DNG 3: BI TP V AXIT NITRIC V MUI NITRAT Cu 1: ( HKA 2007) Ha tan hon ton 12 g hn hp gm Fe v Cu ( t l mol 1:1) bng HNO3, thu

c V lt (ktc) hn hp X gm (NO v NO2) v dd Y ( Ch cha hai mui v axit d) t khi ca X i vi H2 bng 19. Gi tr ca V l A. 2,24 B. 4,48 C. 5,6 D. 3,36 Cu 2: (HKB 2007) Nung m gam bt st trong oxi thu c 3 gam hn hp cht rn X. Ha tan ht hn hp X trong dung dch HNO3 d, thot ra 0,56 lt (ktc) NO ( sn phm kh duy nht). Gi tr ca m l A. 2,52 B. 2,22 C. 2,62 D. 2,32 Cu 3: (HKB 2007) Khi cho Cu tc dng vi dd H2SO4 (l) v NaNO3, vai tr ca NaNO3 trong phn ng l A. Cht xc tc B. Cht oxi ha C. Mi trng D. Cht kh Cu 4: (HKB 2007) Cho hn hp gm Fe v Cu phn ng vi dd HNO3 long. Sau khi phn ng xy ra hon ton, thu c dung dch ch cha mt cht tan v kim loi d. Cht tan l A. Cu(NO3)2 B. HNO3 C. Fe(NO3)2 D. Fe(NO3)3 Cu 5: (HKB 2007) 1. Cho 3,84 gam Cu vi 80 ml dung dch HNO3 1M thot ra V1(l) NO. 2. Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M v H2SO4 0,5M thot ra V2(l) NO. Bit NO l sn phm kh duy nht, cc th tch o ktc. Quan h gia V1 v V2 l A. V2 = V1 B. V2 = 2V1 C. V2 = 2,5 V1 D. V2 = 1,5V1 Cu 6: (HKA 2008) Cho Cu v dd H2SO4 long tc dng vi cht X ( Mt loi phn bn ha hc) thy thot ra kh khng mu ha nu trong khng kh. Mt khc khi X tc dng vi dd NaOH th c kh mi khai thot ra. Cht X l A. Amophot B. Ure C. Natri nitrat D. amoni nitrat Cu 7: (HKA 2008) Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3 0,8 M v H2SO4 0,2M sau khi phn ng xy ra hon ton, sinh ra V(l) kh NO(sn phm kh duy nht ktc) Gi tr ca V l A. 0,746 B. 0,672 C. 0,448 D. 1,792 Cu 8 (HKA 2008) Cho 11,36g gm Fe, Fe0,Fe203 v Fe304 phn ng ht vi dung dch HN03 long d, thu c 1,344l.NO (sn phm kh duy nht) v dd X .C cn ddX thu c mg mui khan. Ga tr ca m l A 38,72 B 35,5 C49,09 D34.36 Cu 9 ( HKA 2008) Cho 21,6 g Mg tc dng vi dung dch HNO3 d .Sau phn ng xy ra hon ton thu c 0,896l kh NO (ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi dung dch X l. A 8,88g B 13,92g C 6,52g D 13,32g Cu 10: ( HKB 2008) Th tch dung dch HNO3 1M (l) t nht cn dung ha tan hon ton mt hn hp gm 0,15 mol Fe v 0,15 mol Cu l(Bit phn ng to ra cht kh duy nht l NO) A. 1(l) B. 0,6 (l) C. 0,8 (l) D. 1,2 (l) Cu 11 (C 2008) Nhit phn hon ton 34,65 (g) hn hp gm KNO3 v Cu(NO3)2 thu c hn hp kh X c t khi so vi H2 l 18,8. Khi lng ca Cu(NO3)2 trong hn hp ban u l A. 8,6g B. 20,5g C. 11,28g D. 9,4g Cu 12 ( C 2008) Cho dy cc cht: FeO, Fe(OH)2, FeSO4, Fe3O4, Fe2(SO4)3, Fe2O3. S cht trong dy b oxi ha khi tc dng vi dd HNO3 c nng l A. 3 B. 5 C. 4 D. 6 CHUYN N THI I HC 1

Cu 13 Hon toan ha ton m gam Zn vo vo dd HNO3 va , sau phn ng thu c dd A v 4,48 (l) kh B gm NO v N2O (ktc). T khi hi ca B so vi H2 l 18,5. Vit PTP xy ra. Tnh m Cu 14(HKA 2009) Nung 6,58 gam Cu(NO3)2 trong bnh kn khng cha khng kh, sau mt thi gian thu c 4,96 gam cht rn v hn hp kh X. Hp th hon ton X vo nc c 300 ml dung dch Y. DD Y c pH bng A. 4 B. 3 C. 1 D. 2 Cu 15(HKA 2009) Cho hn hp gm 1,12 gam st v 1,92 gam Cu vo 400ml dd cha hh gm H2SO4 0,5M v NaNO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dd X v kh NO (SP kh duy nht). Cho V (ml) dd NaOH 1M vo dd X th lng kt ta thu c l ln nht. Gi tr ti thiu ca V l A. 360 B. 240 C. 400 D. 120 Cu 16 (HKA 2009) Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO3(l), thu c 940,8 ml kh NxOy (SP kh duy nht, ktc) c t khi i vi H2 l 22. Kh NxOy v kim loi M l A. NO v Mg B. NO2 v Al C. N2O v Al D. N2O v Fe Cu 17( HKB 2009) Cho m gam bt st vo 800 ml dd hn hp gm Cu(NO3)2 0,2M v H2SO4 0,25M. Sauk hi phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V(l) kh NO (duy nht ktc). Gi tr ca m v V ln lt l A. 10,8 v 4,48 B. 10,8 v 2,24 C. 17,8 v 2,24 D. 17.8 v 4,48 Cu 18( HKB 2009) Ha tan hon ton 1,23 gam hn hp X gm Al v Cu vo dd HNO3 c nng thu c 1,344 (l) NO2 (SP kh duy nht) v dd Y. Sc t t kh NH3 (d)vo dd Y sau khi phn ng xy ra hon ton thu c m (g) kt ta. Phn trm v khi lng ca Cu trong hn hp X v gi tr ca m l A. 21,95% v 2,25 B. 78,05% v 2,25 C. 21,95% v 0,78 D. 78,05% v 0,78 Cu 19( HKB 2010) Nung 2,23 gam hn hp X gm cc kim loi Fe, Al, Zn, Mg trong oxi, sau mt thi gian thu c 2,71 gam hn hp Y. Ha tan hon ton Y vo dd HNO3 (d) thu c 0,672 (l) kh NO (SP kh duy nht KTC). S mol HNO3 phn ng l A. 0,12 B. 0,16 C. 0,18 D. 0,14 Cu 20: ( HKB 2010) Cho 0,3 mol bt ng v 0,6 mol Fe(NO3)2 vo dd cha 0,9 mol H2SO4 long. Sauk hi cc phn ng xy ra hon ton thu c V (l) kh NO (SP kh duy nht KTC). Gi tr ca V l A. 8,96 B. 4,48 C. 10,08 D. 6,72
Cu 21: Ha tan hon ton hn hp gm cc kim loi Mg, Al, Zn, Fe, Ni, Cu, Ag vo dung dch HNO 3 long (d), thu c dung dch X. Cho X tc dng vi dung dch NaOH (d), thu c kt ta Y. em Y tc dng vi dung dch NH 3 (d), n phn ng hon ton thu c kt ta Z. S hiroxit c trong Y v Z ln lt l A. 7 ; 4. B. 3 ; 2. C. 5 ; 2. D. 4 ; 2. Cu 22: Nhit phn hon ton 29,6 gam mt mui nitrat kim loi, sau phn ng thu c 8 gam oxit kim loi. Cng thc ca mui nitrat l A. Cu(NO3)2. B. Fe(NO3)3. C. Pb(NO3)2. D. Mg(NO3)2. Cu 23: Cho 0,448 lt kh NH3 (ktc) i qua ng s ng 16 gam CuO nung nng, sau khi phn ng xy ra hon ton thu c cht rn X. Cho X vo dung dch HNO3 c, nng (d) thu c V lt kh (ktc). Gi tr ca V l A. 8,960. B. 0,448. C. 0,672. D. 1,344. Cu 24: Ha tan ht m gam hn hp FeS 2 v Cu2S trong dung dch HNO3, sau cc phn ng hon ton thu c dung dch X ch c 2 cht tan, vi tng khi lng cc cht tan l 72 gam. Gi tr ca m l A. 80. B. 20. C. 60. D. 40. Cu 25: Nung hn hp gm 6,4 gam Cu v 54 gam Fe(NO 3)2 trong bnh kn, chn khng. Sau phn ng hon ton thu c hn hp kh X. Cho X phn ng ht vi nc, thu c 2 lt dung dch Y. pH ca dung dch Y l A. 1,3. B. 1. C. 0,523. D. 0,664.

CHUYN N THI I HC

Cu 26: Cho 11,36 gam hn hp gm Fe, FeO, Fe 2O3 v Fe3O4 phn ng ht vi dung dch HNO 3 long (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung dch X thu c m gam mui khan. Gi tr m v s mol HNO3 tham gia phn ng ln lt l A. 38,72; 0,54 B. 38,72; 0,24 C. 26,62 ; 0,24 D. 26,62 ; 0,54 Cu 27: Cho a gam hn hp A gm (Fe, Cu, Ag, Al, Zn, Cr, Ni) tc dng vi dung dch HNO 3 d, sau phn ng thu c dung dch B ( khng c mui amoni) v hn hp kh C gm ( x mol NO2, y mol NO, z mol N2O, t mol N2). C cn dung dch B thu c b gam mui khan. Mi lin h gia a, b, x, y, z, t l: A. b = a + 62(x + 3y + 8z + 10t ) B. b = a + 62(x + 3y + 4z + 5t ) C. b = a + 62(x + y + z + t ) D. b = a + 62(x + y + 2z + 2t ) Cu 28: Cho H (Z=1), N(Z=7), O (Z=8). Trong phn t HNO 3, tng s cp electron lp ngoi cng khng tham gia lin kt ca 5 nguyn t l A. 7. B. 8. C. 9. D. 6. Cu 29: (Bit: O=16; H=1; N=14) Nhit phn mt mui nitrat kim loi c ha tr khng i thu c hn hp kh X v oxit kim loi. Khi lng ring ca hn hp kh X iu kin chun l A. 1,741 gam/L. B. 1,897 gam/L. C. 1,929 gam/L. D. 1,845 gam/L. Cu 30: Ho tan ht 18,2 gam hn hp Zn v Cr trong HNO 3 long thu c dung dch A ch cha hai mui v 0,15 mol hn hp hai kh khng mu c khi lng 5,20 gam trong c mt kh ho nu ngoi khng kh. S mol HNO3 phn ng l A. 0,9 mol B. 0,7 mol C. 0,2 mol D. 0,5 mol Cu 31: Ha tan hn hp X gm 1,92 gam Cu v 2,16 gam FeO trong 100 ml dung dch hn hp H 2SO4 1M v NaNO3 0,4M thu c dung dch Y v kh NO (sn phm kh duy nht). Th tch dung dch NaOH 0,5M nh nht cn dng tc dng vi Y cho lng kt ta ln nht l A. 340 ml. B. 300 ml. C. 460 ml. D. 150 ml. Cu 32: Ha tan hon ton 1,23 gam hn hp X gm Cu v Al vo dd HNO3 c, nng thu c 1,344 lt kh NO2 (duy nht, ktc) v dd Y. Sc t t kh NH3 (d) vo dd Y, sau khi phn ng xy ra hon ton thu c m gam kt ta. Phn trm v khi lng ca Cu trong hn hp X v gi tr ca m ln lt l A. 78,05% v 0,78. B. 21,95% v 0,78 C. 21,95% v 2,25. D. 78,05% v 2,25. Cu 33: Hoa tan m(g) Al vao lng d dung dch hh NaOH va NaNO3 thay xuat hien 26,88 lt (ktc) hh kh NH3 va H2 vi so mol bang nhau. Gia tr cua m la: A. 6,75 B. 30,24 C. 54 D. 89,6 Cu 34: (HSG Thi Bnh 2010- 2011) Nhit phn hon ton R(NO3)2 (vi R l kim loi) thu c 8 gam mt oxit kim loi v 5,04 lt hn hp kh X gm NO2 v O2 (o ktc). Khi lng ca hn hp kh X l 10 gam. Xc nh cng thc ca mui R(NO3)2 ? A. Mg(NO3)2. B. Zn(NO3)2 . C. Fe(NO3)2. D. Cu(NO3)2 . Cu 35: (HSG Thi Bnh 2010- 2011) Cho 3,76 gam hn hp X gm Mg v MgO c t l mol tng ng l 14:1 tc dng ht vi dung dch HNO 3 th thu c 0,448 lt mt kh duy nht (o ktc) v dung dch Y. C cn cn thn dung dch Y thu c 23 gam cht rn khan T. Xc nh s mol HNO3 phn ng ? A. 0,28 B. 0,34 C. 0,36 D. 0,32 Cu 36: (HSG Thi Bnh 2010- 2011) Dung dch X cha 14,6 gam HCl v 22,56 gam Cu(NO 3)2. Thm m (gam) bt st vo dung dch X, sau khi phn ng xy ra hon ton thu c hn hp kim loi c khi lng l 0,5m (gam) v ch to kh NO (sn phm kh duy nht ca N+5). Gi tr ca m l A. 1,92. B. 20,48. C. 9,28. D. 14,88. Cu 37: (HSG Thi Bnh 2010- 2011) Ha tan 2m (gam) kim loi M bng dung dch HNO 3 c, nng, d hay ha tan m (gam) hp cht X (hp cht ca M vi lu hunh) cng trong dung dch HNO3 c, nng, d th cng thu c kh NO2 (sn phm kh duy nht) c th tch bng nhau cng iu kin nhit v p sut. Gi s nguyn t lu hunh ch b oxi ha ln mc cao nht. Kim loi M v cng thc phn t ca X ln lt l CHUYN N THI I HC 3

A. Cu v CuS. B. Cu v Cu2S. C. Mg v MgS. D. Fe v FeS. Cu 38: (HSG Thi Bnh 2010- 2011) Cho hn hp X gm 8,4 gam Fe v 6,4 gam Cu vo dung dch HNO 3. Sau khi phn ng hon ton thu c 3,36 lt kh NO (l sn phm kh duy nht, o ktc). Khi lng mui thu c sau phn ng l A. 36,3 gam. B. 41,1gam. C. 41,3 gam. D. 42,7 gam. Cu 39: (HSG Thi Bnh 2009- 2010)

Ho tan hon ton 0,1 mol FeS 2 trong dung dch HNO3 c nng. Tnh th tch kh NO 2 bay ra (ktc) v s mol HNO3 (ti thiu) phn ng (bit rng lu hunh trong FeS2 b oxi ho ln s oxi ho cao nht) A. 33,6 lt v 1,4 mol B. 33,6 lt v 1,5 mol C. 22,4 lt v 1,5 mol D. 33,6 lt v 1,8 mol Cu 40: (HSG Thi Bnh 2009- 2010) Cho s sau: Cu + dd mui X khng phn ng; Cu + dd mui Y khng phn ng. Cu + dd mui X + dd mui Y phn ng Vi X, Y l mui ca natri. Vy X,Y c th l A. NaAlO2, NaNO3 B. NaNO3, NaHCO3 C. NaNO3, NaHSO4 D. NaNO2, NaHSO3 Cu 41: (HSG Thi Bnh 2009- 2010) Cho 10,32 gam hn hp X gm Cu, Ag tc dng va vi 160 ml dung dch Y gm HNO 31M v H2SO4 0,5 M thu c kh NO duy nht v dung dch Z cha m gam cht tan. Gi tr ca m l A. 20,36 B. 18,75 C. 22,96 D. 23,06 Cu 42: (HSG Thi Bnh 2009- 2010) Cho 11,6 gam FeCO3 tc dng va vi dung dch HNO 3 thu c hn hp kh (CO 2, NO) v dung dch X. Khi thm dung dch HCl d vo dung dch X th ho tan ti a c bao nhiu gam bt Cu (bit c kh NO bay ra) A. 28,8 gam B. 16 gam C. 48 gam D. 32 gam Cu 43: Dung dch A cha 0,01 mol Fe(NO3)3 v 0,15 mol HCl c kh nng ha tan ti a bao nhiu gam Cu kim loi? (Bit NO l sn phm kh duy nht) A. 2,88 gam. B. 3,92 gam. C. 3,2 gam. D. 5,12 gam. Cu 44: Nung 6,58 gam Cu(NO3)2 trong bnh kn khng cha khng kh, sau mt thi gian thu c m gam cht rn v hn hp kh X. Hp th hon ton X vo nc c 300 ml dung dch Y c pH bng 1. Hiu sut ca phn ng nhit phn l: A. 42,86% B.40,56% C. 58,86% D. 62,68% Cu 45: Cho 2,16 gam Al tan ht trong dung dch HNO3 long thu c 0,672 lt kh A duy nht ktc. Kh A l: A. NO. B. NO2. C. N2O. D. N2. Cu 46: Nung nng 34,6 gam hn hp X gm Cu(NO 3)2 v Cu trong bnh kn n khi lng khng i thu c cht rn
Y. ha tan ht Y cn va 500 ml dung dch H2SO4 long 0,5M. Khi lng ca Cu(NO3)2 trong X l A. 23,5 gam. B. 18,8 gam. C. 14,1 gam. D. 28,2 gam. Cu 47: Cho m gam bt Fe tc dng ht vi dung dch HNO 3 long, thu c dung dch X v kh NO (sn phm kh duy nht). C cn dung dch X thu c 51,2 gam mui khan. Bit rng s mol Fe ban u bng 31,25% s mol HNO 3 phn ng. Gi tr ca m l A. 20,72. B. 10,36. C. 28. D. 14. Cho hn hp gm 5,6 gam Fe v 7,8 gam Zn vo dung dch HNO long d, sau khi cc phn ng xy ra hon ton Cu 48: 3 thu c 3,36 lt NO duy nht ( ktc) v dung dch X cha m gam mui. Gi tr ca m l A. 46,88. B. 41,58. C. 47,78. D. 41,3. Cu 49: ( d b i hc khi A 2009) Cho lung kh CO i qua ng s ng m gam Fe 2O3 nung nng. Sau mt thi gian thu c 10,44 gam cht rn X gm Fe, FeO, Fe3O4 v Fe2O3 d. Ha tan ht X trong dd HNO 3 c nng thu c 4,368 (l) NO2 (SP kh duy nht KTC). Gi tr ca m l A. 12 B. 24 C. 10,8 D. 16 Cu 50: d b i hc khi A 2009)

CHUYN N THI I HC

Ha tan 19,2 gam Cu vo 500 ml dd NaNO 3 1M, sau thm vo 500 ml dd HCl 2M. Kt thc phn ng thu c dd X v kh NO duy nht. Phi thm bao nhiu ml dd NaOH 1M vo X kt ta ht ion Cu 2+. A. 600 B. 800 C. 400 D. 120 Cu 51: t chy 5,6gam bt st trong bnh oxi thu c 7,36 gam hn hp A gm Fe 2O3 v Fe3O4, mt phn st cn li. Ha tan hon ton hn hp A bng dd HNO 3 thu c V (l) hn hp kh B gm NO 2 v NO c t khi hi so vi H2 l 19. Tnh th tch V (ktc) ( v = 0,896 (l)) Cu 52: Cho 34 gam mt mui nitrat ca kim loi M ha tr n khng i vo bnh kn dung tch 5,6 (l) cha khng kh (ktc). Nung bnh n khi phn ng hon ton thu c 21,6 gam cht rn B v hn hp kh C. a. Xc nh kim loi M ( Ag) b. Thnh phn ca hn hp kh C v p sut trong bnh sau khi nung a v 0 0C ( 0,2 mol NO2, 0,15 mol O2, 0,2 mol N2) c. Mt hn hp X gm 32,4 gam B v 19,5 gam kim loi M( ha tr 2). Ha tan X trong HNO 3 2M ( va ) thu c dd D v kh NO. Bit th tch NO do B v M to ra hn km nhau 2,24 (l, ktc). Xc nh kim loi M v th tch dd HNO3 2M dng. ( M l Zn, V = 600 ml) Cu 53: Nung mt hn hp X gm cacbon v CuO cho n khi phn ng hon ton thu c cht rn A. Khi cho A tc dng vi 0,5 lt dd HCl 0,4M ( va ) th c mt phn tan, phn cn li tan trong 0,8 (l) dd HNO 3 0,2M ( va ) thu c kh NO. a. Tnh khi lng cacbon v CuO trong hn hp ban u b. Nu cho cng mt lng hn hp X tc dng vi V (l) dd HNO 3 5M (va ) th thu c hn hp hai kh, trong c mt kh mu nu. Xc nh thnh phn hn hp kh v th tch V dng Cu 54: Cho mu khong cht A gm NH4NO3 v tp cht tr. Ly 2,5 gam A ri em trn vi lng d hn hp Al v Zn dng bt cho vo cc v nung nng vi lng d dd NaOH, cht kh thot ra c hp thu hon ton vo bnh ng 100 ml dd H2SO4 0,15M. Lng axit cn d trong bnh tc dng va vi 35 ml dd NaOH 0,1M. Ly 8,3 gam A cho vo cc, cho vo dd H 2SO4 d. Sau khi phn ng kt thc thy khi lng cc cht trong cc gim 1,826 gam. a. Vit PTP b. Tnh % khi lng NH4NO3 v CaCO3 trong A Cu 55: Cho 30 gam hn hp bt Al, Mg vo 2 (l) dd HNO 3. Hai kim loi tan ht v khng c kh bay ra. Thm 200 ml dd naOH 2M vo dd ng thi un nh cho ti khi ngng kh thot ra thu c kh B v dd keo A. t chy hon ton B trong O2 d(xt Pt) ri cho sn phm chy( loi ht O 2 d) tc dng vi nc cha trong bnh kn khng c O2 ta c dd C v kh D khng mu. Cho C phn ng ht vi Cu thu c 0,9184 ( l) kh D. Them 270 ml dd HNO3 2M vo dd keo A th axit ny va chuyn dd keo thnh dd trong sut. Sau thm tip dd KOH n khi thu c kt ta ln nht. Lc kt ta ri em nung n khi lng khng i thu c 52,4 gam cht rn. a. Cho bit tn B v D. b. Tnh CM dd HNO3 ban u Cu 56: Cho m1 gam hn hp Mg, Al vo m 2 gam dd HNO3 24%. Sau khi cc kim loi tan ht thu c 8,96 lt hn hp kh X gm NO, N2O v N2 ( ktc) v dd A. Thm vo mt lng oxi va vo X, sau phn ng c hn hp kh Y. Dn Y t t qua dd NaOH d c 4,48 lt hn hp kh Z bay ra (ktc). T khi ca Z so vi H 2 bng 20. Nu cho dd NaOH vo A c lng kt ta ln nht th thu c 62,2 gam kt ta. a. Tnh m1, m2 bit lng HNO3 ly d 20% so vi lng cn thit. b. Tnh C% cc cht trong dd A Cu 57: Nung 37,6 gam mui nitrat ca kim loi M n khi lng khng i thu c 16 gam cht rn v hn hp kh X c t khi so vi H2 bng 21,6. a. Xc nh cng thc mui nitrat b. Ly 12,8 gam kim loi M tc dng vi 100 ml hn hp HNO 3 1M, HCl 2M, H2SO4 1M th thu c bao nhiu lt NO ktc. Cu 58: Ha tan hon ton hn hp FeS v FeCO3 bng dd HNO3 c, nongsthu c hn hp kh A gm hai kh X v Y c t khi so vi H2 bng 22,805. a. Tnh phn trm khi lng mi mui trong hn hp ban u b. Lm lnh hn hp kh A xung nhit thp hn ta c hn hp kh B gm 3 kh X, Y, Z c t khi so vi H2 bng 30,61. Tnh % kh X b i me ha thnh kh Z. Hy cho bit phn ng ime ha l ta nhit hay thu nhit v mu ca hn hp bin i NTN khi lm lnh hn hp.

CHUYN N THI I HC

Cu 59: Ha tan hon ton 16,2 gam mt kim loi A bng dd HNO 3 thu c 5,6 lt ( ktc) hn hp kh B gm NO v N2 c khi lng 7,2 gam. Kim loi A l A. Cr B. Fe C. Al D. Zn Cu 60: Chia 2,2 gam hn hp gm Fe v kim v kim loi M c ha tr khng i lm hai phn bng nhau. - Ha tan ht phn 1 bng HCl thu c 0,896 (l) H 2 (KTC) - Ha tan ht phn 2 bng dd HNO3 c, nng thu c 2,016 lt NO2 (ktc) a. Tm M b. Tnh phn trm khi lng ca mi kim loi trong hn hp Cu 61: Ha tan hon ton 9,74 gam hn hp Cu v Ag ( mi cht c thnh phn thay i t 0% 100% ) bng HNO3 long thu c V (l) NO (ktc) a. Tm khong xc nh ca V b. Khi V = 1,212 (l), xc nh khi lng mi kim loi trong hn hp Cu 62: Hon tan hon ton 0,368 gam hn hp Al, Zn cn va 25 lt dd HNO 3 0,001. Sau phn ng thu c dd cha 3 mui. Tnh s gam mi kim loi ban u. Cu 63: Ha tan hon ton 16,2 gam mt kim loi ha tr 3 bng dd HNO 3 thu c 5,6 lt (ktc) hn hp A gm NO v N2. Bit t khi ca A so vi O2 l 0,9. a. Xc nh kim loi trn b. Tnh th tch dd HNO3 2,5 M ti thiu cn phi ly Cu 64: Ha tan hon ton 36,8 gam hn hp bt st v Cu bng dd HNO 3 thu c 15,68 lt hn hp NO v NO2 (ktc). Bit t khi ca hn hp kh trn so vi H 2 l 19,57 a. Tnh khi lng dd HNO3 42 % ti thiu cn dng b. C cn dd sau phn ng nhit va phi thu c hn hp hai mui khan nng 123,6 gam. Tnh % khi lng mi kim loi ban u Cu 65: Cho hn hp A gm kim loi R ( ha tr I) v kim loi X ( ha tr II). Ha tan 3 gam A vo dd c cha HNO 3 v H2SO4 thu c 2,94 gam hn hp B gm NO2 v kh D c th tch l 1,344 lt(ktc) a. Hi lng mui khan thu c l bao nhiu? b. Nu cho cng mt lng kh Cl 2 ln lt tc dng vi kim loi R v kim loi X th lng kim loi R phn ng gp 3,375 ln khi lng ca kim loi X. Khi lng mui clorua ca R thu c gp 2,126 ln khi lng mui clorua ca X to thnh. Hy tnh % v khi lng cc kim loi trong A. Cu 66: Cho hn hp gm 3,36 gam Mg v 0,4 gam MgO tc dng vi dung dch HNO 3 long d thu c 0,448 lt kh N2 l sn phm kh duy nht (ktc). C cn dung dch sau phn ng thu c 23 gam cht rn khan. S mol HNO 3 phn ng l: A. 0,32 mol B. 0,28 mol C. 0,34 mol D. 0,36 mol Cu 67: X l hn hp cc mui Cu(NO3)2, Zn(NO3)2, Fe(NO3)3, Mg(NO3)2. Trong O chim 9,6% v khi lng. Nung 50 gam X trong bnh kn khng c oxi n khi phn ng xy ra hon ton thu c m gam oxit. Gi tr ca m l A. 44,6 B. 39,2 C. 17,6 D. 47,3 Cu 68: Cho bt Fe vo dung dch NaNO 3 v H2SO4. n phn ng hon thu c dung dch A, hn hp kh X gm NO v H2 c v cht rn khng tan. Bit dung dch A khng cha mui amoni. Trong dung dch A cha cc mui: A. FeSO4, Fe(NO3)2, Na2SO4, NaNO3. B. FeSO4, Fe2(SO4)3, NaNO3, Na2SO4. C. FeSO4, Na2SO4. D. FeSO4, Fe(NO3)2, Na2SO4. Cu 69: Ha tan hon ton 3,76 gam hn hp: S, FeS, FeS 2 trong HNO3 d c 0,48 mol NO2 v dung dch X. Cho dung dch Ba(OH)2 d vo X, lc kt ta nung n khi lng khng i th khi lng cht rn thu c l: A. 17,545 gam B. 18,355 gam C. 15,145 gam D. 2,4 gam Cu 70: Hn hp X gm bt Fe v kim loi M (ha tr khng i) nng 15,06 gam c chia lm hai phn bng nhau. Phn 1 cho tc dng vi dung dch HCl d thu c dung dch Y v 0,165 mol H 2. Phn 2 cho tc dng vi dung dch HNO 3 d thu c 0,15mol NO (sn phm kh duy nht). Kim loi M l A. Mg B. Zn C. Al D. Cr Cu 71: Ha tan ht cht rn X gm Mg, Zn, Al cn va 1,8 mol HNO 3. Sau phn ng thu c V lt NO (sn phm kh duy nht ktc). Gi tr ca V l A. 13,44 B. 10,08 C. 14,56 D. 11,2 Cu 71: Cho 18,5 gam hn hp gm Fe v Fe3O4 tc dng vi 200 ml HNO3 long, un nng. Sau khi phn ng thu c 2,24 lt NO duy nht (ktc), dung dch D v cn li 1,46 gam kim loi. Nng ca dung dch HNO 3 l:

CHUYN N THI I HC

A. 5,1M B. 3,5M C. 3,2M D. 2,6M Cu 72: Cho 5,8 gam mui FeCO3 tc dng vi dung dch HNO3 va , thu c hn hp kh cha CO 2, NO v dung dch X. Cho dung dch HCl d vo dung dch X c dung dch Y, dung dch Y ny ha tan c ti a m gam Cu, sinh ra sn phm kh NO duy nht. Gi tr ca m l: A. 9,6 gam B. 11,2 gam C. 14,4 gam D. 16 gam Cu 73: Ha tan ht m gam hn hp A gm Al v FexOy bng dung dch HNO3, thu c phn kh gm 0,05 mol NO v 0,03 mol N2O, phn lng l dung dch D. C cn dung dch D, thu c 37,95 gam hn hp mui khan. Nu ha tan lng mui ny trong dung dch xt d th thu c 6,42 gam kt ta mu nu . Gi tr ca m v oxit FexOy l: A. 7,29 gam; FeO B. 9,72 gam; Fe3O4 C. 9,72 gam; Fe2O3 D. 7,29 gam; Fe3O4 Cu 74: Trn u 6,102 gam hn hp Al, Fe 3O4 v CuO (cc cht c cng s mol) ri tin hnh phn ng nhit nhm thu c hn hp X. Cho X tc dng vi dung dch HNO3 d c V ml ( ktc) hn hp kh NO2 v NO theo t l mol tng ng l 1:1. Gi tr ca V l A. 806,4 B. 604,8 C. 403,2 D. 645,12 Cu 75: Ly 1 mu Al d cho vo dung dch NaOH v NaNO 3 c nng bng nhau, khi phn ng hon ton th thu c dung dch X v hn hp kh gm H2 v NH3. Trong X cha nhng ion no? A. Na+, Al3+, NO3-. B. Na+, AlO2-, OH-. C. Na+, AlO2-, NO3-. D. Na+, Al3+, NH4+. Cu 76: Cho 16 gam hn hp X gm Cu, Fe tan hon ton trong 200 ml dung dch HNO3 4M thu c dung dch Y (khng cha acid) v 4,48 lt kh NO2 v NO (ktc). Tnh khi lng mui trong dung dch sau phn ng? A. 55,2 gam B. 54,2 gam C. 56,2 gam M D. 53,2 gam Cu 77: Ha tan hon ton 8,4 gam Fe trong dung dch HNO3 d thu c 6,72 lt hn hp kh X gm NO2 v NO.Tnh s mol HNO3 tham gia phn ng. A. 0,60 mol B. 0,75 mol C. 0,65 mol D. 0,55 mol Cu 78: HNO3 ch th hin tnh axit khi tc dng vi cc cht thuc dy no di y? A. CaCO3, Cu(OH)2, Fe(OH)2, FeO. B. CuO, NaOH, FeCO3, Fe2O3. C. Fe(OH)3, Na2CO3, Fe2O3, NH3. D. KOH, FeS, K2CO3, Cu(OH)2. Dng cho cu 79, 80, 81: Hn hp X gm FeS2 v MS c s mol nh nhau (M l kim loi c ho tr khng i). Cho 6,51g X tc dng hon ton vi dung dch HNO3 d, un nng thu c dung dch A v 13,216 lt hn hp kh B (ktc) c khi lng l 26,34 gam gm NO2 v NO. Cho A tc dng vi dung dch BaCl2 d thu c m gam kt ta. Cu 79: Kim loi M l A. Mg. B. Zn. C. Ni. D. Ca Cu 80: Gi tr ca m l A. 20,97. B. 13,98. C. 15,28. D. 28,52. Cu 81: Phn trm khi lng ca FeS2 trong X l A. 44,7%. B. 33,6%. C. 55,3%. D. 66,4%. Cu 82: Nung m gam Fe trong khng kh, thu c 104,8g hn hp A gm Fe, FeO, Fe2O3, Fe3O4. Ho tan hon ton A trong dung dch HNO3d, thu c dung dch B v 12,096 lt hn hp kh C gm NO v NO2 (ktc) c t khi so vi He l 10,167. Gi tr ca m l A.78,4. B. 84,0. C. 72,8. D. 89,6. Cu 83: t chy 5,6g bt Fe nung trong bnh O2 thu c 7,36 gam hn hp A gm Fe2O3, Fe3O4, FeO v Fe. Ho tan hon ton hn hp A bng dung dch HNO3 thu c Vlit hn hp kh B (ktc) gm NO2 v NO c t khi so vi H2 l 19. Gi tr ca V l A. 0,672. B. 0,224. C. 0,896. D. 1,120. Cu 84: (H Dn lp Phng ng 2001) Ha tan 13,9 (g) mt hn hp A gm Al, Cu, Mg bng V(ml) dd HNO3 c nng 5M va , gii phng ra 20,16 (l) kh NO2 (duy nht ktc) v dd B. Thm dd NaOH d vo B, ly kt ta nung nhit cao c cht rn D, dn mt lung kh H2 d qua D th thu c 14,4 gam cht rn E. a. Vit cc PTP xy ra. Tnh tng s gam mui to thnh trong B b. Tnh phn trm khi lng ca mi kim loi trong A c. Tnh V (ml), bit cc phn ng xy ra hon hon ton. Cu 85( Hc vin Bu Chnh vin thng 2001)

CHUYN N THI I HC

Hn hp A gm 3 oxit st gm Fe2O3, Fe3O4, FeO vi s mol bng nhau. Ly m1 gam A cho vo ng s chu nhit, un nng n ri cho mt lung kh CO i qua ng, CO phn ng ht, ton b kh CO 2 ra khi ng c hp th ht vo bnh ng dd Ba(OH) 2, thu c m2 gam kt ta trng. Cht rn cn li trong ng s sau phn ng c khi lng l 12,9 gam gm Fe, FeO v Fe 3O4, cho hn hp ny tc dng ht vi dd HNO 3 un nng thu c 2,24 (l) NO ( Duy nht KTC) a. Vit PTP xy ra b. Tnh khi lng m1, m2 v s mol HNO3 phn ng. Cu 86: Cho 62,1 gam Al ha tan vo dd HNO3 long ta thu c 16,8 (l) hn hp X gm 2 kh N2O v N2 ktc a. Tnh th tch dd HNO3 2M dng, bit rng ly d 25% so vi lng dd HNO3 cn thit b. Tnh th tch mi kh trong hn hp Cu 87: (H QGTPHCM 1999) Mt oxit kim loi c CT l M 2Oy, trong M chim 72,41% v khi lng. Kh hon ton oxit ny bng kh CO thu c 16,8 gam kim loi M. Ha tan hon ton lng M bng dd HNO 3 un nng thu c mui ca M ha tr III v 0,9 mol NO2. Vit cc PTP xy ra. Xc nh CT oxit kim loi ( Fe3O4) Cu 88: (HQGHN 1999) Cho mt lng Cu2S tc dng hon ton vi dd HNO3 un nng. Phn ng to thnh dd A1 v gii phng ra kh A2 khng mu, b ha nu trong khng kh. Chia A1 thnh hai phn. Thm dd BaCl2 vo phn I, thy to thnh kt ta trng A3 thc t khng tan trong axit d. Thm lng d dd HNO 3 vo phn II, ng thi khuy u hn hp, thu c dd A4 c mu xanh lam m a. Hy ch ra A1, A2, A3, A4 l g b. Vit PTP m t qu trnh ha hc nu trn Cu 89: (HBKHN 1999) Ha tan hon ton mt lng hn hp A gm Fe3O4 v FeS2 trong 63 gam dd HNO3 theo sc phn ng. Fe3O4 + HNO3 Fe(NO3)3 + NO2 + H2O FeS2 + HNO3 Fe(NO3)3 + NO2 + H2SO4 + H2O Th tch kh NO2 thot ra l 1,568(l) (ktc) Dd thu c cho tc dng va vi 200 ml dd NaOH 2M, lc kt ta em nung n khi lng khng i c 9,76 gam cht rn. Tnh s gam mi cht trong A v nng % ca dd HNO 3( GS HNO3 khng b mt do bay hi trong qu trnh phn ng). (mFe3O4 = 9,28, mFeS2 = 0,24, C% HNO3 = 46,2%)

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