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------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).

C: 0436.453.591;D: 01236.575.369
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CHNG1: ESTE - LIPIT


A. TM TT L THUYT:

Khi
nim

Este
- Khi thay nhm OH nhm
cacboxyl ca axit cacboxylic
bng nhm OR th c este.
- Cng thc chung ca este
n chc: RCOOR ( To ra t
axit RCOOH v ancol ROH).
c
RCOOH + ROH HSO
RCOOR+
H2O
CTPT ca Este n chc: CnH2n 2kO2
(n 2)
CTPT ca Este no,n chc,mch h:
CnH2nO2 ( n 2 )
1/ Phn ng thy phn:
+) Mi trng axit:
RCOOR + H2O HSO RCOOH + ROH
+) Mi trng baz ( p/ x phng
ha):
RCOOR + NaOH RCOONa +
ROH
2/ Phn ng kh:
LiAlH
RCOOR + H2 RCH2OH + ROH
3/ Phn ng gc hirocacbon
khng no:
+) Phn ng cng:
VD: CH2 = CH COO CH3 + Br2
CH2Br CHBr COO CH3
+) Phn ng trng hp. Mt s este c
lin kt i C = C tham gia phn ng
trng hp nh anken. V d:
CH3
CH3
2

Tnh
cht
ha
hc

n CH2 =

xt,t

COOCH3
( metyl metacrylat)

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TI LIU N THI 2011.

( - CH2 -

- )n

COOCH3
(Knh kh v)

Lipit Cht bo
Lipit l nhng hp cht hu c c
trong t bo sng, khng ha tan trong
nc, tan nhiu trong dung mi hu
c.
Cht bo l Trieste ca glixerol vi axit
bo ( axit bo l axit n chc c mch
cacbon di v khng phn nhnh).
C H 2 O CO R1
|

CTCT: C| H O CO R2 ; ( RCOO ) 3 C 3 H 5
CH 2 O CO R3

1/ Phn ng thy phn:


( R COO)3C3H5 +3H2O H 3 R COOH +
C3H5(OH)3
2/ Phn ng x phng ha:
( R COO)3C3H5 +3NaOH 3 R COONa +
C3H5(OH)3
3/ Phn ng hiro ha cht bo lng(iu ch
b):
Ni
(C17H33COO)3C3H5+3H2 (C17H35COO)3C3H5
Triolein (Lng)
Tristearin (Rn)
4/ Phn ng oxiha( s i thiu ca lipit):
Du m ng thc vt lu thng c mi kh
chu, ta gi l hin tng i m. Nguyn nhn
ch yu l s oxi ha lin kt i bi O 2, khng
kh, hi nc v xc tc men, bin lipit thnh
peoxit, sau peoxit phn hy to thnh nhng
anehit v xeton c mi v c hi.
Ghi ch:
Ch s axit: l s mg KOH dng trung ha ht
lng axit bo t do c trong 1 gam cht bo.
Ch s x phng ha: l s mg KOH dng x
phng ha hon ton 1 gam cht bo.
Mt s axit bo thng gp:
C15H31COOH ( axit panmitic);
C17H35COOH (axit stearic);
CH3 (CH2)7 CH=CH (CH2)7 -COOH(axit oleic);
CH3 (CH2)4 CH = CH CH2 CH = CH
(CH2)7 COOH ( axit linoleic).
+

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------B. CC DNG BI TP:
1. Tm CTPT da vo phn ng chy:
V d 1: t chy hon ton 7,4 gam hn hp hai este ng phn, thu c 6,72 lt CO2 ( ktc) v 5,4
gam H2O. CTPT ca hai este l
A. C3H6O2
B. C2H4O2
C. C4H6O2
D. C4H8O2
GiI: n C = n CO2 = 0,3 (mol); n H = 2 n H2O = 0,6 (mol); n O = (7,4 0,3.12 0,6.1)/16 = 0,2 (mol).
Ta c: n C : n H : n O = 3 : 6 : 2. CTG ng thi cng l CTPT ca hai este l C3H6O2.
Chn p n A.
2. Tm CTCT thu gn ca cc ng phn este:
V d 2: S ng phn este ca C4H8O2 l:
A. 4
B. 5.
C. 6.
D. 7.
GII: Cc ng phn este ca C4H8O2 c CTCT thu gn l:HCOOCH2CH2CH3;HCOOCH(CH3)2;
CH3COOC2H5; C2H5COOCH3.
Chn p n A.
V d 3: Mt este c CTPT l C4H6O2, khi thy phn trong mi trng axit thu c axetanehit. CTCT thu
gn ca este l:
A. HCOOCH=CHCH3
B. CH2=CHCOOCH3.
C. CH3COOCH=CH2.
D. HCOOC(CH3)=CH2
GII: CH2=CHOH khng bn b phn hy thnh CH3CHO( axetanehit).
Chn p n C.
3. Tm CTCT ca este da vo phn ng thy phn trong mi trng kim:
Ghi nh: Khi x phng ha mt este
* cho mt mui v mt ancol n chc(anehit hoc xeton) th este n chc: RCOOR.
*cho mt mui v nhiu ancol th este a chc: R(COO R )a( axit a chc)
*cho nhiu mui v mt ancol th este a chc: ( R COO)aR ( ancol a chc)
*cho hai mui v nc th este c dng: RCOOC6H4R.
V d 4: X phng ha hon ton 22,2 gam hn hp hai este n chc, no, mch h l ng phn ca nhau
cn dng 300 ml NaOH 1M. Cng thc cu to ca hai este l:
A. CH3COOC2H5 v C2H5COOCH3.
B. HCOOC2H5 v CH3COOCH3.
C. CH3COOC2H3 v C2H3COOCH3.
D. C2H5COOC2H5 v CH3COOC3H7.
GII: CTPT ca este no, n chc mch h l CnH2nO2 ( n 2).
Ta c: n este = n NaOH = 1.0,3 = 0,3 ( mol) Meste = 22,2/0,3 = 74 14 n + 32 = 74 n = 3.
Chn p n B.
V d 5: X phng ha mt hp cht c cng thc phn t C10H14O6 trong dung dch NaOH (d)
thu c glixerol v hn hp gm ba mui ( khng c ng phn hnh hc). Cng thc ca ba mui l:
A. CH2=CH-COONa, HCOONa v CH C-COONa.
B. CH3-COONa, HCOONa v CH3-CH=CH-COONa.
C. HCOONa, CH C-COONa v CH3-CH2-COONa.
D. CH2=CH-COONa, CH3-CH2-COONa v HCOONa.
( Trch TSH A 2009 )
GII: CTTQ ca este l ( RCOO ) 3 C 3 H 5 .Phn ng:
( R COO)3C3H5 +3NaOH 3 R COONa + C3H5(OH)3. Ta c: tng 3 gc axit l C4H9.
Chn p n D.
V d 6: X phng ha 2,76 gam mt este X bng dung dch NaOH va , thu c 4,44 gam hn hp hai
mui ca natri. Nung nng hai mui ny trong oxi d, sau khi phn ng hon ton, thu c 3,18 gam
Na2CO3, 2,464 lt kh CO2 ( ktc) v 0,9 gam nc.Cng thc n gin cng l cng thc phn t ca X.
Vy CTCT thu gn ca X l:
A. HCOOC6H5.
B. CH3COOC6H5
C. HCOOC6H4OH.
D. C6H5COOCH3
GII: S phn ng:
2,76 gam X + NaOH 4,44 gam mui + H2O (1)
4,44 gam mui + O2 3,18 gam Na2CO3 + 2,464 lt CO2 + 0,9 gam H2O (2).
nNaOH = 2 n Na2CO3 = 0,06 (mol); m NaOH =0,06.40 = 2,4 (g). m H2O (1) =m X +mNaOH mmui = 0,72 (g)

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TI LIU N THI 2011.

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------mC(X) = mC( CO2) + mC(Na2CO3) = 1,68 (g); mH(X) = mH(H2O) mH(NaOH) = 0,12 (g);mO(X) = mX mC mH =
0,96 (g). T : nC : nH : nO = 7 : 6 : 3.
CTG v cng l CTPT ca X l C7H6O3.
Chn p n C.
4. Xc nh ch s axit, ch s x phng ha:
CH2 O CO C17H35
|

V d 7: Mt cht bo c cng thc

C H O CO C

H33 . Ch s x phng ha ca cht bo

17

CH2 O CO C17H31
A. 190.
B. 191.
C. 192.
D. 193.
GII: M cht bo = 884; MKOH = 56. Ch s x phng ha l: 56.1000.3/ 884 = 190.
Chn p n A.
V d 8: Trong Lipit khng tinh khit thng ln mt lng nh axit mono cacboxylic t do. Ch s axit ca
Lipit ny l 7. Khi lng NaOH cn dng trung ha 1 gam Lipit l:
A. 6 mg.
B. 5 mg.
C. 7 mg.
D. 4 mg.
GII: mNaOH = 7.40/ 56 = 5 (mg).
Chn p n B.
5. Hn hp este v axit cacboxylic tc dng vi dung dch kim:
V d 9: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH
0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn,
sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82
gam. Cng thc ca hai hp cht hu c trong X l
A. CH3COOH v CH3COOC2H5.
B. C2H5COOH v C2H5COOCH3.
C. HCOOH v HCOOC2H5.
D. HCOOH v HCOOC3H7.
( Trch TSH B 2009 )
GII: Ta c: nKOH = 0,04 (mol) > nancol = 0,015 (mol) hn hp X gm mt axit cacboxilic no, n chc v
mt este no n chc. naxit = 0,025 (mol); neste = 0,015 (mol).
Gi n l s nguyn t C trung bnh trong hn hp X. Cng thc chung C n H 2 n O2. Phn ng:
C n H 2 n O2 + ( 3 n -2)/2 O2 n CO2 + n H2O
Mol:
0,04
0,04 n
0,04 n
Ta c: 0,04 n ( 44 + 18) = 6,82 ; n = 11/4.Gi x; y ln lt l s nguyn t C trong phn t axit v este th:
(0,025x + 0,015 y)/0,04 = 11/4 hay 5 x + 3y =22.T : (x;y)=(2;4).
Chn p n A.
V d 10: Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp hai ln s mol Y) v este
Z c to ra t X v Y. Cho mt lng M tc dng va vi dung dch cha 0,2 mol NaOH, to ra 16,4
gam mui v 8,05 gam ancol. Cng thc ca X v Y l
A. HCOOH v CH3OH.
B. CH3COOH v CH3OH.
C. HCOOH v C3H7OH.
D. CH3COOH v C2H5OH.
( Trch TSH B 2010 )
GII: Gi nX = 2a (mol); nY = a (mol); nZ = b (mol).Theo gt c: nMui = 2a+b = 0,2 mol Mmui = 82
Gc axit l R = 15 X l CH3COOH.
Mt khc: 0,1 =(2a+b)<nancol = a + b < 2a + b = 0,2 40,25<Mancol < 80,5. Chn p n D
6. Bi tp tng hp:
V d 11: Thy phn este Z trong mi trng axit thu c hai cht hu c X v Y (MX < MY). Bng mt
phn ng c th chuyn ha X thnh Y. Cht Z khng th l:
A. metyl propionat.
B. metyl axetat.
C. etyl axetat.
D. vinyl axetat.
( Trch TSH B 2010 )
GII: p n A.

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TI LIU N THI 2011.

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------V d 12: Tng s hp cht hu c no, n chc, mch h, c cng cng thc phn t C5H10O2, phn ng
c vi dung dch NaOH nhng khng c phn ng trng bc l:
A. 4.
B. 5.
C. 8.
D. 9.
( Trch TSH B 2010 )
GiI: Axit c 4. Este c 5. p n D.
V d 13: Hp cht hu c mch h X c cng thc phn t C6H10O4. Thy phn X to ra hai ancol n
chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l:
A. CH3OCO-CH2-COOC2H5.
B. C2H5OCO-COOCH3.
C. CH3OCO-COOC3H7.
D. CH3OCO-CH2 CH2- COOC2H5.
( Trch TSH B 2010 )
GII: p n A.
Ch c este to thnh t hai ancol CH3OH v C2H5OH tc dung vi axit CH2(COOH)2.
V d 14: Hn hp M gm ancol no, n chc X v axit cacboxylicY, u mch h v c cng s nguyn t
C, tng s mol ca hai cht l 0,5 mol (s mol ca Y ln hn s mol ca X). Nu t chy hon ton M th
thu c 33,6 lt kh CO2 (ktc) v 25,2 gam H2O. Mt khc, nu un nng M vi H2SO4 c thc hin
phn ng este ha (hiu sut l 80%) th s gam este thu c l:
a. 34,20.
B. 27,36.
C. 22,80.
D. 18,24.
( Trch TSH A 2010 )
GII: nM =0,5 mol; nCO2 = 1,5 mol X v Y u c 3C trong phn t X l C3H7OH, Y l C3H8-2kO2.
P/ chy: C3H8O +O 2 3CO2 + 4H2O v C3H8 -2kO +O 2 3CO2 + ( 4-k)H2O.
Mol: x
4x
y
(4-k)y

x + y = 0,5

0,5 >y =
Vi: x < y
4 x + (4 k ) y = 1,4

0,6
> 0,25
k

1,2 <k < 2,4 k =2; y = 0,3 mol Y l C2H3COOH.

Este thu c l C2H3COOC3H7 v nEste = 0,2 mol. Vy khi lng mEste = 0,2. 114.80% = 18,24 g.
Chn p n D.
V d 15: Thy phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%, thu
c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l:
A. HCOOH v CH3COOH.
B. CH3COOH v C2H5COOH.
C. C2H5COOH v C3H7COOH.
D. HCOOH v C2H5COOH.
( Trch TSH A 2010 )

GII: nE =0,2 mol; nNaOH = 0,6 mol = 3nE


este E c 3 chc to ra bi ancol 3chc v hai axit.
(R1COO)2ROOCR2 + 3NaOH 2R1COONa + R2COONa + R(OH)3.
Mol:
0,2
0,4
0,2
Khi lng mui: 0,4(R1+67) + 0,2(R2 +67) = 43,6 2R1 + R2 = 17 R1 =1; R2 =15.
Chn p n A.
V d 16: t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu
c th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin). Cho m
gam X tc dng hon ton vi 200ml dung dch KOH 0,7M thu c 12,88 gam cht rn khan. Gi tr ca m
l:
A. 7,20.
B. 6,66.
C. 8,88.
D. 10,56.
( Trch TSH A 2010 )
GII: X l CnH2n-2kO2 ( k<2, v c mt lin kt chc).
3n k 2
6 3n k 2
2n = 3k+6 k=0, n=3.
P/: CnH2n-2kO2 +
O2 nCO2 + (n-k)H2O , ta c: n = .
2
7
2
CTPT ca X l: C3H6O2. CTCT l RCOOR vi R l H hoc CH3-.
Phn ng: RCOOR + KOH RCOOK + ROH
T : x(R + 83) +( 0,14 x).56 = 12,88
Mol:
x
x
x
Bin lun c R l CH3-v nX= 0,12 mol.
(R+27) = 5,04 R = 15, x = 0,12

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TI LIU N THI 2011.

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
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m = 0,12.74 = 8,88 gam. Chn p n C.

C.CU HI V BI TP TRC NGHIM T GII 1(S dng cho kim tra 45 pht):
1. Este no, n chc, mch h co CTPT TQ l
A, CnH2nO2 ( n 1 ).
B. CnH2nO2 ( n 2).
C. CnH2n-2O2 ( n 2).
D. CnH2n+2O2 ( n 2).
2. Este to bi ancol no, n chc, mch h v axit cacboxylic khng no(c mt ni i C = C), n chc,
mch h c CTPTTQ l:
A. CnH2n-2O2 ( n 4).
B. CnH2n-2O2 ( n 3).
C. CnH2nO2 (n 3).
D. CnH2n+2O2 ( n 4).
3. .Este to bi ancol khng no(c mt ni i C = C), n chc, mch h v axit cacboxylic no, n chc,
mch h c CTPTTQ l:
A. CnH2n-2O2 ( n 5).
B. CnH2n-2O2 ( n 4).
C. CnH2nO2 (n 3).
D. CnH2n+2O2 ( n 2).
4. S ng phn cu to ca cht c CTPT C4H8O2, u tc dng c vi dung dch NaOH l:
A. 3.
B. 4.
C. 5.
D. 6.
5. Mt este c CTPT l C3H6O2, c phn ng trng gng vi dung dch AgNO3 trong NH3. CTCT ca este
l:
A. HCOOC2H5
B. CH3COOCH3.
C. HCOOC3H7.
D. CH3COOC2H5.
6. Este C4H6O2 b thy phn trong mi trng axit thu c hn hp khng tham gia phn ng trng
gng. CTCT thu gn ca este l:
A. CH3COOCH=CH2.
B. HCOO-CH=CH-CH3.
C. CH2=CH-COO-CH3
D. HCOO-CH2- CH=CH2.
7. Hai este n chc X v Y l ng phn ca nhau. Khi ha hi 3,7 gam X , thu c th tch hi ng
bng th tch ca 1,4 gam N2 ( o cng iu kin). CTCT thu gn ca X, Y l:
A. C2H5COOCH3 v CH3COOC2H5.
B. HCOOC3H5 v C2H3COOCH3.
C. HCOOC2H5 v CH3COOCH3.
D. C2H3COOC2H5 v C2H5COOC2H3.
8. Cho 21,8 gam cht hu c A ch cha mt loi nhm chc tc dng vi 1 lt dung dch NaOH 0,5 M, thu
c 24,6 gam mui v 0,1 mol ancol.Cng thc cu to thu gn ca A l:
A. C3H7COOCH3.
B. C2H4 (COOC2H5)2
C. (C2H5COO)2C2H4
D. (CH3COO)3C3H5
9. Ha hi 27,2 gam mt este X thu c 4,48 lt kh ( quy v ktc). X phng ha X bng dung dch NaOH (
va ) thu c hn hp hai mui ca natri.Cng thc ca este X l
A. CH3 COO- C6H5.
B. C6H5 COO CH3.
C. C3H3 COO C4H5.
D. C4H5 COO C3H3.
10. t chy hon ton mt lng este no, n chc th th tch kh CO2 sinh ra lun bng th tch kh O2
cn cho phn ng ( o cng iu kin). Cng thc ca este l:
A. CH3COOCH3.
B. HCOOC2H5.
C. HCOOCH3.
D. CH3COOC2H5.
11. Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia phn x phng ha to ra
mt mui ca axit cacboxylic v mt cht c kh nng tham gia phn ng trng gng. S cng thc cu
to ph hp ca X l:
A. 2.
B. 3.
C. 4.
D. 5.
12. Este X c CTPT l C5H10O2. X phng ha X thu c mt ancol khng b oxi hoa bi CuO.
Tn ca X l:
A. isopropylaxetat.
B. isobutylfomiat.
C. propylaxetat.
D. Ter -thutylfomiat.
13. X phng ha hon ton Trieste X bng dung dch NaOH thu c 9,2 gam glixerol v 83,4 gam mui
ca mt axit bo no. Axit bo no l:
A. Axit oleic.
B. Axit stearic.
C. Axit panmitic.
D. Axit linoleic.
14. Hp cht thm A c CTPT C8H8O2 khi x phng ha thu c 2 mui. S ng phn cu to ph hp
ca A l:
A. 5.
B.3.
C. 2.
D. 4.
15. Thy phn este E c cng thc phn t C4H8O2 (c mt H2SO4 long) thu c hai sn phm hu c X
v Y. T X c th iu ch trc tip ra Y bng mt phn ng duy nht. Tn gi ca E l
A. metyl propionat
B. propyl fomiat
C. ancol etylic
D. etyl axetat
16. Thy phn hon ton hn hp gm hai este n chc X, Y l ng phn cu to ca nhau cn 100ml
dung dch NaOH 1M, thu c 7,85 gam hn hp hai mui ca hai axit l ng ng k tip v 4,95 gam hai
ancol bc I. Cng thc cu to v phn trm khi lng ca hai este l

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TI LIU N THI 2011.

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------A. HCOOCH2CH2CH3 75%, CH3COOC2H5 25%
B. HCOOC2H5 45%, CH3COOCH3 55%
C. HCOOC2H5 55%, CH3COOCH3 45%
D. HCOOCH2CH2CH3 25%, CH3COOC2H5 75%
17. Este X c cng thc n gin nht l C 2H4O. un si 4,4 gam X vi 200 gam dung dch NaOH 3% n
khi phn ng hon ton. t dung dch sau phn ng thu c 8,1 gam cht rn khan. Cng thc ca X l:
A. C2H5COOCH3
B. CH3COOC2H5
C. HCOOCH2CH2CH3
D. HCOOCH(CH3)2
18. Thy phn 4,3 gam este X n chc mch h (c xc tc axit) n khi phn ng hon ton thu c
hn hp hai cht hu c Y v Z. Cho Y, Z phn ng vi dung dch d AgNO 3/NH3 thu c 21,6 gam bc.
Cng thc cu to ca X l:
A. CH3COOCH=CH2
B. HCOOCH=CH-CH3
C. HCOOCH2CH=CH2
D. HCOOC(CH3)=CH2
19. Cho s phn ng:
O , memgiam
CH4 X X1 +HO X2 +
X3 +X X4
X4 c tn gi l
A. Natri axetat
B. Vinyl axetat
C. Metyl axetat
D. Ety axetat
20. A l mt este 3 chc mch h. un nng 7,9 gam A vi NaOH d. n khi phn ng hon ton thu
c ancol B v 8,6 gam hn hp mui D. Tch nc t B c th thu c propenal. Cho D tc dng vi
H2SO4 thu c 3 axit no, mch h, n chc, trong 2 axit c khi lng phn t nh l ng phn ca
nhau. Cng thc phn t ca axit c khi lng phn t ln l
A. C5H10O2
B. C7H16O2
C. C4H8O2
D. C6H12O2
21. Cho cc phn ng: X + 3NaOH t C6H5ONa + Y + CH3CHO + H2O
,t
Y + 2NaOH CaO

T + 2Na2CO3
CH3CHO + 2Cu(OH)2 + NaOH t Z +
Z + NaOH CaO,
t T + Na2CO3
Cng thc phn t ca X l
A. C12H20O6
B. C12H14O4
C. C11H10O4
D. C11H12O4
22. Cho s chuyn ha:
ddBr 2
NaOH
CuO ,t 0
O 2 , xt
CH 3OH ,t 0 , Xt :C
E(este a chc).
C3H6 X Y Z T
Tn gi ca Y l:
A. propan-1,3-iol
B. propan-1,2-iol.
C. propan-2-ol.
D. glixerol.
( Trch TSH A 2010 )
23. Cho hn hp X gm ancol metylic v hai axit cacboxylic (no, n chc, k tip nhau trong dy ng
ng) tc dng ht vi Na, gii phng ra 6,72 lt kh H2(ktc). Nu un nng hn hp X (c H2SO4c lm
xc tc) th cc cht trong hn hp phn ng va vi nhau to thnh 25 gam hn hp este (hiu sut
100%). Hai axit trong hn hp X l
A. HCOOH v CH3COOH.
B. CH3COOH v C2H5COOH.
C. C2H5COOH v C3H7COOH.
D. C3H7COOH v C4H9COOH.
( Trch TSH A 2010 )
24. Hp cht hu c mch h X c cng thc phn t C 5H10O. Cht X khng phn ng vi Na, tha mn s
chuyn ha sau:
H 2 ( Xt :Ni ,t 0 )
CH 3COOH ( H 2 SO 4 c )
X +
Y +

Este c mi chui chn.


Tn ca X l
A. pentanal.
B. 2-metylbutanal.
C. 2,2-imetylpropanal. D. 3-metylbutanal.
( Trch TSH B 2010 )
2

25. Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X cn 40 ml dung dch
NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO 2 (ktc) v 11,7 gam
H2O. S mol ca axit linoleic trong m gam hn hp X l
A. 0,015.
B. 0,010.
C. 0,020.
D. 0,005.
( Trch TSH B 2010 )
CU HI V BI TP TRC NGHIM T GII 2(S dng cho kim tra 90 pht) :

==================
TI LIU N THI 2011.

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------Cu 1: S ng phn este ng vi cng thc phn t C3H6O2 l
A. 5.
B. 4.
C. 2.
D. 3.
Cu 2: S ng phn este ng vi cng thc phn t C4H8O2 l
A. 2.
B. 3.
C. 4.
D. 5.
Cu 3: S ng phn n chc ng vi cng thc phn t C3H6O2 l
A. 2.
B. 3.
C. 4.
D. 5.
Cu 4: S ng phn n chc ng vi cng thc phn t C4H8O2 l
A. 6.
B. 3.
C. 4.
D. 5.
Cu 5: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc
dng vi: Na, NaOH, NaHCO3. S phn ng xy ra l
A. 2.
B. 5.
C. 4.
D. 3.
Cu 6: Cht X c cng thc phn t C3H6O2, l este ca axit axetic. Cng thc cu to thu gn ca X l
A. C2H5COOH.
B. HO-C2H4-CHO.
C. CH3COOCH3.
D. HCOOC2H5.
Cu 7: Hp cht X c cng thc cu to: CH3CH2COOCH3. Tn gi ca X l:
A. etyl axetat.
B. metyl propionat.
C. metyl axetat.
D. propyl axetat.
Cu 8: Thy phn este E c cng thc phn t C4H8O2 (c mt H2SO4 long) thu c 2 sn phm hu c
X v Y. T X c th iu ch trc tip ra Y bng mt phn ng duy nht. Tn gi ca E l:
A. metyl propionat.
B. propyl fomat.
C. ancol etylic.
D. etyl axetat.
Cu 9: Este etyl axetat c cng thc l
A. CH3CH2OH
B. CH3COOH.
C. CH3COOC2H5.
D. CH3CHO.
Cu 10: un nng este HCOOCH3 vi mt lng va dung dch NaOH, sn phm thu c l
A. CH3COONa v C2H5OH.
B. HCOONa v CH3OH.
C. HCOONa v C2H5OH.
D. CH3COONa v CH3OH.
Cu 11: Este etyl fomiat c cng thc l
A. CH3COOCH3.
B. HCOOC2H5.
C. HCOOCH=CH2.
D. HCOOCH3.
Cu 12: un nng este CH3COOC2H5 vi mt lng va dung dch NaOH, sn phm thu c l
A. CH3COONa v CH3OH.
B. CH3COONa v C2H5OH.
C. HCOONa v C2H5OH.
D. C2H5COONa v CH3OH.
Cu 13: Thy phn este X trong mi trng kim, thu c natri axetat v ancol etylic. Cng thc ca X l
A. C2H3COOC2H5.
B. CH3COOCH3.
C. C2H5COOCH3.
D. CH3COOC2H5.
Cu 14: Este metyl acrilat c cng thc l
A. CH3COOCH3.
B. CH3COOCH=CH2.
C. CH2=CHCOOCH3.
D. HCOOCH3.
Cu 15: Este vinyl axetat c cng thc l
A. CH3COOCH3.
B. CH3COOCH=CH2.
C. CH2=CHCOOCH3.
D. HCOOCH3.
Cu 16: un nng este CH3COOCH=CH2 vi mt lng va dung dch NaOH, sn phm thu c l
A. CH2=CHCOONa v CH3OH.
B. CH3COONa v CH3CHO.
C. CH3COONa v CH2=CHOH.
D. C2H5COONa v CH3OH.
Cu 17: un nng este CH2=CHCOOCH3 vi mt lng va dung dch NaOH, sn phm thu c l
A. CH2=CHCOONa v CH3OH.
B. CH3COONa v CH3CHO.
C. CH3COONa v CH2=CHOH.
D. C2H5COONa v CH3OH.
Cu 18: Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2 phn ng.
Tn gi ca este l
A. n-propyl axetat.
B. metyl axetat.
C. etyl axetat.
D. metyl fomiat.
Cu 19: Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi:
Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu to ca
X1, X2 ln lt l:
A. CH3-COOH, CH3-COO-CH3.
B. (CH3)2CH-OH, H-COO-CH3.
C. H-COO-CH3, CH3-COOH.
D. CH3-COOH, H-COO-CH3.
Cu 20: Cho s chuyn ha sau (mi mi tn l mt phng trnh phn ng):
Tinh bt X Y Z metyl axetat. Cc cht Y, Z trong s trn ln lt l:
A. C2H5OH, CH3COOH.
B. CH3COOH, CH3OH.

==================
TI LIU N THI 2011.

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------C. CH3COOH, C2H5OH.
D. C2H4, CH3COOH.
Cu 21: Mt este c cng thc phn t l C4H6O2, khi thu phn trong mi trng axit thu c
axetanehit. Cng thc cu to thu gn ca este l
A. HCOO-C(CH3)=CH2.
B. HCOO-CH=CH-CH3.
C. CH3COO-CH=CH2.
D. CH2=CH-COO-CH3.
Cu 22: Cho glixerol phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi trieste
c to ra ti a l
A. 6.
B. 3.
C. 5.
D. 4.
Cu 23: Cho cc cht: etyl axetat, ancol etylic, axit acrylic, phenol, phenylamoni clorua, ancol benzylic, pcrezol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l
A. 4.
B. 6.
C. 5.
D. 3.
Cu 24: Khi thu phn cht bo trong mi trng kim th thu c mui ca axit bo v
A. phenol.
B. glixerol.
C. ancol n chc.
D. este n chc.
Cu 25: Khi x phng ha tristearin ta thu c sn phm l
A. C15H31COONa v etanol.
B. C17H35COOH v glixerol.
C. C15H31COOH v glixerol.
D. C17H35COONa v glixerol.
Cu 26: Khi x phng ha tripanmitin ta thu c sn phm l
A. C15H31COONa v etanol.
B. C17H35COOH v glixerol.
C. C15H31COONa v glixerol.
D. C17H35COONa v glixerol.
Cu 27: Khi x phng ha triolein ta thu c sn phm l
A. C15H31COONa v etanol.
B. C17H35COOH v glixerol.
C. C15H31COONa v glixerol.
D. C17H33COONa v glixerol.
Cu 28: Khi thu phn trong mi trng axit tristearin ta thu c sn phm l
A. C15H31COONa v etanol.
B. C17H35COOH v glixerol.
C. C15H31COOH v glixerol.
D. C17H35COONa v glixerol.
Cu 29: un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti
trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ha l (Cho H = 1; C = 12; O = 16).
A. 50%
B. 62,5%
C. 55%
D. 75%
Cu 30: Cho 6 gam mt este ca axit cacboxylic no n chc v ancol no n chc phn ng va ht vi
100 ml dung dch NaOH 1M. Tn gi ca este l
A. etyl axetat.
B. propyl fomiat.
C. metyl axetat.
D. metyl fomiat.
Cu 31: trung ha lng axit t do c trong 14 gam mt mu cht bo cn 15ml dung dch KOH 0,1M.
Ch s axit ca mu cht bo trn l (Cho H = 1; O = 16; K = 39)
A. 4,8
B. 6,0
C. 5,5
D. 7,2
Cu 32: X phng ho hon ton 22,2 gam hn hp gm hai este HCOOC2H5 v CH3COOCH3 bng dung
dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l
A. 400 ml.
B. 300 ml.
C. 150 ml.
D. 200 ml.
Cu 33: X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau
phn ng thu c khi lng x phng l
A. 16,68 gam.
B. 18,38 gam.
C. 18,24 gam.
D. 17,80 gam.
Cu 34: X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra
hon ton, c cn dung dch thu c cht rn khan c khi lng l (cho H = 1, C = 12, O = 16, Na = 23)
A. 3,28 gam.
B. 8,56 gam.
C. 8,2 gam.
D. 10,4 gam.
Cu 35: Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S cht
trong dy tham gia phn ng trng gng l
A. 3.
B. 6.
C. 4.
D. 5.
Cu 36: Cht X c cng thc phn t C2H4O2, cho cht X tc dng vi dung dch NaOH to ra mui v
nc. Cht X thuc loi
A. ancol no a chc.
B. axit khng no n chc.
C. este no n chc.
D. axit no n chc.
Cu 37: t chy hon ton 7,8 gam este X thu c 11,44 gam CO 2 v 4,68 gam H2O. Cng thc phn t
ca este l

==================
TI LIU N THI 2011.

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------A. C4H8O4
B. C4H8O2
C. C2H4O2
D. C3H6O2
Cu 38: Thu phn hon ton 11,44 gam este no, n chc, mch h X vi 100ml dung dch NaOH 1,3M
(va ) thu c 5,98 gam mt ancol Y. Tn gi ca X l
A. Etyl fomat
B. Etyl axetat
C. Etyl propionat
D. Propyl axetat
Cu 39: Thu phn este X c CTPT C4H8O2 trong dung dch NaOH thu c hn hp hai cht hu c Y v
Z trong Y c t khi hi so vi H2 l 16. X c cng thc l
A. HCOOC3H7
B. CH3COOC2H5
C. HCOOC3H5
D. C2H5COOCH3
Cu 40: Propyl fomat c iu ch t
A. axit fomic v ancol metylic.
B. axit fomic v ancol propylic.
C. axit axetic v ancol propylic.
D. axit propionic v ancol metylic.
Cu 41: trung ho 14 gam mt cht bo cn 1,5 ml dung dch KOH 1M. Ch s axit ca cht bo l
A. 6
B. 5
C. 7
D. 8
Cu 42: C th gi tn este (C17H33COO)3C3H5 l
A. triolein
B. tristearin
C. tripanmitin
D. stearic
Cu 43: un nng cht bo cn va 40 kg dung dch NaOH 15%, gi s phn ng xy ra hon ton.
Khi lng (kg) glixerol thu c l:
A. 13,8
B. 4,6
C. 6,975
D. 9,2
Cu 44: X phng ho hon ton 37,0 gam hn hp 2 este l HCOOC 2H5 v CH3COOCH3 bng dung dch
NaOH, un nng. Khi lng NaOH cn dng l
A. 8,0g
B. 20,0g
C. 16,0g
D. 12,0g
Cu 45: Hp cht Y c cng thc phn t C4H8O2. Khi cho Y tc dng vi dung dch NaOH sinh ra cht Z c
cng thc C3H5O2Na. Cng thc cu to ca Y l
A. C2H5COOC2H5.
B. CH3COOC2H5.
C. C2H5COOCH3.
D. HCOOC3H7.
Cu 46: X phng ho hon ton 17,6 gam hn hp 2 este l etyl axetat v metyl propionat bng lng va
v (ml) dung dch NaOH 0,5M. Gi tr v dng l
A. 200 ml.
B. 500 ml.
C. 400 ml.
D. 600 ml.
Cu 47: Trong phn t este (X) no, n chc, mch h c thnh phn oxi chim 36,36 % khi lng. S
ng phn cu to ca X l:
A. 4.
B. 2.
C. 3.
D. 5.
Cu 48: X c cng thc phn t C4H8O2. Cho 20 gam X tc dng va vi NaOH c 15,44 gam mui X
l
A. C2H5COOCH3
B. HCOOC3H7
C. CH3COOC2H5
D. C3H7COOH
Cu 49: Thu phn este X trong mi trng kim thu c ancol etylic. Bit khi lng phn t ca ancol
bng 62,16% khi lng phn t ca este. Vy X c cng thc cu to l
A. HCOOCH3
B. HCOOC2H5
C. CH3COOC2H5
D. CH3COOCH3
Cu 50: t chy hon ton a gam hn hp cc este no, n chc mch h. Sn phm chy c dn vo
bnh ng dung dch Ca(OH)2 d thy khi lng bnh tng 12,4 gam. Khi lng kt ta to ra l
A. 12,40 gam
B. 10,00 gam
C. 20,00 gam
D. 28,18 gam

==================
TI LIU N THI 2011.

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------CHNG II: CACBOHIRAT
A.TM TT L THUYT:
Hp cht
MONOSACCARIT
Cacbohirat
Glucoz
Fructoz
Cng thc
C6H12O6
C6H12O6
phn t
CH2OH(CHOH)4
CH2OH[CHOH]3
CTCT thu
CHO
COCH2OH
gn
c im
-C nhiu
-C nhiu
cu to
nhm OH k
nhm OH k
nhau
nhau.
-C nhm
-Khng c
CHO
nhm CHO
Ha tnh
1/Tnhcht
AgNO3/ NH3
C
anehit
(do chuyn
ha glucoz)
2/Tnh cht
ancol a chc

ISACCARIT
Saccaroz
C12H22O11
C6H11O5 O
C6H11O5
- C nhiu
nhm OH k
nhau.
- Hai nhm
C6H12O5
Khng(ng
phn mantoz
c p/)

+Cu(OH)2

[C6H7O2(OH)3]n
- Mchxon.
-Nhiunhm
C6H12O5

-Mch thng
- C 3 nhm
OH k nhau
- Nhiu nhm
C6H12O5.

Khng

Khng

+Cu(OH)2

+Cu(OH)2
Khng

3/ Phn ng
thy phn

Khng

4/ Tnh cht
khc

POLISACCARIT
Tinh bt
Xenlunoz
(C6H10O5)n
(C6H10O5)n

Ln men
ru.

p/ mu vi I2

Chuyn ha
glucoz

+ HNO3,

1.Ha tnh ca Glucoz:


a. Tnh cht anehit n chc;
CH2OH[CHOH]4CHO + 2AgNO3 + 3NH3 + H2O CH2OH[CHOH]4COONH4 + 2Ag + NH4NO3.
CH2OH[CHOH]4CHO + 2Cu(OH)2 + NaOH t 0 CH2OH[CHOH]4COONa + 2Cu2O + 3H2O.
CH2OH[CHOH]4CHO + H2 Ni,t 0 CH2OH[CHOH]4CH2OH (sobitol).
b. Tnh cht ancol a chc:
2CH2OH[CHOH]4CHO + Cu(OH)2 (C6H11O6)2Cu + H2O
pridin
CH2OH[CHOH]4CHO + (CH3CO)2O
Este cha 5 gc CH3COO ( p/ chng t glucoz c 5 nhm OH).
c. Phn ng ln men:
, 30 35
C6H12O6 enzim

2 C2H5OH + 2CO2.
0

2. Ha tnh ca saccaroz:
Dung dch saccaroz + Cu(OH)2 dung dch ng saccarat mu xanh lam.
C12H22O11 + H2O H,t C6H12O6 (glucoz) + C6H12O6 (fructoz).
3. Ha tnh ca tinh bt v xenluloz:
H ,t
(C6H10O5)n (tinh bt hoc xenluloz) + n H2O n C6H12O6 ( glucoz).
H tinh bt + dd I2 hp cht mu xanh ( du hiu nhn bit h tinh bt)
[C6H7O2(OH)3]n ( Xenluloz) + 3n HNO3 [C6H7O2(ONO2)3]n + 3n H2O.
B. CC DNG BI TP:
DNG 1 Phn ng trng gng ca glucoz (C6H12O6)
+

==================
TI LIU N THI 2011.

10

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------C6H12O6 2Ag
m: 180 g 316 g
VD1: un nng 37,5 gam dung dch glucoz vi lng AgNO 3 /dung dch NH3 d, thu Nng %
ca dung dch glucoz l
A. 11,4 %
B. 14,4 %
C. 13,4 %
D. 12,4 %
6,48.180

HD: % = 108.37,5.2 .100% = 14,4%.Chn p n B.


DNG 2: Phn ng ln men ca glucoz (C6H12O6)
C6H12O6 2C2H5OH + 2CO2

Mol: 1
2
2
Lu : Bi ton thng gn vi gi thit cho CO2 hp th hon ton dd nc vi trong Ca(OH)2 thu
c khi lng kt ta CaCO3 hocs mol hn hp mui...T tnh c s mol CO 2 da vo
s mol mui.
VD2: Ln men m gam glucoz vi hiu sut 75%. Ton b CO 2 thot ra c dn vo dung dch
NaOH thu c 0,4 mol hn hp mui. Gi tr ca m l:
A. 36.
B. 48.
C. 27.
D. 54.
HD: m = 0,2.180 : 75% = 48( gam). Chn p n B
DNG 3: Phn ng thy phn saccaroz (C12H22O11)
C12H22O11 (saccaroz) C6H12O6 (glucoz) + C6H12O6 (fructoz)
C12H22O11 (mantoz) 2C6H12O6 (glucoz)
VD 3: Mun c 162 gam glucoz th khi lng saccaroz cn em thu phn hon ton l
A. 307,8 gam.
B. 412,2gam.
C. 421,4 gam.
D. 370,8 gam.
HD:
C12H22O11(Saccaroz)
C6H12O6
342 g
180 g

m=?
162g
msacaz =

162.342 9.342
=
=307,8(g). Chn p n A.
180
10

DNG 4: Phn ng thy phn tinh bt hoc xenluloz (C 6H10O5)n


( C6H10O5)n H n C6H12O6 (glucoz) H 2n C2H5OH + 2n CO2.

m:
162n
180n
92n
88n
VD4: Thy phn m gam tinh bt , sn phm thu c em ln men sn xut ancol
etylic, ton b kh CO2 sinh ra cho qua dung dch Ca(OH)2 d, thu c 750 gam kt
ta. Nu hiu sut qu trnh sn xut ancol l 80% th m c gi tr l:
A. 486,0.
B. 949,2.
C. 759,4.
D. 607,5.
1

HD: nCO2 = nCaCO3 = 7,5 mol. Vy m =

7,5.162n 100
.
= 759,4 (g). Chn p n C.
2n
80

DNG 5: Xenluloz + axitnitrit xenluloz trinitrat


[C6H7O2(OH)3]n + 3nHNO3 [C6H7O2(ONO2)3]n + 3nH2O
m:
162n
189n
297n
VD 5: T 16,20 tn xenluloz ngi ta sn xut c m tn xenluloz trinitrat (bit hiu sut phn
ng tnh theo xenluloz l 90%). Gi tr ca m l
A. 26,73.
B. 33,00.
C. 25,46.
D. 29,70.
HD: [C6H7O2(OH)3]n + 3nHNO3 [C6H7O2(ONO2)3]n + 3nH2O
162n
3n.63
297n
==================
TI LIU N THI 2011.

11

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------16,2
m=?
16, 2.297 n 90
.
m=
= 26,73 tn
162n
100
DNG 6: Kh glucoz bng hyro
C6H12O6 (glucoz) + H2 C6H14O6 (sobitol)
VD 6: Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l
A. 2,25 gam.
B. 1,80 gam.
C. 1,82 gam.
D. 1,44 gam.
HD: m =

1,82
100
.180.
= 2,25 (g). Chn p n A
182
80

DNG 7: Xc nh s mt xch (n)


VD 7:. Trong 1kg go cha 81% tinh bt c s mt xch C 6H10O5 l :
A. 3,011.1024.
B. 5,212.1024.
C. 3,011.1021.
D. 5,212.1021.
HD: S mt xch l:

1.103.81
.6,022.10 23 = 3,011.1024. Chn p n A.
100.162

DNG 8: Ton tng hp


VD 8: Phn ng tng hp glucoz trong cy xanh cn c cung cp nng lng t nh sng mt
tri:
C6H12O6
6 CO2 + 6H2O + 673 Kcal ASMT
C trong mt pht, mi cm2 l xanh nhn c 0,5 cal nng lng mt tri, nhng ch c 10%
c s dng vo phn ng tng hp glucoz. Thi gian mt cy c 1000 l xanh (din tch
mi l 10 cm2) sn sinh c 18 gam glucoz l:
A. 2 gi 14 pht 36 giy. B. 4 gi 29 pht 12. C. 2 gi 30 pht15.
D. 5 gi 00 pht00.
HD: sn sinh 18 gam glucoz cn: 673.18/180 = 67,3 (kcal)= 67300 (cal).
Trong mi pht, cy xanh nhn c: 1000.10.0,5 = 5000 (cal).
Nng lng c s dng sn sinh glucoz l: 5000.10% = 500 (cal).
Vy thi gian cn thit l: 67300/500 = 134,6(p)= 2 gi1436
Chn p n A.
VD 9: t chy hon ton 0,1 mol mt Cacbohirat (cacbohidrat) X thu c 52,8gam CO 2 v 19,8 gam
H2O. Bit X c phn ng trng bc, X l
A. Glucoz

B. Fructoz

HD: nC = nCO2 = 1,2mol ;

C. Saccaroz

D. Mantoz

n A = 2n H 2O = 2,2mol Cng thc cacbohirat l C12H22O11.

M X c phn ng trng bc. Vy X l mantoz . Chn p n D.


Ch :

H
1) A
B ( H l hiu sut phn ng)

mA = mB.

100
H
; mB = mA.
H
100

H1
2) A

H2

C ( H1, H2 l hiu sut phn ng)


100 100
H1 H 2
.
.
mA = mC.
; mC = mA.
.
H1 H 2
100 100
C.CU HI V BI TP TRC NGHIM 1 (Dng cho kim tra 45 pht):
1. phn bit glucoz v fructoz th nn chn thuc th no di y?
A. Cu(OH)2 trong mi trng kim nng
B. Dung dch AgNO3 trong NH3
C. Dung dch brom
D. Cu(OH)2

==================
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------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------2. nhn bit c tt c cc dung dch ca glucoz, glixerol, fomanehit,etanol cn dng thuc
th l
A. Cu(OH)2 trong mi trng kim
B. [Ag(NH3)2](OH)
C. Na kim loi.
D. Nc brom
3. phn bit cc dung dch ha cht ring bit: saccaroz, mantoz, etanol, fomalin c th dng
mt ha cht duy nht l
A. Cu(OH)2/ OH B. AgNO3/ NH3
C. H2/ Ni
D. Vi sa
4. Phn ng chng t glucoz c dng mch vng l phn ng vi:
A. Cu(OH)2
B. [Ag(NH3)2](OH)
C. H2/Ni (t0)
D. CH3OH/HCl
5. Fructoz khng phn ng vi cht no sau y?
A. H2/Ni,t0
B. Cu(OH)2
C. AgNO3/ NH3
D. dung dch brom
6. Phn ng no sau y c th chuyn ha glucz, fructoz thnh nhng sn phm ging nhau?
A. phn ng vi Cu(OH)2 B. phn ng vi [Ag(NH3)2](OH)
C. phn ng vi H2/Ni, t0
D. phn ng vi Na
7. Saccaroz c th tc dng c vi cc cht no di y?
A. H2/Ni,t0 v Cu(OH)2
B. Cu(OH)2 v CH3COOH/H2SO4 c
C. Cu(OH)2 v [Ag(NH3)2](OH)
D. H2/Ni,t0 v CH3COOH/H2SO4 c
8. Gia saccaroz v glucoz c c im ging nhau l:
A. u c ly t c ci ng
B. u b oxihoa bi [Ag(NH3)2](OH)
C.u c trong bit dchuyt thanh ngt
D.u ha tan Cu(OH)2 t0 thng cho dd xanh
lam
9. Tinh bt v xenluloz khc nhau ch:
A. phn ng thy phn
B. tan trong nc
C. thnh phn phn t
D. cu trc mch phn t
10. im ging nhau gia phn ng thy phn tinh bt v thy phn xenluloz l:
A. sn phm cui cng thu c
B. loi enzim lm xc tc
C. sn phm trung gian
D. lng nc tham gia qu trnh thy phn
11. un nng xenluloz trong dung dich axit v c long, thu c sn phm l:
A. saccaroz
B. glucoz
C. fructoz
D. mantoz
12. Mt cht khi thy phn trong mi trng axit long, un nng khng to ra glucoz.
Cht l:
A. saccaroz
B. xenluloz
C. tinh bt
D. protein
13. Cht khng tham gia phn ng thy phn l:
A.saccaroz
B. xenluloz
C. fructoz
D. tinh bt
14, Tinh bt, xenluloz, saccroz, mantoz u c kh nng tham gia phn ng:
A. ha tan Cu(OH)2
B. thy phn
C. trng gng
D. trng ngng
15. Pht biu khng ng l:
A. Dung dch fructoz ha tan c Cu(OH)2.
B. Thy phn (xc tc H+, t0) sacaroz cng nh mantoz u cho cng mt monosacarit.
C. Sn phm thy phn xenluloz (xc tc H +, t0) c th tham gia phn ng trng gng.
D. Dung dch mantoz tc dng vi Cu(OH)2 khi un nng cho kt ta Cu2O.
16. Cacbohirat ch cha hai gc glucoz trong phn t l
A. saccaroz.
B. mantoz.
C. tinh bt.
D. xenluloz.
17. ng dng no sau y khng phi l ng dng ca glucoz?
A. Trng gng, trng phch.
B. Nguyn liu sn xut cht do PVC.
C. Nguyn liu sn xut ancol etylic.
D. Lm thc phm dinh dng v thuc tng lc.
18. Dy gm cc dung dch u tham gia phn ng trng bc l:
A. glucoz, mantoz, axit fomic, anehit axetic
==================
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13

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------B. fructoz, mantoz, glixerol, anehit axetic
C. glucoz, glixerol, mantoz, axit fomic
D. glucoz, fructoz, mantoz, saccaroz
( Trch TSH A 2009 )
19. Pht biu no sau y l ng?
A. Saccaroz lm mt mu nc brom.
C. Xenluloz c cu trc mch phn nhnh.

B. Glucoz b kh bi dung dch AgNO3 trong NH3.


D. Amilopectin c cu trc mch phn nhnh.
( Trch TSH B 2009 )

20. Pht biu no sau y khng ng?


A. Glucoz tc dng c vi nc brom.
B. Khi glucoz dng mch vng th tt c cc nhm OH u to ete vi CH 3OH.
C. Glucoz tn ti dng mch h v dng mch vng.
D. dng mch h, glucoz c 5 nhm OH k nhau.
( Trch TSH B 2009 )
21. Ln men m gam glucoz vi hiu sut 90%, lng kh CO 2 sinh ra hp th ht vo dung dch
nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi
khi lng dung dch nc vi trong ban u. Gi tr ca m l:
A. 13,5.
B. 30,0.
C. 15,0.
D. 20,0.
( Trch TSH A 2009 )
22. T 1 tn nc ma cha 12% saccaroz c th thu hi c m (kg) saccaroz , vi hiu sut
thu hi 80%. Gi tr ca m l:
A. 96.
B.100.
C. 120.
D. 80.
23. Cho m gam tinh bt ln men sn xut ancol etylic, ton b lng CO 2 sinh ra cho qua dung
dch Ca(OH)2 d, thu c 750 gam kt ta. Bit hiu sut mi giai on ln men l 80%. Gi tr
ca m l:
A. 950,8.
B. 949,2.
C. 960,4.
D. 952,6.
24. Nh my ru bia H Ni sn xut ancol etylic t mn ca g cha 50% xenluloz. Mun iu
ch 1 tn ancol etylic ( hiu sut 70%) th khi lng ( kg) mn ca g cn dng l:
A. 5430.
B. 5432.
C. 5031.
D. 5060.
25. Xenluloz trinitrat l cht d chy v n mnh, c iu ch t xenluloz v axit nitric.
Mun iu ch 29,7 kg xenluloz trintrat (hiu sut 90%) th th tch axit ntric 96%
( D= 1,52 g/ml) cn dng l:
A. 14,39 lit.
B. 15,24 lt.
C. 14,52 lt.
D. 20,36 lt.
CU HI V BI TP TRC NGHIM T GII 2 (Dng cho kim tra 90 pht):
Cu 1: Trong phn t ca cacbohyrat lun c
A. nhm chc axit.
B. nhm chc xeton. C. nhm chc ancol. D. nhm chc anehit.
Cu 2: Cht thuc loi isaccarit l
A. glucoz.
B. saccaroz.
C. xenluloz.
D. fructoz.
Cu 3: Hai cht ng phn ca nhau l
A. glucoz v mantoz.B. fructoz v glucoz.C. fructoz v mantoz.D. saccaroz v glucoz.
Cu 4: Trong iu kin thch hp glucoz ln men to thnh kh CO 2 v
A. C2H5OH.
B. CH3COOH.
C. HCOOH.
D. CH3CHO.
Cu 5: Saccaroz v glucoz u c
A. phn ng vi AgNO3 trong dung dch NH3, un nng.
B. phn ng vi dung dch NaCl.
C. phn ng vi Cu(OH)2 nhit thng to thnh dung dch xanh lam.
D. phn ng thu phn trong mi trng axit.
==================
TI LIU N THI 2011.

14

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------Cu 6: Cho s chuyn ho: Glucoz X Y CH3COOH. Hai cht X, Y ln lt l
A. CH3CHO v CH3CH2OH.
B. CH3CH2OH v CH3CHO.
C. CH3CH(OH)COOH v CH3CHO.
D. CH3CH2OH v CH2=CH2.
Cu 7: Cht tham gia phn ng trng gng l
A. xenluloz.
B. tinh bt.
C. fructoz.
D. saccaroz.
Cu 8: Cht khng phn ng vi AgNO3 trong dung dch NH3, un nng to thnh Ag l
A. C6H12O6 (glucoz).B. CH3COOH.
C. HCHO.
D. HCOOH.
Cu 9: Dy gm cc dung dch u tc dng vi Cu(OH)2 l
A. glucoz, glixerol, ancol etylic.
B. glucoz, andehit fomic, natri axetat.
C. glucoz, glixerol, axit axetic.
D. glucoz, glixerol, natri axetat.
Cu 10: chng minh trong phn t ca glucoz c nhiu nhm hiroxyl, ngi ta cho dung dch
glucoz phn ng vi
A. Cu(OH)2 trong NaOH, un nng.
B. AgNO3 trong dung dch NH3, un nng.
C. Cu(OH)2 nhit thng.
D. kim loi Na.
Cu 11: Khi ln men 360 gam glucoz vi hiu sut 100%, khi lng ancol etylic thu c l
A. 184 gam.
B. 276 gam.
C. 92 gam.
D. 138 gam.
Cu 12: Cho m gam glucoz ln men thnh ru etylic vi hiu sut 80%. Hp th hon ton kh
CO2 sinh ra vo nc vi trong d thu c 20 gam kt ta. Gi tr ca m l
A. 14,4
B. 45.
C. 11,25
D. 22,5
Cu 13: un nng dung dch cha 27 gam glucoz vi AgNO 3 trong dung dch NH3 (d) th khi
lng Ag ti a thu c l
A. 16,2 gam.
B. 10,8 gam.
C. 21,6 gam.
D. 32,4 gam.
Cu 14: Cho 50ml dung dch glucoz cha r nng tc dng vi mt lng d AgNO 3 trong
dung dch NH3 thu c 2,16 gam bc kt ta. Nng mol (hoc mol/l) ca dung dch glucoz
dng l (Cho Ag = 108)
A. 0,20M
B. 0,01M
C. 0,02M
D. 0,10M
Cu 15: Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l
A. 2,25 gam.
B. 1,80 gam.
C. 1,82 gam.
D. 1,44 gam.
Cu 16: un nng xenluloz trong dung dch axit v c, thu c sn phm l
A. saccaroz.
B. glucoz.
C. fructoz.
D. mantoz.
Cu 17: Cho s chuyn ha sau: Tinh bt X Y axit axetic. X v Y ln lt l
A. ancol etylic, anehit axetic.
B. glucoz, ancol etylic.
C. glucoz, etyl axetat.
D. glucoz, anehit axetic.
Cu 18: Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia phn ng
A. ho tan Cu(OH)2. B. trng ngng.
C. trng gng.
D. thy phn.
Cu 19: Mt cht khi thy phn trong mi trng axit, un nng khng to ra glucoz. Cht l
A. protit.
B. saccaroz.
C. tinh bt.
D. xenluloz.
Cu 20: Cho dy cc cht: glucoz, xenluloz, saccaroz, tinh bt, fructoz. S cht trong dy
tham gia phn ng trng gng l
A. 3.
B. 4.
C. 2.
D. 5.
Cu 21: Thy phn 324 gam tinh bt vi hiu sut ca phn ng l 75%, khi lng glucoz thu
c l
A. 250 gam.
B. 300 gam.
C. 360 gam.
D. 270 gam.
Cu 22: T 16,20 tn xenluloz ngi ta sn xut c m tn xenluloz trinitrat (bit hiu sut
phn ng tnh theo xenluloz l 90%). Gi tr ca m l
A. 26,73.
B. 33,00.
C. 25,46.
D. 29,70.
Cu 23: Cho cc cht: ancol etylic, glixerol, glucoz, imetyl ete v axit fomic. S cht tc dng
c vi Cu(OH)2 l
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------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------A. 3.
B. 1.
C. 4.
D. 2.
Cu 24: Mun c 2610 gam glucoz th khi lng saccaroz cn em thu phn hon ton l
A. 4595 gam.
B. 4468 gam.
C. 4959 gam.
D. 4995 gam.
Cu 25: Thuc th phn bit glucoz v fructoz l
A. Cu(OH)2
B. dung dch brom.
C. [Ag(NH3)2] NO3
D. Na
Cu 26: un nng 37,5 gam dung dch glucoz vi lng AgNO 3/dung dch NH3 d, thu c 6,48
gam bc. Nng % ca dung dch glucoz l
A. 11,4 %
B. 14,4 %
C. 13,4 %
D. 12,4 %
Cu 27: Phn t khi trung bnh ca xenluloz l 1620 000. Gi tr n trong cng thc (C 6H10O5)n l
A. 10000.
B. 8000
C. 9000
D. 7000
Cu 28: Trng bc hon ton m gam glucoz thu c 86,4 gam Ag. Nu ln men hon ton m
gam glucoz ri cho kh CO2 thu c hp th vo nc vi trong d th lng kt ta thu c l
A. 60g.
B. 20g.
C. 40g.
D. 80g.
Cu 29: Trong cc cht sau: axit axetic, glixerol, glucoz, ancol etylic, xenluloz. S cht ha tan
c Cu(OH)2 nhit thng l
A. 3.
B. 5
C. 1
D. 4
Cu 30: Ln men 41,4 gam glucoz vi hiu sut 80%, lng kh thu c cho hp th hon ton
vo dung dch nc vi trong d th lng kt ta thu c l
A. 18,4.
B. 28,75g
C. 36,8g
D. 23g.
Cu 31: Cho m gam glucoz ln men thnh ancol etylic. Kh sinh ra cho vo nuc vi trong d thu
c 120 gam kt ta, bit hiu sut qu trnh ln men t 60%. Gi tr m l
A. 225 gam.
B. 112,5 gam.
C. 120 gam.
D. 180 gam
Cu 32: Cho cc dung dch sau: saccaroz, glucoz, anehit axetic, glixerol, ancol etylic, axetilen,
fructoz. S lng dung dch c th tham gia phn ng trng gng l
A. 3.
B. 4.
C. 5.
D. 2.
Cu 33: Khi thy phn saccaroz th thu c
A. ancol etylic.
B. glucoz v fructoz. C. glucoz.
D. fructoz.
Cu 34: Cng thc no sau y l ca xenluloz?
A. [C6H7O2(OH)3]n.
B. [C6H8O2(OH)3]n.
C. [C6H7O3(OH)3]n.
D. [C6H5O2(OH)3]n.
Cu 35: Dy cc cht no sau y u c phn ng thu phn trong mi trng axit?
A. Tinh bt, xenluloz, glucoz.
B. Tinh bt, xenluloz, fructoz.
C. Tinh bt, xenluloz, saccaroz.
D. Tinh bt, saccaroz, fructoz
Cu 36: T 1 kg go np ( c 80% tinh bt) khi ln men v chng ct s thu c V lt ancol etylic
( Ru np) c nng 450. Bit hiu sut ca qu trnh ln men l 80% v khi lng ring ca
ancol etylic l 0,807 g/ml. Gi tr ca V l:
A. 1,0.
B. 2,4.
C. 4,6
D. 2,0
Cu 37: t chy hon ton 10,26 gam mt cacbohirat X thu c 8,064 lt CO 2 ( ktc) v 5,94
gam H2O. X c M < 400 v c kh nng d phn ng trng gng. Tn gi ca X l:
A. glucoz.
B. saccaroz.
C. fructoz.
D. mantoz.
Cu 38: Cho s bin ha:
80%
40%
G (Xenluloz) 30% C6H12O6 C2H5OH 60% C4H6 Cao su buna.
Khi lng (tn) g cn dng sn xut 1 tn cao su l:
A. 52,08.
B. 54,20.
C. 40,86.
D. 42,35.
Cu 39: Cho 13,68 gam hn hp saccaroz v mantoz tc dng vi lng d dung dch AgNO 3
trong NH3 thu c 2,16 gam Ag kt ta. S mol ca saccaroz v mantoz trong hn hp
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16

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------tng ng l:
A. 0,01 v 0,03.
B. 0,03 v 0,01.
C. 0,01 v 0,02.
D. 0,02 v 0,03.
Cu 40: Phn ng tng hp glucoz trong cy xanh cn c cung cp nng lng t nh sng
mt tri:
C6H12O6
6 CO2 + 6H2O + 673 Kcal ASMT
2
C trong mt pht, mi cm l xanh nhn c 0,5 cal nng lng mt tri, nhng ch c 10%
c s dng vo phn ng tng hp glucoz. Thi gian mt cy c 1000 l xanh (din tch
mi l 10 cm2) sn sinh c 18 gam glucoz l:
A. 2 gi 14 pht 36 giy. B. 4 gi 29 pht 12. C. 2 gi 30 pht15.
D. 5 gi 00 pht00.
Cu 41: Thy phn hon ton 100ml dung dch ng mantoz 2M th thu c dung
dch X . Cho dung dch X tc dng vi dung dch AgNO3 / NH3 (d) th c m gam kt
ta. Gi tr ca m l
A. 21,6 gam
B. 43,2 gam
C. 86,4 gam
D. 32,4 gam
Cu 42: Cho cc dung dch v cc cht lng ring bit sau: glucoz , tinh bt, glixezol,
phenol, anehit axetic v benzen. Thuc th nhn bit cc dung dch trn l
A. Na, qu tm, Cu(OH)2.
B. Na, qu tm, AgNO3/NH3.
C. Na, qu tm, nc brom.
D. Cu(OH)2, dung dch I2, nc
brom.
Cu 43: Dng ha cht no sau y c th phn bit c cc dung dch Saccaroz ,
mantoz, etannol, etanal?
A. Cu(OH)2/OH- .
B. AgNO3/NH3
C. nc brom.
D. H2/Ni,t0.
Cu 44: Ln men a gam glucoz vi hiu sut 90% lng CO2 sinh ra hp th ht vo dung
dch nc vi trong thu c 10 gam kt ta, phn khi lng dung dch gim 3,4 gam so
vi ban u. Tnh a?
A. 13,5 gam.
B. 20,0 gam.
C. 15,0 gam.
D. 25,0 gam.
Cu 45: Khi sn xut ancol etylic t m gam glucoz, kh sinh ra cho hp th ht vo
dung dch cha 0,3 mol Ca(OH)2 thu c 20 gam kt ta. Bit hiu sut ca c qu
trmh l 60%. Khi lng m gam glucoz dng l:
A. 30 gam
B.30 gam hoc 60 gam.
C. 60 gam hoc 120
gam. D. Tt c u sai.
Cu 46: Dy gm cc dung dch u tc dng vi Cu(OH)2 l:
A. Glucoz, glixerin, mantoz, ru etylic.
B. Glucoz, glixerin, anehit fomic,
natri axetat.
C. Glucoz, glixerin, mantoz, natri axetat.
D. Glucoz, glixerin, mantoz,
axit axetic.
Cu 47: T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic ( hiu sut
80%). Oxi ha 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X. trung ha
hn hp X cn 720 ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l
A. 80%.
B. 10%.
C. 90%.
D. 20%.
( Trch TSH A - 2010 ).
Cu 48: Mt phn t saccaroz c:
A. mt gc - glucoz v mt gc fructoz. B. mt gc - glucoz v mt gc fructoz.
C. hai gc - glucoz
D. mt gc - glucoz v mt gc fructoz.
( Trch TSH A - 2010 ).
Cu 49: Cc dung dch phn ng c vi Cu(OH)2 nhit thng l:
A. glixerol, axit axetic, glucoz.
B. lng trng trng, fructoz, axeton.

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TI LIU N THI 2011.

17

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------C. anehit axetic, saccaroz, axit axetic.

D. Fructoz, axit acrylic, ancol etylic.


( Trch TSH B - 2010 ).
Cu 50: Cht X c c im sau: phn t c nhiu nhm OH, c v ngt, ha tan Cu(OH)2 nhit
thng, phn t c lin kt glicozit, lm mt mu nc brom. Cht X l:
A. xenluloz.
B. mantoz.
C. glucoz.
D. saccaroz.
( Trch TSH B - 2010 ).

CHNG III: AMIN AMINO AXIT - PROTEIN


A.TM TT L THUYT:
Amin
Aminoaxit
Amin l hp cht hu c coi nh
Aminoaxit l hp cht hu
Khi
c to nn khi thay th mt hay c tp chc, phn t cha
nim
nhiu nguyn t H trong phn t
ng thi nhm amino -NH2
NH3 bng gc hidrocacbon
v nhm cacboxyl -COOH.
TQ: RNH2( Bc 1)
TQ: H2N R COOH
VD: CH3 NH2
C6H5 NH2
VD: H2N CH2 COOH
CH3 NH CH3
( anilin )
(glyxin)
CTPT
CH3 N CH3
CH3 C H COOH
|
|
(alanin)
CH3
NH2
Ha tnh Tnh baz:
khng tan
- Lng tnh
CH3 NH2 +H2O
- p/ ha este
+
[CH3NH3] OH
- p/ trng gng
HCl
To mui
To mui
To mui
R NH2 + HCl
[C6H5
H2N - R- COOH + HCl
[R NH3]+Cl NH3]+Cl ClH3N R COOH
Kim
To mui
NaOH
H2N R COOH + NaOH
H2N RCOONa + H2O
Ancol
To este
Br2/H2
Cu(OH)2
Trng
ngng
1/ Ha tnh ca Amin:
a)Tnh baz:

Peptit v Protein
Peptit l hp cht cha
t 2 50 gc amino axit lin kt vi
nhau bi cc lin kt
peptit CO NH
Protein l loi polipeptit
cao phn t c PTK t
vi chc nghn n vi
triu.
-

p/ thy phn.
p/ mu biure.

To mui hoc thy


phn khi un nng
Thy phn khi un
nng

trng

v - aminoaxit tham d
p/ trng ngng

To hp cht mu tm

R NH2 + H OH R NH3+ + OH
+) Lc baz ca amin c nh gi bng hng s baz K b hoc pKb :
[ RNH 3+ ][OH ]
Kb =
v pKb = -log Kb.
[ RNH 2 ]
+) Anilin khng tan trong nc, khng lm i mu qu tm.
+) Tc dng vi axit: RNH2 + HCl RNH3Cl
+) Cc mui amoni tc dng d dng vi kim: RNH 3Cl + NaOH RNH2 + NaCl + H2O.
b) So snh tnh baz ca cc amin:
Tnh baz ca amin ph thuc vo s linh ng ca cp electron t do trn nguyn t nit:
+) Nhm y e s lm tng linh ng ca cp electron t do (n) trn nguyn t N nn tnh baz
tng.
==================
TI LIU N THI 2011.

18

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------+) Nhm ht e s lm gim s linh ng ca cp e t do trn nguyn t N nn tnh baz gim.
+) Khi c s lin hp n - ( nhm chc amin gn vo cacbon mang ni ) th cp e t do trn
nguyn t N cng km linh ng v tnh baz gim.
+) Tnh baz ca amin bc 3 cn ph thuc vo nhiu yu t khc trong c nh hng hiu ng
khng gian ca cc gc R.
S liu v pKa ca axit lin hp vi amin (pKa cng ln th tnh baz cng mnh):
(C6H5)2NH:0,9; C6H5NHC(CH3)3:3,78; C6H5NH2: 4,58; C6H5NHCH3: 4,85; C6H5NHC2H5: 5,11; NH3:
9,25; C3H5NH2: 9,7; (CH3)3N: 9,80; n- C4H9NH2: 10,60; CH3NH2: 10,62; C2H5NH2 v n-C12H25NH2:
10,63; n- C8H17NH2: 10,65; (CH3)2NH: 10,77; (C2H5)3N: 10,87; (C2H5)2NH: 10,93.
c) Phn ng th gc thm:
+) Halogen ha: Tng t phenol, anilin tc dng vi nc Br 2 to thnh kt ta trng 2,4,6- tribrom
anilin.
+) Sunfo ha: un nng anilin vi H2SO4 1800C s xy ra mt chui phn ng m sn phm
cui cng l axit sunfanilic.Cc amit ca axit sunfanilic gi l sunfonamit hay sunfamit c tnh cht
st trng khng sinh, c dng nhiu lm thuc tr bnh.
d) Phn ng vi axit nitr:
+) iu ch HNO2 : NaNO2 + H+ Na+ + HNO2.
+) Phn ng ca amin vi HNO2:
Amin bc 1 s c hin tng si bt kh: R-NH2 + HO NO R OH + N2 + H2O.
Amin bc 2 s to hp cht nit z mu vng:

R
R'

N H + HO N = O

R
R'

N N = O + H2O.

Amin bc 3 khng phn ng.


2/ Ha tnh ca Aminoaxit:
a) Tnh cht lng tnh:
+) Phn ng vi axit mnh: HOOC- CH2NH2 + HCl HOOC CH2 NH3 +Cl
+) Phn ng vi baz mnh: NH2- CH2- COOH + NaOH H2N CH2 COOONa + H2O
+) Tnh axit- baz ca dung dch amino axit ( R(NH 2)a(COOH)b )ph thuc vo a,b.
- Vi dung dch glyxin: NH2- CH2- COOH +H3N- CH2 COODung dch c mi trng trung tnh( a = b = 1) nn qu tm khng i mu
- Vi dung dch axit glutamic ( a = 1, b= 2)lm qu tm chuyn thnh mu
- Vi dung dch Lysin ( a=2, b =1)lm qu tm chuyn thnh mu xanh.
b) Phn ng este ho ca nhm -COOH

H 2N -CH 2-COOH +C 2H 5OH

khHCl

H 2N -CH2 -COOC2H5+H 2O

c) Phn ng trng ngng


- Cc axit-6-aminohexanoic v 7-aminoheptanoic c phn ng trng ngng khi un nng to ra
polime thuc loi poliamit.

n H-NH-[CH 2]5 CO-OH t

( NH-[CH 2]5 CO ) n +n H 2O
policaproamit (nilon-6)

3/ Ha tnh ca peptit v protein:


a) Phn ng thy phn:
+) Vi peptit: H2N- C H-CO-NH- C H-COOH+H2O
|

==================
TI LIU N THI 2011.

,t
H

hayenzim

NH2 - C| H-COOH + NH2- C| H-COO


19

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------R1
R2
R1
R2
+) Vi protein: Trong mi trng axit hoc ba z, protein b thy phn thnh cc aminoaxit.
b) Phn ng mu biure
Tc dng vi Cu(OH)2 cho hp cht phc mu tm
. a s cc aminoaxit trong thin nhin l -aminoaxit.
Sau y l s liu lin quan n 15 aminoaxit thng gp trong cu trc ca protein:
CNG THC
A. Axit monoaminomonocacboxylic
1/ C| H2 COOH
NH2
2/ CH3 C| H - COOH
NH2
3/ CH3 C| H C| H COOH
CH3 NH2
4/ CH3 C| H CH2 C| H COOH
CH3
NH2
5/ CH3 CH2 C| H C| H COOH
CH3 NH2
B. Axit iaminomonocacboxylic
6/ C| H2 CH2 CH2 CH2 C| H COOH
NH2
NH2
C. Axit monoaminoicacboxylic
7/ HOOC CH2 C| H COOH
NH2
8/ HOOC CH2 CH2 C| H COOH
NH2
C
C
9/ H2N || CH2 | H COOH
O
NH2
C
10/ H2N || CH2 CH2 C| H COOH
O
NH2
D. Aminoaxit cha nhm OH , -SH, -SR
11/ HO CH2 C| H - COOH
NH2
12/ CH3 C| H C| H COOH
OH NH2
13/ HS CH2 C| H COOH
NH2
14/ CH3S CH2 CH2 C| H COOH
==================
TI LIU N THI 2011.

TN GI

VIT TT

TAN

pHI

Glyxin
M= 75
Alanin
M= 89

Gly

25,5

5,97

Ala

16,6

6,00

Valin
M= 117

Val

6,8

5,96

Leuxin
M= 131

Leu

2,4

5,98

Iso leuxin
M= 131

Ile

2,1

6,00

Lysin
M= 146

Lys

Tt

9,74

Axit aspactic
M= 133

Asp

0,5

2,77

Axit glutamic
M= 147

Glu

0,7

3,22

Asparagin
M= 132

Asn

2,5

5,4

Glutamin
M= 146

Gln

3,6

5,7

Serin
M= 105
Threonin
M= 119

Ser

4,3

5,68

Thr

20,5

5,60

Xistein
M= 121

Cys

Tt

5,10

Methionin

Met

3,3

5,74
20

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------NH2
E. Aminoaxit cha vng thm
15/ C6H5 CH2 C| H COOH
NH2

M= 149
Phenylalanin
M= 165

Phe

2,7

5,48

B.CC DNG BI TP:


1.Xc nh CTPT ca hp cht cha Nit da vo phn ng chy:
CxHyOzNt + ( x +

y
z
) O2
4
2

x CO2 +

y
t
H2O +
N2.
2
2

V d 1: t chy hon ton hn hp hai amin no, n chc, mch h l ng ng lin tip thu
c 2,24 lt kh CO2 ( ktc) v 3,6 gam H2O. CTPT ca hai amin l:
A. CH3NH2 v C2H5NH2.B. C2H5NH2 v C3H7NH2.
C. C3H7NH2 v C4H9NH2.
D. C4H9NH2 v C5H11NH2.
HD: CTPTTQ ca amin no, n chc, mch h l CnH2n+3N.
nC(hh) = nC(CO2) = 2,24/22,4 = 0,1 (mol); nH(hh) = 2nH(H2O) = 2.3,6/18 = 0,4 nC : nH =1:4

n
=1/4
2n + 3

= 1,5 2 amin l: CH3NH2 v C2H5NH2.

Chn p n A.
2. Xc nh CTCT ca amin, ng phn amin:
V d 2: Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui.
S ng phn cu to ca X l:
A.8.
B.7.
C.5.
D.4.
( Trch TSH A 2009 )
HD: Phn ng: R NH2 + HCl [R-NH3]+Cl - .
S mol n amin = nHCl = (15 10)/ 36,5 m amin = ( R + 16)/ 7,3 = 10 R = 57 R l C4H9 - .
Cc ng phn amin ca X l: CH3CH2CH2CH2NH2; CH3CH(CH3)CH2NH2;
(CH3)3 C(NH2);CH3CH2CH(NH2)CH3; CH3CH2CH2NHCH3;CH3CH2NHCH2CH3;(CH3)2 CH(NH)CH3;
CH3CH2N(CH3)2; C 8 ng phn.
Chn p n A.
Ch : Khi vit ng phn amin nn vit t ng phn bc 1( R-NH 2), n bc 2(R-NH-R),
bc 3(R-N-R).
|
R
3. Xc nh cng thc aminoaxit:
V d 3: Cho 1 mol aminoaxit X phn ng vi dung dch HCl (d), thu c m 1 gam mui Y. Cng
1 mol aminoaxit X phn ng vi dung dch NaOH (d), thu c m 2 gam mui Z. Bit m2 m1 =
7,5. Cng thc phn t ca X l:
A. C4H10O2N.
B. C5H9O4N.
C. C4H8O4N2.
D. C5H11O2N.
( Trch TSH A 2009 )
HD: (H2N)xR(COOH)y + x HCl (ClH3N)xR(COOH)y;
(H2N)xR(COOH)y +y NaOH (H2N)xR(COONa)y + y H2O.
Theo bi ra v theo cc phn ng ta c: m2 m1 = 23 y 36,5x y = 7,5 44y = 73x +15.
Ch c x =1; y = 2 l ph hp vi cc kt qu trong p n.
Chn p n B.
Ch : Nu y l bi ton t lun th s c v s p n v c v s cp x,y tha mn, mt khc
mi cp x, y li tng ng vi gc R ty .
==================
TI LIU N THI 2011.

21

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------V d 4: Cho 0,02 mol aminoaxit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67
gam mui khan. Mt khc 0,02 mol X tc tc dng va vi 40 gam dung dch NaOH 4%. Cng
thc ca X l:
A. H2NC2H3(COOH)2. B. H2NC3H5(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH.
( Trch TSH B 2009 )
HD: (H2N)xR(COOH)y + x HCl (ClH3N)xR(COOH)y;
(H2N)xR(COOH)y +y NaOH (H2N)xR(COONa)y + y H2O.
Ta c: nHCl = 0,1.200.10 -3 = 0,02 (mol) = nX; nNaOH = 40.4%/40 = 0,04 (mol) = 2nx x =1; y = 2.
mMui = 0,02( R + 52,5 + 2.45) = 3,67 R = 41 R l C3H5.
Chn p n B.
4. Vit cng thc cu to cc ng phn Peptit v protein;
V d 5: S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l:
A. 3.
B. 1.
C.2.
D. 4.
( Trch TSH B 2009 )
HD: Gly Ala v Ala Gly l hai cht khc nhau.
H2NCH2CONHCH2COOH (Gly Gly); H2NCH2CONHCH(CH3)COOH ( Gly Ala);
H2NCH(CH3)CONHCH(CH3) COOH; H2NCH(CH3)CONHCH2COOH ( Ala Gly);
Chn p n D.
5. Bi tp tng hp:
V d 6: Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn
ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO 2, x mol H2O v y
mol N2. Cc gi tr x, y tng ng l
A. 7 v 1,0.
B. 8 v 1,5.
C. 8 v 1,0.
D. 7 v 1,5.
( Trch TSH A 2010 )
HD: aminoaxit l CmH2m -1O4N, amin l CnH2n+3N
2m 1
1
H2O + N2
2
2
2
n
+
3
1
CnH2n+3N +O 2 nCO2 +
H2O +
N2
2
2
S mol CO2 l : n+m =6 nH2O = n + m+ 1 = 7. S mol N2 = 1. Chn p n A.
V d 7: t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp gm
kh cacbonic, kh nit v hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc dng
vi axit nitr nhit thng, gii phng kh nit. Cht X l
A. CH3-CH2-CH2-NH2.
B. CH2=CH-CH2-NH2.
C. CH3-CH2-NH-CH3.
D. CH2=CH-NH-CH3.

Phn ng chy: CmH2m -1O4N +O 2 m CO2 +

( Trch TSH A 2010 )


HD: L amin bc 1: R NH2 + HO NO R OH + N2 + H2O. Chn p n A.
V d 8: Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch
NaOH (d), thu c dung dch Y cha (m+30,8) gam mui. Mt khc, nu cho m gam X tc dng
hon ton vi dung dch HCl, thu c dung dch Z cha (m+36,5) gam mui. Gi tr ca m l
A. 171,0.
B. 165,6.
C. 123,8.
D. 112,2.
( Trch TSH B 2010 )
HD: S dng phng php tng gim khi lng.
m gam X + HCl (m+36,5) gam mui. Do : nX = nHCl = 1 mol.
CH3 CH(NH2)- COOH + NaOH
CH3 CH(NH2)- COONa + H2O
mol:
x
x
C3H7N (COOH)2 + 2 NaOH
C3H7N (COONa)2 + 2 H2O.
mol:
y
y
==================
22
TI LIU N THI 2011.

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
--------------------------------------------------------------------------------------------------------------------------

x+ y = 1
Ta c h:

22 x + 44 y = 30,8

x = 0,6
. Vy m = 0,6.89 + 0,4. 147 = 112,2(g).
y = 0,4

Chn p n D.

C. CU HI V BI TP TRC NGHIM T GII 1 ( Dng cho kim tra 45 pht):


1. Nguyn nhn gy ra tnh baz ca amin l:
A. do amin d tan trong nc.
B. do nguyn t N cn cp electron t do.
C. do phn t amin b phn cc.
D. do amin c kh nng tc dng vi axit.
2. Trong cc cht: CH3CH2NH2; (CH3)2NH; (CH3)3N v NH3. Cht c tnh baz mnh nht l:
A. NH3.
B. (CH3)3N.
C. (CH3)2NH.
D. CH3CH2NH2.
3. Trong cc cht: CH3NH2; C2H5NH2; (CH3)2NH; C6H5NH2.Cht c tnh baz mnh nht l:
A. CH3NH2.
B. C2H5NH2.
C. (CH3)2NH.
D. C6H5NH2.
4. tch ring hn hp kh CH4 v CH3NH2 c th dng dung dch:
A. HCl.
B. HNO3.
C. HCl v NaOH.
D. NaOH v Br2.
5. Pht biu no sau y khng ng?
A. Anilin tc dng c vi HBr v trn N cn c i electron t do.
B. Anilin c tnh baz yu hn NH3 v nh hng ht e ca nhn thm ln nhm chc NH 2.
C. Anilin tc dng c vi dung dch Br2 v c tnh baz.
D. Anilin khng lm i mu giy qu tm m.
6. Tn gi ca aminoaxit c cng thc cu to CH 3 CH(NH2) COOH l:
A. axit - aminopropionic.
B. axit - aminoaxetic.

C. axit
- aminopropionic.
D. axit - aminoaxetic.
7. Trong cc hp cht sau, hp cht no khng lng tnh?
A. Amino axetat.
B. Lizin.
C. Phenol.
D. Alanin.
8. S ng phn aminoaxit ca C4H9O2N l:
A. 3.
B. 4.
C. 5.
D. 6.
9. S ng phn cu to c cng thc phn t C4H11N l:
A. 5.
B. 6.
C. 7.
D. 8.
10. Dung dch glixin ( axit amino axetic) c mi trng:
A. axit.
B. baz.
C. trung tnh.
D. khng xc nh.
11. Cht X c cng thc phn t C3H7O2N. X c th tc dng vi NaOH, HCl v lm mt mu dung
dch brom. Cng thc cu to ca X l:
A. CH2=CHCOONH4.
B. H2NCH2CH2COOH.
C. CH3CH(NH2)COOH.
D. CH3CH2CH2NO2.
12. Khng nh no sau y khng ng?
A. Cc amin u kt hp vi prpton.
B. Tnh baz ca cc amin u mnh hn NH3.
C. CTTQ ca amin no, mch h l CnH2n+2+kNk.D. Metylamin c tnh baz mnh hn anilin.
13. Cho (CH3)2NH vo nc, lc nh, sau yn th c:
A. hn hp c nh sa.
B. hai lp cht lng khng tan vo nhau.
C. dung dch trong sut ng nht.
D. cc ht kt tinh khng mu lng xung y.
14. Cp ancol v amin no sau y cng bc?
A. (CH3)2CHOH v (CH3)2CHNH2.
B.(CH3)3COH v (CH3)3CNH2.
C. C6H5CH(OH)CH3 v C6H5NHCH3.
D. C6H5CH2OH v (C6H5)2NH.
15. Phn ng no di y khng th hin tnh baz ca amin?
A. CH3NH2 + H2O CH3NH3+ + OH -.
B. Fe3++ 3CH3NH2+ 3H2O Fe(OH)3 +3CH3NH3+.
==================
TI LIU N THI 2011.

23

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------C. CH3NH2 + HNO2 CH3OH + N2 + H2O. D. C6H5NH2 + HCl C6H5NH3Cl.
16. Cho s phn ng: X C6H6 Y anilin. X v Y tng ng l:
A. C2H2 v C6H5NO2.
B. C2H2 v C6H5-CH3
C.xiclohecxan v C6H5-CH3.
D. CH4 v C6H5NO2.
17. phn bit 3 dung dch H2NCH2COOH, CH3COOH v C2H5NH2 ch cn dng mt thuc th l:
A. Na kim loi.
B. dung dch NaOH. C. qu tm.
D. dung dch HCl.
18. Pht biu no sau y l ng?
A. Anilin tc dng vi axit nitr khi un nng thu c mui iazoni.
B. Benzen lm mt mu nc brom nhit thng.
C. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh.
D. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam.
( Trch TSH A 2009 )
19. Thuc th c dng phn bit Gly Ala Gly vi Gly Ala l:
A. Cu(OH)2 trong mi trng kim.
B. dung dch NaCl.
C. dung dch HCl.
D. dung dch NaOH.
( Trch TSH A 2009 )
20. Dy gm cc cht v thuc u c th gy nghin cho con ngi l:
A. penixilin, paradol, cocain.
B. heroin, seduxen, erythromixin.
C. cocain, seduxen, cafein.
D. ampixilin, erythromixin, cafein.
( Trch TSH A 2009 )
21. Ngi ta iu ch anilin bng s sau:
HNO c ( H SO )
t )
Benzen +
(
Anilin.

Nitrobenzen Fe+ HCl


Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t
50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l:
A. 186,0 gam.
B. 55,8 gam.
C. 93,0 gam.
D. 111,6 gam.
( Trch TSH B 2009 )
22. Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi
dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh , lm giy qu
tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z
thu c m gam mui khan. Gi tr ca m l:
A. 8,2.
B. 10,8.
C. 9,4.
D. 9,6.
( Trch TSH A 2009 )
23. Cht X ( cha C,H,O,N) c thnh phn % theo khi lng cc nguyn t C,H,O ln lt l
40,45%;7,86%; 35,96%. X tc dng vi NaOH v vi HCl, X c ngun gc t thin nhin v
MX <100. Cng thc cu to thu gn ca X l:
A. CH3CH(NH2)COOH.
B. H2NCH2CH2COOH.
C. H2NCH2COOH.
D. H2NCH2CH(NH2)COOH.
24. Cho 18,6 gam mt ankylamin tc dng vi dung dch FeCl 3 (d), thu c 21,4 gam kt ta.
Cng thc cu to thu gn ca ankylamin l:
A. CH3NH2.
B. C2H5NH2.
C. C3H7NH2.
D. C4H9NH2.
25. X l mt - aminoaxit ch cha 1 nhm NH2 v 1 nhm COOH, Cho 0,89 gam X phn ng
va vi NaOH to ra 1,11 gam mui. Cng thc cu to ca X c th l:
A. NH2 CH2 COOH.
B. CH3 CH(NH2) COOH.
C. NH2 CH2 CH2 COOH.
D. NH2 CH = CH COOH.
C. CU HI V BI TP TRC NGHIM T GII 2 ( Dng cho kim tra 90 pht):
3

Cu 1: S ng phn amin c cng thc phn t C2H7N l


A. 4.
B. 3.
C. 2.
Cu 2: S ng phn amin c cng thc phn t C3H9N l

==================
TI LIU N THI 2011.

D. 5.

24

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------A. 4.
B. 3.
C. 2.
D. 5.
Cu 3: S ng phn amin c cng thc phn t C4H11N l
A. 5.
B. 7.
C. 6.
D. 8.
Cu 4: S ng phn amin bc mt ng vi cng thc phn t C3H9N l
A. 4.
B. 3.
C. 2.
D. 5.
Cu 5: S ng phn amin bc mt ng vi cng thc phn t C4H11N l
A. 4.
B. 3.
C. 2.
D. 5.
Cu 6: C bao nhiu amin cha vng benzen c cng cng thc phn t C7H9N ?
A. 3 amin.
B. 5 amin.
C. 6 amin.
D. 7 amin.
Cu 7: Anilin c cng thc l
A. CH3COOH.
B. C6H5OH.
C. C6H5NH2.
D. CH3OH.
Cu 8: Trong cc cht sau, cht no l amin bc 2?
A. H2N-[CH2]6NH2
B. CH3CH(CH3)NH2
C. CH3NHCH3
D. C6H5NH2
Cu 9: C bao nhiu amin bc hai c cng cng thc phn t C5H13N ?
A. 4 amin.
B. 5 amin.
C. 6 amin.
D. 7 amin.
Cu 10: Trong cc tn gi di y, tn no ph hp vi cht CH3CH(CH3)NH2?
A. Metyletylamin.
B. Etylmetylamin.
C. Isopropanamin.
D. Isopropylamin.
Cu 11: Trong cc cht: C6H5CH2NH2 , NH3 , C6H5NH2 , (CH3)2NH , cht c lc baz mnh nht l:
A. NH3
B. C6H5CH2NH2
C. C6H5NH2
D. (CH3)2NH
Cu 12: Trong cc cht: C6H5NH2 , C6H5CH2NH2 , (C6H5)2NH, NH3 cht c lc baz yu nht l:
A. C6H5NH2
B. C6H5CH2NH2
C. (C6H5)2NH
D. NH3
Cu 13: Trong cc tn gi di y, tn no ph hp vi cht C6H5-CH2-NH2?
A. Phenylamin.
B. Benzylamin.
C. Anilin.
D. Phenylmetylamin.
Cu 14: Trong cc cht di y, cht no c tnh baz mnh nht ?
A. C6H5NH2.
B. (C6H5)2NH
C. p-CH3-C6H4-NH2.
D. C6H5-CH2-NH2
Cu 15: Cht khng c kh nng lm xanh nc qu tm l
A. Anilin
B. Natri hiroxit.
C. Natri axetat.
D. Amoniac.
Cu 16: Cht khng phn ng vi dung dch NaOH l
A. C6H5NH3Cl.
B. C6H5CH2OH.
C. p-CH3C6H4OH.
D. C6H5OH.
Cu 17: C th tch ring cc cht t hn hp lng gm benzen v anilin bng nhng cht no?
A. Dung dch NaOH, dung dch brom

B. Dung dch HCl, dung dch NaOH

C. H2O, dung dch brom

D. Dung dch NaCl, dung dch brom

Cu 18: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l:


A. anilin, metyl amin, amoniac.
B. amoni clorua, metyl amin, natri hiroxit.
C. anilin, amoniac, natri hiroxit.
D. metyl amin, amoniac, natri axetat.
Cu 19: Kt ta xut hin khi nh dung dch brom vo
A. ancol etylic.
B. benzen.
C. anilin.
D. axit axetic.
Cu 20: Cht lm giy qu tm m chuyn thnh mu xanh l
A. C2H5OH.
B. CH3NH2.
C. C6H5NH2.
D. NaCl.
Cu 21: Anilin (C6H5NH2) phn ng vi dung dch
A. NaOH.
B. HCl.
C. Na2CO3.
D. NaCl.
Cu 22: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3
cht lng trn l
A. dung dch phenolphtalein.
B. nc brom.
C. dung dch NaOH.
D. giy qu tm.
Cu 23: Anilin (C6H5NH2) v phenol (C6H5OH) u c phn ng vi
A. dung dch NaCl.
B. dung dch HCl.
C. nc Br2.
D. dung dch NaOH.
Cu 24: Dung dch metylamin trong nc lm
A. qu tm khng i mu.
B. qu tm ha xanh.
C. phenolphtalein ho xanh.
D. phenolphtalein khng i mu.

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------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------Cu 25: Cht c tnh baz l
A. CH3NH2.
B. CH3COOH.
C. CH3CHO.
D. C6H5OH.
Cu 26: em trng ngng hn hp gm 22,5 gam glyxin v 44,5 gam alanin thu c m gam protein vi
hiu sut mi phn ng l 80%. Vy m c gi tr l:
A. 42,08 gam.

B. 38,40gam

C. 49,20gam

D. 52,60 gam

Cu 27: Cho 9,3 gam anilin (C6H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l
A. 11,95 gam.
B. 12,95 gam.
C. 12,59 gam.
D. 11,85 gam.
Cu 28: Cho 5,9 gam etylamin (C3H7NH2) tc dng va vi axit HCl. Khi lng mui (C3H7NH3Cl) thu
c l (Cho H = 1, C = 12, N = 14)
A. 8,15 gam.
B. 9,65 gam.
C. 8,10 gam.
D. 9,55 gam.
Cu 29: Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l
A. 7,65 gam.
B. 8,15 gam.
C. 8,10 gam.
D. 0,85 gam.
Cu 30: Cho anilin tc dng va vi dung dch HCl thu c 38,85 gam mui. Khi lng anilin phn
ng l
A. 18,6g
B. 9,3g
C. 37,2g
D. 27,9g.
Cu 31: Trung ha 11,8 gam mt amin n chc cn 200 ml dung dch HCl 1M. Cng thc phn t ca X l
A. C2H5N
B. CH5N
C. C3H9N
D. C3H7N
Cu 32: Nicotine l mt cht hu c c trong thuc l, gy nghin v mm mng ca bnh ung th. Hp
cht ny c to bi 3 nguyn t C,H,N. em t chy ht 2,349 gam nicotine , thu c nit n cht,
1,827 gam H2O v 3,248 lit ( ktc) kh CO2. CTG ca nicotine l:
A. C3H5N.
B. C3H7N2.
C. C4H9N.
D. C5H7N.

Cu 33: Cho
- aminoaxit mch thng X c cng thc H2NR(COOH)2 tc dng va vi 100 ml dung
dch NaOH 1M, thu c 9,55 gam mui. Tn gi ca X l:
A. Axit 2- aminopropanioic.
B. Axit 2- aminobutanioic.
C. Axit 2- aminopentanioic.
D. Axit 2- aminohexanioic.
Cu 34: Hn hp A gm hai aminoaxit no, mch h, ng ng k tip, c cha mt nhm amino v mt
nhm chc axit trong phn t. Ly 47,8 gam hn hp A cho tc dng vi 200 ml dung dch HCl 3,5 M (c
d), c dung dch B. tc dng ht cc cht trong dung dch B cn 1300 ml dung dch NaOH 1M. Cng
thc hai cht trong hn hp A l:
A. CH3CH(NH2)COOH ; CH3 CH2CH(NH2)COOH.
B. CH3 CH2CH(NH2)COOH ; CH3 CH2CH2CH(NH2)COOH.
C. CH3 CH2CH2CH(NH2)COOH ; CH3 CH2CH2 CH2CH(NH2)COOH.
D. H2NCH2COOH ; CH3CH(NH2)COOH.
Cu 35: Keo dn ure fomanehit c tng hp theo s :
H2NCONH2 + HCHO t, xt H2NCONH-CH2OH ( - NH CONH CH2 - )n
Bit hiu sut ca c qu trnh trn l 60%. Khi lng dung dch HCHO 80% cn dng tng hp c
180 gam keo dn trn l:
A. 156,25 gam.
B.160,42 gam.
C. 128,12 gam.
D. 132,18 gam.
Cu 36: Este X c iu ch t mt aminoaxit v ancol etylic. t chy hon ton 20,6 gam X thu c
16,2 gam H2O, 17,92 lit CO2 v 2,24 lt N2. Cc th tch kh o ktc. T khi hi ca X so vi khng kh gn
bng 3,552. Cng thc cu to thu gn ca X l:
A. H2NCH2COOC2H5.
B. H2N(CH2)2COOC2H5.
C. H2NC(CH3)2COOC2H5.
D. H2NCH(CH3)COOC2H5.
Cu 37: t chy hon ton 8,9 gam mt cht hu c X thu c 13,2 gam CO2 , 6,3 gam H2O v 11,2 lt
kh N2 ( ktc). T khi hi ca X so vi hidro l 44,5. Cng thc phn t ca X l:
A. C3H5O2N.
B. C3H7O2N.
C. C2H5O2N2.
D. C3H9ON2.
Cu 38: t chy hon ton 2 amin no, n chc, mch h, ng ng lin tip thu c CO2 v H2O theo
t l mol tng ng l 1 : 2. Cng thc phn t ca 2 amin l:
A. CH5N v C2H7N.
B. C2H7N v C3H9N.
C. C3H9N v C4H11N.
D. C4H11N v C5H13N.
Cu 39: t chy hon ton m gam aminoaxit X cha 1 nhm - NH2 v 1 nhm COOH thu c 6,72 lt
CO2 , 1,12 lt N2 v 4,5 gam H2O. Cc th tch kh o ktc. Gi tr ca m l:
0

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26

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------A. 17,4.
B. 15,2.
C. 8,7.
D. 9,4.

Cu 40: X l mt
- aminoaxit ch cha 1 nhm NH2 v 1 nhm COOH. Cho 1,72 gam X phn ng va
vi HCl to ra 2,51 gam mui. Cng thc cu to ca X l:
A. CH2 = C(NH2) COOH.
B. CH3 CH(NH2) COOH .
C. H2N CH = CH COOH .
D. H2N CH2 CH2 COOH .
Cu 41: Mt mui X c cng thc phn t C3H10O3N2. Cho 14,64 gam X phn ng ht vi 150 ml dung dch
KOH 1M. C cn dung dch sau phn ng c cht rn v phn hi. Trong phn hi c mt cht c Y bc
1, trong phn rn ch l hn hp ca cc hp cht v c. Cht rn c khi lng l:
A. 14,8 gam.
B. 14,5 gam.
C. 13,8 gam.
D. 13,5 gam.
Cu 42: Cht hu c X c 1 nhm amino, 1 chc este. Hm lng nit trong X l 15,73%. X phng ha m
gam cht X, hi ancol bay ra cho i qua CuO nung nng c anehit Y. Cho Y thc hin phn ng trng
bc thy c 16,2 gam Ag kt ta. Gi tr ca m l:
A. 3,3375 gam.
B. 6,6750 gam.
C. 7,6455 gam.
D. 8,7450 gam.
Tuyn sinh i hc KB 2010:
Cu 43: t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va , thu c 0,5 mol hn
hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl (d), s mol HCl phn ng l
A. 0,3.
B. 0,1.
C. 0,4.
D. 0,2.
Cu 44: Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1
mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe
v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l
A. Gly-Phe-Gly-Ala-Val.
B. Gly-Ala-Val-Phe-Gly.
C. Gly-Ala-Val-Val-Phe.
D. Val-Phe-Gly-Ala-Gly.
Cu 45: Trung ho hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng
axit HCl, to ra 17,64 gam mui. Amin c cng thc l
A. CH3CH2CH2NH2.
B. H2NCH2CH2CH2NH2.
C. H2NCH2CH2NH2.
D. H2NCH2CH2CH2CH2NH2.
Cu 46: ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h,
trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c
tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho
li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l
A. 120.
B. 45.
C. 30.
D. 60.
Cu 47: Hai hp cht hu c X v Y c cng cng thc phn t l C3H7NO2, u l cht rn iu
kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng
ngng. Cc cht X v Y ln lt l
A. axit 2-aminopropionic v axit 3-aminopropionic.
B. axit 2-aminopropionic v amoni acrylat.
C. vinylamoni fomat v amoni acrylat.
D. amoni acrylat v axit 2-aminopropionic.
Cu 48: Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch
NaOH (d), thu c dung dch Y cha (m+30,8) gam mui. Mt khc, nu cho m gam X tc dng
hon ton vi dung dch HCl, thu c dung dch Z cha (m+36,5) gam mui. Gi tr ca m l
A. 171,0.
B. 165,6.
C. 123,8.
D. 112,2.
Tuyn sinh i hc KA 2010:
Cu 49: Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch
X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l
A. 0,70.
B. 0,50.
C. 0,65.
D. 0,55.
Cu 50: Hn hp kh X gm imetylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml
hn hp X bng mt lng oxi va , thu c 550 ml hn hp Y gm kh v hi nc. Nu cho Y i qua

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27

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------dung dch axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o cng iu kin). Cng
thc phn t ca hai hirocacbon l
A. CH4 v C2H6.
B. C2H4 v C3H6.
C. C2H6 v C3H8.
D. C3H6 v C4H8.

CHNG IV: POLIME V VT LIU POLIME


A. TM TT L THUYT:
I. POLIME:
1.Khi nim: Poli me hay hp cht cao phn t l nhng hp cht c PTK ln do nhiu n
v c s gi l mt xch lin kt vi nhau to nn.
V d: ( - CH2 CH = CH CH2 - )n. vi n: h s polime ha ( polime ha).
2. Tnh cht ha hc: C phn ng ct mch ; gi nguyn mch; tng mch.
3. iu ch:
- Phn ng trng hp: l qu trnh kt hp nhiu phn t nh ( monome) ging nhau hay
tng t nhau thnh phn t ln (polime).
c im cu to ca monome tham gia phn ng trng hp l phi c lin kt bi hoc
vng.
- Phn ng trng ngng: l qu trnh kt hp nhiu phn t nh (monome) thnh phn t
ln (polime) ng thi gii phng nhng phn t nh khc ( v d H 2O).
c im cu to ca monome tham gia phn ng trng ngng l phi c t hai nhm chc
(c th ging nhau hoc khc nhau) tr ln.
II. VT LIU POLIME:
1. Cht do l nhng vt liu polime c tnh do.
Vt liu compozit gm: Polime do (thnh phn c bn), cht ha do, cht n, cht ph.
V d:
XT ,t 0

1/ polietilen (PE): n CH2 = CH2 ( - CH2 CH2 - )n.


XT ,t
2/ Polivinyl clorua ( PVC ): n CH2 = CH
( - CH2 CH - )n.
|
|
Cl
Cl
3/ Polimetyl metacrylat:
CH3
CH3
|
|
XT ,t
n CH2 = C
( - CH2 C ) n
|
|
COOCH3
COOCH3
4/ Nha phenolfomanehit ( PPF ).
C 3 dng: novolac; rezol;rezit.
0

2.T l nhng polime hnh si di v mnh vi bn nht nh.


C hai loi t: T thin nhin ( c sn trong thin nhin nh t tm, len, bng) v t ha hc (t nhn to v
t tng hp).
T nhn to c sn xut t polime thin nhin nhng c ch bin thm bng con ng ha hc, v
d: t visco, t axetat, t ng ammoniac.
T tng hp c sn xut t nhng polime tng hp, v d: t poliamit, t polieste
T nilon 6,6: n H2N-(CH2)6 NH2 + n HCOOC (CH2)4 COOH XT,t
( - HN (CH2)6 NH C (CH2)4 C - )n + 2n H2O.
||
||
O
O
T nilon tng hp: n CH2 = CH( CN) xt,t ( - CH2 CH(CN) - )n.
0

3.Cao su l loi vt liu polime c tnh n hi.


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28

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------Cao su thin nhin: ( - CH2 C(CH3) = CH CH2 - )n
Cao su tng hp: ( - CH2 CH = CH CH2 - )n.

4. Keo dn l loi vt liu c kh nng kt dnh hai mnh vt liu rn.


VD: Nha v xm, keo dn epoxi v keo dn ure fomanehit.

B. CU HI V BI TP TRC NGHIM 1 ( Dng cho kim tra 45 pht):


1. Polime no sau y c iu ch bng phn ng trng hp?
A. Poli vinyl clorua.
B. Poli saccarit.
C. Protein.
D. Nilon 6;6.
2. Poli ( metyl metacrylat) v nilon 6 c to thnh t cc monome tng ng l:
A. CH3 COO CH = CH2 v H2N (CH2)5 COOH.
B. CH2 = C(CH3) COOCH3 v H2N (CH2)6 COOH.
C. CH2 = C(CH3) COOCH3 v H2N (CH2)5 COOH.
D. CH2 = CH COOCH3 v H2N (CH2)6 COOH.
( Trch TSH A 2009 )
3. Pht biu no sau y l ng?
A. T visco l t tng hp.
B. Trng ngng buta 1,3 ien vi acrilonitrin c xc tc Na c cao su buna N.
C. Trng hp stiren thu c poli(phenol fomanehit).
D. Poli(etylen terephtalat) c iu ch bng phn ng trng ngng cc monome tng ng.
( Trch TSH B 2009 )
4. Dy gm cc cht u c kh nng tham gia phn ng trng hp l:
A. stiren; clobenzen; isoprene; but 1 en.
B. 1,2 iclopropan; vinylaxetilen; vinylbenzen; toluen.
C. buta 1,3 ien; cumen; etilen; trans but 2 en.
D. 1,1,2,2 tetrafloeten; propilen; stiren; vinyl clorua.
( Trch TSH B 2009 )
5. Polime khng c nhit nng chy c nh v
A. c ln tp cht.
B. c lin kt cng ha tr khng phn cc.
C. l tp hp nhiu loi phn t, c cu to mt xch nh nhau nhng s lng mt xch trong
phn t khc nhau.
D. c khi lng phn t rt ln v cu trc phn t phc tp.
6. T nilon thuc loi:
A. t nhn to.
B. t thin nhin.
C. t polieste.
D. t poliamit.
7. Nhn nh no sau y khng ng?
A. T tm, bng, cao su, tinh bt l polime thin nhin.
B. T capron, t enang, t clorin v nilon -6,6 l t tng hp.
C. T capron, t enang, t clorin v nilon -6,6 b phn hy trong c mi trng axit v baz.
D. Cht do l vt liu b bin dng di tc dng ca nhit , p sut v gi nguyn s bin
dng y khi thi tc dng.
8. Cht no di y khng tham gia phn ng trng hp?
A. axetilen.
B. isopren.
C. stiren.
D. xilen.
9. Nhn nh ng l:
A. Cao su l polime thin nhin ca isoprene.
B. Si xenluloz c th b epolime ha khi b un nng.
C. Monome l mt xch c bn trong phn t polime.
D. Polime l nhng hp cht c phn t khi rt ln, do nhiu n v nh (mt xch) lin kt vi
nhau to nn.
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29

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------10. T nilon -6,6 ging nh cc loi t thuc loi poliamit khc, c s dng rng ri trong nhiu
lnh vc ca i sng v chng c c tnh bn
A. v mt c hc.
B. trong axit.
C. trong kim.
D. v nhit.
11. Cht khng c kh nng tham gia phn ng trng ngng l:
A. glyxin.
B. axit terephtalic.
C. axit axetic.
D. etylen glycol.
12. Nha phenol fomanehit c tng hp bng phng php un nng phenol vi:
A. CH3COOH trong mi trng axit.
B. HCHO trong mi trng axit.
C. HCOOH trong mi trng axit.
D. CH3CHO trong mi trng axit.
13. Polime c cu trc mng khng gian ( mng li) l:
A. nha baketit.
B. amilopectin.
C. PVC.
D. PE.
( Trch TSH B 2008 )
14. Trong s cc loi to sau: t tm, t visco, t nilon -6,6, t axetat, t capron, t enang; nhng
loi t thuc loi t nhn to l:
A. t tm v t enang.
B. t visco v t nilon -6,6.
C. t nilon -6,6 v t capron.
D. t visco v t axetat.
( Trch TSH A 2007 )
15. Dy gm cc cht c dng tng hp cao su Buna S l:
A. CH2 = C(CH3) CH = CH2 , C6H5CH = CH2.B. CH2 =CH CH = CH2 , C6H5 CH = CH2.
C. CH2 = CH CH = CH2 , lu hunh.
D. CH2 = CH CH = CH2 , CH3 CH = CH2.
( Trch TSH B 2007 )
16. Poli (vinyl axetat) l polime c iu ch bng phn ng trng hp:
A. C2H5COO CH = CH2.
B. CH2 = CH COO C2H5.
C. CH3COO CH = CH2.
D. CH2 = CH COO CH3.
( Trch TSH A 2007 )
17. Polime dng ch to thy tinh hu c (Plexiglas) c iu ch bng phn ng trng hp:
A. CH2 = C (CH3)COOCH3.
B. CH2 = CHCOOCH3.
C. C6H5CH = CH2.
D. CH3COOCH = CH2.
( Trch TSH A 2007 )
18. Cho s chuyn ha: CH4 C2H2 C2H3 Cl PVC. tng hp 250 kg PVC theo s
trn th cn V m3 kh thin nhin ( ktc). Gi tr ca V ( bit CH 4 chim 80% th tch kh thin
nhin v hiu sut ca c qu trnh l 50%)
A. 358,4.
B. 448,0.
C. 286,7.
D. 224.0.
( Trch TSH A 2008 )
19. Clo ha PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh mt phn t clo
phn ng vi k mt xch trong mch PVC. Gi tr ca k l:
A. 3.
B.4.
B. 5.
D. 6.
( Trch TSH A 2007 ).
20. Mt on mch polime c khi lng l 8,4 mg. S mt xch etilen ( - CH 2 - CH2 - ) c trong
on mch l:
A. 1,626.1023.
B. 1,807.1023.
C. 1,626.1020 .
D. 1,807.1020 .
21. Khi trng ngng phenol (C6H5OH) vi metanal (HCHO) d trong mi trng kim, to ra polime
c cu trc:
A. Dng mch khng phn nhnh

B. Dng mch khng gian

C. Dng mch phn nhnh

D. Dng mch thng

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30

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------22. Khi lng ca mt on mch t nilon-6,6 l 27346 u v ca mt on mch t capron l
17176 u. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l
A. 113 v 152

B. 113 v 114

C. 121 v 152

D. 121 v 114

23. Mt loi polime c cu to khng phn nhnh nh sau


-CH2-CH2 -CH2-CH2 -CH2-CH2 -CH2-CH2-CH2- CH2 Cng thc mt mt xch ca polime ny l
A. -CH2-

B. -CH2-CH2-CH2-

C. - CH2-CH2-

D. -CH2-CH2-CH2-CH2-

24. Trong s cc polime sau: t nhn, xenluloz, si capron, nha phenol-fomanehit, poliisopren,
len lng cu, poli (vinyl axetat). S cht khng bn, b ct mch polime khi tip xc vi dung dch
kim l
A. 3

B. 4

C. 5

D. 2

25. Trong cc polime c cng s mt xch sau y, polime no c khi lng phn t ln nht?
A. Poli (vinyl axetat)

B. T capron

C. Thu tinh hu c

D. Polistiren

CU HI V BI TP TRC NGHIM T GII 2 ( Dng cho kim tra 90 pht):


Cu 1: Polivinyl clorua c cng thc l
A. (-CH2-CHCl-)2.
B. (-CH2-CH2-)n.
C. (-CH2-CHBr-)n.
D. (-CH2-CHF-)n.
Cu 2: Cht khng c kh nng tham gia phn ng trng hp l
A. stiren.
B. isopren.
C. propen.
D. toluen.
Cu 3: Cht c kh nng tham gia phn ng trng hp l
A. propan.
B. propen.
C. etan.
D. toluen.
Cu 4: Qu trnh nhiu phn t nh (monome) kt hp vi nhau thnh phn t ln (polime) ng thi gii
phng nhng phn t nc gi l phn ng
A. nhit phn.
B. trao i.
C. trng hp.
D. trng ngng.
Cu 5: Trong cc Polime: PVC, PE, amilopectin trong tinh bt, cao su lu ho. S polime c cu trc mng
khng gian l
A. 1

B. 2

C. 3

D. 4

Cu 6: Tn gi ca polime c cng thc (-CH2-CH2-)n l


A. polivinyl clorua.
B. polietilen.
C. polimetyl metacrylat. D. polistiren.
Cu 7: T monome nao sau y co th iu ch c poli(vinyl ancol)?
A. CH2=CH-COOCH3. B. CH2=CH-OCOCH3.
C. CH2=CH-COOC2H5. D. CH2=CH-CH2OH.
Cu 8: Cht tham gia phn ng trng hp to ra polime l
A. CH3-CH2-Cl.
B. CH3-CH3.
C. CH2=CH-CH3.
D. CH3-CH2-CH3.
Cu 9: Monome c dng iu ch polietilen l
A. CH2=CH-CH3.
B. CH2=CH2.
C. CHCH.
D. CH2=CH-CH=CH2.
Cu 10: Dy gm cc cht c dng tng hp cao su Buna-S l:
A. CH2=C(CH3)-CH=CH2, C6H5CH=CH2.
B. CH2=CH-CH=CH2, C6H5CH=CH2.
C. CH2=CH-CH=CH2, lu hunh.
D. CH2=CH-CH=CH2, CH3-CH=CH2.
Cu 11: Cho cc polime sau: (-CH2 CH2-)n ; (- CH2- CH=CH- CH2-)n ; (- NH-CH2 -CO-)n
Cng thc ca cc monome khi trng hp hoc trng ngng to ra cc polime trn ln lt l
A. CH2=CHCl, CH3-CH=CH-CH3, CH3- CH(NH2)- COOH.
B. CH2=CH2, CH2=CH-CH= CH2, NH2- CH2- COOH.
C. CH2=CH2, CH3- CH=C= CH2, NH2- CH2- COOH.

==================
TI LIU N THI 2011.

31

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------D. CH2=CH2, CH3- CH=CH-CH3, NH2- CH2- CH2- COOH.
Cu 12: Cho dy cc cht: CH 2=CHCl, CH2=CH2, CH2=CH-CH=CH2, H2NCH2COOH. S cht trong dy c
kh nng tham gia phn ng trng hp l
A. 1.
B. 4
C. 3
D. 2
Cu 13: Polime c iu ch bng phn ng trng ngng l
A. nilon-6,6.
B. poli(metyl metacrylat).
C. poli(vinyl clorua).
D. polietilen.
Cu 14: T no sau y thuc loi t bn tng hp (t nhn to)?
A. Bng.
B. T visco.
C. T nilon-6,6.
D. T tm.
Cu 15: Cho cc cht stiren(I), vinyl axetilen(II), buta-1,3-ien(III), 2-phenyletan-1-ol(IV). Hai
cht c th dng iu ch cao su Buna-S bng 3 phn ng l
A. (I) v (III).
B. (I) v (II).
C. (III) v (IV).
D. (II) v (IV).
Cu 16: Trong s cc cht: etylen, axetilen, stiren, buta-1,3-ien, caprolactam,

metyletilenoxit, s cht c tham gia phn ng trng hp l:


A.3 cht
B.4 cht
C.5 cht

D.6 cht

Cu 17: un nng dung dch fomalin vi phenol (d) c axit lm xc tc thu dc polime c cu
trc:
A. Mch thng.
B. Dng phn nhnh.
C. Mng li khng gian.
D. Cc phng n u sai.
Cu 18: Cho bin ha sau: Xenluloz A B C Caosubuna. A, B, C l nhng cht no ?
A. CH3COOH,C2H5OH, CH3CHO.
B. C6H12O6(glucoz), C2H5OH, CH2=CH CH=CH2
C. C6H12O6(glucoz), CH3COOH, HCOOH
D. CH3CHO, CH3COOH, C2H5OH.
Cu 19: X l hp cht thm c CTPT C8H10O. ng phn no ca X tha mn dy bin ha sau:
X H 2O X trunghop
polime.
A. C6H5CH2CH2OH
B. C6H5CH(OH)CH3
C. CH3C6H4CH2OH
D. C6H5CH2CH2OH v C6H5CH(OH)CH3
Cu 20: Cho dy chuyn ha :

Tinh bt

+H2O
H+

A men r u

ZnO, MgO
500 0C

t,p,xt

E l cht no trong cc cht sau ?


A. Cao su buna.
B. butaien-1,3 (buta-1,3-ien)
C. axit axetic
D. polietilen
Cu 21: Polime no sau y l nguyn liu sn xut t visco ?
A. xenluloz
B. caprolactam.
C. axit terephtalic v etilenglicol.
D. vinyl axetat
Cu 22: Polime no trong s polime sau khng b thy phn trong mi trng kim ?
A. cao su buna.
B. t enan.
C. t nilon-6,6
D. poli(vinyl axetat).
Cu 23: Phenol khng phi l nguyn liu iu ch :
A. thy tinh hu c.
B. nha bakelit.
C. 2,4-D v 2,4,5-T.
D. axit picric.
Cu 24: Polime c dng ch to thu tinh hu c (plexiglas) l
A. poli ( metyl acrylat).
B. poli( metyl metacrylat).
C. poli (phenol fomanehit).
D. poli (metyl axetat).
Cu 25:T khng thuc loi t poliamit l t
A. nilon-6,6.
B. tm.
C. nilon-7.
D. nitron.
Cu 26: T lapsan thuc loi t:
A. poliamit.
B. polieste.
C. poliete.
D. vinylic.
Cu 27: Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt on mch t capron l
17176 vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l
A. 113 v 152.

==================
TI LIU N THI 2011.

B. 121 v 114.

C. 121 v 152.

D. 113 v 114.

32

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------Cu 28: Khi clo ha PVC, tnh trung bnh c k mt xch trong mch PVC phn ng vi mt phn t clo. Sau
khi clo ha, thu c mt polime cha 63,96% clo v khi lng. Gi tr ca k l
A. 3
B. 4
C. 5
D. 6
Cu 29: Trong s cc polime:t tm, si bng, len, t enang, t visco, nilon-6,6, t axetat, loi t c ngun
gc xenluloz l
A. T tm, si bng,nilon-6,6
B. Si bng, len, nilon-6,6
C. T visco, nilon-6,6, t axetat
D. Si bng, t axetat, t visco
Cu 30: T nilon 6,6 c cng thc l

A.

NH[CH2]5CO n .

B.

NH[CH2]6CO n .

C.

NH[CH2]6NHCO[CH2]4CO n .

D.

NHCH(CH3)CO n .

Cu 31: Nhm vt liu uc ch to t polime thin nhin:


A. T visco
B. t tm.
C. t enang.
D. nha lm phim nh.
Cu 32: Gii trng hp polime
(CH2CH(CH3)CH(C6H5)CH2 )n ta s c monome no sau y ?
A. 2-metyl3phenylbut-2-en

B. 2metyl3phenylbutan

C. Propilen v stiren

D. Isopren v toluen

Cu 33: git o bng len lng cu cn dng loi x phng c tnh cht no sau y ?
A. X phng c tnh baz

B. X phng c tnh axit

C. X phng trung tnh

D. Loi no cng c

Cu 34: Hai cht no di y tham gia phn ng trng ngng vi nhau to t nilon- 6,6
A. Axit aipic v etylen glicol

B. Axit picric v hexametyleniamin

C. Axit aipic v hexametyleniamin

D. Axit glutamic v hexaetyleniamin

Cu 35: Polime no sau y c tn gi "t nilon" hay "olon" c dng dt may qun o m?
A. Poli(metylmetacrylat)

B. Poliacrilonitrin

C. Poli(vinylclorua)

D. Poli(phenol-fomanehit)

Cu 36: H s trng hp ca loi polietilen c khi lng phn t l 4984 vC v ca polisaccarit (C 6H10O5)n
c khi lng phn t 162000 vC ln lt l:
A. 178 v 1000
B. 278 v 1000
C. 178 v 2000
D. 187 v 100
Cu 37: em trng hp 10,8 gam buta-1,3-ien thu c sn phm gm caosu buna v buta-1,3-ien d.
Ly 1/2 sn phm tc dng hon ton vi dung dch Br 2 d thy 19,2 g Br2 phn ng.Vy hiu sut phn
ng l
A. 40%

B. 80%

C.60%

D.79%

Cu 38: Tin hnh phn ng trng hp 5,2 gam stiren, sau phn ng ta thm 400 ml dung dch nc brom
0,125M, khuy u cho phn ng hon ton thy d 0,04 mol Br2. Khi lng polime sinh ra l
A. 4,16 gam.

B. 5,20 gam.

C. 1,02 gam.

D. 2,08 gam.

Cu 39: Polime c trng hp t etilen. Hi 280g polietilen c trng hp t ti thiu bao nhiu phn
t etilen?
A. 3,01.1024

==================
TI LIU N THI 2011.

B. 6,02.1024

C. 6,02.1023

D. 10

33

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------Cu 40: t chy hon ton mt lng polietilen, sn phm chy cho i qua bnh ng dung dch Ca(OH) 2
d thy xut hin 10 gam kt ta. Khi lng bnh thay i nh th no?
A. Tng 4,4g

B. Tng 6,2g

C. Gim 3,8g

D. Gim 5,6g

Cu 41: Sn phm trng hp ca buta-1,3-ien vi CH2=CH-CN c tn gi thng thng:


A. Cao su

B. Cao su buna

C. Cao su buna N

D. Cao su buna S

Cu 42: Dng poli(vinylaxetat) c th lm c vt liu no sau y?


A. Cht do

B. Polime

C. T

D. Cao su

Cu 43: Khi t chy polime X ch thu c kh CO2 v hi nc vi t l s mol tng ng l 1 : 1. X l


polime no di y ?
A. Polipropilen

B. Tinh bt

C. Polistiren (PS)

D. Polivinyl clorua (PVC)

Cu 44: Cho sn phm khi trng hp 1 mol etilen iu kin thch hp tc dng va 16g Brom. Hiu
sut phn ng trng hp v khi lng PE thu c l
A. 80%; 22,4 g

B. 90%; 25,2 g

C. 20%; 25,2 g

D. 10%; 28 g

Cu 45: PVC c iu ch t kh thin nhin theo s sau:


CH4 C2H2 CH2 = CHCl PVC.
Nu hiu sut ton b qu trnh iu ch l 20% th th tch kh thin nhin (ktc) cn ly iu ch 1 tn
PVC l (xem kh thin nhin cha 100% metan v th tch):
A. 1792 m3.

B. 2915 m3.

C. 3584 m3.

D. 896 m3.

Cu 46: Polime X trong phn t ch cha C, H v c th c O. H s trng hp ca phn t X l 1800, phn


t khi l 122400. X l
A. Cao su isopren

B. PE (polietilen)

C. PVA (poli(vinyl axetat))

D. PVC (poli (vinyl clorua))

Cu 47: Cc cht u khng b thu phn trong dung dch H2SO4 long nng l:
A. t capron; nilon-6,6; polietilen.
B. nilon-6,6; poli(etylen-terephtalat); polistiren.
C. poli(vinyl axetat); polietilen; cao su buna.
D. polietilen; cao su buna; polistiren.
Cu 48: Cho cc loi t: bng, t capron, t xenluloz axetat, t tm, t nitron, nilon-6,6. S t tng hp l
A. 5.
B. 2.
C. 3.
D. 4.

( Trch TSH A 2010 )


Cu 49: Trong cc polime sau: (1) poli(metyl metacrylat); (2) polistiren; (3) nilon-7; (4) poli(etylenterephtalat); (5) nilon-6,6; (6) poli(vinyl axetat), cc polime l sn phm ca phn ng trng ngng l:
A. (1), (3), (6).
B. (1), (2), (3).
C. (1), (3), (5).
D. (3), (4), (5).

( Trch TSH A 2010 )


Cu 50: Cho s chuyn ha sau
H , t , Pd , PbCO
Z , ( t , xt , p )
C2H2 xt,t X +

Cao su buna N
Y +
Cc cht X, Y, Z ln lt l:
0

==================
TI LIU N THI 2011.

34

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------A. benzen; xiclohexan; amoniac.
C. vilynaxetilen; buta-1,3-ien; stiren.

B. axetanehit; ancol etylic; buta-1,3-ien.


D. vilynaxetilen; buta-1,3-ien; acrilonitrin

( Trch TSH B 2010 )

CU HI V BI TP TRC NGHIM 3:
4.1. Khi nim ng v polime l
A. Polime l hp cht c to thnh t cc phn t ln
B Polime l hp cht c to thnh t cc phn t c phn t khi nh hn
C. Polime l sn phm duy nht ca phn trng hp hoc trng ngng
D. Polime l hp cht cao phn t gm n mt xch to thnh
4.2. Trong cc cht sau y cht no khng phi l polime
A. Tri stearat glixerol

B. Nha bakelit

C. Cao su

D. Tinh bt

4.3. Cht no di y khng th tham gia phn ng trng hp


A. Propilen

B. Stiren

C. Propin

D. Toluen

4.4. Sn phm ( C2H4-O-CO-C6H4-CO )n c to thnh t phn ng no sau y


A. C2H5OH

HOOC-C6H4-COOH

B. C2H5-COOH

C. CH2=CH-COOH
D. HO-C2H4-OH

HO-C6H4-OH
+

HOOC-C6H4-COOH

HOOC-C6H4-COOH

4.5. Cht c cng thc cu to sau c to thnh t phn ng

( CH2 - CH=CH-CH2-CH2-CH )n
CH

A. CH3-CH=CH-CH3 v CH2=CH-C66H55

B. CH2=CH2 v CH2=CH-CH2-CH2-C6H5

C. CH2=CH-CH3 v CH2=CH-CH2-C6H5

D. CH2=CH-CH=CH2 v CH2=CH-C6H5

4.6. T nilon-6 thuc loi t thuc loi t no sau y


A. T nhn to

B. T t nhin

C. T poliamit

D. T polieste

C. T nhn to

D. T poliamit

4.7. Xenluloz triaxetat c xem l


A. Cht do

B. T tng hp

4.8. Khi lng ca mt on mch t nilon-6,6 l 27346 u v ca mt on mch t capron l 17176 u. S


lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l
A. 113 v 152

B. 113 v 114

C. 121 v 152

D. 121 v 114

4.9. Da vo ngun gc, si dng trong cng nghip dt, c chia thnh
A. Si ho hc v si tng hp

B. Si ho hc v si t nhin

C. Si tng hp v si t nhin

D. Si t nhin v si nhn to

4.10. T 15kg metyl metacrylat c th iu ch c bao nhiu gam thu tinh hu c c hiu sut 90%?

==================
TI LIU N THI 2011.

35

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------A. 13500n (kg)

B. 13500 g

C. 150n (kg)

D. 13,5 (kg)

4.11. Khi t chy polime X ch thu c kh CO2 v hi nc vi t l s mol tng ng l 1 : 1. X l polime


no di y ?
A. Polipropilen

B. Tinh bt

C. Polivinyl clorua (PVC)

D. Polistiren (PS)

4.12. Polime c trng hp t etilen. Hi 280g polietilen c trng hp t ti thiu bao nhiu phn t
etilen?
A. 3,01.1024

B. 6,02.1024

C. 6,02.1023

D. 10

4.13. t chy hon ton mt lng polietilen, sn phm chy cho i qua bnh ng dung dch Ca(OH) 2 d
thy xut hin 10 gam kt ta. Khi lng bnh thay i nh th no?
A. Tng 4,4g

B. Tng 6,2g

C. Gim 3,8g

D. Gim 5,6g

4.14. Cho sn phm khi trng hp 1 mol etilen iu kin thch hp tc dng va 16g Brom. Hiu sut
phn ng trng hp v khi lng PE thu c l
A. 80%; 22,4 g

B. 90%; 25,2 g

C. 20%; 25,2 g

D. 10%; 28 g

4.15. Tin hnh phn ng trng hp 5,2 gam stiren, sau phn ng ta thm 400 ml dung dch nc brom
0,125M, khuy u cho phn ng hon ton thy d 0,04 mol Br2. Khi lng polime sinh ra l
A. 4,16 gam.

B. 5,20 gam.

C. 1,02 gam.

D. 2,08 gam.

4.16. Mt loi polime c cu to khng phn nhnh nh sau


-CH2-CH2 -CH2-CH2 -CH2-CH2 -CH2-CH2Cng thc mt mt xch ca polime ny l
A. -CH2-

B. -CH2-CH2-CH2-

C. - CH2-CH2-

D. -CH2-CH2-CH2-CH2-

4.17.Polime X c phn t khi l 280000 v h s trng hp n=10000. Vy X l


A. ( CH2-CH2 )n

B.

( CF2-CF2 )n

C. ( CH2CH(Cl) )n

D. ( CH2-CH(CH3) )n

4.18: Qua nghin cu thc nghim cho thy cao su thin nhin l polime ca monome
A. buta-1,3-ien v stiren

B. 2-metylbuta-1,3-ien

C. buta-1,3-ien

D. buta-1,2-ien

4.19. Ch r monome ca sn phm trng hp c tn gi poli propilen (P.P)


A. ( CH2-CH2 )n

B. CH2=CH-CH3

C. CH2=CH2

D. ( CH2-CH(CH3) )n

4.20: C 2,62g cao su buna-S phn ng va ht vi 1,6 gam brom trong CCl 4. Hi t l s mt xch butaien
v stiren trong cao su buna-S l bao nhiu ?
A. 2/3

B. 1/3

C.

D. 3/5

4.21. Sn phm trng hp ca buta-1,3-ien vi CH2=CH-CN c tn gi thng thng:


A. Cao su

B. Cao su buna

C. Cao su buna N

D. Cao su buna S

4.22. Gii trng hp polime ( CH2CH(CH3)CH(C6H5)CH2 )n ta s c monome no sau y ?


A. 2-metyl3phenylbut-2-en

B. 2metyl3phenylbutan

C. Propilen v stiren

D. Isopren v toluen

==================
TI LIU N THI 2011.

36

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------4.23. Dng poli(vinylaxetat) c th lm c vt liu no sau y?
A. Cht do

B. Polime

C. T

D. Cao su

4.24. Nhn xt v tnh cht vt l chung ca polime no di y khng ng ?


A. Hu ht l nhng cht rn, khng bay hi
B. Hu ht polime u ng thi c tnh do, tnh n hi v c th ko thnh si dai, bn.
C. a s nng chy mt khong nhit rng, hoc khng nng chy m b phn hu khi un nng
D. a s khng tan trong cc dung mi thng thng, mt s tan trong dung mi thch hp to dung dch
nht
4.25. Hai cht no di y tham gia phn ng trng ngng vi nhau to t nilon- 6,6
A. Axit aipic v etylen glicol

B. Axit picric v hexametyleniamin

C. Axit aipic v hexametyleniamin

D. Axit glutamic v hexaetyleniamin

4.26. Polime no sau y c tn gi "t nilon" hay "olon" c dng dt may qun o m?
A. Poli(metylmetacrylat)

B. Poliacrilonitrin

C. Poli(vinylclorua)

D. Poli(phenol-fomanehit)

4.27. Poli(vinyl axetat) l polime c iu ch t sn phm trng hp monome no sau y:


A. CH2=CH-COOCH3

B. CH2=CH-COOH

C. CH2=CH-COOC2H5

D. CH2=CH-OCOCH3

4.28: Trong s cc polime tng hp sau y: nha PVC (1), caosu isopren (2), nha bakelit (3), thu tinh
hu c (4), t nilon-6,6 (5). Cc polime l sn phm trng ngng gm:
A. (1) v (5).

B. (1) v (2)

C. (3) v (4)

D. (3) v (5).

4.29. git o bng len lng cu cn dng loi x phng c tnh cht no sau y ?
A. X phng c tnh baz B. X phng c tnh axit C. X phng trung tnh

D. Loi no cng c

4.30. Khi un nng, cc phn t alanin (axit -aminopropionic) c th to sn phm no sau y:


A. [ HN-CH2-CO ]n

B. [ HN-CH(NH2)CO ]n

C. [ HN-CH(CH3)-CO ]n

D. [ HN-CH(COOH)-CH2 ]n

4.31. Trong s cc polime sau: (1) t tm, (2) si bng, (3) si len, (4) t enang, (5) t visco, (6) t nilon,
(7) t axetat. Loi t no c cng ngun gc xenluloz?
A. (1), (2), (6)

B. (2), (3), (7)

C. (2), (5), (7)

D. (5), (6), (7)

4.32. Khi trng ngng phenol (C6H5OH) vi metanal (HCHO) d trong mi trng kim, to ra polime c cu
trc:
A. Dng mch khng phn nhnh

B. Dng mch khng gian

C. Dng mch phn nhnh

D. Dng mch thng

4.33. Trong mi trng axit v mi trng kim, cc polime trong dy sau u km bn:
A. T nilon- 6,6, t capron, t tm

B. Si bng, t capron, t nilon -6,6

C. Polistiren, polietilen, t tm

D. Nha phenol-fomaehit, poli(vinyl clorua), t capron

==================
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37

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------4.34. Poli (etyl acrylat) c iu ch bng cch trng hp monome no sau y
A. CH2=CHCOOCH2CH3.

B. CH2=CHOOCCH3.

C. CH3COOCH=CHCH3.

D. CH2=CH-CH2OOCH

4.35. Dy gm cc polime c dng lm t si l


A. Tinh bt, xenluloz, nilon-6,6

B. Xenluloz axetat, poli(vinyl xianua), nilon-6,6

C. PE, PVC, polistiren

D. Xenluloz, protein, nilon-6,6

4.36. Ti nilon dng trong sinh hot thng ngy c cu to ch yu t polime:


A. Nilon-6

B. Nilon-7

C. Polietilen (PE)

D. Poli(vinyl clorua) (PVC)

4.37. Polime l cc phn t rt ln hnh thnh do s trng hp cc monome. Nu propen CH 2=CHCH3 l


monome th cng thc ca polime tng ng c biu din l
A. ( CH2CH2 )n

B. ( CH2CH2CH2 )n

C. ( CH2CH(CH3) )n

D. ( CH2(=CH2) CH2 )n

4.38: iu no sau y khng ng?


A. T tm, bng, len l polime thin nhin.
B. T visco, t axetat l t tng hp.
C. Cht do l nhng vt liu b bin dng di tc dng ca nhit v p sut m vn gi nguyn bin
dng khi thi tc dng.
D. Nilon-6,6 v t capron l poliamit
4.39. Thu tinh hu c l sn phm trng hp ca monome:
A. Etyl acrylat

B. Metyl acrylat

C. Metyl metacrylat

D. Etyl metacrylat

4.40. Trong cc Polime: PVC, PE, amilopectin trong tinh bt, cao su lu ho. S polime c cu trc mng
khng gian l
A. 1

B. 2

C. 3

D. 4

4.41. Khi tin hnh ng trng hp buta-1,3-ien v acrilonitrin thu c mt loi cao su buna-N cha
8,69% nit. Tnh t l s mol buta-1,3-ien v acrolonitrin trong cao su
A. 1:2

B. 1:1

C. 2:1

D. 3:1

4.42. Trong cc loi t: t tm, t visco, t xenluloz axetat, t capron, t nilon- 6,6. S t tng hp l
A. 1

B. 2

C. 3

D. 4

4.43. Polime no d b thu phn trong mi trng kim ?


A. ( CH2-CH2 )n

B. ( CH2-CH2-O )n

C. ( HN-CH2-CO )n

D. ( CH2-CH=CH-CH2 )n

4.44. Khi trng hp buta-1,3- ien th thu c ti a bao nhiu loi polime mch h ?
A. 1

B. 2

C. 3

D. 4

4.45. Hy chn cc cht c th trng hp hoc trng ngng thnh polime:


CH3COOH(1), CH2=CH-COOH(2), NH2-R-COOH(3), HCHO(3), C2H4(OH)2(4), C6H5NH2 (5), C6H5OH (6).
A. 2, 3, 4

B. 2, 3, 4, 6

C.1, 2, 3, 4, 5, 6

D. 2, 3, 4, 6

4.46. Phenol khng phi l nguyn liu iu ch

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38

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------A. Nha baketit

B. Axit picric

C. 2,4 - D v 2,4,5 - T

D. Thy tinh hu c

4.47. Hy chn pht biu sai ?


A. Thnh phn chnh ca cao su thin nhin l poliisopren dng ng phn cis.
B. Thnh phn chnh ca cao su thin nhin l poliisopren dng ng phn trans
C. Cao su thin nhin c tnh n hi cao hn cao su Buna.
D. C th ci tin tnh cht c hc ca cao su Buna.
4.48: Mnh no sau y khng ng:
A. H s polime ha cng ln th khi lng polome cng ln
B. Nhiu polime c iu ch bng phn ng trng hp, trng ngng, ng trng hp hay ng trng
ngng.
C. Ty phn ng m mch polilme co th b thay i
D. Ty thuc vo iu kin phn ng m tt c cc cht n chc cng c th trng hp thnh polime
4.49. Cao su thin nhin l polime no sau y:
A. ( CH2-CH=CH-CH2 )n
B. ( CH2-C=CH-CH2 )n
Cl

C. ( CH2-C=CH-CH2 )n
CH3
D. ( CH2CH )n
CH=CH2

4.50: Khi iu ch cao su Buna, ngi ta cn thu c mt sn phm ph l polime c nhnh no sau y?
A. ( CH2 CH CH2 )n

B. ( CH2 CH )n

CH3
C. ( CH2 C = CH2 )n

CH = CH2
D. ( CH2 CH )n

CH3
CH3
4.51. M t khng ng v cu trc mch ca cc polime l
A. PVC (poli (vinyl clorua)) c dng mch thng
B. Amilopectin c dng mch phn nhnh
C. PVA (poli (vinyl axetat)) c dng mch phn nhnh
D. Cao su lu ha c dng mch mng li khng gian
4.52. Nhn xt no sau y ng khi tng hp t capron (nilon-6)
Cch 1. T m gam -aminocaproic vi hiu sut 100%
Cch 2. t m gam caprolactam vi hiu sut 86,26%
A. Khi lng t capron hai cch l nh nhau
B. Khi lng t capron thu cch mt ln hn cch hai
C. Khi lng t capron thu cch hai ln hn cch mt

==================
TI LIU N THI 2011.

39

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------D. Khng th so snh c v phn ng tng hp l khc nhau
4.53. Clo ho PVC c mt loi t clorin cha 63,96% clo. Trung bnh 1 phn t Cl2 tc dng c vi:
A. 2 mt xch PVC

B. 1 mt xch PVC

C. 3 mt xch PVC

D. 4 mt xch PVC

4.54. Polime no sau y l sn phm ca phn ng trng ngng?


(1) tinh bt (C6H10O5)n, (2) cao su (C5H8)n, (3) t tm (NHRCO)n.
A. (1).

B. (3).

C. (1), (2).

D. (1), (3).

4.55. Cho cc phng trnh phn ng sau:


(1) CH2 = C(CH3) CH = CH2 polime.
(2) CH2 = CH CH3 + C6H5 CH = CH2 polime.
(3) H2N (CH2)6 COOH H2O + polime.
(4) C6H5OH + HCHO H2O + polime.
Cc phn ng trn, phn ng no l phn ng trng ngng?
A. (1), (2).

B. (3), (4).

C. (3)

D. (1), (4).

4.56. Polime X trong phn t ch cha C, H v c th c O. H s trng hp ca phn t X l 1800, phn t


khi l 122400. X l
A. Cao su isopren
4.57. Polime

B. PE (polietilen)

C. PVA (poli(vinyl axetat)) D. PVC (poli (vinyl clorua))

( CH2 CH CH2 C = CH - CH2 )n


CH3

CH3

c iu ch bng phn ng trng hp monome:


A. CH2 = CH CH3.

B. CH2 = C CH = CH2.
CH3

C. CH2 = CH CH = CH2.

D. C A v B.

4.58. PVC c iu ch t kh thin nhin theo s sau:


CH4 C2H2 CH2 = CHCl PVC.
Nu hiu sut ton b qu trnh iu ch l 20% th th tch kh thin nhin (ktc) cn ly iu ch 1 tn
PVC l (xem kh thin nhin cha 100% metan v th tch):
A. 1792 m3.

B. 2915 m3.

C. 3584 m3.

D. 896 m3.

4.59. T nilon- 6,6 c iu ch t cht no sau y bng phng php trng ngng:
A. Hexametyleniamin v axit terephtalic.

B. Axit aipic v hexametyleniamin.

C. Axit - aminocaproic.

D. Glixin v alanin.

4.60: Ch ra pht biu sai:


A. T bn tng hp hay t nhn to (xut pht t polime thin nhin nhng c ch bin thm bng
phng php ho hc) nh t visco, t xenluloz, t capron,...
B. T tng hp (ch to t cc loi polime tng hp) nh nilon- 6,6, t lapsan, t nitron,...

==================
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40

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------C. T t nhin (sn c trong t nhin) nh bng, len, t tm.
D. Polime dng sn xut t phi c mch cacbon khng nhnh, xp song song, khng c, c kh nng
nhum mu, mm dai.
4.61. Cao su t nhin l polime ca isopren cn cao su nhn to (cao su Buna) l polime ca buta- 1,3-ien.
Chn pht biu ng trong cc pht biu sau?
(1) Cao su thin nhin c tnh n hi hn cao su Buna.
(2) Cao su thin nhin c cu trc ng u hn cao su Buna.
(3) C th ci tin tnh cht c hc ca cao su Buna.
A. (1)

B. (2)

C. (1), (2), (3)

D. (1), (2)

4.62. Chn pht biu ng:


(1) Polistiren dng mch thng.
(2) Khi trng hp stiren nu c thm mt t ivinylbenzen th sn phm c c cu mng khng gian.
(3) T l ivinylbenzen : stiren cng ln th polime thu c cng cng.
A. (1)

B. (2)

C. (3)

D. (1), (2), (3)

4.63. Chn pht biu sai:


(1) S lu ho cao su thin nhin c c l do trn mch cacbon cn c lin kt i.
(2) C th dng C thay S nhm tng cng ca cao su.
(3) Lng S dng trong phng php lu ha cao su cng cao, cao su cng n hi.
A. (1)

B. (2)

C. (3)

D. (1), (2), (3)

4.64. Hirocacbon X c cng thc phn t C4H6, X c dng iu ch cao su nhn to. X l
A. buta-1,2-ien

B. but-2-in

C. buta-1,3-ien

D. but-1-in

4.65. T clorin c cng thc cu to vn tt l


A. [ CH2CH ]n

B. [ CH2CHCHCH ]n
Cl

Cl

C. [ CH2C=CHCH2 ]n

Cl

Cl

D. [ CH2CH=CHCH2CHCH2 ]n

4.66. Polime c tn l polipropilen c cu to mch nh sau:


- CH2- CH- CH2- CH- CH2- CH- CH2- CH- CH2CH3

CH3

CH3

CH3

Cng thc chung ca polime l


A. ( CH2 )n

B. ( CH2 CH )n
CH3

C. ( CH2CHCH2 )
CH3

D. ( CH2CHCH2CHCH2 )n CH3
CH3

4.67. Phn ng no cho di y l phn ng m mch ca polime b ct ra:


A. Cao su isopren + HCl

==================
TI LIU N THI 2011.

B. PVC + Cl2

t clorin

41

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------C. poli (vinyl axetat) + NaOH d

D. t capron + H2O OH

4.68: Dy polime no sau y khng th trc tip iu ch bng phng php trng hp:
A. Cao su buna, cao su isopren, cao su cloropren, cao su buna-S.
B. PE, PVC, thy tinh hu c, poli stiren, t capron.
C. Nilon-6,6, t axetat, t tm, tinh bt, poli(vinyl ancol)
D. PVA, t capron, cao su buna-N, polipropilen.
4.69. Khng nh no sau y khng ng khi ni v s lu ha cao su?
A. Bn cht qu trnh lu ha cao su l to ra nhng cu ni(-S-S-)
B. Cao su lu ha c cu to mng khng gian
C. Cao su lu ha c nhng tnh cht hn hn cao su th nh bn i vi nhit n hi hn lu mn, kh
tan trong dung mi hu c
D. Nh s lu ha m cao su c nhng tnh cht vt l hn cao su th nh: tnh n hi, tnh do, bn vi
tc ng ca mi trng
4.70: Khi trng hp buta-1,3-ien (xc tc, p, t0) th khng th sinh ra cht no di y?
A. [ CH2CH = CHCH2 ]n

B. [ CH2 - CH ]n

CH = CH2

- CH = CH2

- CH = CH2

C.

D.

4.71. Cao su cloropren c iu ch t monome no sau y:


A. CH2=CCl-CCl=CH2

B. CH2=C(CH2Cl)-CH=CH2

C. CH2=CCl-CH=CH2

D. CH3-CH=CH-CH2Cl

4.72. Trong s cc polime sau: t nhn, xenluloz, si capron, nha phenol-fomanehit, poliisopren, len
lng cu, poli (vinyl axetat). S cht khng bn, b ct mch polime khi tip xc vi dung dch kim l
A. 3

B. 4

C. 5

D. 2

4.73. Trong cc polime c cng s mt xch sau y, polime no c khi lng phn t ln nht?
A. Poli (vinyl axetat)

B. T capron

C. Thu tinh hu c

D. Polistiren

4.74. T xenluloz v cc cht xc tc cn thit c th iu ch c loi t no?


A. T nilon

B. T axetat

C. T capron

D. T enang

4.75. Trong cc polime c cng s mt xch sau y, polime no c khi lng phn t nh nht?
A. Poli (vinyl axetat)

B. T capron

C. Thu tinh hu c

D. Polistiren

4.76. Poli (metyl metacrylat) l sn phm trng hp ca monome:


A. CH2=CHCl.

B. CH2=CHCOOCH3.

C. CH2=C(CH3)COOCH3. D. CH2=C(CH3)COOC2H5.

4.77. Cho s :
(X)

(Y)

poli (vinyl ancol)

Cc cht X,Y trong s trn khng th l

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42

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------A. CH CH, CH2=CHOH.

C. CH3COOCH=CH2, poli (vinylaxetat)

B. CH2=CHCl, Poli (vinylclorua)

D. B v C

4.78: Trong th chin th II ngi ta phi iu ch cao su buna t tinh bt theo s sau:
Tinh bt Glucoz Ancol etylic Buta-1,3-ien Caosu buna
T 10 tn khoai cha 80% tinh bt iu ch c bao nhiu tn caosu buna? (Bit hiu sut ca c qu
trnh l 60%)
A. 3,1 tn

B. 2,0 tn

C. 2,5 tn

D. 1,6 tn

4.79. Nhng polime no sau y c th c iu ch bng phng php trng hp: PVC, Nilon-6,6, t
capron, thy tinh hu c, t axetat, caosu Buna, PE
A. PVC, thy tinh hu c, caosu Buna, PE

B. PVC, t capron, thy tinh hu c, caosu Buna, PE

C. PVC, , t axetat, caosu Buna, PE

D. Nilon-6,6, t capron, t axetat, caosu Buna

4.80. Dy gm cc cht c dng tng hp cao su Buna-S l


A. CH2=CH-CH=CH2, lu hunh

B. CH2=CH-CH=CH2, CH3-CH=CH2

C. CH2=C(CH3)-CH=CH2, C6H5CH=CH2

D. CH2=CH-CH=CH2, C6H5CH=CH2

4.81. Aminoaxit X c cng thc phn t l C3H7NO2. X c th trc tip to ra c bao nhiu kiu lin kt
peptit
A. 2

B. 3

C. 5.

D. 4

4.82. Dy gm cc polime dng lm t si l


A. tinh bt, xeluloz, nilon-6

B. xenluloz diaxetat, poli (vinyl xianua), nilon-6,6

C. PE , PVC, Polistiren

D. xenluloz, protein, nilon-6,6

4.83. em trng hp 10,8 gam buta-1,3-ien thu c sn phm gm caosu buna v buta-1,3-ien d. Ly
1/2 sn phm tc dng hon ton vi dung dch Br2 d thy 10,2 g Br2 phn ng.Vy hiu sut phn ng l
A. 40%

B. 80%

C.60%

D.79%

4.84. Buta-1,3-ien l monome tng hp cao su buna. T nguyn liu no khng th trc tip c
monome ?
A. C2H5OH

B. CH3-CH2-CH2-CH3

C. CH3COONa

D. CH2=CH-COONa

4.85. Nguyn liu trc tip iu ch t lapsan (thuc loi t polieste) l


A. Etilen glicol v axit aipic

B. Axit terephtalic v etilen glicol

C. Axit - aminocaproic

D. Xenluloz trinitrat

4.86. ABS l polime kt hp c cc u im v cng v bn ca cu t nha vinyl vi dai v


sc va p ca thnh phn cao su, c to ra bng phn ng polyme ha qua li gia acrilonitrin (nitrin
acrilic) vi buta-1,3-ien v stiren. Cng thc phn t ca cc monome to ra ABS l
A. C3H3N, C4H6, C8H8

B. C2H3N, C4H6, C8H8

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TI LIU N THI 2011.

C. C2H3N, C4H6, C8H6

D. C3H3N, C4H6, C8H6

43

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------4.87. Cho cc polime sau: ( CH2-CH2 )n, ( CH2-CH=CH-CH2 )n, ( NH-CH2-CO )n. Cng thc ca cc monome
khi trng hp hoc trng ngng to ra cc monome trn ln lt l
A. CH2=CH2, CH2=CH-CH=CH2, H2N-CH2-COOH

B. CH2=CH2, CH3-CH=CH-CH3, H2N-CH2-CH2-COOH

C. CH2=CH2, CH3-CH=C=CH2, H2N-CH2-COOH

D. CH2=CHCl, CH3-CH=CH-CH3, CH3-CH(NH2)-COOH

4.88. Trng hp hon ton vinyl clorua thu c PVC c khi lng phn t 7,525.10 22 u. S mt xch -CH 2CHCl- c trong PVC ni trn l
A. 12,04.1021

B. 12,04.1022

C. 12,04.1020

D. 12,04.1023

C. (1), (2)

D. (1), (3)

4.89. Trong s cc loi t sau


[ NH-(CH2)6-NH-CO-(CH2)4-CO ]n (1)
[ NH-(CH2)5-CO ]n

(2)

[ C6H7O2(OOCCH3)3 ]n

(3)

T thuc loi poliamit l


A. (1), (2), (3)

B. (2), (3)

4.90. Cho cc cht sau: phenylamoniclorua, natri phenolat, vinyl clorua, ancol benzylic, este phenyl benzoat v t
nilon-6,6. Tng s cht tc dng c vi NaOH un nng l
A. 6.

B. 5

C. 4

D. 3

4.91. Trng hp hon ton 16,8 gam etilen thu c polietilen (PE). S mt xch
-CH2-CH2- c trong lng trn PE l
A. 3,614.1023

B. 3,720.1023

C. 12,460.1023

D. 4,140.1022

4.92. Phn ng lu ha cao su thuc loi phn ng


A. Gi nguyn mch polime B. Gim mch polime C. ipolime ha

D. Tng mch polime

4.93. Polime X trong phn t ch cha C, H v c th c O. H s trng hp ca phn t X l 1800, phn t


khi l 154800. X l
A. Cao su isopren

B. PE (polietilen)

C. PVA (poli (vinyl axetat)) D. PVC (poli(vinyl clorua))

4.94. Dy hp cht no sau y ch cha t nhn to ?


A. T capron, t axetat, t visco

B. T axetat, t visco, t ng - amoniac

C. T polieste, t visco, t ng - amoniac

D. T polieste, t visco, t axetat

4.95. Cht no sau y l nguyn liu sn xut t visco ?


A. Xenluloz

B. Caprolactam

C. Vinyl axetat

D. Alanin

4.96. Polime no sau y khng b thy phn trong mi trng kim ?


A. PVA (poli (vinyl axetat) B. T nilon - 6,6

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TI LIU N THI 2011.

C. T capron

D. Cao su thin nhin

44

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------4.97. Cch phn loi no sau y ng ?
A. Cc loi vi si, si len u l t thin nhin

B. T capron l t nhn to

C. T visco l t tng hp

D. T xenluloz axetat l t ha hc

4.98: Cht no di y khng th trc tip tng hp c cao su ?


A. ivinyl

B. Isopren

C. Clopren

D. But-2-en

4.99. Nha phenol-fomaehit c iu ch bng cch un nng phenol (d) vi dung dch no sau y ?
A. CH3CHO trong mi trng axit

B. CH3COOH trong mi trng axit

C. HCOOH trong mi trng axit

D. HCHO trong mi trng axit

4.100. Khi trng ngng a gam axit aminoaxetic vi hiu sut 80%, ngoi aminoaxit d ngi ta cn thu
c m gam polime v 2,88 gam nc. Gi tr ca m l
A. 7,296 gam

B. 11,40 gam

C. 11,12 gam

D. 9,120 gam

P N CHNG 1:
p n cu hi trc nghim 1:
1B 2A 3B 4D 5A 6C 7C 8D 9A 10C 11C 12D 13C 14D 15D 16D 17B 18B 19D 20A 21C 22A 23B
24D 25A.
p n cu hi trc nghim 2: 1C 2C 3B 4A 5C 6C 7B 8D 9C 10B 11B 12B 13D 14C 15B 16B
17A 18D 19D 20A 21C 22A 23D 24B 25D 26C 27D 28B 29B 30D 31B 32B 33D 34A 35A 36D 37C
38B 39D 40B 41A 42A 43B 44B 45C 46C 47A 48B 49B 50C.
P N CHNG 2:
p n cu hi trc nghim 1:
1C, 2A, 3A, 4D, 5D, 6C, 7B, 8D, 9D, 10A, 11B, 12D, 13C, 14B, 15B, 16B, 17B, 18A, 19D, 20B,
21C, 22A, 23B, 24C, 25A.
p n cu hi trc nghim 2:
1C, 2B, 3B, 4A, 5C, 6B, 7C, 8B, 9C, 10C, 11A, 12D, 13D, 14A, 15A, 16B, 17B, 18D, 19A, 20C,
21D, 22A, 23A, 24C, 25B, 26B, 27A, 28D, 29A, 30C, 31D, 32C, 33B, 34A, 35C, 36A, 37D, 38A,
39B, 40A, 41C, 42D, 43A, 44C, 45B, 46D, 47C, 48D, 49A, 50B.
P N CHNG 3:
Trc nghim 1:
1B, 2C, 3C, 4C, 5C, 6A, 7C, 8C, 9D, 10C, 11A, 12B, 13C, 14C, 15C, 16A, 17C, 18C, 19A, 20C,
21B, 22C, 23A, 24A, 25B.
Trc nghim 2:

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TI LIU N THI 2011.

45

------------------------------------------------------------------------------------------------------------------------GV: V PHN ( YN S- HONG MAI- HN).


C: 0436.453.591;D: 01236.575.369
-------------------------------------------------------------------------------------------------------------------------1C, 2A, 3D, 4C, 5A, 6B, 7C, 8C, 9B, 10D, 11D, 12C, 13D, 14D, 15A, 16B, 17B, 18D, 19C, 20B,
21B, 22B, 23C, 24B, 25A, 26A, 27C, 28D, 29B, 30D, 31C, 32D, 33C, 34D, 35A, 36A, 37B, 38A,
39C, 40B, 41C, 42A, 43D, 44B, 45B, 46A, 47D, 48D, 49C, 50B.
P N CHNG 4:
Trc nghim 1:
1A, 2C, 3D, 4D, 5C, 6D, 7C, 8D, 9D, 10A, 11C, 12B, 13A, 14D, 15B, 16C, 17A, 18B, 19A, 20D,
21B, 22C, 23C, 24B, 25B.
Trc nghim 2:
1A, 2D, 3B, 4D, 5B, 6B, 7D, 8C, 9B, 10B, 11B, 12C, 13A, 14B, 15D, 16D, 17A, 18B, 19D, 20A,
21A, 22A, 23A, 24B, 25D, 26B, 27D, 28A, 29D, 30C, 31D, 32C, 33C, 34C, 35B, 36A, 37B, 38A,
39B, 40B, 41C, 42A, 43A, 44B, 45C, 46C, 47D, 48C, 49D, 50D.

==================
TI LIU N THI 2011.

46

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