BI TP V ANKAN- ANKEN- XICLOANKAN Mc 2- trong thi i hc 2007- 2010: Cu 1: Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha

ha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnhtng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l (cho H = 1, C = 12) A. C2H2 v C4H6. B. C2H2 v C4H8. C. C3H4 v C4H8. D. C2H2 v C3H8. Cu 2: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l (cho H = 1, C = 12, O = 16, Ca = 40) A. 20. B. 40. C. 30. D. 10. Cu 3: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5) A. C3H6. B. C3H4. C. C2H4. D. C4H8. Cu 4: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. 2-metylpropen v but-1-en (hoc buten-1).B. propen v but-2-en (hoc buten-2). C. eten v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). Cu 5: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l (cho H = 1, C = 12, O = 16) A. C3H8. B. C3H6. C. C4H8. D. C3H4. Cu 6: Cho s chuyn ha: CH4 C2H2 C2H3ClPVC. tng hp 250 kg PVC theo s trn th cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca c qu trnh l 50%) A. 358,4. B. 448,0. C. 286,7. D. 224,0. Cu 7: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3-C(CH3)=CH-CH3, CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l A. 2. B. 3. C. 1. D. 4. Cu 8: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc) A. CH4 v C2H4. B. CH4 v C3H4. C. CH4 v C3H6. D. C2H6 v C3H6. Cu 9: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankan. B. ankaien. C. anken. D. ankin Cu 10: Cng thc n gin nht ca mt hirocacbon l CnH2n+1. Hirocacbon thuc dy ng ng ca A. ankan. B. ankin. C. ankaien. D. anken. Cu 11: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l

A. 12,9. B. 25,8. C. 22,2. D. 11,1. Cu 12: t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O. Khi X tc dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. Tn gi ca X l A. 2-Metylbutan. B. etan. C. 2,2-imetylpropan. D. 2-Metylpropan Cu 13: Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l A. xiclohexan. B. xiclopropan. C. propen. D. etilen Cu 14: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l A. CH2=C(CH3)2. B. CH2=CH2. C. CH2=CH-CH2-CH3. D. CH3-CH=CH-CH3 Cu 15: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l A. but-1-en. B. xiclopropan. C. but-2-en. D. propilen. Cu 16: Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H 2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO 2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l A. CH4 v C2H4. B. C2H6 v C2H4. C. CH4 v C3H6. D. CH4 v C4H8.