BI TP V ANKEN

1) Khi t chy mt th tch hirocacbon A c lin kt i trong phn t cn 6 th tch oxi v sinh ra 4 th tch CO 2(Cc th tch kh o cng iu kin) Bit rng A c th tc dng vi hiro to thnh mt hirocacbon no mch nhnh. Xc nh cng thc cu to ca A v vit cc phng trnh phn ng. 2) Cho 3,36 lt hn hp gm mt anken v mt ankan i qua dung dch brom thy c 8g brom tham gia phn ng. Bit rng khi lng 6,72 lt hn hp l 13gam. a. Xc nh cng thc phn t ca hai hydrocacbon. b. t chy 3,36 lt hn hp th c bao nhiu lt kh CO2 v bao nhiu gam nc. Bit rng cc kh o ktc. 3) Cho 1gam hn hp etan v etilen i qua dung dch brom. a. Vit phn ng xy ra. b. Xc nh thnh phn khi lng ca hn hp, bit rng cho phn ng xy ra hon ton l phi dng ht 80g dung dch brom 5%. 4) hiro ha hon ton 0,7gam mt anken cn dng 246,4cm 3 hiro ( 27,3oC v 1 atm). Xc nh cng thc phn t. Vit cng thc cu to, bit rng anken c cu to mch khng nhnh 5) Cho 2,24 lt mt hn hp kh A (ktc) gm etan, propan, propilen dn qua dung dch brom d, thy khi lng bnh tng thm 2,1gam. Nu t chy kh cn li thu c mt lng CO2 v 3,24 gam H2O. a. Tnh thnh phn % th tch mi kh. b. Dn lng CO2 ni trn vo bnh ng 200ml dung dch KOH 2,6 M. Hy xc nh nng mol cc cht trong dung dch sau phn ng. 6) Mt hn hp X gm ankan A v anken B, s nguyn t hiro trong phn t A bng s nguyn t cacbon trong B. Khi t chy 3gam hn hp X th thu c 5,4 gam nc. Xc nh cng thc phn t A, B v tnh % th tch cc kh trong hn hp A. 7) Mt hn hp gm H2, mt ankan v mt anken ( c cng s nguyn t cacbon vi ankan). Khi t 100 ml hn hp thu c 210 ml kh CO2. Mt khc khi nung nng 100ml hn hp vi Ni th sau phn ng cn li 70ml mt hirocacbon duy nht. a. Tm cng thc phn t ca ankan v anken. b. nh % th tch ca ankan v anken. c. Tnh th tch O2 cn t chy 10ml hn hp (Cc kh o cng iu kin) 8) Cho hn hp X gm anken v hiro c t khi so vi heli bng 3,33. Cho X i qua bt niken nung nng n khi phn ng xy ra hon ton thu c hn hp Y c t khi so vi heli l 4. Tm cng thc phn t ca anken. 9) Cho hn hp kh A gm 2 anken. t chy hon ton 7 th tch A cn 31 th tch oxi cng iu kin. a. Xc nh cng thc phn t 2 anken. Bit rng olefin nhiu cacbon chim t l trong khong t 40 n 50% th tch ca A. b. Tm % khi lng cc anken trong A. 10) Cho hn hp H2 v etilen c t khi hi so vi hiro l 7,5. a. Tnh thnh phn % th tch kh trong hn hp. b. Cho hn hp trn vo bnh kn c bt niken nung nng lm xc tc th sau phn ng thu c mt hn hp kh c t khi so vi H2 l 9. Xc nh thnh phn % hn hp kh sau phn ng. 11) t chy hon ton 0,25 mol kh A thu c 33g CO2 v 13,5g hi nc. a. Tm cng thc phn t v cng th cu to ca A, bit rng (ktc) khi lng ring ca A l 1,875g/l. b. Tnh khi lng sn phm to thnh khi cho lng cht A trn qua dung dch brom d. 12) Hai hirocacbon A v B u th kh, A c cng thc C2xHy; B c cng thc CxH2x (tr s x trong c 2 cng thc l bng nhau). a. Lp cng thc phn t A v B. Bit rng t khi ca A i vi metan bng 3,625 v t khi ca B i vi He l 7. Vit cng thc cu to ca A v B. b. Tnh lng sn phm thu c khi cho hn hp trn tc dng va vi 16g dung dch brom. 13) t chy hon ton 0,03696 lt anken X 27,3oC v 1 atm, thu ton b kh CO2 vo dung dch KOH ta c 0,3g mui axit v 0,207g mui trung tnh. Xc nh cng thc phn t v cng thc cu to ca X. 14) A v B l hai anken ng ng lin tip nhau. Cho 13,44 lt hn hp hai anken A v B (ktc) qua bnh ng dung dch brom thy bnh tng thm 28g. a. Xc nh cng thc phn t, vit cng thc cu to hai anken. b. Cho hn hp anken tc dng vi HCl th thu c ti a 3 sn phm cng. Xc nh cng thc cu to hai anken v gi tn chng. 15) Mt hn hp hai anken ng ng k tip nhau c th tch 17,92 lt (o 0 oC v 2,5 atm) dn qua bnh cha dung dch KMnO4 d, thy khi lng bnh cha dung dch KMnO4 tng 70g. a. Xc nh cng thc phn t, vit cng thc cu to hai olefin. b. Tnh % khi lng 2 anken trong hn hp. c. t chy hon ton th tch trn ca hn hp ri cho sn phm vo 5 lt dung dch NaOH 1,8M s thu c bao nhiu gam mui khan? 16) Cho 10 lt hn hp kh (54,6oC; 0,8064 atm) gm 2 anken li qua bnh dung dch brom d thy khi lng bnh brom tng 16,8g. a. Tnh tng s mol 2 anken b. Xc nh cng thc phn t 2 anken, bit s nguyn t cacbon trong mi olefin khng qu 5. 17) Hn hp A v B l hai anken c khi lng 12,6g trn theo t l mol l 1:1 tc dng va vi 32g brom. Nu trn hn hp trn theo t l khi lng l 1:1 th 16,8g hn hp tc dng va vi 0,6g H2. Tm cng thc phn t ca A v B, bit MA < MB. 18) Cho H2 v 1 anken c th tch bng nhau qua Ni nung nng thu c hn hp A. Bit rng t khi hi ca A i vi H 2 l 23,2. Hiu sut phn ng hydro ha l 75%. a. Tm cng thc v gi tn anken. b. t V lt (ktc) hn hp A ni trn ri cho ton b sn phm chy qua 128g dung dch H 2SO4 98% sau th nghim nng dung dch H2SO4 l 62,72%. Tnh V

19) Mt hirocacbon A cha 85,71% C. a. Tm cng thc n gin nht ca A. b. Cho A tc dng vi dung dch Br2 c sn phm cng B. B cha 85,11% brom. Hy xc nh cng thc cu to ca A 20) t chy hon ton a gam cht hu c A cn dng 6,72 lt O 2 (ktc). Sn phm chy ln lt qua bnh P 2O5 thy bnh tng 3,6 gam ri qua bnh nc vi trong d thy xut hin 20 gam kt ta trng. a. Tnh a? b. Lp cng thc thc nghim ri suy ra cng thc phn t ca A, bit t khi hi ca A so vi nit l 2. c. Vit cng thc cu to c th c, suy ra cng thc ng ca A, bit A cng vi H2O cho 1 sn phm duy nht. 21) Cho 9,8g hn hp hai anken lin tip trong dy ng ng tc dng vi 1 lt dung dch brom 0,4M. Sau khi phn ng xy ra hon ton nng dung dch brom gim i 50%. a. Xc nh 2 anken trn v % m tng cht trong hn hp ban u. b. Vit tt c cng thc cu to ng phn mch h ca 2 anken v cho bit cng thc cu to no khi cng nc cho 1 sn phm duy nht 22) C 1,12 lt(ktc) hn hp X gm H 2, ankan, anken (ankan v anken cng s nguyn t cacbon), t khi hi ca X i vi oxi l 0,575. Khi cho 560 ml hn hp X i qua bnh brom thy 16g dung dch Br2 5% mt mu ng thi lng bnh tng thm 0,14 gam. a. Xc nh cng thc phn t ankan, anken. b. Xc nh thnh phn % ca hn hp ban u theo th tch. 23) Sau khi cracking butan ta thu c 1 hn hp A cc hirocacbon. Cho 22,4 lt hn hp qua bnh ng dung dch brom th cn li 13,44 lt. Ly 1,68 lt kh cn li em t chy thu c 4,06 lt CO2. Cc th tch o ktc. a. Tnh % cc kh trong hn hp A theo th tch. b. Khi lng bnh brom tng hay gim bao nhiu? c. Hiu sut phn ng cracking. 24) Hn hp X gm 2 hydrocacbon A v B (B c s cacbon ln hn A, A v B u phn ng vi dung dch Br 2). 8,96 lit hn hp X tc dng ht vi nc brom cn ti thiu 64g brom. Mt khc, em t 8,96 lit hn hp X tng s CO 2 thu c l 48,4g v khi lng H2O sinh ra t B ln hn A 12,6 gam. a. Xc nh cng thc phn t ca A, B. b. T B vit phng trnh phn ng iu ch A. 25) Cho hn hp A gm C2H4 v H2 qua Ni, c hn hp B c dB/H2 = 4,5. Nu cho A qua dung dch Br2 d th khi lng bnh brom tng 0,14g. Cc phn ng xy ra hon ton. a. Tnh khi lng cc cht trong A. b. Tnh th tch dung dch brom 0,5M ti thiu cn dng. 26) t chy hon ton 4,8g cht hu c A thu c 8,064 lt CO 2 (ktc) v 4,32g H2O. T khi hi ca A so vi khng kh l 1,38. Lp cng thc phn t ca A. 27) Mt hn hp kh X cha 0,15 mol H 2 v 0,1 mol C2H4. Cho hn hp X qua bt Ni nng ta c hn hp kh Y. Cho Y qua dung dch brom thy c 0,8g Br2 tham gia phn ng. a. Tnh hiu sut phn ng hiro ha. b. Tnh t khi ca hn hp Y i vi O2. 28) Hn hp X gm 1 ankan v 1 anken c cng s nguyn t cacbon trong phn t v c cng s mol. Bit m gam hn hp X lm mt mu va 80 gam dung dch Br2 20%. t chy hon ton m gam hh X thu c 13,44 lt CO 2 (ktc). CTPT ca ankan va anken l: A. C2H6 v C2H4 B. C3H8 v C3H6 C. C4H10 v C4H8 D. C5H12 v C5H10 29) t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tchCH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l A. 25,8. B. 12,9. C. 22,2. D. 11,1. 30) t chy hon ton 4 lt hh 2 hirocacbon A,B thu c 6 lt CO 2 v 6 lt hi H2O (cc th tch o cng iu kin t 0, p) .Cng thc phn t ca A,B l: A. CH4;C2H2 B. CH4; C3H4 C. C2H6; C2H2 D. C2H6 ;C4H6 31) Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l A. CH4 v C2H4. B. C2H6 v C2H4. C. CH4 v C3H6. D. CH4 v C4H8 32) Hn hp A gm H2 v 2 hircacbon (mt ankan, mt anken). Cho A vo bnh kn c niken lm xc tc, un nng bnh mt thi gian thu c hn hp B. Pht biu no sau y ng: A. S mol A - s mol B = s mol H2 tham gia phn ng. B. Tng s mol hirocacbon c trong B lun bng tng s mol hirocacbon c trong A C. S mol CO2 v H2O to ra khi t chy hon ton A bng s mol CO2 v H2O to ra khi t chy hon ton B D. C A, B, C u ng 33) Hn hp kh A cha etilen v hiro. T khi ca A i vi hiro l 7,5. Dn A i qua cht xuc tc Ni nung nng th thu c hn hp kh B c t khi i vi hiro l 9,0. Hiu sut phn ng cng hiro ca etilen l: A. 33,3% B. 66,7% C. 25% D. 50% 34) (H 2009-KB) Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht.T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thuc hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cuto ca anken l A. CH2 =C(CH3)2. B. CH2 =CH2 . C. CH2=CH-CH2-CH3. D. CH3-CH=CH-CH3

35) Mt hn hp gm 1 ankan v 1 anken. Dn hn hp qua dung dch brom thy dung dch brom nht mu v khi lng bnh tng 2,8 gam, sau phn ng thy thot ra 3,36 lit mt hn hp kh (ktc). t chy hon ton hn hp kh bay ra thu c 8,8 gam CO2 v 5,4 gam nc. Vy cng thc ca anken v ankan ln lt l: A. CH4 v C2H4 B. C2H6 v C2H4 C. C2H6 v C3H6 D. CH4 v C3H6 . 36) ( thi HSG 2009-TB) Khi Crckinh V lt butan c hn hp A ch gm cc anken v ankan. T khi hi ca hn hp A so vi H2 bng 21,75. Hiu sut ca phn ng Crckinh butan l bao nhiu? A. 33,33% B. 50.33% C. 46,67% D. 66,67% 37) ( thi HSG 2009-TB) Tin hnh trng hp 1mol etilen iu kin thch hp, em sn phm sau trng hp tc dng vi dung dch brom th lng brom phn ng l 36 gam. Hiu sut phn ng trng hp v khi lng poli etilen (PE) thu c l A. 85% v 23,8 gam B. 77,5 % v 22,4 gam C. 77,5% v 21,7 gam D. 70% v 23,8 gam

BI TP TRC NGHIM
Cu 1: Anken X c cng thc cu to: CH3CH2C(CH3)=CHCH3. Tn ca X l A. isohexan. B. 3-metylpent-3-en. C. 3-metylpent-2-en. D. 2-etylbut-2-en. Cu 2: S ng phn ca C4H8 l A. 3. B. 4. C. 6. D. 5. Cu 3: Hp cht C5H10 mch h c bao nhiu ng phn cu to ? A. 4. B. 5. C. 6. D. 10. Cu 4: Hp cht C5H10 c bao nhiu ng phn anken ? A. 4. B. 5. C. 6. D. 7. Cu 5: Hp cht C5H10 c bao nhiu ng phn cu to ? A. 4. B. 5. C. 6. D. 10. Cu 6: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankin. B. ankan. C. ankaien. D. anken. Cu 7: Anken X c c im: Trong phn t c 8 lin kt xch ma. CTPT ca X l A. C2H4. B. C4H8. C. C3H6. D. C5H10. Cu 8: Vitamin A cng thc phn t C20H30O, co cha 1 vong 6 canh va khng co cha lin kt ba. S lin kt i trong phn t vitamin A la A. 7. B. 6. C. 5. D. 4. Cu 9: Licopen, cng thc phn t C40H56 la cht mau o trong qua ca chua, chi cha lin kt i va lin kt n trong phn t. Hiro hoa hoan toan licopen c hirocacbon C40H82. Vy licopen co A. 1 vong; 12 ni i. B. 1 vong; 5 ni i. C. 4 vong; 5 ni i. D. mach h; 13 ni i. Cu 10: Cho cc cht sau: 2-metylbut-1-en (1); 3,3-imetylbut-1-en (2); 3-metylpent-1-en (3); 3-metylpent-2-en (4); Nhng cht no l ng phn ca nhau ? A. (3) v (4). B. (1), (2) v (3). C. (1) v (2). D. (2), (3) v (4). Cu 11: Hp cht no sau y c ng phn hnh hc ? A. 2-metylbut-2-en. B. 2-clo-but-1-en. C. 2,3- iclobut-2-en. D. 2,3- imetylpent-2-en. Cu 12: Nhng hp cht no sau y c ng phn hnh hc (cis-trans) ? CH3CH=CH2 (I); CH3CH=CHCl (II); CH3CH=C(CH3)2 (III); C2H5C(CH3)=C(CH3)C2H5 (IV); C2H5C(CH3)=CClCH3 (V). A. (I), (IV), (V). B. (II), (IV), (V). C. (III), (IV). D. (II), III, (IV), (V). Cu 13: Cho cc cht sau: CH2=CHCH2CH2CH=CH2; CH2=CHCH=CHCH2CH3; CH3C(CH3)=CHCH2; CH2=CHCH2CH=CH2; CH3CH2CH=CHCH2CH3; CH3C(CH3)=CHCH2CH3; CH3CH2C(CH3)=C(C2H5)CH(CH3)2; CH3CH=CHCH3. S cht c ng phn hnh hc l: A. 4. B. 1. C. 2. D. 3. Cu 14: p dng quy tc Maccopnhicop vo trng hp no sau y ? A. Phn ng cng ca Br2 vi anken i xng. C. Phn ng cng ca HX vo anken i xng. B. Phn ng trng hp ca anken. D. Phn ng cng ca HX vo anken bt i xng. Cu 15: Khi cho but-1-en tc dng vi dung dch HBr, theo qui tc Maccopnhicop sn phm no sau y l sn phm chnh A. CH3-CH2-CHBr-CH2Br. C. CH3-CH2-CHBr-CH3. B. CH2Br-CH2-CH2-CH2Br . D. CH3-CH2-CH2-CH2Br. Cu 16: Anken C4H8 c bao nhiu ng phn khi tc dng vi dung dch HCl ch cho mt sn phm hu c duy nht ? A. 2. B. 1. C. 3. D. 4. Cu 17: Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc cht sau khi phn ng vi H2 (d, xc tc Ni, to), cho cng mt sn phm l: A. xiclobutan, cis-but-2-en v but-1-en. B. but-1-en, 2-metylpropen v cis-but-2-en.

C. xiclobutan, 2-metylbut-2-en v but-1-en. D. 2-metylpropen, cis -but-2-en v xiclobutan. Cu 18: Cho hn hp tt c cc ng phn mch h ca C 4H8 tc dng vi H2O (H+,to) thu c ti a bao nhiu sn phm cng ? A. 2. B. 4. C. 6. D. 5 Cu 19: C bao nhiu anken th kh (kt) m khi cho mi anken tc dng vi dung dch HCl ch cho mt sn phm hu c duy nht ? A. 2. B. 1. C. 3. D. 4. Cu 20: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. 2-metylpropen v but-1-en (hoc buten-1). B. propen v but-2-en (hoc buten-2). C. eten v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). Cu 21: Anken thch hp iu ch ancol sau y (CH3 CH2)3C-OH l A. 3-etylpent-2-en. B. 3-etylpent-3-en. C. 3-etylpent-1-en. D. 3,3- imetylpent-1-en. Cu 22: Hirat ha hn hp X gm 2 anken thu c ch thu c 2 ancol. X gm A. CH2=CH2 v CH2=CHCH3. B. CH2=CH2 v CH3CH=CHCH3. C. B hoc D. D. CH3CH=CHCH3 v CH2=CHCH2CH3. Cu 35: Khi lng etilen thu c khi un nng 230 gam ru etylic vi H2SO4 m c, hiu sut phn ng t 40% l: A. 56 gam. B. 84 gam. C. 196 gam. D. 350 gam. Cu 36: Cho 3,36 lt hn hp etan v etilen (ktc) i chm qua qua dung dch brom d. Sau phn ng khi lng bnh brom tng thm 2,8 gam. S mol etan v etilen trong hn hp ln lt l: A. 0,05 v 0,1. B. 0,1 v 0,05. C. 0,12 v 0,03. D. 0,03 v 0,12. Cu 37: 2,8 gam anken A lam mt mau va u dung dich cha 8 gam Br 2. Hirat hoa A chi thu c mt ancol duy nht. A co tn la: A. etilen. B. but - 2-en. C. hex- 2-en. D. 2,3-dimetylbut-2-en. Cu 38: 0,05 mol hirocacbon X lam mt mau va u dung dich cha 8 gam brom cho ra san phm co ham lng brom at 69,56%. Cng thc phn t cua X la: A. C3H6. B. C4H8. C. C5H10. D. C5H8. Cu 39: Dn t t 8,4 gam hn hp X gm but-1-en v but-2-en li chm qua bnh ng dung dch Br 2, khi kt thc phn ng thy c m gam brom phn ng. m c gi tr l: A. 12 gam. B. 24 gam. C. 36 gam. D. 48 gam. Cu 40: Dn 3,36 lt (ktc) hn hp X gm 2 anken l ng ng k tip vo bnh nc brom d, thy khi lng bnh tng thm 7,7 gam. Thnh phn phn % v th tch ca hai anken l: A. 25% v 75%. B. 33,33% v 66,67%. C. 40% v 60%. D. 35% v 65%. Cu 41: Hn hp X gm 2 anken l ng ng lin tip c th tch 4,48 lt ( ktc). Nu cho hn hp X i qua bnh ng nc brom d, khi lng bnh tng ln 9,8 gam. % th tch ca mt trong 2 anken l: A. 50%. B. 40%. C. 70%. D. 80%. Cu 42: Dn 3,36 lt (ktc) hn hp X gm 2 anken l ng ng k tip vo bnh nc brom d, thy khi lng bnh tng thm 7,7 gam. CTPT ca 2 anken l: A. C2H4 v C3H6. B. C3H6 v C4H8. C. C4H8 v C5H10. D. C5H10 v C6H12. Cu 43: Mt hn hp X c th tch 11,2 lt (ktc), X gm 2 anken ng ng k tip nhau. Khi cho X qua nc Br 2 d thy khi lng bnh Br2 tng 15,4 gam. Xc nh CTPT v s mol mi anken trong hn hp X. A. 0,2 mol C2H4 v 0,3 mol C3H6. B. 0,2 mol C3H6 v 0,2 mol C4H8. C. 0,4 mol C2H4 v 0,1 mol C3H6. D. 0,3 mol C2H4 v 0,2 mol C3H6. Cu 44: Mt hn hp X gm ankan A v anken B, A c nhiu hn B mt nguyn t cacbon, A v B u th kh ( ktc). Khi cho 6,72 lt kh X (ktc) i qua nc brom d, khi lng bnh brom tng ln 2,8 gam; th tch kh cn li ch bng 2/3 th tch hn hp X ban u. CTPT ca A, B v khi lng ca hn hp X l: A. C4H10, C3H6 ; 5,8 gam. B. C3H8, C2H4 ; 5,8 gam. C. C4H10, C3H6 ; 12,8 gam. D. C3H8, C2H4 ; 11,6 gam. Cu 45: Mt hn hp X gm ankan A v mt anken B c cng s nguyn t C v u th kh ktc. Cho hn hp X i qua nc Br2 d th th tch kh Y cn li bng na th tch X, cn khi lng Y bng 15/29 khi lng X. CTPT A, B v thnh phn % theo th tch ca hn hp X l A. 40% C2H6 v 60% C2H4. B. 50% C3H8v 50% C3H6 C. 50% C4H10 v 50% C4H8. D. 50% C2H6 v 50% C2H4 Cu 46 : Hn hp X gm metan v 1 olefin. Cho 10,8 lt hn hp X qua dung dch brom d thy c 1 cht kh bay ra, t chy hon ton kh ny thu c 5,544 gam CO2. Thnh phn % v th tch metan v olefin trong hn hp X l: A. 26,13% v 73,87%. B. 36,5% v 63,5%. C. 20% v 80%. D. 73,9% v 26,1%. Cu 47: Cho 8960 ml (ktc) anken X qua dung dch brom d. Sau phn ng thy khi lng bnh brom tng 22,4 gam. Bit X c ng phn hnh hc. CTCT ca X l: A. CH2=CHCH2CH3. B. CH3CH=CHCH3. C. CH3CH=CHCH2CH3. D. (CH3)2C=CH2. Cu 48: a. Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l: A. but-1-en. B. but-2-en. C. Propilen. D. Xiclopropan.

b. Hirocacbon X cng HCl theo ti l mol 1:1 tao san phm co ham lng clo la 55,04%. X co cng thc phn t l: A. C4H8. B. C2H4. C. C5H10. D. C3H6. Cu 49: Hn hp X gm metan v anken, cho 5,6 lt X qua dung dch brom d thy khi lng bnh brom tng 7,28 gam v c 2,688 lt kh bay ra (ktc). CTPT ca anken l: A. C4H8. B. C5H10. C. C3H6. D. C2H4 Cu 50: Dn 3,36 lt (ktc) hn hp X gm 2 anken l vo bnh nc brom d, thy khi lng bnh tng thm 7,7 gam. CTPT ca 2 anken l: A. C2H4 v C4H8. B. C3H6 v C4H8. C. C4H8 v C5H10. D. A hoc B. Cu 51: Cho 10 lt hn hp kh (54,6 oC; 0,8064 atm) gm 2 olefin li qua bnh dung dch brom d thy khi lng bnh brom tng 16,8 gam. CTPT ca 2 anken l (Bit s C trong cc anken khng vt qu 5) A. C2H4 v C5H10. B. C3H6 v C5H10. C. C4H8 v C5H10. D. A hoc B. Cu 52: Cho buta-1,3-ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (ng phn cu to v ng phn hnh hc) thu c l A. 2. B. 3. C. 4. D. 1. Cu 53: Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l A.3-etylpent-3-en. B. 2-etylpent-2-en. C. 3-etylpent-2-en. D. 3-etylpent-1-en. Cu 54: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c khi lng A.12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l A. 0,1 mol C2H4 v 0,2 mol C2H2. B. 0,2 mol C2H4 v 0,1 mol C2H2. C. 0,1 mol C3H6 v 0,2 mol C3H4. D. 0,2 mol C3H6 v 0,1 mol C3H4. Cu 55: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3-C(CH3)=CH-CH3, CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l A.2. B. 3. C. 1. D. 4. Cu 56: Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l A.2. B. 3. C. 5. D. 4. Cu 57: Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br 2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l (cho H = 1, C = 12) A.C2H2 v C4H6. B. C2H2 v C4H8. C. C3H4 v C4H8. D. C2H2 v C3H8. Cu 58: Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo phn ng vi k mt xch trong mch PVC. Gi tr ca k l (cho H = 1, C = 12, Cl = 35,5) A.3. B. 6. C. 4. D. 5. Cu 59: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l (cho H = 1, C = 12, O = 16, Ca = 40) A.20. B. 40. C. 30. D. 10. Cu 60: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5) A.C3H6. B. C3H4. C. C2H4. D. C4H8. Cu 61: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. 2-metylpropen v but-1-en (hoc buten-1). B. propen v but-2-en (hoc buten-2). C. eten v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). Cu 62: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l (cho H = 1, C = 12, O = 16) A.C3H8. B. C3H6. C. C4H8. D. C3H4. Cu 63: Cht no sau y c ng phn hnh hc? A. CH2=CH-CH=CH2. B. CH3-CH=C(CH3)2. C. CH3-CH=CH-CH=CH2. D. CH2=CH-CH2-CH3. Cu 64: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l A.20%. B. 25%. C. 50%. D. 40%. Cu 65: Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc cht sau khi phn ng vi H 2 (d, xc tc Ni, to), cho cng mt sn phm l: A. xiclobutan, cis-but-2-en v but-1-en. B. but-1-en, 2-metylpropen v cis-but-2-en. C. xiclobutan, 2-metylbut-2-en v but-1-en. D. 2-metylpropen, cis-but-2-en v xiclobutan. Cu 66: Cho cc cht: CH2=CHCH=CH2; CH3CH2CH=C(CH3)2; CH3CH=CHCH=CH2; CH3CH=CH2; CH3CH=CHCOOH. S cht c ng phn hnh hc l A.4. B. 3. C. 2. D. 1. Cu 67: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH 4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l A.12,9. B. 25,8. C. 22,2. D. 11,1. Cu 68: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu

c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (Cho: H = 1; C = 12; O = 16; th tch dung dch thay i khng ng k) A. C2H5OH v C3H7OH. B. C3H7OH v C4H9OH. C. C2H5OH v C4H9OH. D. C4H9OH v C5H11OH. Cu 69: Cho phn ng: C6H5-CH=CH2 + KMnO4 C6H5-COOK + K2CO3 + MnO2 + KOH + H2O. Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ho hc ca phn ng trn l A.27. B. 24. C. 34. D. 31. Cu 70: S ng phn cu to ca C5H10 phn ng c vi dung dch brom l A.8. B. 7. C. 9. D. 5. Cu 71: Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l A.CH4 v C2H4. B. C2H6 v C2H4. C. CH4 v C3H6. D. CH4 v C4H8. Cu 72: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l A. but-1-en. B. xiclopropan. C. but-2-en. D. propilen. Cu 73: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO 2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc) A. CH4 v C2H4. B. CH4 v C3H4. C. CH4 v C3H6. D. C2H6 v C3H6 Cu 74: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankan. B. ankaien. C. anken. D. ankin. Cu 75: Hiro ha hon ton hirocacbon mch h X thu c isopentan. S cng thc cu to c th c ca X l A. 6. B. 5. C. 7. D. 4. Cu 76: t chy hon ton 3 lt hn hp X gm 2 anken k tip nhau trong dy ng ng cn va 10,5 lt O 2 (cc th tch kh o trong cng iu kin nhit , p sut). Hirat ha hon ton X trong iu kin thch hp thu c hn hp ancol Y, trong khi lng ancol bc hai bng 6/13 ln tng khi lng cc ancol bc mt. Phn trm khi lng ca ancol bc mt (c s nguyn t cacbon ln hn) trong Y l A. 46,43%. B. 31,58%. C. 10,88%. D. 7,89%. Cu 77: Hn hp X gm H2 v C2H4 c t khi so vi H2 l 7,5. Dn X qua Ni nung nng, thu c hn hp Y c t khi so vi H2 l 12,5. Hiu sut ca phn ng hiro ha l A. 70%. B. 60%. C. 50%. D. 80%. Cu 78: Hirat ha 2-metylbut-2-en (iu kin nhit , xc tc thch hp) thu c sn phm chnh l A. 2-metylbutan-2-ol. B. 3-metylbutan-2-ol. C. 3-metylbutan-1-ol. D. 2-metylbutan-3-ol.