ANCOL (RU), PHENOL. Cu 1: .

(KB-08) Cho cc phn ng: t0 HBr + C2H5OH ; C2H4 + Br2 C2H4 + HBr askt(1:1mol) C2H6 + Br2 S phn ng to ra C2H5Br l : A. 4. B. 3. C. 2. D. 1. Cu 2: (C-07) Cho cc cht c cng thc cu to nh sau: HOCH2-CH2OH (X); HOCH2-CH2-CH2OH (Y); HOCH2-CHOH-CH2OH (Z); CH3-CH2-OCH2-CH3 (R); CH3-CHOH-CH2OH (T). Nhng cht tc dng c vi Cu(OH)2 to thnh dung dch mu xanh lam l A. X, Y, R, T. B. X, Z, T. C. Z, R, T. D. X, Y, Z, T. Cu 3: (KB-09) Cho cc hp cht sau : (a) HOCH2-CH2OH (b) HOCH2-CH2-CH2OH (c) HOCH2-CH(OH)-CH2OH (d) CH3-CH(OH)-CH2OH (e) CH3-CH2OH (f) CH3-O-CH2CH3Cc cht u tc dng c vi Na, Cu(OH)2 l A. (c), (d), (f) B. (a), (b), (c) C. (a), (c), (d) D. (c), (d), (e) Cu 4: Dy gm cc cht u tc dng vi ancol etylic l: A. NaOH, K, MgO, HCOOH (xc tc). B. Na2CO3, CuO (to), CH3COOH (xc tc), (CH3CO)2O. C. Ca, CuO (to), C6H5OH (phenol), HOCH2CH2OH. D. HBr (to), Na, CuO (to), CH3COOH (xc tc). Cu 5: (KB-2010) Cho cac cht : (1) axit picric; (2) cumen; (3) xiclohexanol; (4) 1,2-ihiroxi-4metylbenzen; (5) 4-metylphenol; (6) -naphtol. Cac cht thuc loai phenol la: A. (1), (3), (5), (6) B. (1), (2), (4), (6) C. (1), (2), (4), (5) D. (1), (4), (5), (6) Cu 6: (KB-08) un nng mt ancol (ru) n chc X vi dung dch H2SO4 c trong iu kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca X l A. C3H8O. B. C2H6O. C. CH4O. D. C4H8O. Cu 7: (C-2010) Oxi ho khng hon ton ancol isopropylic bng CuO nung nng, thu c cht hu c X. Tn gi ca X l A. metyl phenyl xeton B. propanal C. metyl vinyl xeton D. imetyl xeton Cu 8: (KB-07) Cho glixerol (glixerin) phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi trieste c to ra ti a l A. 6. B. 3. C. 4. D. 5. Cu 9: (C-2010) Phat biu ung la A. Phenol phan ng c vi dung dich NaHCO3 B. Phenol phan ng c vi nc brom C. Vinyl axetat phan ng vi dung dich NaOH sinh ra ancol etylic D. Thuy phn benzyl clorua thu c phenol Cu 10: (KA-2010) Trong s cac phat biu sau v phenol (C6H5OH): (1) Phenol tan it trong nc nhng tan nhiu trong dung dich HCl (2) Phenol co tinh axit, dung dich phenol khng lam i mau quy tim (3) Phenol dung san xut keo dan, cht dit nm mc (4) Phenol tham gia phan ng th brom va th nitro d hn benzen Cac phat biu ung la A. (1), (2), (4) B. (2), (3), (4) C. (1), (2), (3) D. (1), (3), (4) Cu 11: (KB-07) Dy gm cc cht u phn ng vi phenol l: A. dung dch NaCl, dung dch NaOH, kim loi Na. B. nc brom, axit axetic, dung dch NaOH. C. nc brom, anhirit axetic, dung dch NaOH. D. nc brom, anehit axetic, dung dch NaOH. Cu 12: (KA-09) Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung dch NaHCO3. Tn gi ca X l A. metyl axetat. B. axit acrylic. C. anilin. D. phenol. Cu 13: (KB-08) nh hng ca nhm OH n gc C6H5- trong phn t phenol th hin qua phn ng gia phenol vi A. dung dch NaOH. B. Na kim loi. C. nc Br2. D. H2 (Ni, nung nng). + Br2 (1:1mol),Fe,t 0 + NaOH (d ),t 0 ,p + HCl(d) X Y Z Cu 14: (KB-08) Cho s chuyn ho sau: Toluen Trong X, Y, Z u l hn hp ca cc cht hu c. Z c thnh phn chnh gm A. m-metylphenol v o-metylphenol. B. benzyl bromua v o-bromtoluen. C. o-bromtoluen v p-bromtoluen. D. o-metylphenol v p-metylphenol.

+ NaOH (du ) +X t0 Cu 15: (KA-09) Cho dy chuyn ha sau: Phenol Phenyl axetat Y (hp cht thm) Hai cht X,Y trong s trn ln lt l A. anhirit axetic, phenol. B. anhirit axetic, natri phenolat C. axit axetic, natri phenolat. D. axit axetic, phenol. Cu 16: .(C-09) Trong thc t, phenol c dng sn xut A. poli(phenol-fomanehit), cht dit c 2,4-D v axit picric B. nha rezol, nha rezit v thuc tr su 666 C. nha poli(vinyl clorua), nha novolac v cht dit c 2,4-D D. nha rezit, cht dit c 2,4-D v thuc n TNT Cu 17: (C-2010) Cho 10 ml dung dich ancol etylic 460 phan ng ht vi kim lai Na (d), thu c V lit khi H2 (ktc). Bit khi lng ring cua ancol etylic nguyn cht bng 0,8 g/ml. Gia tri cua V la A. 4,256 B. 0,896 C. 3,360 D. 2,128 Cu 18: (C-08) Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy nht l xeton Y (t khi hi ca Y so vi hiro bng 29). Cng thc cu to ca X l A. CH3-CHOH-CH3 B. CH3-CH2-CHOH-CH3 C. CH3-CO-CH3 D. CH3-CH2-CH2-OH Cu 19: (C-07) Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn hp Z gm hai ancol (ru) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (Cho : H = 1 ; C = 12 ; O = 16 ; th tch dung dch thay i khng ng k) A. C2H5OH v C3H7OH. B. C3H7OH v C4H9OH. C. C2H5OH v C4H9OH. D. C4H9OH v C5H11OH. Cu 20: (KB-08) Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l A. 76,6%. B. 80,0%. C. 65,5%. D. 70,4%. Cu 21: .(KA-07) Cho 15,6 gam hn hp hai ancol (ru) n chc, k tip nhau trong dy ng ng tc dng ht vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l (cho O = 16, Na = 23) A. C3H5OH v C4H7OH. B. C2H5OH v C3H7OH. C. C3H7OH v C4H9OH. D. CH3OH v C2H5OH. Cu 22: .(KB-08) un nng hn hp gm hai ancol (ru) n chc, mch h, k tip nhau trong dy ng ng vi H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v 1,8 gam nc. Cng thc phn t ca hai ru trn l A. CH3OH v C2H5OH. B. C2H5OH v C3H7OH. C. C3H5OH v C4H7OH. D. C3H7OH v C4H9OH. Cu 23: (C-08) t chy hon ton hn hp M gm hai ancol (ru) X v Y l ng ng k tip ca nhau, thu c 0,3 mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol hn hp M tc dng vi Na (d), thu c cha n 0,15 mol H2. Cng thc phn t ca X, Y l : A. C2H6O2, C3H8O B. C2H6O, CH4O C. C3H6O, C4H8O D. C2H6O, C3H8O Cu 24: (KA-2010) Oxi hoa ht 2,2 gam hn hp hai ancol n chc thanh anehit cn va u 4,8 gam CuO. Cho toan b lng anehit trn tac dung vi lng d dung dich AgNO3 trong NH3, thu c 23,76 gam Ag. Hai ancol la : A. C2H5OH, C2H5CH2OH B. C2H5OH, C3H7CH2OH C. CH3OH, C2H5CH2OH D. CH3OH, C2H5OH Cu 25: (C-09) Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v etanol d. Cho ton b X tc dng vi dung dch NaHCO3 (d) thu c 0,56 lt kh CO2 ( ktc). Khi lng etanol b oxi ho to ra axit l A. 4,60 gam B. 1,15 gam C. 5,75 gam D. 2,30 gam Cu 26: (KA-08) Cho m gam hn hp X gm hai ancol (ru) no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d AgNO3 (hoc Ag2O) trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l A. 7,8. B. 7,4. C. 9,2. D. 8,8. Cu 27: (KB-2010) Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi hiro bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi cc phn ng xy ra hon ton, thu c hn hp Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y tc

dng hon ton vi lng d dung dch AgNO3 trong NH3, to ra 48,6 gam Ag. Phn trm khi lng ca propan-1-ol trong X l A. 65,2%. B. 16,3%. C. 48,9%. D. 83,7%. Cu 28: (KA-09) t chy hon ton 0,2 mol mt ancol X no, mch h, cn va 17,92 lt kh O2 ( ktc). Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH)2 th to thnh dung dch c mu xanh lam. Gi tr ca m v tn gi ca X tng ng l A. 4,9 v propan-1,2-iol B. 9,8 v propan-1,2-iol C. 4,9 v glixerol. D. 4,9 v propan-1,3-iol Cu 29: (KB-08) Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ancol (ru) etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l 0,8 g/ml) A. 5,4 kg. B. 5,0 kg. C. 6,0 kg. D. 4,5 kg. Cu 30: (KA-07) Cho m gam tinh bt ln men thnh ancol (ru) etylic vi hiu sut 81%. Ton b lng CO2 sinh ra c hp th hon ton vo dung dch Ca(OH)2, thu c 550 gam kt ta v dung dch X. un k dung dch X thu thm c 100 gam kt ta. Gi tr ca m l A. 550. B. 810. C. 650. D. 750. Cu 31: (KB-08) Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H6O v c cc tnh cht: X, Z u phn ng vi nc brom; X, Y, Z u phn ng vi H2 nhng ch c Z khng b thay i nhm chc; cht Y ch tc dng vi brom khi c mt CH3COOH. Cc cht X, Y, Z ln lt l: A. C2H5CHO, CH2=CH-O-CH3, (CH3)2CO. B. (CH3)2CO, C2H5CHO, CH2=CH-CH2OH. C. C2H5CHO, (CH3)2CO, CH2=CH-CH2OH. D. CH2=CH-CH2OH, C2H5CHO, (CH3)2CO. Cu 32: (KB-2010) Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit cao. Sau khi phn ng xy ra hon ton, thu c x mol hn hp kh gm: CO2, CO, N2 v H2. Gi tr ca x l A. 0,60. B. 0,36. C. 0,54. D. 0,45. Cu 33: Trong ancol X, oxi chim 26,667% v khi lng. un nng X vi H 2SO4 c thu c anken Y. Phn t khi ca Y l A. 56. B. 70. C. 28. D. 42. Cu 34: t chy hon ton 3 lt hn hp X gm 2 anken kt tip nhau trong dy ng ng cn va 10,5 lt O2 (cc th tch kh o trong cng iu kin nhit , p sut). Hirat ha hon ton X trong iu kin thch hp thu c hn hp ancol Y, trong khi lng ancol bc hai bng 6/13 ln tng khi lng cc ancol bc mt. Phn trm khi lng ca ancol bc mt (c s nguyn t cacbon ln hn) trong Y l A. 46,43%. B. 31,58%. C. 10,88%. D. 7,89%. Cu 35: Cho hn hp X gm ancol metylic, etylen glicol v glixerol. t chy hon ton m gam X thu c 6,72 lt kh CO2 (ktc). Cng m gam X trn cho tc dng vi Na d thu c ti a V lt kh H 2 (ktc). Gi tr ca V l A. 3,36 B. 11,20 C. 5,60 D. 6,72 Cu 36: C bao nhiu cht cha vng benzene c cng cng thc phn t C7H8O? A. 3 B. 5 C. 6 D. 4 Cu 37: Hp cht hu c X cha vng benzen c CTPT trng vi cng thc n gin nht. Trong X, t l khi lng cc nguyn t l m C : mH : mO = 21 : 2 : 8. Bit khi X phn ng hon ton vi Na th thu c s mol kh hir bng s mol ca X phn ng. X c bao nhiu ng phn (cha vng benzen) tha mn cc tnh cht trn? A. 9 B. 3. C. 7. D. 10. Cu 38: Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut ton b qu trnh l 90%, Hp th ton b lng CO 2, sinh ra khi ln men m gam tinh bt vo nc vi trong , thu c 330 gam kt ta v dung dch X. Bit khi lng X gim i so vi khi lng nc vi trong ban u l 132 gam. Gi tr ca m l: A. 405. B. 324 C. 486 D.297