TRNG THPT CHUYN NGUYN BNH KHIM

M THI : 101
( thi c 6 trang) THI TH I HC NM HC 2012 2013 Mn thi: HA HC Thi gian lm bi 90 pht ( khng k thi gian giao ).

Cho bit nguyn t khi ca cc nguyn t: C = 12; H = 1; O = 16; N = 14; P = 31; S = 32; He = 4; Na = 23; K = 39; Ca = 40; Ba = 137; Al = 27; Zn = 65; Fe = 56; Cu = 64; Ag = 108; Cr = 52. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1. Nguyn t nguyn t X v Y to ion tng ng l Xn+ v Y-. C Xn+, Y- u c cu hnh e l 1s22s22p6. So snh bn knh ca X, Y, Xn+ v Y- ? A. Xn+ < Y < Y- < X. B. Xn+ < Y < X < Y- C. Xn+ < X < Y < Y- D. Y < Xn+ < X < YCu 2: Cc pht biu : (1). Cc nhm A bao gm cc nguyn t s v nguyn t p. (2). Trong mt chu k, bn knh nguyn t kim loi nh hn bn knh nguyn t phi kim. (3). Cc kim loi thng c nh kim do cc electron t do phn x nh sng nhn thy c. (4). m in ca brom ln hn m in ca iot. (5). Tnh axit ca HF mnh hn tnh axit ca HCl. (6). Tnh kh ca ion Br- mnh hn tnh kh ca ion Cl-. S pht biu ng l: A. 2 B. 3 C. 4 D. 5 Cu 3. Cho 22,925 gam gam hn hp AlCl3 v FeCl3 vi t l mol 1:2 tc dng vi dung dch Na2S d sau phn ng thu c bao nhiu gam kt ta: A. 10,5 gam B. 12,4 gam C. 10,4 gam D. 14,3 gam Cu 4. Dung dch X cha: HCO3, Ba2+, Na+ v 0,3 mol Cl. Cho dung dch X tc dng vi dung dch NaOH d, kt thc cc phn ng thu c 9,85 gam kt ta. Mt khc, cho lng d dung dch NaHSO4 vo dung dch X cn li, sau phn ng hon ton thu c 17,475 gam kt ta. Nu un nng ton b lng X trn ti phn ng hon ton, lc b kt ta ri c cn nc lc th thu c bao nhiu gam mui khan ? A. 26,65 gam. B. 39,60 gam. C. 26,68 gam. D. 26,60 gam. Cu 5. Ha tan m gam P2O5 vo 500ml dung dch NaOH 1M, sau phn ng hon ton thu c dung dch X cha cht tan c nng CM bng nhau. Nu thm dung dch CaCl2 d vo X th sau phn ng trong dung dch ch cn mui Cl-. Hy tm m. A. 7,1 gam B. 28,4 gam C. 14,2g D. 21,3 gam Cu 6. Cho SO2 ln lt tc dng vi cc cht sau: BaO, dung dch Ca(OH) 2, dung dch BaCl2, H2S, O2, dung dch Br2, dung dch KMnO4, dung dch K2SO4, dung dch Na2SO3. S trng hp xy ra phn ng l (khng tnh phn ng gia SO2 vi H2O). A. 6. B. 7. C. 8. D. 9. Cu 7. Thc hin phn ng este ho 2 mol C2H5OH vi 1 mol HCOOH nhit khng i (xt H2SO4 c) khi h cn bng thu c 0,8 mol este. cng iu kin trn, este ho 1 mol C2H5OH v x mol HCOOH, khi h cn bng thu c 0,7 mol este. Gi tr ca x l: A. 2,225 B. 1,75 C. 1 D. 1,3125 Cu 8. Cho etan qua xt ( nhit cao) thu c mt hn hp X gm etan, etilen, axetilen v H2. T khi ca hn hp X i vi etan l 0,4. Hy cho bit nu cho 0,4 mol hn hp X qua dung dch Br2 d th s mol Br2 phn ng l bao nhiu? A. 0,24 mol B. 0,16 mol C. 0,40 mol D. 0,32 mol Cu 9. t chy 16,1 gam Na trong bnh cha y kh O2, sau mt thi gian thu c m gam hn hp rn Y gm Na2O, Na2O2 v Na d. Ho tan ht ton b lng Y trn vo nc nng, sinh ra 5,04 lt (ktc) hn hp kh Z, c t khi so vi He l 3. Gi tr ca m l A. 18,8. B. 21,7. C. 18,5. D. 21,4.

Cu 10. Hn hp X gm MgO, CaO, Mg v Ca. Ha tan 21,44 g hn hp X bng dung dch HCl va thu c 6,496 lit H2 ktc v dung dch Y trong c 24,7 g MgCl2 v x gam CaCl2. Gi tr ca x l: A. 29,97 B. 31,08 C. 32,19 D. 34,41 Cu 11. Nung 14,38 gam hn hp KClO3 v KMnO4 mt thi gian c hn hp cht rn A v 1,344 lt kh (ktc) thot ra. Cho dung dch HCl c d vo A n khi cc phn ng kt thc thy c 3,36 lt kh (ktc) thot ra (cho rng cc kh to thnh u thot ht khi dung dch). Thnh phn % khi lng ca KMnO4 trong hn hp ban u bng : A. 60%. B. 65,9%. C. 42,8% D. 34,1%. Cu 12. Cc pht biu sau (1). HI l cht c tnh kh, c th kh c H2SO4 n H2S. (2). Nguyn tc iu ch Cl2 l kh ion Cl- bng cc cht nh KMnO4, MnO2, KClO3 trong mi trng axit (3). Lu hunh t phng v n t l hai dng th hnh ca nhau. (4). HF va c tnh kh mnh, va c kh nng n mn thu tinh. (5). nhit cao, N2 c th ng vai tr l cht kh hoc cht oxi ha. (6). Dung dch Na2SO3 c th lm mt mu nc brom. S ph biu ng l A. 3 B. 4 C. 5 D. 6 Cu 13. Cho bt Al d vo dung dch Ba(OH) 2 thu c dung dch X. Cho X ln lt tc dng vi: CO 2 d, Na2CO3, NaHSO4 d, NH3, NaOH, HCl d, AlCl3, NH4Cl. S phn ng m to thnh kt ta sau phn ng l: A. 3. B. 2. C. 5. D. 4. Cu 14. Ha tan hon ton m gam hn hp X gm Na v K vo dung dch HCl d thu c dung dch Y. C cn dung dch Y thu c (m + 31,95) gam hn hp cht rn khan. Ha tan hon ton 2m gam hn hp X vo nc thu c dung dch Z. Cho t t ht dung dch Z vo 0,5 lt dung dch CrCl 3 1M n phn ng hon ton thu c kt ta c khi lng l A. 51,5 gam. B. 30,9 gam. C. 20,6 gam. D. 54,0 gam. Cu 15. Thc hin cc th nghim sau: (1) Cho rt t t dung dch Na2CO3 vo dung dch FeCl3 . (2) Cho rt t t dung dch cha 0,1mol HCl vo dung dch cha 0,1 mol Na2CO3 v 0,1 mol NaHCO3 . (3) Cho dung dch NaHSO4 vo dung dch Ca(HCO3)2. (4) Cho rt t t dung dch Na2S vo dung dch AlCl3 (5) . Cho dung dch NH4HSO4 vo dung dch Ca(HSO3)2. Th nghim c gii phng kh l A. (1), (2) (3) v (4). B. (1), (2) (3) v (5). C. (1) (2) (4) v (5). D. (1) (3) (4) v (5). Cu 16. Cho 7,65 gam hn hp X gm Mg v Fe vo 375 ml dung dch CuSO4 aM. Sau khi cc phn ng xy ra hon ton, lc, thu c 10,35 gam cht rn Y v dung dch Z. Thm dung dch NaOH d vo Z. Lc ly kt ta em nung ngoi khng kh n khi lng khng i c 6,75 gam cht rn. Gi tr ca a l A. 0,15. B. 0,2. C. 0,3. D. 0,25. Cu 17. Ha tan hon ton 19,2 gam hn hp X gm Fe, FeO, Fe3O4 v Fe2O3 trong 400 ml dung dch HNO3 3M (d) un nng, thu c dung dch Y v V lt kh NO (ktc) (sn phm kh duy nht). Cho 350 ml dung dch NaOH 2M vo dung dch Y thu c 21,4 gam kt ta. Gi tr ca V l: A. 3,36 lt. B. 5,04 lt. C. 5,60 lt. D. 4,48 lt. Cu 18. C cc phn ng sau: (1) poli(vinylclorua) +Cl2 (2) Cao su thin nhin + HCl (3) Cao su BuNa S + Br2 (4) poli(vinylclorua) + NaOH + (5) Amiloz + H2O (H ) (6) Xenluloz + HNO3 (H2SO4) Phn ng gi nguyn mch polime l A. (1), (2),(4),(6) B. (1), (2), (3),(6) C. (1), (2), (3), (4), (6) D. (1),(2),(3),(4),(5), (6) Cu 19: Hp th hon ton 3,36 lt CO2 (ktc) vo 100 ml dung dch gm K2CO3 0,2M v KOH x M, sau khi cc phn ng xy ra hon ton thu c dung dch Y. Cho ton b Y tc dng vi dung dch CaCl 2(d), thu c 5 gam kt ta. Gi tr ca x l: A. 1,2. B. 1,8. C. 3,4. D. 1,6.

Cu 20: Cho cc pht biu sau: (1). Ca(OH)2 c dng lm mt tnh cng vnh cu ca nc (2) Kh SO2 gy ra hin tng ma axit. (3) Khi c thi ra kh quyn, freon (ch yu l CFCl3 v CF2Cl2) ph hy tng ozon. (4). CrO3 tc dng vi nc to ra hn hp axit. (5). Tt c cc phn ng ca lu hunh vi kim loi u cn un nng. (6). Trong cng nghip, nhm c sn xut t qung olomit. (7). Kh CO2 gy ra hin tng hiu ng nh knh. S pht biu sai l A. 3. B. 1. C. 2. D. 4. Cu 21: Trong cc th nghim sau :
(1). Nhit phn KClO3 (xc tc MnO2) (2) Cho kh SO2 tc dng vi kh H2S. (3) Cho kh NH3 tc dng vi CuO un nng. (4) Cho CaOCl 2 tc dng vi dung dch HCl c. (5) Cho Si tc dng vi dung dch NaOH. (6) Cho kh O3 tc dng vi Ag. (7) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 un nng. (8) Cho SiO2 tc dng vi axit HF S th nghim to ra n cht l: A. 4 B. 7 C. 6 D. 5

Cu 22: in phn dung dich cha 0,2 mol NaCl va x mol Cu(NO3)2 (in cc tr,mang ngn xp) sau mt thi gian thu c dung dich X va khi lng dung dich giam 21,5 gam. Cho thanh st vao dung dich X n khi cac phan ng xay ra hoan toan thy khi lng thanh st giam 2,6 gam v thy thot ra kh NO duy nht. Gia tri ca x la: A. 0,3 B. 0,4 C. 0,2 D. 0,5 Cu 23. Thy phn 152 gam hh cc tripeptit thu c 159,2 gam hh X gm cc aminoaxit ch cha mt nhm -NH2 v mt nhm COOH. Cho 1/5 hh X tc dng vi dd KOH d, khi lng mui thu c l : A. 36,4gam B.182 gam C. 34,48gam D. 34,24 gam Cu 24: . Cho cc phat biu : (1) Phenol tham gia phn ng th brom v th nitro d hn benzen. (2). Khi un C2H5Br vi dung dich KOH chi thu c etilen (3). Dung dich phenol lam phenolphtalein khng mau chuyn thanh mau hng (4). Day cac cht : C2H5Cl, C2H5Br, C2H5I co nhit si tng dn t trai sang phai (5). un ancol etylic 1400C (xuc tac H2SO4 c) thu c imetyl ete (6) Phenol dng sn xut keo dn, cht dit nm mc. (7) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm. S pht biu ng l A. 2 B. 3 C. 4 D. 5 Cu 25: Hn hp A gm 1 axit no n chc mch h (X) v 1 axit khng no mch h 2 chc c 1 ni i C=C (Y) vi s mol bng nhau. t a mol hn hp A thu c 3a mol CO 2 v 2a mol H2O. Cho m gam hn hp A tc dng vi 400 ml dung dch NaOH 1M (d) thu c dg dch cha (m+10,06) gam cht tan. Gi tr ca m l: A. 20,04 B. 22,36 C. 14,24 D. 19,36 Cu 26: X v Y l 2 cht hu c c 5C, mch nhnh v h. Nu hidro ha X hoc Y thu c 3-metyl butan-1ol. Nu oxi ha X bng CuO,to thu c cht hu c Z l ng phn ca Y. S cp X,Y tha mn l: A. 1 B. 2 C. 3 D. 4 Cu 27: Cho m gam hn hp 2 amino axit (trong phn t ch cha 1 nhm amino v 1 nhm cacboxyl) tc dng vi 100 ml dung dch HCl 2,2M thu c dung dch X. phn ng ht vi cc cht trong dung dch X cn dng 100 gam dung dch NaOH 16,8% thu c dung dch Y. C cn dung dch Y thu c 34,37 gam cht rn khan. Gi tr ca m l: A. 18,1 gam B. 17,1 gam C. 15,1 gam D. 16,1 gam Cu 28: Oxi ha anehit X n chc bng O 2 (xc tc thch hp) vi hiu sut phn ng l 75% thu c hn hp Y gm axit cacboxylic tng ng v anehit d. Trung ha axit trong hn hp Y cn 100 ml dung dch NaOH 0,75M ri c cn dung dch sau phn ng thu c 5,1 gam cht rn khan. Nu cho hn hp Y tc dng hon ton vi dung dch AgNO3 trong NH3 d, un nng th thu c khi lng Ag l: A.5,4 gam. B. 21,6 gam. C. 10,8 gam. D. 27,0 gam.

Cu 29: t chy hon ton m gam mt cht bo (triglixerit) cn 1,61 mol O2, sinh ra 1,14 mol CO2 v 1,06 mol H2O. Cng m gam cht bo ny tc dng va vi dung dch NaOH th khi lng mui to thnh l : A. 23,00 gam. B. 20,28 gam. C. 18,28 gam. D. 16,68 gam. Cu 30. Cho cc pht biu sau: (1) Tt c cc axit cacboxylic u khng tham gia phn ng trng bc; (2) Phn ng thy phn este trong mi trng axit l phn ng thun nghch; (3) Tt c cc ancol no, a chc u ha tan c Cu(OH)2. (4) Lin kt ha hc ch yu trong hp cht hu c l lin kt cng ha tr. (5) Nhng hp cht hu c khc nhau c cng phn t khi l ng phn ca nhau (6) Trong thnh phn hp cht hu c nht thit phi c cacbon. (7) Khi t chy hton mt hirocacbon X bt k, nu thu c s mol CO2 bng s mol H2O th X l anken. S pht biu ng l A. 4 B. 3 C. 2 D. 5 Cu 31. Cho dd cha m g hn hp gm phenol v axit axetic tc dng va vi nc Br2 thu c dd X v 33,1g 2,4,6-tribromphenol. Trung ha hon ton X cn va 500 ml dd NaOH 1M. Gi tr ca m l: A.33,4 B. 24,8 C. 21,4 D. 39,4 Cu 32: Hp cht hu c X mch h, c cng thc phn t C4H8O3. Cho a mol X tc dng ht vi dung dch NaHCO3, sinh ra a mol CO2. Cng a mol X phn ng ht vi Na, thu c a mol H2. S cng thc cu to tho mn iu kin trn ca X l A. 5. B. 4. C. 9. D. 6. Cu 33. Trong s cc cu sau: (1) Cc cht: amoniac, etylamin, hiro, ancol metylic u kh c ng (II) oxit khi nung nng. (2) Propen v xiclopropan khi cng brom u cho cng mt sn phm. (3) Cc cht rn: km hiroxit, bc oxit, bc clorua u tan c trong dung dch amoniac m c. (4) Khi cho dung dch natri stearat vo dung dch canxi hirocacbonat c kt ta to thnh. (5) Stiren v toluen u c kh nng lm mt mu dung dch thuc tm iu kin thch hp. S cu ng l A. 3. B. 5. C. 4. D. 2. Cu 34. Trong s cc cht: clobenzen, toluen, nitrobenzen, anilin, phenol, axit benzoic, benzanehit, naphtalen, p-xilen, cumen, p-crezol,s cht tham gia phn ng th nhn thm d hn so vi benzen l A. 7. B. 9. C. 8. D. 6. Cu 35: C cc cht: Fe, dung dch FeCl 2, dung dch HCl, dung dch Fe(NO3)2, dung dch FeCl3, dung dch AgNO3. Cho tng cp cht phn ng vi nhau th s trng hp xy ra phn ng l: A. 5. B. 4. C. 8. D. 6. Cu 36: Cho hai cht hu c X v Y c cng cng thc phn t C 3H7O2N. X v Y thc hin cc chuyn ho sau: +[ H ] +HCl +NaOH X amin vY Z C3H6O2NNa. Tng s ng phn ca X v Y tha mn l: A. 5 B. 6 C. 2 D. 4 Cu 37: Dy gm cc cht u b thu phn trong dung dch NaOH long, nng l A. vinyl axetat, anlyl clorua, benzyl bromua, nilon-6, triolein. B. tristearin, vinyl clorua, phenyl bromua, nilon-6,6, acrilonitrin. C. saccaroz, anlyl clorua, metyl bromua, nilon-6,6, cao su buna. D. metyl axetat, vinyl clorua, benzyl bromua, nilon-7, peptit. Cu 38. Hn hp M gm anken X v 2 amin no n chc mch h Y v Z (M Y < MZ). t chy hon ton mt lng M cn dng 21 lt O2 sinh ra 11,2 lt CO2 (ktc). Cng thc ca Y l: A. CH3CH2CH2NH2 B. CH3CH2NHCH3 C. CH3NH2 D. C2H5NH2 Cu 39. Hn hp A gm X, Y (MX < MY) l hai este n chc c chung gc axit. un nng m gam A vi 400 ml dung dch KOH 1M d thu c dun dch B v (m 12,6) gam hn hp hai anehit no, n chc ng ng k tip c t khi hi so vi H2 l 26,2. C cn dung dch B thu c (m + 6,68) gam cht rn khan. Phn trm khi lng ca Y trong A l: A. 64,66% B. 35,34% C. 63,56% D. 36,44%

Cu 40. Cho m gam bt Fe tc dng ht vi dung dch HNO3 long, thu c dung dch X v kh NO (sn phm kh duy
nht). C cn dung dch X thu 51,2 gam mui khan. Bit s mol Fe ban u bng 31,25% s mol HNO 3 phn ng. Gi tr m l: A. 14 B. 10,36 C. 20,27 D. 28

II. PHN RING (Th sinh ch c chn mt trong hai phn sau: phn A hoc phn B) A. Theo chng trnh Chun (10 cu: T cu 41 n cu 50) Cu 41. Cho m (g) Cu v Fe2O3 tan va ht trong dung dch HCl 18,25% thu c dung dch X ch gm 2 mui. C cn dung dch X thu c 58,35g mui khan. Nng % ca CuCl2 trong dung dch l : A. 11,2% B. 8,42% C. 10,26% D. 9,48% Cu 42: Hn hp M gm anehit X, xeton Y (X, Y c cng s nguyn t cacbon) v anken Z. t chy hon ton m gam M cn dng 8,848 lt O2 (ktc) sinh ra 6,496 lt CO2 (ktc) v 5,22 gam H2O. Cng thc ca anehit X l A. C2H5CHO B. CH3CHO C. C3H7CHO D. C4H9CHO Cu 43: Cho dy cc cht: but-2-en, axit acrylic, propilen, ancol anlylic, 2-metylhex-3-en, axit oleic, hexa-1,4ien, stiren. S cht trong dy c ng phn hnh hc l A. 4. B. 5. C. 6. D. 7. Cu 44. Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl, va tc dng c vi dung dch AgNO3? A. Zn, Cu, Mg. B. Al, Fe, FeCl2. C. Hg, Na, Ca. D. Fe, Ni, Fe(NO3)2. Cu 45. Cho cc th nghim sau : (1) t t dung dch (H+, Li+, Cl-,SO42-) d vo dung dch (Na+, Ba2+, HCO3-,HS-) (2) t t dung dch AlCl3 vo dung dch (Na+, K+, HCO3-, CO32-) (3) Cho 1 mu Na vo dung dch (Ba2+, Mg2+, Cl-, HCO3-) (4) Cho t t dung dch (NaOH, LiOH) d vo dung dch (NH4+, K+, PO42-,SO42-) (5) Cho t t AgNO3 d vo dung dch (Na+, K+, Cl-, CO32-, F-) S th nghim sau phn ng to mt kt ta v mt kh l A. 5 B. 4 C. 3 D. 2 Cu 46. : Cho cc nhn xt sau: (1). Trong in phn dung dch NaCl trn catot xy ra s oxi ho nc. (2). Khi nhng thanh Fe vo dung dch hn hp CuSO4 v H2SO4 th c bn Fe b n mn in ho. (3). Kh O3 c th gy c hi cho con ngi (4). Khi nhit k thy ngn b v th dng bt S rc ln thy ngn ri gom li. (5). Nguyn tc sn xut gang l kh qung st oxit bng than cc trong l cao. (6). Dung dch FeCl3 khng lm mt mu dung dch KMnO4 trong H2SO4 long S nhn xt ng l A. 2. B. 3. C. 4. D. 5. Cu 47. Cho phng trnh ion thu gn : a Zn + b NO3- + c OH- dZnO22- + eNH3 + g H2O Tng cc h s (s nguyn ti gin) ca cc cht tham gia phn ng (a + b + c) l : A. 12 B. 10 C. 9 D. 11 Cu 48: Thu phn 51,3 gam mantoz trong mi trng axit vi hiu sut phn ng t 80% thu c hn hp X. Trung ho X bng NaOH thu c dung dch Y. Cho Y tc dng ht vi lng d dung dch AgNO3 trong NH3 un nng, sinh ra m gam Ag. Gi tr ca m l A. 55,08. B. 51,84. C. 32,40. D. 58,32. Cu 49. Cho 7,8 lt dung dch Ba(OH)2 0,125M vo V lt dung dch Cr2(SO4)3 0,125M. Sau phn ng thu c 179,9 gam kt ta. Gi tr ca V l A. 1,8. B. 2,6. C. 1,6. D. 2,0. Cu 50: Trong s cc cht: Axetyl clorua, anhirit axetic, axit nitric, nc brom, kali hiroxit, axit axetic, anehit fomic. S cht phn ng c vi phenol l trong iu kin thch hp l: A. 7 B. 6 C. 5 D. 4

B. Theo chng trnh Nng cao (10 cu: T cu 51 n cu 60) Cu 51: Hn hp M gm xeton X v anken Y. t chy hon ton mt lng M cn dng va 12,32 lt O2 (ktc), sinh ra 8,96 lt CO2 (ktc) v 7,2 gam H2O. Cng thc cu to thu gn ca X l A. CH3COCH3. B. CH3COCH2CH3. C. CH3COCH2COCH3. D. CH3CH2COCH2CH3. Cu 52: Cho sut in ng chun ca cc pin in ho : E0 XY = 0,78V ; E0 X-Z= 1,24V ; E0 TY = 0,47V (X, Y, Z, T l bn kim loi). Khng nh no sau y l sai ? A. Sut in ng chun ca pin in ho X - T l 0,31V B. Tnh kh gim dn t tri qua phi theo dy : Z, Y, T, X. C. Trong cc pin in ho: X - Y, X - T v X - Z th X u b oxi ho. D. Trong pin in ho Y - Z th Y l anot. Cu 53: Dung dch Y gm CH3COOH 0,1M v HCl 0,005M. Bit 25oC Ka ca CH3COOH l 1,75.10-5. Gi tr pH ca dung dch Y 25oC l A. 2,27. B. 2,30. C. 1,77. D. 2,33. Cu 54: Cho mt ipeptit Y c cng thc phn t C6H12N2O3. S ng phn peptit ca Y (ch cha gc -amino axit) mch h l A. 5. B. 4. C. 7. D. 6. Cu 55. Cho cc pht biu sau: (1). Fe, Zn, Ni, Sn u tc dng c vi dung dch HCl v dung dch AgNO3. (2). Khi un nng trong khng kh, thic v ch tc dng vi O2 theo cng t l v s mol. (3). Bc v vng u b oxi ha trong hn hp (HNO3 + 3HCl c) . (4).Thm dung dch kim vo dung dch mui icromat thy dung dch chuyn t mu da cam sang mu vng (5). Sn(OH)2, Pb(OH)2, Al(OH)3, Cr(OH)3, Zn(OH)2 u c tnh cht lng tnh. (6). CrO3 l oxit axit v c tnh kh mnh. S pht biu ng : A. 3. B. 4. C.5. D.6. + Cu 56: Khi cho 100 ml dung dch Ba(OH)2 aM vo dung dch X cha x mol Na , y mol HCO3-, z mol CO32- v t mol SO42- th thu c lng kt ta ln nht. Gi tr ca a l A. 10(z + t). B. 10(z t). C. 5(x y). D. 5(x + y). Cu 57: Ancol bc ba, mch h X c cng thc phn t C5H10O. T X ngi ta thc hin s bin ho sau: +Br2 +NaOH X C5H10OBr2 C5H12O3 (cht Y). Dy cc cht u c th tc dng c vi Y l: A. Na, NaOH, v CH3COOH (xc tc H2SO4 c, to). B. NaHCO3, NaOH v Cu(OH)2. C. Na2O, NaHCO3, v CH3OH (xc tc H2SO4 c, to). D. Na, Cu(OH)2, v C2H5OH (xc tc H2SO4 c, to). Cu 58. T Glyxin v Alanin to hn hp cc ipeptit X. Cho 14,892g hn hp X phn ng va vi dung dch HCl un nng. Khi lng mui thu c sau phn ng l: A. 18,615g B. 24,174g C. 20,415g D. 23,338g Cu 59. phn bit cc kh sau (ng trong cc l ring bit): H2S, HCl, CO2, HI, c th dng A. dung dch KOH. B. dung dch AgNO3. C. dung dch NaBr. D. dung dch BaCl2. Cu 60. Cho 0,25 mol mt anehit mch h X phn ng vi lng d AgNO3/ NH3 thu c 54 gam Ag. Mt khc, khi
cho X tc dng vi H2 d (xc tc Ni, to) th 0,125 mol X phn ng ht vi 0,375 mol H2. Cht X c cng thc chung l: A. CnH2n-3CHO (n 2). B. CnH2n-1CHO (n 2). C. CnH2n(CHO)2 (n 0). D. CnH2n+1CHO (n 0).

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TRNG THPT CHUYN NGUYN BNH KHIM

M THI : 707
( thi c 6 trang) THI TH I HC NM HC 2012 2013 Mn thi: HA HC Thi gian lm bi 90 pht ( khng k thi gian giao ).

Cho bit nguyn t khi ca cc nguyn t: C = 12; H = 1; O = 16; N = 14; P = 31; S = 32; He = 4; Na = 23; K = 39; Ca = 40; Ba = 137; Al = 27; Zn = 65; Fe = 56; Cu = 64; Ag = 108; Cr = 52. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1. Cc pht biu sau (1). HI l cht c tnh kh, c th kh c H2SO4 n H2S. (2). Nguyn tc iu ch Cl2 l kh ion Cl- bng cc cht nh KMnO4, MnO2, KClO3 trong mi trng axit (3). Lu hunh t phng v n t l hai dng th hnh ca nhau. (4). HF va c tnh kh mnh, va c kh nng n mn thu tinh. (5). nhit cao, N2 c th ng vai tr l cht kh hoc cht oxi ha. (6). Dung dch Na2SO3 c th lm mt mu nc brom. S ph biu ng l A. 3 B. 4 C. 5 D. 6 Cu 2. Cho bt Al d vo dung dch Ba(OH) 2 thu c dung dch X. Cho X ln lt tc dng vi: CO 2 d, Na2CO3, NaHSO4 d, NH3, NaOH, HCl d, AlCl3, NH4Cl. S phn ng m to thnh kt ta sau phn ng l: A. 3. B. 2. C. 5. D. 4. Cu 3. Ha tan hon ton m gam hn hp X gm Na v K vo dung dch HCl d thu c dung dch Y. C cn dung dch Y thu c (m + 31,95) gam hn hp cht rn khan. Ha tan hon ton 2m gam hn hp X vo nc thu c dung dch Z. Cho t t ht dung dch Z vo 0,5 lt dung dch CrCl 3 1M n phn ng hon ton thu c kt ta c khi lng l A. 51,5 gam. B. 30,9 gam. C. 20,6 gam. D. 54,0 gam. Cu 4. Thc hin cc th nghim sau: (1) Cho rt t t dung dch Na2CO3 vo dung dch FeCl3 . (2) Cho rt t t dung dch cha 0,1mol HCl vo dung dch cha 0,1 mol Na2CO3 v 0,1 mol NaHCO3 . (3) Cho dung dch NaHSO4 vo dung dch Ca(HCO3)2. (4) Cho rt t t dung dch Na2S vo dung dch AlCl3 (5) Cho dung dch NH4HSO4 vo dung dch Ca(HSO3)2. Th nghim c gii phng kh l A. (1), (2) (3) v (4). B. (1), (2) (3) v (5). C. (1) (2) (4) v (5). D. (1) (3) (4) v (5). Cu 5. Cho 7,65 gam hn hp X gm Mg v Fe vo 375 ml dung dch CuSO4 aM. Sau khi cc phn ng xy ra hon ton, lc, thu c 10,35 gam cht rn Y v dung dch Z. Thm dung dch NaOH d vo Z. Lc ly kt ta em nung ngoi khng kh n khi lng khng i c 6,75 gam cht rn. Gi tr ca a l A. 0,15. B. 0,2. C. 0,3. D. 0,25. Cu 6. Ha tan hon ton 19,2 gam hn hp X gm Fe, FeO, Fe3O4 v Fe2O3 trong 400 ml dung dch HNO3 3M (d) un nng, thu c dung dch Y v V lt kh NO (ktc) (sn phm kh duy nht). Cho 350 ml dung dch NaOH 2M vo dung dch Y thu c 21,4 gam kt ta. Gi tr ca V l: A. 3,36 lt. B. 5,04 lt. C. 5,60 lt. D. 4,48 lt. Cu 7. C cc phn ng sau: (1) poli(vinylclorua) +Cl2 (2) Cao su thin nhin + HCl (3) Cao su BuNa S + Br2 (4) poli(vinylclorua) + NaOH (5) Amiloz + H2O (H+) (6) Xenluloz + HNO3 (H2SO4) Phn ng gi nguyn mch polime l A. (1), (2),(4),(6) B. (1), (2), (3),(6) C. (1), (2), (3), (4), (6) D. (1),(2),(3),(4),(5), (6)

Cu 8. Hp th hon ton 3,36 lt CO 2 (ktc) vo 100 ml dung dch gm K 2CO3 0,2M v KOH x M, sau khi cc phn ng xy ra hon ton thu c dung dch Y. Cho ton b Y tc dng vi dung dch CaCl 2(d), thu c 5 gam kt ta. Gi tr ca x l: A. 1,2. B. 1,8. C. 3,4. D. 1,6. Cu 9. Cho cc pht biu sau: (1). Ca(OH)2 c dng lm mt tnh cng vnh cu ca nc (2) Kh SO2 gy ra hin tng ma axit. (3) Khi c thi ra kh quyn, freon (ch yu l CFCl3 v CF2Cl2) ph hy tng ozon. (4). CrO3 tc dng vi nc to ra hn hp axit. (5). Tt c cc phn ng ca lu hunh vi kim loi u cn un nng. (6). Trong cng nghip, nhm c sn xut t qung olomit. (7). Kh CO2 gy ra hin tng hiu ng nh knh. S pht biu sai l A. 3. B. 1. C. 2. D. 4. Cu 10. Trong cc th nghim sau : (1). Nhit phn KClO3 (xc tc MnO2) (2) Cho kh SO2 tc dng vi kh H2S. (3) Cho kh NH3 tc dng vi CuO un nng. (4) Cho CaOCl2 tc dng vi dung dch HCl c. (5) Cho Si tc dng vi dung dch NaOH. (6) Cho kh O3 tc dng vi Ag. (7) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 un nng. (8) Cho SiO2 tc dng vi axit HF S th nghim to ra n cht l: A. 4 B. 7 C. 6 D. 5 Cu 11. in phn dung dich cha 0,2 mol NaCl va x mol Cu(NO3)2 (in cc tr,mang ngn xp) sau mt thi gian thu c dung dich X va khi lng dung dich giam 21,5 gam. Cho thanh st vao dung dich X n khi cac phan ng xay ra hoan toan thy khi lng thanh st giam 2,6 gam v thy thot ra kh NO duy nht. Gia tri ca x la: A. 0,3 B. 0,4 C. 0,2 D. 0,5 Cu 12. Thy phn 152 gam hh cc tripeptit thu c 159,2 gam hh X gm cc aminoaxit ch cha mt nhm -NH2 v mt nhm COOH. Cho 1/5 hh X tc dng vi dd KOH d, khi lng mui thu c l : A. 36,4gam B.182 gam C. 34,48gam D. 34,24 gam Cu 13. Cho cc phat biu : (1) Phenol tham gia phn ng th brom v th nitro d hn benzen. (2). Khi un C2H5Br vi dung dich KOH chi thu c etilen (3). Dung dich phenol lam phenolphtalein khng mau chuyn thanh mau hng (4). Day cac cht : C2H5Cl, C2H5Br, C2H5I co nhit si tng dn t trai sang phai (5). un ancol etylic 1400C (xuc tac H2SO4 c) thu c imetyl ete (6) Phenol dng sn xut keo dn, cht dit nm mc. (7) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm. S pht biu ng l A. 2 B. 3 C. 4 D. 5 Cu 14: Hn hp A gm 1 axit no n chc mch h (X) v 1 axit khng no mch h 2 chc c 1 ni i C=C (Y) vi s mol bng nhau. t a mol hn hp A thu c 3a mol CO 2 v 2a mol H2O. Cho m gam hn hp A tc dng vi 400 ml dung dch NaOH 1M (d) thu c dg dch cha (m+10,06) gam cht tan. Gi tr ca m l: A. 20,04 B. 22,36 C. 14,24 D. 19,36 Cu 15: X v Y l 2 cht hu c c 5C, mch nhnh v h. Nu hidro ha X hoc Y thu c 3-metyl butan-1ol. Nu oxi ha X bng CuO,to thu c cht hu c Z l ng phn ca Y. S cp X,Y tha mn l: A. 1 B. 2 C. 3 D. 4 Cu 16: Cho m gam hn hp 2 amino axit (trong phn t ch cha 1 nhm amino v 1 nhm cacboxyl) tc dng vi 100 ml dung dch HCl 2,2M thu c dung dch X. phn ng ht vi cc cht trong dung dch X cn dng 100 gam dung dch NaOH 16,8% thu c dung dch Y. C cn dung dch Y thu c 34,37 gam cht rn khan. Gi tr ca m l: A. 18,1 gam B. 17,1 gam C. 15,1 gam D. 16,1 gam

Cu 17: Oxi ha anehit X n chc bng O 2 (xc tc thch hp) vi hiu sut phn ng l 75% thu c hn hp Y gm axit cacboxylic tng ng v anehit d. Trung ha axit trong hn hp Y cn 100 ml dung dch NaOH 0,75M ri c cn dung dch sau phn ng thu c 5,1 gam cht rn khan. Nu cho hn hp Y tc dng hon ton vi dung dch AgNO3 trong NH3 d, un nng th thu c khi lng Ag l: A.5,4 gam. B. 21,6 gam. C. 10,8 gam. D. 27,0 gam. Cu 18: t chy hon ton m gam mt cht bo (triglixerit) cn 1,61 mol O2, sinh ra 1,14 mol CO2 v 1,06 mol H2O. Cng m gam cht bo ny tc dng va vi dung dch NaOH th khi lng mui to thnh l : A. 23,00 gam. B. 20,28 gam. C. 18,28 gam. D. 16,68 gam. Cu 19. Cho cc pht biu sau: (1) Tt c cc axit cacboxylic u khng tham gia phn ng trng bc; (2) Phn ng thy phn este trong mi trng axit l phn ng thun nghch; (3) Tt c cc ancol no, a chc u ha tan c Cu(OH)2. (4) Lin kt ha hc ch yu trong hp cht hu c l lin kt cng ha tr. (5) Nhng hp cht hu c khc nhau c cng phn t khi l ng phn ca nhau (6) Trong thnh phn hp cht hu c nht thit phi c cacbon. (7) Khi t chy hton mt hirocacbon X bt k, nu thu c s mol CO2 bng s mol H2O th X l anken. S pht biu ng l A. 4 B. 3 C. 2 D. 5 Cu 20. Cho dd cha m g hn hp gm phenol v axit axetic tc dng va vi nc Br2 thu c dd X v 33,1g 2,4,6-tribromphenol. Trung ha hon ton X cn va 500 ml dd NaOH 1M. Gi tr ca m l: A.33,4 B. 24,8 C. 21,4 D. 39,4 Cu 21: Hp cht hu c X mch h, c cng thc phn t C4H8O3. Cho a mol X tc dng ht vi dung dch NaHCO3, sinh ra a mol CO2. Cng a mol X phn ng ht vi Na, thu c a mol H2. S cng thc cu to tho mn iu kin trn ca X l A. 5. B. 4. C. 9. D. 6. Cu 22. Trong s cc cu sau: (1) Cc cht: amoniac, etylamin, hiro, ancol metylic u kh c ng (II) oxit khi nung nng. (2) Propen v xiclopropan khi cng brom u cho cng mt sn phm. (3) Cc cht rn: km hiroxit, bc oxit, bc clorua u tan c trong dung dch amoniac m c. (4) Khi cho dung dch natri stearat vo dung dch canxi hirocacbonat c kt ta to thnh. (5) Stiren v toluen u c kh nng lm mt mu dung dch thuc tm iu kin thch hp. S cu ng l A. 3. B. 5. C. 4. D. 2. Cu 23. Trong s cc cht: clobenzen, toluen, nitrobenzen, anilin, phenol, axit benzoic, benzanehit, naphtalen, p-xilen, cumen, p-crezol,s cht tham gia phn ng th nhn thm d hn so vi benzen l A. 7. B. 9. C. 8. D. 6. Cu 24: C cc cht: Fe, dung dch FeCl2, dung dch HCl, dung dch Fe(NO3)2, dung dch FeCl3, dung dch AgNO3. Cho tng cp cht phn ng vi nhau th s trng hp xy ra phn ng l: A. 5. B. 4. C. 8. D. 6. Cu 25: Cho hai cht hu c X v Y c cng cng thc phn t C 3H7O2N. X v Y thc hin cc chuyn ho sau: +[ H ] +HCl +NaOH X amin vY Z C3H6O2NNa. Tng s ng phn ca X v Y tha mn l: A. 5 B. 6 C. 2 D. 4 Cu 26: Dy gm cc cht u b thu phn trong dung dch NaOH long, nng l A. vinyl axetat, anlyl clorua, benzyl bromua, nilon-6, triolein. B. tristearin, vinyl clorua, phenyl bromua, nilon-6,6, acrilonitrin. C. saccaroz, anlyl clorua, metyl bromua, nilon-6,6, cao su buna. D. metyl axetat, vinyl clorua, benzyl bromua, nilon-7, peptit. Cu 27. Hn hp M gm anken X v 2 amin no n chc mch h Y v Z (M Y < MZ). t chy hon ton mt lng M cn dng 21 lt O2 sinh ra 11,2 lt CO2 (ktc). Cng thc ca Y l: A. CH3CH2CH2NH2 B. CH3CH2NHCH3 C. CH3NH2 D. C2H5NH2

Cu 28. Hn hp A gm X, Y (MX < MY) l hai este n chc c chung gc axit. un nng m gam A vi 400 ml dung dch KOH 1M d thu c dun dch B v (m 12,6) gam hn hp hai anehit no, n chc ng ng k tip c t khi hi so vi H2 l 26,2. C cn dung dch B thu c (m + 6,68) gam cht rn khan. Phn trm khi lng ca Y trong A l: A. 64,66% B. 35,34% C. 63,56% D. 36,44% Cu 29. Cho m gam bt Fe tc dng ht vi dung dch HNO3 long, thu c dung dch X v kh NO (sn phm kh duy
nht). C cn dung dch X thu 51,2 gam mui khan. Bit s mol Fe ban u bng 31,25% s mol HNO 3 phn ng. Gi tr m l: A. 14 B. 10,36 C. 20,27 D. 28

Cu 30. Nguyn t nguyn t X v Y to ion tng ng l X n+ v Y-. C Xn+, Y- u c cu hnh e l 1s22s22p6. So snh bn knh ca X, Y, Xn+ v Y- ? A. Xn+ < Y < Y- < X. B. Xn+ < Y < X < Y- C. Xn+ < X < Y < Y- D. Y < Xn+ < X < YCu 31. Cc pht biu : (1). Cc nhm A bao gm cc nguyn t s v nguyn t p. (2). Trong mt chu k, bn knh nguyn t kim loi nh hn bn knh nguyn t phi kim. (3). Cc kim loi thng c nh kim do cc electron t do phn x nh sng nhn thy c. (4). m in ca brom ln hn m in ca iot. (5). Tnh axit ca HF mnh hn tnh axit ca HCl. (6). Tnh kh ca ion Br- mnh hn tnh kh ca ion Cl-. S pht biu ng l: A. 2 B. 3 C. 4 D. 5 Cu 32. Cho 22,925 gam gam hn hp AlCl 3 v FeCl3 vi t l mol 1:2 tc dng vi dung dch Na 2S d sau phn ng thu c bao nhiu gam kt ta: A. 10,5 gam B. 12,4 gam C. 10,4 gam D. 14,3 gam Cu 33. Dung dch X cha: HCO3, Ba2+, Na+ v 0,3 mol Cl. Cho dung dch X tc dng vi dung dch NaOH d, kt thc cc phn ng thu c 9,85 gam kt ta. Mt khc, cho lng d dung dch NaHSO4 vo dung dch X cn li, sau phn ng hon ton thu c 17,475 gam kt ta. Nu un nng ton b lng X trn ti phn ng hon ton, lc b kt ta ri c cn nc lc th thu c bao nhiu gam mui khan ? A. 26,65 gam. B. 39,60 gam. C. 26,68 gam. D. 26,60 gam. Cu 34. Ha tan m gam P2O5 vo 500ml dung dch NaOH 1M, sau phn ng hon ton thu c dung dch X cha cht tan c nng CM bng nhau. Nu thm dung dch CaCl2 d vo X th sau phn ng trong dung dch ch cn mui Cl-. Hy tm m. A. 7,1 gam B. 28,4 gam C. 14,2g D. 21,3 gam Cu 35. Cho SO2 ln lt tc dng vi cc cht sau: BaO, dung dch Ca(OH) 2, dung dch BaCl2, H2S, O2, dung dch Br2, dung dch KMnO4, dung dch K2SO4, dung dch Na2SO3. S trng hp xy ra phn ng l (khng tnh phn ng gia SO2 vi H2O). A. 6. B. 7. C. 8. D. 9. Cu 36. Thc hin phn ng este ho 2 mol C2H5OH vi 1 mol HCOOH nhit khng i (xt H2SO4 c) khi h cn bng thu c 0,8 mol este. cng iu kin trn, este ho 1 mol C2H5OH v x mol HCOOH, khi h cn bng thu c 0,7 mol este. Gi tr ca x l: A. 2,225 B. 1,75 C. 1 D. 1,3125 Cu 37. Cho etan qua xt ( nhit cao) thu c mt hn hp X gm etan, etilen, axetilen v H2. T khi ca hn hp X i vi etan l 0,4. Hy cho bit nu cho 0,4 mol hn hp X qua dung dch Br2 d th s mol Br2 phn ng l bao nhiu? A. 0,24 mol B. 0,16 mol C. 0,40 mol D. 0,32 mol Cu 38. t chy 16,1 gam Na trong bnh cha y kh O2, sau mt thi gian thu c m gam hn hp rn Y gm Na2O, Na2O2 v Na d. Ho tan ht ton b lng Y trn vo nc nng, sinh ra 5,04 lt (ktc) hn hp kh Z, c t khi so vi He l 3. Gi tr ca m l A. 18,8. B. 21,7. C. 18,5. D. 21,4.

Cu 39.. Hn hp X gm MgO, CaO, Mg v Ca. Ha tan 21,44 g hn hp X bng dung dch HCl va thu c 6,496 lit H2 ktc v dung dch Y trong c 24,7 g MgCl2 v x gam CaCl2. Gi tr ca x l: A. 29,97 B. 31,08 C. 32,19 D. 34,41 Cu 40.. Nung 14,38 gam hn hp KClO3 v KMnO4 mt thi gian c hn hp cht rn A v 1,344 lt kh (ktc) thot ra. Cho dung dch HCl c d vo A n khi cc phn ng kt thc thy c 3,36 lt kh (ktc) thot ra (cho rng cc kh to thnh u thot ht khi dung dch). Thnh phn % khi lng ca KMnO4 trong hn hp ban u bng : A. 60%. B. 65,9%. C. 42,8% D. 34,1%. II. PHN RING (Th sinh ch c chn mt trong hai phn sau: phn A hoc phn B) A. Theo chng trnh Chun (10 cu: T cu 41 n cu 50) Cu 41. Cho cc th nghim sau : (1) t t dung dch (H+, Li+, Cl-,SO42-) d vo dung dch (Na+, Ba2+, HCO3-,HS-) (2) t t dung dch AlCl3 vo dung dch (Na+, K+, HCO3-, CO32-) (3) Cho 1 mu Na vo dung dch (Ba2+, Mg2+, Cl-, HCO3-) (4) Cho t t dung dch (NaOH, LiOH) d vo dung dch (NH4+, K+, PO42-,SO42-) (5) Cho t t AgNO3 d vo dung dch (Na+, K+, Cl-, CO32-, F-) S th nghim sau phn ng to mt kt ta v mt kh l A. 5 B. 4 C. 3 D. 2 Cu 42. Cho cc nhn xt sau: (1). Trong in phn dung dch NaCl trn catot xy ra s oxi ho nc. (2). Khi nhng thanh Fe vo dung dch hn hp CuSO4 v H2SO4 th c bn Fe b n mn in ho. (3). Kh O3 c th gy c hi cho con ngi (4). Khi nhit k thy ngn b v th dng bt S rc ln thy ngn ri gom li. (5). Nguyn tc sn xut gang l kh qung st oxit bng than cc trong l cao. (6). Dung dch FeCl3 khng lm mt mu dung dch KMnO4 trong H2SO4 long S nhn xt ng l A. 2. B. 3. C. 4. D. 5. Cu 43. Cho phng trnh ion thu gn : a Zn + b NO3- + c OH- dZnO22- + eNH3 + g H2O Tng cc h s (s nguyn ti gin) ca cc cht tham gia phn ng (a + b + c) l : A. 12 B. 10 C. 9 D. 11 Cu 44: Thu phn 51,3 gam mantoz trong mi trng axit vi hiu sut phn ng t 80% thu c hn hp X. Trung ho X bng NaOH thu c dung dch Y. Cho Y tc dng ht vi lng d dung dch AgNO3 trong NH3 un nng, sinh ra m gam Ag. Gi tr ca m l A. 55,08. B. 51,84. C. 32,40. D. 58,32. Cu 45. Cho 7,8 lt dung dch Ba(OH)2 0,125M vo V lt dung dch Cr2(SO4)3 0,125M. Sau phn ng thu c 179,9 gam kt ta. Gi tr ca V l A. 1,8. B. 2,6. C. 1,6. D. 2,0. Cu 46: Trong s cc cht: Axetyl clorua, anhirit axetic, axit nitric, nc brom, kali hiroxit, axit axetic, anehit fomic. S cht phn ng c vi phenol l trong iu kin thch hp l: A. 7 B. 6 C. 5 D. 4 Cu 47. Cho m (g) Cu v Fe2O3 tan va ht trong dung dch HCl 18,25% thu c dung dch X ch gm 2 mui. C cn dung dch X thu c 58,35g mui khan. Nng % ca CuCl2 trong dung dch l : A. 11,2% B. 8,42% C. 10,26% D. 9,48% Cu 48: Hn hp M gm anehit X, xeton Y (X, Y c cng s nguyn t cacbon) v anken Z. t chy hon ton m gam M cn dng 8,848 lt O2 (ktc) sinh ra 6,496 lt CO2 (ktc) v 5,22 gam H2O. Cng thc ca anehit X l A. C2H5CHO B. CH3CHO C. C3H7CHO D. C4H9CHO Cu 49: Cho dy cc cht: but-2-en, axit acrylic, propilen, ancol anlylic, 2-metylhex-3-en, axit oleic, hexa-1,4ien, stiren. S cht trong dy c ng phn hnh hc l A. 4. B. 5. C. 6. D. 7.

Cu 50. Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl, va tc dng c vi dung dch AgNO3? A. Zn, Cu, Mg. B. Al, Fe, FeCl2. C. Hg, Na, Ca. D. Fe, Ni, Fe(NO3)2. B. Theo chng trnh Nng cao (10 cu: T cu 51 n cu 60) Cu 51. Cho cc pht biu sau: (1). Fe, Zn, Ni, Sn u tc dng c vi dung dch HCl v dung dch AgNO3. (2). Khi un nng trong khng kh, thic v ch tc dng vi O2 theo cng t l v s mol. (3). Bc v vng u b oxi ha trong hn hp (HNO3 + 3HCl c) . (4).Thm dung dch kim vo dung dch mui icromat thy dung dch chuyn t mu da cam sang mu vng (5). Sn(OH)2, Pb(OH)2, Al(OH)3, Cr(OH)3, Zn(OH)2 u c tnh cht lng tnh. (6). CrO3 l oxit axit v c tnh kh mnh. S pht biu ng : A. 3. B. 4. C.5. D.6. + Cu 52: Khi cho 100 ml dung dch Ba(OH)2 aM vo dung dch X cha x mol Na , y mol HCO3-, z mol CO32- v t mol SO42- th thu c lng kt ta ln nht. Gi tr ca a l A. 10(z + t). B. 10(z t). C. 5(x y). D. 5(x + y). Cu 53: Ancol bc ba, mch h X c cng thc phn t C5H10O. T X ngi ta thc hin s bin ho sau: +Br2 +NaOH X C5H10OBr2 C5H12O3 (cht Y). Dy cc cht u c th tc dng c vi Y l: A. Na, NaOH, v CH3COOH (xc tc H2SO4 c, to). B. NaHCO3, NaOH v Cu(OH)2. C. Na2O, NaHCO3, v CH3OH (xc tc H2SO4 c, to). D. Na, Cu(OH)2, v C2H5OH (xc tc H2SO4 c, to). Cu 54. T Glyxin v Alanin to hn hp cc ipeptit X. Cho 14,892g hn hp X phn ng va vi dung dch HCl un nng. Khi lng mui thu c sau phn ng l: A. 18,615g B. 24,174g C. 20,415g D. 23,338g Cu 55. phn bit cc kh sau (ng trong cc l ring bit): H2S, HCl, CO2, HI, c th dng A. dung dch KOH. B. dung dch AgNO3. C. dung dch NaBr. D. dung dch BaCl2. Cu 56. Cho 0,25 mol mt anehit mch h X phn ng vi lng d AgNO3/ NH3 thu c 54 gam Ag. Mt khc, khi
cho X tc dng vi H2 d (xc tc Ni, to) th 0,125 mol X phn ng ht vi 0,375 mol H2. Cht X c cng thc chung l: A. CnH2n-3CHO (n 2). B. CnH2n-1CHO (n 2). C. CnH2n(CHO)2 (n 0). D. CnH2n+1CHO (n 0).

Cu 57: Hn hp M gm xeton X v anken Y. t chy hon ton mt lng M cn dng va 12,32 lt O2 (ktc), sinh ra 8,96 lt CO2 (ktc) v 7,2 gam H2O. Cng thc cu to thu gn ca X l A. CH3COCH3. B. CH3COCH2CH3. C. CH3COCH2COCH3. D. CH3CH2COCH2CH3. Cu 58: Cho sut in ng chun ca cc pin in ho : E0 XY = 0,78V ; E0 X-Z= 1,24V ; E0 TY = 0,47V (X, Y, Z, T l bn kim loi). Khng nh no sau y l sai ? A. Sut in ng chun ca pin in ho X - T l 0,31V B. Tnh kh gim dn t tri qua phi theo dy : Z, Y, T, X. C. Trong cc pin in ho: X - Y, X - T v X - Z th X u b oxi ho. D. Trong pin in ho Y - Z th Y l anot. Cu 59: Dung dch Y gm CH3COOH 0,1M v HCl 0,005M. Bit 25oC Ka ca CH3COOH l 1,75.10-5. Gi tr pH ca dung dch Y 25oC l A. 2,27. B. 2,30. C. 1,77. D. 2,33. Cu 60: Cho mt ipeptit Y c cng thc phn t C6H12N2O3. S ng phn peptit ca Y (ch cha gc -amino axit) mch h l A. 5. B. 4. C. 7. D. 6. ============================================================ TRNG THPT CHUYN NGUYN BNH KHIM

M THI : 303
( thi c 6 trang) THI TH I HC NM HC 2012 2013 Mn thi: HA HC Thi gian lm bi 90 pht ( khng k thi gian giao ).

Cho bit nguyn t khi ca cc nguyn t: C = 12; H = 1; O = 16; N = 14; P = 31; S = 32; He = 4; Na = 23; K = 39; Ca = 40; Ba = 137; Al = 27; Zn = 65; Fe = 56; Cu = 64; Ag = 108; Cr = 52. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Trong cc th nghim sau : (1). Nhit phn KClO3 (xc tc MnO2) (2) Cho kh SO2 tc dng vi kh H2S. (3) Cho kh NH3 tc dng vi CuO un nng. (4) Cho CaOCl2 tc dng vi dung dch HCl c. (5) Cho Si tc dng vi dung dch NaOH. (6) Cho kh O3 tc dng vi Ag. (7) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 un nng. (8) Cho SiO2 tc dng vi axit HF S th nghim to ra n cht l: A. 4 B. 7 C. 6 D. 5 Cu 2: in phn dung dich cha 0,2 mol NaCl va x mol Cu(NO3)2 (in cc tr,mang ngn xp) sau mt thi gian thu c dung dich X va khi lng dung dich giam 21,5 gam. Cho thanh st vao dung dich X n khi cac phan ng xay ra hoan toan thy khi lng thanh st giam 2,6 gam v thy thot ra kh NO duy nht. Gia tri ca x la: A. 0,3 B. 0,4 C. 0,2 D. 0,5 Cu 3. Thy phn 152 gam hh cc tripeptit thu c 159,2 gam hh X gm cc aminoaxit ch cha mt nhm -NH2 v mt nhm COOH. Cho 1/5 hh X tc dng vi dd KOH d, khi lng mui thu c l : A. 36,4gam B.182 gam C. 34,48gam D. 34,24 gam Cu 4: Cho cc phat biu : (1) Phenol tham gia phn ng th brom v th nitro d hn benzen. (2). Khi un C2H5Br vi dung dich KOH chi thu c etilen (3). Dung dich phenol lam phenolphtalein khng mau chuyn thanh mau hng (4). Day cac cht : C2H5Cl, C2H5Br, C2H5I co nhit si tng dn t trai sang phai (5). un ancol etylic 1400C (xuc tac H2SO4 c) thu c imetyl ete (6) Phenol dng sn xut keo dn, cht dit nm mc. (7) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm. S pht biu ng l A. 2 B. 3 C. 4 D. 5 Cu 5: Hn hp A gm 1 axit no n chc mch h (X) v 1 axit khng no mch h 2 chc c 1 ni i C=C (Y) vi s mol bng nhau. t a mol hn hp A thu c 3a mol CO 2 v 2a mol H2O. Cho m gam hn hp A tc dng vi 400 ml dung dch NaOH 1M (d) thu c dg dch cha (m+10,06) gam cht tan. Gi tr ca m l: A. 20,04 B. 22,36 C. 14,24 D. 19,36 Cu 6: X v Y l 2 cht hu c c 5C, mch nhnh v h. Nu hidro ha X hoc Y thu c 3-metyl butan-1ol. Nu oxi ha X bng CuO,to thu c cht hu c Z l ng phn ca Y. S cp X,Y tha mn l: A. 1 B. 2 C. 3 D. 4 Cu 7: Cho m gam hn hp 2 amino axit (trong phn t ch cha 1 nhm amino v 1 nhm cacboxyl) tc dng vi 100 ml dung dch HCl 2,2M thu c dung dch X. phn ng ht vi cc cht trong dung dch X cn dng 100 gam dung dch NaOH 16,8% thu c dung dch Y. C cn dung dch Y thu c 34,37 gam cht rn khan. Gi tr ca m l: A. 18,1 gam B. 17,1 gam C. 15,1 gam D. 16,1 gam Cu 8: Oxi ha anehit X n chc bng O2 (xc tc thch hp) vi hiu sut phn ng l 75% thu c hn hp Y gm axit cacboxylic tng ng v anehit d. Trung ha axit trong hn hp Y cn 100 ml dung dch

NaOH 0,75M ri c cn dung dch sau phn ng thu c 5,1 gam cht rn khan. Nu cho hn hp Y tc dng hon ton vi dung dch AgNO3 trong NH3 d, un nng th thu c khi lng Ag l: A.5,4 gam. B. 21,6 gam. C. 10,8 gam. D. 27,0 gam. Cu 9: t chy hon ton m gam mt cht bo (triglixerit) cn 1,61 mol O 2, sinh ra 1,14 mol CO 2 v 1,06 mol H2O. Cng m gam cht bo ny tc dng va vi dung dch NaOH th khi lng mui to thnh l : A. 23,00 gam. B. 20,28 gam. C. 18,28 gam. D. 16,68 gam. Cu 10. Cho cc pht biu sau: (1) Tt c cc axit cacboxylic u khng tham gia phn ng trng bc; (2) Phn ng thy phn este trong mi trng axit l phn ng thun nghch; (3) Tt c cc ancol no, a chc u ha tan c Cu(OH)2. (4) Lin kt ha hc ch yu trong hp cht hu c l lin kt cng ha tr. (5) Nhng hp cht hu c khc nhau c cng phn t khi l ng phn ca nhau (6) Trong thnh phn hp cht hu c nht thit phi c cacbon. (7) Khi t chy hton mt hirocacbon X bt k, nu thu c s mol CO2 bng s mol H2O th X l anken. S pht biu ng l A. 4 B. 3 C. 2 D. 5 Cu 11. Cho dd cha m g hn hp gm phenol v axit axetic tc dng va vi nc Br2 thu c dd X v 33,1g 2,4,6-tribromphenol. Trung ha hon ton X cn va 500 ml dd NaOH 1M. Gi tr ca m l: A.33,4 B. 24,8 C. 21,4 D. 39,4 Cu 12: Hp cht hu c X mch h, c cng thc phn t C4H8O3. Cho a mol X tc dng ht vi dung dch NaHCO3, sinh ra a mol CO2. Cng a mol X phn ng ht vi Na, thu c a mol H2. S cng thc cu to tho mn iu kin trn ca X l A. 5. B. 4. C. 9. D. 6. Cu 13. Trong s cc cu sau: (1) Cc cht: amoniac, etylamin, hiro, ancol metylic u kh c ng (II) oxit khi nung nng. (2) Propen v xiclopropan khi cng brom u cho cng mt sn phm. (3) Cc cht rn: km hiroxit, bc oxit, bc clorua u tan c trong dung dch amoniac m c. (4) Khi cho dung dch natri stearat vo dung dch canxi hirocacbonat c kt ta to thnh. (5) Stiren v toluen u c kh nng lm mt mu dung dch thuc tm iu kin thch hp. S cu ng l A. 3. B. 5. C. 4. D. 2. Cu 14. Trong s cc cht: clobenzen, toluen, nitrobenzen, anilin, phenol, axit benzoic, benzanehit, naphtalen, p-xilen, cumen, p-crezol,s cht tham gia phn ng th nhn thm d hn so vi benzen l A. 7. B. 9. C. 8. D. 6. Cu 15: C cc cht: Fe, dung dch FeCl 2, dung dch HCl, dung dch Fe(NO3)2, dung dch FeCl3, dung dch AgNO3. Cho tng cp cht phn ng vi nhau th s trng hp xy ra phn ng l: A. 5. B. 4. C. 8. D. 6. Cu 16: Cho hai cht hu c X v Y c cng cng thc phn t C 3H7O2N. X v Y thc hin cc chuyn ho +[ H ] +HCl +NaOH sau: X amin vY Z C3H6O2NNa. Tng s ng phn ca X v Y tha mn l: A. 5 B. 6 C. 2 D. 4 Cu 17: Dy gm cc cht u b thu phn trong dung dch NaOH long, nng l A. vinyl axetat, anlyl clorua, benzyl bromua, nilon-6, triolein. B. tristearin, vinyl clorua, phenyl bromua, nilon-6,6, acrilonitrin. C. saccaroz, anlyl clorua, metyl bromua, nilon-6,6, cao su buna. D. metyl axetat, vinyl clorua, benzyl bromua, nilon-7, peptit. Cu 18. Hn hp M gm anken X v 2 amin no n chc mch h Y v Z (M Y < MZ). t chy hon ton mt lng M cn dng 21 lt O2 sinh ra 11,2 lt CO2 (ktc). Cng thc ca Y l: A. CH3CH2CH2NH2 B. CH3CH2NHCH3 C. CH3NH2 D. C2H5NH2 Cu 19. Hn hp A gm X, Y (MX < MY) l hai este n chc c chung gc axit. un nng m gam A vi 400 ml dung dch KOH 1M d thu c dun dch B v (m 12,6) gam hn hp hai anehit no, n chc ng ng k tip c t khi hi so vi H2 l 26,2. C cn dung dch B thu c (m + 6,68) gam cht rn khan. Phn trm

khi lng ca Y trong A l: A. 64,66% B. 35,34% C. 63,56% D. 36,44% Cu 20. Cho m gam bt Fe tc dng ht vi dung dch HNO3 long, thu c dung dch X v kh NO (sn phm kh duy
nht). C cn dung dch X thu 51,2 gam mui khan. Bit s mol Fe ban u bng 31,25% s mol HNO 3 phn ng. Gi tr m l: A. 14 B. 10,36 C. 20,27 D. 28

Cu 21. Nguyn t nguyn t X v Y to ion tng ng l X n+ v Y-. C Xn+, Y- u c cu hnh e l 1s22s22p6. So snh bn knh ca X, Y, Xn+ v Y- ? A. Xn+ < Y < Y- < X. B. Xn+ < Y < X < Y- C. Xn+ < X < Y < Y- D. Y < Xn+ < X < YCu 22: Cc pht biu : (1). Cc nhm A bao gm cc nguyn t s v nguyn t p. (2). Trong mt chu k, bn knh nguyn t kim loi nh hn bn knh nguyn t phi kim. (3). Cc kim loi thng c nh kim do cc electron t do phn x nh sng nhn thy c. (4). m in ca brom ln hn m in ca iot. (5). Tnh axit ca HF mnh hn tnh axit ca HCl. (6). Tnh kh ca ion Br- mnh hn tnh kh ca ion Cl-. S pht biu ng l: A. 2 B. 3 C. 4 D. 5 Cu 23. Cho 22,925 gam gam hn hp AlCl 3 v FeCl3 vi t l mol 1:2 tc dng vi dung dch Na 2S d sau phn ng thu c bao nhiu gam kt ta: A. 10,5 gam B. 12,4 gam C. 10,4 gam D. 14,3 gam Cu 24. Dung dch X cha: HCO3, Ba2+, Na+ v 0,3 mol Cl. Cho dung dch X tc dng vi dung dch NaOH d, kt thc cc phn ng thu c 9,85 gam kt ta. Mt khc, cho lng d dung dch NaHSO4 vo dung dch X cn li, sau phn ng hon ton thu c 17,475 gam kt ta. Nu un nng ton b lng X trn ti phn ng hon ton, lc b kt ta ri c cn nc lc th thu c bao nhiu gam mui khan ? A. 26,65 gam. B. 39,60 gam. C. 26,68 gam. D. 26,60 gam. Cu 25. Ha tan m gam P2O5 vo 500ml dung dch NaOH 1M, sau phn ng hon ton thu c dung dch X cha cht tan c nng CM bng nhau. Nu thm dung dch CaCl2 d vo X th sau phn ng trong dung dch ch cn mui Cl-. Hy tm m. A. 7,1 gam B. 28,4 gam C. 14,2g D. 21,3 gam Cu 26. Cho SO2 ln lt tc dng vi cc cht sau: BaO, dung dch Ca(OH) 2, dung dch BaCl2, H2S, O2, dung dch Br2, dung dch KMnO4, dung dch K2SO4, dung dch Na2SO3. S trng hp xy ra phn ng l (khng tnh phn ng gia SO2 vi H2O). A. 6. B. 7. C. 8. D. 9. Cu 27. Thc hin phn ng este ho 2 mol C2H5OH vi 1 mol HCOOH nhit khng i (xt H2SO4 c) khi h cn bng thu c 0,8 mol este. cng iu kin trn, este ho 1 mol C2H5OH v x mol HCOOH, khi h cn bng thu c 0,7 mol este. Gi tr ca x l: A. 2,225 B. 1,75 C. 1 D. 1,3125 Cu 28. Cho etan qua xt ( nhit cao) thu c mt hn hp X gm etan, etilen, axetilen v H2. T khi ca hn hp X i vi etan l 0,4. Hy cho bit nu cho 0,4 mol hn hp X qua dung dch Br2 d th s mol Br2 phn ng l bao nhiu? A. 0,24 mol B. 0,16 mol C. 0,40 mol D. 0,32 mol Cu 29. t chy 16,1 gam Na trong bnh cha y kh O2, sau mt thi gian thu c m gam hn hp rn Y gm Na2O, Na2O2 v Na d. Ho tan ht ton b lng Y trn vo nc nng, sinh ra 5,04 lt (ktc) hn hp kh Z, c t khi so vi He l 3. Gi tr ca m l A. 18,8. B. 21,7. C. 18,5. D. 21,4. Cu 30. Hn hp X gm MgO, CaO, Mg v Ca. Ha tan 21,44 g hn hp X bng dung dch HCl va thu c 6,496 lit H2 ktc v dung dch Y trong c 24,7 g MgCl2 v x gam CaCl2. Gi tr ca x l: A. 29,97 B. 31,08 C. 32,19 D. 34,41 Cu 31. Nung 14,38 gam hn hp KClO3 v KMnO4 mt thi gian c hn hp cht rn A v 1,344 lt kh

(ktc) thot ra. Cho dung dch HCl c d vo A n khi cc phn ng kt thc thy c 3,36 lt kh (ktc) thot ra (cho rng cc kh to thnh u thot ht khi dung dch). Thnh phn % khi lng ca KMnO4 trong hn hp ban u bng : A. 60%. B. 65,9%. C. 42,8% D. 34,1%. Cu 32. Cc pht biu sau (1). HI l cht c tnh kh, c th kh c H2SO4 n H2S. (2). Nguyn tc iu ch Cl2 l kh ion Cl- bng cc cht nh KMnO4, MnO2, KClO3 trong mi trng axit (3). Lu hunh t phng v n t l hai dng th hnh ca nhau. (4). HF va c tnh kh mnh, va c kh nng n mn thu tinh. (5). nhit cao, N2 c th ng vai tr l cht kh hoc cht oxi ha. (6). Dung dch Na2SO3 c th lm mt mu nc brom. S ph biu ng l A. 3 B. 4 C. 5 D. 6 Cu 33. Cho bt Al d vo dung dch Ba(OH) 2 thu c dung dch X. Cho X ln lt tc dng vi: CO 2 d, Na2CO3, NaHSO4 d, NH3, NaOH, HCl d, AlCl3, NH4Cl. S phn ng m to thnh kt ta sau phn ng l: A. 3. B. 2. C. 5. D. 4. Cu 34. Ha tan hon ton m gam hn hp X gm Na v K vo dung dch HCl d thu c dung dch Y. C cn dung dch Y thu c (m + 31,95) gam hn hp cht rn khan. Ha tan hon ton 2m gam hn hp X vo nc thu c dung dch Z. Cho t t ht dung dch Z vo 0,5 lt dung dch CrCl 3 1M n phn ng hon ton thu c kt ta c khi lng l A. 51,5 gam. B. 30,9 gam. C. 20,6 gam. D. 54,0 gam. Cu 35. Thc hin cc th nghim sau: (1) Cho rt t t dung dch Na2CO3 vo dung dch FeCl3 . (2) Cho rt t t dung dch cha 0,1mol HCl vo dung dch cha 0,1 mol Na2CO3 v 0,1 mol NaHCO3 . (3) Cho dung dch NaHSO4 vo dung dch Ca(HCO3)2. (4) Cho rt t t dung dch Na2S vo dung dch AlCl3 (5) . Cho dung dch NH4HSO4 vo dung dch Ca(HSO3)2. Th nghim c gii phng kh l A. (1), (2) (3) v (4). B. (1), (2) (3) v (5). C. (1) (2) (4) v (5). D. (1) (3) (4) v (5). Cu 36. Cho 7,65 gam hn hp X gm Mg v Fe vo 375 ml dung dch CuSO4 aM. Sau khi cc phn ng xy ra hon ton, lc, thu c 10,35 gam cht rn Y v dung dch Z. Thm dung dch NaOH d vo Z. Lc ly kt ta em nung ngoi khng kh n khi lng khng i c 6,75 gam cht rn. Gi tr ca a l A. 0,15. B. 0,2. C. 0,3. D. 0,25. Cu 37. Ha tan hon ton 19,2 gam hn hp X gm Fe, FeO, Fe3O4 v Fe2O3 trong 400 ml dung dch HNO3 3M (d) un nng, thu c dung dch Y v V lt kh NO (ktc) (sn phm kh duy nht). Cho 350 ml dung dch NaOH 2M vo dung dch Y thu c 21,4 gam kt ta. Gi tr ca V l: A. 3,36 lt. B. 5,04 lt. C. 5,60 lt. D. 4,48 lt. Cu 38. C cc phn ng sau: (1) poli(vinylclorua) +Cl2 (2) Cao su thin nhin + HCl (3) Cao su BuNa S + Br2 (4) poli(vinylclorua) + NaOH + (5) Amiloz + H2O (H ) (6) Xenluloz + HNO3 (H2SO4) Phn ng gi nguyn mch polime l A. (1), (2),(4),(6) B. (1), (2), (3),(6) C. (1), (2), (3), (4), (6) D. (1),(2),(3),(4),(5), (6) Cu 39: Hp th hon ton 3,36 lt CO2 (ktc) vo 100 ml dung dch gm K2CO3 0,2M v KOH x M, sau khi cc phn ng xy ra hon ton thu c dung dch Y. Cho ton b Y tc dng vi dung dch CaCl 2(d), thu c 5 gam kt ta. Gi tr ca x l: A. 1,2. B. 1,8. C. 3,4. D. 1,6. Cu 40: Cho cc pht biu sau: (1). Ca(OH)2 c dng lm mt tnh cng vnh cu ca nc (2) Kh SO2 gy ra hin tng ma axit. (3) Khi c thi ra kh quyn, freon (ch yu l CFCl3 v CF2Cl2) ph hy tng ozon.

(4). CrO3 tc dng vi nc to ra hn hp axit. (5). Tt c cc phn ng ca lu hunh vi kim loi u cn un nng. (6). Trong cng nghip, nhm c sn xut t qung olomit. (7). Kh CO2 gy ra hin tng hiu ng nh knh. S pht biu sai l A. 3. B. 1. C. 2. D. 4. II. PHN RING (Th sinh ch c chn mt trong hai phn sau: phn A hoc phn B) A. Theo chng trnh Chun (10 cu: T cu 41 n cu 50) Cu 41. Cho phng trnh ion thu gn : a Zn + b NO3- + c OH- dZnO22- + eNH3 + g H2O Tng cc h s (s nguyn ti gin) ca cc cht tham gia phn ng (a + b + c) l : A. 12 B. 10 C. 9 D. 11 Cu 42: Thu phn 51,3 gam mantoz trong mi trng axit vi hiu sut phn ng t 80% thu c hn hp X. Trung ho X bng NaOH thu c dung dch Y. Cho Y tc dng ht vi lng d dung dch AgNO3 trong NH3 un nng, sinh ra m gam Ag. Gi tr ca m l A. 55,08. B. 51,84. C. 32,40. D. 58,32. Cu 43. Cho 7,8 lt dung dch Ba(OH)2 0,125M vo V lt dung dch Cr2(SO4)3 0,125M. Sau phn ng thu c 179,9 gam kt ta. Gi tr ca V l A. 1,8. B. 2,6. C. 1,6. D. 2,0. Cu 44: Trong s cc cht: Axetyl clorua, anhirit axetic, axit nitric, nc brom, kali hiroxit, axit axetic, anehit fomic. S cht phn ng c vi phenol l trong iu kin thch hp l: A. 7 B. 6 C. 5 D. 4 Cu 45. Cho m (g) Cu v Fe2O3 tan va ht trong dung dch HCl 18,25% thu c dung dch X ch gm 2 mui. C cn dung dch X thu c 58,35g mui khan. Nng % ca CuCl2 trong dung dch l : A. 11,2% B. 8,42% C. 10,26% D. 9,48% Cu 46: Hn hp M gm anehit X, xeton Y (X, Y c cng s nguyn t cacbon) v anken Z. t chy hon ton m gam M cn dng 8,848 lt O2 (ktc) sinh ra 6,496 lt CO2 (ktc) v 5,22 gam H2O. Cng thc ca anehit X l A. C2H5CHO B. CH3CHO C. C3H7CHO D. C4H9CHO Cu 47: Cho dy cc cht: but-2-en, axit acrylic, propilen, ancol anlylic, 2-metylhex-3-en, axit oleic, hexa-1,4ien, stiren. S cht trong dy c ng phn hnh hc l A. 4. B. 5. C. 6. D. 7. Cu 48. Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl, va tc dng c vi dung dch AgNO3? A. Zn, Cu, Mg. B. Al, Fe, FeCl2. C. Hg, Na, Ca. D. Fe, Ni, Fe(NO3)2. Cu 49. Cho cc th nghim sau : (1) t t dung dch (H+, Li+, Cl-,SO42-) d vo dung dch (Na+, Ba2+, HCO3-,HS-) (2) t t dung dch AlCl3 vo dung dch (Na+, K+, HCO3-, CO32-) (3) Cho 1 mu Na vo dung dch (Ba2+, Mg2+, Cl-, HCO3-) (4) Cho t t dung dch (NaOH, LiOH) d vo dung dch (NH4+, K+, PO42-,SO42-) (5) Cho t t AgNO3 d vo dung dch (Na+, K+, Cl-, CO32-, F-) S th nghim sau phn ng to mt kt ta v mt kh l A. 5 B. 4 C. 3 D. 2 Cu 50 Cho cc nhn xt sau: (1). Trong in phn dung dch NaCl trn catot xy ra s oxi ho nc. (2). Khi nhng thanh Fe vo dung dch hn hp CuSO4 v H2SO4 th c bn Fe b n mn in ho. (3). Kh O3 c th gy c hi cho con ngi (4). Khi nhit k thy ngn b v th dng bt S rc ln thy ngn ri gom li. (5). Nguyn tc sn xut gang l kh qung st oxit bng than cc trong l cao. (6). Dung dch FeCl3 khng lm mt mu dung dch KMnO4 trong H2SO4 long S nhn xt ng l A. 2. B. 3. C. 4. D. 5.

B. Theo chng trnh Nng cao (10 cu: T cu 51 n cu 60) Cu 51 T Glyxin v Alanin to hn hp cc ipeptit X. Cho 14,892g hn hp X phn ng va vi dung dch HCl un nng. Khi lng mui thu c sau phn ng l: A. 18,615g B. 24,174g C. 20,415g D. 23,338g Cu 52 phn bit cc kh sau (ng trong cc l ring bit): H2S, HCl, CO2, HI, c th dng A. dung dch KOH. B. dung dch AgNO3. C. dung dch NaBr. D. dung dch BaCl2. Cu 63 Cho 0,25 mol mt anehit mch h X phn ng vi lng d AgNO3/ NH3 thu c 54 gam Ag. Mt khc, khi
cho X tc dng vi H2 d (xc tc Ni, to) th 0,125 mol X phn ng ht vi 0,375 mol H2. Cht X c cng thc chung l: A. CnH2n-3CHO (n 2). B. CnH2n-1CHO (n 2). C. CnH2n(CHO)2 (n 0). D. CnH2n+1CHO (n 0).

Cu 54 Hn hp M gm xeton X v anken Y. t chy hon ton mt lng M cn dng va 12,32 lt O2 (ktc), sinh ra 8,96 lt CO2 (ktc) v 7,2 gam H2O. Cng thc cu to thu gn ca X l A. CH3COCH3. B. CH3COCH2CH3. C. CH3COCH2COCH3. D. CH3CH2COCH2CH3. Cu 55 Cho sut in ng chun ca cc pin in ho : E0 XY = 0,78V ; E0 X-Z= 1,24V ; E0 TY = 0,47V (X, Y, Z, T l bn kim loi). Khng nh no sau y l sai ? A. Sut in ng chun ca pin in ho X - T l 0,31V B. Tnh kh gim dn t tri qua phi theo dy : Z, Y, T, X. C. Trong cc pin in ho: X - Y, X - T v X - Z th X u b oxi ho. D. Trong pin in ho Y - Z th Y l anot. Cu 56 Dung dch Y gm CH3COOH 0,1M v HCl 0,005M. Bit 25 oC Ka ca CH3COOH l 1,75.10-5. Gi tr pH ca dung dch Y 25oC l A. 2,27. B. 2,30. C. 1,77. D. 2,33. Cu 57 Cho mt ipeptit Y c cng thc phn t C6H12N2O3. S ng phn peptit ca Y (ch cha gc -amino axit) mch h l A. 5. B. 4. C. 7. D. 6. Cu 58 Cho cc pht biu sau: (1). Fe, Zn, Ni, Sn u tc dng c vi dung dch HCl v dung dch AgNO3. (2). Khi un nng trong khng kh, thic v ch tc dng vi O2 theo cng t l v s mol. (3). Bc v vng u b oxi ha trong hn hp (HNO3 + 3HCl c) . (4).Thm dung dch kim vo dung dch mui icromat thy dung dch chuyn t mu da cam sang mu vng (5). Sn(OH)2, Pb(OH)2, Al(OH)3, Cr(OH)3, Zn(OH)2 u c tnh cht lng tnh. (6). CrO3 l oxit axit v c tnh kh mnh. S pht biu ng : A. 3. B. 4. C.5. D.6. + Cu 59 Khi cho 100 ml dung dch Ba(OH)2 aM vo dung dch X cha x mol Na , y mol HCO3-, z mol CO32- v t mol SO42- th thu c lng kt ta ln nht. Gi tr ca a l A. 10(z + t). B. 10(z t). C. 5(x y). D. 5(x + y). Cu 60Ancol bc ba, mch h X c cng thc phn t C5H10O. T X ngi ta thc hin s bin ho sau: +Br2 +NaOH X C5H10OBr2 C5H12O3 (cht Y). Dy cc cht u c th tc dng c vi Y l: A. Na, NaOH, v CH3COOH (xc tc H2SO4 c, to). B. NaHCO3, NaOH v Cu(OH)2. C. Na2O, NaHCO3, v CH3OH (xc tc H2SO4 c, to). D. Na, Cu(OH)2, v C2H5OH (xc tc H2SO4 c, to). ============================================================