TRNG THPT TNH GIA I T HA - SINH

CNG N TP HC K II Mn: Ha hc 10 (nm hc 2011-2012)

A. Phn Chung 1. Hon thnh chui phn ng: a. KMnO4Cl2HCl FeCl3 AgCl Cl2Br2I2ZnI2 Zn(OH)2 b. KMnO4 Cl2 KClO3 KCl Cl2 HCl FeCl2 FeCl3 Fe(OH)3 c. S FeS SO2 Na2SO3 NaHSO3 BaSO3 d. FeS2 SO2 HBr NaBr Br2 I2 SO3 H2SO4 KHSO4 K2SO4 KCl KNO3 e. H2 H2S SO2 SO3 H2SO4 HCl Cl2 2. Phn bit cc dd sau ng trong cac lo mt nhan. a. HCl, H2SO4, H2SO3 d.. AgNO3, Na2CO3, NaCl, K2SO4. b.Na2SO4,Na2SO3,NaCl e KCl, Na2CO3, NaI, CuSO4, BaCl2. c. Na2SO3, Na2CO3, NaCl, MgSO4, NaNO3. g.NaCl, NaNO3, Na2CO3, Na2SO4. 2 3.Cho 8g h Fe v Mg tc dng vi 200ml dung dch H2SO4 long th thu c 4,48 lt kh H2 (ktc) a) Tnh % khi lng mi kim loi trong hn hp u. b) Tnh nng mol dung dch H2SO4 dng. 4. Ch dng thm mt thuc th (khng dng cht ch th mu), hy nhn bit cc dung dch sau: natri sunfat, axit sunfuric, natri cacbonat, axit clohiric 5. Vit pt chng minh SO2 va c tnh oxi ha va c tnh kh. 6. Vit 2 pt chng minh S l mt cht oxi ha, 2 pt chng minh S l cht kh. 7. Vit phng trnh phn ng khi H 2SO4 long v H2SO4 c nng tc dng vi cc cht sau: Fe, Cu, FeO, Na2CO3. T cc phn ng trn rt ra kt lun g vi axit sunfuric. 8. Trnh by hai phng php iu ch hiro sufua t cc cht sau: S, Fe, axit HCl. 9. T mui n, nc, H 2SO4 c. Vit cc phng trnh phn ng (ghi k phn ng nu c) iu ch: Kh Cl 2, H2S, SO2 , nc Javen, Na2SO4 10. T qung pirit st, mui n, khng kh, nc, khng kh; hy vit phng trnh iu ch: Fe 2(SO4)3, Na2SO4, nc Javen, Na2SO3, Fe(OH)3, Natri, Natriclorat, NaHSO4, NaHSO3. 11. Cho 78,3 gam mangan ioxit tc dng vi HCl c. Lng clo thu c dn qua 500ml dung dch NaOH 4M ( iu kin thng) c dung dch A. a. Vit phng trnh phn ng. b. Tnh nng mol ca cc cht trong dung dch A (coi Vdd khng thay i). 12. Cho 4,8g Mg tc dng vi 250ml dung dch H2SO4 10% (D = 1,176g/ml) thu c kh H2 v dung dch A. a. Tnh th tch kh H2(kc) thu c. b. Tnh nng % cc cht trong dung dch A. 13. Hp th hon ton 3,36lt kh hidrosunfua ( ktc) vo 90ml dung dch NaOH 2M (D =1,221g/ml) a. Vit PTHH ca phn ng xy ra. b. Tnh nng mol v nng phn trm ca cht c trong dung dch thu c. 14. Cho 11 gam hn hp A gm st v nhm phn ng va vi dung dch H 2SO4 c nng thu c 10,08 lit kh SO2 (sn phm kh duy nht) ( ktc). Hp th ton b kh sinh ra vo 300 gam dung dch NaOH 10% thu c dung dch B. a) Vit phng trnh phn ng. b) Tnh thnh phn phn trm theo khi lng cc cht trong hn hp A? c) Tnh nng phn trm cc cht trong dung dch B? V O ,t H < 0 15. Cho pt ho hc: 2SO2 (k) + O2 (k) 2SO3 (k) Cn bng ho hc ca phn ng s chuyn dch v pha no khi:
2 5 0

a. Tng nhit ca bnh phn ng? b. Tng p sut chung ca hn hp? c. Tng nng kh oxi? d. Gim nng kh sunfur? 16- Trong bnh kn cha 1 mol H 2, 1 mol N2. Khi phn ng t n trng thi cn bng, c 0,4 mol NH3 c to thnh. a) Tnh hng s cn bng ca phn ng tng hp NH3. b) Khi h ang trng thi cn bng, nu tng p sut, cn bng s chuyn dch theo chiu no ? Ti sao ? II. Phn Ring Dnh cho hs CB 1. Cho 36 g hn hp X cha Fe 2O3 v CuO tc dng va vi dung dch H 2SO4 20% thu c 80 g hn hp mui. a) Tnh % khi lng tng cht trong hn hp X. b) Tnh khi lng dung dch H2SO4 dng. 2. Cho 6,8 g hn hp X gm Mg v Fe vo dung dch H2SO4 long th thu c 3,36 lit kh bay ra (kc). a) Tnh % khi lng mi kim loi trong X? b) Nu cho hn hp trn tc dng vi H2SO4 , nng.Tnh VSO2 (kc)? 3. Cho 35,2 g hn hp X gm Fe v CuO tc dng va vi 800 g dd H 2SO4 long th thu c 4,48 lit kh (kc) v dd A. a) Tnh % khi lng mi cht trong X. b) Tnh C% dung dch H2SO4 dng. c) Tnh khi lng cc mui trong dung dch A. Dnh cho HSNC 1. Mt hn hp A gm Fe v mt kim loi M ho tr 2. - Ha tan hon ton 12,1g hn hp A bng H2SO4 long th thu c 4,48lt kh H2(kc). - Ha tan hon ton 12,1g hn hp A bng H2SO4 c nng th thu c 5,6 lt kh SO2(kc). a. Vit cc phng trnh phn ng c th xy ra. b. Xc nh kim loi M. 2. Ho tan 24,8g hh X gm Fe, Mg, Cu trong dd H 2SO4 , nng d thu c dung dch A. Sau khi c cn dd A thu c 132 g mui khan. 24,8 g X tc dng vi dd HCl d th thu c 11,2 lt kh (kc). a. Vit phng trnh phn ng b. Tnh % khi lng mi kim loi trong hh X. 3. t chy hon ton 12,8 g S. Kh sinh ra c hp th ht bi 150 ml dung dch NaOH 20% (D = 1,28 g/ml). Tm CM, C% ca cc cht trong dung dch thu c sau phn ng. 4. Cho 40 g hn hp Fe Cu tc dng va vi dung dch H2SO4 98% nng thu c 15,68 lit SO2 (kc). a.Tnh % khi lng mi kim loi trong hn hp? b.Tnh khi lng dung dch H2SO4 dng? 5. Cho 20,8 g hn hp Cu v CuO tc dng va dung dch H2SO4 , nng thu c 4,48 lit kh (kc). a. Tnh % khi lng mi kim loi trong hn hp? b.Tnh khi lng dung dch H2SO4 80% cn dng v khi lng mui sinh ra. 6. Cho 7,6 g hn hp gm Fe, Mg, Cu vo dung dch H2SO4 , ngui d th thu c 6,16 lit kh SO2 (kc). Phn khng tan cho tc dng vi dung dch HCl d thu c 1,12 lit kh (kc).Tnh % khi lng hn hp u. 7. Cho 10,38 g hn hp gm Fe, Al v Ag chia lm 2 phn bng nhau: - Phn 1: Tc dng vi dung dch H2SO4 long d thu c 2,352 lit khi (kc). - Phn 2: Tc dng vi dung dch H2SO4 , nng d thu c 2,912lit kh SO2 (kc). Tnh khi lng tng kim loi trong hn hp ban u. 8. Cho h2 Fe va FeS td vi dd H2SO4 loang c 6,72 lit h2 khi ktc. Cho h2 khi nay i qua dung dch Pb( NO3)2 c 47,8 g kt tua en. a. h2 khi thu c gm nhng khi nao? Th tich mi khi la bao nhiu? b. tinh % cua Fe va FeS trong h2 ban u?