Thanh Tng_ sv HKHTN_HQGHN_n luyn thi i hc ha hc nm hc 2010. Mi thc mc v bi xin lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.

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BI TP N TP PHN HIROCACBON
I/ L thuyt 1. nh ngha hirocacbon l hp cht hu c cu to bi 2 nguyn t nguyn t H v C 2. Cng thc tng qut ca hirocacbon lun c dng CnH2n+2-2k trong n 1 v k l s lin kt pi +vng v k=( 2sntC+2 sntH)/2 3. Trong phn ny chng ta s nghin cu v hp cht c tn gi l ankan, anken, ankin, ankadddien, xicloankan,.. 4. ANKAN a) nh ngha: ankan l hirocacbon c cng thc tng qut l CnH2n+2 vi n1 v k=0 b) Cu to ha hc :trong phn t ankan ch cha cc lin kt n c c im bn trong cc p ha hc, tnh cht ha hc c trng l p th c) Tnh cht ha hc : - nkan c p th vi Cl2: CnH2n+2n + Cl2 CnH2n+1Cl + HCl - ankan c p cracking to hir hoc to ankan v anken mi VD CnH2n+2 CmH2m+2 +CkH2k vi n3 v m+k =n -ankan c p t chy CnH2n+2 + O2 n CO2 + (n+1) H2O 5. ANKEN a) nh ngha : anken l hirocacbon c cng thc phn t CnH2n vi k n 2 b) Cu to phn t : trong phn t hp cht anken c mt lin kt i v cn li l lin kt n. Lin kt n ny km bn, d b t ra trong cc phn ng ha hc, phn ng c trng l phn ng cng c) Tnh cht ha hc c p cng vi H2; Br2; H2O; HCl. VD; CnH2n + H2 CnH2n+2 c p trng hp to polime, VD: CH2=CH2 -(-CH2-CH2-)nc p oxi ha khng hon ton: anken lm mt mu dd thuc tm KMnO4 c p t chy CnH2n + O2 n CO2 + n H2O (Lu khi t chy anken s mol CO2 thu c lun bng s mol nc) 6. ANKIN a) nh ngha: ankin l hirocacbon c cng thc pt l CnH2n-2 vi n 2 b) Cu to phn t : trong phn t ankin c 1 lin kt 3 cn li l lin kt n, lin kt 3 ny km bn, d b t ra trong cc ha hc, p c trng l p cng c) Tnh cht ha hc ankin c p cng H2, HCl, H2O, Br2(dd) - ankin c p nh hp v tam hp ca axetilen - ankin lm mt mau dd KMnO4 - ankin c p oxi ha hon ton bi oxi v s mol nc tr s mol CO2 bng s mol ankin 7. B sung quy tc cng maccopnhicop : khi cng anken hoc ankin vi H2O; HX ta cng phn cha hiro vo phn cacsbon cha nhiu hio hn

Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng

Thanh Tng_ sv HKHTN_HQGHN_n luyn thi i hc ha hc nm hc 2010. Mi thc mc v bi xin lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com

B/ Bi tp
I/ Bi tp tng hp: ANKAN Dng I: Phn bi tp xc nh cng thc pt hp cht hu c Cu 1. Xc nh CTPT ca ankan trong cc trng hp sau: a) Ankan cha 16% hydro. p s: C7H16 b) Ankan cha 83,33% cacbon. p s: C5H12 c) t chy hon ton 2 lt ankan A c 8 lt H2O (cc kh o cng iu kin nhit , p sut). p s: C3H8 d) t chy hon ton 8,7 gam ankan A c 26,4 gam CO2. p s: C4H10 Cu 2. Hn hp A gm mt ankan v 1 xicloankan, sau phn ng thu c 11,2 lit CO2 (ktc) v 9,9 gam H2O. Thnh phn % th tch ca xicloankan trong A l: Cu 2. Mt ankan to c dn xut monoclo trong clo chim 33,33% v khi lng. Xc nh CTPT ca ankan. p s: C5H12 Cu 3. Mt ankan to c dn xut monobrom trong brom chim 73,39% v khi lng. Xc nh CTPT ca ankan. p s: C2H6 Cu 4. Ankan X c cacbon chim 83,33% khi lng phn t. X tc dng vi brom un nng c chiu sng c th to 4 dn xut ng phn cha mt nguyn t brom trong phn t. Xc nh CTCT v tn X. p s: C5H12 Cu 5. Cho ankan A tc dng brom thu c mt dn xut cha brom c t khi i vi khng kh bng 5,207. Xc nh CTCT v gi tn ca ankan A. p s: C5H12 Cu 6. Mt ankan phn ng vi clo theo t l mol 1 : 2 thu c sn phm cha 83,53% clo v khi lng. CTPT ca ankan l g? p s: CH4 Cu 7. Cho 5,6 lt ankan kh (27,3 oC v 2,2 atm) tc dng vi clo ngoi nh sng ch to mt dn xut clo duy nht c khi lng l 49,5 gam. A) Xc nh CTCT c th c ca ankan. p s: C2H6 B) Xc nh % th tch ca ankan v clo trong hn hp u. Bit t khi hi ca hn hp so vi H2 bng 30,375 . Dng II: PP Trung bnh Cu 1. t chy hon ton hn hp A gm hai ankan thu c 3,36 lt CO2 (ktc) v 3,96 gam H2O. Tnh th tch oxi tham gia phn ng ( ktc) l Cu 2. Cho hn hp X gm 2 ankan ng ng lin tip c khi lng l 20,6 gam v c th tch bng th tch ca 14 gam kh nit ( cng iu kin nhit , p sut). Tm CTPT v % th tch ca mi ankan. Cu 3. t chy hon ton V lt (kc) hn hp 2 hydrocacbon l ng ng lin tip nhau, sn phm chy t t cho qua bnh 1 ng CaCl2 khan v bnh 2 ng KOH d th thy khi lng bnh 1 tng 14,4 gam, bnh 2 tng 22 gam. Tm CTPT v % th tch ca mi hydrocacbon Cu 4. Cho hn hp X gm 2 ankan ng ng lin tip. t chy hon ton 4,12 gam hn hp X to ra 12,32 gam CO2. Tm CTPT v % th tch ca mi ankan. Cu 5. t chy hon ton hn hp 2 hydrocacbon l ng ng lin tip cn 1,35 mol O2 to thnh 0,8 mol CO2. CTPT ca 2 hydrocacbon? p s: C2H6 ; C3H8 Cu 6. t chy hon ton V lt (kc) hn hp 2 hydrocacbon l ng ng lin tip nhau, sn phm chy thu c c t l th tch CO2 v H2O l 12 : 23. Tm CTPT v % th tch ca mi hydrocacbon Cu 7. Hn hp A gm etan v propan. t chy m gam A thu c 8,96 lit CO2 (ktc) v 9,9 gam nc. Thnh phn % khi lng etan trong hn hp l: Cu 8. Hn hp X gm 2 ankan, phn t khi hn km nhau 28 vC. t chy hon ton 1,76 gam hn hp X cn 2,24 lt O2 ( 0oC ; 2 atm). Tm CTPT v % th tch ca mi ankan Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng

Thanh Tng_ sv HKHTN_HQGHN_n luyn thi i hc ha hc nm hc 2010. Mi thc mc v bi xin lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com Cu 9. t chy hon ton hn hp 2 hydrocacbon l ng ng nhau to thnh 22 gam CO2 v 12,6 gam H2O . Xc nh CTPT ca 2 hydrocacbon bit s nguyn t Cacbon trong hai phn t gp i nhau. Cu 10. Hn hp B gm hai ankan c trn theo t l mol 1:2. t chy ht hn hp B thu c 8,96 lit CO2 (ktc) v 9,9 gam H2O. Cng thc phn t ca hai Hidrocacbon l: Dng III: P cracking ankan Cu 1:(H - A- 08) Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y(cc th tch o cng iu kin nhit v p sut), t khi ca Y so vi H2 bng 12. Cng thc ca X l: A. C6H14 B. C3H8 C. C4H10 D. C5H12 Cu 2:(H - B- 08) Ba hiocacbon X,Y,Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X,Y,Z thuc dy ng ng: A. Ankan B. ankadien C. Anken D. Ankin. Cu 3:(H - B- 07) Nhit phn metan thu c hn hp X gm C2H2, CH4 v H2. T khi hi ca X so vi H2 bng 5. Hiu sut qu trnh nhit phn l: A. 50% B. 60% C. 70% D.80%. Cu 4: Thc hin phn ng crackinh hon ton m gam isobutan, thu c hn hp A gm hai hircacbon. Cho hn hp A qua dung dch nc brom c ha tan 11,2 gam brom. Brom b mt mu hon ton. C 2,912 lt kh KTC thot ra khi bnh brom, kh ny c t khi so vi CO2 bng 0,5. Gi tr ca m l: A. 5,22 gam B. 6,96 gam C. 5,80 gam D.4,64 gam. Cu 5: Thc hin phn ng hi ha hn hp M gm etan v propan thu c hn hp N gm bn hicacbon v hir. Gi d l t khi ca M so vi N. Nhn xt no sau y ng? A. 0 < d < 1 B. d > 1 C. d = 1 D.1<d<2. Cu 6: Crackinh 5,8 gam C4H10 c hn hp kh X. Khi lng nc thu c khi t chy hon ton X l: A. 9 gam B. 4,5 gam C. 18 gam D.36 gam Cu 7: Crackinh 0,1 mol n- pentan c hn hp X. t chy ht X ri hp th sn phm chy bi nc vi trong d. Hi khi lng cui cng thu c tng hay gim bao nhiu? A. gim 17,2 gam B. tng 32,8 gam C. tng 10,8 gam D.tng 22 gam. Cu 8: Crackinh V lt butan thu c 35 lt hn hp A gm H2,CH4, C2H4, C3H6, C4H8 v mt phn butan cha b crakinh. Cho hn hp A li rt t t qua bnh ng nc brom d, thy th tch cn li 20 lt. % butan phn ng l? A. 25% B. 60% C. 75% D.85%. Cu 9: Nhit phn 8,8 gam C3H8 ta thu c hn hp A gm CH4, C2H4, C3H6, H2 v C3H8 d cha b nhit phn. T khi ca hn hp A so vi H2 l? A. 11,58 B. 15,58 C. 11,85 D.18,55. Cu 10: Khi crackinh mt ankan kh iu kin thng thu c mt hn hp gm ankan v anken trong c hai cht X v Y c t khi so vi Y l 1,5. Cng thc ca X v Y l? A. C2H6 v C3H8 B. C2H4 V C3H6 C. C4H8V C6H12 D. C3H8 v C5H6. Cu 11: Hn hp kh gm etan v propan c t khi so vi hidro l 20,25 c nung trong bnh kn vi cht xc tc thc hin phn ng hidro ha. Sau mt thi gian thu c hn hp kh c t khi hi so vi H2 l 16,2 gm ankan, anken v hidro. Tnh hiu sut phn ng hidro bit rng tc phn ng ca etan v propan l nh nhau. A. 30% B. 50% C. 25% D.40%. Cu 12: Thc hin phn ng crackinh 11,2 lt hi isopentan KTC, thu c hn hp A ch gm ankan v anken. Trong hn hp A c cha 7,2 gam mt cht X m t chy th thu c 11,2 lt CO2 v 10,8 gam nc. Hiu sut phn ng l: A. 30% B. 50% C. 80% D.40%. Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng

Thanh Tng_ sv HKHTN_HQGHN_n luyn thi i hc ha hc nm hc 2010. Mi thc mc v bi xin lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com Cu 13: Thc hin phn ng crackinh m gam isobutan, thu c hn hp A gm cc hidrocacbon. Dn hn hp A qua bnh nc brom c ha tan 6,4 gam brom. Nc brom mt mu ht, c 4,704 lt hn hp kh B KTC gm cc hidrocacbon thot ra. T khi ca B so vi hidro bng 117/7. Gi tr ca m l: A. 8,7 gam B. 5,8 gam C. 6,96 gam D.10,44 gam. Dng IV: phn ng chy ankan Phn ng t chy c dng: 3n 1 CnH2n+2 + O2 nCO2 + n+1H2O 2 Suy ra: Phng php cn nh ankan khi chy cho nCO2 nH 2O
nankan nH 2O nCO 2

nO2(pu)= nCO2 1/ 2nH 2O

mtan g mCO2 mH 2O mkt

mgiam mkt mCO2 mH 2O

Cu 1. Oxi ha hon ton hydrocacbon X c 11,2 lt CO2 (kc) v 10,8 gam H2O. Xc nh CTCT v tn ca X bit clo ha X ch thu c mt dn xut monoclo duy nht. p s: C5H12 Cu 2. Oxi ha hon ton hydrocacbon X c 2,24 lt CO2 (kc) v 2,16 gam H2O. Xc nh CTCT v tn ca X bit clo ha X theo t l mol 1:1 to 4 sn phm th. p s: C5H12 Cu 3. t chy hon ton mt Hidrocacbon A thu c 2,24 lit CO2 (ktc) v 3,6g H2O. xc nh CTPT A p s: CH4 Cu 4. t chy hon ton mt Hidrocacbon X phi cn 11,2 lit Oxi (ktc), sau phn ng dn sn phm qua bnh nc vi trong d thu c 30 gam kt ta. Cng thc phn t ca X l p s C3H8 Cu 5. t chy hon ton mt Hidrocacbon X phi cn 1,456 lit Oxi (ktc), sau phn ng dn sn phm qua bnh ng H2SO4 c d th khi lng bnh tng 0,9 gam. Cng thc phn t ca X l p s C4H10 Cu 6. t chy hon ton mt Hidrocacbon X phi cn 1,792 lit Oxi (ktc), sau phn ng dn sn phm qua bnh nc vi trong d khi lng bnh tng 3,28 gam. Cng thc phn t ca X l p s C5H12 Cu 7. t chy Hidrocacbon A thu c 3 lit CO2 v 4 lit hi nc, o cng iu kin v nhit p sut. Xc nh CTPT A. p s C3H8 Cu 8. t chy hon ton 0,05 mol ankan A ri dn sn phm chy qua bnh cha nc vi trong d thu c 20 gam kt ta. sau th nghim khi lng bnh tng l. p s 13,3g Cu 9. t chy ht V lt (ktc) hidrocacbon X ri dn sn phm qua bnh cha dung dch Ba(OH)2 d. Sau th nghim thu c 7,88g kt ta, ng thi khi lng dung dch gim 5,22g. Gi tr ca V.p s: 0,224 lit Cu 10.t chy ht V lt (ktc) hidrocacbon X ri dn sn phm qua bnh cha nc vi trong d. Sau th nghim thu c 15 g kt ta, ng thi khi lng dung dch tng 10,2 g. Gi tr ca V.p s: 1,12 lit

II. Bi tp anken
1.Hon thnh dy chuyn ha sau . C2H2 -> C2H4 -> C2H5OH -> C2H4 -> C2H4(OH)2 2.C3H7OH -> C3H6 -> C3H8 -> C2H4 -> C2H5OH. 3.t chy hon ton 2,24 l kh ktc ri hp thu ton b vo dd cha 11,1 g Ca(OH)2 .Hi sau khi hp th khi lng dd tng hoc gim bao nhiu gam ? Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng

Thanh Tng_ sv HKHTN_HQGHN_n luyn thi i hc ha hc nm hc 2010. Mi thc mc v bi xin lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com 4. Hn hp X gm ankan v anken c t l s mol 3:2 .t chy hon ton X , dn hi chy qua dd Ca(OH)2 bnh tng 7,08 g v c 8 g kt ta . Phn dd nc lc tc dng vi Ca(OH)2 d xut hin thm 4 g kt ta na . Tm cng thc phn t mi cht . 5.A l ankan , B l anken u th kh t chy 0,1 mol hn hp ( cha a mol A v b mol B ) thu c khi lng CO2 ln hn nc l 7,6 g t chy 0,1 mol hn hp ( cha a mol A v b mol B ) thu c khi lng CO2 ln hn nc l 6,2 g Tm ctpt A, B .bit s nguyn t trong B ln hn A 6. Hn hp A gm hidro v 1 olefin c t l s mol 1:1 . un nng hn hp A vi niken xc tc thu c hn hp B c t khi so vi hidro l 12,5 . Hiu sut phn ng l h a. Lp biu thc tnh h theo n b.bit h > 70% xc nh cng thc phn t ca olefin v tnh h 7.Ly hai th tch bng nhau ca 1 anken th kh cho p ring r vi dd clo , brom . Khi lng ca hai sn phm cng khc nhau 44 ,5 g a. Tnh th tch anken dng 27,3 0 C v 1 at . Gi s hiu sut p u t 80 % b. Vit cng tha cu to c th c ca anken bit rng khi lng sn phm cng brom thu c l 108 g v nu cho p vi HCl ch thu c 1 sn phm duy nht 8.Hn hp kh A cha 1 ankan v 1 anken .Khi lng hn hp a l 9 g v th tch l 8,96 l . t chy hon ton A thu 13,44 l CO2 . Cc kh u o ktc . Xc nh cng thc v tnh % mi anken 10.cn bao nhiu ml etilen ktc iu ch 1 tn PE . Gi s hiu sut p trng hp t 80 %. 11. Hn hp A gm anken v hidro c t khi so vi hidro bng 9 ,dn hn hp i qua bt niken nung nng n khi p hon ton thu c kh B x t khi so vi H2 bng 15 . Tm ctpt ca X v tnh % th tch ca kh trong A v B . 12.Cho mt lng anken X tc dng vi nc c cht hu c Y , thy khi lng bnh ng nc ban u tng 4,2 g .nu cho lng X nh trn tc dng vi HBr thu c cht Z thy khi lng Y , Z khc nhau 9,45 g .Tm cng thc phn t v gi tn X , gi s cc p xy ra hon ton 13.t chy hon ton 2,24 l ktc mt hidrocacbon X mch h , sau dn sn phm chy ln lt i qua H2SO4 c v dd Ca(OH)2 d .Sau th nghim thy khi lng bnh ng axit tng 5,4 g v bnh Ca(OH)2 c 30 g kt ta .Tm cng thc phn t ca X 14.Cho hn hp 2 anken qua bnh nc brom d . thy khi lng bnh brom tng 16 g . Tng s mol 2 anken l A. 0,1 B .0,2 C.0,05 D. 0,15 15.Hn hp A gm 1 ankan v 1 anken c cng s nguyn t C trong phn t v c cng s mol . Hn hp ny lm mt mu va 80 g dd brom 20 % . Cn t chy hn hp cho 13,44 l CO2 ktc.Ctpt l A.C4H6, C2H4 B.C4H10 ,C4H8 C.C3H8 , C3H6 D. KT QU KHC 16.Mt hn hp gm 3 anken C3H6,C4H8 , C5H10 . Nu t chy hn hp cho 6,72 l hi nc ktc . Nu cho hn hp p vi hidro d c xc tc ,t chy sn phm ri dn sn phm chy vo nc vi trng d , th khi lng kt ta sinh ra l A.30 g B .31g C. 32 g D . 29 g 17.t chy anken X thu 2,24 l CO2 ktc , nu dn ton b sn phm chy vo nc vi trong d th khi lng bnh tng A.6,2 g B.5,2 C.4,2 D. 10 18.Cho 6,72 l hn hp gm 2 anken li qua dd brom d ,thy khi lng bnh tng 16,8 g . Tm cng thc pt ca anken , bit s C mi anken khng qu 5 . A. C2H4 , C4H8 B. C3H6 , C4H8 C . C4H8 , C5 H10 D. kt qu khc Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng

Thanh Tng_ sv HKHTN_HQGHN_n luyn thi i hc ha hc nm hc 2010. Mi thc mc v bi xin lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com 19. Khi t chy mt HC A mch h cn 30 th tch khng kh , sinh ra 4 th tch CO2 . A tc dng vi hidro c xc tc Ni to mt hidrocacbon no mch nhnh .Xc nh ctct ca A bit khng kh chim 20 % th tch 20.dn 3,584 l hn hp X gm 2 anken lin tip nhau trong dy ng ng vo nc brom d thy khi lng bnh ng nc brom tng 10,50 g a. Tm ctpt ca A , B . Bit th tochs kh o 00 C vaf 1,25 at b. Tnh t khi ca hn hp so vi hidro 21. Vit phng trnh cho dy chuyn ha sau

Bi 22 : Hn hp A v B l hai anken c khi lng 12,6g trn theo t l ng mol tc dng va vi 32g brom. Nu trn hn hp trn ng lng th 16,8g hn hp tc dng va vi 0,6g H2. Tm cng thc phn t ca A v B, bit MA < MB. S : C3H6 v C6H12 Bi 23 : C 1,12 lt hn hp X gm H2, ankan, anken (ankan v anken cng s nguyn t cacbon), t khi hi ca X i vi oxi l 0,575. Khi cho 560ml hn hp X i qua bnh brom thy 16g dung dch Br2 5% mt mu ng thi lng bnh tng thm 0,14 gam. 1. Xc nh cng thc phn t ankan, anken. 2. Xc nh thnh phn % ca hn hp ban u theo th tch. Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng

Thanh Tng_ sv HKHTN_HQGHN_n luyn thi i hc ha hc nm hc 2010. Mi thc mc v bi xin lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com 3. Tnh th tch oxi cn t 1,12 lt hn hp X. S : C2H6 v C2H4; %H2=%C2H6=40; %C2H4=20 Bi 24 : hiro ha hon ton 0,7g mt anken cn dng 246,4cm3 hiro ( 27,3oC v 1 atm). Xc nh cng thc phn t. Vit cng thc cu to, bit rng anken c cu to mch thng. S : C5H10 Bi 25 : Cho hn hp A gm C2H4 v H2 qua Ni, c hn hp B c d B/H 2 = 4,5. Nu cho A qua dung dch Br2 d th khi lng bnh brom tng 0,14g. Cc phn ng xy ra hon ton. 1. Tnh khi lng cc cht trong A. 2. Tnh th tch dung dch brom 0,5M ti thiu cn dng. S : 0,14; 0,04; 10ml Bi 26 : Cho hn hp hiro v etilen c t khi hi so vi hiro l 7,5. 1. Tnh thnh phn % th tch kh trong hn hp. 2. Cho hn hp trn vo bnh kn c bt niken nung nng lm xc tc th sau phn ng thu c mt hn hp kh c t khi so vi H2 l 9. Xc nh thnh phn % hn hp kh sau phn ng. S : 50% v 50%; 20%, 40%, 40% Bi 27 : Cho hn hp X gm anken v hiro c t khi so vi heli bng 3,33. Cho X i qua bt niken nung nng th ton b anken b hiro ha c hn hp Y c t khi so vi heli l 4. 1. Tm cng thc phn t ca anken. 2. Suy ra thnh phn ca hn hp. S : C5H10, X (16%, 84%), Y (20%, 80%) Bi 28 : Cho H2 v 1 olefin c th tch bng nhau qua Ni nung nng thu c hn hp A. Bit rng t khi hi ca A i vi H2 l 23,2. Hiu sut phn ng hiro ha l 75%. 1. Tm cng thc v gi tn olefin. 2. t V (lt) hn hp A ni trn ri cho ton b sn phm chy qua 128g dung dch H2SO4 98% sau th nghim nng dung dch H2SO4 l 62,72%. Tnh V (lt) (ktc). S : C4H8; 22,4 lt Bi 29 : Cho hn hp A gm 2 olefin l ng ng k tip nhau tham gia phn ng hp nc c xc tc th c hn hp ancol B. Cho B tc dng vi Na thu c 5,6 lt kh (ktc). Mt khc nu t chy hon ton hn hp A ri cho ton b sn phm chy hp th ht vo nc vi trong th thu c 75g mui trung tnh v 40,5g mui axit. 1. xc nh cng thc 2 olefin. 2. Tm % khi lng v th tch tng olefin trong A. S : C2H4 v C3H6, 50% Bi 30 : t chy hon ton 0,672 lt hn hp gm hirocacbon v nit th thu c 0,88g CO2 v 0,36g H2O. Bit khi lng hn hp l 0,84g v th tch o (ktc). 1. Tm cng thc phn t ca hirocacbon. 2. Suy ra thnh phn hn hp. S : C2H4, 33,33% v 66,67% Bi 31: Cho hn hp kh A (ktc) gm 2 olefin. t chy hon ton 7 th tch A cn 31 th tch oxi (ktc). 1. Xc nh cng thc phn t 2 olefin. Bit rng olefin nhiu cacbon chim t l trong 40 50% th tch ca A. 2. Tm % khi lng cc olefin trong A. S : C2H4 v C4H8; 35,5% v 64,5% Bi 32 : Khi t chy mt th tch hirocacbon A cn 6 th tch oxi v sinh ra 4 th tch CO2. A c th lm mt mu dung dch brom c ni i v c th kt hp vi hiro to thnh mt hirocacbon no mch nhnh. Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng

Thanh Tng_ sv HKHTN_HQGHN_n luyn thi i hc ha hc nm hc 2010. Mi thc mc v bi xin lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com Xc nh cng thc cu to ca A v vit cc phng trnh phn ng. S : C4H8 Bi 33 : Cho 2,24 lt mt hn hp kh A (ktc) gm etan, propan, propilen sc qua dung dch brom d, thy khi lng bnh tng thm 2,1g. Nu t chy kh cn li thu c mt lng CO2 v 3,24g H2O. 1. Tnh thnh phn % th tch mi kh. 2. Dn lng CO2 ni trn vo bnh ng 200ml dung dch KOH 2,6M. Hy xc nh nng M cc cht trong dung dch sau phn ng. S : 50%, 20%, 30%, 0,65M. 1,3M Bi 34 : Mt hn hp X gm ankan A v anken B, s nguyn t hiro trong phn t A bng s nguyn t cacbon trong B. Khi t chy 3g hn hp X th thu c 5,4g nc. Xc nh cng thc phn t A, B v tnh % th tch cc kh trong hn hp A. S : CH4 v C4H8; 80% v 20% Bi 35 : Mt hn hp gm H2, mt ankan v mt anken ( c cng s nguyn t cacbon vi ankan). Khi t 100ml hn hp thu c 210ml kh CO2. Mt khc khi nung nng 100ml hn hp vi Ni th sau phn ng cn li 70ml mt hirocacbon duy nht. 1. Tm cng thc phn t ca ankan v anken. 2. nh % th tch ca ankan v anken. 3. Tnh th tch O2 cn t chy 10ml hn hp (cc kh o cng iu kin) S : C3H6 v C3H8; 30%, 40%, 350ml Bi 36 : Mt hn hp kh gm nit v mt hirocacbon; 0,42g hn hp chim th tch 336cm3 (ktc). t chy lng hn hp ngi ta c 0,44g CO2 v 0,18g H2O. 1. Xc nh thnh phn nguyn t ca hirocacbon v cng thc nguyn ca n. 2. Xc nh khi lng phn t v cng thc cu to. S : 85,72%, 14,28%, C2H4 Bi 37 : t chy hon ton 0,25 mol kh A thu c 33g CO2 v 13,5g hi nc. 1. Tm cng thc phn t v cng th cu to ca A, bit rng (ktc) khi lng ring ca A l 1,875g/l. 2. Tnh khi lng sn phm to thnh khi cho lng cht A trn qua dung dch brom d. S : C3H6 ; 50g Bi 38 : Hai hirocacbon A v B u th kh, A c cng thc C2xHy; B c cng thc CxH2x (tr s x trong c 2 cng thc l bng nhau). 1. Lp cng thc phn t A v B. Bit rng t khi ca A i vi metan bng 3,625 v t khi ca B i vi He l 7. Vit cng thc cu to ca A v B. 2. Tnh lng sn phm thu c khi cho hn hp trn tc dng va vi 16g dung dch brom. S : x=2, y=10, 18,8g Bi 39 : t chy hon ton 0,03696 lt anken X 27,3oC v 1 atm, thu ton b kh CO2 vo dung dch KOH ta c 0,3g mui axit v 0,207g mui trung tnh. Xc nh cng thc phn t v cng thc cu to ca X. S : C3H6 Bi 40 : Cho 3,5g mt anken tc dng vi dung dch KMnO4 long th c 5,2g sn phm hu c. 1. Tm cng thc phn t ca anken. 2. Tnh th tch oxi (ktc) cn thit t chy ht lng anken trn. S : C5H10 v 8,4ml Bi 41 : Mt hn hp hai olefin ng ng k tip nhau c th tch 17,92 lt (o 0oC v 2,5 atm) dn qua bnh cha dung dch KMnO4 d, thy khi lng bnh cha dung dch KMnO4 tng 70g. Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng

Thanh Tng_ sv HKHTN_HQGHN_n luyn thi i hc ha hc nm hc 2010. Mi thc mc v bi xin lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com 1. Xc nh cng thc phn t, vit cng thc cu to hai olefin. 2. Tnh % khi lng 2 olefin trong hn hp. 3. t chy hon ton th tch trn ca hn hp ri cho sn phm vo 5 lt dung dch NaOH 1,8M s thu c mui g? Bao nhiu gam? S : C3H6 v C2H4; 40% v 60%; 424g v 84g Bi 42 : Mt hn hp X gm CO v mt hirocacbon A mch h. t chy hon ton 1,96g hn hp X c 4,84g CO2 v 1,44g H2O. 1. Tm dy ng ng ca A. 2. Tm cng thc phn t ca A, bit d X/H 2 = 19,6. S : CnH2n; C4H8 Bi 43 : Dn 2,24 lt mt anken A (ktc) qua bt CuO nung nng, khi lng bt CuO gim 14,4g. Phn ng hon ton. 1. Tm cng thc phn t ca A. 2. Vit phng trnh phn ng trng hp, phn ng ca A vi dung dch KMnO4. 3. Hn hp A vi mt ng ng B trn theo t l mol 1:1. t chy hon ton mt th tch hn hp cn 3,75 th tch oxi trong cng iu kin. Hy gi tn B. S : C3H6, C2H4 Bi 44 : t chy hon ton a gam cht hu c A cn dng 6,72 lt O2 (ktc). Sn phm chy ln lt qua bnh P2O5 thy bnh tng 3,6g ri qua bnh nc vi trong thy xut hin 20g kt ta trng. 1. Tnh s gam a? 2. Lp cng thc thc nghim ri suy ra cng thc phn t ca A, bit t khi hi ca A so vi nit l 2. 3. Vit cng thc cu to c th c, suy ra cng thc ng ca A, bit A cng vi H2O cho 1 sn phm duy nht. S : 2,8; C4H8 Bi 45 : Hn hp X gm 2 hirocacbon A v B (B c s cacbon ln hn A, A v B u phn ng vi dung dch Br2). 8,96 lt hn hp X tc dng ht vi nc brom cn ti thiu 64g brom. Mt khc, em t 8,96 lt hn hp X tng s CO2 thu c l 48,4g. Hiu s hi nc sinh ra ca B so vi A l 12,6g. Xc nh cng thc phn t ca A, B. S : C3H6; C2H4

III. Bi tp v ankin
Cu 01. Vit phng trnh minh ha cho dy chuyn ha

Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng

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Cu 2: Khi t chy mt hirocacbon X ta thu c CO2, H2O vi t l s mol CO2:H2O l 2. X l hirocacbon no sau y? A. C2H4 B. C2H2 C. C3H6 D. C4H8 Cu 3: t chy hon ton 1 ankin (kc) thu c 22g CO2 v 7,2g H2O. CTPT ca ankin l: A. C4H6 B. C3H4 C. C5H8 D. C2H2 Cu 4: t chy mt ankin mch h X thu c lng nc c khi lng ng bng khi lng X em t. Bit X c kh nng tc dng vi dung dch AgNO3 trong NH3 to kt ta. CTCT ca X l g? A. CH CH B. CH C - CH3 C. CH C - CH2 - CH3 D. CH C - (CH2)2 - CH3 Cu 5: Cho 0,3 mol hn hp gm propin v ankin X phn ng va vi dung dch cha 0,2 mol AgNO3 /NH3 . Cht X l: A. Axetylen B. But-1-in C. But-2-in D. Pent-1-in Cu 6: Mt hn hp X gm 2 ankin l ng ng k tip nhau. Ho hi hn hp X c 5,6 lt (o iu kin tiu chun) ri dn qua bnh dung dch Br2 (ly d) th thy khi lng bnh tng 8,6 gam. Cng thc phn t 2 ankin l:

Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng

Thanh Tng_ sv HKHTN_HQGHN_n luyn thi i hc ha hc nm hc 2010. Mi thc mc v bi xin lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com
A. C2H2 v C3H4 B. C3H4 v C4H6 C. C4H6 v C5 H8 D. C5H8 v C6H10 Cu 7: t chy 6,72 lt kh ( ktc) 2 hidrocacbon cng dy ng ng to thnh 39,6 gam CO 2 v 10,8 gam H2O. Cng thc phn t 2 hidrocacbon l: A. C2H6; C3H8 B. C2H2; C3H4 C. C3H8; C5H12 D. C2H2; C4H6 Cu 8: t chy hon ton V lt (kc) mt ankin thu c 10,8g H 2 O. Tt c sn phm chy cho hp th ht vo bnh nc vi trong thy khi lng bnh tng 50,4g. V c gi tr l: A. 6,72 lt B. 4,48 lt C. 13,44 lt D. 12 lt Cu 9: t chy hon ton Vlt (ktc) mt ankin thu c 5,4g H2O. Tt c sn phm chy cho hp th vo ht dung dch nc vi trong thy khi lng bnh tng 25,2g. V c gi tr l bao nhiu? A. 3,36 lt B. 2,24 lt C. 6,72 lt D. 6 lt Cu 10: Hn hp X gm propin v but-2-in li tht chm qua bnh dd AgNO3/NH3 d thy c 44,1 g kt ta. %V mi kh trong hn hp X l: A. 80%; 20% B. 25%; 75% C. 68,96%; 31,04% D. Kt qu khc Cu 11: t chy hon ton 0,1 mol ankin c 0,2 mol nc. Nu hiro ho hon ton 0,1 mol ankin ny ri t chy th s mol nc thu c l: A. 0.3mol B. 0.4mol C. 0.5mol D. 0.6mol Cu 12: Hn hp X gm 0,2 mol C2H2 v 0,3 mol H2 c dn qua ng ng bt Ni nung nng thu c hn hp Y gm C2H6, C2H4, C2H2 v H2. S mol xi cn dng t chy hn hp Y l: A. 0,65mol B. 0,75 mol C. 0,55mol D. 0,45 mol Cu 13: Cho 13,44 lt kh hn hp gm mt ankin v 1 ankan kc i qua bnh ng nc Brm d, thy c 8,96 lt kh thot ra kc. Khi lng brm tham gia p l: A.64g B. 70g C. 65g D. 74g Cu 14: t chy hon ton 4,48 lit ankin(kc) thu c 7,2g H2O . Nu hiro ho hon ton 4,48 lit ankin ny ri t chy th lng nc thu c l: A. 9g B. 14,4g C. 7,2g D. 21,6g Cu 15: Chia hn hp ankin C3H4 v C4H6 thnh 2 phn u nhau. Phn 1 em t chy han tan thu c 3,08 gam CO2 v 0,9 gam H2O. Phn 2 dn qua dung dch Br2 d th lng Brm phn ng l bao nhiu? A. 3,8 gam B. 6,4 gam C. 3,2 gam D. 6,8 gam Cu 16: iu ch 5,1617 lt axetilen(ktc) vi hiu sut 95% cn lng CaC2 cha 10% tp cht l: A. 17,6g B. 15g C. 16,54g D. Kt qu khc. Cu 17: A l mt hirocacbon, th tch metylaxetilen bng 1,75 th tch hi A c cng khi lng trong cng iu kin. S ng phn mch h ca A l: A. 6 B. 5 C. 4 D. 3 Cu 18: Hn hp X gm 2 Hyr cacbon k tip nhau trong dy ng ng. t chy hon ton X th th tch kh CO2 sinh ra bng th tch O2 cn dng t chy ht X. CTPT ca 2 Hyr cacbon trong X l: A- C2H6 v C3H6 B- C2H2 v C3H4. C- C4H8 v C5H10 D- C A, B, C Cu 19: Mt hirocacbon A mch h, th kh. Khi lng ca V lt kh ny bng 2 ln khi lng ca V lt kh N2 cng iu kin nhit , p sut. Cng thc phn t ca hirocacbon l g? A. C2H6 B. C2H4 C. C4H10 D. C4H8 Cu 20: t chy hon ton 0,25 mol hn hp khi gm ankin A v anken B thu c sn phm ln lt qua bnh 1 ng P2O5 d v bnh 2 ng KOH d m c th thy bnh 1 tng 11,7 gam; bnh 02 tng 30,8 gam Xc nh cng thc phn t ca A,B bit rng A km B mt nguyn t C Cu 21: mt hn hp axetilen ,propen, metan - t chy hon ton 11gam hn hp th thu c 12,6 gam nc - mt khc 5,6 l (ktc) phn ng va vi dd cha 50 g Br2 Xc nh thnh phn th tch hn hp u Cu 22: mt hn hp kh X gm mt ankan, mt anken, mt ankin c th tch 1,792 l (ktc) c chia thnh 2 phn bng nhau

Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng

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- phn 01 cho qua dd AgNO3 trong NH3 d to ra 0,735 g kt ta v th tch hn hp gim 12,5% - phn 2 em t chy hon ton ri hp th ton b sn phm vo 9,2 l dd Ca(OH)2 0,0125M thy c 11 g kt ta Xc nh cng thc phn t ca cc hirocacbon Cu 23: t chy hon ton hn hp X gm 2 hirocacbon thuc cng dy ng ng thu c 19,712 lit CO2(ktc) v 10,08 g nc a) Xc nh ng ng ca A,B bit rng chng c th l ankan, anken, ankin b) Xc nh CTPT, CTCT c th c ca A,B bit chng th kh k thng c) Chn cng thc ng ca A,B bit rng khi cho lng hn hp X tc dng vi

AgNO3 trong NH3 d th ta c 4,8 g kt ta Cu 24: dn ton b 6,72 l hn hp gm 2 ankin cho qua dd AgNO3 th thy c 2,24 l kh thot ra c khi lng ng bng khi lng ca 7,56 l khi CH4 ng thi thu c 29,4 g kt ta, xc nh cng thc cu to ca ankin Cu 25: A l hn hp gm 2 hirocacbon th kh cng dy ng ng ankan, anken, ankin. t chy hon ton A sau dn qua ng ng P2O5 d ri ng ng NaOH d th thy ng 1 tng 9 g cn ng 2 tng 30,8 g a) Xc nh cng thc phn t ca hn hp A b) Xc nh cng thc cu to ng cc cht trong A bit rng khi chng tc dng vi AgNO3/NH3 d th thu c 14,7 g kt ta

BI TP B SUNG
Cu 1: Cho cc cht sau: CH 3 - CH = CH CH 3 CH =C(CH 3 )
2 2

(1) ; CH 3 - CH = CHCl (2) ;

(3) ;

CH3
C=C

CH3
(4)

CH3
C=C

Cl
(5)

C2H5

C2H5

C2H5

Cht c ng cis-trans l: A.(1), (2) v (3) B.(2), (4) v (5) C.(1), (4) v (5) D.(2), (3) v (4) Cu 2: Hirocacbon c cng thc phn t C 4 H 8 v c tnh i xng phn t cao nht trong s cc ng phn mch h c tn gi no sau y? A. Cis but 2 en B. Trans but 2 en C. 2-metyl but-2-en D. But-2-en Cu 3: S ng phn mch h c cng thc C5H10 l: A. 3 B. 5 C. 8 D. Kt qu khc Cu 4: C5H10 c bao nhiu /phn anken khi cng vi HCl to sp trong clo lin kt vi cacbon bc 3? A. 1 B. 2 C. 3 D. 4 Cu 5: c tn hp cht sau theo danh php IUPAC

CH3 C=C Cl

CH3 Br

A. 2- Brom-3- clobut-2-en B. 2,3-brom clo-2- buten C. cis-2-brom-3-clobut-2-en D. Cis-3-clo-2-brombut-2-en Cu 6: Khi cng HBr vo 2-metylbut-2-en theo t l 1 : 1, s lng sn phm thu c l bao nhiu?

Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng

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A. 1 B. 2 C. 3 D. 4 Cu 7: iu ch etilen trong phng th nghim t ( c, ) thng ln cc oxit nh . Chn mt trong s cc cht sau loi b A. Dd brom d B. Dd NaOH d C. Dd Na2CO3 d D. Dd KMnO4 long, d Cu 8: Mt hiro cacbon (X) th kh c cng thc phn t dng C x 1 H 3 x . CTPT ng ca (X) l: A. CH 4 B. C 2 H 4 C.C 2 H 6 D.C 3 H 6 Cu 9: i vi Ankin, nguyn t cacbon lin kt ba trng thi lai ho no? A. sp B. sp2 C. sp3 D. sp4 Cu 10: C bao nhiu ng phn cu to, mch h c cng thc phn t C5H8 tc dng vi H2 d (Ni, ) thu c sn phm l isopentan? A. 3 B. 4 C. 5 D. 6 Cu 11: Thc hin th nghim sau : thu vo bnh nn th tch kh C2H2 v th tch kh Cl2 .y bnh bng nt bc. Ly tay m ming bnh v a ngn la que m vo gn ming bnh. Tip tc a vo ming bnh giy qu tm t. Cho bit hin tng g xy ra?

Cl2

C2H2

A. Qu tm khng i mu, v sn phm ca phn ng l ClCH=ChCl khng phi l axit hoc baz . B. Thnh bnh c nhiu mui than, qu tm chuyn sang mu v xy ra phn ng : CHCH + Cl2 2C + 2HCl C. Khng c hin tng g xy ra, qu tm khng i mu . D. Qu tm khng i mu v xy ra phn ng: CHCH + Cl2 Cl2CH-CHCl2 Cu 12: Hn hp gm C2H4, C2H6, C2H2 , tinh ch C2H6 ngi ta cho hn hp li chm qua : A. dd KMnO4. B. Dd Br2. C. dd AgNO3/NH3; dd Br2. D. A,B,C. Cu 13 : t chy hon ton mt hirocacbon X ri dn ton b sn phm chy qua bnh cha CaCl 2 khan v d2 NaOH th thy khi lng cc bnh tng ln lt l 0,72g v 2,2g. Dy ng ng ca X: A. Ankan B. Anken C. Ankin D. Xyclo ankan Cu 14: Cng thc tng qut ca hydrocacbon c dng CnH2n + 2 2a . Gi tr a = 2 ng vi : A. xiclopentan B. 2-metyl butadien-1,3 C. vinylaxetylen D. xiclohexan Cu 15: Isopren c th cng hp brm theo t l s mol 1:1 to thnh cc ng phn v tr. S ng phn v tr l : A. 1 B. 2 C. 3 D. 4 Cu 16: Cao su isopren v cao su buna khc nhau ch: A.Cu trc lp th B. Thnh phn monome C.Cng thc cu to ca cc mt xch D. Ch c tn thng mi Cu 17: Mt hn hp X gm anken v H2. Khi t chy hon ton 2,24lt kh X(dktc) vi lng d oxi ri cho sn phm chy i qua dung dch Ba(OH)2 d th c 31,52g kt ta. Sau khi lc kt ta, khi lng dung dch cn li nh hn khi lng dung dch ban u l 20,52g. Vy, CTPT ca A l: A. C2H4 B. C3H6 C. C4H8 D. C5H10 Cu 18: Cho 5,6 lt hn hp 2 olefin l ng ng lin tip hp nc (c xc tc) c hn hp 2 ru. Thu hn hp 2 ru ny dng khan ri chia lm 2 phn bng nhau. Phn 1 phn ng ht vi Na d thu c 840 ml kh. t chy ht phn 2 ri cho ton b sn phm chy hp th vo bnh ng NaOH d th khi lng bnh NaOH tng 13,75 gam. Cng thc phn t ca 2 olefin l: A. C2H4; C3H6 B. C3H6; C4H8 C. C4H8; C5H10 D. C5H10; C6H12 Cu 19: t chy hon ton a gam hn hp C2H4, C3H6, C4H8, C5H10 cn 24,99 lt O2(ktc) thu c 16,8 lt CO2( ktc). Hi a c gi tr bao nhiu? A. 7,5g B. 10,5g C. 4g D. 12g Cu 20: t chy hon ton hn hp 2 anken thu c 7,2 gam nc. Dn ton b kh CO 2 va thu c vo dung dch Ca(OH)2 d th thu c bao nhiu gam kt ta?

Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng

Thanh Tng_ sv HKHTN_HQGHN_n luyn thi i hc ha hc nm hc 2010. Mi thc mc v bi xin lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com
A. 40 gam B. 20 gam C. 100 gam D. 200 gam Cu 21: t chy hon ton V lt C3H6 ( ktc) ri cho ton b sn phm chy hp th ht vo dung dch c cha 102,6 gam Ba(OH)2 th thu c lng kt ta cc i. V c gi tr no sau y? A. 2,24 lt B. 4,48 lt C. 5,6 lt D. 8,96 lt Cu 22: Hn hp A gm Buten-2 v Propen. Sau khi hirat ha hon ton hn hp A, thu c h2 B gm ba cht hu c. t chy hon ton h2 B, ch thu c x mol CO2 v y mol H2O. Chn kt lun ng: A. x = y B. x > y C. A, B u sai D. x c th bng, ln hn hoc nh hn y l cn ph thuc vo s mol mi cht trong hn hp B Cu 23: Cho polivinyl clorua ( - CH 2 -CHCl-) n tc dng vi kh Clo ngi ta c mt polime c cha 66,77% Clo trong phn t. Tnh xem trung bnh mt phn t Clo tc dng vi my mc xch CH 2 -CHCl-. Gi thuyt rng h s trng hp n khng thay i trong phn ng. A. 2 B. 3 C. 4 D. 5 Cu 24: Bit 1 mol kh etilen chy hon ton to ra 1 nhit lng l 1423kj. Nhit lng to ra khi t chy 1 kg etilen l : A. 50821,4kj B. 50281,4kj C. 50128,4kj D. 50812,4kj Cu 25: t chy hon ton Vlt (kc) mt ankin th kh thu c H O v CO c tng khi lng l 92g. Nu cho sn phm chy i qua dung dch Ca(OH)2 d, thu c 160g kt ta. CTPT ca ankin l: A. C H B. C H C. C H D. C H 0 Cu 26: Oxi ha hon ton 0,1344 lt mt ankin A ( 273 c v 1 atm) ri dn tt c kh CO2 sinh ra vo dung dch Ca(OH)2 th thu c 0,729g mui trung ha v 0,3g mui axit. Cng thc phn t ca A: A. C3H4 B. C3H6 C. C5H10 D. C4H6 Cu 27: Cht A c cng thc phn t C6H6. 1 mol A tc dng vi AgNO3 d trong dung dch NH3 to ra 292 gam kt ta. Cht A l : A. Hexadiin-1,5 B. Hexadiin-1,4 C. Hexadiin-1,3 D. Mt cht khc Cu 28: Trong mt bnh kn cha hn hp A gm hirocacbon X v H2 vi Ni. Nung nng bnh 1 thi gian ta thu c 1 kh B duy nht. t chy B, thu c 8,8 gam CO2 v 5,4 gam nc. Bit VA = 3VB. Cng thc ca X l: A. C3H4 B. C3H8 C. C2H2 D. C2H4 Cu 29: Cho135ml hn hp kh A gm H2, mt olefin v mt ankin i qua ng c Ni nung nng, sau phn ng ch cn 60ml mt hirocacbon duy nht. Mt khc, nu t chy hon ton 60ml hn hp A th thu c 80ml CO2. Cc th tch o cng iu kin. Vy, CTPT ca hai hirocacbon: A. C2H2 ; C2H4 B. C3H4 ; C3H6 C. C2H2 ; C6H6 D. kin khc Cu 30: Chia hn hp gm C2H2, C2H4 v C2H6 thnh hai phn u nhau. Phn 1, em t chy hon ton thu c 22,4 lt CO2(ktc). Phn 2, em hiro ho hon ton, sau t chy ht th thu c th tch CO2(ktc) l: A. 22,4lt B. 11,2lt C. 33,6lt D. 44,8lt Cu 31: Hn hp X gm 3 kh C3H4, C2H2, H2 cho vo bnh kn dung tch 9,7744 lit 250C p sut 1 atm cha 1 t Ni nung nng bnh mt thi gian thu c h2 kh Y, bit dX/Y=0,75. S mol H2 tham gia p l : A. 0,75mol B. 0,3mol C. 0,15mol D. Kt qu khc. Cu 32: Hn hp A gm Etan, Etilen, Axetilen v Butaien-1,3. t chy ht m gam hn hp A. Cho sn phm chy hp th vo dung dch nc vi d, thu c 100 gam kt ta v khi lng dung dch nc vi sau phn ng gim 39,8 gam. Tr s ca m l: A. 58,75g B. 13,8g C. 60,2g D. 37,4g

Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng

Thanh Tng_ sv HKHTN_HQGHN_n luyn thi i hc ha hc nm hc 2010. Mi thc mc v bi xin lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com
Cu 33: Trong mt bnh kn dung tch khng i cha hn hp xi d v mt ankadien lin hp A theo t l th tch 9:1 nhit to C v p sut p atm. Bt tia la in t chy ht A ri a nhit bnh v toC th p sut trong bnh lc ny bng 21p:20 atm. Cc cht u th kh. Tn cht A l: A. propanien. B. ivinyl C. penta-1,3-ien. D. buta-1,2-ien. Cu 34: Cho V lt ( iu kin tiu chun) hn hp kh gm 2 olefin lin tip nhau trong dy ng ng hp nc (c H2SO4 long xc tc) thu c 6,45 gam hn hp A gm 3 ru. em un hn hp A trong H2SO4 c 1400C th thu c 5,325 gam B gm 6 ete khan. Gi thit hiu sut ca tt c cc loi phn ng u t 100%. Cho bit cng thc cu to ca cc ru? A. CH3OH v CH3-CH2-CH2-CH2-OH B. C2H5OH; CH2=CH-CH2-OH v C4H9OH C. CH2=CH-OH; CH3OH v C2H5OH D. Kt qu khc Cu 35: Hn hp X gm 2 hidrocacbon A, B c cng s nguyn t cacbon v c s lin kt pi hm km nhau 1 n v . t 8.96 lit hh X cn 36,08 lt O2 v sn phm chy khi cho qua P2O5 th khi lng tng 18 g.(cc kh o ktc) a. CTPT ca A & B l : A. C3H4 & C3H6 B. C2H2 & C2H4 C. C4H6 & C4H8 D. Tt c u sai b. Nu thm 1 hidrocacbon D vo 8.96 lit hh X th thu c hh Y. t Y thu c 66 g CO 2 & 35.2 g H2O. CTPT ca D l : A.C2H10 B.C3H8 C.C2H6 D. Tt c u sai c. Thnh phn % V hh Y (A, B ,D) ln lt l : A.40/40/20 B.30/40/30 C.10/60/30 D. Tt c u sai

Mi s khi u u gian nan vt v. Hy c gng v chn cho mnh con ng ngn nht n thnh cng