZY) vo dung dch AgNO3
(d), thu c 8,61 gam kt ta. Phn trm khi lng ca NaX trong hn hp ban u l
A. 58,2%.
B. 52,8%.
C. 41,8%.
D. 47,2%.
gi s mi Ag ca X v Y u kt ta. NaX + AgNO3 NaNO3 + AgX
(23+X)a
(108+X)a m tng = 85a=8,61- 6,06
6,03
- 23 = 178 9. Khng tho mn c NaF (AgF khng kt ta) cn li NaCl
a = 0,03 . M X ,Y =
0,03...
6, 03 - 0,06.58,5
.100 = 41, 8(%)
nNaCl = NAgCl = 0,06 %NaF =
6, 03

p n C

Cu 12: Ha tan hon ton 20,88 gam mt oxit st bng dung dch H2SO4 c, nng thu c dung dch
X v 3,248 lt kh SO2 (sn phm kh duy nht, ktc). C cn dung dch X, thu c m gam mui
sunfat khan. Gi tr ca m l
A. 52,2.
B. 48,4.
C. 54,0.
D. 58,0.
Qui FexOy thnh Fe v O : Cho : Fe 3e Fe3+ . Nhn: O + 2e O2- v S+6 + 2e S+4. nSO2 = 0,145(mol)
X
3x x
y
2y
0,29<--0,145
56x + 16y = 20,88 x = 0,29

3x = 2y + 0,29 y = 0,29 mMui [Fe2(SO4)3 ] = .0,29.400 = 58 (g)

p n D

Cu 13: Cho cc phn ng ha hc sau:

(1) (NH4)2SO4 + BaCl2
(2) CuSO4 + Ba(NO3)2
(3) Na2SO4 + BaCl2
(4) H2SO4 + BaSO3
(5) (NH4)2SO4 + Ba(OH)2
(6) Fe2(SO4)3 + Ba(NO3)2
Cc phn ng u c cng mt phng trnh ion thu gn l:
A. (1), (2), (3), (6).
B. (3), (4), (5), (6).
C. (2), (3), (4), (6).
D. (1), (3), (5), (6).
GV: Nguyn Kim Chin

 1,2,3,6 c cng pt ion thu gn l: SO42- + Ba2+ BaSO4

p n A

Cu 14: Ha tan m gam hn hp gm Al, Fe vo dung dch H2SO4 long (d). Sau khi cc phn ng xy
ra hon ton, thu c dung dch X. Cho dung dch Ba(OH)2 (d) vo dung dch X, thu c kt ta Y.
Nung Y trong khng kh n khi lng khng i, thu c cht rn Z l
A. hn hp gm Al2O3 v Fe2O3.
B. hn hp gm BaSO4 v FeO.
C. hn hp gm BaSO4 v Fe2O3.
D. Fe2O3.
Fe
FeSO4
FeOH
(
)2
FeOH
( )3
+H 2SO4
+Ba( OH)2, du
+O2 +H2 O, 0t

t0

FeO

2 3, BaSO4
Al (OH )3 ,tan
Al
Al2(SO4)3
BaSO 4
BaSO 4

p n C

Cu 15: Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam
mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l
A. (H2N)2C3H5COOH.B. H2NC2C2H3(COOH)2.
C. H2NC3H6COOH.
D. H2NC3H5(COOH)2.
nHCl=nX = 0,02, nNaOH = 2nX c 1nhm -NH2 v 2 nhm COOH
(HOOC)2RNH2 + HCl (HOOC)2RNH3Cl
0,02

0,02

mui

= 45.2 + R + 52,5 =

V y X l:(HOOC)2C3H5NH2

3,67
= 183,5 R = 41 (C3H5)
0,02

p n D

Cu 16: Cho 2,24 gam bt st vo 200 ml dung dch cha hn hp gm AgNO 3 0,1M v Cu(NO3)2 0,5M.
Sau khi cc phn ng xy ra hon ton, thu c dung dch X v m gam cht rn Y. Gi tr ca m l
A. 2,80.
B. 4,08.
C. 2,16.
D. 0,64.
nFe = 0,04 ; nCu2+ = 0,1 ; nAg+ = 0,02 . Fe + 2Ag+ Fe2+ + 2Ag
0,01 0,02 ------ 0,02
m= 0,02.108 + 0,03.64 = 4,08 (g)

Fe + Cu2+ Fe2+ + Cu
(0,04-0,01)
----------- 0,03

p n B

Cu 17: Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc
nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H 2 ( ktc). Cng thc
cu to thu gn ca X l
A. CH3-C6H3(OH)2.
B. HO-C6H4-COOCH3.
C. HO-CH2-C6H4-OH.
D. HO-C6H4-COOH.
nA = nNaOH, nH2 = nA . c 1nhm OH khng linh ng v 1 nhm OH linh ng (-OH g n tr c ti p v i vng
th m) ho c COOH.

p n C

Cu 18: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T

khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c
hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca
anken l
A. CH3-CH=CH-CH3.
B. CH2=CH-CH2-CH3.
C. CH2=C(CH3)2.
D. CH2=CH2.
Gi s hhX c 1mol, s mol CnH2n+2(x) v H2(1-x). Sau ph n ng kh i l ng h n h p khng i: 14nx + 2(1-x).
CnH2n + H2
CnH2n+2 .
Tr
c
x
1-x
0
tng: 1 (mol)
Phn ng
x
x
x
Sau
0
1-2x
x
tng : 1 - 2x + 2= 1-x (mol)

14nx + 2(1- x) = 9,1.2 x = 0,3

14nx + 2(1- x) = 13.2(1- x) n = 4

Xc c u t o d i x ng (c ng Br2 t o 1 s n ph m). V y CTCT CH3CH=CHCH3

p n A

Cu 19: Th nghim no sau y c kt ta sau phn ng?

A. Cho dung dch NaOH n d vo dung dch Cr(NO3)3.
B. Cho dung dch HCl n d vo dung dch NaAlO2 (hoc Na[Al(OH)4]).
C. Thi CO2 n d vo dung dch Ca(OH)2.
D. Cho dung dch NH3 n d vo dung dch AlCl3.

ch: AlCl3 + 3NH3 + 3H2O Al(OH)3 + 3NH4Cl. Al(OH)3 khng tan trong dd NH3 d

GV: Nguyn Kim Chin

p n D

Cu 20: Cho mt s tnh cht: c dng si (1); tan trong nc (2); tan trong nc Svayde (3); phn ng
vi axit nitric c (xc tc axit sunfuric c) (4); tham gia phn ng trng bc (5); b thu phn trong
dung dch axit un nng (6). Cc tnh cht ca xenluloz l:
A. (3), (4), (5) v (6) B. (1), (3), (4) v (6)
C. (2), (3), (4) v (5) D. (1,), (2), (3) v (4).
Tnh cht Xenlulozl (1), (3), (4), (6). (xem li SGK 12)

p n B

Cu 21: Cho cc hp cht sau :

(a) HOCH2-CH2OH
(b) HOCH2-CH2-CH2OH
(c) HOCH2-CH(OH)-CH2OH
(d) CH3-CH(OH)-CH2OH
(e) CH3-CH2OH
(f) CH3-O-CH2CH3
Cc cht u tc dng c vi Na, Cu(OH)2 l
A. (c), (d), (f)
B. (a), (b), (c)
C. (a), (c), (d)
D. (c), (d), (e)
Tc d
ng v
i Na v Cu(OH)2 C t nht 2 Nhm OH cnh nhau (hoc COOH).

p n C

Cu 22: S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l

A. 2

B. 3

C. 4

D. 1

Cc dipeptit l: Ala-ala; ala-gli; gli-ala; gli-gli.

p n C

Cu 23: Cho cc phn ng sau :

(a) 4HCl + PbO2 PbCl2 + Cl2 + 2H2O
(b) HCl + NH4HCO3 NH4Cl + CO2 + H2O
(c) 2HCl + 2HNO3 2NO3 + Cl2 + 2H2O
(d) 2HCl + Zn ZnCl2 + H2
S phn ng trong HCl th hin tnh kh l
A. 2
B. 4
C. 1
D. 3
(a), (c) c 2Cl- Cl2 + 2e( cht kh)

p n A

Cu 24: Cho hai hp cht hu c X, Y c cng cng thc phn t l C 3H7NO2 . Khi phn ng vi dung
dch NaOH, X to ra H2NCH2COONa v cht hu c Z ; cn Y to ra CH2=CHCOONa v kh T. Cc
cht Z v T ln lt l
A. CH3OH v CH3NH2
B. C2H5OH v N2
C. CH3OH v NH3
D. CH3NH2 v NH3
C3H7NO2 + NaOH H2NCH2COONa + CH3OH ;
t)
(X)
(Z)

C3H7NO2 + NaOH CH2=CHCOONa + NH3 (bo ton nguyn

(Y)

(T)

p n C

Cu 25: Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn
ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c
dung dch Y, cht rn Z v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam
kt ta. Gi tr ca m l
A. 48,3
B. 57,0
C. 45,6
D. 36,7
8Al + 3Fe3O4 9Fe + 4Al2O3 . Tc dng vi NaOH to kh Al d.
2x
3/4x
x
Al + NaOH + H2O NaAlO2 + 3/2H2 ; Al2O3 + 2NaOH 2NaAlO2 + H2O; CO2 + 2H2O + NaAlO2 Al(OH)3 + NaHCO3
0,1
0,1
0,15
x
2x
0,5
2x + 0,1 = 0,5 ; x=0,2. m = .0,2.232 + (2.0,2+0,1).27 = 48,3 (g)

p n A

Cu 26: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d)
th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng
vi lng d dung dch AgNO3 trong NH3 , thu c 36 gam kt ta. Phn trm th tch ca CH 4 c
trong X l:
A. 40%
B. 20%
C. 25%
D. 50%
C2H2 + 2Br2 C2H2Br4 ;C2H4 + Br2 C2H4Br2 ; C2H2 + 2AgNO3 + 2NH3 C2 Ag2 + 2NH4NO3
c
2c
b
b
c
c
nhhX = 0,6 ; nC2H2 = 36 : 240 = 0,15 nhh X = 4.nC2H2 hay: a + b + c = 4c(1) ; 16a + 28b + 26c = 8,6 (2) ; b + 2c = 0,3 (3)
Gi i h (1),(2),(3) ta c: a = 0,2 ; b = 0,1 ; c = 0,1 %VCH4 = 50 (%)

p n D

GV: Nguyn Kim Chin

Cu 27: Cho cht xc tc MnO2 vo 100 ml dung dch H2O2, sau 60 giy thu c 33,6 ml kh O2 (
ktc) . Tc trung bnh ca phn ng (tnh theo H2O2) trong 60 giy trn l
A. 2,5.10-4 mol/(l.s)
B. 5,0.10-4 mol/(l.s)
C. 1,0.10-3 mol/(l.s)
D. 5,0.10-5 mol/(l.s)
H2O2 H2O + O2. nH 2O2 = 2nO2 =

p n B

2.33,6
DC
3.10- 2
= 3, 0.10- 4 ; D CH2O2 = 3.10- 2 ; v =
=
= 5.10- 4 (mol / l.s)
1000.22.4
Dt
60

Cu 28: Trn 100 ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100 ml dung dch hn hp
gm NaOH 0,2M v Ba(OH)2 0,1M thu c dung dch X. Dung dch X c pH l
A. 1,2
B. 1,0
C. 12,8
D. 13,0
nH+ = 0,1(2CMH2SO4 + CMHCl )= 0,02; nNaOH = 0,1[CMNaOH + 2CMBa(OH)2] = 0,04.
H+ + OH- H2O d 0,02 mol OH-. [OH-] = 0,02/(0,1+0,1) = 0,1 = 10-1. [H+] = 10-13. pH = 13

p n D

Cu 29: in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl2 0,1M v NaCl 0,5M (in
cc tr, hiu sut in phn 100%) vi cng dng in 5A trong 3860 giy. Dung dch thu c sau
in phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l
A. 4,05
B. 2,70
C. 1,35
D. 5,40
mCl2 =

35,5.5.3860
= 7,1( g) ng vi nCl2 = 0,1 (mol); nCuCl2 = 0,05; nNaCl = 0,25
96500.1

dpdd
dpdd
CuCl2
Cu + Cl2 ; 2NaCl + 2H2O
2NaOH + H2 + Cl2 ;
0,05 ---------------- 0,05
0,1 -------------------- 0,1 --0,05
mAlmax = 0,1.27= 2,7 (g)

Al + NaOH + H2O NaAlO2 + 3/2H2

0,1 0,1

p n B

Cu 30: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch
KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn
hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH) 2 (d) th khi lng
bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l
A. HCOOH v HCOOC2H5
B. CH3COOH v CH3COOC2H5
C. C2H5COOH v C2H5COOCH3
D. HCOOH v HCOOC3H7
n X = nNaOH = 0,04; nancol = 0,015< nX. 1 axit v 1 este ca axit . C n H2 n O2 n CO2 + n H2O, 44x+18x =6,82.
x= 0,11. n = nCO2/nX = 2,75 ; n.(0,04-0,015) +m.0,015 = 2,75.0,04 ; n= 2 (CH3COOH) v m = 4(CH3COOC2H5)

p n B

Cu 31: Cho cc hp cht hu c :

(1) ankan;
(2) ancol no, n chc, mch h;
(3) xicloankan;
(4) ete no, n chc, mch h;
(5) anken;
(6) ancol khng no (c mt lin kt i C=C), mch h
(7) ankin;
(8) anehit no, n chc, mch h;
(9) axit no, n chc, mch h (10) axit khng no (c mt lin kt i C=C), n chc
Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l :
A. (3), (5), (6), (8), (9)
B. (3), (4), (6), (7), (10)
C. (2), (3), (5), (7), (9)
D. (1), (3), (5), (6), (8)
nCO2 = NH2O CT chung hp cht CnH2nOx...C (3),(5),(6),(8),(9) tho mn.

p n A

Cu 32: in phn nng chy Al2O3 vi anot than ch (hiu sut in phn 100%) thu c m kg Al
catot v 67,2 m3 ( ktc) hn hp kh X c t khi so vi hiro bng 16. Ly 2,24 lt ( ktc) hn hp kh
X sc vo dung dch nc vi trong (d) thu c 2 gam kt ta. Gi tr ca m l
A. 54,0
B. 75,6
C. 67,5
D. 108,0
dpnc
dpnc
dpnc
2Al2O3 + 3C
4Al + 3CO2 ; Al2O3 + C
2Al + 3CO ; 2Al2O3
4Al + 3O2 ; nX = 3 (Kmol)
4/3x x
2/3y
y
4/3z
z

Trong 2,24lit X nCO2= 0,02; nCO= 0,08; Nu X ch c CO v CO2 th M X =

0,02.44 + 0,08.28
= 31,2 16*2 vy X c O2
0,1

Trong X nCO2 = 0.02.3/0,1 = 0,6(Kmol)

x = 0,6
x +y +z = 3

y = 1,8
x = 0.6

. Vy m = 27.(4/3.0,6 +2/3.1,8 +4/3.0,6) = 75,56 (g)

44x + 28y + 32z

z = 0,6

= 16.2
3

p n B

GV: Nguyn Kim Chin

Cu 33: Khi nhit phn hon ton 100 gam mi cht sau : KClO3 (xc tc MnO2), KMnO4, KNO3 v
AgNO3. Cht to ra lng O2 ln nht l
A. KNO3
B. AgNO3

C. KMnO4

D. KClO3

nKNO3 = 100/101; n AgNO3 = 100/170 ; nKMnO4 = 100/142 ; nKClO3 = 100/122,5

KNO3 O2 ;
AgNO3 O2 ;
KMnO4 3/4 O2 ;
KClO3 O2(*)
100/(2.101)
100/(2.170)
(100.3)/(4.142)
100/122,5 (ln nht)

p n D

Cu 34: Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va
3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH, thu
c mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l
A. C2H4O2 v C3H6O2
B. C3H4O2 v C4H6O2
C. C3H6O2 v C4H8O2
D. C2H4O2 v C5H10O2
Thu phn to 1 mui v 2 ancol lin tip 2 este no n chc mch h l ng ng k tip
CnH2nO2 + 1/2(3n-2) O2 nCO2 + nH2O
0,1775
0,145
0,1774n = .(3n-2).0,145 n=3,625 (C3H6O2 v C4H8O2)

p n C

Cu 35: Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng

bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca X
v Y tng ng l
A. HO-CH2-CH2-CHO v HO-CH2-CH2-CH2-CHO
B. HO-CH(CH3)-CHO v HOOC-CH2-CHO
C. HO-CH2-CHO v HO-CH2-CH2-CHO
D. HCOOCH3 v HCOOCH2-CH3
Th: loi B( khc dy ), loi D(khng tc dng vi Na). Cc cht trn u c CT chung CnH2nO2

32
53,33
32
43,24
=
n = 2;%OY =
=
m=3
14n + 32
100
14m + 32
100
p n C
%OX =

Cu 36: Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO 3
trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O 2 (cng iu kin v nhit
v p sut). Khi t chy hon ton 1 gam X th th tch kh CO2 thu c vt qu 0,7 lt ( ktc).
Cng thc cu to ca X l
A. CH3COOCH3
B. O=CH-CH2-CH2OH C. HOOC-CHO
D. HCOOC2H5
Loi A (khng tc dng vi AgNO3/NH3),loi B khn tc dng vi NaOH. C nX = no2 . MX = 37/no2 = 74. CaHbOc
t X: nX = 1/74 ; nco2 0,7/22,4 a nco2/nX = 2,3215 . Vy X l HCOOC2H5

p n D

Cu 37: Thc hin cc th nghim sau :

(I) Cho dung dch NaCl vo dung dch KOH.
(II) Cho dung dch Na2CO3 vo dung dch Ca(OH)2
(III) in phn dung dch NaCl vi in cc tr, c mng ngn
(IV) Cho Cu(OH)2 vo dung dch NaNO3
(V) Sc kh NH3 vo dung dch Na2CO3.
(VI) Cho dung dch Na2SO4 vo dung dch Ba(OH)2.
Cc th nghim u iu ch c NaOH l:
A. II, V v VI
B. II, III v VI
C. I, II v III

D. I, IV v V

iu ch NaOH t (II),(III),(VI)

p n B

Cu 38: Ho tan hon ton 2,9 gam hn hp gm kim loi M v oxit ca n vo nc, thu c 500 ml
dung dch cha mt cht tan c nng 0,04M v 0,224 lt kh H2 ( ktc). Kim loi M l
A. Ca
B. Ba
C. K
D. Na
M + nH2O M(OH)n + n/2H2 ; M2On + nH2O 2M(OH)n ; M Mn+ + ne; O + 2e O2-; 2H+ + 2e H2
x
nx y
2y
0,02 0,01
Mx + 16y = 2,9(1)

2,9 - 16(0, 02n - 0,02) 3, 06 - 0,16n

=
x = nM (OH )n = 0,02(2) M =
; n = 2 M =137 (Ba)

2.0,02
0,02
nx = 2y + 0,02(3)

p n B

GV: Nguyn Kim Chin

Cu 39: Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi
NaHCO3 th u sinh ra a mol kh. Cht X l
A. etylen glicol
C. axit 3-hiroxipropanoic

B. axit aipic
D. ancol o-hiroxibenzylic

Tc dng vi NaHCO3 l axit: R(COOH)n + nNaHCO3 ...+ nCO2 + ... C nX = nCO2 1nhm COOH.
Tc dng vi Na nX = nH2 c thm 1 nhm OH. (axit 3-hidroxipropanoic: HO-CH2-CH2-COOH tho mn)
A.HOCH2-CH2OH v D.o- HO-C6H4-CH2OH khng td NaHCO3; B.HOOC-(CH2)4-COOH td vi NaHCO3 -2a mol CO2.

p n C

Cu 40: Pht biu no sau y l ng?

A. Nc thuc loi tinh th phn t.
B. th rn, NaCl tn ti di dng tinh th phn t
C. Photpho trng c cu trc tinh th nguyn t
D. Kim cng c cu trc tinh th phn t.
NaCl tinh th ion ; P trng tinh th phn t; kim cng tinh th nguyn t.

p n A

II. PHN RING: [10 cu]

Th sinh ch c chn lm mt trong hai phn (phn A hoc B)
A. Theo chng trnh Chun: (10 cu, t cu 41 n cu 50)
Cu 41: Pht biu no sau y l ng ?
A. Glucoz b kh bi dung dch AgNO3 trong NH3
B. Xenluloz c cu trc mch phn nhnh
C. Amilopectin c cu trc mch phn nhnh
D. Saccaroz lm mt mu nc brom.
Amilopectin : mch phn nhnh. Amiloz: mch thng.

p n C

Cu 42: Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm Cu(NO 3)2 0,2M v
AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi thit
cc kim loi to thnh u bm ht vo thanh st). Khi lng st phn ng l
A. 2,16 gam
B. 0,84 gam
C. 1,72 gam
D. 1,40 gam
nCu(NO3)2=0,02 ; nAgNO3= 0,02. st dFe2+ . mtng = 101,72-100 = 1,72 (g)
Fe + 2AgNO3 Fe(NO3)2 + 2Ag (1) ; Fe + Cu(NO3)2 Cu + Fe(NO3)2 (2). T (1) mtng = 0,02.108-0,01.56 = 1,6(g)
0,010,02
0,01
tng do (2) l: 0,12 = 64x 56x ; x= 0,015 ; m = 0,01.56+0,015.56 = 1,4 (g)

p n D

Cu 43: Hir ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau
trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m
gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l
A. 10,5
B. 17,8
C. 8,8
D. 24,8
CnH2nO + H2 CnH2n+1OH : c (14n + 18)x (14n + 16)x = m+1-m 2x = 1 ; x = 0,5 mol
CnH2nO + (3n-1)O2 nCO2 + nH2O
1
(1,5n+0,5)
0,5
0,8
0,5(1,5n+0,5) = 0,8.1 n = 1,4 m = (14n+16)0,5 = 17,8 (g)

p n B

Cu 44: Cho 100 ml dung dch KOH 1,5M vo 200 ml dung dch H 3PO4 0,5M, thu c dung dch X.
C cn dung dch X, thu c hn hp gm cc cht l
A. K3PO4 v KOH
B. KH2PO4 v K3PO4
C. KH2PO4 v H3PO4
D. KH2PO4 v K2HPO4
nK OH

nKOH = 0,15. nH3PO4 = 0,1. Vy: 1 < n

H 3PO4

< 2 to NaH2PO4 v Na2HPO4

p n D

Cu 45: ng dng no sau y khng phi ca ozon?

A. Cha su rng
C. iu ch oxi trong phng th nghim

B. Ty trng tinh bt, du n

D. St trng nc sinh hot

A,B,D l ng dng ca ozon

p n C

GV: Nguyn Kim Chin

Cu 46: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht
hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c
khc nhau. Tn gi ca X l
A. but-1-en
B. but-2-en
C. propilen
D. Xiclopropan
2.80
74,08
=
;n = 4 ; Khi tc dng vi HBr to nhiu sn phm X c cu
C 1 lin kt pi CnH2n %Br =
14n + 2.80
100
tao bt i xng : But-1-en

p n A

Cu 47: Cho s chuyn ho gia cc hp cht ca crom :

+ (Cl 2 + KOH)
+ H 2SO4
+ (FeSO4 + H 2SO 4 )
+ KOH
Cr(OH)3
X
Y
Z
T
Cc cht X, Y, Z, T theo th t l:
A. KCrO2; K2CrO4; K2Cr2O7; Cr2(SO4)3
B. K2CrO4; KCrO2; K2Cr2O7; Cr2(SO4)3
C. KCrO2; K2Cr2O7; K2CrO4; CrSO4
D. KCrO2; K2Cr2O7; K2CrO4; Cr2(SO4)3
+ ( Cl2 +KOH )
( FeSO4 H+2 SO4 )
+ KOH

4 (Y )H2 SO+4 K2 Cr

+ (Cr

(SO
Vit li chui : Cr(OH 3) KCrO2 (X ) KCrO
2 O
7 (Z)
2
4
3

p n A

Cu 48: Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi
hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH
1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l:
A. 29,75
B. 27,75
C. 26,25
D. 24,25
(NH2 )mR(COOR)n =103 . MROH >32 (ROH khc CH3OH)m= n = 1; R l -C2H5 V y CTCT X l NH2-CH2COOC2H5
nNaOH =0,3. n X = 0,25 d 0,05 mol NaOH
NH2CH2COOC2H5 + NaOH NH2CH2COONa + C2H5OH;
0,25
0,25
0,25
0,25
m = mX + mNaOH mc2H5oH = 25,75 + 0,3.40 - 0,25.46 = 26,25 (g)

p n C

Cu 49: Ho tan hon ton 24,4 gam hn hp gm FeCl2 v NaCl (c t l s mol tng ng l 1 : 2) vo
mt lng nc (d), thu c dung dch X. Cho dung dch AgNO 3 (d) vo dung dch X, sau khi phn
ng xy ra hon ton sinh ra m gam cht rn. Gi tr ca m l
A. 68,2
B. 28,7
C. 10,8
D. 57,4
127x + 58,5.2.x= 24,4 x = 0,1.
FeCl2 + 2AgNO3 2AgCl + Fe(NO3)2 ; NaCl + AgNO3 AgCl + NaNO3 ; Fe(NO3)2 + AgNO3 Fe(NO3)3 + Ag (*)
x
2x
x
2x
2x
x
---- - x
m = (0,01.2 + 0,02)143,5 + 108.0,1 = 68,2 (g); !! L u ph n ng (*)

p n A

Cu 50: t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X tc dng c vi
Na, tham gia phn ng trng bc v phn ng cng Br2 theo t l mol 1 : 1. Cng thc cu to ca X l
A. HOOC-CH=CH-COOH
B. HO-CH2-CH2-CH=CH-CHO
C. HO-CH2-CH2-CH2-CHO
D. HO-CH2-CH=CH-CHO

nCO2 = 4 c 4C; T/d ng v i Na c -OH ho c -COOH; c ph n ng trng Ag c -CH=O; c ng Br2 (1:1) c 1lin k t C=C
CTCT l HO-CH2-CH=CH-CH=O

p n D

B. Theo chng trnh Nng cao: (10 cu, t cu 51 n cu 60)

Cu 51: Cho s chuyn ho:
H SO a
c,to

+ HBr
+ Mg,etekhan
2 4
Butan 2 ol
X(anken)
Y
Z
Trong X, Y, Z l sn phm chnh. Cng thc ca Z l
A. CH3-CH(MgBr)-CH2-CH3
B. (CH3)3C-MgBr
C. CH3-CH2-CH2-CH2-MgBr
D. (CH3)2CH-CH2-MgBr

Chu i vi t l i d ng

H Br
4 ac,t
Butan 2 ol H2 SO
X (But 2 +en)

M g,ete
+ khan
Y (2
brombut
an)

Z(CH
r)

CH
CH (M
gB )3
2 CH

p n A
0
0
0
Cu 52: Cho cc th in cc chun : E Al3+ /Al = 1, 66V; EZn 2+ /Zn = 0, 76V ; EPb2+ /Pb = 0,13V ;

E0

Cu 2 + /Cu

= +0,34V . Trong cc pin sau y, pin no c sut in ng chun ln nht?

A. Pin Zn - Pb

B. Pin Pb - Cu

C. Pin Al - Zn

D. Pin Zn Cu

GV: Nguyn Kim Chin

Xem l i SGK 12

p n D

Cu 53: Pht biu no sau y khng ng?

A. Glucoz tn ti dng mch h v dng mch vng
B. Glucoz tc dng c vi nc brom
C. Khi glucoz dng vng th tt c cc nhm OH u to ete vi CH3OH
D. dng mch h, glucoz c 5 nhm OH k nhau.

Xem li SGK 12

p n C

Cu 54: Cho dung dch X cha hn hp gm CH3COOH 0,1M v CH3COONa 0,1M. Bit 250C Ka ca
CH3COOH l 1,75.10-5 v b qua s phn li ca nc. Gi tr pH ca dung dch X 25oC l
A. 1,00
B. 4,24
C. 2,88
D. 4,76
CH3COOH CH3COO- + H+ ;
0,1-x
x
x

CH3COONa CH3COO- + Na+

0,1
0,1
0,1

[CH 3COO - ].[H + ] (0,1 + x).x 0,1x

=
=
= 1,75.10- 5 x = 1,75.10-5 pH = -Log(1,75.10-5) = 4,76
[CH 3COOH ]
0,1- x
0,1
p n D
KA =

Cu 55: Khi ho tan hon ton 0,02 mol Au bng nc cng toan th s mol HCl phn ng v s mol
NO (sn phm kh duy nht) to thnh ln lt l
A. 0,03 v 0,01 B. 0,06 v 0,02
C. 0,03 v 0,02

D. 0,06 v 0,01

Au + 3HCl + HNO3 AuCl3 + NO + 2H2O

0,02 0,06
0,02

p n B

Cu 56: Cho 0,04 mol mt hn hp X gm CH2=CH-COOH, CH3COOH v CH2=CH-CHO phn ng

va vi dung dch cha 6,4 gam brom. Mt khc, trung ho 0,04 mol X cn dng va 40 ml
dung dch NaOH 0,75 M . Khi lng ca CH2=CH-COOH trong X l
A. 1,44 gam
B. 2,88 gam
C. 0,72 gam
D. 0,56 gam
CH2=CH-COOH + Br2 ;
X
x

CH2=CH-CHO + 2Br2 ;
z
2z

CH2=CH-COOH + NaOH ;
x
x

CH3-COOH + NaOH
y
y

x + y + z = 0,04(1) x = 0,02

Gii h x + 2z = 0, 04(2) y = 0, 01 mCH 2 = CH - COOH = 0, 01.72 = 0,72(g)

x + y + 0, 03(3) z = 0,01

p n A

Cu 57: Ngi ta iu ch anilin bng s sau

+ HNO a
c

Fe+ HCl
3
Benzen
Nitrobenzen
Anilin
0
H SO a
c
2

Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t
50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l
A. 186,0 gam
B. 111,6 gam
C. 55,8 gam
D. 93,0 gam
93.156 60 50
mAnilin =
.
.
= 55,8(g)
78 100 100
p n C

Cu 58: Phn bn no sau y lm tng chua ca t?

A. NaNO3
NH

+
4

B. KCl

C. NH4NO3

D. K2CO3

+ H2O NH3 + H3O (axit lm chua t)

+

p n C

Cu 59: Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ho
hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hp
sn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO 3 trong NH3, thu c 54 gam
Ag. Gi tr ca m l
A. 15,3
B. 8,5
C. 8,1
D. 13,5
nAg = 0,5 > 2nX vy c HCH=O, 2 ancol l CH3OH: xmol v C2H5OH: y mol gii h x=0,05; y= 0,15
m = 0,15.32 + 0,05.46 = 8,5 (g)

p n B

GV: Nguyn Kim Chin

Cu 60: Ho tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO 3 c, nng thu c
1,344 lt kh NO2 (sn phm kh duy nht, ktc) v dung dch Y. Sc t t kh NH3 (d) vo dung dch
Y, sau khi phn ng xy ra hon ton thu c m gam kt ta. Phn trm v khi lng ca Cu trong
hn hp X v gi tr ca m ln lt l
A. 21,95% v 0,78
B. 78,05% v 0,78
C. 78,05% v 2,25
D. 21,95% v 2,25
Cho: Cu Cu+2 + 2e; nhn: Al Al+3 + 3e ; N+5 + 1e N+4
X
2x
y
3y
0,06 0,06

2x + 3y = 0,06 x = 0.015
0,015.64
%Cu =
.100 = 78,05(5), m = mAl (OH )3 = 0,01.78 = 0,78(g)

64x + 27y = 1,23 y = 0,01

1
,23

( y Cu(OH)2 tan ht trong dd NH3)

p n B

B GD & T

GII THI TUYN SINH I HC 2009

Mn thi : HO, khi A - M : 825

* Cho bit khi lng nguyn t (theo vC) ca cc nguyn t :

H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5;
K = 39; Ca = 40; Cr = 52, Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Sn = 119; Ba=137; Pb =
207.

PHN CHUNG CHO TT C TH SINH: (40 cu, t cu 1 n cu 40)

Cu 1 : Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm H 2SO4
0,5M v Na NO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn
phm kh duy nht). Cho V ml dung dch NaOH 1M vo dung dch X th lng kt ta thu c l ln
nht. Gi tr ti thiu ca V l
A. 240.
B. 120.
C. 360.
D. 400.
nH+=0,4 mol nNO3=0,08 mol nFe=0,2 mol nCu=0,3 mol
Fe
Fe3+ +3e
Cu Cu2+ + 2e
0,02
0,02 0,06
0,03
0,03 0,06
Tng s mol e nhng = 0,12 mol
NO3-+3e+4H+ NO+2H2O
0,08 0,24
ne nhn>ne nhng nn Fe tan ht
0,04 0,12 0,16
nH+ d=0,4-0,16=0,24 mol
Trung ho X
Tng s mol OH-=3nFe3++2nCu2++nOH-=0,06+0,06+0,24=0,36 mol
S mol NaOH=0,36 lt=360 ml
p n C

Cu 2 : X phng ha hon ton 66,6 gam hn hp hai este HCOOC2H5 v CH3COOCH3 bng dung
dch NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H2SO4 c 1400C, sau khi
phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l
A. 18,00.
B. 8,10.
C. 16,20.
D. 4,05.
HCOOC2H5 v CH3COOCH3 cng ng phn C3H6O2
Tng s mol hai cht = 66,6:74=0,9 (mol)
RCOOR+ NaOH RCOONa + ROH
2ROH R2O + H2O
0,9
0,9 (mol)
0,9
0,45 (mol)
Khi lng nc = 0,45 . 18 =8,1(gam)
p n B

Cu 3: Trng hp no sau y khng xy ra phn ng ha hc?

A. Cho Fe vo dung dch H2SO4 long, ngui. B. Sc kh Cl2 vo dung dch FeCl2.
C. Sc kh H2S vo dung dch CuCl2.
D. Sc kh H2S vo dung dch FeCl2.

H2S khng phn ng vi FeCl2

GV: Nguyn Kim Chin

p n D

Cu 4: Cho cc hp kim sau: Cu-Fe (I); Zn Fe (II); Fe-C (III); Sn-Fe (IV). Khi tip xc vi dung dch
cht in li th cc hp kim m trong Fe u b n mn trc l:
A. I, II v III.
B. I, II v IV.
C. I, III v IV.
Tnh kh Fe>Cu(I), Zn>Fe(II), Fe>C(III), Fe>Sn(IV)
Fe b n mn I, III, IV
p n C

D. II, III v IV.

Cu 5: Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng

xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam
H2O v 7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l
A. 65,00%.
B. 46,15%.
C. 35,00%
D. 53,85%.
S mol HCHO=s mol CO2=0,35 (mol)
HCHOH2O
0,35
0,35 (mol) Suy ra s mol H2=(11,7:18)-0,35=0,3(mol)
% th tch H2=(0,3:0,65).100%=46,15%
p n B

Cu 6: Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na 2O v Al2O3; Cu v

FeCl3; BaCl2 v CuSO4; Ba v NaHCO3. S hn hp c th tan hon ton trong nc (d) ch to ra
dung dch l
A. 4.
B. 2.
C. 1.
D. 3.
Ch to ra mt dung dch l:
p n C

Cu 7: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp

X c khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l
A. 0,1 mol C2H4 v 0,2 mol C2H2.
B. 0,1 mol C3H6 v 0,2 mol C3H4.
C. 0,2 mol C2H4 v 0,1 mol C2H2.
D. 0,2 mol C3H6 v 0,1 mol C3H4.
Phng php th
m=0,2.42+0,1.40=12,4(g)
p n D

Cu 8: X phng ha hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam
mui ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca
hai este l
A. HCOOCH3 v HCOOC2H5.
B. C2H5COOCH3 v C2H5COOC2H5.
C. CH3COOC2H5 v CH3COOC3H7.
D. CH3COOCH3 v CH3COOC2H5.
p dng bo ton khi lng
mNaOH=0,94+2,05-1,99=1(g) nNaOH=0,025(mol)
M=1,99:0,025=79,6
p n D

Cu 9: Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m 1 gam mui Y. Cng 1
mol amino axit X phn ng vi dung dch NaOH (d), thu c m 2 gam mui Z. Bit m2m1=7,5. Cng
thc phn t ca X l
A. C4H10O2N2.
B. C5H9O4N.
C. C4H8O4N2.
D. C5H11O2N.
t cng thc l
(NH2)xR(COOH)y Ta c phng trnh
22y-36,5x=7,5 Nghim duy nht tho mn x=1, y=2 chn B
p n B

Cu 10: Ha tan ht m gam ZnSO4 vo nc c dung dch X. Cho 110ml dung dch KOH 2M vo X,
thu c a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th cng thu c a gam
kt ta. Gi tr ca m l
A. 20,125.
B. 12,375.
C. 22,540.
D. 17,710.
TNI: Zn2+ d OH- ht
Zn2++2OH- Zn(OH)2
0,22
0,11
TNII: Zn2+ ht OH- d ho tan mt phn kt ta
Zn2++2OH- Zn(OH)2
x
2x
x
Zn(OH)2+2OH-[Zn(OH)-4]
x-0,11
2x-0,22
Tng s mol OH-=0,28=2x+2x-0,22 suy ra x=0,125
m=0,125.161=20,125(g)

GV: Nguyn Kim Chin

p n A

Cu 11: Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l

A. etilen.

B. xiclopropan.

C. xiclohexan

Xiclo hexan khng lm mt mu nc brom k thng

p n C

D. stiren.

Cu 12: Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al2O3 nung nng n khi phn
ng hon ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l
A. 0,8 gam.
B. 8,3 gam.
C. 2,0 gam.
D. 4,0 gam.
mO=9,1-8,3=0,8(g) nO=nCuO=0,05(mol) mCuO=0,05.80=4(g)
p n D

Cu 13: un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp gm cc ete.

Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO 2 ( ktc) v 7,2 gam
H2O. Hai ancol l
A. CH3OH v CH2=CH-CH2-OH.
B. C2H5OH v CH2=CH-CH2-OH.
C. CH3OH v C3H7OH.
D. C2H5OH v CH3OH.
nCO2=nH2O=0,4 nn c mt ancol cha no
Cng thc ancol l CnH2n+1OH
Ete : (CnH2n+1)2O 28n+18=7,2: (0,4:n) nn n=1,8 nn chn A
p n A

Cu 14: Dy gm cc cht u tc dng c vi dung dch HCl long l

A. AgNO3, (NH4)2CO3, CuS.
C. FeS, BaSO4, KOH.

B. Mg(HCO3)2, HCOONa, CuO.

D. KNO3, CaCO3, Fe(OH)3.

Dy Mg(HCO3)2, HCOONa, CuO tc dng c vi HCl long

p n B

Cu 15: Cho phng trnh ha hc: Fe3O4 + HNO3 Fe(NO3)3 + NxOy + H2O

Sau khi cn bng phng php ha hc trn vi h s ca cc cht l nhng s nguyn, ti gin th h
s ca HNO3 l
A. 46x 18y.
B. 45x 18y.
C. 13x 9y.
D. 23x 9y.
Cn bng
(5x-2y)Fe3O4+(46x-18y)HNO3 3(5x-2y)Fe(NO3)3+NxOy+(23x-9y)H2O
p n A

Cu 16: X phng ha mt hp cht c cng thc phn t C 10H14O6 trong dung dch NaOH (d), thu
c glixerol v hn hp gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l:
A. CH2=CH-COONa, HCOONa v CH C-COONa.
B. CH3-COONa, HCOONa v CH3-CH=CH-COONa.
C. HCOONa, CH C-COONa v CH3-CH2-COONa.
D. CH2=CH-COONa, CH3-CH2-COONa v HCOONa.
C10H14O6
Tng k=4 = 3pi(COO)+1pi gc nn chn phng n B hoc D
B CH3CH=CHCOONa c ng phn hnh hc nn chn D
p n D

Cu 17: Ln men m gam glucoz vi hiu sut 90%, lng kh CO 2 sinh ra hp th ht vo dung dch
nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi khi
lng dung dch nc vi trong ban u. Gi tr ca m l
A. 13,5.
B. 30,0.
C. 15,0.
D. 20,0.
Khi lng CO2=10-3,4=6,6(g)
S : C6H12O62CO2
180
88
x
6,6 x=13,5(g)
H=90% nn
Khi lng glucoz=(100.13,5):90=15(g)
p n C

Cu 18: Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy hon
ton hn hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l
A. C2H4(OH)2 v C3H6(OH)2.
B. C2H5OH v C4H9OH.
C. C2H4(OH)2 v C4H8(OH)2.
D. C3H5(OH)3 v C4H7(OH)3.
Hai ancol a chc c t l s mol CO2 v nc l 3:4 th chng t hai ancol no c
n trung bnh = 3 chn C
p n C

GV: Nguyn Kim Chin

Cu 19: Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung dchH 2SO4 10% thu
c 2,24 lt kh H2 ( ktc). Khi lng dung dch thu c sau phn ng l
A. 101,48 gam.
B. 101,68 gam.
C. 97,80 gam.
D. 88,20 gam.
S mol H2SO4 phn ng = s mol H2=0,1(mol)
Khi lng dung dch H2SO4=[ (0,1.98).100]:10=98(g)
Khi lng dung dch sau phn ng =98+3,68-0,1.2=101,48(g)
p n A

Cu 20: Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi lng d
dung dch HCl c, cht to ra lng kh Cl2 nhiu nht l
A. KMnO4.
B. K2Cr2O7.
C. CaOCl2.
K2Cr2O73Cl2; KMnO42,5Cl2; CaOCl2Cl2; MnO2Cl2
p n B

D. MnO2.

Cu 21: Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO3 trong NH3 thu
c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, t0) th 0,125 mol X phn ng ht
vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l
A. CnH2n-1CHO (n 2).
B. CnH2n-3CHO (n 2).
C. CnH2n(CHO)2 (n 0).
D. CnH2n+1CHO (n 0).
S mol Ag = 2 ln s mol anehit chng t anehit n chc
S mol H2=2 ln s mol anehit chng t anehit cha no cha 1 pi
p n A

Cu 22: Ha tan hon ton 12,42 gam Al bng dung dch HNO3 long (d), thu c dung dch X v
1,344 lt ( ktc) hn hp kh Y gm hai kh l N 2O v N2. T khi ca hn hp kh Y so vi kh H 2 l 18.
C cn dung dch X, thu c m gam cht rn khan. Gi tr ca m l
A. 97,98.
B. 106,38.
C. 38,34.
D. 34,08.
44a+28b=0,06.18.2 a=0,03
Ta c h

b=0,03
a+b=0,06

2N+5+8eN2O
2N+5+10eN2 Tng s mol e nhn=0,54(mol)
0,24 0,03
0,3 0,03
S mol Al=0,46(mol)
AlAl3++3e
0,46
1,38 > 0,54(s mol e nhn ) chng t phn ng cn to NH4NO3
N+5 + 8e

NH4NO3
(1,38-0,54)
0,105
Tng khi lng mui = 0,46.nAl(NO3)3 + 80.nNH4NO3 = 106,38(g)
p n B

Cu 23: Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO3 long, thu c 940,8 ml kh
NxOy (sn phm kh duy nht, ktc) c t khi i vi H2 bng 22. Kh NxOy v kim loi M l
A. NO v Mg.
B. N2O v Al
C. N2O v Fe.
D. NO2 v Al.
MKh=22 chng t NxOy l N2O duy nht
2N+5+ 8e N2O
MMn++ne
0,336 0,042
Khi M=3,024: (0,336:n) M=9n (n=3, M=27) Chn Al
p n B

Cu 24: Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S
ng phn cu to ca X l
A. 8.
B. 7.

C. 5.

Theo bo ton khi lng nHCl=(15-10):36,5

MAmin=10:s mol Axit HCl = 73 (C4H11N) c tng 8 ng phn
p n A

D. 4.

Cu 25: Cho hn hp gm Fe v Zn vo dung dch AgNO3 n khi cc phn ng xy ra hon ton, thu
c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X l
A. Fe(NO3)2 v AgNO3.
B. AgNO3 v Zn(NO3)2.
C. Zn(NO3)2 v Fe(NO3)2.
D. Fe(NO3)3 v Zn(NO3)2.
Dung dch cha 2 mui chng t Fe phn ng mt phn v AgNO3 ht
Dung dch cha Fe(NO3)2 v Zn(NO3)2
p n C

Cu 26: Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l

A. Cu(OH)2 trong mi trng kim.
C. dung dch HCl.

B. dung dch NaCl.

D. dung dch NaOH.
GV: Nguyn Kim Chin

Dng Cu(OH)2/OHp n A

Cu 27: Cho 6,72 gam Fe vo 400ml dung dch HNO3 1M, n khi phn ng xy ra hon ton, thu c
kh NO (sn phm kh duy nht) v dung dch X. Dung dch X c th ha tan ti a m gam Cu. Gi tr
ca m l
A. 1,92.
B. 0,64.
C. 3,84.
D. 3,20.
S mol Fe=0,12(mol) s mol HNO3=0,4 (mol)
Fe+4HNO3Fe(NO3)3+NO+2H2O
Fe + 2Fe(NO3)33Fe(NO3)2
0,1 0,4
0,1
0,02
0,04
Fe(NO3)3 d =0,1-0,04=0,06(mol)
Cu + 2Fe(NO3)3Cu(NO3)2+2Fe(NO3)2
0,03 0,06
p n A

mCu=0,03.64=1,92(g)

Cu 28: Mt hp cht X cha ba nguyn t C, H, O c t l khi lng m C : mH : mO = 21:2:4. Hp cht

X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht
thm ng vi cng thc phn t ca X l
A. 5.
B. 4.
C. 6.
D. 3.
CxHyOz x:y:z=(21:12):2:(4:16)=7:8:1 Cng thc C7H8O=3 phenol+1 ete+1 ancol
p n A

Cu 29: Cho dy cc cht v ion: Zn, S, FeO, SO 2, N2, HCl, Cu2+, Cl-. S cht v ion c c tnh oxi ha
v tnh kh l
A. 4.

B. 6.

C. 5.

Cht tho mn S, FeO, SO2, N2, HCl

p n C

D. 7.

Cu 30: Nung 6,58 gam Cu(NO3)2 trong bnh kn khng cha khng kh, sau mt thi gian thu c
4,96 gam cht rn v hn hp kh X. Hp th hon ton X vo nc c 300 ml dung dch Y. Dung
dch Y c pH bng
A. 2.
B. 3.
C. 4.
D. 1.
Theo phng php tng gim khi lng
S mol mui phn ng =(6,58-4,96):108=0,015(mol)
Cu(NO3)22NO2+1/2O2
0,015
0,03
4NO24HNO3
0,03
0,03 [H+]=0,03:0,3=0,1(M) pH=1
p n D

Cu 31: Poli (metyl metacrylat) v nilon-6 c to thnh t cc monome tng ng l

A. CH3-COO-CH=CH2 v H2N-[CH2]5-COOH.
B. CH2=C(CH3)-COOCH3 v H2N-[CH2]6-COOH.
C. CH2=C(CH3)-COOCH3 v H2N-[CH2]5-COOH.
D. CH2=CH-COOCH3 v H2N-[CH2]6-COOH.

Hai monome ln lt l
CH2=C(CH3)COOCH3 v H2N-[CH2]5-COOH
p n C

Cu 32: Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc
dng vi dung dch NaHCO3. Tn gi ca X l
A. metyl axetat.
B. axit acrylic.
C. anilin.

X tc dng c vi NaOH v Br2, khng tc dng vi NaHCO3 l phenol

p n D

D. phenol.

Cu 33: Nguyn t ca nguyn t X c cu hnh electron lp ngoi cng l ns 2np4. Trong hp cht kh
ca nguyn t X vi hir, X chim 94,12% khi lng. Phn trm khi lng ca nguyn t X trong
oxit cao nht l
A. 27,27%.
B. 40,00%.
C. 60,00%.
D. 50,00%.
Hp cht vi H l H2X c %X theo khi lng l 94,12% X l S nn %S trong SO3 l 40%
p n B

Cu 34: Dy gm cc cht u iu ch trc tip (bng mt phn ng) to ra anehit axetic l:

A. CH3COOH, C2H2, C2H4.
C. C2H5OH, C2H4, C2H2.

Dy cht iu ch trc tip to ra CH3CHO l

C2H5OH, C2H4, C2H2
p n C

B. C2H5OH, C2H2, CH3COOC2H5.

D. HCOOC2H3, C2H2, CH3COOH.

GV: Nguyn Kim Chin

Cu 35: Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht
200 ml dung dch HCl 1M vo 100 ml dung dch X, sinh ra V lt kh ( ktc). Gi tr ca V l
A. 4,48.
B. 1,12.
C. 2,24.
D. 3,36.
S mol CO32-=0,15 (mol) ; s mol HCO3-=0,1(mol) ; s mol H+=0,2(mol)
H++CO32-HCO3- ; Tng s mol HCO3-=0,25 ; H++ HCO3- CO2+H2O
0,15 0,15 0,15
0,05 0,25 0,05
p n B

VCO2=0,05.22,4=1,12 (lt)

Cu 36: Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh
CO2 ( ktc) v a gam H2O. Biu thc lin h gia m, a v V l:
V
V
V
A. m = a
.
B. m = 2a
.
C. m = 2a
.
5, 6
11, 2
22, 4

D. m = a +

V
.
5,6

m=mC+mH+mO=12.(V:22,4)+a:9+16.(a:18-V:22,4)
p n A

Cu 37: C ba dung dch: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol
etylic, benzen, anilin ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l
dung dch HCl th nhn bit c ti a bao nhiu ng nghim?
A. 5.
B. 6.
C. 3.
D. 4.
Dng HCl nhn ra 6 cht: NH4HCO3 c kh thot ra ; NaAlO2 c kt ta keo sau tan ; Phenolat natri c hin tng
vn c ; C2H5OH dung dch trong sut ; Phenol phn lp ; Anilin ban u phn lp sau lc u to dung dch
trong sut vi HCl d
p n B

Cu 38: Cho 0,448 lt kh CO2 ( ktc) hp th ht vo 100 ml dung dch cha hn hp NaOH 0,06M v
Ba(OH)2 0,12M, thu c m gam kt ta. Gi tr ca m l
A. 3,940.
B. 1,182.
C. 2,364.

D. 1,970.

nOH-=0,006+2.0,012=0,03(mol)
nCO2=0,02(mol) 1<nOH-/nCO2<2 nn to ra 2 ion s mol bng nhau=0,01mol
Ba2++CO32- BaCO3
0,012 0,01
0,01
khi lng kt ta = 0,01.197=1,97(g)
p n D

Cu 39: Dy cc kim loi u c th c iu ch bng phng php in phn dung dch mui ca
chng l:
A. Ba, Ag, Au.

B. Fe, Cu, Ag.

C. Al, Fe, Cr.

D. Mg, Zn, Cu.

Fe, Cu, Ag
p n B

Cu 40: Cu hnh electron ca ion X2+ l 1s22s22p63s23p63d6. Trong bng tun hon cc nguyn t ha
hc, nguyn t X thuc
A. chu k 4, nhm VIIIB.
C. chu k 3, nhm VIB.
Cu hnh ca X l
3d64s2 chu k 4, nhm VIIIB
p n A

B. chu k 4, nhm VIIIA.

D. chu k 4, nhm IIA.

II. PHN RING [10 cu]: Th sinh ch c lm mt trong hai phn (phn A hoc B)
A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41: Cho cc hp cht hu c: C2H2; C2H4; CH2O; CH2O2 (mch h); C3H4O2 (mch h, n chc).
Bit C3H4O2 khng lm chuyn mu qu tm m. S cht tc dng c vi dung dch AgNO3 trong NH3
to ra kt ta l
A. 3.
B. 4
C. 2
D. 5
CH=CH, HCHO, HCOOH, CH=C-COOCH3, 4 cht ny u tc dng vi AgNO3/NH3
p n B

Cu 42: C nm dung dch ng ring bit trong nm ng nghim: (NH4)2SO4, FeCl2, Cr(NO3)3, K2CO3,
Al(NO3)3. Cho dung dch Ba(OH)2 n d vo nm dung dch trn. Sau khi phn ng kt thc, s ng
nghim c kt ta l
A. 5.
B. 2.
C. 4.
D. 3
(NH4)2SO4, FeCl2, K2CO3 to kt ta vi Ba(OH)2 v cc kt ta to ra khng tan
p n D

GV: Nguyn Kim Chin

Cu 43: Ha tan hon ton 14,6 gam hn hp X gm Al v Sn bng dung dch HCl (d), thu c 5,6 lt
H2( ktc). Th tch kh O2 ( ktc) cn phn ng hon ton vi 14,6 gam hn hp X l
A. 3,92 lt.
B. 1,68 lt
C. 2,80 lt
D. 4,48 lt
Al + 3/2HCl AlCl3 + 3/2H2
X
3/2x

27x+119y=14,6

3/ 2x+y=0,25

Zn + HCl ZnCl2 + H2
y
y

x=0,1

y=0,1

p : 4Al +
3O2 2Al2O3 . Sn + O2 SnO2
0,1 0,1*3/4
0,1 0,1
nO2 = (0,1*3/4 + 0,1*1) = 0,175 (mol) Vo2 = 0,175*22,4 = 3,92 (lt)
p n A

Cu 44: Cacbohirat nht thit phi cha nhm chc ca

A. Xeton

B. Anehit

C. Amin

Cacbohirat phi c nhm OH(ancol)

p n D

D. Ancol.

Cu 45: Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2 mol Cu2+ v 1 mol Ag+ n khi
cc phn ng xy ra hon ton, thu c mt dung dch cha 3 ion kim loi. Trong cc gi tr sau y,
gi tr no ca x tha mn trng hp trn?
A. 1,5
B. 1,8
C. 2,0
D. 1,2
MgMg2++2e
1,2
2,4
Ag++1eAg
1
1
Tho mn ra
p n D

ZnZn2++2e
x
2x
Cu2++2eCu
2
4
th 2,4+2x<1+4 hay x<1,3(mol)

Cu 46: Cho hn hp X gm hai axit cacboxylic no, mch khng phn nhnh. t chy hon ton 0,3
mol hn hp X, thu dc 11,2 lit kh CO2 ( ktc). Nu trung ha 0,3 mol X th cn dng 500 ml dung
dch NaOH 1M. Hai axit l:
A. HCOOH, HOOC-CH2-COOH.
B. HCOOH, CH3COOH.
C. HCOOH, C2H5COOH
D. HCOOH, HOOC-COOH.
0,3 mol axit trung ho 0,5 mol NaOH th phi c 1 axit n chc v mt axit hai chc
n trung bnh l 5/3 nn chn D
p n D

Cu 47: Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi
dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm
m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c
m gam mui khan. Gi tr ca m l
A. 8,2
B. 10,8
C. 9,4
D. 9,6
Cng thc thu gn ca X l CH2=CHCOONH3CH3
CH2=CHCOONH3CH3+NaOHCH2=CHCOONa+CH3NH2+H2O
0,1mol
0,1 mol
Khi lng cht rn = 0,1.94=9,4(g)
p n C

Cu 48: Cho cn bng sau trong bnh kn: 2NO 2 ( k ) N2O4 (k).
(mu nu )
(khng mu)
Bit khi h nhit ca bnh th mu nu nht dn. Phn ng thun c:
A. H < 0, phn ng thu nhit
B. H > 0, phn ng ta nhit
C. H > 0, phn ng thu nhit
D. H < 0, phn ng ta nhit
Phn ng to nhit tc delta H<O
p n D

Cu 49: t chy hon ton 0,2 mol mt ancol X no, mch h, cn va 17,92 lt kh O2 ( ktc). Mt
khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH)2 th to thnh dung dch c mu xanh lam.
Gi tr ca m v tn gi ca X tng ng l
A. 4,9 v propan-1,2-iol
B. 9,8 v propan-1,2-iol
C. 4,9 v glixerol.
D. 4,9 v propan-1,3-iol
s mol Cu(OH)2=1/2s mol X=0,05(mol)
Khi lng Cu(OH)2=4,9(g)

GV: Nguyn Kim Chin

chn A hoc C ch c A tha mn

p n A

Cu 50: Pht biu no sau y l ng?

A. Phn ur c cng thc l (NH4)2CO3.
B. Phn hn hp cha nit, photpho, kali c gi chung l phn NPK.
C. Phn ln cung cp nit ha hp cho cy di dng ion nitrat (NO3-) v ion amoni (NH4+)
D. Amophot l hn hp cc mui (NH4)2HPO4 v KNO3.

Phng n B
p n B

B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)

Cu 51: Mt bnh phn ng c dung tch khng i, cha hn hp kh N2 v H2 vi nng tng ng l 0,3
M v 0,7 M. Sau khi phn ng tng hp NH3 t trng thi cn bng t0C, H2 chim 50% th tch hn hp thu
c. Hng s cn bng KC t0C ca phn ng c gi tr l
A. 2,500
B. 0,609
C. 0,500
D. 3,125
Cu 52: Cho sut in ng chun ca cc pin in ha: Zn-Cu l 1,1 V; Cu-Ag l 0,46 V. Bit th in cc
0
0
0
chun E Ag + / Ag = +0,8V . Th din cc chun EZn2+ / Zn v ECu 2+ / Cu c gi tr ln lt l
A. +1,56 V v +0,64 V
B. 1,46 V v 0,34 V
C. 0,76 V v + 0,34 V
D. 1,56 V v +0,64 V
Cu 53: Nung nng m gam PbS ngoi khng kh sau mt thi gian, thu c hn hp rn (c cha mt oxit)
nng 0,95 m gam. Phn trm khi lng PbS b t chy l
A. 74,69 %
B. 95,00 %
C. 25,31 %
D. 64,68 %
Cu 54: Pht biu no sau y l ng?
A. Anilin tc dng vi axit nitr khi un nng thu c mui iazoni
B. Benzen lm mt mu nc brom nhit thng.
C. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh.
D. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam.
Cu 55: Dy gm cc dung dch u tham gia phn ng trng bc l:
A. Glucoz, mantoz, axit fomic, anehit axetic
B. Frutoz, mantoz, glixerol, anehit axetic
C. Glucoz, glixerol, mantoz, axit fomic.
D. Glucoz, frutoz, mantoz, saccaroz.
Cu 56: Dy gm cc cht v thuc u c th gy nghin cho con ngi l
A. penixilin, paradol, cocain.
B. heroin, seduxen, erythromixin
C. cocain, seduxen, cafein.
D. ampixilin, erythromixin, cafein.
Cu 57: Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X tc dng va ht vi dung dch NaOH,
thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc ca X l
A. CH3COOC(CH3)=CH2.
B. HCOOC(CH3)=CHCH3.
C. HCOOCH2CH=CHCH3
D. HCOOCH=CHCH2CH3.
Cu 58: Cho dy chuyn ha sau:
+ NaOH (du)
+X
Y (hp cht thm)
Phenol
Phenyl axetat
t0
Hai cht X,Y trong s trn ln lt l:
A. anhirit axetic, phenol.
B. anhirit axetic, natri phenolat
C. axit axetic, natri phenolat.
D. axit axetic, phenol.
Cu 59: Cho s chuyn ha:
H 3O +
KCN
Y
CH3CH2Cl
X
t0
Cng thc cu to ca X, Y ln lt l:
A. CH3CH2CN, CH3CH2CHO.
C. CH3CH2CN, CH3CH2COONH4.
Cu 60: Trng hp xy ra phn ng l
A. Cu + Pb(NO3)2 (long)
C. Cu + HCl (long) + O2

B. CH3CH2NH2, CH3CH2COOH.
D. CH3CH2CN, CH3CH2COOH.
B. Cu + HCl (long)
D. Cu + H2SO4 (long)
GV: Nguyn Kim Chin

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GV: Nguyn Kim Chin