TRNG THPT CHUYN NGUYN HU

THI TH I HC LN TH NHT
NM HC 2012-2013 MN : HA HC - KHI A, B

Thi gian lm bi: 90 pht; (60 cu trc nghim) H, tn th sinh:.......................................................................... S bo danh:............................................................................... (Th sinh khng c s dng ti liu)
M thi 132

I. Phn chung cho tt c cc th sinh( 40 cu, t cu 1 n cu 40)

Cu 1: Chn cht c tinh th phn t: A. nc , naphtalen, iot. B. iot, nc , kali clorua. C. than ch, kim cng, silic. D. iot, naphtalen, kim cng. Cu 2: Cch no sau y khng iu ch c NaOH: A. Cho Na tc dng vi nc. B. in phn dung dch NaCl khng c mng ngn xp (in cc tr). C. Cho dd Ca(OH)2 tc dng vi dd Na2CO3. D. in phn dd NaCl c mng ngn xp (in cc tr). Cu 3: C bao nhiu cht hoc dung dch sau y cho phn ng vi nc brm: glucoz, fructoz, saccaroz, mantoz, ancol etylic, anehit axetic, axit fomic, axit benzoic, phenol v anilin? A. 6 B. 7 C. 5 D. 8 Cu 4: Loi phn ha hc no sau y khi bn cho t lm tng chua ca t: A. m 2 l (NH4NO3) B. Ure: (NH2)2CO C. phn vi lng D. Phn Kali (KCl) Cu 5: A, B, D l 3 hp cht thm c cng thc phn t l C 7H6Cl2. Khi un nng vi dung dch NaOH long, th A phn ng theo t l mol 1: 2, B phn ng theo t l mol 1:1, cn D khng phn ng. S ng phn cu to ca A, B, D l: A. 1, 3, 5 B. 1, 2, 3 C. 1, 3, 4 D. 1, 3, 6 Cu 6: Cho cc cht sau: CH3COOCH2CH2Cl, ClH3N-CH2COOH, C6H5Cl (thm), HCOOC6H5 (thm), C6H5COOCH3 (thm), HO-C6H4-CH2OH (thm), CH3CCl3, CH3COOC(Cl2)-CH3. C bao nhiu cht khi tc dng vi NaOH c d, nhit v p sut cao cho sn phm c 2 mui? A. 7 B. 4 C. 5 D. 6 Cu 7: Hn hp X gm phenol v anilin. Ly m gam X tc dng va vi 200 ml dung dch HCl 1M thu c hn hp Y. Cho hn hp Y tc dng ht vi 500 ml dung dch NaOH 1M, ri c cn thy cn li 31,3 gam cht rn khan. Gi tr ca m l: A. 18,7 B. 28 C. 65,6 D. 14 Cu 8: S trng hp xy ra phn ng oxi ha-kh trong cc p sau: (a) Propin + H2, xc tc Ni, t 0; (b) metyl axetilen + Br2/CCl4 -200C; (c) axetilen + H2, xc tc Pd/PbCO 3; (d) propilen + dd AgNO 3/NH3; (e) butaien + Br2/CCl4 - 400C; (g) isobutilen + HCl; (h) etilen + H 2O, xc tc H+, t0; (i) anlyl clorua + dd NaOH; (k) glixerol + Cu(OH)2. S trng hp xy ra phn ng oxi ha - kh l: A. 5 B. 4 C. 7 D. 6 Cu 9: Cho 7,1 gam P2O5 vo 100 ml dung dch KOH 1,5M thu c dung dch X. C cn dung dch X c hn hp gm cc cht l: A. KH2PO4 v H3PO4. B. KH2PO4 v K2HPO4 C. KH2PO4 v K3PO4. D. K3PO4 v K2HPO4. Cu 10: Cho 28,2 gam hn hp hai ancol n chc tc dng ht vi 11,5 gam Na, sau phn ng thu 39,3 gam cht rn. Nu un 28,2 gam hn hp trn vi H2SO4 c 1400C, th thu c bao nhiu gam ete: A. 19,2 gam B. 23,7 gam C. 24,6 gam D. 21,0 gam Cu 11: X l este c to bi axit 2 chc, mch h v ancol no, 2 chc, mch h c cng thc n gin nht l C3H2O2. hidro ha hon ton 1 mol X (xt Ni, t0) cn bao nhiu mol H2? A. 2 mol B. 3 mol C. 1 mol D. 4 mol Cu 12: Theo nh ngha v axit-baz ca Bron-stt, c bao nhiu ion l baz trong s cc ion sau y: Ba 2+, 2 NO3 , Br , NH + 4 , C 6 H 5O , CH 3COO , CO 3 , HS , HSO 4 :
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A. 5 B. 6 C. 3 D. 4 Cu 13: Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh (gm 20% th tch O2 v 80% th tch N2) n khi phn ng xy ra hon ton, thu c cht rn v hn hp kh Y c thnh phn th tch: N2 = 84,77%; SO2 = 10,6%; cn li l O2. Thnh phn % theo khi lng ca FeS trong X l: A. 59,46% B. 42,3% C. 68,75% D. 26,83% Cu 14: Mt hn hp gm Al2(SO4)3 v K2SO4, trong s nguyn t oxi chim 20/31 tng s nguyn t c trong hn hp. Ho tan hn hp trn vo nc ri cho tc dng vi dung dch BaCl 2 d, hi khi lng kt ta thu c gp bao nhiu ln khi lng hn hp ban u: A. 1,788 ln B. 1,488 ln C. 1,688 ln D. 1,588 ln. Cu 15: Cho kh H2S tc dng vi cc cht: dung dch NaOH, kh clo, nc clo, dung dch KMnO 4/H+, kh oxi d un nng, dung dch FeCl3, dung dch ZnCl2, Pb(NO3)2, KClO3. S trng hp xy ra phn ng v s trng hp trong lu hunh b oxi ha ln S+6 l: A. 9 - 3 B. 6 -2 C. 8 - 1 D. 6 -1 Cu 16: Hn hp X gm axetilen, etilen v hidrocacbon A chy hon ton thu c CO 2 v H2O theo t l mol 1:1. Dn X i qua bnh ng dung dch brom d thy khi lng bnh tng ln 0,82 gam, kh thot ra khi bnh em t chy hon ton thu c 1,32 gam CO2 v 0,72 gam H2O. % V ca A trong X l: A. 75 B. 50 C. 33,33 D. 25 Cu 17: Cho 94,8 gam phn chua (KAl(SO4)2.12H2O) tc dng vi 350 ml dung dch cha Ba(OH)2 0,5M v NaOH 1M, sau khi cc phn ng xy ra hon ton th thu c m gam kt ta. Gi tr m l: A. 111,4 gam B. 48,575 gam C. 56,375 gam D. 101 gam Cu 18: t chy hon ton 22 gam hp cht hu c X ch to ra 22,4 lt CO 2 (ktc) v 18 gam nc. Khi tc dng vi LiAlH4 th mt phn t X ch to ra hai phn t hp cht hu c Y. Cng thc ca X tha mn l: A. C2H5COOCH3 B. CH3COOC2H5 C. CH3COOCH3 D. HOCH2CH2CHO Cu 19: Tin hnh nhit phn hn hp X gm butan v heptan (t l 1:2 v s mol) th thu c hn hp Y (Gi s ch xy ra phn ng cracking ankan vi hiu sut 100%). Xc nh khi lng phn t trung bnh ca Y ( M Y )? A. M Y =43 B. 32 M Y 43 C. 25,8 M Y 32 D. 25,8 M Y 43 Cu 20: Ngi ta iu ch etyl axetat t xenluloz v cc cht v c theo s sau: xenluloz glucoz ancol etylic axit axetic etyl axetat. Tnh khi lng xenluloz cn dng c th iu ch c 1 mol etyl axetat. Bit hiu sut chung ca qu trnh t 40%. A. 506,25 gam B. 405 gam C. 202,5 gam D. 162 gam Cu 21: Cho 17,9 gam hn hp gm Fe, Cu v Al vo bnh ng 200 gam dung dch H 2SO4 24,01%. Sau khi cc phn ng xy ra hon ton, thu c 9,6 gam cht rn v c 5,6 lt kh (ktc) thot ra. Thm tip vo bnh 10,2 gam NaNO3, khi cc phn ng kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi lng mui trong dung dch l: A. 2,24 lt v 59,18 gam. B. 2,688 lt v 59,18 gam. C. 2,688 lt v 67,7 gam. D. 2,24 lt v 56,3 gam. Cu 22: Khng nh no sau y khng ng? as 2Ag + Br2 A. AgBr trc y c dng ch to phim nh do c phn ng: 2AgBr
t B. KMnO4 iu ch oxi trong phng th nghim theo phn ng: 2KMnO 4 K 2 MnO 4 + MnO 2 + O 2 C. Axit HF c dng khc thy tinh do c phn ng: SiO2 + 4HF SiH4 + 2F2O D. Nc Javen c tnh ty mu do c phn ng: NaClO + CO2 + H2O NaHCO3 + HClO Cu 23: Nhn bit cc cht lng ring bit: ancol etylic, clorofom, benzen bng 1 thuc th no sau y: A. Cu(OH)2 B. CuO C. H2O D. Na Cu 24: Hp cht hu c X c cng thc phn t C 8H11N, X tan c trong axit. Cho X tc dng vi HNO 2 to ra hp cht Y c cng thc phn t C8H10O. un nng Y vi dung dch H2SO4 c to ra hp cht Z. Trung hp Z thu c polistiren. S ng phn cua X thoa mn: A. 1 B. 2 C. 3 D. 4 Cu 25: Nguyn t X c electron cui cng in vo lp M, trng thi c bn c 3 electron c thn. iu nhn nh no sau y ng: A. X chu k 4, nhm VIIB B. X chu k 3, nhm IIIA C. X chu k 3, nhm VA D. X chu k 4, nhm IIIB
0

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Cu 26: Phn ng no sau y chng t Fe2+ c tnh kh yu hn so vi Cu: A. Cu2+ + 2Fe2+ 2Fe3+ + Cu B. Fe2+ + Cu Cu2+ + Fe 2+ 2+ C. Fe + Cu Fe + Cu D. 2Fe3+ + Cu 2Fe2+ + Cu2+ Cu 27: Thc hin 2 th nghim:- TN 1: Trn KClO3 vi MnO2, un nng iu ch kh O2 - TN 2: Dung dch HCl c, un nng vi MnO2 iu ch kh Cl2 Nhn nh no sau y ng: A. TN 1: MnO2 ng vai tr cht xc tc, TN 2: MnO2 ng vai tr cht oxi ha B. TN 1: MnO2 ng vai tr cht oxi ha, TN 2: MnO2 ng vai tr cht oxi ha C. TN 1: MnO2 ng vai tr cht kh, TN 2: MnO2 ng vai tr cht oxi ha D. TN 1: MnO2 ng vai tr cht oxi ha, TN 2: MnO2 ng vai tr cht kh Cu 28: Khi lng tripeptit c to thnh t 178 gam alanin v 75 gam glyxin l: A. 253 g B. 235g C. 217g D. 199g. Cu 29: un nng V lt hi anehit X vi 3V lt kh H 2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z; cho Z tc dng vi Na sinh ra H 2 c s mol bng mt na s mol Z phn ng. Cht X l anehit: A. khng no (cha mt ni i C=C), hai chc. B. khng no (cha mt ni i C=C), n chc. C. no, n chc. D. no, hai chc Cu 30: Phn ng ha hc no khng xy ra nhng cp cht sau: A. CO2 + dd Na2SiO3 B. Si + dd NaOH C. SiO2 + Mg D. Si + dd HCl Cu 31: Cho xenlulz tc dng vi HNO 3 c (H2SO4 c) v bng phng php thch hp tch thu c 0,08 mol hai sn phm A v B c cng s mol. Thnh phn phn trm khi lng nit trong A v B ln lt l 11,11 % v 14,14 %. Khi lng ca A v B l: A. 8,28 g v 10,08g B. 9,84g v 11,52g C. 8,28g v 11,88g D. 10,08g v 11,88g Cu 32: Nung 8,42 gam hn hp X gm Al, Mg, Fe trong oxi sau mt thi gian thu c 11,62 gam hn hp Y. Ha tan hon ton Y trong dung dch HNO 3 d thu c 1,344 lt NO (ktc) l sn phm kh duy nht. S mol HNO3 phn ng l: A. 0,56 mol B. 0,48 mol C. 0,72 mol D. 0,64 mol Cu 33: Thc hin phn ng este ho 2 mol C 2H5OH vi 1 mol HCOOH nhit khng i (xt H 2SO4 c) khi h cn bng thu c 0,8 mol este. cng iu kin trn, este ho 1 mol C 2H5OH v x mol HCOOH, khi h cn bng thu c 0,7 mol este. Gi tr ca x l: A. 2,225 B. 1,75 C. 1 D. 1,3125 Cu 34: Hn hp X gm SO2 v O2 c t khi so vi H2 bng 28. Ly 4,48 lt hn hp X (ktc) cho i qua bnh ng V2O5 nung nng. Hn hp thu c li qua dung dch Ba(OH) 2 d thy c 33,19 gam kt ta. Hiu sut phn ng oxi ho SO2 l: A. 94,96% B. 40% C. 75% D. 25% Cu 35: Cho cc mnh sau: (1) Nc cng l ngun nc cha nhiu ion Ca2+, Mg2+ (2) C th lm mm nc cng ton phn bng dung dch Na2CO3 (3) C th phn bit nc cng tm thi v nc cng vnh cu bng cch un nng (4) C th lm mm nc cng tm thi bng dung dch HCl (5) C th dng NaOH va lm mm nc cng tm thi S mnh ng l: A. 3 B. 2 C. 4 D. 1 Cu 36: Cho dy cht: phenyl clorua, sec-butyl clorua, natri phenolat, phenylamoni clorua, tinh bt, amoni axetat, crezol. S cht trong dy khng tc dng vi dung dch NaOH long nhit thng l: A. 5. B. 3. C. 6. D. 4 Cu 37: CH3COOH khng th iu ch trc tip bng cch: A. metanol tc dng vi cacbon monoxit B. Oxi ha CH3CHO bng dd AgNO3/NH3. C. Oxi ha CH3CHO bng O2 (xc tc Mn2+). D. Ln men gim. Cu 38: C 5 dung dch ring bit l: CuCl 2, FeCl3, AgNO3, HCl v HCl c ln CuCl2. Nhng vo mi dung dch mt thanh Fe nguyn cht. S trng hp xut hin n mn in ha l: A. 3 B. 2 C. 1 D. 4 Cu 39: Aminoaxit no sau y c hai nhm amino. A. Alanin. B. Lysin. C. Axit Glutamic. D. Valin.
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Cu 40: Phng php iu ch polime no sau y l ng: A. ng trng ngng buta-1,3-ien v vinylxianua iu ch cao su buna-N B. Trng hp caprolactam to t nilon-6 C. Trng hp ancol vinylic iu ch poli(vinyl ancol) D. ng trng hp axit terephtalic v etylen glicol iu ch c poli(etylen-terephtalat)

II. Phn ring( 10 cu) Th sinh c chn lm 1 trong 2 phn ( phn I hoc phn II ) Phn I: Theo chng trnh Chun ( t cu 41 n cu 50)
Cu 41: Fomalin hay fomon (dng bo qun xc ng vt chng thi ra) l: A. Ancol C2H5OH 46o. B. Dung dch CH3CHO 40% v th tch trong nc. C. Dung dch HCHO 25%- 30% v th tch trong nc. D. Dung dch HCHO 37%-40% v khi lng trong nc. Cu 42: Cho 0,15 mol -aminoaxit mch cacbon khng phn nhnh A phn ng va ht vi 150ml dung dch HCl 1M to 25,425 gam mui. Cho tip lng NaOH va vo dung dch sau phn ng to ra 35,325 gam mui khan. Cng thc cu to ca A l: A. HOOC-CH2-CH(NH2)-COOH B. H2N- CH2-CH2-CH(NH2)-COOH C. HOOC-CH2-CH2-CH(NH2)-COOH D. HOOC-CH2-CH2-CH2-CH(NH2)-COOH Cu 43: S ng phn cu to ca C5H10 phn ng c vi dung dch brom l: A. 8. B. 5. C. 9. D. 7. Cu 44: Cho dy cc cht rn sau: Al, NaHCO3, (NH4)2CO3, NH4Cl, Al2O3, Zn(OH)2, Fe(OH)3, K2CO3, CaCO3, AlCl3. Trong dy trn bao nhiu cht c th va tan c trong dung dch HCl, va tan c trong dung dch NaOH? A. 9. B. 5. C. 8. D. 6. Cu 45: Cho m gam X gm Fe, FeO, Fe 3O4, Fe2O3 vo 400 ml dung dch HCl 2M, sau phn ng thu c 2,24 lt H2 (ktc), dung dch Y, v 2,8 gam Fe khng tan. Gi tr m l: A. 30,0 B. 22,4 C. 25,2 D. 27,2 Cu 46: Pht biu khng ng l: A. Vt liu compozit, vt liu nano, vt liu quang in t l nhng vt liu mi c nhiu tnh nng c bit. B. Cc kh SO2, NO2 gy ma axit, kh CO2 gy hiu ng nh knh cn hp cht CFC gy thng tng ozon. C. Cc cht: Penixilin, amphetamin, erythromixin thuc loi thuc khng sinh, cn: Seduxen, moocphin, ampixilin thuc loi cht gy nghin. D. Vic s dng cc cht: Fomon, ure, hn the, phn m trong bo qun v ch bin thc phm l vi phm v sinh an ton thc phm. Cu 47: xc nh ru ca dung dch ru etylic (X) ngi ta ly 10ml dung dch X cho tc dng vi Na d thu c 2,564 lt H2 (ktc). Tnh ru ca X, bit d C2H5OH = 0,8g / ml, d H2O =1g / ml ? A. 85,580 B. 92,50 C. 87,50 D. 91,00 Cu 48: ng dng khng hp l ca crom l? A. iu kin thng, crom to c lp mng oxit mn, bn chc nn c dng m bo v thp. B. Crom l kim loi rt cng c th dng ct thy tinh. C. Crom l kim loi nh, nn c s dng to cc hp kim dng trong ngnh hng khng. D. Crom lm hp kim cng v chu nhit, nn dng to thp cng, khng g, chu nhit. Cu 49: in phn 100 ml dung dch CuSO 4 1M vi in cc tr trong thi gian 25 pht 44 giy, cng dng in l 5A th dng li. Khi lng dung dch gim l: A. 3,2 gam B. 3,84 gam C. 2,88 gam D. 2,56 gam Cu 50: Hn hp A gm 2 axit cacboxylic n chc X, Y. Cho 13,4 gam A ha tan ht vo nc ri cho tc dng vi AgNO3/NH3 d c 21,6 gam Ag. Mt khc cng lng hn hp trn trung ha va vi 100 ml dung dch NaOH 2M. CTCT ca X, Y l: A. CH3COOH, C2H5COOH B. HCOOH, CH3COOH C. HCOOH, C2H5COOH D. HCOOH, C3H7COOH

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Phn II: Theo chng trnh nng cao ( t cu 51 n cu 60)

Cu 51: Cho hn hp 2 axit no n chc ng ng k tip tc dng ht vi NaOH. L ng mui sinh ra cho phn ng vi vi ti xt ti hon ton, c hn hp kh c d/He = 3,3. Hai axit c % s mol ln lt l: A. 30% v 70% B. 20% v 80% C. Kt qu khc. D. 50% v 50% 0 0 0 Cu 52: Cho sut in ng chun ca cc pin in ho: E Ni X =1, 06V; E Y Ni = 0, 50V; E Ni Z =1, 76V (X, Y, Z l cc kim loi khc st). Khi in phn dung dch hn hp mui nitrat ca cc kim loi X, Y, Z, Ni (in cc tr, c mng ngn) th cc kim loi thot ra catt theo th t (t tri qua phi) l: A. X, Z, Y, Ni B. Z, X, Ni, Y C. Z, X, Y, Ni D. X, Z, Ni, Y Cu 53: Cho cc phn ng: (1) O3 + dung dch KI (2) F2+ H2O ( 3) KClO3(rn) + HCl(c) (4) SO2 + dung dch H2S (5) Cl2 + dung dch H2S (6) NH3(d) + Cl2 t0 (7) NaNO2(bo ho) + NH4Cl(bo ho) (8) NO2 + NaOH(dd) S phn ng to ra n cht l: A. 6. B. 3. C. 2. D. 5. Cu 54: Thm 0,08 mol NaOH vo dung dch cha 0,03 mol CrCl 2, ri trong khng kh n khi phn ng hon ton th khi lng kt ta thu c l: A. 1,72g B. 0,86g C. 1,03g D. 0g Cu 55: hiro ho etylbenzen thu c stiren vi hiu sut l 60%. hiro ho butan thu c butaien vi hiu sut l 45%. Trng hp butaien v stiren thu c sn phm X (t l mt xch ca butaien v stiren l 1: 1) c tnh n hi rt cao vi hiu sut 75%. iu ch c 500kg sn phm X cn khi lng butan v etylbezen l: A. 543,8 kg v 745,4 kg B. 506,3 kg v 731,4 kg C. 335,44 kg v 183,54 kg D. 150,95 kg v 61,95 kg Cu 56: C 3 bnh, mi bnh ng mt dung dch sau: HCl, H 2SO3, H2SO4. Nu ch dng thm mt cht lm thuc th th c th chn cht no sau y phn bit cc dung dch trn : A. Bari hiroxit B. Bari clorua C. Bari hiroxit hoc bari clorua D. Natri hirxit Cu 57: C cc pht biu sau: (1) ng c th tan trong dung dch HCl c mt oxi. (2) Mui Na2CO3 d b nhit phn hu. (3) Hn hp Cu v Fe2O3 c s mol bng nhau s tan ht c trong dung dch HCl d. (4) Khi pin in hoa Zn Cu phong in, thi tng v giam khi lng cua 2 in cc lun bng nhau. (5) Kim loai Na, K, Ba u co cu tao mang tinh th lp phng tm khi. S cu phat biu ung la: A. 5 B. 2 C. 4 D. 3 Cu 58: Cho cc dung dch sau (nng khong 1M): NaAlO 2, C6H5NH3Cl, C2H5NH2, FeCl3, C6H5ONa, CH3COOH. Ln lt trn ln tng cp dung dch vi nhau, s trng hp c phn ng xy ra l: A. 8 B. 10 C. 7 D. 9 Cu 59: Ch s iot c trng cho s ni i trong cc hp cht khng no (v d cht bo...), l s gam iot cng hp vo 100 gam hp cht hu c. Ch s iot ca triolein l: A. 28,73. B. 2,873. C. 86,2. D. 8,62. Cu 60: Hai cht ng phn A, B (A c ly t ngun thin nhin) c cha 40,45%C, 7,86%H; 15,73% N v cn li l O. T khi hi ca cht lng so vi khng kh l 3,069. Khi phn ng vi NaOH, A cho mui C3H6O2NNa, cn B cho mui C2H4O2NNa. Nhn nh no di y l sai? A. A v B u tc dng vi HNO2 to kh N2. B. A c tnh lng tnh nhng B ch c tnh baz C. A l alanin, B l metyl amino axetat. D. t0 thng A l cht lng, B l cht rn. ----------- HT ----------

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Thi thu 2013-THPT CHUYN NGUYN HU CU M132 CU M132 1 A 31 D 2 B 32 D 3 A 33 D 4 A 34 B 5 D 35 C 6 D 36 D 7 B 37 B 8 D 38 A 9 B 39 B 10 C 40 B 11 A 41 D 12 C 42 A 13 A 43 A 14 C 44 C 15 C 45 A 16 D 46 C 17 B 47 A 18 B 48 C 19 D 49 A 20 B 50 D 21 C 51 B 22 C 52 B 23 C 53 A 24 B 54 C 25 C 55 A 26 D 56 A 27 A 57 D 28 C 58 D 29 B 59 C 30 D 60 D

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