BI TP V LEUM

Oleum l Axit bc khi C cng thc : H2SO4.nSO2 nn khi tc dng H2O (n +1) H2SO4
n H 2SO 4
(n + 1).98
Nn : nOleum =
. Khi pha trn dung dch th c th coi oleum l axit c nng :
sau
98+ 80n
n +1
dng ng cho hoc cc kin thc dung dch tnh
Khi xc nh cng thc ca Oleum cn xc nh nH2 SO4 : n SO 3 theo bi tp lp cng thc
Phn ny rt t thi nn cc bn dng tham kho v c gng b sung cho t liu nh
Cu 1: Cho 0,015 mol mt loi hp cht oleum vo nc thu c 200 ml dung dch X. trung ho 100 ml
dung dch X cn dng 200 ml dung dch NaOH 0,15M. Phn trm v khi lng ca nguyn t lu hunh trong
oleum trn l
A. 23,97%.
B. 35,95%*.
C. 32,65%.
D. 37,86%.
n
Hng dn: nNaOH = 0,03 H SO = 0,015 Trong 200ml c 0,03 mol Cng thc: nSO3. H2SO4
2

0,03
.32

Bo ton cho S: (1 + n)0,015 = 0,03 n = 1 %S = 0,015

= 0,3595
.178
Cu 2: Ha tan 3,38g mt Oleum vo nc thu c dung dch A. trung ha A cn 800 ml dung dch KOH
0,1M . a) Hy xc nh cng thc ca Oleum
b) Cn ly bao nhiu gam A ha tan vo 200g nc thu c dung dch H2SO4 10%
Hng dn : nKOH = 0,08 n H 2SO 4 = 0,04 a =

3,38(n +1)
0,04
M=
= 84,5(n+1) = 98 + 80n n =
0,08
n +1

3
b) M = 338 Ly m gam mdd = (200 + m) mt = (200 + m).0,1 n H 2SO 4 =

( 200+ m ).0,1

98

( 200+ m ).0,1
m
=
11,6m = 200 + m m = 18,87g
338
98.4
98.4
392
Cch 2: Coi Oleum l dung dch H2SO4 =
=
= 116% Dng ng cho
98+ 80.3 338

a=

Cu 3: Ho tan 6,67g Oleum A vo nc thnh 200ml dung dch H2SO4 . Ly 10 ml dung dch ny trung ho
va ht 16 ml dung dch NaOH 0,5M.. Xc nh cng thc ca A
Hng dn : nNaOH = 0,008 n H
M=

2SO 4

= 0,004 Trong 200 ml c: 0,08 mol H2SO4 a =

6,67(n + 1)
= 83,375(n +1) = 98 + 80n n = 4
0,08

0,08
n +1

Cu 4: C 1 loi oleum X trong SO3 chim 71% theo khi lng. Xc nh cng thc ca X
Hng dn : CT ca oleum l H2SO4.nSO3

80n
= 0,71 n = 3
80n + 98

Cu 5: Hy xc nh cng thc lum to thnh khi cho 180g dung dch H2SO4 98% hp th ht 22,4 l SO3
(ktc). Tnh % khi lng SO3 trong oleum
Hng dn : n H 2SO 4 u = 1,8 m H 2SO 4 = 176,4 m H 2O = 3,6 n H 2O = 0,2 n H 2SO 4 thm 0,2 Tng 2
mol
n SO = 1 tham gia 0,2 cn 0,8 T l: 0,8 : 2 = 0,4 : 1 n = 0,4 H2SO4.0,4SO3
3

0,4.80

Tnh %SO3 = 98+ 0,4.80= 24,6%

Cu 6: cho 24,64 lit SO3(ktc) hp th ht vo 90g dd H2SO4 98%, thu c oleum c cng thc H2SO4.nSO3
Xc nh cng thc oleum
Hng dn : n H 2SO 4 u = 0,9 m H 2SO 4 = 88,2 m H 2O = 1,8 n H 2O = 0,1 n H 2SO 4 thm 0,1 Tng 1
mol
n SO = 1,1 tham gia 0,1 cn 1 T l: 1 : 1 n = 0,5 H2SO4.SO3
Bi 7:
Xc nh cng thc ca oleum A, bit rng sau khi em ha tan 3,38g A vo nc, phi dng 800ml
dung dch KOH 0,1 M mi trung ha ht dung dch to thnh.
- Cn ha tan bao nhiu gam oleum A vo 200g H2O c dung dch H2SO4 10%?
3

- Cn ha tan bao nhiu gam oleum A vo 200g dd H2SO4 98% c dd H2SO4 80%?
Bi 8:
Ha tan m gam SO3 vo 180g dung dch H2SO4 20% thu c dung dch H2SO4 32,5%. Gi tr m l bao
nhiu?
Bi 9:
Mt oleum c cng thc H2SO4.nSO3. Ly 3,38g oleum ni trn pha thnh 100ml dung dch X. trung
ha 50ml dung dch X cn dng 100ml dung dch NaOH 0,4M. Xc nh cng thc oleum.
Bi 10:
Cho 0,015 mol mt loi hp cht oleum vo nc thu c 200 ml dung dch X. trung ha 100ml
dung dch X cn dng 200ml dung dch NaOH 0,15M. Tnh phn trm v khi lng ca nguyn t lu
hunh trong oleum ni trn.
Bi 11:
Axit H2SO4 100% hp th SO3 to ra oleum theo phng trnh:
H2SO4 + SO3 = H2SO4.nSO3
Ha tan 6,76g oleum vo nc thnh 200ml dung dch H2SO4. trung ha 10ml dung dch ny cn
16ml dung dch NaOH 0,5M.
a) Tnh n
b) Tnh hm lng % ca SO3 trong oleum ni trn.
c) Cn bao nhiu gam oleum c hm lng SO3 nh trn pha vo 100ml dung dch H2SO4 40%(d=
1,31) to ra oleum c hm lng SO3 l 10%.