D NG

14

Bi tp phenol

Cu 1: Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4. Hp cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm ng vi cng thc phn t ca X l A. 3. B. 6. C. 4. D. 5. thi TSHC khi A 2009 Cu 2: Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung dch NaHCO3. Tn gi ca X l A. anilin. B. phenol. C. axit acrylic. D. metyl axetat. thi TSHC khi A 2009 Cu 3: Trong thc t, phenol c dng sn xut A. nha poli(vinyl clorua), nha novolac v cht dit c 2,4-D. B. nha rezol, nha rezit v thuc tr su 666. C. poli(phenol-fomanehit), cht dit c 2,4-D v axit picric. D. nha rezit, cht dit c 2,4-D v thuc n TNT. thi TSC 2009 Cu 4: Dy gm cc cht u phn ng vi phenol l: A. nc brom, anehit axetic, dung dch NaOH. B. dung dch NaCl, dung dch NaOH, kim loi Na. C. nc brom, axit axetic, dung dch NaOH. D. nc brom, anhirit axetic, dung dch NaOH. thi TSHC khi B 2007 Cu 5: nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng gia phenol vi A. dung dch NaOH B. Na kim loi. C. . nc Br2. D. H2 (Ni, nung nng). thi TSHC khi B 2008
+ Cl2 (1:1) + NaOH, du + HCl X Y Z Cu 6: Cho s C6 H 6 Fe, t o t o cao,P cao Hai cht hu c Y, Z ln lt l: A. C6H6(OH)6, C6H6Cl6. B. C6H4(OH)2, C6H4Cl2. C. C6H5OH, C6H5Cl. D. C6H5ONa, C6H5OH. thi TSHC khi A 2007 Cu 7: Cho s chuyn ho sau : + Br2 (1:1mol),Fe,t 0 + NaOH (d ),t 0 ,p + HCl(d) Toluen X Y Z Trong X, Y, Z u l hn hp ca cc cht hu c, Z c thnh phn chnh gm : A. m-metylphenol v o-metylphenol B. benzyl bromua v o-bromtoluen C. o-bromtoluen v p-bromtoluen D. o-metylphenol v p-metylphenol thi TSHC khi B 2008 Cu 8: Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO2 thu c nh hn 35,2 gam. Bit rng, 1 mol X ch tc dng c vi 1 mol NaOH. Cng thc cu to thu gn ca X l A. HOCH2C6H4COOH. B. C6H4 (OH)2. C. HO C6H4CH2OH. D. C2H5C6H4OH. thi TSHC khi B 2007 Cu 9: S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi dung dch NaOH l A. 3. B. 1. C. 4. D. 2. thi TSHC khi B 2007 Cu 10: Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c tnh cht: tch nc thu c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S lng ng phn ng vi cng thc phn t C8H10O, tho mn tnh cht trn l A. 2. B. 4. C. 1. D. 3. thi TSHC khi B 2007 Cu 11: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia

GV: st: 0919.107.387 & 0976.822.954

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phn ng v X ch tc dng c vi NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l A. HOC6H4CH2OH. B. CH3C6H3(OH)2 C. CH3OC6H4OH. D. C6H5CH(OH)2. thi TSC 2007 Cu 12: Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l A. HO-C6H4-COOCH3 B. CH3-C6H3(OH)2. C. HO-CH2-C6H4-OH D. HO-C6H4-COOH. thi TSHC khi B 2009 Cu 13/ Cht X c cha vng benzen v CTPT l C8H10O. X tc dng vi Na nhng khng tc dng tc dng vi NaOH. Oxi ho X bng CuO thu c cht hu c Y c CTPT l C8H8O. Hy cho bit X c bao nhiu CTCT: a. 3 b. 4 c. 5 d. 2 Cu 14: Cht hu c X c cng thc phn t C7H8O2. Tm cng thc cu to ca X bit: X tc dng vi Na gii phng hidro, vi : nH 2 : nX = 1:1 Trung ho 0,2 mol X cn dung ng 100 ml dung dch NaOH 2M. A. CH3 O C6H4 OH B. C6H3(OH)2CH3 C. HO CH2 O C6H5 D. HO C6H4 CH2OH Cu 15: Trong s cc pht biu sau v phenol (C6H5OH): (1) Phenol tan t trong nc nhng tan nhiu trong dung dch HCl. (2) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm. (3) Phenol dng sn xut keo dn, cht dit nm mc. (4) Phenol tham gia phn ng th brom v th nitro d hn benzen. Cc pht biu ng l: A. (1), (3), (4). B. (1), (2), (3). C. (2), (3), (4). D. (1), (2), (4). thi TSC khi A 2010 Cu 16: S hp cht ng phn cu to ca nhau c cng thc phn t C 8H10O, trong phn t c vng benzen, tc dng c vi Na, khng tc dng c vi NaOH l A. 7. B. 6. C. 4. D. 5. thi TSC 2011 Cu 17: Hp cht hu c X cha vng benzen c cng thc phn t trng vi cng thc n gin nht. Trong X, t l khi lng cc nguyn t l mC : mH : mO = 21 : 2 : 8. Bit khi X phn ng hon ton vi Na th thu c s mol kh hiro bng s mol ca X phn ng. X c bao nhiu ng phn (cha vng benzen) tha mn cc tnh cht trn? A. 7. B. 10. C. 3. D. 9. thi TSHC khi A 2011 Cu 18: Cho m gam hn hp X gm phenol v etanol phn ng hon ton vi natri (d), thu c 2,24 lt kh H2 (ktc). Mt khc, phn ng hon ton vi m gam X cn 100 ml dung dch NaOH 1M. Gi tr ca m l A. 7,0. B. 21,0. C. 14,0. D. 10,5. thi TSC 2008 Cu 19). nhn bit cc cht ring bit gm C2H5OH, CH2=CH-CH2OH, C6H5OH, C2H4(OH)2 ta dng cp ho cht nao sau y? A). Nc Br2 v Cu(OH)2. B). Dung dch NaOH v Cu(OH)2. C). Nc Br2 v dung dch NaOH D). Dung dch KMnO4 v Cu(OH)2. Cu 20: Cho cc cht sau: C2H5OH, dung dch C6H5ONa, dung dch NaOH, kh CO2, dung dch HCl . Cho tng cp cht tc dng vi nhau c xt , s cp cht c phn ng xy ra l A. 6 B. 4 C. 3 D. 5 Cu 21: Cho cumen tc dng vi CH3Cl trong AlCl3 thu c cc sn phm monometyl ha trong c X. Khi cho X tc dng vi KMnO4 un nng thu c cht Y c cng thc C8H4O4K2 cu to i xng. Cng thc cu to ca X l: A. p-CH3-C6H4-CH(CH3)2 B. o-CH3-C6H4-CH(CH3)2 C. m-CH3-C6H4-CH(CH3)2 D. C A, B, C u ng Cu 22: X l hp cht thm c CTPT C8H10O. ng phn no ca X tha mn dy bin ha sau: H 2O trung hop X X polime. A. C6H5CH2CH2OH B. C6H5CH(OH)CH3 C. CH3C6H4CH2OH D. C6H5CH2CH2OH v C6H5CH(OH)CH3

GV: st: 0919.107.387 & 0976.822.954

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Cu 23: T C2H2 v cc cht v c cn thit khc, c th iu ch 2,4,6-triamino phenol (X) bng s phn ng no sau y: A. C2H2C6H6 C6H3(NO2)3 C6H3(NH2)3 C6H2(NH2)3Br X B. C2H2C6H6 C6H5Br C6H5OH C6H2(NO2)3OH X C. C2H2C6H6 C6H5NO2 NH2C6H2Br3 X D. Cch khc Cu 24: Cho m gam hn hp gm 2 cht: phenol v ancol benzylic tc dng vi Na d c 448ml kh thot ra (ktc). Mt khc m gam hn hp ny lm mt mu va ht 100ml dung dch nc Br2 0,3M. Thnh phn % s mol ca phenol trong hn hp l: A: 74,6% B: 22,5% C: 25% D: 32,4% Cu 25: Dung dch phenol phn ng vi my cht trong s cc cht sau y: Na, dd Brom, dd NaCl, dd NaOH, axit HNO3 (xc tc H2SO4); dd NaHCO3; dd Na2CO3? a4 b3 c6 d5 Cu 26). Trong cc cp cht sau cp cht no khng phi l ng ng ca nhau: A). C6H5OH v CH3C6H4OH. B). C6H5OH v C6H5CH2OH. C). CH3OH v C2H5OH. D). CH4 v C3H8. Cu 27: Cho cc pht biu v tnh cht ca phenol nh sau: (1) Phenol c tnh axit mnh hn etanol v nhn bezen ht electron ca nhm OH bng hiu ng lin hp, trong khi nhm C2H5 li y electron vo nhm OH. (2) Phenol c tnh axit mnh hn etanol va c minh hot bng phn ng phenol tc dng vi dung dch NaOH cn C2H5OH th khng. (3) Tnh axit ca phenol yu hn H2CO3 v sc CO2 vo dung dch C6H5ONa ta s c C6H5OH. (4) Phenol trong nc cho mi trng axit, lm qu tm ha . Nhm gm cc pht biu ng l A. (2), (3), (4). B. (1), (2), (3) C. (1), (2), (4). D. (3), (1), (4). Cu 28. Dy gm cc cht u phn ng vi phenol l: A. nc brom, axit axetic, dung dch NaOH. B. nc brom, anehit axetic, dung dch NaOH. C. nc brom, anhirit axetic, dung dch NaOH. D. dung dch NH4Cl, dung dch NaOH, kim loi Na. Cu 29. Khi thay nguyn t H ca hirocacbon bng nhm -OH th c dn xut hiroxi. C cc nhn nh sau: a) Phenol l dn xut hiroxi ca hirocacbon thm. b) Phenol l dn xut hiroxi m nhm OH nh vi C ca vng thm. c) Ancol thm l dn xut hiroxi ca hirocacbon thm. d) Ancol thm l ng ng ca phenol. S nhn xt ng l A. 3. B. 1. C. 4. D. 2. Cu 30. Sn phm ca phn ng este ho gia anhirit axetic v phenol c tn l: A. phenyl axetat B. phenyl fomat C. benzyl fomat D. benzyl axetat Cu 31: Mt hp cht thm c CTPT C7H8O. S ng phn tc dng c vi dung dch Br2 trong nc l: A. 4 B. 5 C. 6 D. 7 Cu 32. Cho cc cu sau: 1/ Nhng hp cht m phn t c cha nhm hidroxyl-OH v vng benzen thuc loi phenol 2/ Phenol l hp cht m phn t c cha nhm hidroxyl-OH lin kt trc tip vi nguyn t cacbon ca vng benzen 3/ Nhng hp cht m phn t c cha nhm hidroxyl-OH lin kt vi gc hidrocacbon u thuc loi phenol 4/ Nhng hp cht m phn t c cha nhm hidroxyl-OH lin kt trc tip vi nguyn t cacbon lai ho sp2 u thuc loi phenol 5/ iu kin thng,phenol hu nh khng tan trong nc,nhng tan nhiu trong etanol 6/ Phenol va l tn 1 loi hp cht va l tn ca 1 hp cht C6H5OH. Nhng cu ng l. A. 2,3,4,5 B. 1,2,3,4 C. 2,5,6 D. 1,3,5,6 + O2 CH 2 =CH CH 3 X + Y. S o tren dung e B Cau 33. Cho s o sau: A H 2 SO4 H+ ieu che c chat X, Y. Chat X va Y la chat nao trong cac chat sau ay? A. Phenol va axeton. B. ancol acrylic va axit propionic.

GV: st: 0919.107.387 & 0976.822.954

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C. Axit acrylic va anehit acrylic. D. Ancol benzylic va ancol acrylic. Cau 34. Xet phan t phenol . Tm phat bieu ung. A. Do nhom OH ay electron ve nhan thm nen lien ket OH phan cc manh nen phenol the hien tnh axit. B. Do nhom OH co the tao lien ket hiro vi nc nen phenol de tan trong nc. C. Do s di chuyen e t nguyen t Oxi ve nhan thm gay hieu ng lam tang mat o e tren nhan thm tai cac v tr ortho va para. D. Do anh hng cua nhom OH en nhan thm lam cho phenol co tnh axit. Do anh hng cua nhan thm en nhom OH nen lam cho phenol de tham gia phan ng the. Cu 35. Chn pht biu sai A. Phnol c tnh axit nhng yu hn axit cacbonic B. Phenol cho phn ng cng d dng vi brm to kt ta trng 2,4,6-tribromphenol. C.Do nhn bezen ht in t khin OH ca phenol c tnh axit D. Dung dch phenol khng lm i mu qu tm v tnh axit ca phenol rt yu. Cu 36. nhn bit cc cht etanol, propenol, etilenglicol, phenol c th dng cc cp cht: A. Nc Br2 v NaOH B. NaOH v Cu(OH)2 C. KMnO4 v Cu(OH)2 D. Nc Br2 v Cu(OH)2 Cu 37. ng vi cng thc C7H8O c bao nhiu ng phn cha vng bezen va phn ng vi Na, va phn ng vi NaOH ? A. 2 ng phn B. 5 ng phn C. 3 ng phn D. 4 ng phn Cu 38. Mt hn hp gm 25 gam phenol v benzen khi cho tc dng vi dung dch NaOH d thy tch ra 2 lp cht lng phn cch, lp cht lng pha trn (ben zen) c th tch 19,5 ml v c khi lng ring l 0,8 g/ml. Khi lng phenol trong hn hp ny l : A. 9,4 gam. B. 15,6 gam. C. 24,375 gam. D. 0,625 gam. Cu 39: Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit cao. Sau khi phn ng xy ra hon ton, thu c x mol hn hp kh gm: CO 2, CO, N2 v H2. Gi tr ca x l A. 0,60. B. 0,54. C. 0,36. D. 0,45. TSHC khi B 2010

GV: st: 0919.107.387 & 0976.822.954

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