BI TP V ANDEHIT V XETON (2)

Cu 1 Dy gm cc cht u tham gia phn ng trng gng l A. CH2=CH2, CH2=CHCHO, C6H5CHO. B. CH3CHO, HCOOH, HCOOCH3. C. CHCH, CH3CHO, HCO-CHO. D. HCHO, CH3COCH3, HCOOH. Cu 2. Khi cho 6 gam an ehit fomic tc dng vi lng d dung dch AgNO3 trong NH3. Sau khi phn ng xy ra hon ton ta thu c kt ta Ag. Khi lng ca Ag thu c l A. 86,4 gam. B. 43,2 gam. C. 54 gam. D. 64,8 gam. Cu 3 Cho 2 gam dung dch fomalin tc dng vi dung dch AgNO 3/NH3 d , thy c 10,8 gam Ag to thnh. Nng % ca dung dch fomalin l A. 75%. B. 35%. C. 40%. D. 37,5%. Cu 4 Cho 8 g hn hp hai andhit k tip nhau trong dy ng ng ca anehit no, n chc, mch h tc dng vi Ag 2O d trong NH3, thu c 32,4 g Ag kt ta. Tn gi ca cc andhit l: A. butanal v pentanal. B. etanal v prpanal. C. andhit focmc v anehit axtc. D. anehit prpionc v andhyt butyric Cu 5 Cho 3,6 gam ankanal X phn ng hon ton vi Ag2O/ dd NH3 d (t0) lng Ag sinh ra cho tc dng hon ton vi dd HNO 3 c, d thu c 2,8 lt kh NO2 (sn phm kh duy nht) 136,5 0C, p sut 1,2 atm. Cng thc ca X l: A. C3H7CHO. B. HCHO. C. C2H5CHO. D. C4H9CHO. Cu 6: Cho 1,02 gam hn hp 2 andehit X v Y k tip nhau trong dy ng ng ca andehit no, n chc tc dng vi dung dch AgNO 3 trong NH3 d thu c 4,32 gam kim loi. X v Y c CTPT l: A. C2H5CHO, C3H7CHO B. CH3CHO, C2H5CHO C. HCHO, CH3CHO D. C3H7CHO, C4H9CHO

Cu 7: Hp cht hu c X c cng thc phn t C 4H7O2Cl , khi thy phn trong mi trng kim c cc sn phm, trong c 2 cht c kh nng phn ng trng gng. Cng thc cu to ca X l A. HOOC-CH2CHCl-CH3. B. CH3COO-CH2CH2Cl. C. HOOC-CHCl-CH2-CH3. D. CH2COO-CH3CH2Cl Cu 8Cho 4,5 gam mt anhit n chc tc dng hon ton vi Ag 2O trong dd NH3 d thu c 64,4 gam Ag. Cng thc phn t ca anht l. A. HCHO B. CH3CHO C. C2H5CHO D. C2H3CHO Cu 9 t chy hon ton hn hp A gm 0,05 mol mt andehit n chc v 0,05 mol 1 xeton n chc. Thu ton b sn phm chy cho hp th ht vo bnh nc vi trong d, th khi lng bnh tng thm 12,4 g khi lc thu c 20 gam kt ta. 1. Xc nh CTCT ca andehit v xeton 2. Vit phn ng ca andehit vi dung dch AgNO3 trong amoniac. Cu 10 Cho hn hp A gm 2 andehit A 1 v A2 l ng ng k tip nhau. t chy A1 to ra CO2 v H2O vi t s mol l 1:1; Trong A1 c 53,33% oxi v khi lng. Oxi ho m gam hn hp A thu c (m + 3,2) gam hn hp B gm 2 axit tng ng. Mt khc nu cho m gam hn hp A phn ng vi dung dch AgNO 3 (d) trong NH3 thu c 51,84 gam Ag. 1. Tnh m 2. Chng minh rng t khi d ca B so vi A c gi tr trong khong 1,3636 < d < 1,5333 Cu 11 Mt hn hp gm Ru no n chc v andehit no n chc c khi lng 5,04 gam b t chy hon ton. Sn phm chy chia i, mt na cho i qua CaO d thy lng CaO tng 7,8 gam, na cn li cho i qua P2O5 d thy lng P2O5 tng 2,52 gam. Hy xc nh cng thc mi cht v thnh phn hn hp.