Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc

Vn 6 : Ancol - Phenol
Cu 1: S lng ng phn cu to ca C4H8Cl2 l A. 6. A. 2. B.7. B. 3. C. 8. C. 4.
o

D. 9. D. 5.

Cu 2: S ng phn cu to (k c ng phn cis - trans) ca C3H5Br l Cu 3: Cho s phn ng:

HBr 2, Pd vi PbCO3 KOH, ancol, t But-1-in H A1 A2 A3

Trong A1, A2, A3 l sn phm chnh. Cng thc ca A3 l A. CH3-CH(OH)-CH2-CH3. C. CH3-CH=CH-CH3. B. CH3-C C-CH3. D. CH2=CH-CH2-CH3.
H O+

KCN 3 Y Cu 4: Cho s chuyn ho: CH3CH2Cl X to

Cng thc cu to ca X, Y ln lt l A. CH3CH2NH2, CH3CH2COOH. C. CH3CH2CN, CH3CH2CHO. Cu 5: Nhn xt no sau y khng ng ? A. ng vi cng thc C3H5Br c 4 ng phn cu to. B. Anlyl bromua d tham gia phn ng th hn phenyl bromua. C. Vinyl clorua c th c iu ch t etilen. D. Etyl clorua thuc loi dn xut halogen bc hai. Cu 6: un hn hp gm C2H5Br v KOH d trong C2H5OH, sau khi phn ng xy ra hon ton, dn kh sinh ra qua dung dch Br2 d, thy c 8 gam Br2 phn ng. Khi lng C2H5Br em phn ng l A. 10,9 gam. B. 5,45 gam. C. 8,175 gam. D. 5,718 gam. Cu 7: un nng 2,92 gam hn hp X gm propyl clorua v phenyl clorua vi dung dch NaOH long (va ), sau thm tip dung dch AgNO3 n d vo hn hp sau phn ng thu c 2,87 gam kt ta. Thnh phn % khi lng phenyl clorua c trong X l A. 46,23%. A. 1. B. 61,47%. B. 2. C. 53,77%. C. 3. D. 38,53%. D. 4. Cu 8: ng vi cng thc phn t C5H12O c my ng phn ancol bc mt ? Cu 9: C bao nhiu ancol bc hai, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18% ? A. 2. B. 3. C. 4. D. 5. B. CH3CH2CN, CH3CH2COOH. D. CH3CH2CN, CH3CH2COONH4.

THPTSo1BaoThang.Org Ngi trng chung ca hc tr Vit

Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc Cu 10: Khi phn tch thnh phn mt ancol n chc X th thu c kt qu: tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ancol ng vi cng thc phn t ca X l A. 3. A. 1. B. 4. B. 2. C. 2. C. 3. D. 1. D. 4. Cu 11: S loi lin kt hiro c th c khi ho tan ancol etylic vo nc l Cu 12: Khi un nng hn hp ancol gm CH3OH v C2H5OH (xc tc H2SO4 c, 140oC) th s ete thu c ti a l A. 4. B. 2. C. 1. D. 3. Cu 13: un nng hn hp metanol v etanol vi H2SO4 c trong khong nhit t 130oC n 180oC. S lng sn phm hu c thu c l A. 2. A. propan-2-ol. C. pentan-3-ol. A. Ancol sec-butylic. C. Ancol isobutylic. A. Ancol butylic. C. Ancol sec-butylic. B. 3. C. 4. B. etanol. D. 2-metylpropan-2-ol. B. Ancol tert-butylic. D. Ancol butylic. B. Ancol isobutylic. D. Ancol tert-butylic. D. 5. Cu 14: Ancol b oxi ho bi CuO cho sn phm c kh nng tham gia phn ng trng gng l

Cu 15: Ancol no sau y kh b oxi ho nht ?

Cu 16: ng phn no ca ancol C4H10O khi tch nc s cho hai olefin ?

Cu 17: Dy gm cc cht u tc dng vi ancol etylic l A. HBr (to), Na, CuO (to), CH3COOH (xc tc). B. Ca, CuO (to), C6H5OH (phenol), HOCH2CH2OH. C. NaOH, K, MgO, HCOOH (xc tc). D. Na2CO3, CuO (to), CH3COOH (xc tc), (CH3CO)2O. Cu 18: Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy nht l xeton Y (t khi hi ca Y so vi kh hiro bng 29). A. CH3-CHOH-CH3. C. CH3-CO-CH3. A. Ln men tinh bt. B. Thu phn etyl bromua trong dung dch kim khi un nng. C. Hirat ho etilen xc tc axit. Cng thc cu to ca X l B. CH3-CH2-CHOH-CH3. D. CH3-CH2-CH2-OH.

Cu 19: Phng php no iu ch ancol etylic di y ch dng trong phng th nghim ?

THPTSo1BaoThang.Org Ngi trng chung ca hc tr Vit

Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc D. Phn ng kh anehit axetic bng H2 xc tc Ni un nng. Cu 20: Hirat ho 2 anken ch to thnh 2 ancol. Hai anken l A. 2-metylpropen v but-1-en. C. eten v but-2-en. Cu 21: Chn cu ng trong cc cu sau: A. un nng ancol metylic vi H2SO4 c 140 - 170oC thu c ete. B. Ancol a chc ho tan Cu(OH)2 to thnh dung dch mu xanh da tri. C. iu ch ancol no, n chc bc mt l cho anken cng nc. D. Khi oxi ho ancol no, n chc thu c anehit. Cu 22: Propan-2-ol khng th iu ch trc tip t A. propilen. B. axeton. C. 2-clopropan. D. propanal. Cu 23: Cho s chuyn ho sau (mi mi tn l mt phng trnh phn ng): Tinh bt X Y Z metyl axetat Cc cht Y, Z trong s trn ln lt l A. C2H5OH, CH3COOH. C. CH3COOH, C2H5OH. A. 3-metylbut-1-en. C. 3-metylbut-2-en. B. CH3COOH, CH3OH. D. C2H4, CH3COOH. B. 2-metylbut-2-en. D. 2-metylbut-3-en. B. propen v but-2-en. D. eten v but-1-en.

Cu 24: Khi tch nc t ancol 3-metylbutan-2-ol, sn phm chnh thu c l

Cu 25: Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh ba anken l ng phn ca nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn ca X l A. (CH3)3COH. C. CH3CH(OH)CH2CH3. B. CH3OCH2CH2CH3. D. CH3CH(CH3)CH2OH.

Cu 26: Khi tch nc t 2 ancol ng phn c cng thc C 4H10O vi H2SO4 c 170oC thu c 3 anken (khng k ng phn hnh hc). Cng thc cu to ca hai ancol l A. CH3CH2CH2CH2OH v (CH3)2CHCH2OH. B. (CH3)2CHCH2OH v (CH3)3COH. C. CH3CH(OH)CH2CH3 v CH3CH2CH2CH2OH. D. CH3CH(OH)CH2CH3 v (CH3)3COH. Cu 27: Hiro ho cht A mch h c cng thc C4H6O c ancol butylic. S cng thc cu to c th c ca A l A. 4. B. 6. C. 5. D. 3. Cu 28: C my ng phn ng vi cng thc phn t C 4H8Br2 khi thu phn trong dung dch kim cho sn phm l anehit ?

THPTSo1BaoThang.Org Ngi trng chung ca hc tr Vit

Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc A. 4. B. 3. C. 2. D. 1.

+ HCl + NaOH Cu 29: Cho s chuyn ho sau: C2H2 A CH3CHO

Cng thc cu to ca cht A c th l A. CH2=CHCl. C. ClCH2-CH2Cl. B. CH3-CHCl2. D. CH2=CHCl hoc CH3-CHCl2.

Cu 30: Cho cc cht c cng thc cu to nh sau: HOCH2-CH2OH (X) ; HOCH2-CH2-CH2OH (Y) ; HOCH2-CHOH-CH2OH (Z) ; CH3-CH2-O-CH2-CH3 (R) ; CH3-CHOH-CH2OH (T). Nhng cht tc dng c vi Cu(OH)2 to thnh dung dch mu xanh lam l A. X, Y, R, T. B. X, Z, T. C. Z, R, T. D. X, Y, Z, T. Cu 31: Cho cc hp cht sau: (a) HOCH2-CH2OH ; (c) HOCH2-CH(OH)-CH2OH ; (e) CH3-CH2OH ; (b) HOCH2-CH2-CH2OH (d) CH3-CH(OH)-CH2OH (f) CH3-O-CH2CH3

Cc cht u tc dng c vi Na, Cu(OH)2 l A. (a), (b), (c). C. (a), (c), (d). B. (c), (d), (f). D. (c), (d), (e).

Cu 32: Cht hu c X mch h, bn, tn ti dng trans c cng thc phn t C4H8O, X lm mt mu dung dch Br2 v tc dng vi Na gii phng kh H 2. Cng thc cu to thu gn ca X l A. CH2=CHCH2CH2OH. C. CH2=C(CH3)CH2OH. Cu 33: Cho cc phn ng:
t HBr + C2H5OH
o

B. CH3CH2CH=CHOH. D. CH3CH=CHCH2OH.

C2H4 + Br2
askt (1 : 1 mol) C2H6 + Br2

C2H4 + HBr S phn ng to ra C2H5Br l A. 4. B. 3.

H2SO4 c, to

C. 2.

D. 1.

Cu 34: Cho s chuyn ho:

+ HBr + Mg, ete khan Butan-2-ol X (anken) Y Z

Trong X, Y, Z l sn phm chnh. Cng thc ca Z l A. (CH3)3C-MgBr. C. CH3-CH(MgBr)-CH2-CH3. gia phenol vi B. CH3-CH2-CH2-CH2-MgBr. D. (CH3)2CH-CH2-MgBr.

Cu 35: nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng

THPTSo1BaoThang.Org Ngi trng chung ca hc tr Vit

Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc A. dung dch NaOH. C. nc Br2. ca phenol vi A. Na v nc brom. C. nc brom v dung dch NaOH. A. mch khng phn nhnh. C. mng li khng gian. dung dch NaOH l A. 3. A. 3 ; 2. A. tng. C. va tng va gim. A. Dung dch Br2. C. Dung dch NaOH. B. 4. B. 4 ; 3. C. 2. C. 3 ; 4. B. gim. D. khng thay i. B. Dung dch HCl. D. Dung dch HNO3. D. 1. D. 4 ; 4. Cu 39: S hp cht thm c cng thc C7H8O tc dng vi Na, vi dung dch NaOH ln lt l Cu 40: Cho dy cc axit: phenic, picric, p-nitrophenol. T tri sang phi tnh axit B. dung dch NaOH v nc brom. D. dung dch NaOH v fomanehit. B. mch phn nhnh. D. C A, C u ng. B. Na kim loi. D. H2 (Ni, nung nng).

Cu 36: nh hng ca nhm -OH n gc phenyl v ngc li c chng minh bi phn ng

Cu 37: un nng fomanehit vi phenol (d) c axit lm xc tc thu c polime c cu trc

Cu 38: S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) khng tc dng vi

Cu 41: Dng mt ho cht no sau y nhn bit stiren, toluen, phenol ?

Cu 42: C 4 cht lng ng trong 4 l b mt nhn: ancol etylic, toluen, phenol, axit fomic. nhn bit 4 cht c th dng nhm thuc th no sau y ? A. Qu tm, nc Br2, dung dch NaOH. B. Dung dch Na2CO3, nc Br2, Na. C. Qu tm, nc Br2, dung dch K2CO3. D. Na, dung dch HCl, dung dch AgNO3 trong NH3. Cu 43: Cho s : C6H6 (benzen) X Fe, t o Hai cht hu c Y, Z ln lt l A. C6H6(OH)6, C6H6Cl6. C. C6H5OH, C6H5Cl. Cu 44: Cho s chuyn ho sau:
(1) (2) (3) (4) (5) Metan A2 A4 A1 A3 phenol

+ Cl2 (1 : 1 mol)

o
t , P cao

+ NaOH c, d

+ axit HCl Y Z

B. C6H4(OH)2, C6H4Cl2. D. C6H5ONa, C6H5OH.

THPTSo1BaoThang.Org Ngi trng chung ca hc tr Vit

Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc Cng thc cu to ca cc cht hu c A1, A2, A3, A4 ln lt l A. HCHO, C6H12O6, C6H6, C6H5Cl. B. CH CH, C6H6, C6H5NO2, C6H5NH3Cl. C. CH CH, CH2=CH2, C6H6, C6H5Cl. D. CH CH, C6H6, C6H5Br, C6H5ONa. Cu 45: Cho s chuyn ho sau:
+ Br2 (1 : 1 mol) Toluen X Y Z t o , P cao Fe, t o + NaOH c (d) + HCl (d)

Trong X, Y, Z u l hn hp ca cc cht hu c. Z c thnh phn chnh gm A. m-metylphenol v o-metylphenol. C. o-bromtoluen v p-bromtoluen. B. benzyl bromua v o-bromtoluen. D. o-metylphenol v p-metylphenol.

Cu 46: Cho 4 cht: phenol (A), ancol etylic (B), benzen (C), axit axetic (D). linh ng ca nguyn t hiro trong phn t cc cht trn tng dn theo th t l A. A < B < C < D. C. C < B < A < D. A. Na, KOH, dung dch Br2, HCl. B. K, NaOH, HNO3 c, dung dch Br2. C. Na, NaOH, CaCO3, CH3COOH. D. K, HCl, axit cacbonic, dung dch Br2. Cu 48: Dy gm cc cht u phn ng vi phenol l A. dung dch NaCl, dung dch NaOH, kim loi Na. B. nc brom, anhirit axetic, dung dch NaOH. C. nc brom, axit axetic, dung dch NaOH. D. nc brom, anehit axetic, dung dch NaOH. Cu 49: Trong thc t, phenol c dng sn xut A. nha poli(vinyl clorua), nha novolac v cht dit c 2,4-D. B. nha rezol, nha rezit v thuc tr su 666. C. poli(phenol-fomanehit), cht dit c 2,4-D v axit picric. D. nha rezit, cht dit c 2,4-D v thuc n TNT. Cu 50: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn ng v X ch tc dng c vi NaOH theo t l s mol 1 : 1. Cng thc cu to thu gn ca X l A. C6H5CH(OH)2. B. HOC6H4CH2OH. B. C < D < B < A. D. B < C < D < A.

Cu 47: Phenol tc dng vi tt c cc cht trong nhm no sau y ?

THPTSo1BaoThang.Org Ngi trng chung ca hc tr Vit

Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc C. CH3C6H3(OH)2. D. CH3OC6H4OH.

Cu 51: Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung dch NaHCO3. Tn gi ca X l A. anilin. B. phenol. C. axit acrylic. D. metyl axetat. Cu 52: t chy hon ton 1 mol cht X (C, H, O) cho ra 4 mol CO 2. Bit X cng Br2 theo t l mol 1 : 1 ; X tc dng vi Na cho ra kh H 2 v X cho phn ng trng gng. Cng thc cu to ca hp cht X l A. HO-CH=CH-CH2-CHO. C. CH2=CH-CH(OH)-CHO. B. CH2=C(OH)-CH2-CHO. D. C A, B, C u ng.

Cu 53: un nng mt ancol n chc X vi dung dch H2SO4 c trong iu kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca Y l A. C3H8O. B. C2H6O. C. CH4O. D. C4H8O. ( ktc) v 5,4 gam nc. C D. 2. Cu 54: Khi thc hin phn ng tch nc i vi ancol X, ch thu c mt anken duy nht. Oxi ho hon ton mt lng cht X thu c 5,6 lt CO2 bao nhiu cng thc cu to ph hp vi X ? A. 5. B. 4. C. 3. Cu 55: Tch nc hon ton t hn hp X gm 2 ancol A v B ta c hn hp Y gm cc olefin. Nu t chy hon ton X th thu c 1,76 gam CO2. Khi t chy hon ton Y th tng khi lng H2O v CO2 sinh ra l A. 1,76 gam B. 2,76 gam. C. 2,48 gam. D. 2,94 gam. 0,32 gam. Hn hp hi thu c D. 0,46. Cu 56: Cho m gam mt ancol no, n chc X qua bnh ng CuO (d), nung nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim c t khi i vi hiro l 15,5. Gi tr ca m l A. 0,92. B. 0,32. C. 0,64. Cu 57: t chy hon ton mt ancol X thu c CO2 v H2O c t l s mol tng ng l 3 : 4. Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO2 thu c ( cng iu kin). Cng thc phn t ca X l A. C3H8O3. B. C3H4O. C. C3H8O2. D. C3H8O. Cu 58: un 12 gam axit axetic vi 13,8 gam etanol (c H 2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l A. 55%. B. 50%. C. 62,5%. D. 75%. Cu 59: un nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH (c H2SO4 lm xc tc, hiu sut phn ng este ho bng 50%). Khi lng este to thnh l

THPTSo1BaoThang.Org Ngi trng chung ca hc tr Vit

Ti liu kha hc : Luyn k nng lm bi trc nghim ha hc A. 6,0 gam. B. 4,4 gam. C. 8,8 gam. D. 5,2 gam.

Cu 60: Khi ln men 1 lt ancol etylic 9,2o thu c dung dch cha x gam axit axetic. Bit hiu sut qu trnh ln men l 80% v khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml. Gi tr ca x l A. 96. B. 76,8. C. 120. D. 80.

P N CC BI TP TRC NGHIM VN 6

1D 11C 21A 31C 41A 51B

2D 12D 22D 32D 42B 52C

3C 13C 23A 33B 43D 53B

4B 14B 24B 34C 44D 54B

5D 15B 25C 35C 45D 55C

6B 16C 26D 36C 46C 56A

7A 17A 27C 37A 47B 57D

8D 18A 28C 38C 48B 58C

9B 19B 29D 39B 49C 59B

10B 20C 30B 40C 50B 60B

Gio vin: Phm Ngc Sn Ngun: Hocmai.vn

THPTSo1BaoThang.Org Ngi trng chung ca hc tr Vit