S GIO DC V O TO

TRNG THPT CHUYN VNH PHC

THI KHO ST LN 3 NM HC 2012-2013

Mn Ho Hc 12- Khi A,B
(Thi gian lm bi 90 pht)

M thi 169

H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cu 1: Pht biu no sau y l ng:
A. Ancol o-hiroxibenzylic l sn phm trung gian trong qu trnh iu ch nha novolac t
phenol v fomanehit.
B. T nilon-6,6 thuc loi t poliamit, c iu ch bng phn ng ng trng hp cc monome
tng ng.
C. Cao su buna-S thu c khi cho cao su buna tc dng vi lu hunh.
D. T visco, t xenluloz axetat, t nitron cng thuc loi t nhn to.
Cu 2: ng vi cng thc phn t C7H8O c bao nhiu ng phn l dn xut ca benzen v s ng
phn u tc dng c vi cc cht: K, KOH, (CH3CO)2O
A. 5 v 2
B. 4 v 2
C. 4 v 3
D. 5 v 3
Cu 3: Hn hp X gm Fe(NO3)2; BaCl2, NH4NO3 c ha tan vo nc c d.dch A . Chia
dung dch A thnh 2 phn bng nhau. Phn 1: Cho HCl ( rt d) vo v un nng thot ra 448 ml
kh NO . Tip tc thm mt mu Cu ( ng) d vo v un nng thy thot ra tip 3136ml kh NO.
Cc kh o iu kin tiu chun. Phn 2: Cho Na2CO3 (rt d) vo to ra 12,87 gam kt ta.
Thnh phn % khi lng ca ba mui trong hn hp ban u l:
A. Fe(NO3)2 : 30,35% ;
BaCl2 : 31,48% ; NH4NO3 : 38,17%.
B. Fe(NO3)2 : 35,27% ;
BaCl2 : 20,38% ; NH4NO3 : 44,35%.
C. Fe(NO3)2 : 53,36% ;
BaCl2 : 30,83% ; NH4NO3 : 15,81%.
D. Fe(NO3)2 : 35,13% ;
BaCl2 : 42,24% ; NH4NO3 : 22,53%.
Cu 4: Chn phng n ng trong s cc phng n sau:
A. un cc ancol thuc dy ng ng ca ancol etylic vi H2SO4 c 1700C u thu c
anken
B. Phenol tc dng c vi c dd NaOH v dd Na2CO3
C. Mt mol anehit n chc phn ng trng gng to ra ti a hai mol Ag
D. Oxi ha ancol no, n chc thu c anehit
Cu 5: Mt bnh phn ng c dung tch khng i, cha hn hp kh N 2 v H2 vi nng tng
ng l 0,3 M v 0,7 M. Sau khi phn ng tng hp NH 3 t trng thi cn bng t0C, H2 chim 50%
th tch hn hp thu c. Hng s cn bng KC t0C ca phn ng c gi tr l
A. 0,609
B. 3,125
C. 0,500
D. 2,500
Cu 6: Cho cac cht: NaHCO3, CO, Al(OH)3, Fe(OH)3, HF, Cl2, NH4Cl. S cht tac dung c vi
dung dich NaOH loang nhit thng la
A. 5
B. 6
C. 3
D. 4
Cu 7: Cn bao nhiu tn qung hematit cha 5% tp cht sn xut 1 tn gang c cha 95% Fe
(Bit rng hiu sut ca qu trnh luyn gang l 90%)
A. 1,457 tn
B. 1,623 tn
C. 1,537 tn
D. 1,587 tn
Cu 8: Cho cn bng ha hc: N2 (k) + 3H2(k)
2NH3 (k), (H < 0). tng hiu sut tng hp
NH3 ta cn phi:
A. Tng p sut, gim nhit .
B. Gim p sut, gim nhit .
C. Tng p sut, tng nhit .
D. Gim p sut, tng nhit .
Cu 9: Pht biu no sau y khng ng:
A. in phn dung dch NaCl, khng c mng ngn iu ch nc gia-ven.
B. Khng th dp tt cc m chy Mg bng kh cacbonic.
C. Phn bn phc hp l sn phm trn ln cc loi phn n theo t l khc nhau.
D. Axit HCl va c tnh oxi ha, va c tnh kh.
Trang 1/5 - M thi 169

Cu 10: Cho hp cht X tc dng vi NaOH to ra kh Y lm xanh qu tm m. Mt khc, cht X tc

dng vi axit HCl to ra kh Z va lm vn c nc vi trong, va lm mt mu dung dch Brom.
Cht X khng tc dng vi dung dch BaCl2. Vy cht X c th l:
A. (NH4)2SO3
B. NH4HCO3
C. NH4HSO3
D. (NH4)2CO3
Cu 11: Cho cc pht biu sau:
(1) Trong mt chu k, theo chiu tng ca in tch ht nhn th bn knh nguyn t gim dn.
(2) Trong mt nhm A, theo chiu tng dn ca in tch ht nhn th m in tng dn.
(3) Lin kt ha hc gia mt kim loi nhm IA v mt phi kim nhm VIIA lun l lin kt ion.
(4) Nguyn t N trong NH3 v trong NH4+ c cng cng ha tr l 3.
(5) S oxi ha ca Cr trong K2Cr2O7 l +6.
S pht biu ng l
A. 5
B. 3
C. 4
D. 2
Cu 12: in phn c mng ngn 200 gam dung dch X cha KCl v NaCl n khi t khi kh ant
bt u gim th dng li. Trung ha dung dch sau in phn cn 200 ml dung dch H2SO4 0,5M, c
cn dung dch thu c 15,8 gam mui khan. Nng phn trm mi mui c trong dung dch X ln
lt l
A. 3,725% v 2,925%
B. 18,625% v 14,625%
C. 37,25% v 29,25%
D. 7,5% v 5,85 %
Cu 13: X c vng benzen v c CTPT l C 9H8O2. X tc dng d dng vi dd brom thu c cht Y
c cng thc phn t l C9H8O2Br2. Mt khc, cho X tc dng vi NaHCO 3 thu c mui Z c
CTPT l C9H7O2Na Hy cho bit X c bao nhiu cng thc cu to ?
A. 4
B. 5
C. 3
D. 6
Cu 14: C a gam hn hp X gm gm 1 axit no n chc A v 1 este to ra bi 1 axit
no n chc B l ng ng k tip ca A v 1 ru no n chc. Cho a gam
hn hp X tc dng va NaHCO 3, thu c 1,92 gam mui. Nu cho a gam hn
hp X tc dng vi mt lng va NaOH un nng, thu c 4,38 gam hn hp 2
mui ca axit A v B v 0,03 mol ru, ru ny c t khi hi so vi hyro l 23.
t chy 2 mui bng 1 lng oxi th thu c mui Na2CO3, hi nc v 2,128 lt
CO2(ktc). Gi thit cc p iu xy ra hon ton. Gi tr ca a l:
A. 3,98 gam
B. 4,12 gam
C. 3,56 gam
D. 2,06 gam
Cu 15: (X) l hp cht hu c c cng thc phn t C 5H11O2N. un X vi dd NaOH thu c mt
hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t o thu c cht
hu c (Z) khng c kh nng phn ng trng bc. Cng thc cu to ca (X) l:
A. NH2 - CH2 - COO - CH(CH3)2
B. NH2 - CH2COO - CH2 - CH2 - CH3
C. CH3(CH2)4NO2
D. H2N - CH2 - CH2 - COOC2H5
Cu 16: Benzyl axetat l mt este c mi thm ca hoa nhi. Cng thc ca benzyl axetat l
A. C6H5-COO-CH3
B. CH3-COO-CH2-C6H5
C. CH3-COO-C6H5
D. C6H5-CH2-COO-CH3
Cu 17: Pht biu no sau y khng ng
A. Thy phn Saccaroz thu c 2 monosaccarit khc nhau.
B. Trong phn t Amiloz tn ti c lin kt -1,4-glicozit v -1,6-glicozit
C. Thy phn hon ton tinh bt v xenluloz cng thu c mt monosaccarit.
D. Glucoz v Fructoz l ng phn ca nhau.
Cu 18: X gm O2 v O3 c dX/He = 10. Th tch ca X t hon ton 25 lt Y l hn hp 2 ankan
k tip c dY/He = 11,875 l (Th tch kh o cng iu kin):
A. 107 lt.
B. 105 lt.
C. 105,7 llt.
D. 107,5 lt.
Cu 19: C hai bnh in phn (1) v bnh in phn (2) .Trong bnh 1 ng dung dch (1) l
NaOH c th tch 38 ml v nng 0,5M. Trong bnh 2 cha dung dch gm 2 mui Cu(NO3)2
v NaCl tng khi lng cht tan 258,2 gam. Mc ni tip bnh (1) v bnh (2). in phn cho n
khi bnh (2) va c kh thot ra c hai in cc th dng li. Ly dung dch sau phn ng :
- bnh (1): nh lng xc nh thy nng NaOH sau in phn l 0,95M.
- bnh (2) em phn ng vi lng d bt Fe. Hi sau phn ng khi lng bt Fe b
Trang 2/5 - M thi 169

tan ra l m gam, v thot ra mt kh duy nht l NO c th tch x (lt) c o iu kin tiu

chun.
Gi tr ca m v x ln lt l:
A. 7,47 gam v 2,99
B. 11,2 v 4,48
C. 11,2 gam v 6,72
D. 16,8 v 4,48
Cu 20: Phn bn no sau y lm tng chua ca t ?
A. NaNO3.
B. NH4NO3
C. KCl.
D. (NH2)2CO
Cu 21: Phn ng no sau y c dng phc hi cc bc tranh c c v bng bt trng ch
[2PbCO3, Pb(OH)2] lu ngy trong khng kh b ha en.
A. Pb(OH)2 + H2O2 B. PbCO3 + H2SO4
C. PbS + HNO3.
D. PbS + H2O2
Cu 22: Ha tan 19,5 gam hn hp gm Na 2O v Al2O3 trong nc thu c 500 ml dung dch A
trong sut. Thm dn dung dch HCl 1M vo dung dch A n khi bt u xut hin kt ta th dng
li thy th tch dung dch HCl cn dng l 100 ml. Phn trm s mol mi cht trong A ln lt l
A. 45% v 55%
B. 25% v 75%
C. 30% v 70%
D. 60 % v 40%
Cu 23: Cho a gam hn hp bt gm Ni v Cu vo dung dch AgNO 3 (d). Sau khi kt thc phn
ng thu c 54 gam cht rn. Mt khc cng cho a gam hn hp 2 kim loi trn vo dung dch
CuSO4 (d), sau khi kt thc phn ng thu c cht rn c khi lng (a + 0,5) gam. Gi tr ca a l
A. 15,5 gam
B. 42,5 gam
C. 33,7 gam
D. 53,5 gam
Cu 24: Cho V lt dung dch A cha ng thi FeCl 3 1M v Fe2(SO4)3 0,5M tc dng vi dung dch
Na2CO3 d, phn ng kt thc thy khi lng dung dch sau phn ng gim 69,2 gam so vi tng
khi lng ca cc dung dch ban u. Gi tr ca V l
A. 0,2 lt.
B. 0,24 lt.
C. 0,237 lt.
D. 0,336 lt.
Cu 25: Chia 23,6 gam hn hp gm HCHO v cht hu c X l ng ng ca HCHO thnh 2 phn
bng nhau. Phn 1, cho tc dng vi H2 d (t0C, xc tc), sau phn ng thu c 12,4 gam hn hp
ancol. Phn 2, cho tc dng vi dung dch AgNO 3/NH3 d thu c 108 gam bc. Cng thc phn t
ca X l
A. C2H3CHO
B. (CHO)2
C. CH3CHO
D. C2H5CHO
Cu 26: Ha tan 20 gam mui sunfat ngm nc ca kim loi M (cha r ha tr) vo nc ri em
in phn hon ton, thy catot tch ra 5,12 gam kim loi, anot thot ra 0,896 lit kh ( ktc).
Cng thc ca mui ngm nc l
A. Al2(SO4)3
B. CuSO4.5H2O
C. CuSO4.3H2O
D. FeSO4.7H2O
Cu 27: Cht hu c X mch h, bn, tn ti dng trans c cng thc phn t C4H8O, X lm mt
mu dung dch Br2 v tc dng vi Na gii phng kh H2. Cng thc cu to thu gn ca X l:
A. CH3CH=CHCH2OH.
B. CH2=C(CH3)CH2OH.
C. CH3CH2CH=CHOH
D. CH2=CHCH2CH2OH.
Cu 28: Cho dy cc cht sau y: Cl2, KH2PO4, C3H8O3, CH3COONa, HCOOH, SO2, Mg(OH)2,
C6H6, NH4Cl. S cht in li trong dy l
A. 4
B. 3
C. 5
D. 6
Cu 29: Cho hn hp gm Mg v Fe c khi lng 8,64 gam. c chia thnh hai phn bng nhau:
Phn 1 hon tan hon ton vo dung dch HNO 3 long, d thot ra 555 ml hn hp kh NO v N 2O
o 27,3oC v 2atm v c t khi hi i vi H2 bng 18,889. Phn 2 em ha tan vo 400 ml dung
dch cha AgNO3 v Cu(NO3)2. Sau phn ng thu c cht rn gm 3 kim loi c khi lng 7,68
gam. Ha tan cht rn ny trong dung dch HCl d thy khi lng cht rn gim i 21,88%. Nng
ca dung dch AgNO3 v Cu(NO3)2 trong dung dch ln lt l:
A. 0,15M v 0,1M
B. 0,1M v 0,1M
C. 0,05M v 0,15M.
D. 0,125M v 0,215M
Cu 30: Ha tan a gam hn hp Cu v Fe (trong Fe chim 30% v khi lng) bng 50 ml dung
dch HNO3 63% (d=1,38 g/ml), khuy u cho ti phn ng hon ton thu ccht rn A cn nng
0,75a gam, dung dch B v 6,104 lt hn hp kh NO v NO2 (ktc). Khi lng mui khan khi c cn
dung dch B l:
A. 50,5175 gam
B. 101,035 gam
C. 75,15 gam
D. 37,575 gam
Cu 31: Cho cc phn ng sau:
2FeI2 ;
(1) 2Fe + 3I2
(2) 3Fe(d) + 8HNO3 ( l)
3Fe(NO2)2 + 2NO + 4H2O
Trang 3/5 - M thi 169

 Fe(NO3)3 + Ag ;
(3)AgNO3 + Fe(NO3)2
2CaCO3 + Mg(OH)2 + 2H2O
(4) Mg(HCO3)2 + 2Ca(OH)2 (d)

(5) 2AlCl3 + 3Na2CO3

Al2(CO3)3 + 6NaCl ;

(6) FeO + 2HNO3 (l)

Fe(NO3)2 + H2O
(7) NaHCO3 + Ca(OH)2T l mol 1 : 1
CaCO3 + NaOH + H2O.
Nhng phn ng ng l:
A. (2), (3), (4), (7)
B. (1), (2), (4), (6), (7) C. (1), (2), (3), (4), (7) D. (2), (3), (5), (7)
Cu 32: Cht A c cng thc phn t C 4H6O2. Cho m gam A phn ng va vi dung dch cha 2
gam NaOH, to ra 4,1 gam mui. Kt lun no sau y l ng cho cht A
A. A c phn ng trng bc v c lm mt mu nc brom
B. A c kh nng lm i mu qu tm thnh
C. A khng tham gia phn ng trng bc nhng c lm mt mu nc brom
D. A c phn ng trng bc nhng khng lm mt mu nc brom
Cu 33: C th iu ch cao su Buna (X) t cc ngun thin nhin theo cc s sau. Hy ch ra s
sai
A. CaCO3 CaO CaC2 C2H2 C4H4 Buta-1,3-ien X.
B. Tinh bt glucoz C2H5OH Buta-1,3-ien X.
C. CH4 C2H2 C4H4 Buta-1,3-ien X.
D. Xenluloz glucoz C2H4 C2H5OH Buta-1,3-ien X.
Cu 34: Cho cac phat biu sau:
1. Phan ng thun nghich la phan ng xay ra theo 2 chiu ngc nhau.
2. Cht xc tc c tc dng lm tng tc phn ng thun v nghch.
3. Cn bng hoa hoc la trang thai ma phan ng a xay ra hoan toan.
4. Khi phan ng thun nghich at trang thai cn bng hoa hoc, lng cac cht se khng i.
5. Khi phan ng thun nghich at trang thai cn bng hoa hoc, phan ng dng lai.
Cac phat biu sai:
A. 3, 4.
B. 3, 5.
C. 2, 3.
D. 4, 5.
Cu 35: Cho 0,5 lt hn hp gm hirocacbon v kh cacbonic vo 2,5 lt oxi (ly d) ri t. Th
tch ca hn hp thu c sau khi t l 3,4 lt. Cho hn hp qua thit b lm lnh, th tch hn hp
kh cn li 1,8 lt v cho li qua dung dch KOH ch cn 0,5 lt kh. Th tch cc kh c o trong
cng iu kin. Tn gi ca hyrocacbon l
A. xiclopropan.
B. xiclobutan.
C. propen.
D. propan.
Cu 36: Nhm th c sn trn nhn benzen nh hng phn ng th vo v tr ortho v para l:
A. OH , NH2 , gc ankyl , halogen
B. OH , NH2 , CHO
C. CnH2n+1- , COOH
D. CnH2n+1- , NO2
Cu 37: Trong mt cc nc c ho tan a mol Ca(HCO 3)2 v b mol Mg(HCO3)2. lm mm nc
trong cc cn dng V lt nc vi trong, nng p mol/lit. Biu thc lin h gia V vi a, b, p l:
A. V = (a +2b)/p.
B. V = (a + b)/2p.
C. V = (a + b)/p.
D. V = (a + b)p.
Cu 38: t chy hon ton 0,04 mol hp cht X cn va 24,64 lt khng kh o iu kin tiu
chun. Hp th hon ton sn phm chy qua bnh ng nc vi trong thu c 8 gam kt ta v
bnh ng tng thm 10,64 gam so vi dung dch Ca(OH) 2 ban u, thot ra 20,608 lt kh o iu
kin tiu chun. Thm tip dung dch NaOH d vo bnh sau phn ng thy to thm 4 gam kt ta.
Cng thc phn t ca hp cht hu c :
A. C3H9O2N
B. C4H10O2N2
C. C4H10O2N
D. C3H10O2N.
Cu 39: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc l axit sunfuric
c nng. c 29,7 kg xenluloz trinitrat, cn dng dung dch cha m kg axit nitric (hiu sut phn
ng l 90%). Gi tr ca m l
A. 10 kg
B. 42 kg
C. 21 kg
D. 30 kg
Cu 40: Cho cc cht: Cu, Mg, FeCl 2, Fe3O4. C my cht trong s cc cht tc dng c vi dd
cha Mg(NO3)2 v H2SO4 ?
A. 2
B. 4
C. 3
D. 1
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Cu 41: Oxi ho ancol etylic bng xc tc men gim, sau phn ng thu c hn hp X (gi s
khng to ra anehit). Chia hn hp X thnh 2 phn bng nhau. Phn 1, cho tc dng vi Na d, thu
c 6,272 lt H2 (ktc). Trung ho phn 2 bng dung dch NaOH 2M thy ht 120ml. Hiu sut phn
ng oxi ho ancol etylic l
A. 75%
B. 66,7%
C. 85,7%
D. 42,86%
Cu 42: Trong cc dd sau dd BaCl2 ; dd Br2/H2O ; dd Br2/CCl4 ; dd Ba(OH)2 c bao nhiu dd c th
dng phn bit 2 cht SO2 v SO3 u th kh.
A. 3
B. 2
C. 1
D. 4
Cu 43: Nhit phn hon ton hn hp gm m1 gam Fe(NO3)2 v m2 gam Al(NO3)3 thu c hn hp
kh X Trn hn hp kh X vi 112 ml kh O2 (ddktc) c hn hp kh Y. Hp th hon ton hn hp
kh Y vo 3,5 lt H2O ( khng thy c kh thot ra) c dung dch c pH = 1,7. Gi tr m 1 v m2 ln
lt l:
A. 4,5 v 6,39
B. 2,700 v 3,195
C. 3,60 v 2,130
D. 1,80 v 0,260
Cu 44: S ng phn -aminoaxit c cng thc phn t C4H9O2N l
A. 4
B. 5
C. 3
D. 2
Cu 45: Ha tan hon ton 3,76 gam hn hp: S, FeS, FeS 2 trong HNO3 d c 0,48 mol NO2 v
dung dch X. Cho dung dch Ba(OH)2 d vo X, lc kt ta nung n khi lng khng i th khi
lng cht rn thu c l:
A. 18,355 gam
B. 15,145 gam
C. 17,545 gam
D. 2,4 gam.
Cu 46: in phn nng chy Al2O3 vi anot than ch (hiu sut in phn 100%) thu c m gam
Al catot v 67,2 lt ( ktc) hn hp kh X c t khi so vi oxi bng 1. Ly 1,12 lt ( ktc) hn
hp kh X sc vo dung dch nc vi trong (d) thu c 1 gam kt ta. Gi tr ca m l
A. 54,0
B. 108,0
C. 75,6
D. 67,5
Cu 47: Cho a gam cht hu c X cha C, H, O tc dng vi dung dch NaOH va , sau chng
kh th phn bay hi ch c 1,8 gam nc, phn cht rn khan cn li cha hai mui ca natri c khi
lng 11,8 gam. Nung hai mui ny trong oxi d, sau khi phn ng hon ton, ta thu c 7,95 gam
Na2CO3; 7,28 lt kh CO2 (ktc) v 3,15 gam nc. Cng thc n gin nht ca X l:
A. C8H8O3.
B. C8H8O2.
C. C6H6O2.
D. C7H8O3.
Cu 48: Theo danh php IUPAC, hp cht ClCH(CH3)CH2CH(CH3)2 c tn gi l:
A. 4-clo2-metylpetan.
B. 2metylpentan2-clo.
C. 2clo-4-metylpentan.
D. 4etylbutan2clo.
Cu 49: X l mt hp cht mu lc thc t khng tan trong dd long axit v kim. Khi nu chy vi
K2CO3 c mt khng kh th chuyn thnh cht Y c mu vng (d tan trong nc). Cho cht Y tc
dng vi H2SO4 long to thnh cht Z c mu da cam. Cht Z tc dng vi HCl c thy to thnh
cht kh mu vng lc X, Y, Z ln lt l
A. CrO, K2CrO4, K2Cr2O7.
B. Cr2O3, K2CrO4, K2Cr2O7.
C. CrO3, K2Cr2O7, K2CrO4.
D. CrO, K2Cr2O7, K2CrO4.
Cu 50: Dung dch X cha 0,6 mol NaHCO 3 v 0,3 mol Na2CO3. Thm t t dung dch cha 0,8 mol
HCl vo dung dch X c dung dch Y v V lt CO 2 (ktc). Thm vo dung dch Y nc vi trong
d thy to thnh m gam kt ta. Gi tr ca V v m tng ng l
A. 11,2 lt; 90 gam.
B. 16,8 lit; 60 gam.
C. 11,2 lit; 60 gam.
D. 11,2 lt; 40 gam.
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