Ti liu n thi i hc nm 2012 -2013 B S 1 Cu 1: S nguyn t m trong cu hnh electron nguyn t c phn lp ngoi cng l 4s2 l A. 1. B. 3. C. 8. D. 9.

. Cu 2: Cho V lt kh NO2 (ktc) hp th vo mt lng va dung dch NaOH, sau em c cn th thu c hn hp cht rn khan cha 2 mui. Nung cht rn ny ti ch cn mt mui duy nht thy cn li 13,8 gam. Gi tr ca V l A. 1,12 B. 2,24 C. 4,48 D. 5,60 Cu 3: Cho V lt Cl2 (ktc) tc dng vi dung dch NaOH long, ngui, d thu c m 1 gam tng khi lng 2 mui. Cho V lt Cl2 (ktc) tc dng vi dung dch NaOH c, nng, d thu c m 2 gam tng khi lng 2 mui. T l m1 : m2 bng A. 2 : 3 B. 1 : 2. C. 1 : 1. D. 2 : 1. Cu 4: Cho cc trng hp sau: (1) O3 tc dng vi dung dch KI. (5) KClO3 tc dng vi dung dch HCl c, un nng. (2) Axit HF tc dng vi SiO2. (6) un nng dung dch bo ha gm NH4Cl v NaNO2. (3) MnO2 tc dng vi dung dch HCl c, un nng. (7) Cho kh NH3 qua CuO nung nng. (4) Kh SO2 tc dng vi nc Cl2. S trng hp to ra n cht l A. 5. B. 6. C. 4. D. 3. Cu 5: Ha tan 2,8 gam BaCl2.4H2O vo nc thu c 500ml dung dch X. Ly 1/10 dung dch X em in phn vi in cc tr (c mng ngn) trong 16 pht 5 giy vi cng dng in mt chiu bng 0,1A. Thnh phn phn trm v s mol BaCl2 b in phn l A. 50%. B. 70%. C. 45%. D. 60%. Cu 6: Phn ng khng xy ra nhit thng l A. Mg(HCO3)2 + 2Ca(OH)2 Mg(OH)2 + 2CaCO3 + 2H2O. B. Ca(HCO3)2 + Ca(OH)2 2CaCO3 + 2H2O. C. Ca(OH)2 + 2NH4Cl CaCl2 + 2H2O + 2NH3 . D. CaCl2 + 2 NaHCO3 CaCO3 + 2NaCl + 2HCl. Cu 7: Cho phn ng ha hc sau: aMgO + bP2O5 (X). Bit rng trong (X) Mg chim 21,62% v khi lng v cng thc phn t trng vi cng thc n gin nht. Cng thc phn t ca X l A. Mg3(PO4)2. B. Mg3(PO3)2. C. Mg2P4O7. D. Mg2P2O7. Cu 8: X l dung dch AlCl3, Y l dung dch NaOH 2 M. Thm 150 ml dung dch Y vo cc cha 100ml dung dch X, khuy u n phn ng hon ton thy trong cc c 7,8 gam kt ta. Thm tip vo cc 100 ml dung dch Y, khuy u n phn ng hon ton thy trong cc c 10,92 gam kt ta. Nng mol/l ca dung dch X bng A. 3,2 M. B. 2,0 M. C. 1,6 M. D. 1,0 M. 2 + Cu 9: Dung dch X cha 0,025 mol CO 3 ; 0,1 mol Na ; 0,3 mol Cl , cn li l ion NH + 4 . Cho 270 ml dung dch Ba(OH)2 0,2 M vo dung dch X v un nng nh, thy tng khi lng dung dch X v dung dch Ba(OH)2 gim m gam? Gi s nc bay hi khng ng k. Gi tr m l A. 4,215 B. 5,269 C. 6,761 D. 7,015 Cu 10: Cho phng trnh phn ng: X + H2SO4 Fe2(SO4)3+ SO2 + H2O S hp cht X cha 2 nguyn t l A. 2 B. 3 C. 4 D. 5 Cu 11: Ha tan hon ton 12,9 gam hn hp Cu, Zn bng dung dch H 2SO4 c, nng thu c sn phm kh l 3,136 lt SO2 (ktc) v 0,64 gam lu hunh. Phn trm khi lng mi kim loi trong hn hp ban u l A. 45,54% Cu; 54 46% Zn. B. 49,61% Cu; 50,39% Zn. C. 50,15% Cu; 49,85% Zn. D. 51,08% Cu; 48,92% Zn. Cu 12: Trong cc cht cho sau y: xenluloz, ct, canxi cacbua, ancol etylic, cao su, tinh bt, natri clorua, st kim loi, oxi, du m; cht l nguyn liu t nhin l A. xenluloz, ct, canxi cacbua, tinh bt, st kim loi, oxi, du m. B. xenluloz, ct, cao su, tinh bt, natri clorua, oxi, du m. C. xenluloz, ancol etylic, tinh bt, natri clorua, oxi, du m. D. xenluloz, cao su, ancol etylic, tinh bt, st kim loi, oxi, du m.
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Ti liu n thi i hc nm 2012 -2013 Cu 13: Mt hn hp gm ankaien X v O2 ly d (O2 chim 90% th tch) c np y vo mt bnh kn p sut 2 atm. Bt tia la in t chy ht X ri a bnh v nhit ban u cho hi nc ngng t ht th p sut gim 0,5 atm. Cng thc phn t ca X l A. C3H4. B. C4H6. C. C5H8. D. C6H10. Cu 14: xc nh ru ca mt loi ancol etylic (k hiu l X) ngi ta ly 10 ml X cho tc dng ht vi Na d thu c 2,564 lt H2 (ktc). bit khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml. ru l A. 87,5o. B. 85,7o. C. 91,0o. D. 92,5o. Cu 15: Cho cc cht sau y phn ng vi nhau: (1) CH3COONa + CO2 + H2O (2) (CH3COO)2Ca + Na2CO3 (3) CH3COOH + NaHSO4 (4) CH3COOH + CaCO3 (5) C17H35COONa + Ca(HCO3)2 (6) C6H5ONa + CO2 + H2O (7) CH3COONH4 + Ca(OH)2 Cc phn ng khng xy ra l A. 1, 3, 4. B. 1, 3. C. 1, 3, 6. D. 1, 3, 5. Cu 16: Oxi ha hon ton hn hp X gm HCHO v CH 3CHO bng O2 (c xc tc) thu c hn hp Y gm 2 axit tng ng. T khi hi ca Y so vi X l T. Gi tr ca T l A. 1,12 < T < 1,36. B. 1,36 < T < 1,53. C. 1,36 < T < 1,64. D. 1,53 < T < 1,64. Cu 17: Chia hn hp X gm ancol etylic v axit axetic (trong s mol ancol nhiu hn s mol axit) thnh 2 phn bng nhau. Phn 1 cho tc dng ht vi Na d thu c 5,6 lt H 2 (ktc). Phn 2 un nng vi mt t H2SO4 c (chp nhn phn ng este ha l hon ton) th thu c 8,8 gam este. S mol ancol v axit trong X ln lt l A. 0,4 v 0,1. B. 0,8 v 0,2. C. 0,2 v 0,3. D. 0,6 v 0,5. Cu 18: Chia 7,8 gam hn hp ancol etylic v ancol ng ng R-OH thnh 2 phn bng nhau. Phn 1 cho tc dng vi Na d thu c 1,12 lt H 2 (ktc). Phn 2 tc dng vi dung dch cha 30 gam CH 3COOH (c mt H2SO4 c). Bit hiu sut cc phn ng este ha u l 80%, khi lng este thu c l A. 6,48 gam. B. 8,10 gam. C. 8,80 gam. D. 9,60 gam. Cu 19: X l mt -amino axit cha 1 nhm COOH v 1 nhm NH 2. Cho 8,9 gam X tc dng vi 200 ml dung dch HCl 1 M thu c dung dch Y. phn ng ht vi cc cht trong dung dch Y cn dng 300 ml dung dch NaOH 1 M. Cng thc ng ca X l; A. CH3CH(NH2)COOH. B. CH3C(CH3)(NH2)COOH. C. CH3CH2CH(NH2)COOH. D. CH3CH(CH3)CH(NH2)COOH. Cu 20: Cao su Buna-N c iu ch nh loi phn ng A. trng hp. B. cng hp. C. trng ngng. D. ng trng hp. Cu 21: ng vi cng thc phn t C3H6O2 th s ng phn mch h c th tc dng c vi Na v s ng phn mch h khng th tc dng c vi Na l A. 2 v 5. B. 3 v 4. C. 4 v 3. D. 5 v 2. Cu 22: Oxi ha anehit X n chc bng O 2 (xc tc thch hp) vi hiu sut phn ng l 75% thu c hn hp Y gm axit cacboxylic tng ng v anehit d. Trung ha axit trong hn hp Y cn 100 ml dung dch NaOH 0,75M ri c cn dung dch sau phn ng thu c 5,1 gam cht rn khan. Nu cho hn hp Y tc dng hon ton vi dung dch AgNO3 trong NH3 d, un nng th thu c khi lng Ag l A. 21,6 gam. B. 5,4 gam. C. 10,8 gam. D. 27,0 gam. Cu 23: Cho 15,84 gam este no, n chc, mch h tc dng ht vi 30ml dung dch MOH 20% (d=1,2g/ml) vi M l kim loi kim. Sau phn ng hon ton, c cn dung dch thu c cht rn X. t chy hon ton X thu c hn hp kh v hi gm CO 2, H2O v 9,54 gam M2CO3. Kim loi M v cng thc cu to ca este ban u l A. K v CH3COOCH3. B. K v HCOO-CH3. C. Na v CH3COOC2H5. D. Na v HCOO-C2H5. Cu 24: Cho cc dung dch khng mu: HCOOH, CH 3COOH, glucoz, glixerol, C2H5OH, CH3CHO. Nu dng thuc th l Cu(OH)2/OH- th s cht c th phn bit c l A. 6. B. 5. C. 4. D. 3. Cu 25: un 20,4 gam mt cht hu c X n chc vi 300 ml dung dch NaOH 1 M thu c mui Y v hp cht hu c Z n chc. Cho Z tc dng vi Na d thu c 2,24 lt kh H 2 (ktc). Oxi ha Z thu c hp cht
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Ti liu n thi i hc nm 2012 -2013 Z khng phn ng vi dung dch AgNO3/NH3. Nung Y vi NaOH rn thu c kh T c t khi hi so vi O 2 l 0,5. Cng thc cu to ca X l A. CH3COOCH(CH3)2. B. CH3COOCH2CH2CH3. C. C2H5COOCH(CH3)2. D. CH3COOCH(CH3)CH2CH3. Cu 26: Ha tan Fe3O4 trong lng d dung dch H2SO4 long thu c dung dch X. Dung dch X tc dng vi cc cht sau: Cu, NaOH, Br2, AgNO3, KMnO4, MgSO4, Mg(NO3)2, Al. S cht phn ng c l A. 4. B. 5. C. 6. D. 7. Cu 27: Cho m gam hn hp X gm Fe 2O3, CuO, MgO, FeO v Fe3O4 vo dung dch H2SO4 c nng thu c 3,36 lt kh SO2 (ktc). Mt khc nung m gam hn hp X vi kh CO d thu c cht rn Y v hn hp kh Z. Cho Z vo dung dch Ca(OH)2 d thu c 35 gam kt ta. Cho cht rn Y vo dung dch HNO 3 c, nng, d thu c V lt kh NO2 (ktc) l sn phm kh duy nht. Gi tr ca V l A. 11,2. B. 22,4. C. 44,8. D. 33.6. Cu 28: Cho 500ml dung dch FeCl2 1M tc dng vi 200 ml dung dch KMnO41M c axit ha bng dung dch H2SO4 long d. Khi phn ng xy ra hon ton thu c dung dch Y v V lt kh iu kin tiu chun. Gi s Clo khng phn ng vi nc. Gi tr ca V l A. 11,20. B. 5,60. C. 14,93. D. 33,60. Cu 29: Hp cht X c vng benzen v c CTPT l CxHyN. Khi cho X tc dng vi HCl thu c mui Y c cng thc dng RNH2Cl. Trong cc phn t X, phn trm khi lng ca N l 11,57%; s CTCT ca X l A. 32 B. 18 C. 5 D. 34 Cu 30: Cho 8(g) bt Cu vo 200ml dung dch AgNO 3, sau 1 thi gian phn ng lc c dung dch A v 9,52(g) cht rn. Cho tip 8 (g) bt Pb vo dung dch A, phn ng xong lc tch c dung dch B ch cha 1 mui duy nht v 6,705(g) cht rn. Nng mol ca AgNO3 ban u l A. 0,20 B. 0,25. C. 0,35 D. 0,10 Cu 31: Mt hn hp X gm 1 axit no n chc v mt axit no, 2 chc. t chy hon ton a gam hn hp X thu c 0,24 mol CO2 v 0,2 mol H2O. Mt khc, cho a gam hn hp X tc dng vi NaHCO3 d thu c 3,136 lt CO2 (ktc). Cng thc ca 2 axit l A. CH3COOH v HOOC-CH2-COOH B. HCOOH v HOOC-COOH C. HCOOH v HOOC-(CH2)4-COOH D. CH3COOH v HOOC-COOH Cu 32: Cho 4,6 gam ancol X tc dng vi Na d thu c 1,12 lt H 2. Cho 9,0 gam axit hu c Y tc dng vi Na d thu c 1,68 lt H2. un nng hn hp gm 4,6 gam ancol X v 9 gam axit Y ( xc tc H 2SO4 c,t0 ) thu c 6,6 gam este E. t chy hon ton E thu c CO 2 v nc theo t l mol l 1: 1. Cc kh o ktc. Hiu sut phn ng to thnh este l A. 50% B. 60% C. 75% D. 80% Cu 33:Hp cht hu c X c cng thc phn t C 3H9O2N. Bit X tc dng vi NaOH v HCl. S cng thc cu to tha mn l A. 4 B. 3 C. 1 D. 2 n+ n+ 2 Cu 34:Hp cht E to t ion X v Y . C X , Y u c cu hnh e l 1s 2s2 2p6. Sp xp bn knh ca X, Y, Xn+ v Y- theo chiu tng dn l A. Xn+ < Y < Y- < X. B. Xn+ < Y < X < YC. Xn+ < Y- < Y < X. D. Y < Y- < Xn+ < X Cu 35:Cho phng trnh phn ng: FeS2 + Cu2S + HNO3 Fe2(SO4)3 + CuSO4 + NO + H2O Tng cc h s ca phng trnh vi cc s nguyn ti gin c lp theo phng trnh trn l: A. 100 B. 108 C. 118 D. 150 Cu 36: Cho s sau: C4H7ClO2 (A) + NaOH mui X + Y + NaCl. Bit rng c X, Y u tc dng vi Cu(OH)2. CTCT ca A l A. Cl-CH2-COOCH=CH2 B. CH3COO-CHCl-CH3 C. HCOOCH2-CH2-CH2Cl D. HCOO-CH2-CHCl-CH3 Cu 37: Oxi ho 6 gam ancol X bng oxi (xc tc Cu, t 0) thu c 8,4 gam hn hp cht lng Y. Cho hn hp Y tc dng vi Ag2O d trong NH3, un nng thu c ti a m gam Ag. Gi tr ca m l A. 16,2 B. 32,4 C. 64,8 D. 54,0 Cu 38: Kim loi R ha tr khng i vo 100 ml dung dch HCl 1,5M c 2,24 lt H 2 (ktc) v dung dch X. Cho dung dch AgNO3 d vo dung dch X thu m(g) kt ta. Gi tr ca m l
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Ti liu n thi i hc nm 2012 -2013 A. 21,525 B. 26,925 C. 24,225 D. 27,325. Cu 39: Cho dung dch KOH d vo dung dch FeCl2 thu c 13,5 g kt ta. Nu thay dung dch KOH bng dung dch AgNO3 d th thu c m gam kt ta. Gi tr ca m l A. 43,05 B. 59,25 C. 53,85 D. 48,45. Cu 40: Hn hp X gm 2 axit no. t chy hon ton a mol hn hp X thu c a mol H 2O. Mt khc, cho a mol hn hp X tc dng vi NaHCO 3 thu c 1,4 a mol CO 2. Phn trm khi lng ca axit c khi lng mol nh hn trong X l A. 26,4% B. 27,3% C. 43,4% D. 35,8% Cu 41:Cho phng trnh phn ng: Fe (NO3) 2 + H2SO4 Fe2(SO4)3 + HNO3 + NO + H2O Tng cc h s ca phng trnh vi cc s nguyn ti gin c lp theo phng trnh trn l: A. 40 B. 42 C . 34 D. 36 Cu 42:Cho 200ml dung dch A cha CuSO4 (d = 1,25g/ml). Sau khi in phn A, khi lng ca dung dch gim i 8 gam. Mt khc, lm kt ta ht lng CuSO4 cn li cha b in phn phi dng ht 1,12(lt) H2S ( ktc). Nng phn trm ca dung dch CuSO4 trc khi in phn l: A. 9,6% B. 50% C. 20% D. 30% Cu 43: C 6 gi bt mu en CuO, MnO 2, Ag2O, CuS, FeS, PbS. Nu ch c dung dch HCl c th s gi bt nhn bit c l A. 6. B. 3. C. 4. D. 5. Cu 44: Cho cc pht biu sau: (1) phenol c tnh axit nhng yu hn axit cacbonic (2) dung dch phenol lm i mu qu tm sang (3) phenol c tnh axit mnh hn etanol (4) phenol tan tt trong nc lnh do to c lin kt hiro vi nc (5) axit picric (2, 4, 6 trinitrophenol) c tnh axt mnh hn phenol (6) phenol tan tt trong dung dch NaOH S pht biu ng l A. 1, 2, 3, 6. B. 1, 2, 4, 6. C. 1, 3, 5, 6. D. 1, 2, 5, 6. Cu 45: X c cng thc phn t l C9H12O. X tc dng vi NaOH, X tc dng vi dd brom cho kt ta Y c cng thc phn t l C9H9OBr3. S CTCT ca X l A. 3 B. 2 C. 4 D. 5 Cu 46: Trn 19,2 gam Fe2O3 vi 5,4 gam Al ri tin hnh phn ng nhit nhm (khng c mt khng kh v ch xy ra phn ng kh Fe2O3 thnh Fe). Hn hp sau phn ng (sau khi lm ngui) tc dng hon ton vi dung dch HCl d thu c 5,04 lt kh (ktc). Hiu sut phn ng nhit nhm l A. 75,0%. B. 57,5%. C. 60,0%. D. 62,5%. 2 Cu 47: Tng s ht mang in trong anion XY 3 bng 82. S ht proton trong ht nhn X nhiu hn s ht proton trong ht nhn Y l 8 ht. S hiu nguyn t ca X, Y ln lt l A. 14, 8. B. 15, 7. C. 16, 8. D. 17, 9. Cu 48: x phng ha 10 kg cht bo (RCOO) 3C3H5 ngi ta un cht bo vi dung dch cha 1,37 kg NaOH. Lng NaOH d c trung ha bi 500 ml dung dch HCl 1 M. Khi lng glixerol v x phng nguyn cht thu c ln lt l A. 1,035 kg v 11,225 kg. B. 1,050 kg v 10,315 kg. C. 1,035 kg v 10,315 kg. D. 1,050 kg v 11,225 kg. Cu 49: Xenluloz iaxetat c dng sn xut phim nh hoc t axetat. Cng thc n gin nht ca xenluloz iaxetat l A. C10H13O5. B. C12H14O7. C. C10H14O7. D. C12H14O5. Cu 50: Mt hn hp X gm CH3OH, CH2=CHCH2OH, CH3CH2OH, C3H5(OH)3.Cho 25,4 gam hn hp X tc dng vi Na d thu c 5,6 lt H2 (ktc). Mt khc em t chy hon ton 25,4 gam hn hp X thu c m gam CO2 v 27 gam H2O. Gi tr ca m l A. 61,6 gam. B. 52,8 gam. C. 44 gam. D. 55 gam.

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Ti liu n thi i hc nm 2012 -2013 B S 2 Cu 1. Trung ho 5,4 gam X gm CH3COOH, CH2=CHCOOH, C 6H5OH v C6H5COOH cn dung Vml dung dch NaOH 0,1M. C cn dung dch sau phn ng thu c 6,94 gam hn hp cht rn khan. Gi tr V l A. 670 B. 700 C. 900 D. 350 Cu 2. Cho cc dung dch NaHSO4, NaHCO3, (NH4)2SO4, NaNO3,Na2CO3, ZnCl2, CuSO4, CH3COONa. S dung dch c pH > 7 l A.3 B.2 C.5 D.4 Cu 3.Nhit phn hon ton m gam hn hp X gm KNO3 v Fe(NO3)2 . Hn hp kh thu c em dn vo bnh cha 2 lit H2O th khng thy kh thot ra khi bnh . Dung dch thu c c ga tr pH=1 v ch cha mt cht tan duy nht, coi th tch dung dch khng thay i. Gi tr m l A.28,10 B.23,05 C.46,10 D.38,20 Cu 4. trung ho m gam hn hp X gm hai axit no, n chc, mch h k tip nhau trong dy ng ng cn dung 100ml dung dch NaOH 0,3 M. Mt khc t chy m gam X ri cho ton ban phm chy ln lt qua bnh (1) ng P2O 5, bnh (2) ng dung dch KOH d thy khi lng bnh (1) tng a gam, bnh (2) tng (3,64+ a) gam. Thnh phn phn trm v khi lng ca axit c nguyn t cacbon nh hn trong X l A.33,33% B.66,67% C.30,14% D.69,86% Cu 5. Cho tng cht Fe, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO 3)3, FeSO4, Fe2(SO4)3, FeCO3 ln lt tc dng vi H2SO4 c nng. S phn ng thuc loi oxi ha kh l. A.8 B.5 C.6 D.7 Cu 6.Cht hu c X c cng thc phn t C7H8. Cho X tc dng vi AgNO3/NH3 d thu c kt ta Y. phn t khi ca Y ln hn X l 214. S ng phn cu to ca X l A.2 B.3 C.4 D.5 Cu 7. X l hp cht mch h (cha C, H, O) c phn t khi bng 90 vC. Cho X tc dng vi Na d thu c s mol H2 bng s mol X phn ng. Mt khc X c kh nng phn ng vi NaHCO3. S cng thc cu to ca X c th l A. 3 B.4 C.5 D.2 Cu 8. Phenolphtalein (X) c t l khi lng mC:mH:mO = 60:3,5:16. Bit Khi lng phn t ca X nm trong 300 n 320 u. S nguyn t C ca X l A. 20 B.10 C.5 D.12 Cu 9.Mt hn hp hai axit no, n chc , mch h, k tip nhau trong dy ng ng.Ly m gam hn hp ri cho them vo 75 ml dung dch NaOH 0,2M. trung ho NaOH cn d cn thm 25ml dung dch HCl 0,2M. C cn dung dch sau khi trung ho thu c 1,0425 gam cht rn khan. Cng thc ca axit c nguyn t cacbon b hn l A. C3H7COOH B.C2H5COOH C.HCOOH D.CH3COOH Cu 10. Cho cc dung dch sau NaOH, NaHCO3, BaCl2, Na2CO3, NaHSO4. Nu trn cc dung dch vi nhau theo tng i mt th tng s cp c th xy ra l A. 4 B.5 C.6 D.7 Cu 11.Cho cc phn ng : (1) O3+ dung dch KI (2) F2+ H2O ( 3) KClO3 (rn) + HCl c (4) SO2 +dung dch H2S (5) Cl2 + dung dch H2S (6) NH3(d) +Cl2 (7) NaNO2 ( bo ho) +NH4Cl (bo ho) (8) NO2 + NaOH (dd) S phn ng to ra n cht l. A. 4 B.5 C.7 D.6 Cu 12: Cho 0,1 mol cht X c cng thc phn t l C 2H8O3N2 (M = 108) tc dng vi dung dch cha 0,2 mol NaOH un nng thu c kh X lm xanh giy qu tm m v dung dch Y. C cn dung dch Y thu c m gam cht rn khan. Gi tr ca m l A. 5,7 B. 12,5 C. 15,0 D. 21,8 Cu 13 . Cng thc n gin nht ca X l C3H3O. Cho 5,5 gam X tc dng vi dung dch Na CU 12OH c 7,7 gam mui Y c s nguyn t C bng ca X. Phn t khi ca Y ln hn ca X l 44. S ng phn cu to ca X l A. 2 B.3 C.1 D.4
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Ti liu n thi i hc nm 2012 -2013 Cu 14. Hp th hon ton V lit CO2(ktc) vo bnh ng 200ml dung dch NaOH 1M v Na2CO3 0,5M.C cn dung dch sau phn ng thu c 19,9 gam cht rn khan. Gi tr V l A. 2,24 B.3,36 C.5,6 D.1,12 Cu 15.Cho a gam Fe ( d) vo V1lit Cu(NO3)2 1M thu c m gam rn Cho a gam Fe (d) vo V2 lit AgNO3 1M, sau phn ng thu c m gam rn. Mi lin h V1 v V2 l A. V1 =2 V2 B. V1 =10 V2 C. V1 =V2 D. 10V1 = V2 Cu 16. Ch dng Cu(OH)2/OH- c th phn bit c B. saccaroz, glixerol, andehit axetic, etanol A. lng trng trng, glucoz, fructoz, glixerol D. Glucoz, long trng trng,glixerol, etanol C. glucoz,mantoz,glixerol,andehit axetic Cu 17. Chophn ng sau: X + Cu(OH)2/OH dung dch Y xanh lam. Dung dch Y un nng kt ta Z gch Trong tt c cc cht Glucoz, saccaroz, mantoz, fructoz, tinh bt, andehit axetic, glixerol s cht X ph hp l A. 2 B.5 C.4 D.3 Cu 18. Trong cc cht Xiclopropan, xiclohexan, benzene, stiren, axit axetic, axit acrylic, andehit axetic, andehit acrylic,axeton, etyl axetat, vinyl axetat, imetyl ete s cht c kh nng lm mt mu nc brom l A. 5 B.7 C.6 D.4 Cu 19.in phn (in cc tr) dung dch NaCl v CuSO4(t l mol tng ng l 3:1) n khi catot xut hin bt kh th dng li .sn phm kh thu c anot l A. kh Cl2 B.kh H2 v O2 C.kh Cl2v H2 D.kh Cl2v O2 Cu 20. Cho m gam X gm Fe, FeO, Fe3O4, Fe2O3 vo 400 ml dung dch HCl 2M , sau phn ng thu c 2,24 lit H2 (ktc), dung dc Y, v 2,8 gam Fe khng tan. Gi tr m l. A. 30,0 B.31,6 C.27,2 D.24,4 Cu 21. Ion M2+ c tng s ht proton, electron, ntron, l 80. S ht mang in nhiu hn s ht khng mang in l 20. Trong bng tun hon M thuc B. chu k 4, nhm VIIIA A. chu k 4, nhm VIIIB D. chu k 4, nhm IIA C. chu k 3 nhm VIIIB Cu 22.Trong cc loi polime sau. (1) t tm, (2) si bng, (3) Len, (4) T enang, (5) t visco, (6) nilon 6.6 , (7) t axetat. Loi t c ngun gc xenluloz l A. 2, 5, 7 B. 1, 2, 6 C. 2, 3, 7 D. 2, 3, 5 Cu 23. Cho cc cht. C2H3Cl, C2H4, C2H6, C2H3COOH, C6H11NO (caprolactam), vinyl axetat, phenyl axetat. S cht c kh nng tham gia phn ng trng hp l A. 5 B.3 C.2 D.4 Cu 24. Khi dng qu tm v dung dch brom, khng th phn bit c dy cht . A. C2H5OH, CH3CHO, CH3COOH, CH2=CHCOOH B. CH3CHO, CH3COOH, CH2=CHCOOCH3 C.CH3CHO, C2H 5COOH, CH2=CHCOOH D. C2H5OH, CH2=CHCH2OH, CH3COOH, CH2=CHCOOH Cu 25. Hn hp X gm SO2 v O2 c t khi so vi H2 bng 28. Ly 4,48 lit hn hp X (ktc) cho i qua bnh ng V2O5 nung nng. Hn hp thu c li qua dung dch Ba(OH)2 d thy c 33,19 gam kt tA. Hiu sut phn ng oxi ha SO2 l A.75% B.60% C.40% D.25% Cu 26. Ho tan hon ton 34,8 gam hn hp X ( Gm FeO, Fe3O4, Fe2O3) cn ti thiu Vml dung dch H2SO424,25% (D=1,2 g/ml), sau phn ng thu c hn hp hai mui c s mol bng nhau. Gi tr ca V l A.300 B.400 C.250 D.200 Cu 27. Este X khng no, mch h, c t khi hi so vi Oxi bng 2,6875. Khi X tham gia phn ng x phng ho to ra mt adehit v mt mui ca axit hu c. S ng phn cu to ca X l. A.3 B.4 C.5 D.2
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Ti liu n thi i hc nm 2012 -2013 Cu 28. t chy hon ton 17,6 gam FeS v 12gam FeS2 cho ton b kh thu c vo V ml dung dch NaOH 25% (D=1,28 g/ml) Gi tr ti thiu ca V cn dng l A.100 B.150 C.200 D.50 Cu 29:Khi x phng ha hon ton 1,26 g mt cht bo cn 45 ml dung dch KOH 0,1M. Ch s x phng ha ca cht bo l A. 300 B. 150 C. 200 D. 250 Cu 30. Trn dung dch X cha Ba 2+, OH-(0,17 mol), Na+ (0,02 mol) vi dung dch Y cha HCO -, CO 23 3

(0,03 mol), Na (0,1 mol) thu c m gam kt ta. Gi tr ca m l A.14,775 B.13,79 C.5,91 D.7,88 Cu 31. Trn 3,36 gam andehit n chc X vi mt andehit n chc Y (MX >MY) ri thm nc vo c 0,1 lit dung dch Z vi tng nng cc andehit l 0,8M. Thm t t dung dch AgNO3/NH3 d vo dung dch Z ri tin hnh ung nng n phn ng hon ton thu c 21,6 gam Ag. Cng thc cu to ca X, Y ln lt l B. C2H5CHO v HCHO A. CH3CHO v HCHO D. Khng c nghim C. C2H3CHO v HCHO Cu 32. . Cho cc cht CH3NH2 (1), C6H5NH2 (2), (CH3)2NH (3) , (C6H5)2NH (4), NH3(5) th t tng dn tnh baz l. A. 4, 5, 3, 2, 1 B.4, 2, 5, 1, 3 C.4, 5, 2, 1, 3 D. 2,4, 5,1, 3 Cu 33.phn ng no sau y gii thch s hnh thnh thch nh trong hang ng B. CO2+ Ca(OH)2CaCO3 +H2O A. CaCO3 +CO2+H2O Ca(HCO 3)2 D. Ca(HCO3)2 CaCO3 +CO2+H2O C. CaO + CO2 CaCO3 Cu 34. Cho cc cht sau. HBr, CO2, CH4, NH3, Br2, C2H4, Cl2, C2H2, HCl .S cht m phn t phn cc l A.4 B.5 C.7 D.6 Cu 35. Cho phn ng CO(k) + H2O(k) CO2 (k) + H2 (k) + H <0 Trong cc yu t (1) Tng nhit , (2) thm lng CO, (3) them mt lng H2, (4) gim p sut chung ca h, (5) dung cht xc tc. S yu t lm thay i cn bng l A.2 B.4 C.3 D.1 Cu 36.Trong phng th nghim kh CO2 c iu ch c ln kh HCl, hi nc. thu c CO2 tinh khit ngi ta cho qua A.NaOH, H2SO4 B.NaHCO3, H2SO4 C.Na2CO3, NaCl D.H2SO4 c, Na2CO3 Cu 37. Ho tan hon ton hn hp X ( gm x mol Fe, Y mol Cu, Z mol Fe2O3 v t mol Fe3O4 ) trong dung dch HCl khng thy kh c kh bay ra khi khi bnh, dung dch thu c ch cha 2 mui . Mi quan h gia s mol cc cht c trong hn hp X l A.x+y =2z +2t B.x+y =2z +3t C.x+ y = 2z +2t D.x +y = Z +t Cu 38. Cho 3 cht hu c : glyxin, metylamin, axit glutamic, phn bit 3 cht dng A.NaOH B.Na C.HCl D.Qu tm m Cu 39. Cht hu c X c 1 nhm amino, 1 chc este. Hm lng N c trong X l 15,73%. X phng ho m gam X thu c hi ancol Z, cho Zqua CuO d thu c andehit Y ( phn ng hon ton), cho Y phn ng hon ton AgNO3/NH3d thu c 16,2 gam Ag . Gi tr m l A. 7,725 0 B. 6,675 0 C. 0,3375 D. 5,6250 Cu40 . Ho tan ht 7,2 gam hn hp X gm Al v K vo 100ml dung dch HCl 1M thu c 3,36 lit H2 (ktc). Thnh phn phn trm khi lng Al c trong X l A. 15,00% B. 18,75% C. 35,0% D. 79,69% Cu 41.Cho cc cp kim loi tip xc trc tip Fe-Pb, Fe-Zn, Fe-Sn, Fe-Ni, Fe-Cu,nhng tng cp kim loi vo dung dch axit. S cp kim loi m Fe b n mn trc l A.3 B.4 C.1 D.2 Cu42 .Cho X (ch C, H, O) ch cha 1 loi nhm chc.t chy X th thu c s mol H 2O gp 1,5 mol CO2. Cho 0,15 mol X tc dng va Na thu c m gam rn v 3,36 lit H2(ktc). Gi tr m l A.15,9 B.15,6 C.18,0 D.10,2
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Ti liu n thi i hc nm 2012 -2013 Cu 43. t chy ht 9,984 gam kim loi M (c ho tr II khng i ) trong hn hp kh Cl2 v O2. Sau phn ng thu c 20,73 gam cht rn v th tch hn hp kh phn ng l 3,4272 lit (ktc). M l A. Ca B. Mg C. Zn D. Cu Cu 44. Andehit X c t khi hi so vi H2 bng 36. S cng thc cu to X l A. 4 B. 1 C. 3 D. 2 Cu 45.X gm metanol, etanol, propan-1 ol, v H2O, cho m gam X + Na d thu c 15,68 lit H2(ktc). Mt khc t chy hon ton X thu c Vlit CO2(ktc) v 46,8 gam H2O. Gi tr m v V l A.42,0 v 26,88 B.19,6 v 26,88 C.42 v 42,56 D.61,2 v 26,88 Cu 46. phn bit glucoz, fructoz ngi ta dng A.dung dch Br2 B.AgNO3/NH3 C.Cu(OH)2 D.Na Cu 47. Nung nng 66,2 gam Pb(NO3)2 thu c 53,24 gam cht rn v V lit kh (ktc). G tr ca V v hiu sut phn ng ln lt l. A.9,01 v 80,42% B.6,72 v 60% C.6,72 v50 % D.4,48 v 60% Cu 48. trung ho 8,6 gam axit hu c X n chc mch h, cn 100ml dung dch NaOH 1M. S ng phn ca X l A.2 B.5 C.3 D.4 Cu 49. Khi mt in li quc gia,nhiu gia nh s dng ng c iezen pht in, nhng khng nn chy ng c trong phng kn v B. Tiu th nhiu O2 sinh ra kh CO H2S, SO2 c A. Tiu th nhiu O2 sinh ra kh CO2 c C. Cc hirocacbon khng chy ht l cc kh c D. Sinh ra H2S v SO2 Cu 50: Dung dch X gm Al3+, Fe3+, 0,1 mol Na+, 0,2 mol SO 2-, 0,3 mol Cl-. Cho V lit dung dch NaOH
4

1M vo dung dch X th thu c lng kt ta ln nht. Gi tr ca V l A.0,6 B.0,7 C.0,5 B S 3

D.0,8

Cu 1: Phn ng khng thc hin c l A. C2H4 + O2 CH3COOH B. CH3COCH3 + Br2 CH3-CO-CH2Br + HBr C. CH3OH + CO CH3COOH D. C2H5ONa + H2O C2H5OH + NaOH Cu 2: Cho cc th nghim sau y: (1) Nung hn hp NaNO2 v NH4Cl (2) in phn dung dch CuSO4 (3) Dn kh NH3 qua CuO nung nng (4) Nhit phn Ba(NO3)2 (5) Cho kh F2 tc dng vi H2O (6) H2O2 tc dng vi KNO2 (7) Cho kh O3 tc dng vi dung dch KI (8) in phn NaOH nng chy (9) Dn hi nc qua than nng (10) Nhit phn KMnO4 S th nghim thu c kh oxi l A. 7 B. 6 C. 4 D. 5 Cu 3: X l mt hidrocacbon, mch h. X phn ng vi hidro d (xc tc Ni, un nng) thu c butan. S cng thc cu to ca X tho mn (khng k ng phn hnh hc) l A. 10. B. 7 C. 8 D. 9 Cu 4: Nhm cc vt liu polime c iu ch bng phn ng trng hp A. Cao su buna-S, t lapsan, t axetat B. T enang, thu tinh hu c, PE C. Poli(vinyl clorua), nha rezol, PVA D. Polipropilen, t olon, cao su buna Cu 5: Trong s cc cht sau: FeCl3, Cl2, HNO3, HI, H2S v H2SO4 c. Cht tc dng vi dung dch Fe2+ to thnh Fe3+ l A. H2SO4 c, Cl2 v HNO3 B. Cl2, HI v H2SO4 c C. HNO3, H2SO4 c v FeCl3 D. H2S v Cl2 Cu 6: Cho s bin ha sau (mi mi tn l mt phng trnh): + C2 H 4 + Cl2 ,as + NaOH X Benzen Z. (Bit Y l sn phm chnh). Cng thc cu to ca Z l Y t 0 , xt A. o & p-C2H5-C6H4-OH B. C6H5CH(OH)CH3 C. C6H5CH2CH2OH D. o & p-C2H5-C6H4-ONa
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Ti liu n thi i hc nm 2012 -2013 Cu 7: Cho m gam hn hp X gm Fe3O4 v Cu vo dung dch HNO3, thu c dung dch Y, c 4,48 lt (ktc) hn hp Z gm NO v NO2 (c t khi so vi hiro bng 19) thot ra v cn li 6 gam cht rn khng tan. Cho dung dch KOH d vo dung dch Y, lc tch kt ta v nung trong khng kh n khi lng khng i thu c 80 gam cht rn. Thnh phn phn trm v khi lng ca Cu trong hn hp X l A. 38,72% B. 61,28% C. 59,49% D. 40,51% Cu 8: Cho cc phn ng sau: (a) KMnO4 + HCl c (b) FeS + H2SO4 long kh X kh Y (c) NH4HCO3 + Ba(OH)2 (d) Kh X + kh Y kh Z rn R + kh E (e) Kh X + kh Z kh E + kh G Trong s cc kh X, Y, Z, E, G trn, cc kh tc dng vi dung dch NaOH iu kin thng l A. X, Y, Z, E B. X, Y, G C. X, Y, E D. X, Y, E, G Cu 9: Cao su buna c th iu ch theo s sau: 80% 90% 85% 95% Xenluloz glucoz C2H5OH C4H6 cao su buna iu ch c mt tn cao su buna th cn m tn mn ca cha 50% xenluloz. Gi tr ca m l A. 8,57 B. 5,74 C. 3,49 D. 10,32 Cu 10: Este n chc, mch thng X cha 32% oxi v khi lng, khi thu phn X, cho sn phm c kh nng tham gia phn ng trng gng. S ng phn cu to ph hp vi X l A. 5 B. 4 C. 3 D. 6. Cu 11: Chia m gam hn hp X gm Fe, FeO, Fe 3O4 v Fe2O3 lm hai phn bng nhau. Phn mt, tc dng vi dung dch HCl va , thu c dung dch cha 24,15 gam cht tan, ng thi thy thot ra V lt H 2. Ho tan phn hai bng dung dch HNO3 long d, thu c dung dch cha 39,93 gam mui v 1,5V lt kh NO (sn phm kh duy nht). Bit cc th tch o iu kin tiu chun. Gi tr ca m v V ln lt l A. 25,20 v 1,008 B. 24,24 v 0,672 C. 24,24 v 1,008 D. 25,20 v 0,672 Cu 12: t chy hon ton 0,08 mol hn hp hai ancol no, n chc, mch h, bc mt thu c 3,96 gam H2O. Nu oxi ho 0,1 mol hn hp hai ancol trn bng oxi, xc tc Cu vi H = 100%, thu c hn hp anehit. Cho hn hp anehit trn tc dng vi dung dch AgNO3 d trong NH3, thu m gam Ag. Gi tr m l A. 21,6 m < 43,2 B. m = 43,2 C. m =21,6 D. 27,0 m < 43,2 Cu 13: Cho cc pht biu sau: (1) Hn hp CaF2 v H2SO4 c n mn c thu tinh (2) in phn dung dch hn hp KF v HF thu c kh F2 anot (3) Amophot l hn hp gm (NH4)2HPO4 v (NH4)3PO4 thu c khi cho NH3 tc dng vi H3PO4 (4) Trong cng nghip ngi ta sn xut nc Giaven bng cch in phn dung dch NaCl c mng ngn (5) Trong mt pin in ho, anot xy ra s kh, cn catot xy ra s oxi ho (6) CrO3 l oxit axit, Cr2O3 l oxit lng tnh cn CrO l oxit baz (7) iu ch HI bng cch cho NaI (rn) tc dng vi H2SO4 c, d (8) Cc cht: Cl2, NO2, HCl c, P, SO2, N2, Fe3O4, S, H2O2 u va c tnh oxi ho, va c tnh kh (9) Ngy nay cc hp cht CFC khng c s dng lm cht sinh hn trong t lnh do khi thi ra ngoi kh quyn n ph hy tng ozon (10) i t flo n iot nhit nng chy v nhit si ca cc halogen gim dn S pht biu ng l A. 3 B. 5 C. 4 D. 6 Cu 14: Cho 11,2 lt (ktc) hn hp X gm eten, propen v hiro c t khi so vi heli bng 3,94. Trong X, t l mol ca eten v propen l 2 : 3. Dn X qua bt Ni, t 0 thu c hn hp Y c t khi so vi hidro bng 12,3125 (gi s hiu sut phn ng hiro ho hai anken l nh nhau). Dn Y qua bnh cha dung dch brom d thy khi lng bnh brom tng m gam. Gi tr ca m l A. 0,728 B. 3,200 C. 6,400 D. 1,456 Cu 15: Dy gm cc cht va tc dng vi dung dch NaOH, va tc dng vi dung dch HCl l A. Al2O3, KHSO3, Mg(NO3)2, Zn(OH)2 B. NaHCO3, Cr2O3, KH2PO4, Al(NO3)3 C. Cr(OH)3, FeCO3, NH4HCO3, K2HPO4 D. (NH4)2CO3, AgNO3, NaHS, ZnO Cu 16: Hp th hon ton 4,48 lt CO2 (ktc) vo 200 ml dung dch cha ng thi Na 2CO3 0,5M, KOH 0,25M v NaOH 0,5M thu c dung dch X. Cho dung dch BaCl 2 d vo dung dch X, sau phn ng thu c m gam kt ta. Gi tr ca m l
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Ti liu n thi i hc nm 2012 -2013 A. 19,70 B. 11,82 C. 29,55 D. 9,85 Cu 17: Cho cc nhn nh sau: (1) Peptit cha t hai gc aminoaxit tr ln th c phn ng mu biure (2) T tm l polipeptit c cu to ch yu t cc gc ca glyxin, alanin (3) ng vi cng thc phn t C3H7O2N c hai ng phn aminoaxit (4) Khi cho propan 1,2 iamin tc dng HNO2 thu c ancol a chc (5) Tnh baz ca C6H5ONa mnh hn tnh baz ca C2H5ONa (6) Cc cht HCOOH, HCOONa v HCOOCH3 u tham gia phn ng trng gng Cc nhn nh ng l A. 1, 3, 4, 6. B. 2, 3, 4, 6 C. 1, 2, 3, 5 D. 1, 2, 4, 6 Cu 18: Khi cho ankan A ( th kh iu kin thng) tc dng vi brom un nng, thu c hn hp X cha mt s dn xut brom, trong dn xut cha nhiu brom nht c t khi so vi hiro l 101. S dn xut brom trong X cha A. 7 B. 6 C. 5 D. 4 Cu 19: Ho tan m gam hn hp X gm photpho v lu hunh bng 376 ml dung dch HNO 3 10% (D = 1,34 gam/ml), sau phn ng thu c dung dch Y v 13,44 lt NO duy nht iu kin tiu chun. trung ho mt na dung dch Y cn dng 550 ml dung dch NaOH 1M. Gi tr ca m l A. 12,775 B. 11,875 C. 10,607 D. 10,575 Cu 20: Xt cc trng hp sau: (1) t dy Fe trong kh Cl2 (2) Kim loi Zn trong dung dch HCl (3) Thp cacbon trong khng kh m (4) Kim loi Zn trong dd HCl c thm vi git dung dch Cu2+ (5) Ngm l Cu trong dung dch FeCl3 (6) Ngm inh Fe trong dung dch CuSO4 (7) Ngm inh Fe trong dung dch FeCl3 (8) Dy in bng Al ni vi Cu trong khng kh m S trng hp xy ra n mn in ho l A. 3 B. 5 C. 6 D. 4 Cu 21: Cho m gam Ba tan hon ton ton trong nc thu c 300 ml dung dch X. Cng cho m gam Al 2O3 tan va ht trong dung dch H2SO4 thu c dung dch Y. Trn t t n ht 300 ml dung dch X vo dung dch Y, sau khi phn ng kt thc thu c 4,275 gam kt ta. Dung dch X c pH bng A. 12 B. 11 C. 13 D. 10 Cu 22: Ha tan ht 36,3 gam hn hp X gm Mg, Al, Zn, Fe trong dung dch H 2SO4 long (d), sau phn ng thu c 25,76 lit H2 (ktc). Mt khc nu t ht hn hp X trn trong O2 d thu c 55,5 gam cht rn. Phn trm theo khi lng ca Fe c trong hn hp X l A. 17,04 % B. 24,06 % C. 15,43 % D. 36,24 % Cu 23: Cho cc cp cht sau: (a) H2S + dung dch FeCl3 (b) Cho bt lu hunh + thu ngn (c) H2SO4 c + Ca3(PO4)2 (d) HBr c + FeCl3 (e) ZnS + dung dch HCl (f) Cl2 + O2 (g) Ca3(PO4)2 + H3PO4 (h) Si + dung dch NaOH (i) Cr + dung dch Sn2+ (k) H3PO4 + K2HPO4 S cp cht xy ra phn ng l A. 5 B. 7 C. 6 D. 8 Cu 24: Cho hn hp cha 0,2 mol axit propanoic v 0,1 mol metyl axetat phn ng vi dung dch cha 0,25 mol KOH. C cn dung dch sau phn ng thu uc m gam cht rn. Gi tr ca m l A. 31,7 B. 27,3 C. 26,6 D. 30,3 Cu 25: Trung ho 14,4 gam mt axit cacboxylic n chc cn dng 250 ml dung dch hn hp NaOH 0,2M v Ba(OH)2 x mol/lt. C cn dung dch sau phn ng thu c 25,625 gam hn hp mui khan. Gi tr ca x bng A. 0,345 B. 0,265 C. 0,400 D. 0,300 Cu 26: Cho 12,12 gam hn hp X gm Al v Fe tc dng vi dung dch HCl, sau phn ng thu c 400 ml dung dch Y cha 43,4 gam cht tan, bit dung dch Y c pH bng 1. Cng 12,12 gam X tc dng vi dung dch AgNO3 d thu c m gam kt ta. Gi tr ca m l A. 108,00 B. 103,68 C. 106,92 D. 90,72 Cu 27: C cc dung dch khng mu cha trong cc l ring bit khng nhn sau: AgNO3, HCl, NaNO3, NaCl, FeCl3 v Fe(NO3)2. Ch dng kim loi Cu th s dung dch phn bit c l
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Ti liu n thi i hc nm 2012 -2013 A. 3 B. 5 C. 4 D. 6 0 2+ 0 Cu 28:Cho th in cc chun ca cc kim loi: E Ni /Ni = - 0,26V; E Cu2+/Cu = + 0,34V Gi tr sut in ng chun E0 ca pin in ha Ni-Cu l A. + 0,08V B. +0,60V C. 0,08V D. 0,60V Cu 29: Hn hp X gm vinylaxetilen, eten v propin c t khi so vi hidro bng 17. t chy hon ton mt lng X thu c CO2 v 3,6 gam H2O. Nu dn ton b sn phm chy qua dung dch Ca(OH) 2 d th thu c m gam kt ta. Gi tr ca m l A. 12,5 B. 25,0 C. 37,5 D. 50,0 Cu 30: Cho cc nhn xt sau: (1) Lin kt trong hp cht hu c ch yu l lin kt cng ho tr (2) Phn ng hu c thng xy ra khng hon ton v theo nhiu hng (3) Ngi ta dng phng php chit tch hn hp ru etylic v nc (4) Hidrocacbon khng no, mch h cha hai lin kt l ankaien (5) Trong vinylaxetilen c 5 lin kt S nhn xt khng ng l A. 3 B. 1 C. 4 D. 2 Cu 31: in phn 200 ml dung dch X cha Cu(NO3)2 v AgNO3 vi cng dng in 0,804A n khi bt kh bt u thot ra catot th mt 2 gi, khi khi lng catot tng thm 4,2 gam. Nng mol ca Cu(NO3)2 trong dung dch X l A. 0,075M B. 0,1M C. 0,05M D. 0,15M Cu 32: X l mt -amino axit cha mt nhm chc axit. Cho X tc dng vi 200 ml dung dch HCl 1M thu uc dung dch Y. phn ng ht vi cc cht trong Y cn dng 300 ml dung dch NaOH 1M. C cn dung dch sau phn ng thu c 22,8 gam hn hp mui. Tn gi ca X l A. axit 2-aminobutanoic B. axit 2- aminopropanoic C. axit 3- aminopropanoic D. axit 2-amino- 2-metylpropanoic Cu 33: Cho mt dung dch cha 3,045 gam hn hp gm hai mui NaX v NaY (X, Y l hai nguyn t halogen c trong t nhin, hai chu k lin tip, s hiu nguyn t Z X < ZY) vo dung dch AgNO3 d, thu c 5,47 gam kt ta. Phn trm khi lng ca NaY trong hn hp ban u l A. 15,84% B. 9,76% C. 11,16 % D. 20,35% Cu 34: Hn hp X gm hai este ng phn ca nhau. Ly 0,3 mol X tc dng vi 400 ml dung dch NaOH 1M, sau phn ng hon ton thu c 12,75 gam hn hp hai ancol ng ng k tip, c cn dung dch sau phn ng c cht rn Y. Nung Y trong khng kh n phn ng hon ton thu c 17,36 lt CO 2 ktc; 10,35 gam nc v mt lng Na2CO3. Cng thc phn t ca hai este l A. C2H3COOC2H5, C3H5COOCH3 B. C2H3COOC3H7, C3H5COOC2H5 C. C2H5COOC2H5, C3H7COOCH3 D. C2H5COOC3H7, C3H7COOCH3 Cu 35: Khi cho kim loi Mg tc dng vi HNO3, sau phn ng thu c sn phm kh Y duy nht, bit s phn t HNO3 khng b kh gp 4 ln s phn t HNO3 b kh. Tng h s ca cc cht (l cc s nguyn ti gin) c trong phng trnh khi cn bng l A. 24 B. 22 C. 20 D. 29 Cu 36: Cho 28,2 gam hn hp hai ancol n chc tc dng ht vi 11,5 gam Na, sau phn ng thu 39,3 gam cht rn. Nu em tch nc 28,2 gam hn hp trn 140 0C, H2SO4 c th thu c m gam ete. Gi tr ca m l A. 19,2 B. 24,6 C. 23,7 D. 21,0 Cu 37: Trong mt bnh kn dung tch V lt khng i c cha 1,3a mol O 2 v 2,5a mol SO2 100oC, 2 atm (c mt xc tc V2O5), nung nng bnh mt thi gian sau a bnh v nhit ban u, p sut trong bnh lc l p, hiu sut phn ng l h. Biu thc lin h gia h v p l 1, 25h 1, 25h 0, 65h 2,5h A. p = 2. 1 B. p = 2. 2 C. p = 2. 1 D. p = 2. 1 3,8 1,9 3,8 3,8 Cu 38: X phng ho hon ton 500 kg mt loi cht bo cn m (kg) dung dch NaOH 16%, sau phn ng thu c 506,625 kg x phng v 17,25 kg glixerol. Gi tr ca m l A. 400,000 B. 140,625 C. 149,219 D. 156,250
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Ti liu n thi i hc nm 2012 -2013 Cu 39: ng vi cng thc phn t C 3H8On c x ng phn ancol bn, trong c y ng phn c kh nng ho tan Cu(OH)2. Cc gi tr x, y ln lt l A. 5; 2 B. 4; 3 C. 4; 2 D. 5; 3 Cu 40: Cho cn bng sau (trong bnh kn): CO2 (k) + H2 (k) CO (k) + H2O (k) H > 0 Khi h ang trng thi cn bng, tc ng mt trong cc yu t sau: (1) tng nhit ; (2) thm mt lng hi nc; (3) gim p sut; (4) dng cht xc tc; (5) thm mt lng CO2. Tc ng lm cn bng chuyn dch theo chiu thun l A. (1), (3), (5) B. (1), (5) C. (5) D. (2), (3), (4) Cu 41: Cho s chuyn ho sau: KCl X K2CO3 Y KCl (vi X, Y l cc hp cht ca kali). X v Y ln lt l A. KOH v K2O B. K2SO4 v K2O C. KOH v K2SO4 D. KHCO3 v KNO3 Cu 42: S ng phn ancol C5H12O khi tch nc 1700C, xc tc H2SO4 c cho mt olefin duy nht l A. 5 B. 3 C. 4 D. 2 Cu 43: Trn 120 ml dung dch NaOH 3M vi 200 ml dung dch Al 2(SO4)3 nng a mol/lt, phn ng hon ton thu c kt ta X v dung dch Y. Thm tip 60 ml dung dch NaOH 3M vo dung dch Y, khuy k phn ng hon ton th thy khi lng kt ta X tng thm, bit tng khi lng kt ta X thu c l 12,48 gam. Gi tr ca a l A. 0,5325 B. 0,8750 C. 0,4375 D. 0,4735 Cu 44: Ho tan 10,65 gam hn hp gm mt oxit kim loi kim v mt oxit kim loi kim th bng dung dch HCl d, thu c dung dch X. C cn dung dch X, ly mui khan em in phn nng chy hon ton th thu c 3,36 lt kh (ktc) anot v a gam hn hp kim loi catot. Gi tr ca a l A. 8,25 B. 9,45 C. 9,05 D. 5,85 2+ Cu 45: Dn 5,6 lt axetilen ( ktc) qua cc nc cha Hg , un nng nh. Dn ton b kh thot ra qua dung dch AgNO3/NH3 d thu c 55,2 gam kt ta. Nu dn kh thot ra qua lng d dung dch nc Br 2 th c m gam brom phn ng. Gi tr ca m l A. 32 B. 48 C. 40 D. 16 Cu 46: X l axit hu c no, mch h c cng thc phn t CxHyOz. Mi quan h ca x, y, z l z A. y = 2 x + 2 B. y = 2 x + z 2 C. y = 2 x z + 2 D. y = 2 x + 2 2 Cu 47: Cho cc dung dch: axit axetic, etylenglicol, glucoz, saccaroz, xenluloz, glixerol, phenol. S dung dch ho tan c Cu(OH)2 iu kin thng l A. 6 B. 3 C. 5 D. 4 Cu 48: Oxi ho 6,4 gam mt ancol n chc thu c 9,92 gam hn hp X gm anehit, axit, nc v ancol d. Nu cho hn hp X tc dng ht vi NaHCO 3 th thu c 1,344 lt CO2 ktc. Nu cho hn hp X tc dng vi dung dch AgNO3/NH3 d th khi lng kim loi bc thu c l A. 34,50 gam B. 45,90 gam C. 56,16 gam D. 21,60 gam Cu 49: Trng hp no sau y c coi l khng kh sch (% theo th tch) A. Khng kh cha 78% N2, 18% O2, 4% hn hp CO2, SO2 v HCl B. Khng kh cha 78% N2, 21% O2, 1% hn hp SO2, H2S v CO2 C. Khng kh cha 78% N2, 20% O2, 2% hn hp CH4, CO2 v HCl D. Khng kh cha 78% N2, 21% O2, 1% hn hp CO2, H2O v H2 Cu 50: C phng trnh ion rt gn sau: Cu + 2Ag+ Cu2+ + 2Ag Pht biu khng ng l A. Cu c tnh kh mnh hn Ag B. Cu2+ khng oxi ho c Ag C. Kim loi Cu b kh bi Ag+ D. Ag+ b kh bi kim loi Cu

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Ti liu n thi i hc nm 2012 -2013 B S 4 Cu 1: t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO 2 bng s mol H2O. Thnh phn phn trm v s mol ca X v Y trong hn hp M ln lt l A. 50% v 50%. B. 35% v 65%. C. 20% v 80%. D. 75% v 25%. Cu 2: Thm 500 ml dung dch NaOH 1M vo 150 ml dung dch H 3PO4 2M. Mui to thnh v khi lng tng ng l A. 28,4 gam Na2HPO4 ; 16,4 gam Na3PO4. B. 24 gam NaH2PO4 ; 14,2 gam Na3PO4. C. 12gam NaH2PO4 ; 28,4 gam Na2 HPO4. D. 14,2 gam Na2HPO4 ; 32,8 gam Na3PO4. Cu 3: Cho cc phn ng : t0 (a)HBr + C2H5OH (b) C2H4 + Br2 (c) C2H4 + HBr
askt(1:1mol) (d) C2H6 + Br2 . S phn ng to ra C2H5Br l : A. 4 B. 2. C. 3 D. 1 Cu 4: Trong phng th nghim, ngi ta thng iu ch clo bng cch A. cho dung dch HCl c tc dng vi MnO2, un nng. B. cho F2 y Cl2 ra khi dung dch NaCl C. in phn nng chy NaCl. D. in phn dung dch NaCl c mng ngn. Cu 5: Cho cc cht rn ring bit: BaCO 3, BaSO4, Na2CO3, Na2SO4, NaCl. Nu ch dng nc v CO 2 th s cht c th phn bit c l A. 4 B. 0 C. 5 D. 3 Cu 6: Lin kt ho hc gia cc nguyn t trong phn t H2O l lin kt A. cng ho tr phn cc. B. ion. C. hiro. D. cng ho tr khng phn cc. Cu 7: Cho cc dung dch c cng nng : K2CO3 (1), H2SO4 (2), HNO3 (3), NH4NO3 (4). Gi tr pH ca cc dung dch c sp xp theo chiu tng t tri sang phi l: A. (3), (2), (4), (1). B. (2), (3), (4), (1). C. (4), (1), (2), (3). D. (1), (2), (3), (4). Cu 8: Cho 8,04 gam hn hp hi gm CH 3CHO v C2H2 tc dng hon ton vi dung dch AgNO 3/NH3 thu c 55,2 gam kt ta. Cho ton b kt ta ny vo dung dch HCl d, sau khi kt thc phn ng cn li m gam cht khng tan. Gi tr ca m l A. 55,20 B. 41,69 C. 61,78 D. 21,60 Cu 9: Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l A. protit lun cha chc hiroxyl. B. protit lun cha nit. C. protit lun l cht hu c no. D. protit c khi lng phn t ln hn. Cu 10: Trong cng nghip, axeton c iu ch t: A. propan-2-ol. B. xiclopropan. C. propan-1-ol. D. cumen Cu 11: Khi cho 0,03 mol CO2 hoc 0,09 mol CO2 hp th ht vo 120ml dung dch Ba(OH)2 th lng kt ta thu c u nh nhau. Nng mol ca dung dch Ba(OH)2 dng l A. 1,0 B. 1,5 C. 0,5 D. 2,0 Cu 12: Cho cc nguyn t M (Z = 11), X (Z = 17), Y (Z = 9) v R (Z = 19). m in ca cc nguyn t tng dn theo th t: A. R < M < X < Y. B. M < X < Y < R. C. Y < M < X < R. D. M < X < R < Y. Cu 13: C bao nhiu ancol bc 2, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18%? A. 5. B. 3. C. 4. D. 2. Cu 14: S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l: A. 3. B. 4. C. 5. D. 2. Cu 15: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l: A. CH3COOH, HCOOH, C2H5OH, CH3CHO. B. CH3COOH, C2H5OH, HCOOH, CH3CHO. C. CH3CHO, C2H5OH, HCOOH, CH3COOH. D. HCOOH, CH3COOH, C2H5OH, CH3CHO. Cu 16: Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC.

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Ti liu n thi i hc nm 2012 -2013 tng hp 500 kg PVC theo s trn th cn V m 3 kh thin nhin ( ktc). Gi tr ca V l (bit CH 4 chim 80% th tch kh thin nhin v hiu sut ca c qu trnh l 50%). A. 448,0. B. 716,8. C. 573,4. D. 896,0. 2+ Cu 17: Cho dy cc cht v ion: Mg, F 2, S, SO2, NH3, N2, O3, HCl, Cu , Cl , Fe2O3. S cht v ion c c tnh oxi ha v tnh kh l: A. 5. B. 7. C. 6. D. 4. Cu 18: X phng ho hon ton 22,2 gam hn hp gm hai este HCOOC 2H5 v CH3COOCH3 bng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l: A. 300 ml. B. 400 ml. C. 150 ml. D. 200 ml. Cu 19: Ha tan 19,2 gam bt Cu bng 400 ml dung dch HNO 3 0,5 M v H2SO4 1,0 M. Sau khi phn ng hon ton thu c kh NO v dung dch X. Khi lng mui thu c trong dung dch X l A. 48,0 gam. B. 15,8 gam. C. 70,0 gam. D. 56,4 gam. Cu 20: Trong phn ng: K2Cr2O7 + HCl CrCl3 + Cl2 + KCl + H2O S phn t HCl ng vai tr cht kh bng k ln tng s phn t HCl tham gia phn ng. Gi tr ca k l A. 3/14. B. 3/7. C. 4/7. D. 1/7. Cu 21: Trong cc cht: xiclopropan, benzen, stiren, metyl acrylat, vinyl axetat, imetyl ete, s cht c kh nng lm mt mu nc brom l A. 6. B. 4. C. 3. D. 5. Cu 22: Cho cc hp cht sau: (a) HOCH 2-CH2OH; (b)HOCH2CH2CH2OH; (c)HOCH2-CH(OH)-CH2OH; (d)CH3CH(OH)CH2OH; (e) CH3-CH2OH; (f) CH3-O-CH2CH3. Cc cht u tc dng c vi Na v Cu(OH)2 l: A. (a), (b), (c). B. (c), (d), (e). C. (a), (c), (d). D. (c), (d), (f). Cu 23: Cho s chuyn ha sau (mi mi tn l mt phng trnh phn ng): Tinh bt X Y Z metyl axetat. Cc cht Y, Z trong s trn ln lt l: A. CH3COOH, C2H5OH. B. CH3COOH, CH3OH. C. C2H5OH, CH3COOH. D. C2H4, CH3COOH. Cu 24: Thy phn ht hn hp gm m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32 gam Ala Ala v 27,72 gam Ala Ala Ala. Gi tr ca m l A. 90,60 B. 66,44 C. 111,74 D. 81,54 Cu 25: S ng phn este ng vi cng thc phn t C4H8O2 l A. 2. B. 5. C. 6. D. 4. Cu 26: Cho lung kh CO (d) qua hn hp cc oxit CuO, Fe 2O3, ZnO, MgO nung nhit cao. Sau phn ng hn hp rn cn li l A. Cu, Fe, Zn, MgO. B. Cu, Fe, ZnO, MgO. C. Cu, Fe, Zn, Mg. D. Cu, FeO, ZnO, MgO. Cu 27: Cho cc cht: H2N-CH2-COOH; HOOC-CH2-CH2-CH(NH2)-COOH; H2NCH2COOC2H5; CH3COONH4; C2H5NH3NO3. S cht lng tnh l A. 2 B. 5 C. 3 D. 4 Cu 28: Cho 5,7 gam hn hp bt P gm Mg, Al, Zn, Cu tc dng hon ton vi oxi d thu c hn hp rn Q c khi lng l 8,1 gam. Th tch ti thiu dung dch HCl 1M cn dng ho tan hon ton Q l A. 300 ml B. 270 ml C. 360 ml D. 180 ml Cu 29: X phng ha 265,2 kg cht bo c ch s axit bng 7 cn 56,84 kg dung dch NaOH 15%. Khi lng glixerol thu c l (gi s phn ng xy ra hon ton v ch s axit l s mg KOH dng trung ha ht lng axit t do c trong 1 gam cht bo): A. 4,6 kg B. 4,62 kg C. 5,52 kg D. 5,98 kg Cu 30: t chy hon ton mt hirocacbon X thu c 0,165 mol CO 2 v 0,198 mol H2O. Khi X tc dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. X l A. etan. B. 2,2-dimetylpropan . C. 2-metylpropan. D. 2-Metylbutan. Cu 31: Cho dung dch Ba(HCO3)2 ln lt tc dng vi cc dung dch sau: NaOH, NaHSO 4, HCl, KHCO3, K2CO3, H2SO4. S trng hp xy ra phn ng v s trng hp c kt ta l A. 5 v 4 B. 5 v 2 C. 4 v 4 D. 6 v 5 Cu 32: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l: A. C2H4(OH)2, CH3OH, CH3CHO. B. CH3CHO, C6H12O6 (glucoz), CH3OH.
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C. CH3CHO, C2H5OH, C2H5COOCH3. Cu 33: Phn ng nhit phn khng ng l

t N2 + 2H2O. A. NH4NO2
0 0

Ti liu n thi i hc nm 2012 -2013 D. CH3OH, C2H5OH, CH3CHO

t 2NaNO2 + O2. B. 2NaNO3
0 0

t t NH3 + HCl. KOH + CO2. C. NH4Cl D. KHCO3 Cu 34: Dy gm cc cht u c kh nng tham gia phn ng trng hp l: A. buta-1,3-ien; cumen; etilen; trans-but-2-en. B. stiren; clobenzen; isopren; but-1-en. C. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. D. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua. Cu 35: Cho 13,44 lt kh clo ( ktc) i qua 2,5 lt dung dch KOH 100 0C. Sau khi phn ng xy ra hon ton, thu c 37,25 gam KCl. Dung dch KOH trn c nng l A. 0,48 B. 0,20 C. 0,24 D. 0,40 Cu 36: C 6 ng nghim, mi ng nghim cha mt trong cc dung dch sau: glixerol; glucoz; lng trng trng; axit fomic; natri hiroxit; axit axetic . phn bit 6 dung dch ny c th dng mt loi thuc th l A. Qi tm. B. AgNO3/NH3. C. CuSO4. D. Br2. Cu 37: Dy cht khi phn ng vi HNO3 c, nng u c kh NO2 bay ra l A. Fe, BaCO3, Al(OH)3, ZnS. B. CaSO3, Fe(OH)2, Cu, ZnO. C. Fe2O3, CuS, NaNO2, NaI. D. Fe3O4, S, As2S3, Cu. Cu 38: Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy nht l xeton Y (t khi hi ca Y so vi kh hiro bng 29). Cng thc cu to ca X l A. CH3-CHOH-CH3. B. CH3-CH2-CH2-OH. C. CH3-CH2-CHOH-CH3. D. CH3-CO-CH3. to 2NH 3 (k) . Cu 39: Cho phng trnh ha hc ca phn ng tng hp amoniac. N 2 (k) + 3H 2 (k)
xt

Khi tng nng ca hiro ln 3 ln, tc phn ng thun A. tng ln 27 ln. B. tng ln 6 ln. C. tng ln 9 ln. D. gim i 3 ln. Cu 40: t chy hon ton m gam FeS2 bng mt lng O2 va thu c kh X. Hp th ht X vo 1 lt dung dch cha Ba(OH)2 0,2M v KOH 0,2M thu c dung dch Y v 32,55 gam kt ta. Cho dung dch NaOH vo dung dch Y li thy xut hin thm kt ta. Gi tr ca m l A. 30 B. 27 C. 24 D. 36 Cu 41: Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 9,55 gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l A. 5. B. 3. C. 4. D. 2. Cu 42: Nhm cht kh (hoc cht hi) u gy hiu ng nh knh khi nng ca chng trong kh quyn vt qu tiu chun cho php l A. CO2 v O2 B. N2 v CO C. CH4 v H2O D. CO2 v CH4 Cu 43: Khi nhit phn hon ton 100 gam mi cht sau: KClO 3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht to ra lng O2 ln nht l A. KNO3. B. KClO3. C. AgNO3. D. KMnO4. Cu 44: Kh H2S c th y c axit H2SO4 ra khi dung dch A. FeSO4 B. CuSO4 C. ZnSO4 D. Na2SO4 Cu 45: Nung hn hp gm 11,2g Fe; 6,4g Cu v 26g Zn vi mt lng d lu hunh n hon ton. Sn phm ca phn ng tc dng vi dung dich HCl d thu c kh A . Th tch dung dch CuSO 4 10% (d = 1,1g/ml) ti thiu cn dng hp th ht kh A l A. 750,25 ml B. 872,73 ml C. 525,25 ml D. 1018,18 ml Cu 46: Phn ng m HCl ng vai tr l cht oxi ha l A. NaOH + HCl NaCl + H2O B. Fe + KNO3 + 4HCl FeCl3 +KCl + NO + 2H2O C. MnO2 + 4HCl MnCl2 + Cl2 + 2H2O D. Fe + 2HCl FeCl2 + H2 Cu 47: Cng thc phn t ca hp cht to bi nguyn t R v hiro l RH 3. Trong oxit m R c ho tr cao nht th oxi chim 56,338 % v khi lng. Nguyn t R l A. P. B. N. C. As. D. S.
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Ti liu n thi i hc nm 2012 -2013 Cu 48: t chy hon ton m gam hn hp X gm hai anehit no, n chc, mch h thu c 0,4 mol CO 2. Mt khc hiro ha hon ton m gam X cn 0,2 mol H2 (Ni, to), sau phn ng thu c hai ancol no n chc. t chy hon ton hn hp hai ancol ny th s mol H2O thu c l A. 0,3 B. 0,6 C. 0,4 D. 0,5 Cu 49: Dung dch X c cha: 0,07 mol Na+; 0,02 mol SO42- v x mol OH-. Dung dch Y c cha Cl, NO3 v y mol H+; tng s mol Cl, NO3 l 0,04. Trn X v Y c 100 ml dung dch Z. Dung dch Z c pH (b qua s in li ca H2O) l A. 1. B. 12. C. 13. D. 2. Cu 50: Trung ho 8,2 gam hn hp gm axit fomic v mt axit n chc X cn 100 ml dung dch NaOH 1,5M. Nu cho 8,2 gam hn hp trn tc dng vi mt lng d dung dch AgNO 3 trong NH3, un nng th thu c 21,6 gam Ag. X l A. axit acrylic. B. axit propanoic. C. axit etanoic. D. axit metacrylic. B S 5 Cu 1. Cho cc polime: (1)polietilen,(2)poli(metylmetacrilat),(3)polibutaien,(4)polisitiren,(5) poli(vynilaxetat) v (6) t nilon-6,6.Trong cc polime trn cc polime b thy phn trong dung dch axit v trong dung dch kim l A.(2),(3),(6) B.(2),(5),(6) C.(1),(4),(5) D.(1),(2),(5) Cu 2. phn ng ht vi mt lng hn hp gm hai cht hu c n chc X v Y (M X < MY) cn va ht 300ml dung dch NaOH 1M. Sau phn ng xy ra hon ton thu c 28,2g mt mui v m gam mt ancol. t chy hon ton m gam ancol thu c 4,48 l CO2(ktc) v 5,4g nc. Y l A.etylfomat B.etylacrylat C.etylaxetat D.etylpropionat Cu 3 .Hai cht hu c X, Y c thnh phn phn t gm C, H, O (M X <MY<82 ).C X v Y u c kh nng tham gia phn ng trng bc v u phn ng c vi dung dch NaHCO 3 sinh ra kh CO2.T khi ca hi ca Y so vi X c gi tr l A.1,47 B.1,61 C.1,57 D. 1,91 Cu 4 .S ancol n chc ng phn cu to ca nhau m khi cho 4,4 gam mt trong cc ng phn tc dng vi Na d th thot ra 0,05 gam H2 l A.2 B.8 C.4 D.17 Cu 5 .Cho cc cht: Saccaroz,Glucoz,Fructoz,Etylfomat,Axit fomic v Anhitaxetic.Trong cc cht trn,s cht va c kh nng tham gia phn ng trng bc va c kh nng phn ng vi Cu(OH) 2 iu kin thng l A.2 B.3 C.4 D.5 Cu 6 .in phn 200ml dung dch NaCl 2M, in cc tr,vch ngn (d=1,1g/ml) cho n khi catot thot ra 20,9 lit kh (ktc) th dng li.Nng phn trm ca dung dch sau khi in phn l: A.34,84% B.9,32% C.30,85% D.8,32% Cu 7:Ha tan ht hn hp nhm v magie vo dung dch H 2SO4 9,8% va thu c dung dch hn hp Al2(SO4)3 x% v MgSO4 3,627%.Gi tr ca x l A.15,524 B.12,962 C.16,281 D.10,42 Cu 8. Cho 0,02 mol mt tripeptit X (Ala-Gly-Glu) phn ng va ht vi lng cc i l V ml dung dch NaOH 0,5M.Gi tr ca V l A.120 B.160 C.140 D.180 Cu 9. Tng s cc nguyn t ha hc trong chu k ba ca Bng H Thng Tun Hon l A .8 B .18 C .32 D.2 Cu 10. Dy gm cc nguyn t c sp xp theo chiu tng dn tnh kh l (t tri qua phi ) A Mg , Al, Cu,Fe B . Mg,Na, K, Rb. C. Mg,Na, K,Li D .Na,Mg, K,Li Cu 11. Khi cho isopentan tc dng vi brom theo t l mol 1:1, sn phm chnh thu c l A .1,3- ibrompentan B . 2,3-ibrompentan C. 2-metyl-2-brompentan D. 2-brom-2-metylbutan Cu 12. Khi cho isopentan tc dng vi clo theo t l mol1:1, s dn xut monoclo ti a to ra l A. 2 B. 3 C .4 D .5

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Ti liu n thi i hc nm 2012 -2013 Cu 13. t chy hon ton ankanol X ton b sn phm chy c hp th vo dung dch nc vi trong d th to ra 4gam kt ta,ng thi khi lng dung dch nc vi trong gim 1,376 gam. S ng phn cu to ca X l A.8 B .2 C.4 D . 17 Cu 14. Mc phn cc ca lin ha hc trong cc phn t c sp xp theo th t gim dn t tri qua phi l: A.HBr, HI, HCl B.HI, HBr, HCl C.HCl, HBr, HI D.HI, HCl, HBr Cu 15 .Khi cho a mol mt cht bo trung tnh lm mt mu va ht 3a mol brom trong CCl 4. Cng thc tng qut ca cht bo l A . CnH2n-10O6 B . CnH2n-12O6 C . CnH2n-8O6 D. CnH2n-6O6 Cu 16 .Hp cht hu c X tc dng vi dung dch axitnitric to ra kt ta mu vng th X l A .Valin B . Tyrosin C . Lysin D . Alanin Cu 17. C cc cht : axetilen,natrifomat, glucoz, fructoz v etylfomat.S cc cht (trong s cc cht cho) tham gia phn ng trng bc l A.5 B .4 C .3 D .2 Cu 18. Hn hp X gm O2 v O3 c t khi so vi H2 bng 20. t chy hon ton 9,4 gam hn hp CH 4 v CO c t khi so vi nit l x cn 7,616 lt hn hp X (ktc). Gi tr ca x l A. 0,685 B. 0,6786 C. 0,7857 D. 0,839 Cu 19. Cho t t dung dch cha x mol HCl vo dung dch cha y mol Na 2CO3, thu c 2,24 lt kh (ktc) v dung dch X. Khi cho nc vi trong d vo dung dch X thy xut hin 5 gam kt ta. Gi tr ca x v y ln lt l A. 0,15 v 0,075. B. 0,15 v 0,150. C. 0,25 v 0,100. D. 0,25 v 0,150. Cu 20. Hn hp X gm NaBr v NaI. Cho hn hp X tan trong nc thu c dung dch A. Nu cho brom d vo dung dch A, sau phn ng hon ton, c cn thy khi lng mui khan thu c gim 7,05 gam. Nu sc kh clo d vo dung dch A, phn ng hon ton, c cn dung dch thy khi lng mui khan gim 22,625 gam. Thnh phn % khi lng ca mt cht trong hn hp X l A. 64,3% B. 39,1% C. 47,8% D. 35,9% Cu 21. t chy hon ton m gam FeS2 bng mt lng O2 va , thu c kh X. Hp th ht X vo 1 lt dung dch cha Ba(OH)2 0,15M v KOH 0,1M, thu c dung dch Y v 27,125 gam kt ta. Cho Y vo dung dch NaOH, thy xut hin thm kt ta. Gi tr ca m l A. 16,5. B. 36,0. C. 18,0. D. 13,8. Cu 22.Khi cho 7,67 gam mt amin n chc phn ng va ht vi dung dch axitclohiric thu c dung dch X. C cn X c 12,415 gam mui khan. S ng phn cu to ca amin l A .2 B .8 C .4 D .1 Cu 23.Cho 1,86 gam hp cht c cng thc phn t C 3H12O3N2 phn ng hon ton vi 200 ml dung dch NaOH 0,2 M ,thu c mt hp cht hu c bc mt n chc v dung dch X ch cha cc cht v c .C cn X c a gam cht rn khan .Gi tr ca a l. A. 2,050 B.2,275 C.1,990 D .1,590 Cu 24 .Ch t cp kh no sau y ta iu ch c axit HNO3 A .NO v O2 B .NH3 v O2 C . N2 v O2 D .N2 v H2 Cu 25 .Cho cc cht: imetylamin, alanin, lysin, natriaxetat v amoniac. S cht trong cc cht cho lm i mu nc qu tm l A .5 B .4 C.2 D .3 Cu 26 .C cc loai t: nitron, nilon-6, nilon-6,6,visco v nilon-7 .T thuc t ha hc l A. 1 B .3 C.4 D. 5 Cu 27 .Cu to mch polime c th l A.Khng nhnh B.C nhnh C.Mch mng li D.C A;B;C Cu 28 .X phng ha 0,1 mol este X va ht vi 200 ml dung dch NaOH 1M thu c 19,8 gam hn hp sn phm hu c.Cng thc cu to ca X c th l A.HCOOC6H5 B.CH3COOC6H5 C.HCOOC2H4OOCH D.C A;B;C u ng Cu 29.Cho hp cht hu c C4H6O2 mch h tc dng va ht vi dung dch NaOH cho 2 cht hu c khng c kh nng phn ng trng gng.S ng phn cu to C4H6O2 c th c l A.2 B.1 C.3 D.4
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Ti liu n thi i hc nm 2012 -2013 Cu 30 .Hp cht hu c X ch cha mt loi nhm chc (C,H,O).Trong H chim 2,439% v khi lng.Khi t chy X th thu c s mol nc bng s mol X chy.Nu cho 24,6g X tc dng vi dung dch AgNO3/NH3 (d) thu c a gam bc.Gi tr ca a l A.32,4 B.64,8 C.129,6 D.86,4 Cu 31:Cho 0,01 mol mt aminoaxit X tc dng va ht vi 80ml dung dch HCl 0,125M c dung dch Y.Dung dch Y tc dng va ht vi 300ml dung dch NaOH 0,1M c dung dch Z.C cn Z c 2,835g cht rn khan. X l A.lysin B.tyrosin C. axit glutamic D.valin Cu 32 . Dung dch axit HX v dung dch HCl c cng nng mol/lit, c PH tng ng l x v y th biu thc lin h gia x v y l ( bit c 100 phn t HX c 10 phn t phn li) A . x= 10y B .x= y+1 C . y= x +1 D . y = 10x Cu 33 . Dung dch X gm CH3COOH 1M (KA=1,75.105) v HCl 0,001M. Gi tr pH ca dung dch X l A. 2,55. B. 2,33. C. 1,77. D. 2,43. Cu 34 . Cho cccht :etilen, toluen, cumen v axitacrylic. S cht lm mt mu nc brom l A .4 B .2 C .1 D .3 Cu 35. Tnh kh ca cc hidro halogenua tng dn theo th t sau: A. HF < HBr < HCl < HI B. HF < HCl < HI < HBr C. HI < HBr < HCl < HF D. HF < HCl < HBr < HI Cu 36 .Cracking 4,48 lit butan (ktc)thu c hn hp X gm 6 cht: H 2, CH4,C2H6,C2H4,C3H6 v C4H8 dn ton b sn phm X i qua bnh dung dch Brom d th thy khi lng dung dch Brom tng 8,4 gam v kh bay ra khi dung dch Brom l hn hp Y.Th tch oxi (ktc) cn t chy hon ton Y l A.5,60 lt B.8,96 lt C.4,48 lt D.6,76 lt Cu 37 .Cho cn bng: N2O4(k) 2NO2(k) 25oC.Khi chuyn dch sang mt trng thi cn bng mi nu nng ca N2O4 tng ln 9 ln th nng ca NO2 l A. Tng 9 ln B.Tng 3 ln C.Tng 4,5 ln D.Gim 3 ln Cu 38 .C cc cht: glucoz ,metylaxetat, etilen,etylfomat v metylacrylat .S cc cht cho ch mt phn ng ha hc trc tip to ra etanol l A .2 B.3 C .4 D.5 Cu 39 . Pht biu ng l A.T olon thuc t thin nhin B.T olon thuc t poliamit C.T olon thuc t nhn to D.T olon thuc t tng hp Cu 40 .Ln men dung dch cha 300g glucz thu c 92g ancol etylic.Hiu sut ln men to thnh ancol etylic l: A.80% B.40% C.60% D.54% Cu 41 .S hp cht ng phn cu to ca nhau c cng thc phn t C 8H10O,trong phn t c vng benzen, tc dng c vi Na, khng tc dng c vi NaOH l A.4 B.6 C.7 D.5 Cu 42 .Dy gm cc ion u oxi ha c kim loi st l A. Cr2+,Au3+,Fe3+. B.Fe3+,Ag+,Cu2+ C.Zn2+,Ag+,Cu2+ D.Ag+,Cu2+,Cr2+ 37 35 Cu 43 . Trong t nhin clo c hai ng v bn: 17 Cl chim 24,23% tng s nguyn t, cn li l 17 Cl . Thnh 35 phn % theo khi lng ca 17 Cl trong HClO4 l A. 21,68%. B. 26,76%. C. 8,64%. D. 6,84%. Cu 44 .Trn 600 ml dung dch HCl 1M vi 400ml dung dch Ba(OH) 2 a mol/lit thu c 1 lt dung dch X c pH = 1.Gi tr ca a l A.0,625 B.0,75 C.1,25 D. 0,95 Cu 45 .Cho 26 gam hn hp rn A gm Ca, MgO, Na 2O tc dng ht vi V ml dung dch HCl 1M (va ) thu c dung dch A trong c 23,4 gam NaCl. Gi tr ca V l A. 1200. B. 1080. C. 720. D. 900. Cu 46 .Hp cht hu c X c cng thc phn t l C 4H8O3.X c kh nng phn ng vi Na, vi NaOH.Sn phm thy phn X trong mi trng kim thu c hai hp cht hu c c kh nng tham gia phn ng trng bc.Cng thc cu to ng nht ca X l
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Ti liu n thi i hc nm 2012 -2013 A.CH3CH(OH)CH(OH)CHO B.CH3COOCHOHCH3 C.HCOOCH(OH)CH2CH3 D.CH2(OH)CH2CH2OOCH Cu 47 .Ha tan m gam hn hp FeO v Fe3O4 va ht trong dung dch cha 0,07 mol H2SO4 iu kin thch hp thu c 224ml SO2 (ktc) sn phm kh duy nht v dung dch X.C cn dung dch X c khi lng mui sunfat khan l A.8 gam B.12gam C.16 gam D.4 gam Cu 48 .X phng ha hon ton 52,8 gam hn hp 2 este no, n chc, mch h l ng phn ca nhau cn va 600ml NaOH 1M. Bit c hai este khng tham gia phn ng trng bc.Tn gi ca hai este l A.etylaxetat v propyl fomat B.etylpropionat v metylbutirat C.metylpropionat v etylaxetat D.izo-propylaxetat v propylaxetat Cu 49 .C cc cht: metanol,etanol,natriaxetat,anehitaxetic v etylfomat.S cht cho ch bng mt phn ng to ra axit axetic l A.2 B.3 C.4 D.5 Cu 50 .un si hn hp gm propyl bromua, kalihiroxit v etanol thu c sn phm hu c l A.Propin B.Propan-2-ol C.Propen D.Propan. B S 6 Cu 1: Dy gm cc cht c th iu ch trc tip (bng mt p) to ra axit axetic l: A. CH3CHO, C2H5OH, C2H5COOCH3. B. C2H4(OH)2, CH3OH, CH3CHO. C. CH3OH, C2H5OH, CH3CHO. D. CH3CHO, C6H12O6 (glucoz), CH3OH. Cu 2: Cho t t 150 ml dd HCl 1M vo 500 ml dung dch X gm Na2CO3 v NaHCO3 th thu c 1,008 lt kh (ktc) v dd Y. Cho dd Y tc dng vi dung dch Ba(OH) 2 d th thu c 29,55 gam kt ta. Nng mol ca Na 2CO3 v NaHCO3 trong dung dch X ln lt l: A. 0,21M v 0,18M B. 0,20M v 0,40M C. 0,21M v 0,32M D. 0,80M v 0,26M Cu 3: Thy phn dung dch cha 34,2 gam mantoz mt thi gian. Ly ton b sn phm thu c sau phn ng thy phn cho tc dng vi lng d dung dch AgNO3/ NH3, sau phn ng hon ton thu c 31,32 gam Ag. Hiu sut ca phn ng thy phn mantoz l A. 45% B. 50% C. 25% D. 55% Cu 4: X l hp cht hu c, mch h ch cha mt loi nhm chc. t chy hon ton X ch thu c CO2 v H2O. Khi lm bay hi hon ton 4,5 gam X thu c th tch bng th tch ca 2,1 gam kh N 2 cng iu kin. S CTCT ca X ph hp A. 5 B. 6 C. 3 D. 4 Cu 5: Dy cc kim loi c cu trc mng tinh th lp phng tm khi l: A. Na, K, Ba B. Ca, Sr, Ba C. Mg, Ca, Ba D. Na, K, Mg Cu 6: Dy ch cha nhng amino axit c s nhm amino v s nhm cacboxyl bng nhau l A. Gly, Glu, Lys B. Gly, Val, Ala C. Val , Lys, Ala D. Gly, Ala, Glu Cu 7: Ho tan ht m gam Al2(SO4)3 vo nc c dung dch X. Cho 360 ml dung dch NaOH 1M vo X, thu c 2a gam kt ta. Mc khc, nu cho 400 ml dung dch NaOH 1M vo X, cng thu c a gam kt ta. Cc phn ng xy ra hon ton, gi tr ca m l A. 18,81 B. 15,39 C. 20,52 D. 19,67 Cu 8: Cho phng trnh ho hc: FeSO 4 + KMnO4 + KHSO4 Fe2(SO4)3 + MnSO4 + K2SO4 + H2O. Tng h s ( s nguyn t, ti gin) ca cc cht c trong phng trnh phn ng l A. 48 B. 52 C. 54 D. 40 Cu 9: Dy gm cc cht no sau y u c tnh lng tnh ? A. AlCl3, H2O, NaHCO3, Zn(OH)2, ZnO B. ZnCl2, AlCl3, NaAlO2, NaHCO3, H2NCH2COOH C. H2O, Zn(OH)2, HOOC-COONa, H2NCH2COOH, NaHCO3 D. Al, NaHCO3, NaAlO2, ZnO, Be(OH)2 Cu 10: Cho gi tr th in cc chun E 0(V) ca cc cp oxi ha - kh Mg 2+/Mg; Zn2+/Zn; Pb2+/Pb, Cu2+/Cu ln lt l: - 2,37; -0,76; -0,13; +0,34. Pin in ha c sut in ng chun nh nht l A. Zn v Pb B. Pb v Cu C. Zn v Cu D. Mg v Cu Cu 11: Cho m gam Fe tc dng ht vi dung dch cha y mol CuSO4 v z mol H2SO4 long, sau phn ng hon ton thu c kh H2, m gam Cu v dung dch ch cha mt cht tan duy nht. Mi quan h gia y v z l
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Ti liu n thi i hc nm 2012 -2013 A. y = 7z. B. y = 5z. C. y = z. D. y = 3z. Cu 12: un nng 10,71 gam hn hp X gm propyl clorua v phenyl clorua vi dung dch NaOH long, va v un nng, sau thm tip dung dch AgNO3 n d vo hn hp sau phn ng thu c 8,61 gam kt ta, cc p xy ra hon ton. Khi lng phenyl clorua c trong hn hp X l A. 4,0 gam. B. 2,71 gam. C. 4,71 gam D. 6,0 gam. Cu 13: Sc V lt CO2 (ktc) vo 200 ml dung dch X gm Ba(OH)2 1M v NaOH 1M. Sau phn ng thu c 19,7 gam kt ta, gi tr ln nht ca V l A. 8,96 B. 11,20 C. 6,72 D. 13,44 Cu 14: Cho 3,2 gam Cu tc dng vi 100 ml dung dch hn hp HNO 3 0,8M v H2SO4 0,2M, sn phm kh duy nht l kh NO. S gam mui khan thu c khi c cn dung dch sau phn ng l A. 8,84 B. 5,64 C. 7,90 D. 10,08 Cu 15: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2(anilin), C6H5OH (phenol), C6H6 (benzen), CH3CHO. S cht trong dy lm mt mu dung dch brom l A. 6 B. 5 C. 7 D. 8 Cu 16: Cho hn hp gm 3,36 gam Mg v 0,4 gam MgO tc dng vi dd HNO 3 long d thu c kh N2. C cn dung dch sau phn ng thu c 23 gam cht rn khan. S mol HNO3 l p l: A. 0,32 B. 0,28 C. 0,34 D. 0,36 Cu 17: Cho cc polime sau: t nilon-6,6; poli(vinyl clorua); thy tinh plexiglas; teflon; nha novolac; t visco, t nitron, cao su buna. Trong , s polime c iu ch bng phn ng trng hp l A. 5 B. 6 C. 7 D. 4 Cu 18: Ha tan mt lng ancol X vo nc thu c 6,4 gam dung dch Y, nng ca X trong Y l 71,875%. Cho 6,4 gam dung dch Y tc dng vi lng d Na thu c 2,8 lt H2 (dktc). S nguyn t H c trong CTPT ancol X l A. 10 B. 4 C. 8 D. 6 Cu 19: Khi nhit phn hon ton 100 gam mi cht sau: KClO 3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht to ra lng O2 t nht l A. KMnO4 B. KNO3 C. AgNO3 D. KClO3 Cu 20: t chy hon ton 4,872 gam mt hirocacbon X, dn sn phm chy qua bnh ng dd nc vi trong. Sau phn ng thu c 27,93 gam kt ta v thy khi lng dung dch gim 5,586 gam. CTPT ca X l A. CH4 B. C4H8 C. C4H10 D. C3H6 Cu 21: Cho m gam Ca vo 500 ml dung dch cha NaHCO3 1M v CaCl2 0,5M. Sau khi phn ng xy ra hon ton thu c 40 gam kt ta. Gi tr ca m l A. 16,0 B. 6,0 C. 8,0 D. 10,0 Cu 22: Cho cc cht: amoniac (1); anilin (2); p-nitroanilin (3); p-metylanilin (4); metylamin (5); imetylamin (6). Th t tng dn lc baz ca cc cht l: A. (3) < (2) < (4) < (1) < (5) < (6) B. (2) < (3) < (4) < (1) < (5) < (6) C. (2) > (3) > (4) > (1) > (5) > (6) D. (3) < (1) < (4) < (2) < (5) < (6) Cu 23: t chy hon ton mt hn hp X (glucoz, fructoz, metanal v etanoic) cn 3,36 lt O 2 (iu kin chun). Dn sn phm chy qua bnh ng dung dch Ca(OH)2 d, sau p hon ton thu c m gam kt ta. Gi tr ca m l A. 10,0 B. 12,0 C. 15,0 D. 20,5 Cu 24: in phn 2 lt dung dch cha hn hp gm NaCl v CuSO 4 vi in cc tr, c mng ngn n khi H2O bt u in phn c hai cc th dng li. Ti catt thu 1,28 gam kim loi ng thi ti ant thu 0,336 lt kh ( ktc). Coi th tch dung dch khng i th pH ca dung dch sau in phn l A. 3 B. 12 C. 13 D. 2 3+ 5 Cu 25: Ion R c cu hnh electron phn lp ngoi cng l 3d . V tr ca R trong bng tun hon l: A. Chu k 4, nhm VIIB B. Chu k 3 nhm VIIIB C. Chu k 4 nhm VIIIB D. Chu k 4, nhm IIB Cu 26: Cht bo X c ch s axit l 7. trung ha lng axit c trong 10 kg X cn va m gam NaOH. Gi tr ca m l A. 55 B. 70 C. 50 D. 60 Cu 27: Khi cho hn hp Fe3O4 v Cu vo dung dch H2SO4 long d thu c cht rn X v dung dch Y. Dy gm cc cht u tc dng c vi dung dch Y l A. KI, NH3, NH4Cl B. BaCl2, HCl, Cl2 C. NaOH, Na2SO4,Cl2 D. Br2, NaNO3, KMnO4
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Ti liu n thi i hc nm 2012 -2013 Cu 28: Cho cc cht sau: axetilen, axit fomic, fomanehit, phenyl fomat, glucz, anehit axetic, metyl axetat, mantz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l A. 8 B. 5 C. 6 D. 7 Cu 29: Cho m gam hp cht hu c X c CTPT l C 3H6O2 tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. CTCT ca X v gi tr ca m l A. HCOOCH2CH3 v 8,88 B. CH3COOCH3 v 6,66 C. C2H5COOH v 8,88 D. C2H5COOH v 6,66 Cu 30: t chy 3,2 gam mt este E n chc, mch h c 3,584 lt CO 2 (ktc) v 2,304 gam H2O. Nu cho 15 gam E tc dng vi 200 ml dung dch NaOH 1M, c cn dung dch sau phn ng thu c 14,3 gam cht rn khan. Cng thc ca ancol to nn este trn c th l A. CH2=CH-OH B. CH3OH C. CH3CH2OH D. CH2=CH-CH2OH Cu 31: Ancol X, anehit Y, axit cacboxylic Z c cng s nguyn t H trong phn t v u no, n chc, mch h. t hon ton hn hp 3 cht trn (c s mol bng nhau) thu c t l mol gia CO2 v H2O l 11:12. CTPT ca X, Y, Z l: A. CH4O, C2H4O, C2H4O2 B. C4H10O, C5H10O, C5H10O2 C. C2H6O, C3H6O, C3H6O2 D. C3H8O, C4H8O, C4H8O2 Cu 32: S nguyn t ha hc m nguyn t ca n c electron cui cng in vo phn lp 4s l A. 12 B. 1 C. 10 D. 2 Cu 33: a mt hn hp kh N2 v H2 c t l 1: 3 vo thp tng hp, sau phn ng thy th tch kh i ra gim 1/10 so vi ban u. Hiu sut ca phn ng tng hp NH3 l A. 10% B. 20% C. 15% D. 25% Cu 34: X l hn hp cc mui Cu(NO3)2, Zn(NO3)2, Fe(NO3)3, Mg(NO3)2. Trong O chim 9,6% v khi lng. Nung 50 gam X trong bnh kn khng c oxi n khi phn ng xy ra hon ton thu c m gam oxit. Gi tr ca m l A. 44,6 B. 39,2 C. 17,6 D. 47,3 Cu 35: Cho 29,8 gam hn hp 2 amin n chc k tip tc dng ht vi dd HCl, lm kh dung dch thu c 51,7 gam mui khan. CTPT 2 amin l A. C2H5N v C3H7N B. CH5N v C2H7N C. C3H9N v C4H11N D. C2H7N v C3H9N Cu 36: Trong cc ho cht Cu, C, S, Na2SO3, FeS2 , O2, H2SO4 c. Cho tng cp cht phn ng vi nhau trong iu kin thch hp th s cp cht c phn ng to ra kh SO2 l A. 6 B. 7 C. 9 D. 8 Cu 37: nhn bit ba l mt nhn: phenol, stiren, ancol benzylic, ngi ta dng A. dung dch Ca(OH)2 B. dung dch NaOH C. nc brom D. Na Cu 38: Ha tan hon ton 6,44 gam hn hp bt X gm FexOy v Cu bng dung dch H2SO4 c nng (d). Sau p thu c 0,504 lt kh SO 2 (sn phm kh duy nht, ktc) v dung dch cha 16,6 gam hn hp mui sunfat. Cng thc ca oxit st l A. FeO B. Fe3O4 C. FeO hoc Fe3O4. D. Fe2O3 Cu 39: Thc hin cc th nghim sau: (1). Sc kh C2H4 vo dung dch KMnO4. (2). Sc CO2 d vo dung dch NaAlO2 (3). Chiu sng vo hn hp kh (CH4; Cl2). (4). Sc kh H2S vo dung dch FeCl3. (5). Sc kh NH3 vo dung dch AlCl3. (6). Sc kh SO2 vo dung dch H2S. S th nghim c phn ng oxi ho- kh xy ra l A. 1, 3, 4, 6. B. 1, 2, 4, 5 C. 2, 4, 5, 6. D. 1, 2, 3, 4. Cu 40: Pht biu khng ng l A. Thy tinh lng l dung dch m c ca Na2SiO3 v K2SiO3 B. Nc Gia-ven l dung dch hn hp natri clorua v natri hipoclorit. C. Photpho trng c cu trc mng tinh th phn t. D. Phn bn phc hp l sn phm trn ln cc loi phn n theo t l khc nhau. Cu 41: Thuc th phn bit cc kim loi sau: Mg, Zn, Fe, Ba l A. dung dch NaCl B. nc C. dung dch NaOH D. dung dch H2SO4 long Cu 42: Cho hp cht X tc dng vi NaOH to ra kh Y lm xanh qu tm m. Mt khc, cht X tc dng vi axit HCl to ra kh Z va lm vn c nc vi trong, va lm mt mu dung dch brom. Cht X khng tc dng vi dung dch BaCl2. X l A. NH4HSO3 B. NH4HCO3 C. (NH4)2CO3 D. (NH4)2SO3
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Ti liu n thi i hc nm 2012 -2013 Cu 43: Dy gm cc kim loi u tc dng c vi dung dch FeCl3 l: A. Fe, Mg, Cu, Ag, Al B. Au, Cu, Al, Mg, Zn C. Fe, Zn, Cu, Al, Mg D. Cu, Ag, Au, Mg, Fe Cu 44: Hn hp X gm HCHO v CH 3CHO c t l mol 1 : 1. un nng 7,4 gam X vi lng d dung dch AgNO3/NH3 ti phn ng hon ton thu c m gam cht rn. Gi tr ca m l A. 86,4 B. 64,8 C. 43,2 D. 32,4 Cu 45: Cho cc cht sau: C2H5OH, C6H5OH, C6H5NH2, dung dch C6H5ONa, dung dch NaOH, dung dch CH3COOH, dung dch HCl. Cho tng cp cht tc dng vi nhau iu kin thch hp, s cp cht c phn ng xy ra l A. 8 B. 12 C. 9 D. 10 Cu 46: Cho 0,1 mol hp cht ha c c CTPT CH6O3N2 tc dng vi dung dch cha 0,2 mol NaOH un nng, sau khi phn ng xy ra hon ton thu c cht kh lm xanh giy qu tm m v dung dch Y. C cn dung dch Y thu c m gam rn khan. Gi tr ca m l A. 21,8 B. 15,0 C. 12,5 D. 8,5 Cu 47: Ln men mt lng glucoz thnh ancol etylic th thu c 100 ml ancol 460. Khi lng ring ca ancol nguyn cht l 0,8 gam/ml. Hp th ton b kh CO2 sinh ra trong qu trnh ln men vo dung dch NaOH d thu c m(g) mui. Bit cc phn ng xy ra hon ton. Gi tr ca m l A. 106,0 B. 84,8 C. 212,0 D. 169,6 Cu 48: nhit khng i, cn bng ca p thun - nghch b chuyn dch theo chiu thun khi tng p sut ca h l A. 2SO3(k) 2SO2(k) + O2(k) B. CaCO3(r) CaO(r) + CO2(k) C. N2(k) + 3H2(k) 2NH3(k) D. I2(k) + H2(k) 2HI(k) Cu 49: Trong s cac phat biu sau v anilin (C6H5NH2): (1) Anilin tan it trong nc nhng tan nhiu trong dung dich NaOH. (2) Anilin co tinh baz, dung dich anilin khng lam i mau quy tim. (3) Anilin dung san xut phm nhum, dc phm, polime. (4) Anilin tham gia phan ng th brom vo nhn thm d hn benzen. Cac phat biu ung la A. (1), (2), (3) B. (1), (2), (4) C. (1), (3), (4) D. (2), (3), (4) Cu 50: Cho 200 ml dd AgNO3 2,5a mol/l tc dng vi 200 ml dung dch Fe(NO 3)2 a mol/l. Sau khi phn ng kt thc thu c 17,28 gam cht rn v dung dch X. Cho dung dch HCl d vo dung dch thu c m gam kt ta. Gi tr ca m l A. 34,44 B. 28,70 C. 40,18 D. 43,05

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Ti liu n thi i hc nm 2012 -2013 B S 7 Cu 1: Cho phn ng: 2Al + 2H2O + 2OH- 2AlO-2 + 3H2. Cht oxi ha l: A. OHB. Al C. H2O D. H2O v OHCu 2: Cho hai nguyn t ca hai nguyn t A v B thuc nhm chnh lin tip, tng s hiu ca chng l 23, A thuc nhm V v n cht ca A v B khng phn ng vi nhau nhit thng. A v B l A. P v O2 B. O v S C. N v S . D. P v S Cu 3: Ha tan hon ton m gam hn hp X gm Fe v cc oxit st trong dd H 2SO4 c, nng d thu c 80 gam mui Fe2(SO4)3 v 2,24 lt SO2 (ktc). S mol H2SO4 tham gia p l: A. 0,9 B. 0,7 C. 0,5 mol D. 0,8 Cu 4: Anehit Y c cng thc n gin l C2H3O. S CTCT ca Y l A. 2 B. 4 C. 3 D. 1 Cu 5: Cho 2 ming Zn c cng khi lng vo cc (1) dng dd HCl d v cc 2 ng dd HCl d c thm mt t CuCl2. (Hai dd HCl c cng nng mol/l). Pht biu khng ng l A. kh cc (1) thot ra nhiu hn cc (2). B. kh cc (1) thot ra chm hn cc (2). C. kh cc (1) thot ra t hn cc (2) D. cc (1) n mn ha hc, cc (2) n mn in ha Cu 6: Cho s sau: xenluloz X1 X2 X3 polime X. Bit rng X ch cha 2 nguyn t. S cht ng vi X3 l. A. 2 B. 1 C. 3 D. 4 Cu 7: Cho 100ml dung dch NaOH 4M tc dng vi 100ml dung dch H 3PO4 aM thu c 25,95 gam hai mui. Gi tr ca a l A. 1,50 B. 1,75 C. 1,25 D. 1,00 Cu 8: t 24 gam hn hp X gm Fe v Cu trong khng kh thu c m gam hn hp cht rn Y gm Fe, Cu, CuO, Fe3O4. Cho hn hp Y vo dd H 2SO4 c, nng thu c 6,72 lt SO 2 (ktc) v dd c cha 72 gam mui sunfat. Gi tr ca m l A. 25,6 B. 28,8 C. 27,2 D. 26,4 Cu 9: Thuc th phn bit cc cht rn: Na2CO3, CaSO4.2H2O, NaCl v CaCO3 l dung dch A. Ba(OH)2 long B. NaOH long C. phenolphtalein D. H2SO4 long, d Cu 10: Cht X c CTPT l C5H10. X tc dng vi dung dch Br2 thu c 2 dn xut ibrom. X l A. 1,1,2-trimetyl xiclopropan B. 1,2-imetylxiclopropan C. 2-metylbut-2- en D. 2-metyl but-1- en Cu 11: Thuc th phn bit 5 cht lng khng mu l: Glyxerol, etanol v dung dch glucoz, anilin, lng trng trng l A. Na v dung dch Br2 B. Na v dung dch AgNO3/NH3 C. dung dch AgNO3/NH3 v Cu(OH)2 D. dung dch Br2 v Cu(OH)2 Cu 12: Trng hp thu c kt ta c khi lng ln nht l A. Cho V(lt) dung dch HCl 2M vo V (lt) dung dch NaAlO2 1M B. Cho V(lt) dung dch NaOH 1M vo V (lt) dung dch AlCl3 1M C. Cho V(lt) dung dch HCl 1M vo V (lt) dung dch NaAlO2 1M D. Cho V(lt)dung dch AlCl3 1M vo V (lt) dung dch NaAlO2 1M Cu 13: Cho X l dd CH3COOH 1M c in li l . Ln lt thm vo 100 ml dd X 100 ml cc dd sau: HCl 1M, CH3COOH 1M, CH3COONa 1M, NaCl 1M. S trng hp lm tng in li l A. 2 B. 3 C. 1 D. 4 Cu 14: Cc polime khng c nhit nng chy xc nh do A. c khi lng qa ln B. l hn hp ca nhiu phn t c khi lng khc nhau C. c tnh cht ha hc khc nhau D. c cu trc khng xc nh Cu 15: Ha tan 3,38 gam oleum X vo lng nc d thu c dung dch. trung ha 1/10 dung dch A cn dng 80 ml dd NaOH 0,1M. Cng thc ca oleum l A. H2SO4.4SO3 B. H2SO4.3SO3 C. H2SO4.2SO3 D. H2SO4.SO3 Cu 16: Cho 2 dd H2SO4 v HCOOH c cng nng mol/l v c cc gi tr pH tng ng l x v y. Bit rng c 50 phn t HCOOH th c 1 phn t HCOOH phn ly. Mi quan h gia x v y l A. y = x + 2 B. y = 2x C. y = x - 1 D. y = 10x
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Ti liu n thi i hc nm 2012 -2013 Cu 17: Cho 3,36 lt kh CO2 vo 200,0 ml dung dch cha NaOH xM v Na2CO3 0,4M thu c dung dch X cha 19,98 gam hn hp mui. Nng mol ca NaOH trong dung dch l A. 0,70M B. 0,75M C. 0,50M D. 0,60M Cu 18: in phn dung dch NaOH vi cng khng i l 10A trong thi gian 268 gi. Dung dch cn li sau in phn c khi lng 100g v nng 24%. Nng phn trm ca dung dch ban u l A. 4,8% B. 2,4% C. 9,6% D. 1,2% Cu 19: Cho V(lt) kh CO2 hp th hon ton bi 200 ml dung dch Ba(OH)2 0,5M v NaOH 1,0M. kt ta thu c l cc i th gi tr ca V l A. 2,24 V 6,72 B. 2,24 V 5,60 C. 2,24 V 8,96 D. 2,24 V 4,48 Cu 20: Cho 2,7 gam Al tan hon ton trong dung dch HNO 3 long, nng thu c kh 0,448 lt X duy nht (ktc). C cn dung dch thu c 22,7 gam cht rn khan. X l A. NO B. NO2 C. N2 D. N2O Cu 21: X c vng benzen v c CTPT l C 9H8O2. X tc dng d dng vi dd brom thu c cht Y c CTPT l C9H8O2Br2. Mt khc, cho X tc dng vi NaHCO 3 thu c mui Z c CTPT l C9H7O2Na. S CTCT ca X l A. 3 B. 6 C. 4 D. 5 Cu 22: in phn nng chy Al2O3 khi ti anot thot ra mt hn hp kh gm O 2 10%; CO 20% v CO2 70%. Tng th tch kh l 6,72 m3 (ti nhit 8190C v p sut 2,0 atm). Khi lng Al thu c ti catot l A. 2,16 kg B. 5,40 kg C. 4,86 kg D. 4,32 kg Cu 23: Hn hp X gm CH2=CH-CH2OH v CH3CH2OH. Cho a gam hn hp X tc dng vi Na thu c 2,24 lt H2 (ktc). Mt khc, a gam hn hp X lm mt mu va ht 100 gam dung dch Br 2 20%. Gi tr ca a l A. 12,7 B. 11,7 C. 9,7 D. 10,7 + + Cu 24: Cho cc qu trnh sau : Na Na ; 2H H2 ; NO NO3 ; H2S SO42-, Fe2+ Fe3+; Fe3O4 Fe3+; CH4 HCHO; MnO2 Mn2+;s qu trnh gn lin vi qu trnh oxi ha l A. 7 B. 5 C. 6 D. 4 Cu 25: Hn hp X gm CH4, C3H8, C2H4 v C3H4. em t chy hon ton hn hp X bng khng kh, sau phn ng thu c mt hn hp gm a mol N 2, 0,2 mol O2, 0,4 mol CO2 v 0,5 mol H2O. Bit rng trong khng kh: N2 chim 80% v O2 chim 20% theo th tch. Gi tr ca a l A. 2,4 B. 1,0 C. 3,4 D. 4,4 Cu 26: Cho 12,25 gam KClO3 vo dung dch HCl c, kh Cl2 thot ra cho tc dng vi ht vi kim loi M thu c 30,9 gam hn hp cht rn X. Cho X vo dung dch AgNO3 d, thu c 107,7 gam kt ta. M l A. Zn B. Mg C. Fe D. Cu Cu 27: Cho cc dung dch sau: NaHCO3 (X1); CuSO4 (X2); (NH4)2CO3 (X3); NaNO3 (X4); MgCl2 (X5); KCl (X6). Nhng dung dch khng to kt ta khi cho Ba vo l A. X1, X3, X6 B. X1, X4, X5 C. X4, X6. D. X1, X4, X6 Cu 28: Cho ankan X tc dng vi clo (as) thu c 13,125 gam hn hp cc dn xut clo (mono v iclo). Kh HCl bay ra c hp th hon ton bng nc sau trung ha bng dung dch NaOH thy tn ht 250 ml dung dch NaOH 1M. CTCT ca X l A. C2H6 B. C4H10 C. C3H8 D. CH4 Cu 29: Cho 13,0 gam bt Zn vo dung dch cha 0,1mol Fe(NO3)3, 0,1 mol Cu(NO3)2 v 0,1mol AgNO3 , khuy u cho phn ng hon ton tu m(g) rn. Gi tr ca m l A. 17,2 B. 14,0 C. 19,1 D. 16,4 Cu 30: Trong phn ng t chy naphtalen (C10H8) bng O2 thnh CO2 v H2O th mt phn t C10H8 nhng cho O2 s electron l A. 60 B. 32 C. 36 D. 48 Cu 31: S ancol bc 2, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18% l A. 3 B. 5 C. 4 D. 2 Cu 32: Cho t t tng git ca dung dch cha b mol HCl vo dung dch cha a mol Na2CO3 thu c V lt CO2. Ngc li, cho t t tng git ca dung dch cha a mol Na2CO3 vo dung dch cha b mol HCl thu c 2V lt CO2. Mi quan h ca a v b l A. a = 0,8b B. a = 0,35b C. a = 0,75b D. a = 0,5b
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Ti liu n thi i hc nm 2012 -2013 Cu 33: Cho 8 gam ancol X n chc qua CuO nung nng thu c 11,0 gam hn hp gm ancol X, anehit v H2O. Hiu sut ca phn ng oxi ha l: A. 50,0% B. 75,% C. 62,5% D. 70,0% Cu 34: Pht biu khng ng l A. Trong mi phn t protit, cc aminoaxit c sp xp theo mt th t xc nh B. Phn t c hai nhm - CO-NH- c gi l ipeptit, ba nhm th c gi l tripeptit C. Cc peptit c t 10 n 50 n v amino axit cu thnh c gi l polipeptit D. Nhng hp cht hnh thnh bng cch ngng t hai hay nhiu -aminoaxit c gi l peptit Cu 35: Cho cn bng ha hc 2NO2 N2O4 (1) Hn hp kh X l NO2 v N2O4 c mu nu , hn hp trong mt chu nc thy mu nu nht dn v bin mt. Cn bng (1) c c im A. bt thun nghch B. thu nhit C. l phn ng oxi ha kh D. ta nhit Cu 36: Cho 7,8 gam hn hp X gm 2 ancol n chc, bc I qua CuO d, nung nng (phn ng hon ton) sau phn ng thy khi lng cht rn gim 3,2 gam. Cho hn hp sn phm tc dng vi AgNO 3/ NH3, un nng thu c m gam Ag. Gi tr ca m l A. 64,8 B. 43,2 C. 21,6 D. 86,4 Cu 37: tc dng ht vi 100 gam lipit c ch s axit bng 7 phi dng 17,92 gam KOH. Khi lng mui thu c l A. 110,324 gam. B. 108,107 C. 103,178 D. 108,265 Cu 38: Mui X c CTPT l CH6O3N2. un nng X vi NaOH thu c 2,24 lt kh Y (Y l hp cht cha C, H, N v c kh nng lm xanh giy qu tm m). Khi lng mui thu c l A. 8,2 gam B. 8,5 gam C. 6,8 gam D. 8,3 gam Cu 39: un nng 3,42 gam mantoz trong dung dch axit sunfuric long, un nng, trung ha axit sau phn ng ri cho hn hp tc dng hon ton vi AgNO 3/NH3, un nng thu c 3,78 gam Ag. Hiu sut p thy phn mantoz l A. 69,3% B. 87,5% C. 62,5% D. 75,0% Cu 40: Pht biu khng ng l A. isaccarit l cacbon hirat thy phn sinh ra hai loi monosaccarit B. Polisaccarit l cacbon hirat thy phn sinh ra nhiu phn t monosaccarit C. Monosaccarit l cacbon hirat khng th thy phn c D. Tinh bt, mantoz v glucoz ln lt l poli- i- v monosaccarit Cu 41: in phn dung dch hn hp gm a mol NaCl v b mol CuSO4 vi in cc tr thu c dung dch X c pH > 7. S lin h gia a v b l A. a< 2b B. 2a = b C. a = b D. a > 2b. Cu 42: X l este to t axit n chc v ancol a chc. X khng tc dng vi Na. Thy phn hon ton a gam X cn dng va 100 gam dung dch NaOH 6 % thu c 10,2 gam mui v 4,6 gam ancol. E l A. (CH3COO)2C3H6 B. (HCOO)3C3H5 C. (C2H3COO)3C3H5 D. (HCOO)2C2H4 Cu 43: Cht X c CTPT l CxHyCl. Trong X, clo chim 46,4% v khi lng. S ng phn ca X l: A. 3 B. 4 C. 2 D. 5 Cu 44: t chy hon ton 0,1 mol hn hp kh X gm C 2H4 v C4H4 th thu c s mol CO 2 v s mol H2O ln lt l: A. 0,25 v 0,15 B. 0,15 v 0,2 C. 0,3 v 0,2 D. 0,4 v 0,2 Cu 45: t chy hon ton 29,6 gam hn hp X gm CH 3COOH, CxHyCOOH v (COOH)2 thu c 0,8 mol H2O v m gam CO2. Cng 29,6 gam X tc dng vi lng d NaHCO3 thu c 0,5 mol CO2. Gi tr ca m l A. 44 B. 22 C. 11 D. 33. Cu 46: Cho hn hp X gm 0,1 mol C 2H4, 0,2 mol C2H2 v 0,7 mol H2. X c nung trong bnh kn c xc tc l Ni. Sau mt thi gian thu c 0,8 mol hn hp Y, Y phn ng va vi 100ml dung dch Br 2 aM. Gi tr ca a l A. 3 B. 2,5 C. 2,0 D. 5 Cu 47: ,0Cho cc cht sau: axit benzoic(X), axit fomic(Y), axit propinoic(Z). S sp xp theo chiu tng dn tnh axit l: A. Z < X < Y B. X< Z < Y C. X < Y <Z D. Z < Y < X.
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Ti liu n thi i hc nm 2012 -2013 Cu 48: Cho 6,9 gam Na vo 100,0 ml dung dch HCl thu c dd X cha 14,59 gam cht tan. Cho dung dch X vo dung dch AgNO3 d thu c m gam kt ta. Gi tr ca m l A. 38,65 B. 37,58 C. 40,76 D. 39,20 Cu 49: C cc dd NH3, NH4Cl, NaOH v HCl c cng nng mol/l v c cc gi tr pH tng ng l h 1, h2, h3 v h4. S sp xp theo chiu tng dn cc gi tr pH l A. h4 < h3 < h2 < h1 B. h4 < h2 < h1 < h3 C. h2 < h4 < h1 < h3 D. h1 < h2 < h3 < h4 Cu 50: Cho etan qua xc tc ( nhit cao) thu c mt hn hp X gm etan, etilen, axetilen v H 2. T khi ca hn hp X i vi etan l 0,4. Nu cho 0,4 mol hn hp X qua dung dch Br2 d th s mol Br2 phn ng l A. 0,24 B. 0,16 C. 0,40 D. 0,32 B S 8 Cu 1: Cho hn hp X gm hai kim loi kim tan ht trong 200ml dung dch cha BaCl 2 0,3M v Ba(HCO3)2 0,8M thu c 2,8 lt H2 ( ktc) v m gam kt ta. Gi tr ca m l: A. 43,34 B. 49,25 C. 31,52 D. 39,4 Cu 2: Hn hp X gm hiro, propen, propanal, ancol alylic (CH2=CH-CH2OH). t 1 mol hn hp X thu c 40,32 lt CO2 (ktc). un X vi bt Ni mt thi gian thu c hn hp Y c dY = 1,25. Nu ly 0,1 mol
X

hn hp Y th tc dng va vi V lt dung dch Br2 0,2M. Gi tr ca V l: A. 0,1 lt B. 0,2 lt C. 0,25 lit D. 0,3 mol Cu 3: Dy cc kim loi c cu trc mng tinh th lp phng tm khi l: A. Ca, Sr, Ba B. Na, K, Ba C. Na, K, Mg D. Mg, Ca, Ba Cu 4: Dy no sau y gm cc ion X+, Y2+ ,Z- ,T2- v nguyn t M u c cu hnh e l 1s22s22p63s23p6 ? A. K+, Ca2+, Cl-, S2-, Ar. B. K+, Ca2+, F-, O2-, Ne. C. Na+, Ca2+, Cl-, O2-, Ar. D. K+, Mg2+, Br-, S2-, Ar. Cu 5: Nhng mt l st nh vo dung dch cha lng d mt trong nhng cht sau: FeCl3, AlCl3, CuSO4, Pb(NO3)2, NaCl, HCl, HNO3 long, H2SO4 c nng, NH4NO3. S trng hp phn ng to mui Fe(II) l: A. 4 B. 3 C. 6 D. 5 Cu 6: phn ng ht a mol kim loi M cn 1,25a mol H2SO4 v sinh ra kh X (sn phm kh duy nht). Ha tan ht 19,2 gam kim loi M vo dung dch H 2SO4 to ra 4,48 lt kh X ( sn phm kh duy nht, ktc). Kim loi M l: A. Fe. B. Cu. C. Mg. D. Al. Cu 7: Cho 3,76 gam hn hp X gm Mg v MgO c t l mol tng ng l 14:1 tc dng ht vi dung dch HNO3 th thu c 0,448 lt mt kh duy nht (o ktc) v dung dch Y. C cn cn thn dung dch Y thu c 23 gam cht rn khan T. Xc nh s mol HNO3 phn ng. A. 0,28 B. 0,36 C. 0,32 D. 0,34 Cu 8: t chy hon ton 4,872 gam mt hirocacbon X, dn sn phm chy qua bnh ng dung dch nc vi trong. Sau phn ng thu c 27,93 gam kt ta v thy khi lng dung dch gim 5,586 gam. Cng thc phn t ca X l: A. CH4 B. C4H8 C. C4H10 D. C3H6 Cu 9: Hn hp X cha K2O, NH4Cl, KHCO3 v BaCl2 c s mol bng nhau. Cho X vo nc d, un nng, dung dch thu c cha cht tan l: A. KCl, BaCl2 B. KCl, KOH C. KCl, KHCO3, BaCl2 D. KCl Cu 10: un nng 10,71 gam hn hp X gm propyl clorua v phenyl clorua vi dung dch NaOH long, va v un nng, sau thm tip dung dch AgNO 3 n d vo hn hp sau phn ng thu c 8,61 gam kt ta, cc phn ng xy ra hon ton. Khi lng phenyl clorua c trong hn hp X l: A. 4,0 gam. B. 2,71 gam. C. 4,71 gam D. 6,0 gam. Cu 11: Nung nng hon ton 27,3 gam hn hp NaNO3, Cu(NO3)2. Hn hp kh thot ra c dn vo nc d th thy c 1,12 lt kh (ktc) khng b hp th (lng O 2 ha tan khng ng k). Khi lng Cu(NO3)2 trong hn hp ban u l: A. 4,4 gam. B. 18,8 gam. C. 28,2 gam. D. 8,6 gam. Cu 12: Trn 3 dung dch Ba(OH)2 0,1M, NaOH 0,2M, KOH 0,3 M vi nhng th tch bng nhau thu c dung dch A . Ly 300ml dung dch A cho phn ng vi V lt dung dch B gm HCl 0,2M v HNO 3 0,29M, thu c dung dch C c pH =12. Gi tr ca V l:
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Ti liu n thi i hc nm 2012 -2013 A. 0,134 lt B. 0,414 lt C. 0,424 lt D. 0,214 lt Cu 13: Ha tan mt lng ancol X vo nc thu c 6,4 gam dung dch Y, nng ca X trong Y l 71,875%. Cho 6,4 gam dung dch Y tc dng vi lng d Na thu c 2,8 lt H2 (ktc). S nguyn t H c trong cng thc phn t ancol X l: A. 10 B. 6 C. 8 D. 4 Cu 14: Dung dch X cha 14,6 gam HCl v 22,56 gam Cu(NO 3)2. Thm m (gam) bt st vo dung dch X, sau khi phn ng xy ra hon ton thu c hn hp kim loi c khi lng l 0,628m (gam) v ch to kh NO (sn phm kh duy nht ca N+5). Gi tr ca m l: A. 1,92. B. 9,28. C. 14,88. D. 20,00. Cu 15: Trong t nhin clo c hai ng v c s khi l 35 v 37. Khi lng trung bnh nguyn t ca clo l 35,5. Vy % v khi lng ca 37Cl trong axit pecloric HClO4 l (Cho s khi 1H, 16O): A. 9,204 B. 9,25 C. 9,45 D. 9,404 Cu 16: Nhit si ca ancol etylic (I), anehit axetic (II), axit axetic (III) v axit propionic (IV) sp xp theo th t gim dn l: A. I > II > III > IV. B. IV > III > I > II. C. II > III > I > IV. D. IV > I > III > II. Cu 17: Xt ba nguyn t c cu hnh electron ln lt l: X: 1s22s22p63s1 ; Y: 1s22s22p63s2 ; Z: 1s22s22p63s23p1. Hiroxit ca X, Y, Z xp theo th t tng dn tnh baz l: A. XOH < Y(OH)2 < Z(OH)3 B. Z(OH)2 < Y(OH)3 < XOH C. Y(OH)2 < Z(OH)3 < XOH D. Z(OH)3 < Y(OH)2 < XOH Cu 18: Cho m gam hp cht hu c X c cng thc phn t l C 3H6O2 tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Cng thc cu to ca X v gi tr ca m l: A. C2H5COOH v 8,88 gam. B. CH3COOCH3 v 6,66 gam. C. HCOOCH2CH3 v 8,88 gam. D. C2H5COOH v 6,66 gam. Cu 19: X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m (gam) hn hp cha X v Y c t l s mol ca X v Y tng ng l 1:3 vi dung dch NaOH va . Phn ng hon ton thu c dung dch T. C cn cn thn dung dch T thu c 23,745 gam cht rn khan. Gi tr ca m l: A. 19,455. B. 68,1. C. 17,025. D. 78,4 Cu 20: Hn hp X gm hai cht hu c n chc tc dng vi 500ml dung dch KOH 1M, thu c hai mui ca hai axit hu c v mt ancol. Cho lng ancol trn tc dng vi Na d th c 3,36 lt H 2 (ktc). X gm : A. Hai este. B. Mt este mt ancol. C. Mt este v mt axit. D. Mt axit mt ancol. Cu 21: t chy hon ton mt hn hp X (glucoz, fructoz, metanal v etanoic) cn 3,36 lt O 2 (iu kin chun). Dn sn phm chy qua bnh ng dung dch Ca(OH) 2 d, sau phn ng hon ton thu c m gam kt ta. Gi tr ca m l: A. 10,0 B. 12,0 C. 15,0 D. 20,5 Cu 22: Khi nhit phn hon ton 100 gam mi cht sau: KClO 3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht to ra lng O2 t nht l: A. KMnO4 B. KNO3 C. AgNO3 D. KClO3 Cu 23: C bao nhiu ng phn cu to, mch h c cng thc phn t C5H8 tc dng vi H2 d (xc tc thch hp) thu c sn phm isopentan ? A. 4. B. 2. C. 6. D. 3. Cu 24: Cho cc polime sau: t nilon-6,6; poli(vinyl clorua); thy tinh plexiglas; teflon; nha novolac; t visco, t nitron, cao su buna. Trong , s polime c iu ch bng phn ng trng hp l: A. 5 B. 4 C. 6 D. 7 Cu 25: Chn cu ng trong cc cu sau: A. Ancol a chc ha tan Cu(OH)2 to thnh dung dch mu xanh. B. Phng php chung iu ch ancol no, n chc bc 1 l cho an ken cng nc. C. un nng ancol metylic vi H2SO4 c 170oC thu c ete. D. Khi oxi ha ancol no, n chc th thu c anehit. Cu 26: Nung nng m gam hn hp gm Al v CuO trong iu kin khng c khng kh. Cho cht rn sau phn ng vo dung dch NaOH (d) thu c 672 ml kh H 2 v cht rn X. Ho tan ht X trong dung dch
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Ti liu n thi i hc nm 2012 -2013 HNO3 long (d) thy c 448 ml kh NO (cc phn ng xy ra hon ton v cc th tch kh o ktc). Gi tr m l: A. 2,94 B. 3,48 C. 34,80 D. 29,40 Cu 27: Mt hp cht X c khi lng phn t bng 103. Cho 51,50 gam X phn ng ht vi 500 ml dung dch NaOH 1,20M, thu c dung dch Y trong c mui ca aminaxit v ancol (c khi lng phn t ln hn khi lng phn t O2). C cn Y thu m gam cht rn. Gi tr m l: A. 52,50 B. 24,25 C. 26,25 D. 48,50 Cu 28: Cho Ba kim loi ln lt vo cc dung dch sau: NaHCO 3, CuSO4, (NH4)2CO3, NaNO3, MgCl2. S dung dch to kt ta l: A. 5 B. 4 C. 2 D. 3 Cu 29: Cho cc cht: amoniac (1); anilin (2); p-nitroanilin (3); p-metylanilin (4); metylamin (5); imetylamin (6). Th t tng dn lc baz ca cc cht l: A. (3) < (2) < (4) < (1) < (5) < (6) B. (2) > (3) > (4) > (1) > (5) > (6) C. (3) < (1) < (4) < (2) < (5) < (6) D. (2) < (3) < (4) < (1) < (5) < (6) Cu 30: Hp th hon ton 4,48 lt CO 2 (ktc) vo 200ml dung dch cha Na 2CO3 0,5M v NaOH 0,75M thu c dung dch X. Cho dung dch BaCl2 d vo dung dch X thu c kt ta c khi lng l: A. 29,55 gam. B. 19,7 gam. C. 9,85 gam. D. 39,4 gam. Cu 31: Cho cc cht sau: toluen, etilen, xiclopropan, stiren, vinylaxetilen, etanal, imetyl xeton, propilen. S cht lm mt mu dung dch KMnO4 nhit thng l: A. 4. B. 5. C. 7. D. 6. Cu 32: Hn hp X gm HCOOH v CH 3COOH trn theo t l mol 1 : 1. Cho 10,6 gam hn hp X tc dng vi 11,5 gam C2H5OH (c H2SO4 c lm xc tc) thu c m gam este (hiu sut phn ng este ha t 80%). Gi tr ca m l: A. 16,2. B. 14,08. C. 17,6. D. 12,96. Cu 33: iu no sau y khng ng? A. Cht do l nhng vt liu b bin dng di tc dng ca nhit v p sut m vn gi nguyn bin dng khi thi tc dng. B. T visco, t axetat l t tng hp. C. Nilon-6,6 v t capron l poliamit D. T tm, bng, len l polime thin nhin. Cu 34: Khi ha tan SO2 vo nc ln lt c cc cn bng sau: SO2 + H2O H2SO3 (1) H2SO3 H+ + HSO3- (2) HSO3- H+ + SO32- (3) Nng cn bng ca SO2 s A. gim khi un nng dd hoc thm HCl hoc thm NaOH . B. tng khi un nng dd hoc thm NaOH v gim khi thm HCl. C. gim khi un nng dd hay thm NaOH v tng khi thm HCl. D. tng khi un nng dd hay thm HCl v gim khi thm NaOH. Cu 35: Cho cc nhn xt sau: 1) Sc Ozon vo dung dch KI s thu c dung dch c kh nng lm h tinh bt ho xanh. 2) Hiro peoxit v hiro sunfua c th lm mt mu dung dch thuc tm trong mi trng H2SO4 long. 3) Sc hiro sunfua vo dung dch FeCl3 s thy xut hin vn c mu vng. 4) Dung dch H2S lu trong khng kh s c vn c mu vng. 5) Hiro peoxit l cht kh mnh v khng c tnh oxi ho Cc nhn xt ng l : A. 1, 3, 4. B. 1, 2, 4, 5. C. 1, 2, 3, 4. D. 2, 4, 5. 22+ Cu 36: Cho cc cht v ion sau: Cl , Na, NH3, HCl, O , Fe , SO2, Cl2. Cc cht v ion ch th hin c tnh kh trong cc phn ng oxi ha kh l: A. Cl-, Na, O2B. Cl-, Na, O2-, NH3, Fe2+ C. Na, O2-, NH3, HCl D. Na, O2-, HCl, NH3, Fe2+ Cu 37: t chy 3,2 gam mt este E n chc, mch h c 3,584 lt CO 2 (ktc) v 2,304 gam H2O. Nu cho 15 gam E tc dng vi 200 ml dung dch NaOH 1M, c cn dung dch sau phn ng thu c 14,3 gam cht rn khan. Vy cng thc ca ancol to nn este trn c th l: A. CH2=CH-OH B. CH3OH C. CH3CH2OH D. CH2=CH-CH2OH
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Ti liu n thi i hc nm 2012 -2013 Cu 38: S nguyn t m nguyn t ca n ( trng thi c bn) c tng s electron trn cc phn lp s bng 7 l: A. 9. B. 3. C. 5. D. 1. Cu 39: Cho cc cht sau: axetilen, axit fomic, fomanehit, phenyl fomat, glucz, anehit axetic, metyl axetat, mantz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l: A. 6 B. 7 C. 8 D. 5 Cu 40: Cho cc cht: FeCO3, Fe(NO3)2, Fe2(SO4)3, FeSO4, FeS, FeS2, CuS. S lng cht c th c kh thot ra khi cho vo dung dch HCl v un nng nh l: A. 7. B. 4. C. 5. D. 6. Cu 41: Chia 38,1 gam FeCl2 thnh 2 phn, phn 2 c khi lng gp 3 ln phn 1. em phn 1 phn ng ht vi dung dch KMnO4 d, trong mi trng H2SO4 long, d, thu ly kh thot ra. em ton b kh ny phn ng ht vi phn 2, c cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l? A. 29,640. B. 28,575. C. 24,375. D. 33,900. Cu 42: Pht biu no sau y l ng ? A. Phn t cc amino axit ch c 1 nhm amino. B. Trong peptit mch h to ra t n phn t H2NRCOOH, s lin kt peptit l (n1) C. Dung dch cc amino axit u khng lm i mu qu tm. D. Phn t ipeptit mch h c 2 lin kt peptit. Cu 43: C cc dung dch ring r sau: AlCl 3, NaCl, MgCl2, H2SO4. Ch dng thm mt dung dch no sau y nhn bit c 4 dung dch trn? A. NaOH. B. qu tm. C. AgNO3. D. BaCl2. Cu 44: Cho 35,48 gam hn hp X gm Cu v FeCO 3 vo dung dch HNO3 long, un nng v khuy u. Sau khi cc phn ng xy ra hon ton thu c NO; 0,03 mol kh CO 2; dung dch Y v 21,44 gam kim loi. C cn dung dch Y thu c khi lng cht rn khan l: A. 38,82 g B. 36,24 g C. 36,42 g D. 38,28 g Cu 45: Khi phn tch thnh phn mt ancol n chc X th thu c kt qu: tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ancol ng vi cng thc phn t ca X l: A. 1 B. 2 C. 3 D. 4 Cu 46: Ha tan hon ton 80 gam hn hp X gm CuSO4, FeSO4 v Fe2(SO4)3 trong S chim 22,5% v khi lng trong nc c dung dch X. Thm NaOH d vo X, lc kt ta em nung trong khng kh n khi lng khng i thu c cht rn Y, thi CO d qua Y thu c hn hp rn Z. Bit cc phn ng xy ra hon ton. Khi lng ca Z l: A. 30 gam B. 40 gam C. 26 gam D. 36 gam Cu 47: Cho m gam hn hp X gm hai ancol no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H 2 l 13,75). Cho ton b Y phn ng vi mt lng d AgNO3 trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. (Cc phn ng u xy ra hon ton). Gi tr ca m l: A. 7,4 B. 8,8 C. 9,2 D. 7,8 Cu 48: Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (mantoz). S cht trong dy tham gia c phn ng trng gng l: A. 6 B. 4 C. 5 D. 3 Cu 49: hirat ha 2-metylbutan-2-ol thu c sn phm chnh l anken no sau y? A. 3-metyl but-1-en B. Pent-1-en C. 2-metyl but-1-en D. 2-metyl but-2-en Cu 50: Nung hn hp SO2, O2 c s mol bng nhau trong mt bnh kn c th tch khng i vi cht xc tc thch hp. Sau mt thi gian, a bnh v nht ban u thy p sut trong bnh gim 10% so vi p sut ban u. Hiu sut ca phn ng xy ra bng: A. 40% B. 50% C. 20% D. 75%

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Ti liu n thi i hc nm 2012 -2013 B S 9 Cu 1: Cho 2.46 gam hn hp gm HCOOH, CH 3COOH, C6H5OH, H2NCH2COOH tc dng va vi 40 ml dd NaOH 1M. Tng khi lng mui khan thu c sau khi p l A. 6.45 gam B. 8.42 gam C. 3.52 gam D. 3.34 gam Cu 2: Dy cc cht u lm mt mu dd thuc tm l A. Axeton, etilen, anehit axetic, cumen B. Etilen, axetilen, anehit fomic, toluen C. Benzen, but-1-en, axit fomic, p-xilen D. Xiclobutan, but-1-in, m-xilen, axit axetic Cu 3: Cho cc CTPT sau : C 3H7Cl , C3H8O v C3H9N. Hy cho bit s sp xp no sau y theo chiu tng dn s lng ng phn ng vi cc CTPT ? A. C3H8O < C3H9N < C3H7Cl B. C3H7Cl < C3H8O < C3H9N C. C3H8O < C3H7Cl < C3H9N D. C3H7Cl < C3H9N < C3H8O Cu 4: Cht bo A c ch s axit l 7. x phng ho 10 kg A, ngi ta un nng n vi dd cha 1.420 kg NaOH. Sau khi p xy ra hon ton trung ho hn hp, cn dng 500ml dd HCl 1M. Khi lng x phng (kg) thu c l A. 10.3455 B. 10.3435 C. 10.3445 D. 10.3425 Cu 5: A l hn hp kh gm SO2 v CO2 c t khi hi so vi H2 l 27. Dn a mol hn hp kh A qua bnh ng 1 lt dd NaOH 1.5a M, sau p c cn dd thu c m gam mui. Biu thc lin h gia m v a l A. m=116a B. m=141a C. m=103.5a D. m=105a Cu 6: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3.75. Dn X qua Ni nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca p hiro ho l A. 40% B. 50% C. 25% D. 20% Cu 7: Ru X, anehit Y, axit cacboxylic Z c cng s nguyn t H trong phn t, thuc cc dy ng ng no n chc mch h. t hon ton hn hp 3 cht ny (c s mol bng nhau) thu c t l mol CO2:H2O=11:12 . Vy CTPT ca X, Y, Z l: A. C4H10O, C5H10O, C5H10O2 B. C2H6O, C3H6O, C3H6O2 C. C3H8O, C4H8O, C4H8O2 D. CH4O, C2H4O, C2H4O2 Cu 8: Dy gm cc cht no sau y u c tnh lng tnh ? A. Al, NaHCO3, NaAlO2, ZnO, Be(OH)2 B. ZnCl2, AlCl3, NaAlO2, NaHCO3, H2NCH2COOH C. AlCl3, H2O, NaHCO3, Zn(OH)2, ZnO D. H2O, CH3COONH4, H2NCH2COOH, NaHCO3 Cu 9: t chy 1.6 gam mt este E n chc c 3.52 gam CO 2 v 1.152 gam H2O. Nu cho 10 gam E tc dng vi 150ml dd NaOH 1M , c cn dd sau p thu c 16 gam cht rn khan . Vy cng thc ca axit to nn este trn c th l A. HOOC(CH2)3CH2OH B. HOOC-CH2-CH(OH)-CH3 C. CH2=C(CH3)-COOH D. CH2=CH-COOH Cu 10: Ha tan hon ton hn hp gm x mol Hg 2S v 0,04 mol FeS2 bng dd HNO3 m c, un nng, ch thu cc mui sunfat kim loi c ha tr cao nht v c kh V lt NO2 thot ra(KTC). Tr s ca V l: A. 2,24 lt B. 8,96 lt C. 17,92 lt D. 20,16 lt Cu 11: Dy gm cc cht c th iu ch trc tip (bng mt p) to ra axit axetic l: A. C2H4(OH)2, CH3OH, CH3CHO. B. CH3CHO, C2H5OH, C2H5COOCH3. C. CH3CHO, C6H12O6 (glucoz), CH3OH. D. CH3OH, C2H5OH, CH3CHO. Cu 12: Cho 3.2 gam Cu tc dng vi 100ml dd hn hp HNO3 0.8M v H2SO4 0.2M, sn phm kh duy nht l kh NO. S gam mui khan thu c l A. 8.84 B. 7.90 C. 5.64 D. 10.08 Cu 13: Ho tan ht m gam Al2(SO4)3 vo nc c dd A. Cho 300 ml dd NaOH 1M vo A, thu c a gam kt ta. Mc khc, nu cho 400 ml dd NaOH 1M vo A, cng thu c a gam kt ta. Gi tr ca m l A. 21.375. B. 42.75. C. 17.1. D. 22.8 Cu 14: t chy hon ton 4.872 gam mt Hirocacbon X, dn sn phm chy qua bnh ng dd nc vi trong. Sau p thu c 27.93 gam kt ta v thy khi lng dd gim 5.586 gam. CTPT ca X l A. C3H6 B. C4H8 C. CH4 D. C4H10 Cu 15: Ho tan 5.4 gam bt Al vo 150 ml dd A cha Fe(NO 3)3 1M v Cu(NO3)2 1M. Kt thc p thu c m gam rn. Gi tr ca m l A. 10.95 B. 13.20 C. 15.20 D. 13.80
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Ti liu n thi i hc nm 2012 -2013 Cu 16: Thy phn 34.2 gam mantz vi hiu sut 50%. Sau tin hnh p trng bc vi dd thu c. Khi lng Ag kt ta l A. 10.8 gam B. 43.2 gam C. 32.4 gam D. 21.6 gam Cu 17: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2(anilin), C6H5OH (phenol), C6H6(benzen), CH3CHO. S cht trong dy p c vi nc brom l A. 8 B. 6 C. 7 D. 5 Cu 18: C 4 dd trong sut , mi dd ch cha mt cation v mt loi anion. Cc loi ion trong c 4 dd gm: Ca2+, Mg2+, Pb2+, Na+, SO42-, Cl-, CO32-, NO3-. l 4 dd g? A. BaCO3, MgSO4, NaCl, Pb(NO3)2 B. Mg(NO3)2, BaCl2, Na2CO3, PbSO4 C. BaCl2, PbSO4, MgCl2, Na2CO3 D. BaCl2, MgSO4, Na2CO3, Pb(NO3)2 Cu 19: Dy ch cha nhng amino axit c s nhm amino v s nhm cacboxyl bng nhau l A. Gly, Val, Tyr, Ala B. Gly, Ala, Glu, Tyr C. Gly, Val , Lys, Ala D. Gly, Ala, Glu, Lys Cu 20: Hy cho bit, p no sau y HCl ng vai tr l cht oxi ha? A. Fe + KNO3 + 4HCl FeCl3 + KCl + NO + 2H2O B. MnO2 + 4HCl MnCl2 + Cl2 + 2H2O C. Fe + 2HCl FeCl2 + H2 D. NaOH + HCl NaCl + H2O Cu 21: Cho 6.4 gam dd ru A c nng 71.875% tc dng vi lng d Na thu c 2.8 lt H 2 iu kin chun. S nguyn t H c trong CTPT ru A l A. 6 B. 4 C. 8 D. 10 Cu 22: Cho hn hp kim loi Mg, Zn, Fe vo dd cha AgNO 3 v Cu(NO3)2.. Sau khi p xy ra hon ton thu c dd X gm 3 mui v cht rn Y gm ba kim loi. Ba mui trong X l A. Mg(NO3)2, Zn(NO3)2, Fe(NO3)3 B. Mg(NO3)2, Zn(NO3)2, Fe(NO3)2 C. Mg(NO3)2, Fe(NO3)3, AgNO3 D. Mg(NO3)2, Zn(NO3)2, Cu(NO3)2 Cu 23: Sc V lt CO2 ( iu kin chun) vo 200 ml dd X gm Ba(OH) 2 1M v NaOH 1M . Sau p thu c 19.7 gam kt ta, gi tr ca V l A. 2.24 v 11.2 B. 5.6 v 1.2 C. 2.24 v 4.48 D. 6.72 v 4.48 Cu 24: Tng s ht ca mt nguyn t X l 28. X l A. N B. F C. O D. Ne Cu 25: t chy hon ton mt hn hp A (glucz, anehit fomic, axit axetic) cn 2.24 lt O 2 (iu kin chun). Dn sn phm chy qua bnh ng dd Ca(OH)2, thy khi lng bnh tng m gam. Gi tr ca m l A. 3.1 B. 6.2 C. 12.4 D. 4.4 Cu 26: Cho mt lung kh CO i qua ng s ng m gam Fe 2O3 nung nng. Sau mt thi gian thu c 10.44 gam cht rn X gm Fe, FeO, Fe 2O3 v Fe3O4. Ha tan ht X trong dd HNO 3 c, nng thu c 4.368 lt NO 2 (sn phm kh duy nht iu kin chun). Gi tr ca m l A. 24 B. 10.8 C. 12 D. 16 Cu 27: Cho cc cht sau : axetilen, axit fomic, fomanehit, phenyl fomat, glucz, anehit axetic, metyl axetat, mantz, natri fomat, axeton. S cht c th tham gia p trng gng l A. 5 B. 6 C. 7 D. 8 Cu 28: Bit Cu c s hiu nguyn t l 29. Cu hnh electron ca ion Cu+ l A. [Ar]3d9 B. [Ar]3d94s1 C. [Ar]3d10 D. [Ar]3d104s1 Cu 29: Cho 29.8 gam hn hp 2 amin n chc k tip tc dng ht vi dd HCl, lm kh dd thu c 51.7 gam mui khan. CTPT 2 amin l A. CH5N v C2H7N B. C2H7N v C3H9N C. C3H9N v C4H11N D. C3H7N v C4H9N Cu 30: Cho cc cht: amoniac (1); anilin (2); p-nitroanilin(3); p-metylanilin (4) ; metylamin (5) ; imetylamin (6) . Hy chn s sp xp cc cht trn theo th t lc baz tng dn . A. (3) < (1) < (4) <(2) < (5) < (6) B. (2) > (3) > (4) > (1) > (5) > (6) C. (2) < (3) < (4) < (1) < (5) < (6) D. (3) < (2) < (4) < (1) < (5) < (6) Cu 31: Cho phng trnh ho hc: Al + HNO3 Al(NO3)3 + NO + N2O + H2O (Bit t l th tch N2O: NO = 1 : 3). Sau khi cn bng phng trnh ho hc trn vi h s cc cht l nhng s nguyn, ti gin th h s ca HNO3 l A. 64 B. 66 C. 60 D. 62 Cu 32: C 45.75 gam cao su buna-S p va ht vi 20 gam brom trong CCl 4. T l mt xch butaien v stiren trong cao su buna-S l
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Ti liu n thi i hc nm 2012 -2013 A. 1 : 3 B. 1 : 2 C. 2 : 3 D. 3 : 5 Cu 33: Khi nhit phn hon ton 100 gam mi cht sau: KClO 3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht to ra lng O2 t nht l A. KNO3 B. KMnO4 C. AgNO3 D. KClO3 Cu 34: nhn bit ba l mt nhn: phenol, stiren, ancol benzylic, ngi ta dng mt thuc th duy nht l A. Na B. Dd NaOH C. Nc brom D. Ca(OH)2 Cu 35: Cho t t 150 ml dd HCl 1M vo 500 ml dd A gm Na 2CO3 v NaHCO3 th thu c 1.008 lt kh (iu kin chun) v dd B. Cho dd B tc dng vi dd Ba(OH) 2 d th thu c 29.55 gam kt ta. Nng mol ca Na2CO3 v NaHCO3 trong dd A ln lt l: A. 0.21M v 0.18M B. 0.18M v 0.26M C. 0.2M v 0.4M D. 0.21M v 0.32M Cu 36: a mt hn hp kh N2 v H2 c t l 1: 3 vo thp tng hp, sau p thy th tch kh i ra gim 1/10 so vi ban u. Tnh thnh phn phn trm v th tch ca hn hp kh sau p. A. 22.22%, 66.67%, 11.11% B. 30%, 60%, 10% C. 20%, 60%, 20% D. 33.33%, 50%, 16.67% Cu 37: Cho cc kim loi: Cr, W , Fe , Cu , Cs . Sp xp theo chiu tng dn cng t tri sang phi l A. Cu < Cs < Fe < Cr < W B. Cs < Cu < Fe < W < Cr C. Cu < Cs < Fe < W < Cr D. Cs < Cu < Fe < Cr < W Cu 38: in phn 2 lt dd hn hp gm NaCl v CuSO 4 n khi H2O b in phn hai cc th dng li, ti catt thu 1.28 gam kim loi v ant thu 0.336 lt kh ( iu kin chun). Coi th tch dd khng i th pH ca dd thu c bng A. 12 B. 2 C. 3 D. 13 o t Cu 39: Cho phn ng: FexOy + CO FemOn + CO2. H s ng trc cht b oxi ha bn tc cht p cn bng s nguyn t cc nguyn t l: A. nx my. B. m C. my nx. D. mx 2ny. Cu 40: Cho a mol bt km vo dd c ha tan b mol Fe(NO 3)3. Tm iu kin lin h gia a v b sau khi kt thc p khng c kim loi. A. b > 3a B. a 2b C. b 2a D. b = 2a/3 Cu 41: Cho 13.8 gam axit A tc dng vi 16.8 gam KOH , c cn dd sau p thu c 26.46 gam cht rn. CTCT thu gn ca A l A. CH3COOH B. C3H6COOH C. C2H5COOH D. HCOOH Cu 42: Chn pht biu ng: A. Tnh oxi ha ca Ag+ > Cu2+ > Fe3+ > Ni2+ > Fe2+ B. Tnh oxi ha ca Ag+ > I2 > Fe3+ > Cu2+ > S2C. Tnh kh ca K > Mg > Zn > Ni > Fe > Hg D. Tnh kh ca K > Fe > Cu > I- > Fe2+ > Ag Cu 43: Cn ti thiu bao nhiu gam NaOH (m1) v Cl2 (m2) p hon ton vi 0.01 mol CrCl3. Gi tr ca m1 v m2 ln lt l A. 3.2 v 1.065 B. 3.2 v 0.5325 C. 6.4 v 0.5325 D. 6.4 v 1.065 Cu 44: Cho cc dd sau: Na2CO3, NaOH v CH3COONa c cng nng mol/l v c cc gi tr pH tng ng l pH1, pH2 v pH3. S sp xp no ng vi trnh t tng dn pH. A. pH3< pH2 < pH1 B. pH1 < pH3 < pH2 C. pH3 < pH1 < pH2 D. pH1 < pH2 < pH3 Cu 45: Ch dng mt thuc th phn bit cc kim loi sau: Mg, Zn, Fe, Ba? A. Dd H2SO4 long B. Nc C. Dd NaOH D. Dd HCl Cu 46: Ho tan 19.2 gam Cu vo 500 ml dd NaNO3 1M, sau thm vo 500ml dd HCl 2M . Kt thc p thu c dd X v kh NO duy nht, phi thm bao nhiu ml dd NaOH 1M vo X kt ta ht ion Cu2+ A. 120 B. 400 C. 600 D. 800 Cu 47: Cho Na d tc dng vi a gam dd CH3COOH x% thy sinh ra 0,45833a gam H2. Gi tr x l A. 36% B. 10% C. 5% D. 25% Cu 48: Thy phn hon ton mt lng mantoz, sau cho ton b lng glucoz thu c ln men thnh ancol etylic th thu c 100 ml ancol 460. Khi lng ring ca ancol l 0,8gam/ml. Hp th ton b kh CO 2 vo dd NaOH d thu c mui c khi lng l A. 84.8 gam B. 106 gam C. 212 gam D. 169.6 gam Cu 49: Cho 0.1 mol cht X ( CH6O3N2) tc dng vi dd cha 0.2 mol NaOH un nng thu c cht kh lm xanh giy qu tm m v dd Y. C cn dd Y thu c m gam rn khan. Gi tr ca m l
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Ti liu n thi i hc nm 2012 -2013 A. 8.5 B. 12.5 C. 15 D. 21.8 Cu 50: t chy hon ton 1 mol ancol no A cn 3.5 mol O2. CTPT ca A l A. C3H6O2 B. C3H8O3 C. C2H6O D. C2H6O2 B S 10 Cu 1: Phn ng Cu + H + NO3 Cu + NO + H2O. H s ti gin ca cc cht theo th t l : A. 1, 4, 1, 1, 1, 2 B. 2, 12, 3, 2, 3, 6 C. 3, 8, 2, 3, 1, 6 D. 3, 8, 2, 3, 2, 4 Cu 2: Cho t t dung dch c 0,4mol HCl vo dung dch hn hp cha 0,2mol NaHCO3 v 0,3mol Na2CO3 th th tch kh CO2 thu c ktc l: A. 2,128lt B. 6,72lt C. 2,24lt D. 3,36lt Cu 3: Cho hn hp Fe + Cu tc dng vi dung dch HNO3, phn ng xong thu c dung dch A ch cha mt cht tan. Cht tan l : A. HNO3 B. Fe(NO3)2 C. Fe(NO3)3 D. Cu(NO3)2 Cu 4: Cho 0,1 mol ancol X tc dng vi Na thu c 3,36 lt kh ( ktc). Mt khc nu t chy hon ton mt mt lt ancol X thu c CO2 v hi nc theo t l mol CO2 : mol H2O = 3:4. Cng thc phn t ca X l: A. C4H7(OH)3 B. C3H5(OH)3 C. C3H6(OH)2 D. C4H6(OH)2 Cu 5: Cho 13,8 gam hn hp gm But-1-in v anehit fomic vo lng d dung dch AgNO 3/NH3 thy c 0,6 mol AgNO3 phn ng. Thnh phn phn trm theo khi lng ca anehit fomic c trong hn hp l A. 65,22%. B. 26,40%. C. 32,60%. D. 21,74%. Cu 6: Cu trong t nhin c 2 ng v: 63Cu v 65Cu. Bit nguyn t khi trung bnh ca Cu l 63,54. Tnh % khi lng ca 65Cu trong CuSO4 (S=32, O = 16). A. 29,78%. B. 11%. C. 27%. D. 17,16%. Cu 7: Cho Al vo hn hp FeCl3 v HCl d. Sau khi phn ng xy ra hon ton thu c cc mui: A. AlCl3 v FeCl2. B. AlCl3 v FeCl3. C. AlCl3. D. FeCl3. Cu 8: Nicotin l hot cht c trong thuc l lm tng kh nng ung th phi. Khi lng phn t ca Nicotin khong 160u. Trong phn t Nicotin c 74,03%C; 8,699%H; 17,27%N. Cng thc phn t ca Nicotin l A. C10H12N2 B. C10H12N C. C10H14N2 D. C10H11N Cu 9: Saccaroz v glucoz u c A. Phn ng vi dung dch NaCl B. Phn ng vi AgNO3 trong dung dch NH3, un nng C. Phn ng thy phn trong mi trng axit D. Phn ng vi Cu(OH)2 nhit thng to thnh dung dch xanh lam Cu 10: Xenluloz trinitrat l cht d chy v n mnh, c iu ch t xenluloz v axit nitric. Bit H=90%. Th tch axit nitric 99,67% (d=1,25 g/ml) cn sn xut 53,46 kg xenluloz trinitrat l : A. 30,24 lt B. 24,49 lt C. 30,34 lt D. 24,58 lt Cu 11: Hp cht (A) C3H7O2N tc dng c vi NaOH, H2SO4 v lm mt mu dung dch Br2. Khi(A) tac dung va u vi 0,1 mol NaOH thi khi lng mui thu c la A. 9,4g B. 6,8g C. 8g D. 10,8g Cu 12: Cho 6g Cu kim loi tc dng vi 120ml dung dch A gm HNO3 1M v H2SO4 0,5M thu c V lt kh NO ktc. Gi tr ca V l A. 1,3440 B. 0,6720 C. 0,0672 D. 2,0160 Cu 13: Cho 12,9 g hn hp bt kim loi gm Al v Mg phn ng ht dung dch hn hp 2 axit HNO 3 v H2SO4 c thu c 0,1 mol mi kh : SO2, NO, N2O. Thnh phn phn trm theo s mol ca Mg trong hn hp ban u l A. 60,00% B. 40,00% C. 37,21% D. 62,79% Cu 14: Cho cc cht sau y: propin, vinyl axetilen, andehit axetic, glucoz, fructoz, glixerol, saccaroz, natri fomat, axit axetic, etyl fomat. S cht tc dng vi dung dch AgNO3/NH3 l A. 8. B. 5. C. 6. D. 7. Cu 15: Theo t chc Y t th gii, nng Pb2+ ti a trong nc sinh hot l 0,05 mg/l. Vi kt qu phn tch cc mu nc nh sau, ngun nc b nhim bi Pb2+ l mu A. C 0,15 mg Pb2+ trong 2 lt B. C 0,03 mg Pb2+ trong 0,75 lt C. C 0,16 mg Pb2+ trong 4 lt D. C 0,03 mg Pb2+ trong 1,25 lt
+ 2+

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Trang 33

Ti liu n thi i hc nm 2012 -2013 Cu 16: un nng hn hp 2 ancol ROH v ROH vi H 2SO4 m c 140oC, s lng cc ete thu c ti a l A. 3 B. 2 C. 4 D. 1 Cu 17: Cho 7,8g hn hp Cu v Na ( c t l mol 1:4) vo 100g nc. Nng phn trm ca dung dch thu c l A. 7,66% B. 7,897% C. 8,02% D. 7,75% Cu 18: Ha tan 1,17 gam NaCl vo nc ri em in phn c mng ngn, thu c 500ml dung dch c pH = 12. Hiu sut in phn l A. 35% B. 45% C. 25% D. 15% Cu 19: Dy cht va lm mt mu dung dch Br2 va to kt ta vng nht vi dung dch AgNO3 trong NH3 l A. metan , etilen , axetilen B. axetilen , but-1-in , vinylaxetilen C. axetilen , but-1-in , but-2-in D. etilen ,axetilen , isopren Cu 20: Cho phn ng ha hc : CO (k) + Cl2 (k) COCl2 (k) Bit rng nhit T, nng cn bng ca CO l 0,2M v ca Cl2 l 0,3M v hng s cn bng l 4. Nng cn bng cua cht to thnh (COCl2) nhit T ca phn ng c gi tr A. 0,015M B. 0,240M C. 0,500M D. 0,300M Cu 21: Trong phng th nghim c th iu ch CH4 bng cch A. nhit phn natri axetat vi vi ti xt B. tng hp t cacbon v hiro C. crackinh butan D. kh CH3NH2 bng Al nhit cao Cu 22: Dy cc cht ch c tnh kh l A. NO2, HNO3, Al B. NH3, H2S, Na C. HI, HCl, S D. SO2, H2S, Ca Cu 23: Cho cc cht sau : C6H5NH2 (1) ; C2H5NH2 (2) ; (C2H5)2NH2 (3) ; NaOH (4) ; NH3 (5) . Trt t tng dn tnh baz (t tri qua phi) l A. 1, 5, 3, 2, 4 B. 1, 2, 5, 3, 4 C. 2, 1, 3, 5, 4 D. 1, 5, 2, 3, 4 Cu 24: Ho tan hon ton 49,6g hn hp X gm Fe, FeO, Fe3O4, Fe2O3 bng dung dch H2SO4 c, nng, d thu c dung dch Y v 8,96lt kh SO 2 ktc. C cn dung dch Y thu c m gam mui khan. Gi tr ca m l A. 175 B. 140 C. 70 D. 280 Cu ( OH ) / OH to 2 Cu 25: Cacbohidrat Z tham gia chuyn ha: Z kt ta gch. dung dch xanh lam Z khng th l A. Fructoz B. Glucoz C. Mantoz D. Saccaroz Cu 26: C 5 mu kim loi Ag, Mg, Fe, Zn, Ba. Thuc th c th nhn bit c c 5 mu kim loi l A. Dung dch NaCl B. Dung dch NaOH C. Dung dch H2SO4 long D. Dung dch NH3 Cu 27: Khi in phn dung dch mui, gi tr pH khu vc gn 1 in cc tng ln. Th dung dch mui em in phn l dung dch no sau y? A. AgNO3 B. K2SO4 C. CuSO4 D. KCl Cu 28: Cho 1,97 gam fomalin vo dung dch AgNO3/NH3 d, cho 10,8 gam bc kim loi . Nng phn trm ca dung dch fomalin l : A. 37%. B. 38,07%. C. 36%. D. 58%. Cu 29: C bao nhiu ng phn l hp cht thm c cng thc phn t C 8H10O tc dng c vi Na, nhng khng tc dng vi NaOH? A. 6. B. 7. C. 5. D. 4. Cu 30: t chy 6g cht hu c X ch thu c 4,48lt kh CO 2 ktc v 3,6g nc. S lin kt ti a cha trong X l: A. 1 B. 3 C. 2 D. 0 Cu 31: Cho 4 axit CH3COOH (X), Cl2CHCOOH (Y), ClCH2COOH (Z), BrCH2COOH (T). Chiu tng dn tnh axit ca cc axit trn l : A. T, Z, Y, X B. X, Z, T, Y C. X, T, Z, Y D. Y, Z, T, X Cu 32: Ha tan 10g hn hp cha 2 mui cacbonat ca kim loi ha tr II v I bng dung dch HCl, ta thu c dung dch A v 0,672lt kh bay ra(ktc). Khi c cn dung dch A, khi lng mui khan thu c l: A. 12,33g B. 10,33g C. 9,33g D. 11,33g
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Ti liu n thi i hc nm 2012 -2013 Cu 33: Cho 2,46 gam hn hp gm HCOOH, CH 3COOH, C6H5OH tc dng va vi 40ml dung dch NaOH 1M. Tng khi lng mui khan thu c sau phn ng l : A. 3,52 gam B. 6,45 gam C. 8,42 gam D. 3,34g Cu 34: Cho phn ng: N2 + 3H2 2NH3 . H< 0. cn bng chuyn dch theo chiu thun cn: A. Tng p sut ca h phn ng, tng nhit . B. Tng nng N2, NH3 C. Dng cht xc tc. D. Tng p sut ca h phn ng, h nhit . Cu 35: Dy gm cc cht u phn ng vi phenol l: A. nc brom, axit axetic, dung dch NaOH. B. nc brom, anhirit axetic, dung dch NaOH. C. nc brom, anehit axetic, dung dch NaOH D. dung dch NaCl, dung dch NaOH, kim loi Na. Cu 36: S ng phn amin bc III c cng cng thc phn t C5H13N ? A. 3 B. 4 C. 2 D. 5 Cu 37: t chy hon ton m gam hn hp gm C 2H4, C3H6, C4H8 thu c 1,68 lt kh CO2 (ktc). Gi tr ca m bng: A. 1,25g B. 1,15g C. 1,05g D. 0,95g Cu 38: Phn ng iu ch Fe(NO3)2 l A. Ba(NO3)2 + FeSO4 B. Fe(OH)2 + HNO3 C. Fe + HNO3 D. FeCl2 + HNO3 Cu 39: t nng 12,27 gam hn hp X gm Al, Fe, Cu trong khng kh, sau phn ng hon ton thu c 18,53 gam hn hp Y gm cc oxit. Cho Y tc dng vi dung dch xt thy c ti a 100 ml dung dch NaOH 1M phn ng. kh ht hn hp Y cn dng V lt (ktc) hn hp kh Z gm H2 v CO. Gi tr ca V l A. 10,808 B. 2,702 C. 5,404 D. 4,053 Cu 40: Cht hu c Y c cng thc phn t C4H7ClO2. Bit rng : Y + NaOH mui hu c Z + C2H4(OH)2 + NaCl. Y ph hp l : A. Cl-CH2-OOC-CH2CH3 B. Cl-CH2-COO-CH2CH3 C. CH3COOCHCl-CH3 D. CH3COO-CH2-CH2Cl Cu 41: T mui n, nc v iu kin cn thit khng th iu ch c: A. dung dch NaOH. B. dung dch NaHCO3. C. nc Javen. D. axit HCl. Cu 42: Cho hn hp X gm 0,2 mol axetilen v 0,35 mol H2 vo bnh kn c xc tc Ni nung nng. Sau mt thi gian thu c hn hp Y gm 4 kh. Khi cho Y li qua dung dch Br 2 d thy c 4,48 lt (kc) kh Z bay ra. T khi ca Z so vi H2 l 4,5. tng khi lng ca bnh brom l A. 5,2g. B. 6,0g. C. 4,1g. D. 2,05g. 2+ 2+ 2+ Cu 43: Dung dch X cha 5 loi ion Mg , Ba , Ca , 0,1 mol Cl v 0,2 mol NO3 . Thm t t dung dch K2CO3 1M vo dung dch X n khi c lng kt ta ln nht th th tch dung dch K2CO3 cho vo l A. 200 ml. B. 300 ml. C. 250 ml. D. 150 ml. Cu 44: Cho dung dch NaOH d vo 100 ml dung dch cha ng thi Ba(HCO 3)2 0,5 M v BaCl2 0,4 M th thu c M gam kt ta. Gi tr ca m l A. 17,73 B. 19,70 C. 29,55 D. 23,64 Cu 45: Cho 2,16 gam bt Al vo dung dch cha hn hp gm CuCl2 0,12 mol v FeCl3 0,06 mol. Sau khi phn ng xy ra hon ton c cht rn khng tan X.Khi lng cht rn X l A. 5,76g. B. 1,92g. C. 5,28g. D. 7,68g. Cu 46: Cho cc dung dch sau: dung dch HCl, dung dch Ca(NO 3)2, dung dch FeCl3, dd AgNO3, dung dch hn hp HCl + NaNO3, dung dch hn hp NaHSO4 + NaNO3. S dung dch c th tc dng vi Cu l A. 2. B. 3. C. 4. D. 5. Cu 47: X l dung dch NaOH C%. Ly 18 gam X hoc 74 gam X tc dng vi 400 ml dung dch AlCl 3 0,1M th lng kt ta vn nh nhau. Gi tr ca C l: A. 7,2 B. 8 C. 4 D. 3,6 Cu 48: 100ml dung dch A cha NaOH 0,1M v NaAlO2 0,3M. Thm t t dung dch HCl 0,1M vo dung dch A cho n khi kt ta tan tr li 1 phn. em nung kt ta n khi lng khng i th thu c 1,02g cht rn. Th tch dung dch HCl 0,1M dng l: A. 0,6 lt B. 0,5 lt C. 0,55 lt D. 0,70 lt Cu 49: Cho a gam Al tc dng vi b gam Fe2O3 thu c hn hp X . Ha tan X trong dd HNO3 d, thu c 2,24 lt (ktc) mt kh khng mu, ha nu trong khng kh. Ga tr ca a l: A. 4,00 gam. B. 2,70 gam. C. 1,35 gam. D. 5,40 gam. Cu 50: A, B l 2 ancol n chc. Cho hn hp gm 1,6 gam A v 3 gam B tc dng ht vi Na thu c 1,12 lt H2 (ktc). Cng thc phn t B l: ( bit MA< MB)
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A. C3H7OH

B. C2H5OH

C. CH3OH B S 11

Ti liu n thi i hc nm 2012 -2013 D. C4H9OH

Cu 1: Cho 10 ml dung dch ancol etylic 46 phn ng ht vi kim loi Na (d), thu c V lt kh H2 (ktc). Bit khi lng ring ca ancol etylic nguyn cht bng 0,8 g/ml. Gi tr ca V l A. 3,360. B. 0,896. C. 2,128. D. 4,256. Cu 2: Cho 15,6 gam hn hp hai ancol n chc, k tip nhau trong dy ng ng tc dng ht vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l A. C3H7OH v C4H9OH. B. C2H5OH v C3H7OH. C. C3H5OH v C4H7OH. D. CH3OH v C2H5OH. Cu 3: Cho dy cc cht : CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6 (benzen). S cht trong dy phn ng c vi nc brom l A. 5 B. 6 C. 7 D. 4 Cu 4: Ho tan 5,6 gam Fe bng dung dch H2SO4 long (d), thu c dung dch X. Dung dch X phn ng va vi V ml dung dch KMnO4 0,5M. Gi tr ca V l A. 40. B. 80. C. 60. D. 20. Cu 5: Mt este c cng thc phn t l C 4H6O2, khi thu phn trong mi trng axit thu c axetanehit. Cng thc cu to thu gn ca este l A. HCOO-C(CH3)=CH2. B. CH2=CH-COO-CH3. C. CH3COO-CH=CH2. D. HCOO-CH=CH-CH3. Cu 6: Dung dch lm qu tm chuyn mu xanh l A. etylamin. B. phenylamoni clorua. C. glyxin. D. anilin. Cu 7: Th nghim c kt ta sau phn ng l A. Cho dung dch NH3 n d vo dung dch Cu(NO3)2 B. Thi CO2 n d vo dung dch NaAlO2 C. Cho dung dch NaOH n d vo dung dch Cr(NO3)3. D. Thi CO2 n d vo dung dch Ca(OH)2. Cu 8: Trung ho hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l A. H2NCH2CH2NH2. B. CH3CH2CH2NH2. C. H2NCH2CH2CH2NH2. D. H2NCH2CH2CH2CH2NH2. Cu 9: Cho 1,56 gam hn hp gm Al v Al2O3 phn ng ht vi dung dch HCl (d), thu c V lt kh H2 (ktc) v dung dch X. Nh t t dung dch NH3 n d vo dung dch X thu c kt ta, lc ht lng kt ta, nung n khi lng khng i thu c 2,04 gam cht rn. Gi tr ca V l A. 0,672. B. 0,224. C. 0,448. D. 1,344. Cu 10: S sp xp no sau y ng vi trnh t gim dn tnh baz: (1) C 6H5NH2 ; (2) C2H5NH2 ; (3) (C6H5)2NH; (4) (CH3)2NH ; (5) NaOH v (6) NH3. A. (5) > (1) > (4) > (6) > (2) > (3) B. (1) > (3) > (5) > (4) > (6) > (2) C. (5) > (4) > (1) > (6) > (3) > (2) D. (5) > (4) > (2) > (6) > (1) > (3) Cu 11: C nm dung dch ng ring bit trong nm ng nghim: (NH4)2SO4, FeCl2, Cr(NO3)3, K2CO3, Al(NO3)3. Cho dung dch Ba(OH)2 n d vo nm dung dch trn. Sau khi phn ng kt thc, s ng nghim c kt ta l A. 2. B. 4. C. 5. D. 3. Cu 12: Cho cc cn bng sau :
2SO 3 (k) (1) 2SO 2 (k) + O 2 (k)
o xt,t o

2NH 3 (k) (2) N 2 (k) + 3H 2 (k)

o

xt,t o

t t CO(k) + H 2O(k) H 2 (k) + I 2 (k) (3) CO 2 (k) + H 2 (k) (4) 2HI(k) Khi thay i p sut, nhm gm cc cn bng ho hc u khng b chuyn dch l A. (1) v (2) B. (3) v (4) C. (1) v (3) D. (2) v (4) Cu 13: Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c khng kh) n khi phn ng xy ra hon ton, thu c hn hp rn Y. Chia Y thnh hai phn bng nhau: - Phn 1: Tc dng vi dung dch H2SO4 long (d), sinh ra 3,08 lt kh H2 ( ktc); - Phn 2: Tc dng vi dung dch NaOH (d), sinh ra 0,84 lt kh H2 ( ktc). Gi tr ca m l

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Ti liu n thi i hc nm 2012 -2013 A. 29,43. B. 21,40. C. 29,40. D. 22,75 Cu 14: Cc dung dch phn ng c vi Cu(OH)2 nhit thng l: A. anehit axetic, saccaroz, axit axetic. B. fructoz, axit acrylic, ancol etylic. C. lng trng trng, fructoz, axeton. D. glixerol, axit axetic, glucoz. Cu 15: Cho 5,2 gam Zn tc dng va 200ml axit HNO3 1M thu c sn phm kh duy nht l kh X. Sn phm kh X l A. NO2 . B. N2. C. NO. D. N2O. + H + Cl + HClO Cu 16: Cho cn bng ha hc: Cl2 + H2O Cht thm vo khng lm chuyn dch cn bng l A. KNO3 B. HCl C. NaCl D. NaOH Cu 17: Da nhn to (PVC) c iu ch t kh thin nhin theo s : to to to CH4 C2H2 CH2=CH-Cl [-CH2-CHCl-]n. Nu hiu sut ca ton b qu trnh iu ch l 20%, mun iu ch c 1 tn PVC th th tch kh thin nhin (cha 80% metan) iu kin tiu chun cn dng l A. 4375 m3. B. 4450 m3. C. 4480 m3. D. 6875 m3. Cu 18: Cho 200 ml dd NaOH 1,4M vo 100 ml dung dch AlCl 3 thu c m gam kt ta. Lc tch kt ta, sau sc kh CO2 n d vo li c m gam kt ta na. Nng mol ca dung dch AlCl3 l A. 0,4 B. 0,2 C. 0,8 D. 1,2 Cu 19: Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3, FeCO3 ln lt phn ng vi HNO3 c, nng. S phn ng thuc loi oxi ho - kh l A. 6. B. 5. C. 7. D. 8. Cu 20: Dy gm cc cht c sp xp theo chiu nhit si tng dn t tri sang phi l? A. C2H6; C2H5OH; CH3CHO; CH3COOH B. CH3CHO; C2H5OH; C2H6; CH3COOH C. C2H6; CH3CHO; C2H5OH; CH3COOH D. CH3COOH; C2H6; CH3CHO; C2H5OH Cu 21: Hp cht X l ancol thm cng thc phn t l C8H10O. S CTCT ca X l A. 7 B. 4 C. 6 D. 5 Cu 22: luyn c 800 tn gang c hm lng st 95% , cn dng x tn qung manhetit cha 80% Fe 3O4 (cn li l tp cht khng cha st). Bit rng lng st b hao ht trong qu trnh sn xut l 2%. Gi tr ca x l: A. 1338,68 B. 1311,90 C. 1325,16 D. 959,59 Cu 23: Cht 3-MCPD (3-monoclopropandiol) c trong nc tng v c th gy ra bnh ung th. Cht ny c CTCT l A. HOCH2CHOHCH2Cl B. HOCH2CHClCH2OH C. CH3C(OH)2CH2Cl D. CH3CHClCH(OH)2 Cu 24: Cho dy cc cht: Ca(HCO 3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong dy c tnh cht lng tnh l A. 4. B. 2. C. 5. D. 3. Cu 25: Cho 20 g hn hp 3 amin no, n chc, mch h l ng ng k tip tc dng va vi dung dch HCl 1M. C cn dung dch thu c 31,68g hn hp mui. Th tch HCl dng A. 0,320 lt B. 0,330 lt C. 0,032 lt D. 0,033 lt Cu 26: Cho 0,1 mol amino axit X tc dng va vi 0,1 mol HCl. Ton b sn phm thu c tc dng va vi 0,3 mol NaOH. X l amino axit c A. 1 nhm NH2 v 3 nhm COOH B. 1 nhm NH2 v 2 nhm COOH C. 1 nhm -NH2 v 1 nhm COOH D. 2 nhm NH2 v 1 nhm COOH Cu 27: X l mt hp cht ca st. Ha tan X vo dung dch H 2SO4 long (d), c dung dch Y. Chia Y lm hai phn: - Phn 1: Cho mt t bt Cu vo thy Cu tan ra v dung dch c mu xanh. - Phn 2: Cho mt t dung dch KMnO4 vo thy mt mu tm. Cht X l A. Fe2O3. B. FeO. C. Fe3O4. D. Fe(OH)3. Cu 28: Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO 3 trong dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO 3 long, thot ra 2,24 lt kh NO (sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l
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Ti liu n thi i hc nm 2012 -2013 A. HCHO. B. CH3CHO. C. CH3CH2CHO. D. CH2 = CHCHO. 3+ 2 2 6 2 6 5 Cu 29: Cu hnh electron ca ion X l : 1s 2s 2p 3s 3p 3d . Trong bng tun hon cc nguyn t ho hc X thuc A. chu k 4, nhm VIIIB B. chu k 4, nhm VB C. chu k 4, nhm VIIIA D. chu k 3, nhm VIIIB Cu 30: Cho 30,4 gam hn hp gm glixerol v mt ancol n chc no phn ng vi Na th thu c 8,96 lit kh (ktc). Nu cho hn hp trn tc dng vi Cu(OH)2 th ho tan c 9,8 gam Cu(OH)2. Cng thc ca ancol n chc no l A. C2H5OH B. C3H7OH C. CH3OH D. C4H9OH Cu 31: Cho cc hp cht hu c: (1) ankan; (2) ancol no, n chc, mch h; (3) xicloankan; (4) ete no, n chc, mch h; (5) anken; (6) ancol khng no (c mt lin kt i C=C), mch h; (7) ankin; (8) anehit no, n chc, mch h; (9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc. Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l: A. (3), (5), (6), (8), (9). B. (1), (3), (5), (6), (8). C. (2), (3), (5), (7), (9). D. (3), (4), (6), (7), (10). Cu 32: Trong cc loi qung st, qung c hm lng st cao nht l A. hematit . B. hematit nu. C. xierit. D. manhetit. Cu 33: Khi cho 3,36 lt CO2 (ktc) vo 200 ml dung dch cha NaOH 1M v Ba(OH) 2 0,5M. Khi lng kt ta thu c sau phn ng l A. 9,850 gam B. 19,700 gam C. 15,760 gam. D. 14,775 gam Cu 34: Trung ho 5,48 g hn hp gm axit axetic, phenol v axit benzoic cn dng 600ml dung dch NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp rn khan c khi lng l A. 8,64g B. 6,84g C. 6,8g D. 4,9g Cu 35: Xt v mt khng gian th khi cho buta-1,3-ien tc dng vi Br 2 theo t l mol 1 : 1 th s lng sn phm cng thu c l A. 1. B. 2. C. 3. D. 4. Cu 36: Trong n mn in ho, xy ra A. s oxi ho cc dng v s kh cc m B. s oxy ho cc dng C. s oxi ho cc m v s kh cc dng D. s kh cc m Cu 37: Phat biu ung l A. Kim loai xesi c dung ch tao t bao quang in B. Kim loai magie co kiu mang tinh th lp phng tm din C. Theo chiu tng dn cua in tich hat nhn, cac kim loai kim th (t beri n bari) co nhit nong chay giam dn D. Cac kim loai: natri, bari, beri u tac dung vi nc nhit thng Cu 38: Cho cc dung dch c cng nng : Na2CO3 (1), H2SO4 (2), HCl (3), KNO3 (4). Gi tr pH ca cc dung dch c sp xp theo chiu tng t tri sang phi l: A. (3), (2), (4), (1). B. (2), (3), (4), (1). C. (1), (2), (3), (4). D. (4), (1), (2), (3). Cu 39: Dung dch X cha a mol NaAlO2. Cho 100ml dung dch HCl 1M vo X, thu c b gam kt ta. Mt khc, nu cho 300 ml dung dch HCl 1M vo X th cng thu c b gam kt ta. Gi tr ca a l A. 0,15. B. 0,10. C. 0,20. D. 0,25. Cu 40: Cho cc cht sau : (1) CH3CH(NH2)COOH (2) HOOC- CH2-CH2-COOH (3) H2N[CH2]5COOH 4) CH3OH va C6H5OH (5) HO-CH2-CH2-OH v p-C6H4(COOH)2 (6) H2N[CH2]6NH2 v HOOC[CH2]4COOH. Cc trng hp c th tham gia phn ng trng ngng l A. (1), (3), (4) , (5), (6) B. (1), (3) , (5), (6) C. (1), (2), (3), (4), (5), (6) D. (1), (3), (6) 2+ 2+ Cu 41: Cho cc phn ng: Fe + Cu Fe + Cu (1) ; 2+ 3+ 2Fe + Cl2 2Fe + 2Cl (2); 3+ 2+ 2+ 2Fe + Cu 2Fe + Cu (3). Dy cc cht v ion xp theo chiu gim dn tnh oxi ho: A. Cl2 > Cu2+ > Fe2+ > Fe3+B. Fe3+ > Cl2 > Cu2+ > Fe2+
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Ti liu n thi i hc nm 2012 -2013 C. Cu2+ > Fe2+ > Cl2 > Fe3+ D. Cl2 > Fe3+ > Cu2+ > Fe2+ Cu 42: Cho cc dung dch NH3, NaOH, v Ba(OH)2 c cng nng mol vi gi tr pH tng ng l x, y, z. Quan h gia x, y v z l A. x > y > z. B. x = y = z. C. x > z > y. D. x < y < z. Cu 43: Phn chua c dng trong ngnh cng nghip thuc da, cng nghip giy, cht cm mu trong ngnh nhum vi, cht lm trong nc. Cng thc ha hc ca phn chua l A. Na2SO4.Al2(SO4)3.24H2O. B. (NH4)2SO4.Al2(SO4)3.24H2O. C. K2SO4.Al2(SO4)3.24H2O. D. Li2SO4.Al2(SO4)3.24H2O. Cu 44: phn bit tinh bt v xenlulozo c th dng A. dung dch Br2 B. dung dch Iot C. qu tm D. Na Cu 45: in phn mt dung dch mui nitrat ca mt kim loi M ha tr n vi in cc tr, cng dng in I = 9,65 A, thi gian in phn 400 giy th thy khi lng catot tng 4,32 gam. M l A. Cu B. Ag C. Fe D. Zn Cu 46: R l nguyn t m nguyn t c phn lp electron ngoi cng l np 2n+1 (n l s th t ca lp electron). C cc nhn xt sau v R: (I) Tng s ht mang in ca nguyn t R l 18. (II) S electron lp ngoi cng trong nguyn t R l 7. (III) Oxit cao nht to ra t R l R2O7. (IV) NaR tc dng vi dung dch AgNO3 to kt ta. S nhn xt ng l A. 3. B. 4. C. 2. D. 1. Cu 47: Hai hp cht hu c X v Y c cng cng thc phn t l C 3H7NO2, u l cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. X v Y ln lt l A. vinylamoni fomat v amoni acrylat. B. axit 2-aminopropionic v axit 3-aminopropionic. C. amoni acrylat v axit 2-aminopropionic. D. axit 2-aminopropionic v amoni acrylat. Cu 48: a mol Fe tc dng va ht vi dung dch cha b mol H 2SO4 c, nng, sau phn ng thu c kh SO 2 (duy nht) v dung dch cha 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4. Gi tr ca a v b tng ng l A. 0,12 v 0,40 B. 0,12 v 0,28 C. 0,12 v 0,30 D. 0,12 v 0,16 Cu 49: Nh t t 0,25 lt dung dch NaOH 1,04M vo dung dch gm 0,024 mol FeCl3; 0,016 mol Al2(SO4)3 v 0,04 mol H2SO4 thu c m gam kt ta. Gi tr ca m l A. 4,128. B. 2,568. C. 5,064. D. 1,560. Cu 50: bo v v tu bin bng thp, ngi ta gn cc tm Zn ngoi v tu (phn chm di nc bin). Ngi ta bo v v tu bng phng php A. in ha B. ha hc C. dng cht chng n mn l Zn D. cch li kim loi vi mi trng B S 12 Cu 1: Cho cc nhn nh sau: 1. Tnh cht ca cc hp cht hu c ch ph thuc vo cu to ho hc m khng ph thuc vo thnh phn phn t ca cc cht 2. Trong phn t hp cht hu c, cc phn t lin kt vi nhau theo ng ho tr. 3. Cc cht : CH2 =CH2 , CH2 =CH-CH3 , CH3 -CH=CH-CH3 thuc cng dy ng ng 4. Ancol etylic v axit focmic c khi lng phn t bng nhau nn l cc cht ng phn vi nhau 5. o- xilen v m-xilen l ng phn cu to khc nhau v mch cacbon Nhng nhn nh khng chnh xc l A. 1, 3, 5 B. 1, 2, 4, 5 C. 2, 3, 4 D. 1, 3, 4, 5 Cu 2: Cho a mol Fe vo dung dch cha b mol AgNO 3, phn ng xong, dung dch cn li cha Fe(NO 3)2 v Fe(NO3)3 th t s b/a l A. 1 < b/a < 2 B. b/a = 3 C. b/a 2 D. 2<b/a < 3 Cu 3: Ly 9,1 gam hp cht A c CTPT l C 3H9O2N tc dng vi dung dch NaOH d, un nng, c 2,24 lt ( ktc) kh B thot ra lm xanh giy qu tm m. t chy ht lng kh B ni trn, thu c 4,4 gam CO 2. CTCT ca A v B l:
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Ti liu n thi i hc nm 2012 -2013 A. CH3COONH3CH3; CH3NH2 B. HCOONH3C2H3 ; C2H3NH2 C. CH2=CHCOONH4 ; NH3 D. HCOONH3C2H5 ; C2H5NH2 Cu 4: Cho cng thc phn t ca ancol v amin ln lt l: C4H10O v C4H11N. C tng s bao nhiu ng phn ancol bc 1 v amin bc 2? A. 4 B. 3 C. 6 D. 5 Cu 5: Cho hn hp X (gm CH3OH, C2H4(OH)2, C3H5(OH)3) c khi lng m gam. t chy hon ton X thu c 5,6 lt kh CO2 ( kc). Cng m gam hn hp X trn cho tc dng vi kali thu c V lt kh (ktc). Ga tr ca V bng A. 11,2 B. 2,8 C. 3,36 D. 5,6 Cu 6: Pht biu no sau y l ng ? A. T nilon-6,6 l mt loi t poliamit B. Trng hp isopren to ra sn phm thuc cht do C. T axetat l t tng hp D. Phn ng gia buta-1,3-ien vi acrilonitrin l phn ng trng ngng Cu 7: Dung dch X gm 0,1 mol H+, z mol Al3+, t mol NO3- v 0,02 mol SO42-. Cho 120 ml dung dch Y gm KOH 1,2M v Ba(OH)2 0,1M vo X, sau khi cc phn ng kt thc, thu c 3,732 gam kt ta. Gi tr ca z, t ln lt l : A. 0,120 v 0,020 B. 0,012 v 0,096 C. 0,020 v 0,120 D. 0,020 v 0,012 Cu 8: Cho cht hu c A ch cha mt loi nhm chc tc dng vi 1 lt dung dch NaOH 0,5M thu c 24,6 gam mui v 0,1 mol ancol. Lng NaOH d c th trung ha ht bng 0,5 lit dung dch HCl 0,4M. Cng thc cu to thu gn ca A l A. CH3COOC2H5 B. C3H5(OCOCH3)3 C. (CH3COO)2C2H4 D. (HCOO)3C3H5 Cu 9: Ln men m gam glucoz vi hiu sut 90%, lng kh CO 2 sinh ra hp th ht vo dung dch nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi khi lng dung dch nc vi trong ban u. Gi tr ca m l: A. 13,5 B. 15,0 C. 20,0 D. 30,0 Cu 10: Cho cc cp dung dch sau: (1) Na2CO3 v AlCl3; (2) NaNO3 v FeCl2; (3) HCl v Fe(NO3)2; (4) NaHCO3 v BaCl2; (5) NaHCO3 v NaHSO4. Hy cho bit cp no xy ra phn ng khi trn cc cht trong cc cp vi nhau? A. (1), (3), (4) B. (1), (4), (5) C. (1), (3), (5) D. (3), (2), (5) Cu 11: Cho 14,2 gam P2O5 v 100 ml dung dch cha NaOH 1M v KOH 2M thu c dung dch X. Cc anion c mt trong dung dch X l: A. PO43- v OHB. H2PO4- v PO43C. H2PO4- v HPO42 D. HPO42- v PO43Cu 12: Tng s ng phn c tnh cht lng tnh ng vi cng thc phn t C2H7O2N l A. 2 B. 1 C. 4 D. 3 Cu 13: Cho 48,6 gam Al vo 450 ml dung dch gm KNO3 1M, KOH 3M sau phn ng hon ton thy thot ra kh H2 v NH3 . Th tch kh thot ra ktc l A. 10,08 lit B. 40,32 lit C. 45,34 lit D. 30,24 lit Cu 14: Cho cc phn ng sau: t0 t0 t0 kh X; NH4NO3+ NaOH kh Z KMnO4 kh Y; kh X + kh Y Cc kh X, Y, Z ln lt l: A. O2, NH3, NO B. O2, NH3, N2 C. Cl2, NH3, HCl D. O2, N2, NO Cu 15: Trong bng tun han cc nguyn t ha hc, nguyn t X nhm IIA, nguyn t Y nhm VA. Cng thc ca hp cht to thnh 2 nguyn t trn c dng l A. X5Y2 B. X2Y5 C. X3Y2 D. X2Y3 Cu 16: Tin hnh cc th nghim sau: (1) Sc kh H2S vo dung dch FeSO4 (2) Sc kh H2S vo dung dch CuSO4 (3) Sc kh CO2 (d) vo dung dch Na2SiO3 (4) Sc kh CO2 (d) vo dung dch Ca(OH)2 (5) Nh t t dung dch NH3 n d vo dung dch Al2(SO4)3 (6) Nh t t dung dch Ba(OH)2 n d vo dung dch Al2(SO4)3 Sau khi cc phn ng xy ra hon ton, s th nghim thu c kt ta l A. 6 B. 3 C. 4 D. 5
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Ti liu n thi i hc nm 2012 -2013 Cu 17: Cho 8,4 gam Fe tc dng va vi dung dch cha 0,4 mol H 2SO4 c, nng (gi thit SO2 l sn phm kh duy nht). Sau khi phn ng xy ra hon ton c cn dung dch c m gam mui khan. Gi tr ca m l: A. 35,2 B.27,6 C. 30,0 D. 22,8 Cu 18: Cho 8,04 gam hn hp hi gm CH3CHO v C2H2 tc dng hon ton vi dung dch AgNO3/NH3 thu c 55,2 gam kt ta. Cho kt ta ny vo dung dch HCl d, sau khi kt thc phn ng cn li m gam cht khng tan. Gi tr ca m l A. 21,6 gam B. 61,78 gam C. 55,2 gam D. 41,69 gam Cu 19: 1 mol X c th phn ng ti a 2 mol NaOH. X c th l: (1) CH3COOC6H5 (2) ClH3NCH2COONH4 (3) ClCH2CH2Br (4) HOC6H4CH2OH (5) H2NCH2COOCH3 (6) ClCH2COOCH2Cl C bao nhiu cht X tho mn: A. 2 B. 4 C. 5 D.3 Cu 20: Dy gm cc cht d b nhit phn l: A. Cu(OH)2, Mg(NO3)2, KHCO3, BaSO4 B. Cu(NO3)2, NH4Cl, Mg(HCO3)2, Na2CO3 C. CaCO3, Pb(NO3)2, (NH4)2CO3, K2CO3 D. NH4 HCO3, KNO3, NH4NO2, AgNO3 Cu 21: Chia 0,30 mol hn X gm C2H6, C2H4, C2H2 thnh hai phn bng nhau. t chy hon ton phn 1 thu c 5,40 gam H2O. Cho phn 2 li qua dung dch brom (d) thy khi lng bnh nc brom tng 2,70 gam. Phn trm khi lng ca C2H6 c trong hn hp X l A. 34,05% B. 35,71% C. 33,33% D. 71,42% Cu 22: Cho 29,8 gam hn hp 2 amin n chc k tip tc dng ht vi dung dch HCl, lm kh dung dch thu c 51,7 gam mui khan. Cng thc phn t 2 amin l A. C2H7N v C3H9N B. CH5N v C2H7N C. C3H9N v C4H11N D. C3H7N v C4H9N Cu 23: Hai hp cht hu c X, Y c cng cng thc phn t C 3H6O2. C X v Y u tc dng vi Na; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to ca X v Y ln lt l A. HCOOC2H5v HOCH2CH2CHO. B. HCOOC2H5 v HOCH2COCH3. C. C2H5COOH v HCOOC2H5. D. C2H5COOH v CH3CH(OH)CHO Cu 24: Cho 13,6 gam mt cht hu c X (C, H, O) tc dng va vi 300 ml dung dch AgNO 3/NH3 2M thu c 43,2 gam kt ta. Bit t khi ca X so vi oxi l 2,125. X l A. anehit n chc, mt ni ba u mch. B. anehit no, 2 chc. C. anehit n chc, mt ni ba gia mch. D. anehit n chc, 1 ni i. Cu 25: C ba dung dch: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol etylic, benzen, anilin ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l dung dch HCl th nhn bit c ti a bao nhiu ng nghim? A. 5. B. 4. C. 6 D. 3. Cu 26: Cho 3,84 gam Mg tc dng vi dung dch HNO3 lang, d thu c 1,344 lt NO (ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi dung dch X l: A. 25,38 gam. B. 23,68 gam. C. 24,68 gam. D. 25,08 gam. Cu 27: Dy gm cc cht u c kh nng tham gia phn ng trng hp l: A. buta-1,3-ien; cumen; etilen; trans-but-2-en. B. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. C. stiren; clobenzen; isopren; but-1-en. D. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua. Cu 28: Cho V lit hn hp kh A gm clo v oxi tc dng va ht vi hn hp B gm 0,2 mol Al v 0,1 mol Mg th thu c 25,2 gam hn hp mui clorua v oxit ca 2 kim loi. S mol ca Cl 2 c trong V lit hn hp kh A l A. 0,20 B. 0,25. C. 0,30. D. 0,15. Cu 29: Ba nguyn t c cc electron trn cc lp electron ln lt l: X (2, 8, 5); Y (2, 8, 6); Z (2, 8, 7). Dy no c xp theo th t gim dn tnh axit? A. H3XO4>H2YO4>HZO4 B. HZO4 > H2YO4>H3XO4 C. H2YO4>HZO4>H3XO4 D. H2ZO4>H2YO4>HXO4
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Ti liu n thi i hc nm 2012 -2013 Cu 30: Th tch dung dch Ba(OH)2 0,025M cn cho vo 100ml dung dch hn hp gm HNO3 v HCl c pH = 1, thu c dung dch c pH =2 l A. 0,336 lit. B. 0,224 lit. C. 0,448 lit. D. 0,15 lit. Cu 31: Cho cc pht biu sau 1, Phn ng thun nghch l phn ng xy ra theo 2 chiu ngc nhau. 2, Cht xc tc lm tng tc phn ng thun v nghch. 3, Ti thi im cn bng trong h vn lun c mt cc cht phn ng v cc sn phm. 4, Khi phn ng t trng thi cn bng ho hc, nng cc cht vn c s thay i. 5, Khi phn ng t trng thi cn thun nghch bng ho hc, phn ng dng li. Cc pht biu sai l A. 3,4. B. 2,3. C. 4,5 D. 3,5. Cu 32: Ha tan ht 3,84 gam Cu trong 100 ml dung dch hn hp gm HNO 3 0,60M v H2SO4 0,50M. Sau phn ng thu c kh NO duy nht v dung dch X. Khi lng mui khan thu c khi c cn dung dch X l? A. 9,88 gam. B. 10,00 gam. C. 1,88 gam. D. 8,00 gam. Cu 33: Cch nhn bit no khng chnh xc: A. nhn bit O2 v O3 ta dng dung dch KI c ln tinh bt. B. nhn bit NH3 v CH3NH2ta dng axit HCl c C. nhn bit CO v CO2 ta dng nc vi trong. D. nhn bit SO2 v SO3 ta dng dung dch nc brom. Cu 34: Ly 14,6 gam mt i peptit to ra t glixin v alanin tc dng vi dung dch HCl 1M. Th tch dung dch HCl tham gia phn ng l A. 1 lit. B. 0,1 lit. C. 0,2 lit. D. 0,15 lit. Cu 35: Cho cc phn ng sau: a) FeO + HNO3 (c, nng) b) FeS + H2SO4 (c, nng) c) Al2O3 + HNO3 (c, nng) d) AgNO3 + dung dch Fe(NO3)2 0 t , Ni e) HCHO + H2 f) Cl2 + Ca(OH)2 g) C2H4 + Br2 h) glixerol + Cu(OH)2 Dy gm cc phn ng u thuc loi phn ng oxi ha - kh l A. a, b, d, e, g, h. B. a, b, c, d, e, g. C. a, b, d, e, f, g. D. a, b, c, d, e, h. Cu 36: Cho phn ng oxi ha kh sau: Al + HNO 3 Al(NO3)3 + N2 + N2O + H2O. Vi t l mol gia N2 v N2O = 2:3. H s cn bng ti gin ca HNO3 l A. 24. B. 22. C. 142. D. 162 Cu 37: Cho hn hp gm 0,4 mol Fe v 0,2 mol Zn vo 200 ml dung dch hn hp gm Cu(NO 3)2 1M v AgNO3 3 M. Khi lng dung dch gim l A. 47,8 gam. B. 21,1 gam. C. 53,4 gam. D. 42,2 gam. Cu 38: Oxi ha 3,16 gam hn hp 2 ancol n chc thnh anehit bng CuO, t 0. Sau phn ng thy khi lng cht rn gim 1,44 gam. Cho ton b lng anehit trn tc dng vi lng d dung dch AgNO 3/NH3 thu c 36,72 gam Ag. Hai ancol l A. CH3OH v C2H5CH2OH. B. C2H5OH v C2H5CH2OH. C. CH3OH v C2H5OH. D. C2H5OH v C3H7CH2OH. Cu 39: Hn hp X cha: NaHCO3, NH4NO3 v CaO (cc cht c cng s mol). Ha tan hn hp X vo H 2O (d), un nng. Sau phn ng kt thc, lc b kt ta, thu c dung dch Y. Dung dch Y c mi trng A. lng tnh. B. Trung tnh. C. Axit. D. Baz. Cu 40: Cho hn hp gm 6,96 gam Fe3O4 v 6,40 gam Cu vo 300 ml dung dch HNO3 CM (mol/l). Sau khi cc phn ng kt thc thu c dung dch X v cn li 1,60 gam Cu. Gi tr CM l A. 0,15. B. 1,20. C. 1,50. D. 0,12. Cu 41: Cho dy cc cht: phenylamoni clorua, benzyl clorua, isopropyl clorua, m-crezol, ancol benzylic, natri phenolat, anlyl clorua. S cht trong dy tc dng c vi dung dch NaOH lang, un nng l A. 4. B. 6. C. 5. D. 3. Cu 42: Cho cc pht biu sau: (a) Anehit va c tnh oxi ha va c tnh kh
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Ti liu n thi i hc nm 2012 -2013 (b) Phenol tham gia phn ng th brom kh hn benzen (c) Anehit tc dng vi H2 (d) c xc tc Ni un nng, thu c ancol bc mt (d) Dung dch axit axetic tc dng c vi Cu(OH)2 (e) Dung dch phenol trong nc lm qu tm ha (f) Trong cng nghip, axeton c sn xut t cumen S pht biu ng l: A.4 . B. 2. C. 5. D. 3. Cu 43: Dung dch A long cha 0,04 mol; Fe(NO 3 ) 3 v 0,6 mol HCl c kh nng ho tan c Cu vi khi lng ti a l A. 12,16 gam. B. 6,4 gam. D. 11,52 gam. C. 12,8gam. Cu 44: t chy hon ton 29,6 gam hn hp X gm CH3COOH ,CxHyCOOH v (COOH)2 thu c 0,8 mol H2O v m gam CO2. Cng cho 29,6 gam X tc dng vi lng d NaHCO 3 thu c 0,5 mol CO2. Gi tr ca m l A. 11. B. 33. C. 22. D.44 Cu 45: Cho cc cht tham gia phn ng: a, S+ F2 b, SO2 + H2S c, SO2 + O2 d, S+H2SO4(c nng) e, H2S + Cl2 (d ) + H2O f, SO2 + Br2 + H2O Khi cc iu kin c s phn ng to ra sn phm m lu hynh mc s oxi ho + 6 l A. 4 B. 5. C. 3. D. 2. Cu 46: t chy hon ton 0,11 gam mt este X (to nn t mt axit cacboxylic n chc v mt ancol n chc) thu c 0,22 gam CO2 v 0,09 gam H2O. S ng phn este ca X l A. 5 B. 6 C.4 D. 2 Cu 47: Cho 0,1 mol -aminoaxit X tc dng vi 50 ml dd HCl 1 M thu c dung dch A. Dung dch A tc dng vi 250 ml dd NaOH 1 M thu c dung dch B. C cn dung dch B cn li 20,625 gam cht rn khan. Cong thc ca X l: A. HOOCCH2CH2CH(NH2)COOH. B. NH2CH2COOH. C. CH3CH(NH2)COOH. D. HOOCCH2CH(NH2)2 Cu 48: Pht biu no sau y khng ng? A. Trong cc hp cht, ngoi s oxi ha-1, flo v clo cn c s oxi ha+1,+3,+5,+7 B. mui AgI khng tan trong nc, mui AgF tan trong nc C. Flo c tnh oxi ho mnh hn clo D. dung dch HF ho tan c SiO2 Cu 49: nh hng ca nhm amino n gc phenyl trong phn t anilin c th hin qua phn ng gia anilin vi A. dung dch Br2 v dung dch HCl B. dung dch HCl C. Dung dch Br2 D. dung dch NaOH Cu 50: Nung nng hn hp X gm 0,1 mol vinyl axetilen v 0,3 mol H 2 vi xc tc Ni thu c hn hp Y c t khi hi so vi khng kh l 1. Hn hp Y lm mt mu ti a m gam brom trong CCl4. Gi tr ca m l A. 32.0 B. 8.0 C. 16,0 D. 3,2. B S 13 Cu 1. Trong s cc cht: toluen, nitrobenzen, anilin, phenol, axit benzoic, benzanehit, naphtalen, p-xilen, cumen, p-crezol,s cht tham gia phn ng th nhn thm d hn so vi benzen l A. 7 B. 6 C. 9 D. 8 Cu 2. Khi tc dng vi cht no sau y anehit th hin tnh oxi ha: A. ddAgNO3/NH3(t0) B. O2 C. Dd Brom D. H2(t0,Ni) Cu 3. Cho 38,775 gam hn hp bt Al v AlCl3 vo lng va dung dch NaOH thu c dung dch A (kt ta va tan ht) v 6,72 lt H 2 (ktc). Thm 250ml dung dch HCl vo dung dch A thu c 21,84 gam kt ta. Nng M ca dung dch HCl l : A. 1,12M hoc 2,48M B. 2,24M hoc 2,48M C. 2,24M hoc 3,84M D. 1,12M hoc 3,84M
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Ti liu n thi i hc nm 2012 -2013 Cu 4. Trong cc hirocacbon sau: propen, but-1-en, but-2-en, penta-1,4- ien, penta-1,3- ien hirocacbon cho c hin tng ng phn cis - trans ? A. but-2-en, penta-1,3- ien. B. propen, but-2-en C. penta-1,4-dien, but-1-en D. propen, but-1-en Cu 5. t chy hon ton 17,4(g) axit A mch h thu c 13,44(l) CO2(ktc) v 5,4(g) nc . Nu trung ho 23,2(g) axit trn th cn V(ml) dung dch hn hp NaOH 1M,KOH 1,5M. Gi tr V l A. 120 B. 160 C. 300 D. 350 Cu 6. Mt hn hp kh X gm N 2 v H2 c dX/H2= 2,3 cho vo bnh kn dung tch khng i 8(l) v c cht xc tc thch hp. Gi bnh nhit khng i, khi phn ng t trng thi cn bng th p sut bng 118/125 p sut ban u . Hiu sut phn ng l : A. 20% B. 56% C. 28% D. 46% Cu 7. Cht no khng lm qu tm i mu : A. axit glutamic B. CH3NH3NO3 C. H2NCH2COONa D. C6H5NH3Cl Cu 8. Kh no gy ra hiu ng nh knh lm cho nhit tri t nng ln : A. CO2 B. SO2 C. O3 D. N2 Cu 9. in phn 200ml dung dch hn hp Cu(NO3)2 xM, KCl yM ( in cc tr, mng ngn) n khi nc bt u in phn c 2 in cc th dng li. Dung dch sau in phn c khi lng gim 22,04(g) so vi dung dch ban u v dung dch ny ha tan ti a 7,92(g) Zn(OH) 2. Bit thi gian in phn l 19300 giy. Gi tr ca x, y, cng dng in l: A. 0,5M; 1,2M; 2,5A B. 1M; 1,5M; 1A C. 0,6M; 2M; 2A D. 1M;2M; 2A Cu 10. Khi lng kt ta to thnh khi trn ln dung dch cha 0,0075 mol NaHCO3 vi dung dch cha 0,005 mol Ba(OH)2 l: A. 1,4775(g) B. 0,73875 C. 0,78(g) D. 0,985gam Cu 11. Cho cc cht sau y : Cl2, Na2CO3, CO2, HF, NaHCO3, H2SO4 long, NaCl, Ba(HCO3)2, NaHSO4, NH4Cl, MgCO3, SO2. Dung dch Ca(OH)2 tc dng c vi bao nhiu cht ? A. 12 B. 11 C. 10 D. 9 Cu 12. Hp th 0,07 mol CO2 vo 250ml dung dch NaOH0,32M thu c dung dch G. Thm 250ml dung dch gm BaCl20,16M, Ba(OH)2 xM vo dung dch G thu c 7,88(g) kt ta. Gi tr ca x l : A. 0,02 B. 0,03 C. 0,04 D. 0,06 Cu 13. Trong cc cng thc sau y, cng thc no ca cht bo : A. C3H5(OCOC17H33)3 B. C3H5(OCOC4H9)3 C. (C3H5 OOC)3C15H31 D. C3H5(COOC17H35)3 Cu 14. Trong s cc cht: phenylamoni clorua, natri phenolat, vinyl clorua, anlyl clorua, benzyl clorua, phenyl clorua, phenyl benzoat, t nilon-6, propyl clorua, ancol benzylic, alanin, tripeptit Gly-Gly-Val, mcrezol, s cht phn ng c vi dung dch NaOH long, un nng l: A. 8 B. 9 C. 10 D. 7 Cu 15. Cho cc th nghim: 1, Sc kh sunfur vo dung dch axit sunfuhiric 2, Sc kh Clo vo dung dch kaliiotua 3, Sc kh cacbonic vo dung dch mui cloruavi 4, Sc kh amoniac vo dung dch st(III) sunfat 5, Thi kh CO2 vo dung dch Natrisilicat 6, Cho photpho vo dung dch HNO3 c (d), un nng 7, Sc kh ozon vo dung dch KI S th nghim to ra kt ta l: A. 4 B. 7 C. 5 D. 6 Cu 16. Cho 0,3 mol hn hp X gm CH 3CHO, CH2=CH-COOH, CHC-COOH phn ng ht vi dung dch AgNO3 trong NH3 d thu c 41(g) hn hp kt ta. Mt khc , cho 0,3 mol hn hp X tc dng dung dch NaHCO3 d to 4,48(l) kh CO2(ktc). Khi lng axit CHC-COOH trong hn hp X l : A. 10,5g B. 7g C. 14g D. 3,5g Cu 17. Trung ha 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn dng 600 ml dung dch NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp cht rn khan c khi lng l A. 6,84 gam B. 6,8 gam C. 8,64 gam D. 4,9 gam Cu 18. Ha tan ht m gam hn hp gm Na v Ba vo nc thu c 300 ml dung dch X c pH = 13. Trung ha dung dch X bng dung dch HCl ri c cn th thu c 2,665 gam mui khan. Gi tr ca m l A. 1,6 B. 1,45 C. 2,1 D. 1,92
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Ti liu n thi i hc nm 2012 -2013 Cu 19. Cho a(g) hn hp X gm hai -aminoaxit no, h cha mt nhm amino, mt nhm cacboxyl tc dng 40,15(g) dung dch HCl 20% thu c dung dch A. tc dng ht cc cht trong dung dch A cn 140ml dung dch KOH 3M. t chy hon ton a(g) hn hp X thu c sn phm chy gm CO2, H2O, N2 c dn qua bnh ng dung dch Ca(OH)2d thy khi lng bnh tng 32,8(g). Bit t l khi lng phn t ca chng l 1,56. Aminoaxit c phn t khi ln l : A. valin B. tyrosin C. lysin D. alanin Cu 20. Buta-1,3-ien cha bao nhiu lin kt : A. 9 B. 1 C. 7 D. 6 Cu 21. t chy hon ton 7,2 gam kim loi M (c ho tr hai khng i trong hp cht) trong hn hp kh Cl2 v O2. Sau phn ng thu c 23,0 gam cht rn v th tch hn hp kh phn ng l 5,6 lt ( ktc). Kim loi M l A. Ca. B. Mg. C. Be. D. Cu. Cu 22: Hn hp X gm bn hp cht hu c u c cng thc phn t l C 3H9NO2. Cho hn hp X phn ng vi dung dch KOH va th thu c 1344 ml (ktc) hn hp kh Y mi khai c t khi hi so vi hiro l 17,25 v dung dch Z. C cn dung dch Z thu c m gam cht rn khan. Gi tr ca m l A. 5,67 B. 4,17 C. 5,76 D. 4,71 Cu 23. Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na 2O v Al2O3, Kv Zn, BaCl2 v CuSO4, Ba v NaHCO3. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l: A. 3 B. 2 C. 1 D. 4 Cu 24. un 1 mol hn hp C2H5OH v C4H9OH (t l mol tng ng l 3:2) vi H 2SO4 c 140oC thu c m gam ete, bit hiu sut phn ng ca C2H5OH l 60% v ca C4H9OH l 40% . Gi tr ca m l A. 53,76 B. 19,04 C. 28,4 D. 23,72 Cu 25. Dy gm cc polime trng ngng : A. polienantoamit, t tm, t axetat B. nha novolac, policaproamit , t lapsan C. t nilon-6,6 ; t nitron, t nilon-7 D. Caosubuna-S, t nitron, t nilon-6 Cu 26. Cho imetylamin ln lt tc dng vi cc dung dch : HCl, NH3, C6H5NH3Cl, NH4Cl, NaOH,CH3COOH, H2O,Br2 , FeCl3. S cht phn ng xy ra l: A. 6 B. 8 C. 4 D. 5 Cu 27. Mt este mch h c ti a 3 chc este. Cho este ny tc dng dung dch NaOH d thu c mui v 1,22(g) hn hp 2 ru c th tch hi bng th tch ca 1,32(g) kh CO 2 ( o cng iu kin nhit v p sut). Tn ca ru c khi lng phn t ln hn l: A. ancol anlylic B. ancol etylic C. etilenglicol D. ancol propylic Cu 28. Dung dch X cha cc ion: Ca2+, Na+, HCO3- v Cl-, trong s mol ca ion Cl- l 0,1. Cho 1/2 dung dch X phn ng vi dung dch NaOH (d), thu c 2 gam kt ta. Cho 1/2 dung dch X cn li phn ng vi dung dch Ca(OH)2 (d), thu c 3 gam kt ta. Mt khc, nu un si n cn dung dch X th thu c m gam cht rn khan. Gi tr ca m l A. 7,47 B. 9,26 C. 9,21 D. 8,79 Cu 29. Cho s : + ddNaOHc, d Benzen pheynylclorua X 0 t , xt, p dung dch ca X khng tc dng vi : A. HCl B. CO2 C. NaOH D. CH3COOH Cu 30. Thu phn hon ton 34,2 gam saccaroz. Ly ton b sn phm X ca phn ng thu phn cho tc dng vi lng d AgNO3/NH3 thu c a gam kt ta. Cn nu cho ton b sn phm X tc dng vi dung dch nc brom d th c b gam brom phn ng.Gi tr ca a, b ln lt l : A. 21,6 v 16 B. 43,2 v 32 C. 21,6 v 32 D. 43,2 v 16 Cu 31. Hn hp X gm Zn, Fe, Cu. Cho 18,5 gam hn hp X tc dng vi dung dch HCl d thu c 4,48 lit H2(ktc). Mt khc cho 0,15 mol hn hp X phn ng va vi 3,92 lt kh Cl 2 (ktc). % khi lng Fe c trong 18,5 gam hn hp X l : A. 30,27% B. 24,22% C. 45,46% D. 36,32% Cu 32. Tin hnh bn th nghim sau : - Th nghim 1 : Nhng thanh Fe vo dung dch FeCl3;
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Ti liu n thi i hc nm 2012 -2013 - Th nghim 2 : Nhng thanh Fe vo dung dch CuSO4; - Th nghim 3 : Nhng thanh Cu vo dung dch FeCl3 ; - Th nghim 4 : Cho thanh Fe tip xc vi thanh Cu ri nhng vo dung dch HCl - Th nghim 5 : Th mu Bari vo dung dch ZnSO4 S trng hp xut hin n mn in ho l A. 2 B. 3 C. 3 D. 2 Cu 33. Cho 4,5(g) axit oxalic tc dng va ancol etylic ( xc tc: H2SO4 c, un nng; hiu sut phn ng l 100%) thu c hn hp 2 este v 1,62(g) H 2O. Cho hn hp sau phn ng este ha tc dng vi Na d thu c V(l) kh H2(ktc): A. 0,56 B. 1,12 C. 2,24 D. 1,008 Cu 34. Cht no khng ha tan Cu(OH)2 ngay nhit thng to dung dch mu xanh: A. Saccarozo B. axit axetic C. xenlulozo D. glucozo 2+ Cu 35. Trong ion R , lp M cha 14 electron . V tr R trong bng tun hon l: A. chu k 4, nhm VIIIB B. chu k 4, nhm IIB C. chu k 5, nhm IIA D. chu k 4, nhm VIB Cu 36. Pht biu no sau y sai: A. Bc c ng dng ch to thit b ngn cn tia phng x B. Vng dn in tt hn ng C. Trong y hc , ZnO c dng lm thuc gim au thn kinh, cha bnh nga D. Thic c th dng ph ln b mt st chng g Cu 37. Trong cc cht: Cl2, HCl, Cu(NO3)2 , FeCl2 , FeCl3 , Fe(NO3)3 , Fe(NO3)2 , FeSO4 , Fe2(SO4)3 . S cht c c tnh oxi ho v tnh kh l : A. 6 B. 9 C. 8 D. 7 Cu 38. Cho cc hp cht hu c:(1) ankan; (2) ancol no, n chc, mch h (3) xicloankan n vng; (4) ete no, n chc, mch h (5) ancol khng no (c mt lin kt i C=C),mch h (6) anken (7) ankin (8) anehit v este no, n chc, mch h (9) axit khng no (c mt lin kt i C=C), n chc. (10) axit no, n chc, mch h; Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l: A. (3), (4), (6), (7), (10) B. (3), (5), (6), (8), (10) C. (2), (3), (5), (7), (9) D. (1), (3), (5), (6), (8) Cu 39. Cho 11,6 gam FeCO3 tc dng va vi dung dch HNO3 thu c hn hp kh (CO2, NO) v dung dch X. Khi thm dung dch HCl d vo dung dch X th ho tan ti a c bao nhiu gam bt Cu (bit c kh NO bay ra) A. 16g B. 28,8g C. 32g D. 48g Cu 40. Nhm hn hp cht no tan vo nc to ra dung dch lm qu tm ha xanh: A. Hn hp gm 0,1 mol Cu; 0,3(mol) FeCl3 B. Hn hp gm 0,2 mol NaHSO4 ; 0,2 mol NaOH C. Hn hp gm 0,1 mol Na; 0,2(mol) NaCl; 0,1 (mol) NH4NO3 ( khi cho vo nc un nng nh) D. Hn hp gm 0,1 mol Ba(OH)2; 0,2(mol) Al(OH)3; 0,15 (mol) Ba(NO3)2 Cu 41. Trong cc th nghim sau: (1) Cho F2 vo H2O. (2) Cho kh O2 tc dng vi dd H2S thy dung dch b vn c (3) Cho kh NH3 tc dng vi CuO un nng. (4) Cho K2CrO4 tc dng vi HCl c. (5) Cho Si n cht tc dng vi dung dch NaOH. (6) Cho kh O3 tc dng vi Ag. (7) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 ung nng. (8) Cho ddHI vo dung dch FeCl3 S th nghim to ra n cht l: A. 7 B. 8 C. 5 D. 4

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Ti liu n thi i hc nm 2012 -2013 Cu 42. Hn hp X gm C2H5OH, HCOOH, CH3CHO (C2H5OH chim 50% s mol). t chy hon ton m gam X thu c 3,24 gam nc v 3,136 lt CO2 (ktc). Cho m gam X tc dng vi lng d AgNO3 trong dung dch NH3 thu c s gam Ag do axitfomic to ra l : A. 2,16 B. 8,64 C. 4,32 D. 1,62 Cu 43. Cho a gam bt Al vo dung dch cha 0,3 mol AgNO 3 ; 0,15 mol Cu(NO3)2 v 0,2 mol Fe(NO3)3 thu c dung dch X v 46,2 (g)hn hp cht rn Y. Gi tr ca a l : A. 3,6 gam < a 9 gam B. 8,55 C. 8,83 D. 5,4 gam < a 9 gam Cu 44. Cho m gam Fe vo dung dch cha ng thi H 2SO4 v HNO3 thu c dung dch X v 4,48 lt NO(duy nht). Thm tip H2SO4 vo X th li thu c thm 1,792 lt kh NO duy nht na v dung dch Y. Dung dch Y ho tan va ht 8,32 gam Cu khng c kh bay ra (cc kh o ktc). Khi lng ca Fe cho vo l: A. 16,8 B. 11,2 C. 16,24 D. 9,6 Cu 45. Cho Bari vo nc c dung dch A. Cho lng d dung dch Na 2CO3 v dung dch A ri dn tip lung kh CO2 vo n d. Hin tng no ng trong s cc hin tng sau ? A. Bari tan, si bt kh hiro, ng thi xut hin kt ta trng. B. Bari tan, si bt kh hiro, xut hin kt ta trng, ri tan C. Si bt kh, xut hin kt ta trng ri tan. D. Bari tan, xut hin kt ta trng, ri tan. Cu 46. t chy hon ton m gam hn hp gm anehitfomic,axit propionic, etyl axetat, glucozo, ancol anlylic v isobutilen, ri hp th ton b sn phm chy vo dung dch 200ml Ca(OH) 2 1M. Sau phn ng thu c 15 gam kt ta v dung dch X. Khi lng X so vi khi lng dung dch Ca(OH) 2 ban u thay i nh th no? A. Tng 7,92 gam B. Gim 7,38 gam C. Tng 0,5gam D. Gim 7,74 gam Cu 47. Hp th ht 4,48(l) buta-1,3-ien(ktc) vo 250ml ddBrom1M, iu kin thch hp n khi brom mt mu hon ton thu c hn hp lng X( ch cha dn xut brom) , trong khi lng sn phm cng 1,4 gp 4 ln khi lng sn phm cng 1,2. Khi lng sn phm cng 1,2 trong X l A. 16,05g B. 12,84g C. 1,605g D. 6,42g Cu 48. T 100 lt dung dch ru etylic 400 ( d = 0,8 g/ml) c th iu ch c bao nhiu kg cao su buna ( Bit Hiu sut phn ng c qu trnh l 75% ) ? A. 14,087 kg B. 15,06 kg C. 18,783 kg D. 28,174 kg Cu 49. Cho cc cn bng sau: (II) CaCO3 (r) CaO (r) + CO2 (k); (I) 2HI (k) H2 (k) + I2 (k) (III) FeO (r) + CO (k) Fe (r) + CO2 (k) (IV) 2SO2 (k) + O2 (k) 2SO3 (k). Khi gim p sut ca h, s cn bng b chuyn dch theo chiu nghch A. 1 B. 4 C. 2 D. 3 Cu 50. S m t no sau y khng ng hin tng ha hc: A. Cho anilin t t vo dung dch HCl d thy anilin tan dn to dung dch ng nht B. Sc kh etilen vo dung dch brom thy dung dch brom b mt mu v thu c mt dung dch ng nht C. Cho dung dch axit axetic vo dung dch natriphenolat thy dung dch b vn c D. Nhng giy qu tm vo dung dch propylamin thy giy qu tm ha xanh

B S 14 Cu 1: Cho m gam hn hp Cu, Fe, Zn tc dng vi dung dch HNO 3 long, d thu c dung dch Z (gi thit NO l sn phm kh duy nht). C cn dung dch Z thu c (m + 62) gam mui khan. Nung hn hp mui khan trn n khi lng khng i thu c cht rn c khi lng l A. (m + 8) gam. B. (m + 31) gam. C. (m + 16) gam. D. (m + 4) gam. n+ 2 2 6 Cu 2: Ion X c cu hnh electron l 1s 2s 2p , X l nguyn t thuc nhm A trong bng tun hon cc nguyn t ho hc. S nguyn t ha hc tha mn vi iu kin ca X l A. 2. B. 3. C. 4. D. 5. + O2 + NaOH + NaOH Cu 3: Cht X c cng thc phn t CxHyOz. Cho X tc dng vi NaOH thu c Y v Z. Bit Z khng tc o dng c xt, vitNa v c s chuyn ha CaO, sau: to
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Ti liu n thi i hc nm 2012 -2013 Z T Y ankan n gin nht. Thnh phn phn trm theo khi lng ca cacbon trong X l A. 40,00%. B. 55,81%. C. 48,65%. D. 54,55%. Cu 4: Ho tan m gam Al trong dung dch HNO 3 long (d), thu c dung dch X v 1,344 lt hn hp Y ( ktc) gm N2 v N2O. T khi ca Y so vi hiro l 18. Cho dung dch X tc dng vi dung dch NaOH d thu c 0,672 lt kh ( ktc) lm xanh qu tm m. Gi tr ca m l A. 4,86. B. 6,75. C. 8,10. D. 7,02. Cu 5: X phng ha hon ton cht bo X trong NaOH (d) un nng thu c 9,2 gam glixerol v 91,2 gam mt mui natri ca axit bo. Tn ca X l A. tristearin. B. triolein. C. tripanmitin. D. trilinolein. Cu 6: Cho 16,4 gam hn hp cc kim loi Cr, Fe tc dng vi lng d dung dch H 2SO4 long nng (trong iu kin khng c khng kh), thu c dung dch X v 6,72 lt kh H 2 ( ktc). Cho dung dch X tc dng vi dung dch NaOH (trong iu kin c khng kh) c m gam kt ta. Gi tr ln nht ca m l A. 31,7. B. 19,3. C. 21,0. D. 17,6. Cu 7: Cho Fe3O4 vo dung dch H2SO4 long d thu c dung dch X. Hy cho bit trong cc ha cht sau: KMnO4, Cl2, NaOH, CuSO4, Cu, KNO3, KI, dung dch X tc dng c vi bao nhiu cht ? A. 4. B. 5. C. 7. D. 6. Cu 8: Oxi ho hon ton 11,2 lt SO2 (ktc) bng khng kh (d) nhit cao, c cht xc tc. Ho tan ton b sn phm vo 210 gam dung dch H2SO4 10% thu c dung dch X. Cc phn ng xy ra hon ton. Nng phn trm khi lng ca dung dch X l A. 16%. B. 24%. C. 28%. D. 32%. Cu 9: Thc hin phn ng nhit phn V lt kh metan iu ch axetilen, thu c 11,2 lt hn hp X gm axetilen, hiro v metan cha phn ng ht. Cho ton b X qua dung dch AgNO 3 (d) trong amoniac thu c 24,0 gam kt ta. Cc th tch kh o ktc. Gi tr ca V l A. 2,24. B. 6,72. C. 4,48. D. 3,36. 2 Cu 10: Hiro c nguyn t khi trung bnh l 1,008. Trong nc, hiro ch yu tn ti hai ng v l 1 1 H v 1
2 H. S nguyn t ca ng v 1 H trong 1ml nc l 20 A. 5,33.10 . B. 4,53.1020. C. 5,35.1020. D. 4,55.1020. Cu 11: Hn hp X gm axit axetic v ancol etylic. Cho 14,52 gam hn hp X tc dng vi Na d thu c 3,024 lt H2 (ktc). Thm H2SO4 c vo hn hp X v un nng thu c 8,80 gam este. Hiu sut ca phn ng este ha l A. 75,36%. B. 80,00%. C. 83,33%. D. 66,67%. 2 Cu 12: Ion NO3 oxi ho c Zn trong dung dch kim (OH ) to NH3, ZnO2 v H2O. Ha tan ht 6,5 gam Zn vo 200ml dung dch hn hp gm KNO3 0,1M v NaOH 1,0M. Kt thc phn ng, thu c V lt hn hp kh ( ktc). Gi tr ca V l A. 0,448. B. 0,784. C. 0,896. D. 1,120. Cu 13: Cho phng trnh ion sau: Al + NO3 + OH + H2O AlO2 + NH3 Tng cc h s (cc s nguyn ti gin) ca cc cht tham gia v to thnh sau phn ng l A. 19. B. 29. C. 18. D. 28. Cu 14: Mt hp cht hu c X ch cha C, H, O c t hn 3 oxic phn t khi bng 90. Cho X tc dng ht vi Na thy s mol H 2 sinh ra bng s mol X tham gia phn ng. X khng tc dng vi NaOH. S ng phn cu to ca X l A. 3. B. 6. C. 5. D. 4. Cu 15: Cho 1,2 lt hn hp gm hiro v clo vo bnh thu tinh bng thch anh y kn v chiu sng bng nh sng khuch tn. Sau mt thi gian ngng chiu sng, thu c mt hn hp kh cha 30% hiroclorua v th tch v lng clo gim xung cn 20% so vi lng clo ban u. Thnh phn phn trm v th tch ca hiro trong hn hp ban u l A. 88,25%. B. 30,75%. C. 81,25%. D. 66,25%. Cu 16: Cho cc dung dch sau: Anilin, natri phenolat, natri axetat, metylamin. S dung dch lm xanh qu tm l A. 1 B. 2 C. 3 D. 4

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Ti liu n thi i hc nm 2012 -2013 Cu 17: Cho cc cht sau: Clobenzen, axit oxalic, phenyl axetat, glyxin, benzyl clorua. S cht c th tc dng vi NaOH (trong iu kin thch hp) theo t l mol nX : nNaOH = 1 : 2 l A. 1 B. 2 C. 3 D. 4 Cu 18: Cho 18,4 gam hn hp Y gm ancol metylic, ancol anlylic v etylen glicol tc dng vi Na kim loi (d) thu c V lt kh H2 ( ktc). Mt khc, t 18,4 gam hn hp Y, thu c 30,8 gam CO 2 v 18,0 gam H2O. Gi tr ca V l A. 2,24 B. 3,36 C. 4,48 D. 5,60 Cu 19: X l hp cht hu c cha C, H, O c 32,43% C (v khi lng), phn t khi ca X bng 74. Cho s + H2 phn ng: X Y o
t , xt

Cng thc phn t ca Y l A. C2H2O3 B. C2H4O3 C. C2H6O3 D. C2H4O2 Cu 20: Ngm mt thanh st trong dung dch Fe2(SO4)3 , sau khi phn ng xy ra hon ton thu c dung dch Y c khi lng tng 5,6 gam so vi dung dch Fe 2(SO4)3 ban u. S mol KMnO4 trong H2SO4 long, d phn ng ht vi dung dch Y l A. 0,04. B. 0,05. C. 0,06. D. 0,07. Cu 21: Nung nng m gam hn hp X gm Al v Fe 2O3 ti phn ng hon ton, thu c cht rn Y. Nghin nh, trn u v chia Y lm 2 phn: - Phn 1: Cho tc dng vi dung dch NaOH n d thu c 0,672 lt H 2 (ktc) v cht rn Z. Ha tan cht rn Z trong dung dch HCl d thu c 2,688 lt kh H2 (ktc) - Phn 2: Cho tc dng vi dung dch HCl d thu c 10,08 lt kh H2 (ktc). Gi tr ca m l A. 29,04 gam. B. 43,56 gam. C. 53,52 gam. D. 13,38 gam. Cu 22: X l mt dn xut ca benzen c cng thc phn t l C 7H9NO2. Cho 13,9 gam X tc dng va vi dung dch NaOH, c cn dung dch thu c 14,4 gam mui khan Y. Y tc dng ht vi dung dch HCl d thu c cht hu c Z. Khi lng phn t (theo vC) ca Z l A. 161,5. B. 143,5. C. 144. D.122. Cu 23: Cho 124,0 gam canxi photphat tc dng vi 98,0 gam dung dch axit sunfuric 64,0%. Lm bay hi dung dch thu c n cn kh c m gam mt hn hp rn. Bit cc phn ng xy ra hon ton. Gi tr ca m l A. 186,72. B. 188,72. C. 180,72. D. 190,68. Cu 24: in phn 2 lt dung dch hn hp gm NaCl v CuSO 4 n khi H2O b in phn hai cc th dng li, ti catot thu 1,28 gam kim loi v anot thu 0,336 lt kh ( ktc). Coi th tch dung dch khng i th pH ca dung dch thu c bng A. 12. B. 1. C. 13. D. 2. Cu 25: Hiro ha etylbenzen thu c xicloankan X. Khi cho X tc dng vi clo (c chiu sng) thu c bao nhiu dn xut monoclo ? A. 4. B. 3. C. 5. D. 6. Cu 26: Cho a gam Si tc dng vi dung dch KOH (d) thu c 8,96 lt kh ( ktc). Gi tr ca a l A. 4,2. B. 5,6. C. 7,0. D. 8,4. Cu 27: Hn hp E gm hai cht hu c X, Y mch h c cng chc ho hc. Khi t chy hon ton 21,8 gam hn hp E thu c 24,64 lt CO2 ( ktc) v 19,8 gam H2O. Mt khc, cho 21,8 gam E tc dng vi dung dch NaOH va , thu c 12 gam ancol n chc v m gam hn hp mui ca hai axit hu c n chc k tip nhau trong dy ng ng. Gi tr ca m l A. 17,8. B. 18,8. C. 15,8. D. 21,8. Cu 28: Mt hn hp gm Al2(SO4)3 v K2SO4, trong s nguyn t oxi chim 20/31 tng s nguyn t c trong hn hp. Ho tan hn hp trn vo nc ri cho tc dng vi dung dch BaCl 2 d, hi khi lng kt ta thu c gp bao nhiu ln khi lng hn hp ban u ? A. 1,588 ln. B. 1,788 ln. C. 1,688 ln. D. 1,488 ln. Cu 29: Cho cc nhn xt sau: (1) Cht bo l trieste ca glixerol vi axit bo. (2) T nilon-6,6 , t capron, t enang u iu ch bng phn ng trng ngng. (3) Vinyl axetat khng iu ch c trc tip t axit v ancol tng ng.
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Ti liu n thi i hc nm 2012 -2013 (4) Nitro benzen phn ng vi HNO3 c (xc tc H2SO4 c, un nng) to thnh m-initrobenzen. (5) Anilin phn ng vi nc brom to thnh p-bromanilin. S nhn xt ng l: A. 3. B. 5. C. 2. D. 4. Cu 30: X l hn hp hai anehit n chc mch h. 0,04 mol X c khi lng 1,98 gam tham gia phn ng ht vi dung dch AgNO3/NH3 d thu c 10,8 gam Ag. m gam X kt hp va vi 0,35 gam H 2. Gi tr ca m l . A.8,66 gam B. 5,94 gam. C. 6,93 gam. D. 4,95 gam. Cu 31: Cho s phn ng: Ca(OH)2 + H3PO4 (d) X + H2O. X l A. Ca3(PO4)2. B. CaHPO4 C. Ca(H2PO4)2 D. Ca3(PO4)2 v CaHPO4. Cu 32: Hn hp X gm mt ankan v mt anken. Cho 11,2 lt hn hp X lm mt mu va ht 500 ml dung dch Br2 0,4M. Mt khc, t chy hon ton 5,6 lt hn hp X thu c 13,44 lt CO 2 (th tch cc kh o ktc). Cng thc phn t ca X, Y l A. C2H6 v C3H6. B. C2H6 v C2H4. C. CH4 v C4H8. D. C3H8 v C3H6. Cu 33: Khi cho hn hp Al v K vo nc thy hn hp tan ht, chng t A. nc d. B. Al tan hon ton trong nc. C. nc d v nAl > nK. D. nc d v nK nAl. Cu 34: Cho 9,2 gam hn hp hai ancol no, n chc, mch h tc dng vi Na (d) sinh ra 2,24 lt H 2 (ktc). Mt khc oxi ha hon ton hn hp hai ancol ny bng CuO nung nng, sn phm thu c cho phn ng vi lng d AgNO3 trong NH3, thu c 43,2 gam Ag. Khi lng ca ancol c khi lng mol nh hn l A. 3,2 gam. B. 4,6 gam. C. 6 gam. D. 3 gam. Cu 35: X c cng thc nguyn l (CH)n. Khi t chy 1 mol X c khng qu 5 mol CO 2. Bit X phn ng vi dung dch AgNO3 trong NH3. S cht X tha mn tnh cht trn l A. 1. B. 3. C. 4. D. 2. Cu 36: Cho dung dch cc cht sau: Br2, NaOH, NaHCO3, CH3COOH. S dung dch phn ng vi c vi phenol l A. 2. B. 3. C. 4. D. 5. Cu 37: Oxit Y ca mt nguyn t X ng vi ha tr II c thnh phn phn trm theo khi lng ca X l 42,86%. C cc pht biu sau: (I). Y l kh khng mu, khng mi, khng v, tan nhiu trong nc, l kh rt c. (II). Y l oxit axit. (III). nhit cao, Y c th kh c nhiu oxit kim loi. (IV). Y c th iu ch trc tip t phn ng gia X nung v hi nc. (V). T axit fomic c th iu ch c Y. (VI). T Y, bng mt phn ng trc tip vi metanol (xt, to), c th iu ch c axit axetic. S pht biu ng l A. 3. B. 5. C. 4 D. 6. Cu 38: Khi cho 7,15 gam hn hp kim loi gm Mg, Zn, Al vo dung dch H 2SO4 long (d) thu c 5,60 lt kh ( ktc). Khi lng mui clorua thu c khi cho 7,15 gam hn hp trn tc dng hon ton vi kh clo l A. 26,80 gam. B. 24,90 gam. C. 16,03 gam. D. 25,12 gam. Cu 39: Pht biu no sau y khng ng ? A. iu ch kh HBr bng cch cho NaBr (rn) tc dng vi axit H2SO4 m c, un nng. B. iu ch kh HF bng cch cho CaF2 (rn) tc dng vi axit H2SO4 m c, un nng. C. Cho kh clo tc dng vi sa vi 30OC thu c clorua vi. D. Flo c tnh oxi ho rt mnh, oxi ho mnh lit nc. Cu 40: t chy a mol mt axit cacboxylic X thu c b mol CO 2 v c mol H2O (bit a = b - c). Khi cho a mol cht X tc dng vi NaHCO3 (d) thu c 2a mol kh. X thuc dy ng ng ca axit A. no, n chc. B. no, hai chc C. c 1 ni i, n chc D. c 1 ni i, hai chc. Cu 41: t chy hon ton 1,72 gam hn hp X gm c anehit acrylic v mt anehit no n chc Y cn 2,296 lt oxi ( ktc). Cho ton b sn phm chy hp th ht vo dung dch nc vi trong d c 8,50 gam kt ta. Cng thc cu to ca Y l
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Ti liu n thi i hc nm 2012 -2013 A. CH3-CH=O. B. H-CH=O C. C2H5CH=O D. C3H7-CH=O. Cu 42: Khi dng kh CO kh Fe2O3 thu c hn hp rn X. Ho tan X bng dung dch HCl d thy c 4,48 lt kh thot ra ( ktc). Dung dch thu c sau phn ng tc dng vi NaOH d (khng c mt khng kh) thu c 45 gam kt ta trng xanh. Th tch kh CO ( ktc) cn dng l A. 6,72 lt. B. 8,96 lt. C. 10,08 lt. D. 13,44 lt. Cu 43: Cho glixerol tc dng vi hn hp 3 axit C17H35COOH, C17H33COOH v C15H31COOH. S loi trieste c to thnh cha ng thi c 3 gc axit trn c th l A. 2. B. 4. C. 6. D. 3. Cu 44: Pht biu no sau y khng ng khi so snh tnh cht ha hc ca st v crom ? A. St v crom u b th ng ha trong dung dch HNO3 c ngui. B. St v crom u phn ng vi lu hunh nhit cao theo cng t l v s mol. C. St l kim loi c tnh kh yu hn crom . D. St v crom u tan trong dung dch long khi un nng ca axit HCl v H 2SO4 to mui st(II) v mui crom(II) khi khng c khng kh. Cu 45: Hp cht A1 c cng thc phn t C3H6O2 tha mn s : dd AgNO3/NH3 dd H2SO4 NaOH A1 A 2 A3 A4 Cng thc cu to ca A1 l A. HCOOCH2CH3 B. CH3OCOCH3. C. CH3CH2COOH D. HOCH2CH2CHO. Cu 46: Hai dung dch CH3COONa v NaOH c cng pH, nng mol/l ca cc dung dch tng ng l x v y. Quan h gia x v y l A. x = y. B. x < y. C. x > y. D. x = 0,1y. Cu 47: Hp cht hu c X c cng thc phn t chung l C xHyO2 (x 2), bit cht X l hp cht no, mch h. Pht biu no sau y khng ng ? A. y = 2x + 2; X l ancol no hai chc B. y = 2x - 4; X l anehit no hai chc. C. y = 2x - 2; X l anehit no hai chc D. y = 2x; X l axit hoc este no n chc. Cu 48: Cho a mol cht bo X cng hp ti a vi 5a mol Br 2 . t a mol X c b mol H 2O v V lt CO2. Biu thc lin h gia V, a v b l A. V = 22,4.(4a - b). B. V = 22,4.(b + 5a). C. V = 22,4.(b + 6a). D. V = 22,4.(b + 7a). Cu 49: Cho 45,0 gam hn hp bt Fe v Fe3O4 vo V lt dung dch HCl 1M, khuy u cc phn ng xy ra hon ton, thy thot ra 4,48 lt kh (ktc) v 5,0 gam kim loi khng tan (cho bit th t t tri sang phi ca cc cp oxi ha-kh trong dy in ha nh sau: Fe2+/Fe; H+/H2; Fe3+/Fe2+ ). Gi tr ca V l A. 1,4 lt B. 0,4 lt C. 0,6 lt D. 1,2 lt Cu 50: Cho cc cht sau: C2H5NH2, C6H5NH2, NH3, C2H5NH3Cl, C6H5NH3Cl, NH4Cl. S cp cht phn ng c vi nhau l A. 3. B.2. C. 4 D. 1.

B S 15 Cu 1. Trn a (ml) dung dch Ba(OH)2 0,025M vo 100 ml dung dch gm HNO3 v HCl (c pH = 1) thu c dung dch c pH = 2. Gi tr ca a l A. 250. B. 300. C. 100. D. 150. Cu 2. Cho hn hp X gm Mg v Fe vo dung dch H2SO4 c nng n khi phn ng xy ra hon ton, thu c dung dch Y v mt phn Fe khng tan. Cht tan c trong dung dch Y l A. MgSO4 v Fe2(SO4)3. B. MgSO4 v FeSO4. C. MgSO4, Fe2(SO4)3 v FeSO4. D. MgSO4.
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Ti liu n thi i hc nm 2012 -2013 Cu 3. Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CaCl2, Ca(NO3)2, NaOH, Na2CO3, KHSO4, Ca(OH)2, H2SO4, HCl. S trng hp c xy ra phn ng l A. 5. B. 6. C. 3. D. 7. Cu 4. Hn hp X gm HCOOH, CH 3COOH (t l mol 1:2), hn hp Y gm CH 3OH, C2H5OH (t l mol 2:3). Cho 6,64 gam hn hp X tc dng vi 4,04 gam hn hp Y (c xc tc H 2SO4 c v un nng) thu c m gam este (hiu sut cc phn ng este ha u bng 70%). Gi tr ca m l A. 5,472 gam B. 6,216 gam C. 8,88 gam D. 7,476 gam Cu 5. Thc hin cc th nghim sau: (1) Cho kh CO qua ng s cha bt Al2O3, nung nng. (2) Cho mu Na vo dung dch CuSO4. (3) Nung nng AgNO3. (4) in phn NaOH nng chy. (5) in phn dung dch CuCl2. (6) in phn KCl nng chy. S th nghim c ion kim loi b kh l: A. 2. B. 5. C. 3. D. 4. Cu 6. Cho cc cht phenylaxetilen (1), vinyl clorua (2), axeton (3), axetanehit (4), benzanehit (5). Nhng cht tc dng vi dung dch AgNO3 trong NH3 l A. (1), (4), (5) B. (3), (4), (5) C. (4), (5) D. (2), (3), (4), (5) Cu 7. Cho s chuyn ha CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s trn th cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH 4 chim 80% th tch kh nhin nhin v hiu sut ca c qu trnh l 50%) A. 448,0. B. 358,4. C. 224,0. D. 286,7. Cu 8. Cho 7,52 gam hn hp X gm C2H2 v CH3CHO tc dng ht vi dung dch AgNO3/NH3 (d) thu c 50,4 gam cht rn Y. Ha tan Y bng dung dch HCl (d), thy cn li m gam cht rn Z. Gi tr ca m l A. 34,44 gam B. 38,82 gam C. 56,04 gam D. 21,60 gam Cu 9. Cho isopentan tc dng vi clo theo t l mol 1:1 thu c ti a x dn xut monoclo. Khi isopren tc dng vi brom theo t l mol 1:1 thu c ti a y dn xut ibrom. un si mt dn xut halogen bc hai, mch nhnh c CTPT l C5H11Cl vi kali hiroxit v etanol thu c ti a z sn phm hu c. t T = x + y + z. Gi tr ca T l A. 10 B. 8 C. 11 D. 9 Cu 10. nh gi lng axit bo t do c trong cht bo ngi ta dng ch s axit. l s mg KOH cn trung ha lng axit bo t do c trong 1 gam cht bo. trung ha 14 gam cht bo c ch s axit bng 6 th th tch dung dch KOH 0,1M cn dng l A. 5 ml. B. 10 ml. C. 15 ml. D. 6 ml. Cu 11. Pht biu no sau y ng? A. ng trng hp buta-1,3-ien vi stiren c xc tc Na c cao su buna-S. B. T visco l t tng hp. C. T nilon-6,6 c iu ch bng phn ng trng hp hexametyleniamin vi axit aipic. D. Trng hp stiren thu c poli(phenol-fomanehit). Cu 12. Cho hn hp G gm 0,2 mol axetilen v 0,35 mol H2 vo bnh kn c xc tc Ni nung nng. Sau mt thi gian thu c hn hp Y gm 4 kh. Cho Y li qua dung dch brom d thy c 4,48 lt kh K (ktc) bay ra. T khi ca K i vi H2 l 4,5. tng khi lng ca bnh brom l A. 2,05 gam. B. 5,0 gam. C. 5,2 gam. D. 4,1 gam. Cu 13. Hn hp X gm ba amin c khi lng mol phn t tng dn vi t l s mol tng ng l 1:10:5. Cho 20 gam X tc dng vi dung dch HCl va thu dung dch Y. C cn dung dch Y thu c 31,68 gam hn hp mui. Cng thc cu to thu gn ca ba amin trn ln lt l: A. CH3NH2, C2H5NH2, C3H7NH2. B. C3H7NH2, C4H9NH2, C5H11NH2 C. C4H9NH2, C5H11NH2, C6H13NH2 D. C2H5NH2, C3H7NH2, C4H9NH2 Cu 14. Cht kh sinh ra khi nhit phn mui amoni nitrat l A. NO. B. N2O C. NO2. D. N2. Cu 15. C cc nhn xt sau: - Cht bo thuc loi cht este. - T nilon - 6,6; t nitron; t enang u c iu ch bng phn ng trng ngng. - Vinyl axetat khng iu ch c trc tip t axit v ancol tng ng. - Nitro benzen phn ng vi HNO3 c (xc tc H2SO4 c) to thnh m-initrobenzen.
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Ti liu n thi i hc nm 2012 -2013 - Anilin phn ng vi nc brom d to thnh p-bromanilin. S nhn xt ng l A. 2. B. 3. C. 5. D. 4. 2+ + 2+ 3+ Cu 16. Cho dy cc cht v ion: Fe, Cl2, SO2, HCl, C, Al, Mg , Na , Fe , Fe . S cht v ion va c tnh oxi ha, va c tnh kh l: A. 6 B. 8 C. 5 D. 4 Cu 17. Cho cc cp cht vi t l s mol tng ng nh sau: (a) Fe3O4 v Cu (1:1); (b) CuO v Zn (1:1); (c) Zn v Cu (1:1); (d) Fe2(SO4)3 v Cu (1:1); (e) FeCl2 v Cu (2:1); (g) Fe2O3 v Cu (1:2). S cp cht tan hon ton trong lng d dung dch HCl long, nng l A. 5. B. 3. C. 2. D. 4. 0 Cu 18. un nng hn hp hai ancol n chc, mch h vi H 2SO4 c 140 C, thu c hn hp gm cc ete. Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO 2 ( ktc) v 7,2 gam H2O. Hai ancol l A. C2H5OH v CH3OH. B. C2H5OH v CH2=CH-CH2-OH. C. CH3OH v C3H7OH. D. CH3OH v CH2=CH-CH2-OH. Cu 19. Trong cc cht: propen (I); 2-metylbut-2-en (II); 3,4-imetylhex-3-en (III); 3-cloprop-1-en (IV); 1,2icloeten (V), cht c ng phn hnh hc l A. I, V B. II, IV C. III, V D. I, II, III, IV Cu 20. Axit picric (2,4,6-trinitrophenol) c iu ch bng cch cho phenol phn ng vi dung dch HNO 3 c (xc tc H2SO4 c). Gi s hiu sut phn ng l 100%. Khi lng dung dch HNO 3 72,7% ti thiu cn dng iu ch 57,25 gam axit picric l A. 47,25 gam B. 65 gam C. 15,75 gam D. 36,75 gam Cu 21. Ha tan 24,4 gam hn hp gm FeCl2 v NaCl (c t l s mol tng ng l 1 : 2) vo mt lng nc (d), thu c dung dch X. Cho dung dch AgNO3 (d) vo dung dch X, sau khi phn ng xy ra hon ton sinh ra m gam cht rn. Gi tr ca m l A. 28,7. B. 34,1. C. 68,2. D. 57,4 Cu 22. Ha tan hon ton 8,94 gam hn hp gm Na, K v Ba vo nc, thu c dung dch X v 2,688 lt kh H2 (ktc). Dung dch Y gm HCl v H2SO4, t l mol tng ng l 4:1. Trung ha dung dch X bi dung dch Y, tng khi lng cc mui c to ra l A. 18,46 gam. B. 13,70 gam. C. 14,62 gam. D. 9,23 gam. Cu 23. Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO 3)2 0,2M v H2SO4 0,25M. Sau khi cc phn ng xy ra hon ton, thu c 0,75m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m v V ln lt l A. 28,48 v 2,24. B. 17,8 v 4,48 C. 17,8 v 2,24. D. 10,8 v 4,48. Cu 24. Cho 0,05 mol mt cht hu c X tc dng vi lng d AgNO3 trong dung dch NH3 (un nng) thu c 10,8 gam Ag. Hiro ha X thu c Y. Khi cho 0,1 mol Y phn ng vi Na d gii phng 2,24 lit H 2 (ktc) . Cng thc cu to thu gn ca X l A. CH3COCH2CH=O B. CH3CH=O C. HCH=O D. O=HC-CH=O + Br2 (1:1),as + Br2 (1:1), Fe + CO2 + H 2O NaOH c, d , t0 , p Cu 25. Cho s chuyn ha: Toluen X Y Z T. Hai cht Y v Z ln lt l: A. p-BrC6H4CH2Br v p-HOC6H4CH2OH. B. p-BrC6H4CH2Br v p-NaOC6H4CH2ONa. C. m-BrC6H4CH2Br v m-NaOC6H4CH2OH. D. p-BrC6H4CH2Br v p-NaOC6H4CH2OH. Cu 26. Hn hp A gm 2 este n chc X, Y. Chia 32,6 gam hn hp A thnh 2 phn bng nhau. X phng ho hon ton phn I bng mt lng va 125 ml dung dch NaOH 2M un nng, thu c 1 ancol v 2 mui. Cho phn II tc dng vi lng d dung dch AgNO 3/NH3 thu c 43,2 gam Ag. Khi lng v cng thc ca cc este X,Y c trong hn hp A ln lt l: A. 24 gam HCOOCH3 v 8,6 gam C2H5COOCH3. B. 12 gam HCOOCH3 v 20,6 gam CH3COOCH3. C. 12 gam HCOOCH3 v 20,6 gam C2H3COOCH3. D. 24 gam HCOOCH3 v 8,6 gam C2H3COOCH3. Cu 27. Trong cc phn ng thc hin dy bin ha:
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Ti liu n thi i hc nm 2012 -2013 CHCH CH3CHO C2H5OH CH3COOH CH3COOCH3 CH3COONa CH4 CHCH. S phn ng oxi ha - kh l A. 5 B. 3 C. 6 D. 4 Cu 28. Dy gm cc kim loi u c cu to mng tinh th lp phng tm khi l: A. Li, Na, K , Mg B. Na, K, Ca, Be C. Li, Ba, K, Rb D. Na, K, Ca, Ba Cu 29. iu no sau y ng khi ni v cacbon ioxit? A. Lm vn c dung dch NaOH. B. L kh khng mu, nh hn khng kh. C. L cht kh c th dng cha chy khi c m chy magie. D. C th to ra ''nc kh'' dng to mi trng lnh khng c hi m. Cu 30. Nung 4,46 gam hn hp X gm cc kim loi Fe, Al, Zn, Mg trong oxi, sau mt thi gian thu c 5,42 gam hn hp Y. Ha tan hon ton Y vo dung dch HNO 3 (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc). S mol HNO3 phn ng l A. 0,18. B. 0,12. C. 0,24. D. 0,36. Cu 31. Tp hp ion sau c th cng tn ti trong mt dung dch: A. K+, Na+, CO32-, HCO3-, OH-. B. Cu2+, Na+, Cl-, NO3-, OH-. + 2+ 2+ C. Na , Ca , Fe , NO3 , Cl . D. Fe2+, K+, NO3-, OH-, NH4+. Cu 32. C nm cht hu c: C6H5OH(1); m-CH3C6H4OH (2); m-O2NC6H4OH (3); p-CH3C6H4OH (4); pO2NC6H4OH (5); CH3CH2OH (6); CH2ClCH2OH (7); 2,4,6-(NO2)3C6H2OH (8). Chiu tng dn linh ng ca nguyn t H trong nhm OH ca cc hp cht trn (t tri qua phi) ln lt l A.(8), (5), (3), (1), (2), (4), (7), (6). B. (6), (7), (4), (2), (1), (3), (5), (8). C. (6), (7), (4), (1), (2), (3), (5), (8). D. (6), (7), (1), (2), (4), (3), (5), (8). Cu 33. Cu m t ng tnh cht ca cc kim loi kim khi sp xp chng theo chiu in tch ht nhn tng dn l: A. Bn knh nguyn t gim dn. B. Kh nng phn ng vi nc mnh dn. C. Khi lng ring ca n cht gim dn. D. Nhit nng chy tng dn. Cu 34. Cho cc nguyn t M (Z = 11), X (Z = 17), Y (Z = 9), R (Z = 19). m in ca cc nguyn t tng dn theo th t A. Y<M<X<R. B. R<M<X<Y. C. M<X<Y<R. D. M<X<R<Y. Cu 35. Thc hin cc th nghim sau: (1) Sc SO2 vo dung dch KMnO4. (2) Sc kh H2S vo dung dch Br2. (3) Sc hn hp kh NO2 v O2 vo nc. (4) Cho CaOCl2 vo dung dch HCl c, nng. (5) Nung nng Ag trong kh O2. (6) Cho SiO2 vo dung dch HF. S th nghim c phn ng oxi ha kh xy ra l A. 6. B. 4. C. 5. D. 3. Cu 36. X, Y, Z l 3 hp cht thm c cng thc phn t C7H6Cl2 . Khi un nng vi dung dch NaOH long th X phn ng theo t l mol 1:2 ; Y phn ng theo t l mol 1:1 cn Z khng phn ng. S ng phn cu to ca X, Y, Z ln lt l A. 1,3,4. B. 1,3,6 C. 1,3,5 D. 1,2,3 Cu 37. Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H2 l 17. Nu t chy hon ton 0,1 mol hn hp X ri hp th ton b sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng dung dch thay i nh th no? A. Tng 7,8 gam. B. Tng 14,6 gam. C. Gim 10,4 gam. D. Gim 7,8 gam. Cu 38. Cng thc phn t ca hp cht kh to bi nguyn t R v hiro l RH 3. Trong oxit m R c ho tr cao nht th oxi chim 74,07% v khi lng. Nguyn t R l A. N. B. As. C. P. D. S. Cu 39. Ln men b gam glucoz sau cho ton b lng CO2 sinh ra hp th vo nc vi trong thy to thnh 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi ban u. Bit hiu sut ca qu trnh ln men l 90%. Gi tr ca b l A. 25 B. 14 C. 15 D. 16 Cu 40. Loi phn bn ha hc no sau y lm chua t A. Amoni nitrat: NH4NO3. B. Natri nitrat: NaNO3. C. Ure: (NH2)2CO. D. Kali sunfat: K2SO4.
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Ti liu n thi i hc nm 2012 -2013 Cu 41. Cho 0,015 mol mt loi hp cht oleum vo nc thu c 200 ml dung dch X. trung ha 50 ml dung dch X cn dng 100 ml dung dch NaOH 0,15M. Phn trm v khi lng ca nguyn t lu hunh trong oleum trn l A. 23,97. B. 32,65. C. 35,95. D. 37,86. Cu 42. Trong cc amino axit sau: glyxin, alanin, valin, axit glutamic, lysin c bao nhiu cht c th lm i mu giy qu tm m? A. 4 B. 2 C. 3 D. 5 Cu 43. X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m gam hn hp cha X v Y c t l s mol ca X v Y tng ng l 1:3 vi dung dch NaOH va . Phn ng xy ra hon ton thu c dung dch T. C cn cn thn dung dch T thu c 23,745 gam cht rn khan. Gi tr ca m l A. 78,4. B. 19,455. C. 68,1. D. 17,025. Cu 44. Hai kh no sau y c th cng tn ti trong cng mt bnh cha? A. HI v Cl2. B. O2 v Cl2. C. H2S v SO2. D. NH3 v HCl. Cu 45. Trong qu trnh in phn dung dch NaCl (vi in cc tr, c mng ngn xp), catot xy ra A. s kh phn t nc B. s oxi ho phn t nc C. s oxi ho ion ClD. s kh ion Na+ Cu 46. Cho m gam NaOH vo 2 lt dung dch NaHCO 3 nng a mol/lt, thu c 2 lt dung dch X. Cho 1 lt dung dch X tc dng vi dung dch BaCl2 (d) thu c 11,82 gam kt ta. Cho 1 lt dung dch X vo dung dch Ba(OH)2 (d), sau khi kt thc cc phn ng thu c 15,76 gam kt ta. Mt khc, nu trn 2 lt dung dch X vi 1 lt dung dch CaCl2 0,15M ri un si n cn th thu c x gam cht rn khan. Gi tr ca x l A. 31,49. B. 27,07. C. 14,0. D. 32,73. Cu 47. Cho 10,7 gam hn hp X gm Mg, Al v Fe tc dng hon ton vi dung dch HCl thu c 7,84 lt kh H2 (ktc). Nu cho 10,7 gam X vo dung dch CuSO4 (d), khuy nh n phn ng hon ton th thy khi lng cht rn tng thm m gam. Gi tr ca m l A. 11,7. B. 34,1. C. 11,2. D. 22,4. Cu 48. Cho cc cht: C2H5OH (1), CH3CHO (2), CH3CHCl2 (3), CH3COOCH=CH2 (4), CH3COCH3 (5), CH3COONa (6). Ch bng mt phn ng ha hc, nhng cht c th to ra CH3COOH l A. (1), (2), (3), (4), (6) B. (2), (6) C. (1), (2), (4), (6) D. (1), (2), (6) Cu 49. C 4 l mt nhn, mi l ng mt trong cc cht lng: dung dch glucoz, benzen, ancol etylic v glixerol. phn bit 4 l trn c th dng cc ha cht A. dd AgNO3/NH3, dd NaOH B. Na kim loi, dd AgNO3/NH3 C. nc, Cu(OH)2/OH D. Na kim loi, nc brom Cu 50. Cho 6 gam km ht vo cc ng dung dch H 2SO4 2M nhit thng. Nu gi nguyn cc iu kin khc, ch bin i mt trong cc iu kin sau y th trng hp no khng lm thay i tc phn ng? A. Tng nhit ln n 50OC. B. Thay dung dch H2SO4 2M bng dung dch H2SO4 1M. C. Tng th tch dung dch H2SO4 2M ln 2 ln. D. Thay 6 gam km ht bng 6 gam km bt.

B S 16 Cu 1. Dung dch A cha 0,015 mol Na+, x mol HCO3- , 0,1 mol NH4+ v 0,05 mol NO3- .Cho t t 200 ml dung dch Ca(OH)2 1M vo dung dch A, un nng nh( gi s nc bay hi l khng ng k).Tng khi lng dung dch A v dung dch Ca(OH)2 gim l m(g). Gi tr ca m l A. 8,2 B. 21,7 C. 6,5 D.15,2
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Ti liu n thi i hc nm 2012 -2013 Cu 2. Cht bo A c ch s axit l 7. x phng ho 10 kg A, ngi ta un nng n vi dung dch cha 1,420 kg NaOH. Sau khi phn ng xy ra hon ton trung ho hn hp, cn dng 500ml dung dch HCl 1M. Khi lng x phng (kg) thu c l A. 10,3425 B. 10,3435 C. 10,3445 D. 10,3455 Cu 3. Ho hi 6,7 gam hn hp A gm CH3COOH + CH3COOC2H5 + HCOOCH3 thu c 2,24 lt hi (ktc). t chy hon ton 6,7g hn hp A th s gam nc sinh ra l A. 5,0 B. 4,5 C. 4,0 D. 5,8 Cu 4. Cho 29,8 gam hn hp 2 amin n chc k tip tc dng ht vi dung dch HCl, lm kh dung dch thu c 51,7 gam mui khan. Cng thc phn t 2 amin l A. C2H7N v C3H9N B. CH5N v C2H7N C. C3H9N v C4H11N D. C3H7N v C4H9N Cu 5. Cho cc cht : phenol (1), anilin (2), toluen (3), metyl phenyl ete (4). Nhng cht tc dng vi nc Br2 l: A. (3) v (4) B. (1), (2), (3) v (4) C. (1) v (2) D. (1), (2) v (4) Cu 6. Khi nhit phn cc cht sau: NH4NO2, NH4HCO3, MgCO3, KMnO4, NaNO3. S phn ng thuc phn ng oxi ho kh l: A. 4. B. 2. C. 5. D. 3 Cu 7. Cho phn ng : H2 + 3N2 2NH3 . khi tng nng N2 ln 4 ln nng cc cht khc gi nguyn . th tc phn ng thun s tng A. 32 ln B. 64 ln C. 12 ln D. 16 ln Cu 8. Ho tan hon ton 33,8 gam hn hp gm FeCl2 v NaF (c cng s mol) vo mt lng nc d, thu c dung dch X. Cho dung dch AgNO 3 d vo X, sau khi phn ng xy ra hon ton thu c m gam cht rn. Gi tr ca m l: A. 82,8 B. 57,4 C. 79,0 D. 104,5 Cu 9. Hin tng xy ra khi cho t t dung dch NH3 n d vo dung dch ZnSO4 l A. xut hin kt ta mu trng B. xut hin kt ta mu xanh C. u tin xut hin kt ta mu trng, sau kt ta tan dn cho dung dch trong sut. D. u tin xut hin kt ta mu trng, sau kt ta tan dn cho dung dch c mu xanh. Cu 10. Cho x mol Fe tc dng vi dung dch cha y mol HNO 3 to ra kh NO v dung dch X. dung dch X tn ti cc ion Fe3+, Fe2+, NO 3 th quan h gia x v y l (khng c s thy phn cc ion trong nc) A. y/4 < x < 3y/8 B. 3y/8 < x < y/4 C. y/8 < x < y/4 D . x > 3y/8 Cu 11. Xt cn bng ho hc ca mt s phn ng 1) Fe2O3(r) + 3CO(k) 2Fe(r) + 3CO2(k) 2) CaO(r) + CO2(k) CaCO3(r) 3) N2O4(k) 2NO2(k) 4)H2(k) + I2(k) 2HI(k) 5) 2SO2(k) + O2(k) 2SO3(k) Khi tng p sut, cn bng ho hc khng b dch chuyn cc h A. 1, 2, 4, 5. B. 2, 3, 5. C. 1, 4. D. 1, 2, 4. Cu 12 : Hn hp X gm Ankan A v H2 c t khi hi ca X so vi H2 l : 29. nung nng X cracking hon ton A thu c hh Y c t khi hi so vi H2 l :16,111. Cng thc phn t ca A l A. C4H10 B. C5H12 C. C3H8 D.C6H14 Cu 13.Trong cng nghip HCl c th c iu ch bng phng php sunfat theo phng trnh phn ng: 2NaCl(tinh th) + H2SO4(c) 2HCl + Na2SO4 Phng php ny khng c dng iu ch HBr v HI do A. tnh axit ca H2SO4 yu hn HBr v HI B. NaBr v NaI t tin, kh kim. C. HBr v HI sinh ra l cht c D. c phn ng gia HBr, HI vi H2SO4 (c, nng) Cu 14. Pht biu khng ng l: A. Fe3+ kh c Cu ,do cp Fe3+/Fe2+ ng sau cp Cu2+/Cu trong dy in ha. B. Cu2+ tc dng c vi dung dch H2S to kt ta mu en. C. Ag+ c tnh oxi ha mnh hn Cu2+. D. Tnh oxi ha ca cc ion tng theo th t: Fe2+, H+, Cu2+, Ag+. Cu 15. Cho m gam hn hp gm (Al, Mg, Cu) phn ng vi 200ml dung dch HNO 3 1M. Sau phn ng thu c (m + 6,2g) mui khan (gm 3 mui). Nung mui ny ti khi lng khng i thu cht ran c khi lng l
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Ti liu n thi i hc nm 2012 -2013 A. ( m ) gam B. (m + 3,2) gam C. (m + 1,6) gam D. (m + 0,8)gam Cu 16. Khi in phn vi in cc tr hon ton cc cht tan trong dung dch gm hn hp FeCl 3 , CuCl2 v HCl th qu trnh xy ra anot l : A. Fe3+ nhn electron trc v tip theo l Cu2+. B. Cl- nhng electron trc, H2O nhng electron sau. C. Fe3+ nhn electron trc v H+ nhn electron cui cng l Cu2+. D. ch c Cl- nhng electron. Cu 17. Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc axit sunfuric c, nng. c 118,8 kg xenluloz trinitrat, cn dng dung dch cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l : A. 60 B. 84 C. 42 D. 30 Cu 18. Dung dch X cha AgNO3 v Cu(NO3)2 c cng nng mol. Thm mt lng hn hp gm 0,03 molAl v 0,05 mol Fe vo 100 ml dung dch X cho n khi phn ng kt thc thu c cht rn Y gm 3 kim loi.Cho Y vo HCl d thy thot ra 0,07g kh. Nng mol ca 2 mui l A. 0,45 M. B. 0,3 M. C. 0,4 M. D. 0,5 M. Cu 19. Khi tng nhit ln thm 50oC th tc phn ng tng ln 1024 ln. H s nhit ca tc phn ng l A. 5 B. 3 C. 4 D. 6 Cu 20. Hp cht hu c X mch h c cng thc C xHyO . khi t chy hon ton a mol X thu c b mol CO 2 v c mol H2O. Bit (b c) = 3a. Khi hidro ha hon ton 0,1 mol X th th tch H2 (ktc) cn l: A. 2,24lit B. 6,72 lit C. 8,96 lit D. 4,48 lit Cu 21. Cho m (g) Mg vo 200 ml dung dch Fe(NO 3)3 1M, sau khi phn ng xy ra hon ton thu c 5,6g kim loi. Gi tr ca m l A. 1,6 B. 4,8 C. 8,4 D. 4,1 Cu 22. Cho Ba(HCO3)2 ln lt vo cc dung dch sau : NaHCO 3 , KHSO4 ,HNO3 ,MgSO4 , (NH4)2CO3 , CaCl2 , NaOH. Trng hp c phn ng xy ra l: A. 4 B. 6 C.5 D.3 Cu 23. Trn 8,1 gam bt Al vi 10 gam Fe2O3 ri tin hnh phn ng nhit nhm vi hiu sut 90%. Hn hp sau phn ng c ho tan trong dung dch HNO 3 long d thu c hn hp kh NO, N 2 theo t l mol l 2: 1. Th tch ca hn hp kh ( ktc) l A. 3,780 lt. B. 2,016 lt. C. 5,040 lt. D. 1,792 lt. Cu 24. A,B,C, l ba hp cht cng CTPT l C7 H6 Cl2 . Khi un nng vi NaOH long, theo t l mol 1: 2 . B phn ng theo t l mol 1:1 ,C khng phn ng. S ng phn ca A, B, C ln lt l A. 1,3,5 B.1,2,3 C. 1,3,6 D.1,3,4. 3+ 2+ + 2Cu 25.Cho cc ht vi m: Al , Mg , Na , O , F . Dy c xp ng th t tng dn bn knh ht nhn l A. Al3+< Mg2+<Na+<O2-<FB. Al3+<Mg2+<Na+<F-<O2-. + 2+ 3+ 22+ 2+ 3+ C. Na < Mg <Al < F <O D. O <F < Na < Mg <Al Cu 26. Thm t t cho n ht 0,5 mol dung dch HCl vo hn hp dung dch Y gm 0,2 mol NaOH v 0,15 mol NaAlO2. Lng kt ta thu c l: A. 15,6 gam B. 11,7 gam C. 3,9 gam D. 7,8 gam Cu 27. Cho cc hp cht sau : SO 2 , CO2 , NH4Cl , PCl5 , SO3, H2SO4 theo quy tc bt t s trng hp c lin kt cho nhn l: A. 5 B. 3 C.4 D.2 Cu 28. t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO 2. Cht X tc dng c vi Na, tham gia phn ng trng bc v tc dng vi Br2 trong CCl4 theo t l 1 :1 . Cng thc cu to ca X l A. HOOC-CH=CH-COOH. B. HO-CH2-CH2-CH2-CHO. C. HO-CH2-CH=CH-CHO. D. HO-CH2-CC-CHO. Cu 29. Cho 10,6 gam hn hp X gm 2 axit cacboxylic l ng ng k tip nhau phn ng hon ton vi 150ml dung dch NaOH 1M v KOH 1M, thu c dung dch Y. C cn dung dch Y, thu c 21,4 gam hn hp cht rn khan. Cng thc ca 2 axit trong X l: A. C2H2COOH v C3H6COOH B. CH3COOH v C2H5COOH C. C3H5COOH v C4H4CCOH D. HCOOH v CH3COOH
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Ti liu n thi i hc nm 2012 -2013 Cu 30. Thy phn ht hn hp gm m gam tetrapeptit Ala-Gly-Ala-Gly (mch h) thu c hn hp gm 21,7 gam Ala-Gly-Ala, 7,5 gam Ala v 14,6 gam Ala Gly. Gi tr ca m l A. 41,10 B. 43,80 C. 42,16 D. 34,80 Cu 31. Oxi ha hon ton V (lt) SO2 ktc trong oxi khng kh to thnh SO 3 cho ton b lng SO3 trn vo dung dch H2SO4 10% thu c 100g dung dch H2SO4 20%. Gi tr ca V l A. 3,3600 B. 2,4888 C. 1,1200 D. 1,4220 Cu 32. Cng thc ho hc ca supephotphat kp l: A. Ca3(PO4)2. B. Ca(H2PO4)2. C. CaHPO4. D. Ca(H2PO4)2 v CaSO4. Cu 33. Cho cc cht: anehit axetic, axit axetic, glixerol , Propan -1,2 iol ,v cc dung dch glucoz , sacaroz, fructoz , mantoz. iu kin thng s cht c th tham gia phn ng vi Cu(OH)2 l: A. 6 B. 5 C. 7 D. 4 Cu 34. Cho cc polime sau: poli (vinyl clorua) ; t olon ; cao su Buna ; nilon 6,6 ; thy tinh hu c; t lapsan, poli Stiren. S polime c iu ch t phn ng trng hp l: A. 4 B. 5 C. 6 D. 3 Cu 35. Dy cc cht u lm mt mu dung dch thuc tm l A. benzen, but-1-en, axit fomic, p-xilen B. etilen, axetilen, anehit fomic, toluen C. axeton, etilen, anehit axetic, cumen D. xiclobutan, but-1-in, m-xilen, axit axetic Cu 36. Thy phn este (E) C4H6O2 trong mi trng kim : (E) + NaOH mui (M ) + cht (A) Cho bit c M v A u tham gia phn ng trng gng. Cng thc ng ca E l: A. HCOOCH=CH-CH3. B. HCOOCH2-CH=CH2 C. CH2=CH-COOCH3 D.CH3COOCH=CH2. Cu 37. Dtc hy hon ton 12,88g hn hp gomf mt axit no, n chc v mt ancol no, n chc c 0,54 mol CO2 v 0,64 mol H2O. Thc hin phn ng este ha hon ton lng hn hp trn th thu c m(g) este. Gi tr ca m l A. 10,20 B. 11,08 C. 12,00 D. 8,80 Cu 38. Dung dch X cha a mol Ca(OH) 2 . Cho dung dch X hp th 0,08 mol CO 2 c 2b mol kt ta, nhng nu dng 0,10 mol CO2 th thu c b mol kt ta. Gi tr ca a v b ln lt l: A. 0,07 v 0,04 B. 0,07 v 0,02 C. 0,06 v 0,04 D. 0,06 v 0,02 Cu 39. Dung dch X cha hn hp gm Na 2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 200 ml dung dch HCl 1M vo 100 ml dung dch X, sinh ra V lt kh (ktc). un nng c cn dung dch sau phn ng thu c m (g) mui khan. Gi tr ca m l A. 25,6g B. 30,1 C. 18,2 D. 23,9 Cu 40. Cho loi nc cng cha cc ion sau. Mg2+ x mol , Ca2+ y mol , Cl- 0,2 mol , HCO3- 0,1 mol . Cch lm mm c th s dng lm loi nc cng trn c cng nh nht l A. un si dung dch. B. dng Na3PO4 C. dng Ca(OH)2 D. Dng NaOH d Cu 41. Pht biu khng ng l A.Nng lng ion ha I1 ca kim loi kim gim dn t Li n Cs. B.Cc kim loi Na, K , Ba c mng tinh th lp phng tm khi. C.Cc nguyn t kim loi kim th u tc dng vi nc gii phng H2. D.Phng php c bn iu ch kim loi kim th l in phn mui nng chy ca chng. Cu 42. Khi tch nc 3-etyl pentanol-3 thu c: A. 2-etyl pent-2en. B. 3-etyl pent-3en. C. neo-hex-3en. D. 3-etyl pent-2en. Cu 43. Hn hp A gm glucoz v tinh bt c chia thnh hai phn. Phn th nht c khuy trong nc, lcv cho nc lc phn ng vi dung dch AgNO 3 d/NH3 thy tch ra 2,16g Ag. Phn th hai c un nng vidung dch H2SO4 long, trung ha hn hp thu c bng dung dch NaOH ri cho sn phm tc dng vi dung dchAgNO3 (d)/NH3 thy tch ra 6,48gam Ag. Gi s cc phn ng xy ra hon ton. Phn trm v khi lng glucoz v tinh bt trong hn hp ban u ln lt l A. 35,29% v 64,71% B. 64,71% v 35,29% C. 64,29% v 35,71% D. 35,71% v 64,29% Cu 44. Pht biu khng ng l A. Fructoz tn ti dng , vng 5 cnh trng thi tinh th. B. Oxi ha glucoz bng AgNO3 trong dung dch NH3 thu c amoni gluconat. C. Metyl glucozit c th chuyn c t dng mch vng sang dng mch h. D. Kh glucoz bng H thu c sobitol.
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Ti liu n thi i hc nm 2012 -2013 Cu 45. Cho cc cht sau: (1) Anilin ;(2) etylamin ;(3) iphenylamin ; (4) ietylamin ;(5) natrihidroxit ; (6)Amonic . Dy th t sp xp theo chiu gim dn tnh baz ca cc cht l A. (5) > (4) > (2) > (6) > (1) > (3) B. (6) > (4) > (3) > (5) > (1) > (2) C. (5) > (4) > (2) > (1) > (3) > (6) D. (1) > (3) > (5) > (4) > (2) > (6) Cu 46. in phn dung dch c cha 0,1 mol CuSO 4 v 0,2 mol FeSO4 trong thng in phn khng c mng ngn. Sau mt thi gian thu c 2,24 lt kh anot th dng li. Khi lng kim loi thu c catot l A. 12g B. 6,4g C. 17,6g D. 7,86 g Cu 47. Hn hp X gm C2H5OH v C4H9OH. Khi un nng 0,03 mol hn hp X 140 0C c H2SO4 c lm xc tc thu 0,742g ete. Tch ly phn cha phn ng (60% lng ancol c phn t khi ln, 40% lng ancol c phn t khi nh) un 1800C thu V lit (ktc) hn hp 2 olefin. Gi tr ca V l A. 0,3584 B. 2,2400 C. 3,1360 D. 4,4800 Cu 48. Cho 13,6g mt cht hu c X (cha C, H, O) tc dng va vi 300 ml dd AgNO 3 2M trong NH3 thu c 43,2g Ag. X c cng thc cu to l A. CH2= C = CH CHO B. CH3-CH2-CHO C. HC C CH2-CHO D. HC C CHO Cu 49. Cho m gam hn hp X gm FeO, Fe2O3 v Fe3O4 tc dng va vi dung dch H2SO4 long d thu c c dung dch B. C cn dung dch B c 55,2 gam mui khan. Nu cho dung dch B tc dng vi Cl2 d th c 58,75 gam mui. Gi tr ca m l A.39,2 B. 46,4 C. 23,2 D. 15,2 Cu 50. ha tan hon ton 10 gam bt hn hp Fe, Mg, Zn cn 100 ml dung dch hn hp 2 axit H 2SO4 v HCl c nng tng ng l 0,8M v 1,2M. Sau khi phn ng xong, ly 1/2 lng kh sinh ra cho i qua ng s ng a gam CuO nung nng (phn ng hon ton). Sau khi phn ng kt thc trong ng cn li 14,08 gam cht rn. Khi lng a l A. 25,20 B. 15,20 C. 14,20. D. 15,36 B S 17 Cu 1: S so snh no sau y ng vi chiu tng dn tnh axit ? A. C6H5OH < p-CH3-C6H4OH< p-O2N-C6H4OH< CH3COOH B. p-CH3-C6H4OH < C6H5OH < CH3COOH < p-O2N-C6H4OH. C. p-CH3-C6H4OH < C6H5OH < p-O2N-C6H4OH< CH3COOH D. C6H5OH < p-CH3-C6H4OH < CH3COOH < p-O2N-C6H4OH Cu 2: Dn V lt ( ktc) hn hp X gm axetilen v hiro i qua ng s ng bt Ni nung nng, thu c kh Y. Dn kh Y vo lng d AgNO 3 trong dd NH3 thu c 36 gam kt ta. Kh i ra khi dung dch phn ng va vi 32 gam brom v cn li kh Z. t chy hon ton kh Z thu c 2,24 lt kh CO 2 (ktc) v 4,5 gam nc. Gi tr ca V bng : A. 13, 44 lt B. 15,68 lit C. 17,92 lt D. 11, 2 lt Cu 3: Oxi ha hon ton m gam hai ancol n chc, bc mt, mch h, ng ng lin tip nhau bng CuO d, nung nng thu c hn hp hi X c t khi hi so vi H 2 l 13,75. X lm mt mu va 100ml dung dch Br21,5M. Gi tr ca m l : A. 10,4 B. 3,9 C. 7,4 D. 8,6 Cu 4: Cho m gam hn hp NaBr, NaI phn ng ht vi dd H 2SO4 c nng thu c hn hp kh X k thng. k thch hp, X phn ng va vi nhau to thnh 9,6 gam cht rn mu vng v 1 cht lng khng lm i mu qu tm. Gi tr ca m bng : A. 50,6 B. 240,0 C. 404,8 D. 260,6. Cu 5: Cho cc cht sau : alanin ; anilin ; glixerol ; ancol etylic ; axit axetic ; trimetyl amin ; etyl amin ; benzyl amin; glyxin ; p-Toluiin( p- CH3C6H4NH2). S cht tc dng vi NaNO 2/HCl nhit thng c kh thot ra l: A. 3 B. 5 C. 4 D. 6 Cu 6: Bit hng s cn bng ca phn ng este ho gia axit axetic v ancol etylic bng 4. Nu cho 0,625 mol axit axetic tc dng vi 1 mol ancol etylic (c xc tc H2SO4 c) th khi t n trng thi cn bng, hiu sut phn ng este ho l bao nhiu A. 66,7% B. 62,5% C. 80,0% D. 82,5% Cu 7: Mt - aminoaxit c cng thc phn t l C 2H5NO2, khi t chy 0,1 mol oligopeptit X to nn t aminoaxit th thu c 12,6 gam nc.Vy X l:
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Ti liu n thi i hc nm 2012 -2013 A. ipeptit B. tetrapeptit C. tripeptit D. Pentapeptit Cu 8: Cho hp cht P- HO-C6H4-CH2OH tc dng vi lng d axit axetic c H2SO4 c lm xc tc, un nng phn ng xy ra vi hiu sut 100%. Sn phm to ra l: A. CH3-COO-C6H4-CH2OH B. HO-C6H4-CH2OOC-CH3 C. CH3-COO-C6H4-CH2OOCCH3 D. hn hp gm tt c cc cht trn. Cu 9: Hn hp M gm anken X v hai amin no, n chc, mch h Y, Z (M Y < MZ). t chy hon ton mt lng M cn dng 21 lt O2 sinh ra 11,2 lt CO2 (cc th tch kh u o ktc). Cng thc ca Y l : A. CH3NH2. B. CH3CH2CH2NH2. C. C2H5NH2. D. CH3CH2NHCH3. Cu 10: Cho 6,16 lit kh NH3 v V ml dd H 3PO4 0,1M phn ng ht vi nhau thu c dd X. X phn ng c vi ti a 300 ml dd NaOH 1M. Khi lng mui khan c trong X bng : A. 147 ,0 g B. 14,9 g C. 13,235 g. D. 14,475 g Cu 11: Bnh kn c V=0,5 lt cha 0,5 mol H2 v 0,5 mol N2 t0C khi t ti cn bng c 0,2 mol NH3to thnh . hiu sut tng hp NH3 t 90% cn phi thm vo bao nhiu mol N2 ? A. 25 B. 5 C. 57,25 D. 26,25 Cu 12: Thc hin cc th nghim sau y: (1) Sc kh C2H4 vo dung dch KMnO4 (2) Cho NaHCO3 vo dung dch CH3COOH (3) Chiu sng hn hp kh metan v clo (4) Cho glucoz tc dng vi Cu(OH)2 iu kin thng (5) un etanol vi H2SO4 c 1400C (6) un nng hn hp triolein v hiro (vi xc tc Ni) (7) Cho phenol tc dng vi dung dch NaOH (8) Cho anilin tc dng vi dung dch brom (9) Cho metyl amin tc dng vi dung dch FeCl3 (10) Cho glixerol tc dng vi Na Nhng th nghim xy ra phn ng oxi ho - kh l : A. (1), (3), (6), (8), (10) B. (1), (3), (8), (9), (10) C. (1), (3), (4), (8), (10) D. (1), (3), (5), (8), (10). Cu 13: t chy hon ton m gam mt ancol X thu c CO 2 v H2O c t l s mol tng ng l 3: 4. Th tch O2 cn dung t chy X bng 1,5 ln th tch kh CO 2thu c ( cng iu kin ). Mt khc cho 27,6 gam X tc dng vi Na (d) th thu c V lt H2 (ktc). Gi tr ca V l: A. 10,08 B. 5,152 C. 10,304 D. 6,72. Cu 14: Sc kh CO2 vo cc dung dch ring bit cha cc cht: Na[Al(OH) 4], NaOH d, Na2CO3, NaClO, Na2SiO3 ,CaOCl2, Ca(HCO3)2, CaCl2. S phn ng ho hc xy ra l: A. 7 B. 6 C. 5 D. 8 Cu 15: Cho 8,0 gam mt ankan X phn ng ht vi clo chiu sng sinh ra 2 cht hu c Y v Z ( d hiY/H2 < dhiZ/H2 < 43) . Sn phm ca phn ng cho i qua dd AgNO 3 d thu c 86,1 gam kt ta. T l mol Y : Z bng : A. 4 : 1 B. 1:4 C. 2:3 D. 3:2 Cu 16: Mt hn hp A gm 3 cht hu c n chc c s mol bng nhau gm CH 2O; H2CO2 ; C2H4O2 u c phn ng vi dung dch nc Br2. Cho 0,3 mol hn hp A tc dng vi dung dch AgNO 3/NH3 d thu c m gam kt ta. Gi tr m ? A. 86,4 g B. 64,8 g C. 43,2 g D. 21,6 g Cu 17: Hp th ht 4,48 lt buta-1,3-ien (ktc) vo 250 ml dung dch Br 2 1M, k thch hp n khi Br 2 mt mu hon ton thu hn hp lng X, trong khi lng sn phm cng 1,4 gp 4 ln khi lng sn phm cng 1,2. Khi lng sn phm cng 1,2 trong X l: A. 12,84 gam B. 16,05 gam C. 1,61 gam D. 6.42 gam Cu 18: t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH) 2 (d). Sau phn ng thu c 18 gam kt ta v dung dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban u thay i nh th no? A. Gim 7,38 gam. B. Tng 2,70 gam. C. Gim 7,74 gam. D. Tng 7,92 gam. Cu 19:Cho 20,80 gam hn hp X gm Fe, FeS, FeS 2, S tc dng vi dung dch HNO 3 c nng d thu c V lt kh NO2 (l sn phm kh duy nht, o ktc) v dung dch A. Cho A tc dng vi dung dch Ba(OH) 2 d thu c 91,30 gam kt ta. Vlt kh NO2 v s mol HNO3 cn dng oxi ha hon ton hn hp X ln lt l : A. 53,76 (lt) ; 3,0 (mol) B. 17,92(lt) ; 3,0 (mol) C. 17,92(lt) ; 1,5 (mol) D. 53,76 (lt) ; 2,4 (mol)

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Ti liu n thi i hc nm 2012 -2013 Cu 20: Mt cht hu c mch h, khng phn nhnh ( ch cha C, H, O). Trong phn t X ch cha nhm chc c nguyn t H linh ng, X c kh nng ha tan Cu(OH)2. Khi cho X tc dng vi Na th s mol kh sinh ra bng s mol X phn ng. Bit X c khi lng phn t l 90 vC. S cng thc cu to ph hp X l: A. 7 B. 6 C. 5 D. 4 Cu 21: Xt cn bng trong bnh kn c th tch khng i X (kh) 2Y (kh) Ban u cho 1 mol kh X vo bnh, khi t cn bng th thy - 350C trong bnh c 0,730 mol X - 450C trong bnh c 0,623 mol X Pht biu no sau y khng ng ? A. Thm Y vo hn hp cn bng th lm cho cn bng chuyn dch theo chiu nghch. B. Khi tng p sut, cn bng chuyn dch theo chiu nghch. C. Phn ng thun l phn ng to nhit. D. Phn ng thun l phn ng thu nhit. X Y Z T CH4O.Vi Y, Z, T u c s Cu 22: Cho s sau :C2H6O nguyn t cacbon 2. Hy cho bit X c CTPT l : A. C2H4O2 B. C2H4O C. C2H4 D. A,B,C u ng. Cu 23: Mt chn s c khi lng m1 gam. Cho vo chn m2 gam mt hp cht X ri nung chn trong khng kh n khi lng khng i. ngui chn v cn li , thy nng m3 gam vi m3 > m1 . Trong s cc cht: NH4NO3 , NaNO3 , NH4Cl, Br2 , KHCO3 , Fe, Fe(OH)2 , FeS2 , s cht tho mn X l : A. 3. B. 4 C. 5 D. 6 Cu 24: C cc phn ng sau: t0 t0 (1) poli(vinylclorua) +Cl2 (2) Cao su thin nhin + HCl
t OH t (3). Cao su BuNa S + Br2 (4) poli(vinylaxetat) + H2O + 0 H t (5) Amiloz + H2O Phn ng gi nguyn mch polime l A. (1), (2), (3) B. (1), (2), (3), (4) C. (1), (2),(5) D. (1),(2),(3),(4),(5) Cu 25: Cho m gam Fe tan ht trong 400 ml dung dch FeCl 3 1M thu c dung dch Y. C cn Y thu c 68,92 gam cht rn khan. ha tan ht m gam Fe trn cn ti thiu bao nhiu ml dung dch hn hp H 2SO4 0,2M v Fe(NO3)3 0,025M (sn phm kh N+5 l NO duy nht) ? A. 280 ml B. 400 ml. C. 200 ml D. 560 ml Cu 26: t chy hon ton 0,1 mol hp cht X c cng thc HOOC-(CH 2)n-COOH, cho sn phm chy vo bnh nc vi trong thu c 30 gam kt ta. Y l mt ru no n chc khi b un nng vi H 2SO4 c th to ra olefin. t chy hon ton mt este a chc to bi X v Y c t l khi lng CO 2 : H2O tng ng l 176 : 63. Vy n c gi tr bng: A. 2 B. 0 C. 1 D. 3 Cu 27: Cho cc polime sau: t nilon-6,6 (a); poli(ure-fomanehit) (b); t nitron (c); teflon (d); poli(metyl metacrylat) (e); poli(phenol-fomanehit) (f); capron (g). Dy gm cc polime c iu ch bng phn ng trng hp l : A. (b), (c), (d). B. (c), (d), (e),(g). C. (a), (b), (f). D. (b), (d), (e). Cu 28: Chn pht biu chnh xc: A. Khi in phn dung dch MgCl2 vi in cc tr, c mng ngn th gim khi lng ca dung dch sau in phn khc tng khi lng H2 v Cl2 thot ra (b qua tan ca kh v s bay hi ca nc). B. Hai mui tc dng c vi nhau (trong dung dch) th sn phm lun l 2 mui mi. C. Kim loi c tnh kh mnh hn lun y c kim loi c tnh kh yu hn ra khi dung dch mui. D. Hai axit khng th tc dng c vi nhau Cu 29: Este X to bi ancol no n h v axit n h khng no cha hai ni i trong gc. t chy m gam X 1 thu 15,232 lt kh CO2(.k.c) v 11,52 gam nc.Th tch NaOH 0,1M cn x phng ho hon ton lng X 4 trn l: A. 200 ml B. 250 ml C. 100ml D. 50 ml
0 0

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Ti liu n thi i hc nm 2012 -2013 Cu 30: Cho 0,3 mol hn hp kh X gm HCHO v C 2H2 tc dng hon ton vi lng d dung dch AgNO 3 trong NH3 to ra 91,2 gam kt ta. Nu cho ton b lng X trn vo bnh ng dung dch brom trong CCl 4 th khi lng brom phn ng ti a l: A. 40 gam. B. 80 gam C. 96 gam. D. 64 gam. Cu 31: Ha tan hon ton 9,2 gam hn hp X gm hai kim loi kim vo 400 ml dung dch HCl 0,5M thu c dung dch Y cha 4 cht tan c nng mol/l bng nhau. Hai kim loi trong X l: A. Li v Na. B. Li v Rb. C. Li v K. D. Na v K Cu 32: Cho m gam hn hp X gm hai -aminoaxit cng s mol, u no mch h, c 1 nhm amino v 1 nhm cacboxyl tc dng vi dd cha 0,44 mol HCl c dd Y. Y td va ht vi dd cha 0,84 mol KOH. t chy hon ton m gam X ri hp th sn phm chy bng dd KOH d thy khi lng bnh tng 65,6 g. CTCT 2 cht trong X l : A. H2NCH2COOH v H2NCH(CH3)COOH B. H2NCH(C2H5)COOH v H2NCH2CH2 COOH C. H2NCH(C2H5)COOH v H2NCH(CH3)COOH D. H2NCH2COOH v H2NCH(C2H5)COOH. Cu 33: Nung hn hp gm 6,4 gam Cu v 54 gam Fe(NO 3)2 trong bnh kn, chn khng. Sau phn ng hon ton thu c hn hp kh X. Cho X phn ng ht vi nc, thu c 2 lt dung dch Y. pH ca dung dch Y l : A. 1,3. B. 1. C. 0,664. D. 0,523 Cu 34: t chy hon ton mt amino axit c dng NH 2-[CH2]n-COOH cn x mol O2, sau phn ng thu c y mol CO2 v z mol H2O, bit 2x = y + z. Cng thc ca amino axit l A. NH2-[CH2]4-COOH B. NH2-CH2-COOH C. NH2-[CH2]2-COOH D. NH2-[CH2]3-COOH Cu 35: Dn hn hp X gm 0,05 mol C 2H2; 0,1 mol C3H4 v 0,1 mol H2 qua ng cha Ni nung nng mt thi gian thu c hn hp Y gm 7 cht. t chy hon ton Y ri cho sn phm chy hp th ht vo 700 ml dung dch NaOH 1M, thu c dung dch Z. Tng khi lng cht tan trong Z l: A. 38,2 B. 45,6 C. 40,2 D. 35,8 ki m 2 2 + 2Cr O 4 + 2H Cu 36: Cho cn bng sau: Cr2 O 7 + H2O axit Thm axit HCl c, d vo dung dch K2CrO4 th dung dch chuyn thnh. A. mu da cam B. mu vng C. mu xanh D. khng mu. Cu 37: Phng th nghim b nhim lng nh kh Cl2. Phng php tt nht lai b kh c hi ny l: A. h l ng dung dch NH3 c B. Phun dung dch KBr C. Phun dung dch NaOH D. Phun dung dch Ca(OH)2. Cu 38: Cho cc phn ng sau : (1) F2 + H2O (6) in phn dung dch CuCl 2 (2) Ag + O3 (7) Nhit phn KClO3 (3) KI + H2O + O3 (8) in phn dung dch AgNO3 (4) Nhit phn Cu(NO3) 2 (9) Nhit phn H2O2 (5) in phn dung dch H2SO4 S phn ng m sn phm to ra c O2 l A. 5. B. 7 C. 6. D. 8 Cu 39: t chy hon ton cc cht sau : FeS2, Cu2S, Ag2S, HgS, ZnS, MgCl2 trong oxi (d). Sau cc phn ng xy ra hon ton, s phn ng to ra oxit kim loi l A. 3 B. 2. C. 4. D. 5. Cu 40: Ha tan hon ton hn hp gm cc kim loi Mg, Al, Zn, Fe, Ni, Cu, Ag vo dung dch HNO 3 long (d), thu c dung dch X. Cho X tc dng vi dung dch NaOH (d), thu c kt ta Y. em Y tc dng vi dung dch NH3 (d), n phn ng hon ton thu c kt ta Z. S hiroxit c trong Y v Z ln lt l : A. 7; 4. B. 3; 2. C. 5; 2. D. 4; 2. Cu 41: C bao nhiu nhn xt sau y l chung cho c glucoz v fructoz (1) C phn ng thu phn (2) Dung dch mi cht ha tan c Cu(OH)2 to dung dch mu xanh lam (3) C nhm OH v nhm CHO trong phn t (4) C phn ng trng gng (5) Hiro ha (t0, xt Ni) khng thu c sobitol (6) C nhiu trong mt ong
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Ti liu n thi i hc nm 2012 -2013 (7) Tc dng vi metanol khi c mt axit HCl lm xc tc A. 7 B. 6 C. 5 D. 4 Cu 42: C cc th nghim: (1) Nh dd NaOH d vo dd hn hp {KHCO3 v CaCl2}. (2) un nng nc cng ton phn. (3) un nng nc cng vnh cu. (4) Nh dd Ba(OH)2 d vo dd KAl(SO4)2.12H2O. (5) Cho dd Na3PO4 vo nc cng vnh cu. (6) Cho dung dch NaOH d vo dung dch CrCl2. (7) Cho CO2 d vo dung dch hn hp Ba(OH)2 v NaOH. (8) Cho AlCl3 n d vo dung dch K[Al(OH)4] C ti a my th nghim thu c kt ta? A. 6 B. 5 C. 4 D. 7. Cu 43: Cho cc cht: NH4Cl (1), Na2CO3 (2), NaF(3), H2CO3 (4), KNO3 (5), HClO(6), KClO(7). Trong cc cht trn, s cht m phn t va c lin kt ion va c lin kt cng ha tr l : A. (2), (5), (7). B. (1), (2), (6). C. (2),(3) (5), (7). D. (1), (2), (5), (7). Cu 44: Tm nhn xt sai trong cc nhn xt sau y: A. C cc nguyn t ha hc: 9X; 13M; 15Y; 17R. Th t cc nguyn t c m in tng dn l : M < Y < X.< R. B. C cc nguyn t: K (Z = 19), N (Z = 7), Si (Z = 14), Mg (Z = 12). Cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l: K, Mg, Si, N. C. C ba loi hp cht cao phn t l PVC, thu tinh hu c, nilon-6,6. Loi polime km bn v mt ho hc (d b axit v kim tc dng) l nilon-6,6 D. C th iu ch c nc clo nhng khng th iu ch c nc flo Cu 45: in phn dung dch cha a mol NaCl v b mol CuSO4 (a < b) vi in cc tr mng ngn xp. Khi ton b lng Cu2+ b kh ht th thu c V lt kh anot. Biu thc lin h gia V vi a v b l: A. V= 11,2(b-a) B. V= 5,6(a+2b). C. V= 22,4(b-2a) D. V= 11,2a Cu 46: Ho tan 9,6 gam bt Cu bng 200 ml dd hn hp HNO 3 1,5 M v H2SO4 0,5 M .Sau khi phn ng xy ra hon ton thu c kh NO v dung dch A .C cn cn thn dung dch A th khi lng mui khan thu c l : A. 21,15 g B. 25,4 g C. 24 g D. 28,2 g. Cu 47: Cho hn hp A gm 0,15 mol Mg v 0,35 mol Fe phn ng vi V lt dd HNO 3 1 M thu c dung dch B v hn hp C gm 0,05 mol N2O ; 0,1 mol NO v cn li 2,8 gam kim loi . Gi tr ca V l : A. 1,22 . B. 1,15 . C. 0,9 . D. 1,1 Cu 48: un nng 2 cht hu c X, Y c cng thc phn t l C 5H8O2 trong dung dch NaOH thu c hn hp 2 mui natri ca 2 axit C 3H6O2 (X1) v C3H4O2(Y1) v 2 sn phm khc tng ng l X 2 v Y2. Tnh cht ha hc no ging nhau gia X2 v Y2. A. B oxi ha bi KMnO4 trong mi trng axit mnh. C. B kh bi H2. B. B oxi ha bi dung dch AgNO3 trong NH3. D. Tc dng vi Na. Cu 49: Cho cc dung dch : glucoz, fructoz, mantoz, saccaroz, phenol, axit fomic, axetandehit, ancol anlylic, anilin. S dung dch trn lm mt mu dung dch brom trong dung mi nc l: A. 5 B. 7 C. 8 D. 6 Cu 50: nhn bit ba axit c, ngui HCl, H2SO4, HNO3 ng ring bit trong ba l b mt nhn, c th dng ha cht A. Al. B. CuO. C. Fe D. NaOH. B S 18 Cu 1. Thy phn hon ton 314,25 gam protein X thu c 877,5 gam valin. Bit rng phn t khi ca X l 6285. S mt xch Val trong phn t X l A. 192. B. 197. C. 20. D. 150. Cu 2. Cho cn bng ha hc sau: N2 (k) + 3H2 (k) 2NH3 (k) ; H < 0.
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Ti liu n thi i hc nm 2012 -2013 Cho cc bin php: (1) Gim nhit ; (2) Tng p sut chung ca h phn ng; (3) Dng thm cht xc tc Fe; (4) Gim nng ca NH3. Nhng bin php no lm cho cn bng trn chuyn dch theo chiu thun? A. (2), (4). B. (1), (2), (4). C. (1), (2). D. (1), (2), (3). Cu 3. Cho s bin ha: CH4 XY CH3COOH. tha mn vi s bin ha trn th Y l A. C2H4 hoc C2H5OH. B. CH3CHO hoc CH3CH2Cl. C. CH3CHO. D. C2H5OH. Cu 4. phn ng hon ton vi m gam metyl salixylat cn va 1,08 lt dung dch NaOH 1M. Gi tr ca m l A. 97,2. B. 82,08. C. 64,8. D. 164,16. Cu 5. Hn hp X gm Fe2(SO4)3, FeSO4 v Al2(SO4)3. Thnh phn phn trm v khi lng ca oxi trong X l 49,4845%. Cho 97 gam X tc dng vi dung dch NH3 d thu c kt ta c khi lng l A. 31,375 gam. B. 50,5 gam. C. 76 gam. D. 37,75 gam. Cu 6. Nhit phn hon ton 44,1 gam hn hp X gm AgNO3 v KNO3 thu c hn hp kh Y. Trn Y vi a mol NO2 ri cho ton b vo nc ch thu c 6 lt dung dch (cha mt cht tan duy nht) c pH = 1. Gi tr ca a l A. 0,5. B. 0,4. C. 0,3. D. 0,2. Cu 7. Thc hin cc th nghim sau: (a) un nng hn hp bt Fe v I2. (b) Cho Fe vo dung dch HCl. (c) Cho Fe(OH)2 vo dung dch HNO3 long, d. (d) t dy st trong hi brom. (e) Cho Fe3O4 vo dung dch H2SO4 long, d. S th nghim to ra mui st (II) l A. 1 B. 3 C. 2 D. 4 Cu 8. Cht hu c X c cng thc phn t C5H11Cl v ph hp vi s bin ha: XY (ancol bc I)ZT (ancol bc II)E F (ancol bc III). Y, Z, T, E, F l cc sn phm hu c chnh c to ra. Tn gi ca X l A. 1- Clo-3- metylbutan. B. 4- Clo - 2- metylbutan. C. 1- Clo-2- metylbutan. D. 2- Clo-3- metylbutan. Cu 9. Pht biu no sau y l ng? A. Khi un nng propyl clorua vi KOH/C2H5OH th sn phm hu c chnh thu c l ancol propylic. B. Axit benzoic tham gia phn ng th brom d hn so vi phenol. C. Axeton c th iu ch c bng cch nhit phn canxi axetat. D. Phenyl axetat l sn phm ca phn ng gia l axit axetic v phenol. Cu 10. t chy hon ton 54 gam hn hp X gm axit fomic, axit axetic, axit acrylic, axit oxalic v axit aipic thu c 39,2 lt CO2 (ktc) v m gam H2O. Mt khc, khi cho 54 gam hn hp X phn ng hon ton vi dung dch NaHCO3 d, thu c 21,28 lt CO2 (ktc). Gi tr ca m l A. 21,6. B. 46,8. C. 43,2. D. 23,4. Cu 11. Cho cc pht biu sau: (a) Khi t chy hon ton a mol mt hirocacbon X bt k thu c b mol CO 2 v c mol H2O, nu b - c = a th X l ankin. (b) Trong thnh phn hp cht hu c nht thit phi c hiro. (c) Trong thnh phn ca gc t do phi c t nht hai nguyn t. (d) Mui n d tan trong benzen. (e) trng thi rn, phenol khng tn ti lin kt hiro lin phn t. (g) Trong phn t canxi axetat ch c lin kt cng ha tr. (h) iu kin thng, cc este u trng thi lng. (i) Trong phn t hp cht hu c cha (C, H, O) th s nguyn t H phi l s chn. S pht biu sai l A. 7. B. 8. C. 5. D. 6. Cu 12. Khi so snh 2 oxit Al2O3 v Cr2O3, pht biu khng ng l: A. Hai oxit u c hiroxit tng ng l cht lng tnh. B. Hai oxit u khng th hin tnh kh khi tc dng vi dung dch HNO3 c, nng.
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Ti liu n thi i hc nm 2012 -2013 C. Hai oxit u tan c trong dung dch NaOH long, ngui. D. Oxi trong 2 oxit u c in ha tr bng 2-. Cu 13. Cho 34 gam hn hp X gm 2 este n chc v u thuc loi hp cht thm (t khi hi ca X i vi O2 lun bng 4,25 vi mi t l s mol gia 2 este) tc dng va vi 175 ml dung dch NaOH 2M. C cn dung dch sau phn ng thu c hn hp Y gm 2 mui khan. Thnh phn phn trm v khi lng ca 2 mui trong Y l A. 55,43% v 44,57%. B. 56,67% v 43,33%. C. 46,58% v 53,42%. D. 35,6% v 64,4%. Cu 14. Mt loi cao su thin nhin c lu ha c cha 2,05% lu hunh v khi lng. Hi c bao nhiu mt xch isopren c mt cu ni isunfua -S-S-, gi thit rng S thay th nguyn t H nhm metylen trong mch cao su? A. 46. B. 47. C. 45. D. 23. Cu 15. Pht biu khng ng l: A. Vt liu compozit, vt liu nano, vt liu quang in t l nhng vt liu mi c nhiu tnh nng c bit. B. Cc kh SO2, NO2 gy ma axit, kh CO2 gy hiu ng nh knh cn hp cht CFC gy thng tng ozon. C. Cc cht: Penixilin, amphetamin, erythromixin thuc loi thuc khng sinh, cn: Seduxen, moocphin, ampixilin thuc loi cht gy nghin. D. Vic s dng cc cht: Fomon, ure, hn the, phn m trong bo qun v ch bin thc phm l vi phm v sinh an ton thc phm. Cu 16. Cho 5,528 gam hn hp X gm Fe v Cu (nFe : nCu = 18,6) tc dng vi dung dch cha 0,352 mol HNO3 thu c dung dch Y v kh NO (sn phm kh duy nht). Tin hnh in phn dung dch Y vi in cc tr, cng dng in I = 3,6345 ampe trong thi gian t giy thy khi lng cactt tng 0,88 gam (gi thit kim loi sinh ra bm ht vo catt).Gi tr ca t l A. 1252. B. 797. C. 2337. D. 2602. Cu 17. Hn hp X gm mt anehit n chc, mch h v mt ankin (phn t ankin c cng s nguyn t H nhng t hn mt nguyn t C so vi phn t anehit). t chy hon ton 1 mol hn hp X thu c 2,4 mol CO2 v 1 mol nc. Nu cho 1 mol hn hp X tc dng vi dung dch AgNO 3/NH3 th khi lng kt ta thu c ti a l A. 301,2 gam. B. 144 gam. C. 308 gam. D. 230,4 gam. Cu 18. t chy hon ton m gam hn hp Y gm hai xeton Y1, Y2 (c t l s mol tng ng l 5:1) thu c 9,856 lt (ktc) CO2 v 7,92 gam H2O. Mt khc, nu cho m gam Y tc dng ht vi H 2 (Ni, to) ri cho ton b sn phm to thnh tc dng vi kali (d) thy thot ra 1,344 lt H2 (ktc). Cng thc phn t ca Y2 l A. C6H12O. B. C7H14O. C. C4H8O. D. C5H10O. Cu 19. Cho cc cht: isobutan, isobutilen, isopren, vinyl axetilen, ivinyl, metylxiclopropan, toluen, naphtalen, xiclohexan, xiclohexen. Trong s cc cht trn, s cht phn ng c vi nc brom l A. 7. B. 6. C. 4. D. 5. Cu 20. Thy phn hon ton m gam hn hp X gm saccaroz v mantoz thu c dung dch Y. Cho Y tc dng vi lng d dung dch AgNO 3 trong NH3 thu c 0,2 mol Ag. Mt khc, thy phn m gam hn hp X mt thi gian (hiu sut thy phn mi cht u l 80%) thu c dung dch Z. Cho Z tc dng vi lng d dung dch AgNO3 trong NH3 thu c 0,168 mol Ag. Thnh phn phn trm v khi lng ca saccaroz trong hn hp l A. 55%. B. 40%. C. 45%. D. 60%. Cu 21. Hin tng xy ra khi nh vi git dung dch KOH vo dung dch Na2Cr2O7 l A. dung dch chuyn t khng mu sang mu da cam. B. dung dch chuyn t mu vng thnh khng mu. C. dung dch chuyn t mu da cam sang mu vng. D. dung dch chuyn t mu vng sang mu da cam. Cu 22. Cho t t tng git ca dung dch cha b mol HCl vo dung dch cha a mol Na 2CO3 thu c V lt kh CO2. Ngc li, cho t t tng git ca dung dch cha a mol Na 2CO3 vo dung dch cha b mol HCl thu c 2V lt kh CO2 (cc th tch kh o cng iu kin). Mi quan h gia a v b l A. a = 0,8b. B. a = 0,5b. C. a = 0,35b. D. a = 0,75b. Cu 23. Cho phn ng: ure + NaBrO N2 + CO2 + NaBr + H2O. Sau khi cn bng phng trnh ho hc, tng h s nguyn ti gin ca cc cht phn ng l A. 4. B. 2. C. 11. D. 7. Cu 24. Khi in phn dung dch CuSO4 (cc dng lm bng ng, cc m lm bng than ch) th A. cc m xy ra qu trnh oxi ha ion Cu2+ v cc dng xy ra qu trnh kh Cu.
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Ti liu n thi i hc nm 2012 -2013 B. cc m xy ra qu trnh kh ion Cu2+ v cc dng xy ra qu trnh oxi ha H2O. C. cc m xy ra qu trnh kh ion Cu2+ v cc dng xy ra qu trnh oxi ha Cu. D. cc m xy ra qu trnh oxi ha ion Cu2+ v cc dng xy ra qu trnh kh H2O. Cu 25. Khi cho 200 ml dung dch X gm AlCl 3 a mol/l v NaCl b mol/l (a : b = 4 : 3) tc dng vi 325 ml dung dch KOH 2M, sau khi cc phn ng kt thc thu c 11,7 gam kt ta. Nu cho 80 ml dung dch X tc dng vi dung dch AgNO3 d th thu c kt ta c khi lng l A. 43,05 gam. B. 45,92 gam. C. 107,625 gam. D. 50,225 gam. Cu 26. Cc hp cht hu c mch h, bn X v Y c cng thc phn t tng ng l C 2H4O2 v C3H6O. X tc dng c vi Na, lm mt mu nc brom v c phn ng trng bc. Y lm mt mu nc brom nhng khng c phn ng trng bc. Cc cht X, Y ln lt l A. HO-CH2-CHO v CH2=CH-CH2-OH. B. CH3COOH v CH2=CH-CH2-OH. C. HCOOCH3 v CH3-CO-CH3. D. HO-CH2-CHO v CH3-CH2-CHO. Cu 27. Cho cc phn ng sau: AgNO3 + Fe(NO3)2 Ag + Fe(NO3)3. Cu + Fe(NO3)3 Cu(NO3)2 + Fe(NO3)2. Fe + Cu(NO3)2 Fe(NO3)2 + Cu. Dy c sp xp theo chiu tng dn tnh kh l: A. Fe2+, Cu, Ag, Fe. B. Fe2+,Ag, Cu, Fe. C. Ag, Cu, Fe2+, Fe. D. Ag, Fe2+, Cu, Fe. Cu 28. Pht biu no sau y l sai? A. Tnh axit ca HF yu hn tnh axit ca HI. B. Nhit si ca hiro florua cao hn nhit si ca hiro clorua. C. Tnh kh ca HCl mnh hn tnh kh ca HBr. D. Bn knh ca ion F- nh hn bn knh ca ion Cl-. Cu 29. Cho 36,5 gam hn hp X gm hiroquinon, catechol v axit axetic tc dng vi kali (d) thu c 7,28 lt (ktc) kh H2. Thnh phn phn trm v khi lng ca axit axetic trong hn hp X l A. 32,877%. B. 41,096%. C. 14,438%. D. 24,658%. Cu 30. Dy gm cc kim loi c cng kiu mng tinh th lp phng tm din l: A. Ca, Sr, Cu. B. Mg, Cr, Fe. C. Ca, Sr, Ba. D. Be, Cr, Cu. Cu 31. m gam phi bo st ngoi khng kh, sau mt thi gian thu c hn hp X gm 4 cht c khi lng l 20 gam. Ha tan ht X trong 500 ml dung dch HCl nng a mol/l thy thot ra 2,24 lt (ktc) H 2 v dung dch Y (khng c HCl d). Cho tip dung dch HNO3 ti d vo dung dch Y thu c dung dch Z (cha FeCl3, Fe(NO3)3 v HNO3 d) v 2,24 lt (ktc) NO duy nht. Gi tr ca m v a ln lt l A. 15,68 v 0,4. B. 15,68 v 1,48. C. 16,8 v 0,4. D. 16,8 v 1,2. Cu 32. Cho 6,125 gam KClO3 tc dng vi dung dch HCl c (d), sau khi phn ng xy ra hon ton th s mol HCl b oxi ha l A. 0,25. B. 0,3. C. 0,15. D. 0,05. Cu 33. Cho cc pht biu sau: (a) C th dng nc brom phn bit saccaroz v mantoz. (b) C th phn bit saccaroz v mantoz bng phn ng vi dung dch AgNO3 trong NH3. (c) Trong dung dch, saccaroz v mantoz u ha tan Cu(OH)2 ( to thng) cho dung dch mu xanh lam. (d) Trong dung dch, saccaroz tn ti ch yu dng mch h. (e) Trong mi trng baz, saccaroz v mantoz c th chuyn ha ln nhau. (g) Trong phn t saccaroz c nhm -OH hemiaxetal. S pht biu ng l A. 5. B. 4. C. 3. D. 2. Cu 34. Tin hnh cc th nghim sau: (a) Cho dung dch Ba(OH)2 vo dung dch NaHCO3. (b) Cho dung dch Al2(SO4)3 ti d vo dung dch NaAlO2 (hoc dung dch Na[Al(OH)4]. (c) Sc kh CH3NH2 ti d vo dung dch FeCl3. (d) Sc kh propilen vo dung dch KMnO4. (e) Sc kh CO2 vo dung dch Na2SiO3. (g) Sc kh H2S vo dung dch SO2. (h) Sc kh NH3 ti d vo dung dch AgNO3.
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Ti liu n thi i hc nm 2012 -2013 Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta? A. 6 B. 3 C. 5 D. 4 Cu 35. Cho dy cc cht: Cr(OH)3, CrO3, ZnO, Ca(HCO3)2, Al(OH)3, CrO, CO2, NO2, P2O5, N2O5, PCl5, Al4C3. S cht tc dng c vi dung dch NaOH long, ngui l A. 10. B. 11. C. 9. D. 12. Cu 36. Trong cc th nghim sau: (a) Cho kh O3 tc dng vi dung dch KI. (b) Nhit phn amoni nitrit. (c) Cho NaClO tc dng vi dung dch HCl c. (d) Cho kh H2S tc dng vi dung dch FeCl3. (e) Cho kh NH3 tc dng vi kh Cl2. (g) Cho dung dch H2O2 tc dng vi dung dch cha KMnO4 v H2SO4 (long). (h) Sc kh O2 vo dung dch HBr. (i) Cho NaI tc dng vi dung dch axit H2SO4 c, nng. (k) Cho SiO2 tc dng vi Na2CO3 nng chy. S th nghim to ra n cht l A. 5 B. 8 C. 7 D. 6 Cu 37. t chy hon ton x mol axit cacboxylic E thu c y mol CO 2 v z mol H2O. Bit rng x mol E tc dng va vi z mol Na2CO3 trong dung dch. Tn ca E l A. Axit etanioic. B. Axit metanoic. C. Axit hexan-1,6-ioic. D. Axit propenoic. Cu 38. X phng ha hon ton 1,89 gam mt cht bo cn 67,5 ml dung dch NaOH 0,1M. Ch s x phng ha ca cht bo l A. 378. B. 270. C. 142,86. D. 200. Cu 39. Ha tan ht 5,355 gam hn hp X gm FeCO 3 v FeS2 trong dung dch HNO3 1,25M thu c dung dch Y (cha mt cht tan duy nht) v V lt (ktc) hn hp D (ha nu ngoi khng kh) cha hai kh.Gi tr ca V l A. 1,008. B. 4,116. C. 3,864. D. 1,512. Cu 40. Cho dy cc cht: benzyl axetat, vinyl axetat,metyl fomat, anlyl clorua, phenyl fomat, isopropyl clorua, triolein. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l A. 4. B. 6. C. 5. D. 3. Cu 41. Hp cht T c to bi 4 nguyn t ca 2 nguyn t phi kim R v X (s hiu nguyn t ca R nh hn s hiu nguyn t ca X). Tng s ht mang in trong mt phn t T l 20. Pht biu sai l: A. Hp cht T c th to c lin kt hiro vi nc. B. Trong cc hp cht vi cc nguyn t khc, R c th c s oxi ha bng -1. C. trng thi kch thch, nguyn t nguyn t X c 5 electron c thn. D. Trong phn t T, nguyn t X trng thi lai ha sp3. Cu 42. Cho hn hp X gm Fe 2O3, ZnO v Fe tc dng vi dung dch H 2SO4 (long) thu c dung dch Y, phn kim loi khng tan Z v kh T. Cho Y tc dng vi dung dch NH3 d thu c kt ta A. Fe(OH)2 v Fe(OH)3. B. Fe(OH)2 v Zn(OH)2. C. Fe(OH)2. D. Fe(OH)2, Zn(OH)2 v Fe(OH)3. Cu 43. Cho isopren phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (ng phn cu to v ng phn hnh hc) ti a thu c l A. 4. B. 5. C. 3. D. 2. Cu 44. Nu t chy hon ton hn hp gm mt ancol X (mch h) v mt axit cacboxylic bt k th lun c s mol H2O nh hn hoc bng s mol CO 2. t chy 0,15 mol X ri cho sn phm chy hp th hon ton vo dung dch cha 0,25 mol Ba(OH)2 thy to thnh a gam kt ta.Gi tr ca a l A. 39,4. B. 49,25. C. 29,55. D. 9,85. Cu 45. Ha tan hn hp bt gm m gam Cu v 2,32 gam Fe 3O4 vo dung dch H2SO4 (long, rt d), sau khi cc phn ng kt thc ch thu c dung dch X. Dung dch X lm mt mu va 50 ml dung dch KMnO 4 0,1M. Gi tr ca m l A.0,62. B.0,32. C.1,6. D.0,48.

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Ti liu n thi i hc nm 2012 -2013 Cu 46. Cho 8,2 gam hn hp gm axit glutamic v tyrosin (t l mol 1:1) tc dng vi 125 ml dung dch NaOH 1M, sau khi phn ng xy ra hon ton thu c dung dch Y. C cn cn thn dung dch Y thu c m gam cht rn khan.Gi tr ca m l A. 12,3. B. 11,85. C. 10,4. D. 11,4. Cu 47. Ha tan hon ton 30 gam hn hp X gm Na, K v Ba vo dung dch HCl d thu c dung dch Y. C cn dung dch Y thu c 54,85 gam hn hp cht rn khan. Ha tan hon ton 45 gam hn hp X vo nc thu c dung dch Z. Cho t t n ht dung dch Z vo 0,4 lt dung dch ZnCl 2 1M n phn ng hon ton thu c kt ta c khi lng l A. 25,9875 gam. B. 27,225 gam. C. 34,65 gam. D. 39,6 gam. Cu 48. Thc hin cc th nghim sau: (a) Cho dung dch FeCl2 tc dng vi dung dch AgNO3 d. (b) Cho Cl2 tc dng vi toluen trong iu kin chiu sng (khng c xc tc). (c) Sc kh HI vo dung dch FeCl3. (d) Cho Fe3O4 tc dng vi dung dch HCl. (e) Sc kh axetilen vo dung dch brom trong dung mi CCl4. S th nghim xy ra phn ng oxi ha - kh l A. 3. B. 4. C. 2. D. 5. Cu 49. Cho cc phn ng sau: (a) CuO + HCl (c) (b) K2Cr2O7 + HCl (c) (c) Cu + NaNO3 + HCl (d) Zn + H2SO4 (long) (e) Mg + HNO3(long) (g) CaCO3 + HNO3 (c) (h) FeCO3 + H2SO4 (long) (i) FeSO4 + KMnO4 + H2SO4 (long) S phn ng m ion H+ ca axit ng vai tr cht oxi ha l A. 1. B. 3. C. 2. D. 4. Cu 50. Cho cc pht biu sau: (a) Dung dch natri isopropylat trong nc c th lm qu tm ha xanh. (b) Dung dch axit axetic c th ha tan c CuO to thnh dung dch c mu xanh. (c) Oxi ha ancol bc mt bng CuO (to) thu c xeton. (d) Naphtalen tham gia phn ng th brom kh hn so vi benzen. (e) Phn ng tch H2O t ancol etylic dng iu ch etilen trong cng nghip. (g) Benzen c th tham gia phn ng th v phn ng cng clo. S pht biu ng l A. 3. B. 4. C. 2. D. 5. B S 19 Cu 1: Hn hp X gm HCHO v CH3CHO c t l mol 1 : 1. un nng 7,4 gam X vi dung dch AgNO 3/NH3 (d) ti phn ng hon ton thu c m gam Ag. Gi tr ca m l A. 32,4 B. 64,8 C. 21,6 D. 43,2 Cu 2: Dy gm cc cht c xp theo chiu nhit si tng dn t tri sang phi l : A. C3H8, CH3COOH, C3H7OH, HCOOCH3 B. C3H8, HCOOCH3, C3H7OH, CH3COOH C. C3H7OH, C3H8, CH3COOH, HCOOCH3 D. C3H8, C3H7OH, HCOOCH3, CH3COOH Cu 3: Nguyn t phi kim X c hp cht kh vi H l XH 3. Trong oxit cao nht ca X c cha % khi lng X bng 43,662%. Nguyn t X l: A. N B. P C. As D. S Cu 4: Cho cc phn ng sau: (1) CaOCl2 + 2HCl c CaCl2 + Cl2 + H2O; (2) NH4Cl NH3 + HCl; (3) NH4NO3 N2O + 2H2O; (4) FeS + 2HCl FeCl2 + H2S; (5) Cl2 + 2NaBr 2NaCl + Br2; (6) C + CO2 2CO S phn ng thuc loi phn ng oxi ha kh l A. 4 B. 5 C. 6 D. 3 Cu 5: Cho dy cc cht sau y: Cl2, KH2PO4, C3H8O3, CH3COONa, HCOOH, NH3, Mg(OH)2, C6H6, NH4Cl. S cht in li trong dy l
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Ti liu n thi i hc nm 2012 -2013 A. 4 B. 6 C. 3 D. 5 Cu 6: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 trong X l A. 20%. B. 25%. C. 50%. D. 60%. Cu 7: Hp cht hu c no, mch h X ch cha C, H, O. X c khi lng mol phn t l 90 gam/mol. Cho X tc dng vi NaHCO3 th c kh bay ra. Cho X tc dng ht vi Na thu c s mol H 2 bng s mol X. S cng thc cu to ca X tha mn iu kin bi ton l: A. 4 B. 1 C. 2 D. 3 Cu 8: Cho 360 ml dung dch NaOH 1M vo 500 ml dung dch AlCl 3 aM, thu c 3m gam kt ta . Mt khc, cho 480 ml dung dch NaOH 1M vo 500 ml dung dch AlCl3 aM, thu c 2m gam kt ta. Gi tr ca a l: A. 0,28 B. 0,36 C. 0,14 D. 0,56 2+ 2+ Cu 9: Mt dung dch Y c cha 0,1mol Ca ; 0,3mol Mg ; 0,4mol Cl v y mol HCO3-. Khi c cn dung dch Y thu c m gam mui khan. Gi tr ca m l: A. 37,4 B. 49,8 C. 43,7 D. 49,4 Cu 10: Cho hp cht X tc dng vi NaOH to ra kh Y lm xanh qu tm m. Mt khc, cht X tc dng vi axit HCl to ra kh Z va lm vn c nc vi trong, va lm mt mu dung dch Brom. Cht X khng tc dng vi dung dch BaCl2. Vy cht X c th l: A. NH4HSO3 B. (NH4)2SO3 C. (NH4)2CO3 D. NH4HCO3 Cu 11: S ng phn este c cng thc phn t C 6H12O2 khi thy phn to ra ancol khng b oxi ha bi CuO l A. 1 B. 2 C. 3 D. 4 Cu 12: t chy hon ton a mol mt anehit X mch h to ra b mol CO 2 v c mol H2O (bit b=a+c). Trong phn ng trng bc, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit no sau y: A. no, hai chc. B. no, n chc. C. khng no, c hai ni i, n chc. D. khng no, c mt ni i, n chc. Cu 13: Cho axit Salixylic (X) (axit o-hiroxibenzoic) phn ng vi metanol c H 2SO4 c xc tc thu c metyl Salixylat (Y) dng lm thuc gim au. Cho 0,1 mol Y phn ng vi dung dch NaOH d . S mol NaOH tham gia phn ng l A. 0,1 B. 0,2 C. 0,3 D. 0,05 Cu 14: Cho phn ng: Al + HNO3 Al(NO3)3 + N2O + H2O H s (nguyn, ti gin) ca HNO3 trong PTHH ca phn ng trn l A. 8 B. 12 C. 24 D. 30 Cu 15: Pht biu no sau y khng ng: A. in phn dung dch NaCl, khng c mng ngn iu ch nc gia-ven. B. Phn bn phc hp l sn phm trn ln cc loi phn n theo t l khc nhau. C. Axit HCl va c tnh oxi ha, va c tnh kh. D. Khng th dp tt cc m chy Mg bng ct kh. Cu 16: Cho dy cc cht: Al2O3, NaHCO3, K2CO3, CrO3, Zn(OH)2, Sn(OH)2, AlCl3. S cht trong dy c tnh cht lng tnh l A. 7. B. 5. C. 4. D. 6. Cu 17: Phn supephotphat kp thc t sn xut c thng ch c 40% P 2O5. Vy % khi lng Ca(H2PO4)2 trong phn bn l A. 78,56%. B. 56,94%. C. 65,92%. D. 75,83%. Cu 18: S ng phn -aminoaxit c cng thc phn t C4H9O2N l A. 2 B. 3 C. 4 D. 5 Cu 19 : t chy hon ton 11,8 gam hn hp gm mt ancol no n chc v mt anehit no n chc c cng s nguyn t cacbon trong phn t thu c 13,44 lit CO 2( ktc) v 12,6 gam H2O. Cng thc cu to ca ancol v anehit l A. C2H5OH, CH3CHO B. C4H9OH, C3H7CHO C. C3H7OH, C2H5CHO D. CH3OH, HCHO Cu 20 : Trung ho 100ml dung dch cha mt axit cacboxylic X nng 0,1M cn va 16 gam dung dch NaOH 5%, thu c 1,48 gam mui. Cng thc ca X l A. HOOC-CH2-COOH B. HOOC-COOH
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Ti liu n thi i hc nm 2012 -2013 C. CH3COOH D. HOOC-CH2-CH2-COOH Cu 21: Cho m gam Al vo 100 ml dung dch cha Cu(NO 3)2 0,5M v AgNO3 0,3M sau khi phn ng kt thc thu c 5,16g cht rn . Gi tr ca m l: A. 0,24g B. 0,48g C. 0,81g D. 0,96g Cu 22: t nng mt hn hp gm Al v 16 gam Fe 2O3 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng va vi V ml dung dch NaOH 1M sinh ra 3,36 lt H2 ( ktc). Gi tr ca V l A. 150. B. 100. C. 200. D. 300. Cu 23: Oxi ha hon ton m gam hai ancol n chc, bc mt, mch h, ng ng lin tip nhau bng CuO d, nung nng thu c hn hp hi X c t khi hi so vi H 2 l 13,75. X lm mt mu va 200ml dung dch Br21,5M. Gi tr ca m l A. 7,8 B. 7,4 C. 8,6 D. 10,4 Cu 24: Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S cht trong dy c th tham gia phn ng trng bc l A. 3. B. 6. C. 4. D. 5. Cu 25: Hoa tan hoan toan 2,45 gam hn hp X gm hai kim loai kim th vao 200 ml dung dich HCl 1,25M, thu c dung dich Y cha cac cht tan co nng mol bng nhau. Hai kim loai trong X la A. Mg va Ca B. Be va Mg C. Mg va Sr D. Be va Ca Cu 26: Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CaCl 2, Ca(NO3)2, NaOH, Na2CO3, KHSO4, Na2SO4, Ca(OH)2, H2SO4, HCl. S trng hp c to ra kt ta l A. 4. B. 5. C. 6. D. 7. Cu 27: Pht biu no sau y khng ng A. Glucoz v Fructoz l ng phn ca nhau. B. Trong phn t Amiloz tn ti c lin kt -1,4-glicozit v -1,6-glicozit C. Thy phn Saccaroz thu c 2 monosaccarit khc nhau. D. Thy phn hon ton tinh bt v xenluloz cng thu c mt monosaccarit. Cu 28: Benzyl axetat l mt este c mi thm ca hoa nhi. Cng thc ca benzyl axetat l A. CH3-COO-C6H5 B. C6H5-COO-CH3 C. C6H5-CH2-COO-CH3 D. CH3-COO-CH2-C6H5 Cu 29: Cht M c cng thc phn t C4H6O2. Cho m gam M phn ng va vi dung dch cha 2 gam NaOH, to ra 4,1 gam mui. Kt lun no sau y l ng cho cht M A. M c kh nng lm i mu qu tm thnh B. M c phn ng trng bc v c lm mt mu nc brom C. M c phn ng trng bc nhng khng lm mt mu nc brom D. M khng tham gia phn ng trng bc nhng c lm mt mu nc brom Cu 30: Cho cac cht: NaHCO3, CO, Al(OH)3, Fe(OH)3, HF, Cl2, NH4Cl. S cht tac dung c vi dung dich NaOH loang nhit thng la A. 4 B. 5 C. 3 D. 6 Cu 31: Thi kh CO2 vo dung dch cha 0,02 mol Ba(OH) 2. Gi tr khi lng kt ta bin thin trong khong no khi CO2 bin thin trong khong t 0,005 mol n 0,024 mol? A. 0 gam n 3,94 gam B. 0 gam n 0,985 gam C. 0,985 gam n 3,94 gam D. 0,985 gam n 3,152 gam Cu 32: Ho tan ht hn hp Al v mt oxit st bng dung dch HNO 3 d thu c 2,912 lt NO (ktc) v dung dch X. C cn X thu c 66,99 gam mui khan. Nu ho tan lng mui khan ny vo nc ri cho tc dng vi dung dch NaOH d, lc kt ta, nung kt ta nhit cao n khi lng khng i thu c 14,4 gam cht rn. Cng thc ca oxit st l: A. Fe2O3 B. FeO2 C. Fe3O4 D. FeO Cu 33: Cho HCl c, d tc dng vi cng s mol mi cht: MnO 2, KMnO4, KClO3, KClO. Cht no cho lng clo ln nht? A. KMnO4 B. MnO2 C. KClO3 D. KClO Cu 34: Cho cc cht sau: axetilen, etilen, benzen, buta-1,3-ien, stiren, toluen, anlyl benzen, naphtalen. S cht tc dng c vi dung dch nc brom l
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Ti liu n thi i hc nm 2012 -2013 A. 6 B. 3 C. 5 D. 4 Cu 35: Cho s phn ng: + CH 3OH / H 2 SO4 + O2 / xt + Cl2 /500 o C + NaOH / t o + CuO / t o X Y Q metyl acrylat. Z T Y, Z, T, Q l cc sn phm chnh ca cc phn ng. tn gi ca X v Z l A. propen v ancol anlylic B. propen v andehit acrylic C. propin v propan-1-ol D. xiclopropan v ancol anlylic Cu 36: t chy hon ton mt hn hp A gm: glucoz, anehit fomic, axit axetic cn 2,24 lt O2 (ktc). Dn sn phm chy qua bnh ng dung dch Ca(OH)2, thy khi lng bnh tng m gam. Gi tr ca m l A. 6,2 B. 4,4 C. 3,1 D. 12,4 men + H 2O / H + Cu 37: S iu ch ancol etylic t tinh bt: Tinh bt glucoz ancol etylic. Ln men 162 gam tinh bt vi hiu sut cc giai on ln lt l 80% v 90%. Th tch dung dch ancol etylic 40 0 thu c l (Bit khi lng ring ca C2H5OH nguyn cht l 0,8 g/ml) A. 230 ml B. 207 ml C. 115 ml D. 82,8 ml Cu 38: tc dng ht vi 4,64g hn hp gm FeO, Fe 3O4, Fe2O3 cn dng va 160ml dung dch HCl 1M. Nu kh hon ton 4,64g hn hp trn bng kh CO nhit cao th khi lng Fe thu c l: A. 3,36g B. 3,63g C. 4,36g D. 4,63g Cu 39:Trn 3 dung dch axit HCl 0,2M; HNO3 0,1M v H2SO4 0,15M vi th tch bng nhau c dung dch A. Cho V ml dung dch B cha NaOH 0,2M v Ba(OH) 20,05M vo 400 ml dung dch A thu c (V + 400) ml dung dch D c pH = 13. Gi tr ca V l: A. 600 B. 400 C. 800 D. 300 Cu 40: Cht c dng ty trng giy v bt giy trong cng nghip l A. CO2. B. SO2. C. N2O. D. NO2. Cu 41: un nng 2,3-imetylpentan-2-ol vi H2SO4 c, 1700C, thu c sn phm chnh l A. (CH3)2C=C(CH3)-CH2-CH3. B. CH3-CH=C(CH3)-CH(CH3)2. . C. CH3-CH2-CH(CH3)-C(CH3)=CH2. D. CH2=CH-CH(CH3)-CH(CH3)2. Cu 42: (X) l hp cht hu c c cng thc phn t C 5H11O2N. un X vi dd NaOH thu c mt hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t o thu c cht hu c (Z) khng c kh nng phn ng trng bc. Cng thc cu to ca (X) l: A. CH3(CH2)4NO2 B. NH2 - CH2 - COO - CH(CH3)2 C. NH2 - CH2COO - CH2 - CH2 - CH3 D. H2N - CH2 - CH2 - COOC2H5 Cu 43: Pht biu no sau y l ng: A. T nilon-6,6 thuc loi t poliamit, c iu ch bng phn ng ng trng hp cc monome tng ng. B. Ancol o-hiroxibenzylic l sn phm trung gian trong qu trnh iu ch nha novolac t phenol v fomanehit. C. T visco, t xenluloz axetat, t nitron cng thuc loi t nhn to. D. Cao su buna-S thu c khi cho cao su buna tc dng vi lu hunh. Cu 44: Cho 0,87 gam hn hp gm Fe, Cu v Al vo bnh ng 300 ml dung dch H 2SO4 0,1M. Sau khi cc phn ng xy ra hon ton, thu c 0,32 gam cht rn v c 448 ml kh (ktc) thot ra . Thm tip vo bnh 0,425 gam NaNO3, khi cc phn ng kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi lng mui trong dung dch l A. 0,112 lt v 3,750 gam. B. 0,056 lt v 3,865 gam. C. 0,056 lt v 3,750 gam. D. 0,112 lt v 3,865 gam. Cu 45: Hp th hon ton 0,672 lt kh CO 2 (ktc) vo 1 lt dung dch gm NaOH 0,025M v Ca(OH) 2 0,0125M, thu c x gam kt ta. Gi tr ca x l A. 1,25. B. 0,75. C. 1,00. D. 2,00. Cu 46: Cho 0,15 mol Lysin tc dng vi 200ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l: A. 0,45 B. 0,55 C. 0,35 D. 0,25 Cu 47: Este X c to thnh t etylen glicol v hai axit cacboxylic n chc . Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th lng NaOH phn ng l 10 gam. Gi tr ca m l A. 17,5. B. 15,5. C. 14,5. D. 16,5.
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Ti liu n thi i hc nm 2012 -2013 Cu 48: t chy hon ton 4,872 gam mt hirocacbon X, dn sn phm chy qua bnh ng dung dch nc vi trong. Sau phn ng thu c 27,93 gam kt ta v thy khi lng dung dch gim 5,586 gam. Cng thc phn t ca X l A. CH4 B. C4H8 C. C4H10 D. C3H6 Cu 49: Cho cn bng ha hc: N2 (k) + 3H2(k) 2NH 3 (k), (H < 0). tng hiu sut tng hp NH 3 ta cn phi: A. Tng p sut, gim nhit . B. Gim p sut, gim nhit . C. Tng p sut, tng nhit . D. Gim p sut, tng nhit . Cu 50: Cho cc pht biu sau: (1) Trong mt chu k, theo chiu tng ca in tch ht nhn th bn knh nguyn t gim dn. (2) Trong mt nhm A, theo chiu tng dn ca in tch ht nhn th m in tng dn. (3) Lin kt ha hc gia mt kim loi nhm IA v mt phi kim nhm VIIA lun l lin kt ion. (4) Nguyn t N trong NH3 v trong NH4+ c cng cng ha tr l 3. (5) S oxi ha ca Cr trong K2Cr2O7 l +6. S pht biu ng l A. 2 B. 3 C. 4 D. 5 B S 20 Cu1:Cho cc polime:(1)polietilen,(2)poli(metylmetacrilat),(3)polibutaien,(4)polisitiren,(5) poli(vinylaxetat) ; (6) t nilon-6,6; .Trong cc polime trn cc polime b thy phn trong dung dch axit v trong dung dch kim l: A. (1),(4),(5),(3) B. (1),(2),(5);(4) C. (2),(5),(6), D. (2),(3),(6); Cu 2: Nung 1 mol FeCO3 trong bnh kn cha a mol O2 nhit cao ti phn ng hon ton. Cht rn trong bnh ha tan va ht trong dung dch cha 2,4 mol HCl; a mol O2 c gi tr l A. 0,3 mol B. 0,1 mol C. 0,2 mol D. 0,4 mol Cu 3: in phn 100 ml dung dch cha hn hp CuSO 4 0,1M v NaCl 0,1 M trong bnh in phn c mng ngn vi hai in cc tr, cng dng in bng 0,5 A. Sau mt thi gian, thu c dung dch c pH=2 ( gi s th tch dung dch khng i. Thi gian ( giy) in phn v khi lng ( gam) Cu thu c catot ln lt l A. 1930 v 0,176 B. 2123 v 0,352 C. 1737 v 0,176 D. 1939 v 0,352 Cu 4:Cho Cu( d) tc dng vi dung dch Fe(NO 3)3 c dung dch X. Cho AgNO3 d tc dng vi dung dch X c dung dch Y. Cho Fe (d) tc dng vi dung dch Y c hn hp kim loi Z. S phng trnh phn ng xy ra l A. 6 B. 7 C. 5 D. 4 Cu 5: Cho cc phn ng oxi ho- kh sau: (1) 3I2 + 3H2O HIO3 + 5HI (2) 2HgO 2Hg + O2 (3) 4K2SO3 3K2SO4 + K2S (4) NH4NO3 N2O + 2H2O (5) 2KClO3 2KCl + 3O2 (6) 3NO2 + H2O 2HNO3 + NO (7) 4HClO4 2Cl2 + 7O2 + 2H2O (8) 2H2O2 2H2O+ O2 (9) Cl2 + Ca(OH)2 CaOCl2 + H2O (10) 2KMnO4 K2MnO4 + MnO2 + O2 Trong s cc phn ng oxi ho- kh trn, s phn ng oxi ho- kh ni phn t v t oxi ho- t kh ln lt l A. 5 v 5 B. 6 v 4 C. 8 v 2 D. 7 v 3 Cu 6: Cho 6 gam km ht vo cc ng dung dch H 2SO4 2M nhit thng. Bin i khng lm thay i tc phn ng l A.tng th tch dung dch H2SO4 2M ln 2 ln B. thay 6 gam km ht bng 6 gam km bt C. thay dung dch H2SO4 2M bng dung dch 1M D.tng nhit ln n 500C t0 Cu 7: Cho s chuyn ha: KOH, t0, HCl KOH, HCl CH3CH(CH3)CH2CH2Cl A A BB C D ancol Bit cc cht A, B, C, D l ccancol sn phm chnh.Tn gi ca D l A. 2-clo-3-metylbutan B. 3-metylbut-1-en C. 2-clo-2-metylbutan D. 2-metylbut-2-en Cu 8: Hp cht hu c X c cng thc phn t C8H14O4. Cho X thc hin cc th nghim
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Ti liu n thi i hc nm 2012 -2013 (1) X + 2NaOH X1 + X2 + H2O. (2) X1 + H2SO4 X3 + Na2SO4. (3) nX3 + nX4 nilon 6,6 + nH2O. (4) 2X2 + X3 X5 + 2H2O. Cng thc cu to ph hp ca X l A. CH3OOC[CH2]5COOH. B. CH3OOC[CH2]4COOCH3. C. CH3CH2OOC[CH2]4COOH. D. HCOO[CH2]6OOCH. Cu 9: t chy hon ton mt khi lng nh nhau cc cht hu c (A), (B), (C), (D), (E), u thu c 2,64 gam CO2 v 1,08 gam H2O, th tch O2 cn dng l 1,344 lt (ktc). T l s mol tng ng (A), (B), (C), (D), (E) l 1 : 1,5 : 2 : 3 : 6. Nu s mol ca (C) l 0,02 mol th CTPT ca (A), (B), (C), (D), (E) ln lt l A. C6H12O6; C3H6O3;C4H8O4,; C2H4O2;; CH2O B. C6H12O6; C4H8O4, C3H6O3; C2H4O2;; CH2O C. C6H12O6; C4H8O4, C3H6O3; CH2O ;C2H4O2 D. C6H12O6; C4H8O4, C2H4O2 ;C3H6O3;; CH2O Cu 10: Thc hin cc phn ng sau y: (1) Nhit phn NH4ClO4 (2) Cr2O3 + KNO3 + KOH (3) NH3 + Br2 (4) MnO2 + KCl + KHSO4 (5) I2 + Na2S2O3 (6) H2C2O4 + KMnO4 + H2SO4 (7) FeCl2 + H2O2 + HCl (8) Nung hn hp Ca3(PO4)2 + SiO2 + C Phn ng to ra n cht l: A. (2);(6);(7);(8) B. (1);(4);(7);(8) C. (1); (3);(4); (8) D. (2);(3);(5);(8) Cu 11: Thi CO2 vo dd cha 0,02 mol Ba(OH)2 . Gi tr khi lng kt ta bin thin trong khang no khi CO2 bin thin trong khang t 0,005 mol n 0,024 mol ? A. 0 gam n 0,985 gam B. 0 gam n 3,94 gam C. 0,985 gam n 3,94 gam D. 0,985 gam n 3,152 gam Cu 12: Trong cc cht xiclopropan, xiclohexan, benzen, stiren, axit axetic, axit acrylic, andehit axetic, andehit acrylic, etyl axetat, vinyl axetat, imetyl ete s cht c kh nng lm mt mu nc brom iu kin thng l A. 6 B. 5 C. 7 D. 4 Cu 13: Hn hp X gm HCOOH v CH 3COOH ( t l mol 1:1); hn hp Y gm CH 3OH v C2H5OH ( t l mol 3 : 2). Ly 11,13 gam hn hp X tc dng vi 7,52 gam hn hp Y c xc tc H 2SO4 c, un nng. Khi lng ca este thu c l ( bit hiu sut cc phn ng este u 75%) A. 10,89 gam B. 11,4345 gam C. 14,52 gam D. 11,616 gam Cu 14: Sp xp cc cht sau y theo trnh t gim dn nhit si: CH3COOH (1), HCOOCH3 (2), CH3CH2COOH (3),CH3COOCH3 (4), CH3CH2CH2OH (5). A. (3) > (1) > (4) > (5) > (2). B. (1) > (3) > (4) > (5) > (2). C. (3) > (1) > (5) > (4) > (2). D. (3) > (5) > (1) > (2) > (4). Cu 15: Dy gm cc kim loi u tc dng c vi dd FeCl3 l: A. Au, Cu, Al, Mg, Zn B. Fe, Zn, Cu, Al, Mg C. Cu, Ag, Au, Mg, Fe D. Fe, Mg, Cu, Ag, Al + HCl + Cl2 + NaOHdd + Br2 Cu 16: C s sau : Cr ? ? ? X . X l hp cht no ca Crom? A. Cr(OH)3. B. Na2CrO4. C. Na2Cr2O7. D. NaCrO2. Cu 17: Braikinin c tc dng lm gim huyt p. l mt nonapeptit c cng thc l: Arg-Pro-Pro-Gly-Phe-Ser-Pro-Phe-Arg. Khi thu phn khng hon ton, s tripeptit c cha phenylamin (Phe) l: A. 6 B. 8 C. 7 D. 5 Cu 18: Hn hp A gm metanal v etanal . Khi oxi ho m gam A (hiu sut 100%) thu c hn hp B gm 2 axit hu c tng ng c dB/A = a . Gi tr ca a trong khong A. 1,62 < a < 1,75 B. 1,36 < a < 1,53 C. 1,26 < a < 1,47 D. 1,45 < a < 1,50 + Br2 (1:1) 0 + AgNO / NH NaOH ,t + CuO ,t + 3 3 Z T. 400 C Cu 19: Cho s Buta-1,3 -ien X Y Bit cc cht trn mi tn l sn phm chnh ;T c th l cht no sau y ? A. OHC-CH=CHCHO B. NH4OOC-CH=CH-COONH4 C. CH3CH[CHO]CH[CHO]CH3 D. HOOC-CO-CH=CH2 Cu 20: Cho cc cht: p-crezol, anilin, benzen, axit acylic, axit fomic, andehit metacrylic, axetilen. S cht tc dng vi dung dch Br2 (d) iu kin thng theo t l mol 1 : 1 l A. 5. B. 6. C. 2 D. 3 Cu 21: Cho 20 gam hn hp 3 amin no n chc l ng ng k tip c t l mol tng ng l 1: 10 : 5, tc dng va vi dd HCl thu c 31.68 gam hn hp mui. Tng s ng phn ca 3 amin trn l A. 7 B. 14 C. 28 D. 16
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Ti liu n thi i hc nm 2012 -2013 Cu 22: Cho cc cht sau : Ba(HSO3)2 ; Cr(OH)2; Sn(OH)2; NaHS; NaHSO4; NH4Cl; CH3COONH4; C6H5ONa; ClH3NCH2COOH. S cht va tc dng vi NaOH va tc dng vi HCl l A. 5 B. 6 C. 4 D. 7 Cu 23: Hn hp X gm c C2H5OH. C2H5COOH, CH3CHO trong C2H5OH chim 50% theo s mol. t chy m gam hn hp X thu c 3,06 gam H 2O v 3,136 lt CO2( ktc). Mt khc 13,2 gam hn hp X thc hin phn ng trng bc thy c x gam Ag kt ta. Gi tr ca x l: A. 10,8 gam B. 2,16 gam C. 8,64 gam D. 4,32 gam Cu 24: Hn hp X gm metanol, etanol, propan-1- ol, v H 2O. Cho m gam X + Na d thu c 15,68 lit H2(ktc). Mt khc t chy hon ton X thu c Vlit CO2(ktc) v 46,8 gam H2O. Gi tr m v V l. A. 19,6 v 26,88 B. 42 v 26,88 C. 42 v 42,56 D. 61,2 v 26,88 Cu 25: Cho hn hp HCHO v H 2 qua ng ng bt Ni nung nng. Ton b sn phm thu c em ho tan trong bnh ng nc lnh thy khi lng bng tng 1,564 gam. Thm tip dung dch AgNO 3/NH3 n d v un nh th thu c 7,776 gam Ag. Hiu sut phn ng hiro ho l A. 20% B. 64% C. 80% D. 36% Cu 26: Cho t t dung dch cha 0,15 mol HCl vo dung dch cha 0,05 mol Na 2CO3 v 0,07 mol KHCO3, khuy u, thu c V lt kh (ktc) v dung dch X. Khi cho dung dch nc vi trong d vo dung dch X thy xut hin m gam kt ta. Gi tr ca V v m ln lt l A. 1,12 v 2,0 B. 3,36 v 2,5 C. 2,24 v 2,0 D. 2,24 v 5,0 Cu 27: Hn hp X gm bn hp cht hu c u c cng thc phn t l C 3H9NO2. Cho hn hp X phn ng vi dung dch KOH va th thu c 1344 ml (ktc) hn hp kh Y mi khai c t khi hi so vi hiro l 17,25 v dung dch Z. C cn dung dch Z thu c m gam cht rn khan. Gi tr ca m l A. 5,67 B. 4,17 C. 5,76 D. 4,71 Cu 28: X,Y,Z l 3 nguyn t ha hc. Tng s ht mang in trong 3 phn t X 2Y, ZY2 v X2Z l 200. S ht mang in ca X2Y bng 15/16 ln s ht mang in ca ZY2. trng thi c bn, nguyn t Z c s electron p bng 1,667 ln s electron s. R l phn t hp cht gia X,Y,Z gm 6 nguyn t c tng s ht mang in l : A. 104 B. 52 C. 62 D. 124 Cu 29: Nung m gam hn hp X gm KClO 3 v KMnO4 thu c cht rn Y v O2. Bit KClO3 phn hy hon ton, cn KMnO4 ch b phn hy mt phn. Trong Y c 1,49 gam KCl chim 19,893% theo khi lng. Trn lng O2 trn vi khng kh theo t l th tch VO2 : V KK =1:4 trong mt bnh kn ta thu c hn hp kh Z. Cho vo bnh 0,528 gam cacbon ri t chy ht cacbon, phn ng hon ton, thu c hn hp kh T gm 3 kh O2, N2, CO2, trong CO2 chim 22 % th tch. Gi tr m (gam) l A. 8,53 B. 8,77 C. 8,70 D. 8,91 Cu 30: Cho cc th nghim sau: (1) Sc kh CO2 (d) vo dung dch cha 1 mol Ba(OH)2. (2) Cho dung dch Ba(OH)2 (d) vo dung dch cha 1 mol NaHCO3. (3) Sc kh NH3 (d) vo dung dch cha 1 mol AlCl3. (4) Sc kh NH3 (d) vo dung dch cha 1 mol CuCl2. (5) Cho dung dch HCl (d) vo dung dch cha 1 mol Na[Al(OH)4] (6) Cho dung dch Ba(OH)2 (d) vo dung dch cha 1 mol Na2CO3. (7) Sc kh CO2 (d) vo dung dch cha 1 mol Na[Al(OH)4] Phn ng thu c lng kt ta nhiu nht l A. (2), (6). B. (6). C. (2), (7). D. (2), (3). Cu 31: X l mt sn phm ca phn ng este ho gia glyxerol vi hai axit: axit panmitic v axit stearic. Ha hi 59,6 g este X thu c mt th tch ng bng th tch ca 2,8 g kh nit cng iu kin. Tng s nguyn t cacbon trong 1 phn t X l A. 35. B. 37. C. 54. D. 52. Cu 32: Cho cc cht sau : axetilen, axitfomic, saccaroz ,glucoz, vinylaxetilen; phenylaxetilen axit axetic, metyl axetat , mantz, amoni fomat, axeton, phenyl fomat. S cht c th tham gia phn ng vi AgNO3/NH3: A. 8 B. 5 C. 7 D. 6 Cu 33: Ha tan hn hp gm 6,4 gam CuO v 16 gam Fe 2O3 trong 160 ml dung dch H2SO4 2M n phn ng hon ton. Sau phn ng thy c m gam cht rn khng tan. Gi tr ca m l A. 4,8 gam B. 3,2 gam C. 3,2 gam< m< 4,8 gam D. 4 gam
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Ti liu n thi i hc nm 2012 -2013 Cu 34: Hn hp kh A gm c O2 v O3, t khi ca hn hp A so vi H2 l 19,2. Hn hp kh B gm c H2 v CO; t khi ca hn hp B so vi H 2 l 3,6. S mol hn hp kh A cn dng t chy hon ton 1 mol kh B l ( cc th tch o cng iu kin nhit ; p sut) A. 1,67 B. 0,625 C. 0,833 D. 0,417 Cu 35: Nitro ha benzen bng HNO3 thu c hai cht hu c A,B hn km nhau mt nhm -NO2. t chy hon ton 2,34 gam hn hp A, B to thnh CO2; H2O v 255,8 ml N2 ( o 270C v 740 mmHg). A v B l A. Nitrobenzen v o- initrobenzen B. Nitrobenzen v m-initrobenzen C. O- initrobenzen v 1,2,4- initrobenzen D. M- initrobenzen v 1,3,5- initrobenzen 2 2 S O + 2I 2SO + I Cu 36: Cho phn ng : 2 8 4 2 Nu ban u nng ca ion I bng 1,000 M v nng sau 20 giy l 0,752 M th tc trung bnh ca phn ng trong thi gian ny l A. 6,2.103 mol/l.s B. -12,4.103 mol/l.s C. 24,8.10-3 mol/l.s D. 12,4.103 mol/l.s Cu 37: Ha tan 54,44 gam hn hp X gm PCl 3 v PBr3 vo nc c dung dch Y. trung ha hon ton dung dch Y cn 500 ml dung dch KOH 2,6M. Ty l % khi lng ca PCl3 trong X l A. 8,08%. B. 26,96%. C. 30,31%. D. 12,125%. Cu 38: Thc hin cc phn ng sau: (1) Fe + HCl (2) KMnO4 + HCl (3) Cl2 + HBr (4) KMnO4 + Na2SO3 + H2SO4 (5) Cu + HNO3 (6) Nhit phn HNO3 Phn ng trong axit ch ng mt vai tr l A. (1), (3), (4) B. (3), (4), (6) C. (2), (5), (6) D. (1), (2), (5) Cu 39: T 10 kg go np ( c 80% tinh bt); khi ln men s thu c bao lt cn 96 0? Bit hiu sut qu trnh ln men t 80% v khi lng ring cu ancol etylic l 0,8g/ml: A. ~ 4,73 lt B. ~ 4,35 lt C. ~ 4,1 lt D. ~ 4,52 lt Cu 40: Cho cc cht (X): n Butan; (Y): n Hexan; (Z): isohexan , (T) : neohexan. Cc cht c xp theo chiu gim dn nhit si? A. Y, Z, X, T B. T, Z, Y, X C. Y, Z, T, X D. Y, X, Z, T 2+ 2+ Cu 41: Mt cc nc cha a mol Ca , b mol Mg v c mol HCO3 . Dng V lt dung dch Ca(OH)2 x mol/l kt ta lng cation trong cc. Mi quan h gia V, a, b, x thu c kt ta ln nht l: A. V = (2a + 2b)/x B. V = (2a + b)/x C. V = (a + 2b)/x D. V = (a + b)/x Cu 42: Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh (gm 20% th tch O 2 v 80% th tch N2) n khi phn ng xy ra hon ton, thu c cht rn v hn hp kh Y c thnh phn th tch: N2 = 84,77%; SO2 = 10,6% cn li l O2. Thnh phn % theo khi lng ca FeS trong X l A. 68,75% B. 42,3% C. 26,83% D. 59,46% Cu 43: Mt loi m cha: 50% olein (glixerol trioleat), 30% panmitin (glixerol tripanmitat), 20% stearin (glixerol tristearat). Gi s phn ng xy ra hon ton, khi lng x phng thu c t 100kg loi m l A. 206,50 kg. B. 309,75 kg. C. 51, 63 kg D. 103,25 kg. Cu 44: Mt dung dch cha a mol H2SO4 ha tan ht b mol Fe thu c kh A v 42,8 gam mui khan. Cho a: b= 6 : 2,5. Gi tr ca a, b ln lt l A. 0,3 v 0,125 B. 0,12 v 0,05 C. 0,15 v 0,0625 D. 0,6 v 0,25 Cu 45: Tripeptit mch h X v tetrapeptit mch h Y u c to nn t mt -aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,2 mol Y thu c tng khi lng CO2 v H2O bng 95,6 gam. t chy hon ton 0,1 mol X, sn phm thu c cho hp th vo dung dch Ba(OH)2 d, sau phn ng khi lng dung dch ny A. gim 81,9 gam B. Gim 89 gam C. Gim 91,9 gam D. gim 89,1 gam Cu 46: Crackinh 560 lt C4H10 thu c 1010 lt hn hp kh X khc nhau. Bit cc th tch kh u o iu kin chun. Th tch ( lt) C4H10 cha b crackinh l A. 450 lt B. 100 lt C. 60 lt D. 110 lt Cu 47: Ha tan hn hp gm FeS 2 0,24mol v Cu2S vo dung dch HNO3 va thu c dung dich X(ch cha 2 mui sunfat) v V lt kh NO duy nht (ktc).Gi tr ca V l : A. 35,84 lt B. 34,048 lt C. 25,088 lt D. 39,424 lt Cu 48: t chy hon ton m gam FeS2 bng mt lng O2 va , thu c kh X. Hp th ht X
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Ti liu n thi i hc nm 2012 -2013 vo 1 lt dung dch cha Ba(OH)2 0,15M v KOH 0,1M, thu c dung dch Y v 27,125 gam kt ta.Cho Y vo dung dch NaOH, thy xut hin thm kt ta. Gi tr ca m l A. 18,0. B. 16,5. C. 13,8. D. 36,0. Cu 49: t chy 1,6g mt este E n chc c 3,52g CO 2 v 1,152g H2O .Nu cho 10g E tc dng vi 150ml dung dch NaOH 1M,c cn dung dch sau phn ng thu thu c11,4g cht khan. Vy cng thc ca axit to nn este trn c th l : A. CH2=C[CH3]-COOH B. HOOC-CH2-CH[OH]-CH3 C. HOOC[CH2]3CH2OH D. CH2=CH-COOH Cu 50: t chy hon ton m gam hn hp X gm cc amin ng ng ca vinylamin thu c 41,8 gam CO 2 v 18,9 gam H2O . Gi tr ca m l: A. 16,7 gam B. 17,1 gam C. 16,3 gam D. 15,9 gam B S 21 Cu 1: Hn hp X gm 0,1 mol anlyl clorua; 0,3 mol benzyl bromua; 0,1 mol hexyl clorua; 0,15 mol phenyl bromua. un si X vi nc n khi phn ng xy ra hon ton, chit ly phn nc lc, ri cho tc dng vi dung dch AgNO3 d thu c m gam kt ta. Gi tr ca m l A. 57,4 B. 14,35 C. 70,75 D. 28,7 Cu 2: Cho 3,78 gam hn hp X gm CH 2=CHCOOH, CH3COOH v CH2=CHCH2OH phn ng va vi dung dch cha 8 gam brom. Mt khc, trung ho 0,03 mol X cn dng va 20 ml dung dch NaOH 0,75M. Khi lng ca CH2=CHCOOH c trong 3,78 gam hn hp X l A. 0,72 gam B. 2,16 gam C. 1,08 gam D. 1,44 gam Cu 3: M l hn hp ca mt ancol no X v axit hu c n chc Y u mch h. t chy ht 0,4 mol hn hp M cn 30,24 lt O2 (ktc) va , thu c 52,8 gam CO2 v 19,8 gam H2O. Bit s nguyn t cacbon trong X v Y bng nhau. S mol ca Y ln hn s mol ca X. CTPT ca X, Y l A. C3H8O2 v C3H6O2 B. C3H8O2 v C3H2O2 C. C3H8O2 v C3H4O2 D. C4H8O2 v C4H4O2 Cu 4: Hn hp X gm axit HCOOH v CH 3COOH c s mol bng nhau. Ly 5,3 g hn hp X cho tc dng vi 5,75 g C2H5OH (c H2SO4 c lm xc tc) thu c m (g) hn hp este (hiu sut cc phn ng este ha u bng 80%). Gi tr m l : A. 8,80 B. 8,10 C. 6,48 D. 7,04 Cu 5: Ho tan hon ton m gam bt Al vo 150 ml dung dch HCl 2M thu c dung dch X. Cho dung dch X tc dng vi 320 ml dung dch NaOH 1M thu c 4,68 gam kt ta. Gi tr ca m l A. 2,70 B. 1,62 C. 2,16 D. 1,89 Cu 6: Oxi ha m gam ancol etylic mt thi gian thu c hn hp X. Chia X thnh 3 phn bng nhau: - Phn 1 tc dng va vi dung dch NaHCO3 thot ra 4,48 lt kh.- Phn 2 tc dng vi Na d thot ra 8,96 lt khPhn 3 tc dng vi dung dch AgNO 3/NH3 d to thnh 21,6 gam Ag. Cc phn ng ca hn hp X xy ra hon ton. Th tch kh o ktc. Gi tr ca m v hiu sut phn ng oxi ha ancol etylic l A. 124,2 v 33,33% B. 82,8 v 50% C. 96,8 v 42,86% D. 96 v 60% Cu 7: Bit rng A tc dng vi dung dch NaOH, c cn dung dch sau phn ng thu c cht rn B v hn hp hi C. Chng ct C thu c D, D trng bc to sn phm E. E tc dng vi dung dch NaOH li thu c B. Cng thc cu to ca A l A. HCOOCH2CH=CH2 B. CH3COOCH=CH2 C. HCOOCH=CH-CH3 D. HCOOCH=CH2 Cu 8: Hn hp X gm Fe(NO3)2, Cu(NO3)2 v AgNO3. Thnh phn phn trm khi lng ca N trong X l 11,864%. C th iu ch ti a m gam hn hp 3 kim loi t 14,61 gam X. Gi tr ca m l A. 6,93 B. 7,68 C. 6,72 D. 10,56 Cu 9: Hn hp A gm 0,1 mol propenal v a mol kh hidro. Cho hn hp A qua ng s nung nng c cha Ni lm xc tc, thu c hn hp B gm propanal, propan-1-ol, propenal v 0,15 mol hidro. T khi hi ca hn hp B so vi metan bng 1,55. Gi tr ca a l A. 0,35 B. 0,30 C. 0,20 D. 0,25 Cu 10: Cho 2,7 gam Al tan hon ton trong dung dch HNO 3 long, nng thu c kh 0,448 lt X duy nht (ktc). C cn dung dch thu c 22,7 gam cht rn khan. kh X l A. NO B. NO2 C. N2 D. N2O
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Ti liu n thi i hc nm 2012 -2013 Cu 11: Cho a mol hp cht thm X phn ng va ht vi a lit dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na d thu c 22,4a lit H2 (ktc). Cng thc cu to thu gn ca X l A. HO-C6H4-COOH B. HO-CH2-C6H4OH C. CH3-C6H3(OH)2 D. HO-C6H4-COOCH3 Cu 12: Pht biu sai l A. Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thy tinh. B. nhit thng, tt c kim loi kim th u tc dng c vi nc. C. Nhm bn trong mi trng khng kh v nc l do c mng oxit Al2O3 bn vng bo v D. Theo chiu tng dn ca in tch ht nhn, nhit nng chy ca kim loi kim gim dn Cu 13: Cho phn ng: 2Al + 2H2O + 2OH- 2AlO-2 + 3H2. Cht oxi ha l A. OHB. Al C. H2O D. H2O v OHCu 14: Dy gm cc kim loi c cng kiu mng tinh th lp phng tm khi l A. Mg, Ca, Ba B. Li , Na, Mg C. Na, K, Ba D. Na, K , Ca Cu 15: Ha tan 17 gam hn hp X gm K v Na vo nc c dung dch Y v 6,72 lt H 2 (ktc). trung ha mt na dung dch Y cn dng dung dch hn hp H2SO4 v HCl (t l mol 1:2). Tng khi lng mui c to ra l A. 42,05 gam B. 20,65 gam C. 21,025 gam D. 14,97 gam Cu 16: Trong s cac phat biu sau v anilin (1) Anilin tan it trong nc nhng tan nhiu trong dung dich NaOH. (2) Anilin co tinh baz, dung dich anilin khng lam i mau quy tim. (3) Anilin dung san xut phm nhum, dc phm, polime. (4) Anilin tham gia phan ng th brom vo nhn thm d hn benzen. Cac phat biu ung la A. (2), (3), (4) B. (1), (2), (3) C. (1), (2), (4) D. (1), (3), (4) Cu 17: t chy hon ton m gam hn hp gm anehit fomic, axit axetic, glucoz, glixerol thu c 29,12 lt CO2 (ktc) v 27 gam nc. Thnh phn phn trm khi lng ca glixerol trong hn hp ban u l A. 23,4% B. 18,4% C. 43,8% D. 46,7% Cu 18: Cho hi nc i qua than nng , thu c 17,92 lt hn hp kh X (ktc) gm CO, CO 2 v H2. Cho ton b X tc dng ht vi CuO (d) nung nng, thu c hn hp cht rn Y. Ha tan ton b Y bng dung dch HNO3 (long, d) c 8,96 lt NO (sn phm kh duy nht, ktc). Phn trm th tch kh CO trong X l: A. 28,57% B. 24,50% C. 14,28% D. 12,50% Cu 19: Cho 200 ml dung dch H3PO4 1M vo 250 ml dung dch hn hp NaOH 0,5M v KOH 1,5M. Sau khi phn ng hon ton thu c dung dch X. S gam mui c trong dung dch X l A. 36,6 gam B. 32,6 gam C. 40,2 gam D. 38,4 gam Cu 20: Ha tan ht 10,24 gam Cu bng 200 ml dung dch HNO 3 3M c dung dch A. Thm 400 ml dung dch NaOH 1M vo dung dch A. Lc b kt ta, c cn dung dch ri nung cht rn n khi lng khng i thu c 26,44 gam cht rn. S mol HNO3 phn ng vi Cu l A. 0,48 B. 0,58 C. 0,56 D. 0,40 Cu 21: Hn hp gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc, un nng c hn hp Y. Dn Y qua nc brom thy bnh nc brom tng 10,8 gam v thot ra 4,48 lit hn hp kh (ktc), c t khi so vi hidro l 8. Th tch kh O2 (ktc) va t chy hon ton hn hp Y l A. 33,6 lt B. 22,4 lit C. 26,88 lit D. 44,8 lit Cu 22: S iu ch PVC trong cng nghip hin nay l Cl2 HCl TH ,t , Pcao A. C2H6 C2H5Cl C2H3Cl PVC HCl TH ,t , Pcao 1500o C B. CH4 C2H3Cl PVC C2H2 Cl2 TH ,t , Pcao C. C2H4 C2H3Cl PVC Cl2 HCl TH ,t , Pcao D. C2H4 C2H4Cl2 C2H3Cl PVC Cu 23: Trng hp thu c kt ta c khi lng ln nht l A. Cho V(lt) dung dch HCl 2M vo V (lt) dung dch NaAlO2 1M B. Cho V(lt) dung dch AlCl3 1M vo V (lt) dung dch NaAlO2 1M C. Cho V(lt) dung dch NaOH 1M vo V (lt) dung dch AlCl3 1M D. Cho V(lt) dung dch HCl 1M vo V (lt) dung dch NaAlO2 1M Cu 24: Cho cc cn bng :
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(1) H2(k) + I2(k) 2HI(k) (3) CO(k) +Cl2(k) COCl2(k) (5) CaCO3 (r) CaO (r) + CO2(k) Cc cn bng chuyn dch theo chiu thun khi tng p sut l A. 1, 2, 3 B. 2, 3, 4 C. 1, 3 Cu 25: Cho hai mui X, Y tha mn iu kin sau: X + Y khng xy ra phn ng X + Cu khng xy ra phn ng Y + Cu khng xy ra phn ng X + Y + Cu xy ra phn ng

Ti liu n thi i hc nm 2012 -2013 (2) 2NO(k) + O2(k) 2NO2 (2) (4) N2 (k) + 3H2(k) 2NH3(k) (4) D. 3, 4, 5

X, Y l A. Fe(NO3)3 v NaHSO4. B. NaNO3 v NaHCO3. C. Mg(NO3)2 v KNO3. D. NaNO3 v NaHSO4. Cu 26: Tng s proton trong ht nhn nguyn t X v Y l 25. Y thuc nhm VIIA. iu kin thch hp n cht X tc dng vi Y. Pht biu ng l A. X l kim loi, Y l phi kim. B. trng thi c bn X c 2 electron c thn C. Cng thc oxit cao nht ca X l X2O D. Cng thc oxit cao nht ca Y l Y2O7 Cu 27: Cho cc polime sau: t nilon-6,6; poli(vinyl clorua); thy tinh plexiglas; teflon; nha novolac; t visco, t nitron, cao su buna. Trong , s polime c iu ch bng phn ng trng hp l A. 7 B. 4 C. 6 D. 5 Cu 28: Cho phng trnh ho hc: FeSO4 + KMnO4 + KHSO4 Fe2(SO4)3 + MnSO4 + K2SO4 + H2O. Tng h s ( s nguyn t, ti gin) ca cc cht c trong phng trnh phn ng l A. 54 B. 52 C. 40 D. 48 Cu 29: Khi thu phn 1 peptit, ch thu c cc ipeptit Glu-His ; Asp-Glu ; Phe-Val v Val-Asp. Cu to peptit em thu phn l A. Phe-Val-Asp-Glu-His. B. His- Asp- Glu-Phe-Val-Asp-Glu. C. Asp-Glu-Phe-Val-Asp-Phe-Val-Asp. D. Glu-Phe-Val-Asp-Glu-His-Asp-Val-Asp. Cu 30: Pht biu khng ng l A. Trong mi phn t protit, cc aminoaxit c sp xp theo mt th t xc nh B. Phn t c hai nhm - CO-NH- c gi l ipeptit, ba nhm th c gi l tripeptit C. Cc peptit c t 10 n 50 n v -amino axit cu thnh c gi l polipeptit D. Nhng hp cht hnh thnh bng cch ngng t hai hay nhiu -aminoaxit c gi l peptit Cu 31: Sc V lt CO2 (ktc) vo 200 ml dung dch X gm Ba(OH) 2 1M v NaOH 1M. Sau phn ng thu c 19,7 gam kt ta, gi tr ln nht ca V l A. 6,72 B. 8,96 C. 11,2 D. 13,44 Cu 32: Nhm cc cht u c kh nng tham gia phn ng trng gng l : A. Glucoz, axit fomic, anehit oxalic, mantoz. B. Glucoz, axit axetic, anehit oxalic, mantoz. C. Fructoz, axit fomic, anehit oxalic, saccaroz. D. Fructoz, axit fomic, formanehit, etylen glicol. Cu 33: Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1) vo 30 ml dung dch gm H2SO4 0,5M v HNO3 2M, sau khi cc phn ng xy ra hon ton, thu c a mol kh NO (sn phm kh duy nht). Trn a mol NO trn vi 0,1 mol O2 thu c hn hp kh Y. Cho ton b Y tc dng vi H2O, thu c 150 ml dung dch c pH = z. Gi tr ca z l A. 2 B. 3 C. 4 D. 1 Cu 34: Hp cht hu c A c cng thc phn t l C 6H10O5. Khi A tc dng vi dung dch NaHCO 3 v vi Na u thu c s mol kh bng s mol A phn ng. Mt khc, 0,1 mol A tc dng va vi 200ml dung dch KOH 1M. C cn dung dch sau phn ng thu c m gam mt mui khan duy nht. Cng thc ca A v gi tr ca m l
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Ti liu n thi i hc nm 2012 -2013 A. HO-CH2CH2COOCH2CH2COOH; 25,6g B. HO-CH2CH2COOCH2CH2COOH; 23,8g C. HOOCCH2CHOHCH2CH2COOH; 23,8g D. HOOCCH2CHOHCH2CH2COOH; 25,6g Cu 35: Cho 400 ml dung dch E gm AlCl 3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 612 ml dung dch NaOH 1M, sau khi cc phn ng kt thc thu c 8,424 gam kt ta. Mt khc, khi cho 400 ml E tc dng vi dung dch BaCl2 (d) th thu c 33,552 gam kt ta. T l x : y l A. 3 : 4 B. 4 : 3 C. 3 : 2 D. 7 : 4 Cu 36: Hp th hon ton 2,24 lt CO2 ( ktc) vo 100 ml dung dch gm K2CO3 0,2M v KOH x mol/lit, sau khi cc phn ng xy ra hon ton thu c dung dch Y. Cho ton b Y tc dng vi dung dch BaCl 2 d, thu c 11,82 gam kt ta. Gi tr ca x l A. 1,4 B. 1,2 C. 1,0 D. 1,6 Cu 37 . C cc cht tripanmitin,tristearin, triolein v 1,2,3-triclopropan.S cht bng mt phn ng trc tip to ra glixerol l A .1 B .2 C.3 D .4 Cu 38: Cho dy cc oxit sau: SO2, NO2, NO, SO3, P2O5, CO, N2O5, N2O. S oxit trong dy tc dng c vi H2O iu kin thng l A. 5 B. 7 C. 8 D. 6 Cu 39: Thc hin cc th nghim vi hn hp gm Ag v Cu (hn hp X): (1) Cho X vo bnh cha mt lng d kh O3 ( iu kin thng) (2) Cho X vo mt lng d dung dch HNO3 (c) (3) Cho X vo mt lng d dung dch HCl (khng c mt O2) (4) Cho X vo mt lng d dung dch FeCl3 S th nghim m Cu b oxi ha cn Ag khng b oxi ha l A. 1 B. 2 C. 3 D. 4 Cu 40: Thc hin cc th nghim sau: (a) Nung NH4NO3 rn. (b) un nng NaCl tinh th vi dung dch H2SO4 (c) (c) Sc kh Cl2 vo dung dch NaHCO3. (d) Sc kh CO2 vo dung dch Ca(OH)2 (d). (e)Sc kh SO2 vo dung dch KMnO4. (g) Cho dung dch KHSO4 vo dung dch NaHCO3 (h) Cho PbS vo dung dch HCl (long). (i) Cho Na2SO3 vo dung dch H2SO4 (d), un nng. S th nghim sinh ra cht kh l A. 2 B. 6 C. 5 D. 4 Cu 41: tch c CH3COOH t hn hp gm CH3COOH v C2H5OH ta dng ho cht no sau y? A. Na v dung dch HCl B. Ca(OH)2 v dung dch H2SO4 o C. CuO (t ) v AgNO3/NH3 d D. H2SO4 c Cu 42: Cho cn bng sau trong bnh kn: 2NO2 (k) N2O4 (k). (mu nu ) (khng mu) Bit khi h nhit ca bnh th mu nu nht dn. Phn ng thun c: A. H > 0, phn ng ta nhit B. H > 0, phn ng thu nhit C. H < 0, phn ng thu nhit D. H < 0, phn ng ta nhit Cu 43: C 4 cht X, Y, Z, T c cng thc phn t dng C2H2On (n 0) -X, Y, Z u tc dng c vi dung dch AgNO3/NH3 -Z, T tc dng c vi NaOH -X tc dng c vi nc Gi tr n ca X, Y, Z, T ln lt l A. 3,4,0,2 B. 4,0,3,2 C. 0,2,3,4 D. 2,0,3,4 Cu 44: Cho cc cht: Zn, Cl2, NaOH, NaCl, Cu, HCl, NH3, AgNO3. S cht tc dng c vi dung dch Fe(NO3)2 l A. 7 B. 6 C. 5 D. 4 Cu 45: Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung dch NaHCO3. X l A. metyl axetat. B. axit acrylic. C. phenol. D. anilin. Cu 46: Cho 11,6 gam mui FeCO3 tc dng vi dung dch HNO3 va , thu c hn hp kh cha CO 2, NO v dung dch X. Cho dung dch H2SO4 d vo dung dch X c dung dch Y, dung dch Y ny ha tan c ti a m gam Cu, sinh ra sn phm kh NO duy nht. Gi tr ca m l:
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Ti liu n thi i hc nm 2012 -2013 A. 32,0 B. 28,8 C. 3,2 D. 16,0 Cu 47: X v Y l kim loi trong s cc kim loi sau : Al, Fe, Ag, Cu, Na, Ca, Zn. - X tan trong dung dch HCl, dung dch HNO3 c ngui, dd NaOH m khng tan trong H2O. - Y khng tan trong dung dch NaOH, dung dch HCl, m tan trong dung dch AgNO 3, dung dch HNO3 c ngui. X v Y ln lt l A. Al v Cu B. Na v Mg C. Ca v Ag D. Zn v Cu Cu 48: Mt hn hp X gm 2 amin k tip nhau trong dy ng ng amin no n chc. Ly 32,1 g hn hp cho vo 250 ml dung dch FeCl 3(c d) thu c mt kt ta c khi lng bng khi lng hn hp trn. Loi b kt ta ri thm t t dung dch AgNO 3 vo n khi phn ng kt thc th phi dng 1,5 lit AgNO 3 1M. Nng ban u ca FeCl3 l A. 1M B. 3M C. 2M D. 4M Cu 49: Mt hp cht thm X c CTPT C7H8O tc dng c vi dung dch NaOH. S ng phn tc dng c vi dung dch Br2 trong nc l: A. 4 B. 5 C. 6 D. 3 Cu 50: t chy hon ton m gam hn hp X gm 2 ancol A v B thuc cng dy ng ng thu c 6,72 lt CO2 v 7,65 gam nc. Mt khc khi cho m gam hn hp X tc dng vi Na d thu c 2,8 lt hiro. Bit t khi hi ca mi cht so vi hiro u nh hn 40, cc th tch kh o ktc. A v B c cng thc phn t ln lt l A. CH4O v C2H6O B. C2H6O v C3H8O C. C2H6O2 v C3H8O2 D. C3H8O2 v C4H10O2 B S 22 Cu 1: Dy cc cht u lm mt mu dung dch thuc tm l A. Benzen, but-1-en, axit fomic, p-xilen B. Etilen, axetilen, anehit fomic, toluen C. Axeton, etilen, anehit axetic, cumen D. Xiclobutan, but-1-in, m-xilen, axit axetic Cu 2: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l: A. CH3OH, C2H5OH, CH3CHO. B. C2H4(OH)2, CH3OH, CH3CHO. C. CH3CHO, C6H12O6 (glucoz), CH3OH. D. CH3CHO, C2H5OH, C2H5COOCH3. Cu 3: Tng s ht ca mt nguyn t X l 28. X l A. O B. N C. F D. Ne Cu 4: Dy gm cc cht no sau y u c tnh lng tnh ? A. AlCl3, H2O, NaHCO3, Zn(OH)2, ZnO B. ZnCl2, AlCl3, NaAlO2, NaHCO3, H2NCH2COOH C. Al, NaHCO3, NaAlO2, ZnO, Be(OH)2 D. H2O, Zn(OH)2, CH3COONH4, H2NCH2COOH, NaHCO3 Cu 5: Cho 6,4 gam dung dch ru A c nng 71,875% tc dng vi lng d Na thu c 2,8 lt H2 (ktc). S nguyn t H c trong cng thc phn t ru A l A. 6 B. 10 C. 4 D. 8 Cu 6: Cho a mol bt km vo dung dch c ha tan b mol Fe(NO 3)3. Tm iu kin lin h gia a v b sau khi kt thc phn ng khng c kim loi. A. b > 3a B. a 2b C. b 2a D. b = 2a/3 Cu 7: Cho mt lung kh CO i qua ng s ng m gam Fe 2O3 nung nng. Sau mt thi gian thu c 10,44 gam cht rn X gm Fe, FeO, Fe2O3 v Fe3O4. Ha tan ht X trong dung dch HNO3 c, nng thu c 4,368 lt NO2 (sn phm kh duy nht iu kin chun). Gi tr ca m l A. 10.8 B. 24 C. 12 D. 16 Cu 8: Cho cc cht sau : axetilen, axit fomic, fomanehit, phenyl fomat, glucz, anehit axetic, metyl axetat, mantz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l A. 8 B. 7 C. 6 D. 5 Cu 9: Cho t t 150 ml dd HCl 1M vo 500 ml dung dch A gm Na2CO3 v NaHCO3 th thu c 1,008 lt kh (ktc) v dung dch B. Cho dung dch B tc dng vi dung dch Ba(OH) 2 d th thu c 29,55 gam kt ta. Nng mol ca Na2CO3 v NaHCO3 trong dung dch A ln lt l: A. 0,18M v 0,26M B. 0,21M v 0,32M C. 0,21M v 0,18M D. 0,2M v 0,4M Cu 10: Cho tng cht Fe, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2,Fe(NO3)3, FeSO4, Fe2(SO4)3 , FeCO3 ln lt tc dng vi H2SO4 c nng . S phn ng thuc loi oxi ha kh l. A. 8 B. 6 C. 7 D. 5
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Ti liu n thi i hc nm 2012 -2013 Cu 11: Cho phng trnh ho hc: Al + HNO3 Al(NO3)3 + NO + N2O + H2O (Bit t l th tch N2O: NO = 1 : 3). Sau khi cn bng phng trnh ho hc trn vi h s cc cht l nhng s nguyn, ti gin th h s ca HNO3 l A. 64 B. 66 C. 60 D. 62 Cu 12: t chy hon ton 4,872 gam mt Hirocacbon X, hp th ton b sn phm chy bng dung dch nc vi trong. Sau phn ng thu c 27,93 gam kt ta v thy khi lng dung dch gim 5,586 gam. Cng thc phn t ca X l A. C3H6 B. C4H8 C. CH4 D. C4H10 Cu 13: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6 (benzen), CH3CHO. S cht trong dy phn ng c vi nc brom l A. 6 B. 5 C. 8 D. 7 Cu 14: a mt hn hp kh N2 v H2 c t l 1: 3 vo thp tng hp, sau phn ng thy th tch kh i ra gim 1/10 so vi ban u. Tnh thnh phn phn trm v th tch ca hn hp kh sau phn ng. A. 22.22%, 66.67%, 11.11% B. 30%, 60%, 10% C. 20%, 60%, 20% D. 33.33%, 50%, 16.67% Cu 15: in phn 2 lt dung dch hn hp gm NaCl v CuSO 4 n khi H2O b in phn hai cc th dng li, ti catt thu 1,28 gam kim loi v ant thu 0,336 lt kh ( ktc). Coi th tch dung dch khng i th pH ca dung dch thu c bng A. 12 B. 3 C. 2 D. 13 Cu 16: nhn bit ba l mt nhn: phenol, stiren, ancol benzylic, ngi ta dng mt thuc th duy nht l A. Nc brom B. Ca(OH)2 C. Dung dch NaOH D. Na Cu 17: Cht bo A c ch s axit l 7. x phng ho 10 kg A, ngi ta un nng n vi dung dch cha 1,420 kg NaOH. Sau khi phn ng xy ra hon ton trung ho hn hp, cn dng 500ml dung dch HCl 1M. Khi lng x phng (kg) thu c l A. 10,3445 B. 10,3435 C. 10,3425 D. 10,3455 Cu 18: Cho 29,8 gam hn hp 2 amin n chc k tip tc dng ht vi dung dch HCl, lm kh dung dch thu c 51,7 gam mui khan. Cng thc phn t 2 amin l A. C2H7N v C3H9N B. CH5N v C2H7N C. C3H9N v C4H11N D. C3H7N v C4H9N Cu 19: Cho 3,2 gam Cu tc dng vi 100ml dung dch hn hp HNO 3 0,8M v H2SO4 0,2M, sn phm kh duy nht l kh NO. S gam mui khan thu c l A. 5,64 B. 7,90 C. 10,08 D. 8,84 Cu 20: C 4 dung dch trong sut , mi dung dch ch cha mt cation v mt loi anion. Cc loi ion trong c 4 dung dch gm: Ca2+, Mg2+, Pb2+, Na+, SO42-, Cl-, CO32-, NO3-. l 4 dung dch g? A. BaCO3, MgSO4, NaCl, Pb(NO3)2 B. BaCl2, PbSO4, MgCl2, Na2CO3 C. BaCl2, MgSO4, Na2CO3, Pb(NO3)2 D. Mg(NO3)2, BaCl2, Na2CO3, PbSO4 Cu 21: Ho tan ht m gam Al2(SO4)3 vo nc c dung dch A . Cho 300 ml dung dch NaOH 1M vo A, thu c a gam kt ta. Mt khc, nu cho 400 ml dung dch NaOH 1M vo A, cng thu c a gam kt ta. Gi tr ca m l A. 42,75. B. 17,1. C. 21,375. D. 22,8 Cu 22: Hy cho bit, phn ng no sau y HCl ng vai tr l cht oxi ha? A. Fe + 2HCl FeCl2 + H2 B. NaOH + HCl NaCl + H2O C. MnO2 + 4HCl MnCl2 + Cl2 + 2H2O D. Fe + KNO3 + 4HCl FeCl3 + KCl + NO + 2H2O Cu 23: Ho tan 5,4 gam bt Al vo 150 ml dung dch A cha Fe(NO 3)3 1M v Cu(NO3)2 1M. Kt thc phn ng thu c m gam rn. Gi tr ca m l A. 13,80 B. 15,20 C. 10,95 D. 13,20 Cu 24: t chy hon ton mt hn hp A (glucz, anehit fomic, axit axetic) cn 2,24 lt O 2 (ktc). Dn sn phm chy qua bnh ng dung dch Ca(OH)2, thy khi lng bnh tng m gam. Gi tr ca m l A. 3.1 B. 6.2 C. 12.4 D. 4.4 Cu 25: Cho cc cng thc phn t sau : C3H7Cl , C3H8O v C3H9N. Hy cho bit s sp xp no sau y theo chiu tng dn s lng ng phn ng vi cc cng thc phn t ? A. C3H7Cl < C3H8O < C3H9N B. C3H8O < C3H7Cl < C3H9N
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Ti liu n thi i hc nm 2012 -2013 C. C3H8O < C3H9N < C3H7Cl D. C3H7Cl < C3H9N < C3H8O Cu 26: Cho hn hp kim loi Mg, Zn, Fe vo dung dch cha AgNO3 v Cu(NO3)2.. Sau khi phn ng xy ra hon ton thu c dung dch X gm 3 mui v cht rn Y gm ba kim loi. Ba mui trong X l A. Mg(NO3)2, Zn(NO3)2, Cu(NO3)2 B. Mg(NO3)2, Fe(NO3)3, AgNO3 C. Mg(NO3)2, Zn(NO3)2, Fe(NO3)2 D. Mg(NO3)2, Zn(NO3)2, Fe(NO3)3 Cu 27: Dung dch X gm Al3+, Fe3+, 0,1 mol Na+, 0,2 mol SO42-, 0,3 mol Cl-. Cho V lit dung dch NaOH 1M, vo dung dch X thu c kt ta ln nht th gi tr V l. A. 0,8 B. 0,7 C. 0,6 D. 0,5 Cu 28: Cho cc cht: amoniac (1); anilin (2); p-nitroanilin(3); p-metylanilin (4) ; metylamin (5) ; imetylamin (6) . Hy chn s sp xp cc cht trn theo th t lc baz tng dn . A. (3) < (1) < (4) <(2) < (5) < (6) B. (2) > (3) > (4) > (1) > (5) > (6) C. (2) < (3) < (4) < (1) < (5) < (6) D. (3) < (2) < (4) < (1) < (5) < (6) Cu 29: Cho cc kim loi: Cr, W , Fe , Cu , Cs . Sp xp theo chiu tng dn cng t tri sang phi l A. Cs < Cu < Fe < W < Cr B. Cs < Cu < Fe < Cr < W C. Cu < Cs < Fe < W < Cr D. Cu < Cs < Fe < Cr < W Cu 30: A l hn hp kh gm SO 2 v CO2 c t khi hi so vi H 2 l 27. Dn a mol hn hp kh A qua bnh ng 1 lt dung dch NaOH 1,5a M, sau phn ng lm bay hi cn thn dung dch thu c m gam mui. Biu thc lin h gia m v a l A. m=103,5a B. m=105a C. m=141a D. m=116a Cu 31: Khi nhit phn hon ton 100 gam mi cht sau: KClO 3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht to ra lng O2 t nht l A. KNO3 B. AgNO3 C. KClO3 D. KMnO4 Cu 32: t chy 1,6 gam mt este E n chc c 3,52 gam CO 2 v 1,152 gam H2O. Nu cho 10 gam E tc dng vi 150ml dung dch NaOH 1M , c cn dung dch sau phn ng thu c 16 gam cht rn khan . Vy cng thc ca axit to nn este trn c th l A. CH2=C(CH3)-COOH B. HOOC-CH2-CH(OH)-CH3 C. CH2=CH-COOH D. HOOC(CH2)3CH2OH Cu 33: Sc V lt CO2 ( ktc) vo 200 ml dung dch X gm Ba(OH) 2 1M v NaOH 1M . Sau phn ng thu c 19,7 gam kt ta, gi tr ca V l A. 5,6 v 1,2 B. 2,24 v 11,2 C. 2,24 v 4,48 D. 6,72 v 4,48 Cu 34: Cho 2,46 gam hn hp gm HCOOH, CH3COOH, C6H5OH, H2NCH2COOH tc dng va vi 40 ml dung dch NaOH 1M. Tng khi lng mui khan thu c sau khi phn ng l A. 3,52 gam B. 3,34 gam C. 8,42 gam D. 6,45 gam Cu 35: Ho tan hon ton hn hp X ( gm x mol Fe, y mol Cu, z mol Fe 2O3 v t mol Fe3O4 ) trong dung dch HCl khng thy kh c kh bay ra khi khi bnh, dung dch thu c ch cha 2 mui . Mi quan h gia s mol cc cht c trong hn hp X l. A. x+y =2z +3t B. x+ y = 2z +2t C. x+y =2z +2t D. x +y = z +t o t Cu 36: H s ng trc cht b oxi ha ca phn ng FexOy + CO FemOn + CO2 khi phng trnh cn bng l: A. nx my. B. m C. mx 2ny. D. my nx. Cu 37: Ru X, anehit Y, axit cacboxylic Z c cng s nguyn t H trong phn t, thuc cc dy ng ng no n chc mch h. t hon ton hn hp 3 cht ny (c s mol bng nhau) thu c t l mol CO 2:H2O=11:12 . Vy cng thc phn t ca X, Y, Z l: A. C2H6O, C3H6O, C3H6O2 B. C4H10O, C5H10O, C5H10O2 C. CH4O, C2H4O, C2H4O2 D. C3H8O, C4H8O, C4H8O2 Cu 38: Cho cc nhn xt sau: (1). C th to c ti a 2 ipeptit t phn ng trng ngng hn hp Alanin v Glyxin (2). Khc vi axt axetic, axt amino axetic c th tham gia phn ng vi axit HCl hoc phn ng trng ngng (3). Ging vi axt axetic, aminoaxt c th tc dng vi baz to mui v nc (4). Axt axetic v axt -amino glutaric c th lm i mu qu tm thnh (5). Thy phn khng hon ton peptit: Gly-Phe-Tyr-Gly-Lys-Gly-Phe-Tyr c th thu c 6 tripeptit c cha Gly
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Ti liu n thi i hc nm 2012 -2013 (6). Cho HNO3 c vo ng nghim cha anbumin thy to dung dch mu tm C bao nhiu nhn xt ng? A. 4 B. 6 C. 5 D. 3 Cu 39: C 45,75 gam cao su buna-S phn ng va ht vi 20 gam brom trong CCl4. T l mt xch butaien v stiren trong cao su buna-S l A. 3 : 5 B. 1 : 2 C. 2 : 3 D. 1 : 3 Cu 40: Ha tan hon ton hn hp gm x mol Hg 2S v 0,04 mol FeS2 bng dung dch HNO3 m c, un nng, ch thu cc mui sunfat kim loi c ha tr cao nht v c kh V lt NO2 thot ra (ktc). Tr s ca V l: A. 17,92 lt B. 8,96 lt C. 20,16 lt D. 2,24 lt Cu 41: C cc nhn nh sau: 1)Cu hnh electron ca ion X2+ l 1s22s22p63s23p63d6. Trong bng tun hon cc nguyn t ho hc, nguyn t X thuc chu k 4, nhm VIIIB. 2)Cc ion v nguyn t: Ne , Na+ , F c im chung l c cng s electron. 3)Khi t chy ancol no th ta c n(H2O) : n(CO2)>1. 4)Dy gm cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l K, Mg, Si, 5)Tnh baz ca dy cc hiroxit: NaOH, Mg(OH)2, Al(OH)3 gim dn. Cho: N (Z = 7), F (Z=9), Ne (Z=10), Na (Z=11), Mg (Z=12), Al (Z=13), K (Z = 19), Si (Z = 14). S nhn nh ng: A. 3. B. 5. C. 4. D. 2. Cu 42: Chn pht biu ng: A. Tnh oxi ha ca Ag+ > Cu2+ > Fe3+ > Ni2+ > Fe2+ B. Tnh oxi ha ca Ag+ > I2 > Fe3+ > Cu2+ > S2C. Tnh kh ca K > Mg > Zn > Ni > Fe > Hg D. Tnh kh ca K > Fe > Cu > I- > Fe2+ > Ag Cu 43: Cho Cacbon (C) ln lt tc dng vi Al, H 2O, CuO, HNO3 c, H2SO4 c, KClO3, CO2 iu kin thch hp. S phn ng m trong C ng vai tr l cht kh? A. 4 B. 7 C. 5 D. 6 Cu 44: Cho X (ch C, H, O) ch cha 1 loi nhm chc.t chy X th thu c s mol H 2O gp 1,5 mol CO2. Cho 0,15 mol X tc dng va Na thu c m gam rn v 3,36 lit H2(ktc). Gi tr m l. A.15,9 B.15,6 C.18,0 D.10,2 Cu 45: Ch dng mt thuc th phn bit cc kim loi sau: Mg, Zn, Fe, Ba? A. Dung dch H2SO4 long B. Nc C. Dung dch NaOH D. Dung dch HCl Cu 46: Cho 19,2 gam Cu vo 500 ml dung dch NaNO3 1M, sau thm vo 500ml dung dch HCl 2M . Kt thc phn ng thu c dung dch X v kh NO duy nht, phi thm bao nhiu ml dung dch NaOH 1M vo X kt ta ht ion Cu2+ A. 120 B. 400 C. 600 D. 800 Cu 47: Cho Na d tc dng vi a gam dung dch CH 3COOH. Kt thc phn ng, thy khi lng H2 sinh ra l
11a . 240

Vy nng C% dung dch axit l A. 36% B. 10% C. 4.58% D. 25% Cu 48: Thy phn hon ton mt lng mantoz, sau cho ton b lng glucoz thu c ln men thnh ancol etylic th thu c 100 ml ancol 460. Khi lng ring ca ancol l 0,8gam/ml. Hp th ton b kh CO2 vo dung dch NaOH d thu c mui c khi lng l A. 84,8 gam B. 106 gam C. 212 gam D. 169,6 gam Cu 49: t chy hon ton 1 mol ancol no, mch h A cn 3.5 mol O2. Cng thc phn t ca A l A. C3H6O2 B. C3H8O3 C. C2H6O D. C2H6O2 Cu 50: Cho 0,1 mol cht X ( CH6O3N2) tc dng vi dung dch cha 0,2 mol NaOH un nng thu c cht kh lm xanh giy qu tm m v dung dch Y. C cn dung dch Y thu c m gam rn khan. Gi tr ca m l A. 8,5 B. 12,5 C. 15 D. 21,8 B S 23 Cu 1: Cho Cacbon (C) ln lt tc dng vi Al, H 2O, CuO, HNO3 c, H2SO4 c, KClO3, CO2 iu kin thch hp. S phn ng m trong C ng vai tr l cht kh? A. 6. B. 5. C. 4. D. 7.
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Ti liu n thi i hc nm 2012 -2013 Cu 2: t chy hon ton x mol axit cacboxylic E, thu c 2x mol CO2. Cho x mol E tc dng vi NaHCO3 d thu c 2x mol CO2. Tn ca E l A. axit aipic. B. axit oxalic. C. axit axetic. D. axit fomic. Cu 3: Cho 12 gam hn hp Fe v Cu vo 200ml dung dch HNO 3 2M, thu c mt cht kh (sn phm kh duy nht) khng mu, ha nu trong khng kh, v c mt kim loi d. Sau cho thm dung dch H 2SO4 2M, thy cht kh trn tip tc thot ra, ho tan ht kim loi cn 33,33ml. Khi lng kim loi Fe trong hn hp l A. 2,8 gam. B. 8,4 gam. C. 5,6 gam. D. 1,4 gam. Cu 4: Cho dy cc cht: NaOH, Zn(OH)2, NaHCO3, Al(OH)3, Al, NaHSO4, Cr(OH)3. S cht trong dy c tnh cht lng tnh l A. 5. B. 3. C. 4. D. 2. Cu 5: Cho m gam Na vo 160 ml dung dch gm Fe 2(SO4)3 0,125M v Al2(SO4)3 0,25M. Tch kt ta ri nung n khi lng khng i th thu c 5,24 gam cht rn. Cc phn ng hon ton, gi tr m l A. 11,5. B. 9,43. C. 10,35. D. 9,2. 0 Cu 6: Ln men mt lng glucoz thnh ancol etylic th thu c 100 ml ancol 46 . Khi lng ring ca ancol nguyn cht l 0,8 gam/ml. Hp th ton b kh CO2 sinh ra trong qu trnh ln men vo dung dch NaOH d thu c mui c khi lng l (cc phn ng xy ra hon ton) A. 84,8 gam. B. 169,6 gam. C. 106 gam. D. 212 gam. Cu 7: Cho 25,65 gam mui gm H2NCH2COONa v H2NCH2CH2COONa tc dng va vi 250 ml dung dch H2SO4 1M. Sau phn ng c cn dung dch th khi lng mui do H2NCH2COONa to thnh l A. 29,25 gam. B. 18,6 gam. C. 37,9 gam. D. 12,4 gam. Cu 8: Cho cc monome sau: stiren, toluen, metyl axetat, vinyl axetat, metyl metacrylat, metyl acrylat, propilen, benzen, axit etanoic, axit -aminocaproic. S monome tham gia phn ng trng hp l A. 8. B. 7. C. 5. D. 6. Cu 9: Cho 13,8 gam cht hu c X c cng thc phn t C 7H8 tc dng vi mt lng d dung dch AgNO 3 trong NH3, thu c 45,9 gam kt ta. X c bao nhiu ng phn cu to tha mn tnh cht trn? A. 6. B. 2. C. 5. D. 4. Cu 10: t chy hon ton 2,34 gam hn hp gm metyl axetat, etyl fomat v vinyl axetat ri hp th ton b sn phm chy vo dung dch Ca(OH)2 d. Sau phn ng thu c 10 gam kt ta v dung dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban u thay i nh th no? A. Gim 3,98 gam. B. Tng 3,98 gam. C. Gim 3,38 gam. D. Tng 2,92 gam. Cu 11: Ch dng mt thuc th phn bit cc kim loi sau: Mg, Zn, Fe, Ba? A. Dung dch H2SO4 long. B. Dung dch NaCl. C. Nc. D. Dung dch NaOH. Cu 12: Cho cn bng ha hc sau: N2 (kh) + 3H2 (kh) 2NH3 (kh) ; H < 0. Cho cc bin php : (1) tng nhit ; (2) tng p sut chung ca h phn ng; (3) h nhit ; (4) dng thm cht xc tc bt Fe; (5) gim nng NH3; (6) gim p sut chung ca h phn ng. Nhng bin php no lm cn bng trn chuyn dch theo chiu thun? A. (1), (2), (4), (5). B. (2), (3), (4), (6). C. (2), (3), (5). D. (1), (2), (4). Cu 13: Cho 100 gam dung dch NH4HSO4 11,5% vo 100 gam dung dch Ba(OH)2 13,68% v un nh. Tnh th tch kh mi khai bay ra (ktc) v khi lng kt ta thu c? A. 2,24 lt kh v 23,3 gam kt ta. B. 1,792 lt kh v 18,64 gam kt ta. C. 2,24 lt kh v 18,64 gam kt ta. D. 1,344 lt kh v 18,64 gam kt ta. Cu 14: Cho Isopren phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (k c ng phn hnh hc) thu c l A. 3. B. 2. C. 5. D. 4. Cu 15: Cho dy cc cht: metylamoni clorua, phenyl clorua, isopropyl clorua, m-crezol, ancol benzylic, natri phenolat, anlyl clorua. S cht trong dy tc dng c vi dung dch NaOH long, un nng l A. 4. B. 6. C. 3. D. 5. Cu 16: Cho cc nhn xt sau: (1). C th to c ti a 2 ipeptit t phn ng trng ngng hn hp Alanin v Glyxin (2). Khc vi axit axetic, axt amino axetic c th tham gia phn ng vi axit HCl (3). Ging vi axit axetic, aminoaxit c th tc dng vi baz to mui v nc
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Ti liu n thi i hc nm 2012 -2013 (4). Axit axetic v axit -amino glutaric khng lm i mu qu tm thnh (5). Thy phn khng hon ton peptit: Gly-Ala-Gly-Ala-Gly c th thu c ti a 2 ipeptit (6). Cho Cu(OH)2 vo ng nghim cha anbumin thy to dung dch mu xanh thm S nhn xt khng ng l A. 4. B. 5. C. 6. D. 3. Cu 17: Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc thch hp nung nng, thu c hn hp Y gm C2H4, C2H6, C2H2 v H2. Sc Y vo dung dch brom d th khi lng bnh brom tng m gam so vi ban u v thot ra 4,48 lt hn hp kh (ktc) c t khi so vi H 2 l 8. t chy hon ton Y cn 33,6 lt O2 (ktc). Gi tr m l A. 14,0. B. 9,8. C. 10,8. D. 13,4. Cu 18: Sn phm hu c thu c khi cho hp cht hu c X cha vng benzen v c cng thc CH3COOC6H4CH2Cl tc dng vi dung dch NaOH long, d, ung nng l A. CH3COOH, HOC6H4CH2OH . B. CH3COONa, NaOC6H4CH2ONa. C. CH3COONa, HOC6H4CH2OH. D. CH3COONa, NaOC6H4CH2OH. Cu 19: un 1 mol hn hp C2H5OH v C4H9OH (t l mol tng ng l 3:2) vi H2SO4 c 140oC thu c m gam ete, bit hiu sut phn ng ca C2H5OH l 60% v ca C4H9OH l 40% . Gi tr ca m l A. 53,76 gam. B. 19,04 gam. C. 28,4 gam. D. 23,72 gam. Cu 20: Thc hin cc th nghim sau: (1). Sc kh C2H4 vo dung dch KMnO4. (2). Sc CO2 d vo dung dch NaAlO2 (3). Chiu sng vo hn hp kh (CH4; Cl2) (4). Sc kh H2S vo dung dch FeCl3. (5). Sc kh NH3 vo dung dch AlCl3. (6). Sc kh SO2 vo dung dch H2S. S th nghim c phn ng oxi ho- kh xy ra l A. 1, 2, 3, 4. B. 1, 3, 4, 6. C. 2, 4, 5, 6. D. 1, 2, 4, 5. Cu 21: Dy gm cc cht u c th lm mt tnh cng tm thi ca nc l A. KCl, Ca(OH)2, Na2CO3. B. NaOH, Na3PO4, Na2CO3. C. HCl, Ca(OH)2, Na2CO3. D. HCl, NaOH, Na2CO3. Cu 22: C cc nhn nh sau: (1) Cu hnh electron ca ion X2+ l [Ar]3d6. Trong bng tun hon, nguyn t X thuc chu k 4, nhm VIIIB. (2) Cc ion v nguyn t: Ne , Na+ , F c im chung l c cng s electron. (3) Cc nguyn t m nguyn t c 1,2,3 electron lp ngoi cng u l kim loi (4) Dy cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l K, Mg, Si, N. (5) Tnh baz ca dy cc hiroxit: NaOH, Mg(OH)2, Al(OH)3 gim dn. Cho: N (Z=7), F (Z=9), Ne (Z=10), Na (Z=11), Mg (Z=12), Al (Z=13), K (Z=19), Si (Z=14), Ar (Z=18) S nhn nh ng: A. 3. B. 4. C. 5. D. 2. Cu 23: Thc hin cc th nghim sau: (1) t dy st trong kh clo d. (2) t nng hn hp bt Fe v S (khng c oxi). (3) Cho FeO vo dung dch HNO3 long. (4) Cho Fe vo dung dch AgNO3 d. (5) Cho Fe3O4 vo dung dch HI (long, d). C bao nhiu th nghim to ra mui st (III)? A. 1. B. 4. C. 2. D. 3. Cu 24: S cng thc cu to ca hp cht hu c X c cng thc phn t l C 8H10O, c cha vng benzen v tc dng c vi dung dch NaOH l A. 9. B. 6. C. 7. D. 8. Cu 25: Cho cc dung dch: C6H5NH2 (anilin), CH3NH2, NaOH, C2H5OH, Na2CO3 v H2NCH2COOH. Trong cc dung dch trn, s dung dch c th lm i mu phenolphtalein l A. 4. B. 3. C. 5. D. 2. Cu 26: Hn hp cht rn X gm BaCO3, Fe(OH)2, Al(OH)3, CuO, MgCO3. Nung X trong khng kh n khi lng khng i c hn hp rn Y. Cho Y vo nc d c dung dch Z cha 2 cht tan v phn khng tan E. E cha A. Fe2O3, Cu, MgO. B. FeO, CuO, MgO. C. Fe2O3, CuO, MgO D. Fe2O3, CuO, MgO, Al2O3. Cu 27: Tin hnh cc th nghim sau: (1) Cho dung dch NaHSO4 vo dung dch Ba(HCO3)2.
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Ti liu n thi i hc nm 2012 -2013 (2) Sc kh axetilen vo dung dch AgNO3 trong NH3. (3) Sc kh H2S vo dung dch MgCl2. (4) Sc kh NH3 ti d vo dung dch CuCl2. (5) Sc kh CO2 ti d vo dung dch NaAlO2. (6) Sc kh SO2 vo dung dch KMnO4/H2SO4. Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta? A. 6. B. 3. C. 4. D. 5. Cu 28: Cho dy gm cc cht: Na, Ag, O2, HCl, Cu(OH)2, Mg(HCO3)2, CuO, NaCl, C2H5OH, C6H5OH, C6H5NH2, CH3ONa, HCOONa. S cht tc dng c vi dung dch axit axetic (trong iu kin thch hp) l A. 10. B. 11. C. 9. D. 8. Cu 29: Thm t t tng git ca 200 ml dung dch HCl 1M vo 100 dung dch cha Na 2CO3 1,2M v NaHCO3 0,6M, sau phn ng hon ton thu c dung dch X. Cho dung dch nc vi trong d vo dung dch X th thu c bao nhiu gam kt ta? A. 5,5 gam. B. 10 gam. C. 8 gam. D. 5 gam. Cu 30: Hn hp X gm: HCHO, CH3COOH, HCOOCH3 v CH3CH(OH)COOH. t chy hon ton hn hp X cn V lt O2 (ktc) sau phn ng thu c CO 2 v H2O. Hp th ht sn phm chy vo nc vi trong d thu c 30 gam kt ta. Vy gi tr ca V tng ng l A. 8,40 lt. B. 6,72 lt. C. 7,84 lt. D. 5,60 lt. Cu 31: Este X c to thnh t axit oxalic v hai ancol n chc. Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH d, sau khi phn ng hon ton c 9,6 gam NaOH phn ng. Gi tr ca m l A. 14,5. B. 17,5. C. 15,84. D. 31,68. Cu 32: Hn hp gm hai axit cacboxylic no, mch h X, Y. t chy hon ton 1 mol X hay 1 mol Y u thu c 1 mol H2O. Nu t chy hon ton 13,6 gam hn hp X, Y thu c 6,72 lt CO 2 (ktc). Trung ho hn hp axit trn cn V lt dung dch NaOH 1M. Gi tr ca V l A. 200 ml. B. 400 ml. C. 600 ml. D. 300 ml. Cu 33: Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l A. 0,70. B. 0,50. C. 0,65. D. 0,55. Cu 34: Pht biu no sau y l sai? A. Thch cao sng ( CaSO4.2H2O) c dng b bt, c tng. B. Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thy tinh. C. Thnh phn chnh ca qung olomit l CaCO3.MgCO3. D. Cc kim loi kim u c cu trc mng tinh th lp phng tm khi. Cu 35: Hn hp X c C2H5OH, C2H3COOH, CH3CHO trong C2H5OH chim 50% theo s mol. t chy hon ton m gam hn hp X thu c 5,4 gam H 2O v 5,824 lt CO2 (ktc). Mt khc, cho 14,9 gam hn hp X tc dng vi lng d Na thu c V lt kh ( ktc). Gi tr ca V l A. 1,68. B. 2,24. C. 1,12. D. 2,688. Cu 36: Nha phenolfomanehit c iu ch bng cch un nng phenol d vi dung dch: A. CH3COOH trong mi trng axit. B. CH3CHO trong mi trng axit. C. HCOOH trong mi trng axit. D. HCHO trong mi trng axit. Cu 37: Oxi ho 25,6 gam CH3OH (c xc tc thch hp) thu c hn hp sn phm X gm (HCHO, HCOOH, H2O, CH3OH d). Chia X thnh hai phn bng nhau. Phn 1, tc dng vi lng d dung dch AgNO 3 trong NH3 un nng thu c m gam Ag. Phn 2, tc dng va vi 100ml dung dch KOH 1M. Hiu sut qu trnh oxi ho CH3OH l 75%. Gi tr ca m l A. 108. B. 129,6. C. 64,8. D. 32,4. Cu 38: Cho 2,8 gam bt st tc dng hon ton vi V ml dung dch HNO 3 0,5M thu c sn phm kh NO duy nht v dung dch X. X c th tc dng va vi dung dch cha 0,03 mol AgNO3. Gi tr ca V l A. 420 ml. B. 340 ml. C. 320 ml. D. 280 ml. Cu 39: Dy gm cc cht kh c lm kh bng axit sunfuric c l A. CO2, NH3, H2, Cl2. B. N2, SO3, CO2, SO2. C. SO3, H2S, CO2, O2. D. CO2, HCl, N2, SO2. Cu 40: Cho cc cht sau: imetylete (1), ancol etylic (2), ancol metylic (3), axit axetic (4). Cc cht trn c xp theo nhit si tng dn (t tri sang phi) l A. 4, 2, 3, 1. B. 1, 3, 2, 4. C. 2, 3, 4, 1. D. 1, 2, 4, 3.
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Ti liu n thi i hc nm 2012 -2013 Cu 41: in phn dung dch gm 11,7 gam NaCl v 28,2 gam Cu(NO 3)2 (in cc tr, mng ngn xp) n kh khi lng dung dch gim i 15,1 gam th ngng in phn (gi thit lng nc bay hi khng ng k). Khi lng kim loi thot ra cactot l A. 7,68. B. 6,4. C. 9,6. D. 15,1. Cu 42: Nu vt lm bng hp kim Fe-Zn b n mn in ho th trong qu trnh n mn A. Km ng vai tr catot v b oxi ho. B. St ng vai tr anot v b oxi ho. C. Km ng vai tr anot v b oxi ho. D. St ng vai tr catot v b oxi ho. Cu 43: Pht biu no sau y l ng? A. C th dng cc chai lo thy tinh ng dung dch HF B. Bn knh nguyn t ca clo ln hn bn knh nguyn t ca brom. C. Tnh axit ca HF mnh hn tnh axit ca HCl. D. Tnh kh ca ion Br- ln hn tnh kh ca ion Cl-. Cu 44: Cc kh thi cng nghip v ca cc ng c t, xe my...l nguyn nhn ch yu gy ra ma axit. Nhng thnh phn ha hc ch yu trong cc kh thi trc tip gy ra ma axit l A. NO2, CO2, CO. B. NO, NO2, SO2. C. SO2, CO, NO. D. SO2, CO, NO2. Cu 45: Cho 17,6 gam hn hp bt X gm Fe v Mg tc dng vi 500 ml dung dch CuSO 4 aM. Sau khi phn ng hon ton thu c dung dch Y c cha hai mui v 25,2 gam cht rn Z. Cho Y tc dng vi dung dch NaOH d, ly kt ta em nung nng trong khng kh ti khi lng khng i thu c 22,0 gam cht rn. Gi tr ca a l A. 1,5. B. 1,0. C. 0,7. D. 0,75. Cu 46: Cho cc cht sau y: (1) CH 3COOH; (2) C2H5OH; (3) C2H2; (4) CH3COONa; (5) HCOOCH=CH2; (6) CH3COONH4. Dy gm cc cht c to ra t CH3CHO ch bng mt phn ng l A. 1, 2, 4, 6. B. 1, 2, 3, 4, 5, 6. C. 1, 2. D. 1, 2, 6. Cu 47: Dy gm cc kim loi u tc dng c vi dung dch H 2SO4 long nhng khng tc dng vi dung dch H2SO4 c, ngui l A. Fe, Al, Cr. B. Cu, Fe, Al. C. Fe, Mg, Al. D. Cu, Pb, Ag. Cu 48: Ho tan Fe3O4 trong lng d dung dch H2SO4 long thu c dung dch X. Dung dch X tc dng c vi bao nhiu cht trong s cc cht sau: Cu, NaOH, Br2, AgNO3, KMnO4, MgSO4, Mg(NO3)2, Al? A. 5. B. 7. C. 8. D. 6. Cu 49: Cho 32,64 gam hn hp X gm FeO, Fe 3O4, Fe2O3 tc dng vi dung dch HCl d thu c dung dch c cha 63,99 mui. Nu cho hn hp X trn tc dng vi lng dch dch Y c cha HCl, H 2SO4 long va , thu c dung dch c cha 70,74 gam mui. Cc phn ng hon ton, t l mol gia HCl v H 2SO4 c trong dung dch Y l A. 20/9. B. 9/20. C. 5/3. D. 17/20. 0 Cu 50: Cho 672 ml kh Clo (ktc) i qua 200 ml dung dch KOH 100 C. Sau khi phn ng xy ra hon ton thu c dung dch X c pH = 13. Th tch dung dch khng thay i trong qu trnh phn ng, lng cht rn thu c khi c cn dung dch X l A. 6,07 gam. B. 1,97 gam. C. 3,09 gam. D. 4,95 gam. B S 24 Cu 1: Ha tan ht 19,9 gam hn hp gm Na, K, Ba vo nc thu c 4 lt dung dch X c pH = 13. Trung ha dung dch X bng axit H2SO4 va sau phn ng thu c 23,3 gam kt ta. Phn trm khi lng ca Na trong hn hp trn l A. 11,56%. B. 16%. C. 17,8%. D. 62,55%. Cu 2: Cho 13,12 gam hn hp X gm Fe, Fe3O4, Fe2O3 vo dung dch HNO3 long, d thu c sn phm kh gm hai kh NO, N2O c th tch V lt (ktc) v c t khi so vi H 2 l 18,5. Mt khc nu cho cng lng X trn tc dng vi kh CO d th sau khi phn ng hon ton thu c 9,8 gam Fe. Gi tr ca V l A. 0,448. B. 3,36. C. 2,24. D. 3,136. Cu 3: Cu no sau y l ng khi ni v hiu ng nh knh v ma axit? A. Kh gy ra hiu ng nh knh l SO2 v kh gy ra ma axit l CO2; NO2 B. Kh gy ra hiu ng nh knh l NO2 v kh gy ra ma axit l SO2; CO2 C. Kh gy ra hiu ng nh knh l CO2 v kh gy ra ma axit l SO2; NO2 D. Kh gy ra hiu ng nh knh l SO2; CO2 v kh gy ra ma axit l NO2
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Ti liu n thi i hc nm 2012 -2013 Cu 4: Pht biu ng l A. Ngi ta s dng ozon ty trng tinh bt v du n. B. O2 c tnh oxi ha mnh hn O3 C. O2 v O3 c tnh oxi ha mnh nh nhau. D. trng thi rn, NaCl tn ti di dng tinh th phn t. Cu 5: Ha tan hon ton m gam hn hp gm Na, Ba, K vo nc thu c x gam kh H 2. Nu cho m gam hn hp trn tc dng vi dung dch HCl d, ri c cn dung dch sau phn ng th khi lng mui khan thu c l A. (m + 35,5x) gam. B. (m + 142x) gam. C. (m + 17,75x) gam. D. (m + 71x) gam. Cu 6: Bnh kn c th tch khng i l 0,5 lt cha 0,5 mol H 2 v 0,5 mol N2 t0C, khi trng thi cn bng c 0,2 mol NH3 c to thnh. Gi tr ca hng s cn bng K l A. 4,25. B. 12,5. C. 0,32. D. 3,125. Cu 7: C bao nhiu cht l dn xut ca benzen c cng thc phn t C 8H10O khi b oxi ha bi CuO un nng cho sn phm c kh nng tham gia phn ng trng bc? A. 4. B. 3. C. 5. D. 1. Cu 8: Cho Cr(Z = 24), Cu(Z = 29), Fe (Z = 26), Br (Z = 35). Cu hnh e sai l A. Cr: 1s22s22p63s23p63d54s1 B. Br: 1s22s22p63s23p63d104s24p6 3+ 2 2 6 2 6 5 + 2 2 6 2 6 9 1 C. Fe : 1s 2s 2p 3s 3p 3d D. Cu : 1s 2s 2p 3s 3p 3d 4s Cu 9: Nung nng a mol hn hp X gm C 2H2 v H2 trong bnh kn c xc tc thch hp thu c hn hp kh Y. Dn Y qua lng d dung dch AgNO 3 trong NH3, sau khi phn ng hon ton thu c 24 gam kt ta v hn hp kh Z. Hn hp Z lm mt mu ti a 40 gam brom trong dung dch v cn li hn hp kh T. t chy hon ton T thu c 11,7 gam nc. Vy gi tr ca a l A. 1. B. 0,9. C. 1,25. D. 2,5. Cu 10: Khi thy phn khng hon ton pentapeptit Ala-Gly-Val-Gly-Ala c ti a bao nhiu tripeptit khc nhau? A. 4. B. 3. C. 1. D. 2. + 6 Cu 11: Cation M c cu hnh electron lp v ngoi cng l 2p . V tr ca M trong bng tun hon l A. chu k 3, nhm IIIA B. chu k 2, nhm VIIA C. chu k 3, nhm IIA D. chu k 3, nhm IA Cu 12: Hon tan hon ton 8,1 gam Al bng dung dch cha m gam NaOH (d) thu c dung dch X . Cho 900 ml dung dch HCl 1M vo X thu c 15,6 gam kt ta. Gi tr ln nht ca m l A. 32. B. 40. C. 24. D. 60. Cu 13: Mt anehit mch h X c t khi hi so vi H2 nh hn 30. X phn ng ti a vi H2 theo t l mol 1:3. Cho 0,1 mol X tc dng vi dung dch AgNO3 d trong NH3 th thu c bao nhiu gam cht rn? A. 19,4 gam. B. 41 gam. C. 39,3 gam. D. 21,6 gam. Cu 14: ha tan ht mt mu km trong dung dch HCl 20 0C cn 6 pht. Cng mu km tan trong dung dch axit ni trn 300C trong 3 pht. Hi ha tan ht mu km trong dung dch axit ni trn 800C cn thi gian bao lu? A. 9,45 giy. B. 5,625 giy. C. 45 giy. D. 25 giy. Cu 15: X phng ha 4.2g este hu c no n chc X bng dd NaOH d thu c 4.76g mui. Cng thc ca X l A. HCOOCH3 B. C2H5COOCH3 C. CH3COOCH3 D. CH3COOC2H5 Cu 16: Sp xp cc kim loi sau theo chiu tnh kim loi tng dn: X(Z = 19); Y(Z = 37); Z(Z = 20); T(Z = 12). A. T, X, Z, Y. B. D. Y, X, Z, T. C. Y, Z, X, D. T, Z, X, Y. Cu 17: Oxi ha 0,1 mol mt ancol n chc X bng O 2 c xc tc ph hp thu c 4,4 gam hn hp gm anehit, ancol d v nc. Hiu sut ca phn ng oxi ha ancol l A. 65%. B. 40%. C. 75%. D. 50%. Cu 18: Nhng ion no sau y cng tn ti c trong mt dd: + 3+ A. S2 , Na + , Cl , Cu 2+ B. SO 2 4 , Na , Fe , OH + 2+ C. NO3 , Na + , Cl , Al3+ D. SO 2 , PO3 4 , Na , Zn 4 Cu 19: Ha tan 1,57 gam hn hp bt kim loi gm Al, Zn vo 100 ml dung dch hn hp AgNO 3 0,1M v Cu(NO3)2 0,3M. Sau khi phn ng xy ra hon ton thu c cht rn X v dung dch Y ch cha hai mui.
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Ti liu n thi i hc nm 2012 -2013 Ngm X trong dung dch H 2SO4 long khng thy c kh thot ra. Cho dung dch NH 3 d vo Y th thu c bao nhiu gam kt ta? A. 1,56 gam. B. 1,96 gam. C. 2,74 gam. D. 0,78 gam. Cu 20: C bao nhiu cht hu c mch h c cng thc phn t C 3HyO m bng mt phn ng to ra propan1-ol? A. 5. B. 2. C. 4. D. 3. Cu 21: Cho cc dung dch: glucoz, fructoz, mantoz, saccaroz, phenol, axit fomic, axetanehit, ancol anlylic, anilin. S dung dch trn lm mt mu dung dch brom vi dung mi nc l A. 7 B. 8 C. 6 D. 5 Cu 22: Mt loi tinh bt c phn t khi bng 810000. S mt xch trong phn t tinh bt ni trn l A. 4500 B. 50000 C. 5000 D. 4000. Cu 23: C bao nhiu nguyn t nhm B c lp electron ngoi cng l 4s2? A. 8. B. 2. C. 10. D. 3. Cu 24: Cho mt s tnh cht : l cht kt tinh khng mu (1) ; c v ngt (2) ; tan trong nc (3) ; ho tan Cu(OH)2 (4) ; lm mt mu nc brom (5) ; tham gia phn ng trng bc (6) . Cc tnh cht ca saccaroz l A. (1), (2), 3), (4) v (5). B. (1), (2), (3) v (4). C. (2), (3), (4), (5) v (6). D. (1), (2), (3), (4), (5) v (6). Cu 25: t chy hon ton 9,3 gam hn hp X gm hai este n chc to bi cng mt axit cacboxylic v hai ancol l ng ng k tip thu c 0,45 mol CO 2 v 0,35 mol H2O. Vy phn trm khi lng ca este c phn t khi ln hn trong X l A. 46,24% B. 53,76%. C. 50%. D. 60%. Cu 26: Nhn xt no sau y khng ng? A. Tnh axit tng dn theo chiu phenol, axit cacbonic, axit axetic, axit sunfuric. B. Tnh baz tng dn theo chiu iphenylamin, anilin, amoniac, metylamin. C. Lin kt hiro gia cc phn t axit axetic bn hn gia cc phn t ancol etylic. D. C th dng dung dch BaCl2 phn bit hai kh SO2 v SO3. Cu 27: C th dng H2SO4 c lm kh cht no trong cc cht sau y? A. NaBr. B. H2S. C. NH3. D. HCl. Cu 28: Lng d dung dch no sau y: (1) NaOH; (2) HCl, (3) AgNO 3; (4) Fe(NO3)3 lm sch c Ag c ln Al, Zn? A. Ch (2). B. Ch (1). C. (1) hoc (2) hoc (3) hoc (4). D. Ch (3). Cu 29: Nhit phn hon ton m gam mt mui amoni ca axit cacbonic sau dn ton b sn phm vo 50 gam dung dch H2SO4 19,6% ch to ra mt mui axit. Gi tr ca m l A. 14,4. B. 7,9. C. 11,25. D. 9,6. Cu 30: Pht biu no sau y ng? A. Cho lng trng trng vo Cu(OH)2 cho kt ta gch. B. Trong phn t peptit mch h cha n gc -aminoaxit c s lin kt peptit bng n. C. Khng th dng Cu(OH)2 phn bit dung dch tripeptit v dung dch CH3COOH. D. Trong phn t peptit mch h cha n gc -aminoaxit c s lin kt peptit bng n-1. Cu 31: un nng hn hp kh X gm C 2H2, C2H4, CH2=CH-O-CH3, H2 trong mt bnh kn dung tch khng i v c cht xc tc thch hp. Sau phn ng a bnh v nhit ban u thu c hn hp kh Y khng cha H2 v p sut trong bnh gim 20% so vi ban u. Phn trm th tch H2 trong hn hp ban u l A. 50%. B. 30%. C. 25%. D. 20%. Cu 32: Cho cc cht: CH3COONa, Al2(SO4)3, NaHSO4, Na2HPO4, Na2SO4, NaHCO3, Na2HPO3. C bao nhiu cht l mui trung ha? A. 5. B. 3. C. 2. D. 4. Cu 33: t chy hon ton m gam hn hp X gm hai ancol no, mch h (phn t hn km nhau mt nhm -OH) thu c 0,3 mol CO2 v 0,5 mol H2O. Oxi ha m gam hn hp X thu c hn hp Y. Cho Y tc dng vi lng d dung dch AgNO3 trong NH3 thu c a gam Ag. Gi tr ln nht ca a l A. 64,8. B. 43,2. C. 108. D. 86,4.

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Ti liu n thi i hc nm 2012 -2013 Cu 34: un nng hn hp gm Fe v S c t l mol 1:2 trong bnh kn khng cha khng kh thu c hn hp X . Cho hn hp X tc dng vi dung dch HCl d n khi phn ng xy ra hon ton thy khi lng cht rn gim 60%. Hiu sut phn ng gia Fe v S l A. 50%. B. 25%. C. 60%. D. 80%. Cu 35: Cho phn ng: CH3CH=C(CH3)CH3 + K2Cr2O7 + H2SO4 CH3COOH + CH3COCH3 + Cr2(SO4)3 + K2SO4 + H2O Tng cc h s l s nguyn nh nht ng trc cht kh v cht oxi ha phn ng trn cn bng l A. 14. B. 2. C. 6. D. 5. Cu 36: t chy mt hp cht hu c X (cha C,H,O) thu c H 2O v CO2 c s mol bng nhau th X khng th l A. axit cacboxylic no, mch h, n chc. B. ete no, mch h, a chc. C. este no, mch h, n chc. D. anehit no, mch h, n chc. Cu 37: Trong cc cht di y, cht no l ipeptit ? A. H2NCH2CONHCH(CH3)COOH. B. H2NCH2CONHCH(CH3)CONHCH2COOH. C. H2NCH2CONHCH2CH(CH3)COOH. D. H2NCH(CH3)CONHCH2CH2COOH. Cu 38: Mt anehit X trong oxi chim 37,21% v khi lng. 1 mol X tham gia phn ng trng bc to ti a 4 mol Ag. Khi lng mui hu c sinh ra khi cho 0,25 mol X tc dng vi lng d AgNO 3 trong dung dch NH3 l A. 41 gam. B. 34,5 gam. C. 30,25 gam. D. 38 gam. Cu 39: Nhit phn hon ton hn hp 2 mui KNO3 v Fe(NO3)2 sau phn ng thu c hn hp X gm hai kh c t khi so vi H2 bng 21,6. Phn trm khi lng ca Fe(NO3)2 l A. 60%. B. 34,3%. C. 78,09%. D. 40%. Cu 40: Hp th hon ton 3,36 lt kh CO2 ( ktc) vo m gam dung dch hn hp cha 0,05 mol NaOH; 0,05 mol KOH; 0,05 mol Ba(OH)2. Dung dch sau phn ng c khi lng A. (m - 5,05) gam. B. (m + 6,6) gam. C. (m - 11,65) gam. D. (m - 3,25) gam. Cu 41: Trong hp cht sau y c my lin kt peptit? H2N-CH2-CO-NH-CH-CO-NH-CH-CO-NH-CH2-CH2-COOH CH3 C6H5 A. 2 B. 3 C. 1 D. 4 Cu 42: Cho 8,55 gam dung dch cacbohirat X tc dng hon ton vi dung dch HCl, ri cho sn phm thu c tc dng vi lng d AgNO 3/NH3 to thnh 10,8 gam Ag kt ta. X c th l cht no trong cc cht sau? A. Fructoz B. Glucoz C. Saccaroz D. Xenluloz Cu 43: Hn hp X gm H2 v N2 c khi lng mol trung bnh bng 7,2. Sau khi tin hnh phn ng tng hp NH3 c hn hp Y c khi lng mol trung bnh bng 8, hiu sut ca phn ng tng hp l ? A. 15%. B. 10%. C. 25%. D. 20%. Cu 44: Cho 50 ml dung dch FeCl2 1M vo dung dch AgNO3 d, khi lng cht rn thu c sau phn ng l: A. 18,15g B. 19,75g C. 15,75g D. 14,35g. 2+ 0 Cu 45: Khi cho cht no sau y tc dng vi H2O (Hg ; 80 C) to ra sn phm l xeton? A. Propilen B. Propin C. Etilen D. Axetilen Cu 46: Cho 0,2 mol axit cacboxylic n chc X v 200 ml dung dch NaOH 0,8M th thu c dung dch c cha 15,52 gam cht tan. Vy cng thc ca axit cacboxylic X l ? A. CH3COOH. B. HCOOH. C. C2H5COOH. D. C2H3COOH. Cu 47: Cho dung dch Ba(HCO3)2 ln lt vo cc dd sau: CaCl2 , Ca(NO3)2 , NaOH, Na2CO3, KHSO4 , Na2SO4, Ca(OH)2 , H2SO4, HCl s trng hp c kt ta l ? A. 7. B. 4. C. 6. D. 5. Cu 48: Kim loi Na c dung lm cht chuyn vn nhit trong cc l ht nhn l do: 1.Kim loi Na d nng chy 2.Na dn nhit tt 3.Na c tnh kh rt mnh A. Ch c 2 B. 1 v 2 C. 2 v 3 D. Ch c 1 Cu 49: S oxy ho ca clo trong cc hp cht: HCl, KClO3, HClO, HClO2, HClO4 ln lt l:
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Ti liu n thi i hc nm 2012 -2013 A. +1, +5, -1, +3, +7 B. -1, +5, +1, -3, -7 C. -1, +5, +1, +3, +7 D. -1, -5, -1, -3, -7 Cu 50: ng vi cng thc C3H8On c bao nhiu ng phn ch cha nhm chc OH trong phn t c th ho tan c Cu(OH)2 ? A. 1 B. 2 C. 4 D. 3 B S 25 Cu 1: Cho hn hp gm 6,4gam Cu v 5,6 gam Fe vo cc ng dung dch HCl long d. tc dng ht vi cc cht c trong cc sau phn ng vi dung dch HCl (sn phm kh duy nht l NO), cn t nht khi lng NaNO3 l A. 2,8gam. B. 17gam. C. 5,7gam. D. 8,5gam. Cu 2: t chy hon ton 0,1 mol cht hu c X l dn xut ca benzen thu c CO 2 c khi lng nh hn 35,2 gam. Bit rng a (mol) X phn ng va vi 500 ml dung dch NaOH 2a(M). Cng thc cu to ca X l A. HO-CH2-C6H4-COOH. B. C6H5-CH2OH. C. HO-C6H4-CH2OH. D. C6H4(OH)2. Cu 3: Cho phn ng oxi ha - kh sau: X + HNO3 c, nng ... + NO2 + .... (1). t k = s mol NO2 / s mol X. Nu X l : Zn, S v FeS th k nhn cc gi tr tng ng l: A. 1; 6; 7 B. 2; 5; 9 C. 2; 6; 9 D. 2; 6; 7 Cu 4: C dung dch X gm (KI v mt t h tinh bt). Cho ln lt tng cht sau: O 3, Cl2, H2O2, FeCl3, AgNO3 tc dng vi dung dch X. S cht lm dung dch X chuyn sang mu xanh l A. 4 cht B. 5 cht C. 3 cht D. 2 cht Cu 5: Cho cc cht sau: phenol, kh sunfur, toluen, ancol benzylic, isopren, axit metacrylic, vinyl axetat, phenyl amin, axit benzoic. S cht phn ng c vi dung dch nc brom nhit thng l A. 5. B. 6. C. 3. D. 4. Cu 6: Dy gm cc cht no sau y u c tnh lng tnh ? A. AlCl3, H2O, NaHCO3, Zn(OH)2, ZnO B. H2O, Zn(OH)2, HOOC-COONa, H2NCH2COOH, NaHCO3 C. Al, NaHCO3, NaAlO2, ZnO, Be(OH)2 D. ZnCl2, AlCl3, NaAlO2, NaHCO3, H2NCH2COOH Cu 7: t chy hon ton 14,8 gam hn hp X gm CH3COOH, CxHyCOOH v (COOH)2 thu c 0,4 mol H2O v m gam CO2. Cng cho 14,8 gam X tc dng vi lng d NaHCO3 thu c 0,25 mol CO2. Gi tr ca m l A. 16,5 B. 11 C. 5,5 D. 22 Cu 8: Cho hn hp gm 0,1 mol HCHO ; 0,1 mol HCC-CHO; 0,1 mol HCC-CH 3 v 0,2 mol HCOOH tc dng vi lng d dung dch AgNO3/NH3 thu c khi lng Ag l: A. 129,6g B. 86,4g C. 108g D. 216g Cu 9: Hp cht C2H4O2 c 3 ng phn mch h. Cho cc ng phn ln lt tc dng vi: NaOH, Na, AgNO3/NH3 th s phng trnh phn ng xy ra l A. 5 B. 6 C. 7. D. 4. 35 37 Cu 10: Nguyn t khi trung bnh ca Clo bng 35,5. Clo c hai ng v 17 Cl v 17 Cl . Phn trm khi lng 35 ca 17 Cl c trong axit pecloric l gi tr no sau y? (cho H=1; O=16) A. 26,12% B. 27,2% C. 30,12% D. 26,92% Cu 11: Cho 11,8 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 19,1 gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l A. 5 B. 4 C. 6 D. 3 Cu 12: Hn hp X gm 2 anehit n chc A, B. Khi cho 1,42 gam hn hp X vo dung dch AgNO 3/NH3 d thu c 8,64 gam Ag. Hiro ha hon ton 1,42 gam hn hp X thnh hn hp ancol Y. Cho ton b hn hp Y vo bnh ng Na d thu c 0,336 lt H2 (ktc). Cng thc ca A, B ln lt l. A. HCHO v CH2=CH-CHO B. HCHO v CH3-CH2-CHO C. CH3CHO v CH2=CH-CHO D. CH2=CH-CHO v CH3CHO

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Ti liu n thi i hc nm 2012 -2013 Cu 13: Cho cc cht: AgNO3, Cu(NO3)2, MgCO3, Ba(HCO3)2, NH4HCO3, NH4NO3 v Fe(NO3)2. Nu nung cc cht trn n khi lng khng i trong cc bnh kn khng c khng kh, ri cho nc vo cc bnh, s bnh c th to li cht ban u sau cc th nghim l A. 3. B. 6. C. 4. D. 5. Cu 14: Nhm gm tt c cc cht c kh nng lm nht mu dung dch nc brom l: A. axit acrylic, glucoz, phenol, fructoz. B. axit acrylic, phenol, anken, glucozo. C. mantoz, saccaroz, anilin, ancol anlylic. D. axit metacrylic, anken, cumen, andehit axetic. Cu 15: Cho 17,04 gam hn hp rn A gm Ca, MgO, Na 2O tc dng ht vi 720 ml dung dch HCl 1M (va ) thu c dung dch A. Khi lng mui NaCl c trong dung dich A l A. 14,04g. B. 15,21g. C. 4,68g. D. 8,775g Cu 16: Cho 1 mol Ca3(PO4)2 tc dng vi 2,75 mol HCl th phng trnh phn ng c tng cc h s nguyn ti gin bng bao nhiu? A. B . 32 C . 42 D . 54 Cu 17: t chy hon ton hn hp gm etanol v phenol c t l mol 3:1, cho ton b sn phm chy vo bnh ng dung dch nc vi trong th thu c 15 gam kt ta, ly dung dch sau phn ng tc dng vi dung dch NaOH d th thu c 7,5 gam kt ta na. Khi lng bnh ng dung dch nc vi s A. tng 3,6 gam B. tng 5,4 gam C. tng 13,2 gam D. tng 18,6 gam Cu 18:Ho tan hon ton 24,4 gam hn hp gm FeCl 2 v NaCl(c t l s mol tng ng l 1: 2) vo mt lng nc d thu c dung dch X. Cho dung dch AgNO 3 d vo dung dch X, sau khi phn ng xy ra hon ton sinh ra c m gam cht rn. Gi tr ca m l: A. 28,7g B. 57,4g C. 10,8 g D. 68,2g Cu 19: Cho hi nc i qua than nng thu c 78,4 lt hn hp kh X(o ktc) gm kh CO, CO 2, H2. Kh ht 1/2 hn hp X bng CuO d nung nng thu c cht rn Y. Ho tan hon ton Y trong dung dch HNO 3 long thu c 22,4lt (o ktc) kh NO( sn phm kh duy nht). Phn trm th tch kh CO trong X l: A. 28,57 % B. 18,42 % C. 57,15 % D. 14,28 % Cu 20: t chy hon ton 4,872 gam mt hirocacbon X, dn sn phm chy qua bnh ng dung dch nc vi trong. Sau phn ng thu c 27,93 gam kt ta v thy khi lng dung dch gim 5,586 gam. Cng thc phn t ca X l A. C3H6 B. C4H8 C. CH4 D. C4H10 Cu 21: Ho tan ht a(g) oxit MO (M c ho tr 2 khng i) bng mt lng va dung dch H 2SO4 17,5% thu c dung dch mui c nng 20%. Hy cho bit, khi cho kh CO d i qua ng s ng 12 gam oxit MO thu c bao nhiu gam cht rn ? A. 12. B. 9,6 gam C. 5,4 gam D. 7,2 gam Cu 22: t chy ht m gam hn hp X gm hai anehit n chc, mch h (c mt lin kt i C = C trong phn t) thu c Vlt kh CO2 ktc v a gam H2O. Biu thc lin h gia m; a v V l 5V 9a 5V 7a 4V 7a 4V 9a + + + + A. m = B. m = C. m = D. m = 4 7 4 9 5 9 5 7 Cu 23: Cho cc cht sau: toluen, etilen, xiclopropan, stiren, vinylaxetilen, etanal, imetyl xeton, propilen. S cht lm mt mu dung dch KMnO4 nhit thng l A. 7. B. 5. C. 6. D. 4. Cu 24: Trong s cc loi t sau: t tm, t visco, t nilon-6,6, t axetat, t capron, t enang. Nhng loi t no thuc loi t nhn to l: A. T nilon 6,6 v t capron. B. T tm v t enang. C. T visco v t nilon-6,6. D. T visco v t axetat. Cu 25: Nhng dng c nh bp sau khi nu c, nu c thng li mi tanh. loi ht mi tanh mt cch tt nht nn dng: A. X phng B. Gim (axit axetic) C. X a (Na2CO3) D. Ancoletylic Cu 26: Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin; 1 mol alanin v 1mol valin. Khi thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly; Gly-Ala v tripeptit Gly-Gly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l: A. Ala, Val. B. Gly, Gly. C. Ala, Gly. D. Gly, Val. Cu 27: Nguyn t X c 7 eletron p. Nguyn t Y c tng s ht mang in nhiu hn s ht mang in ca X l 8 ht. Trong hp cht gia X v Y c bao nhiu electron?
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Ti liu n thi i hc nm 2012 -2013 A. 54 B. 30 C. 36 D. 64 Cu 28: Cho cc nhn xt sau: (1) Hp cht H 2N-CH2CH2CONH-CH2CONH-CH2COOH cha 2 lin kt peptitt ; (2) Phn t khi ca mt amino axit cha 1 nhm NH 2 v 1 nhm COOH trong phn t lun l s l ; (3) Cc peptit u tc dng vi Cu(OH)2 trong mi trng kim to ra hp cht mu tm ; (4) Tripeptit l hp cht m phn t cha 3 lin kt peptit ; (5) dung dch ca anilin khng lm xanh qu tm. S nhn xt ng l: A. 2 B. 3 C. 4 D. 5 Cu 29: Cho m gam hn hp 2 amino axit (trong phn t ch cha 1 nhm amino v 1 nhm cacboxyl) tc dng vi 100 ml dung dch HCl 2,2M thu c dung dch X. phn ng ht vi cc cht trong dung dch X cn dng 100 gam dung dch NaOH 16,8% thu c dung dch Y. C cn dung dch Y thu c 34,37 gam cht rn khan. Gi tr ca m l: A. 18,1 gam B. 17,1 gam C. 15,1 gam D. 16,1 gam 3+ 2Cu 30: Cation X v anion Y u c cu hnh electron phn lp ngoi cng l 2p 6. V tr ca X v Y trong bng tun hon ln lt l: A. X chu k 2, nhm IIA v Y chu k 3, nhm VIA. B. X chu k 3, nhm IIIA v Y chu k 2, nhm VIA. C. X chu k 2, nhm IIIA v Y chu k 2, nhm IVA. D. X chu k 3, nhm IIA v Y chu k 3, nhm VIA. Cu 31: Hn hp X c C2H5OH, C2H5COOH, CH3CHO trong C2H5OH chim 50% theo s mol. t chy m gam hn hp X thu c 3,06 gam H2O v 3,136 lt CO2 (ktc). Mt khc 13,2 gam hn hp X thc hin phn ng trng bc thy c p gam Ag kt ta. Gi tr ca p l A. 2,16. B. 9,72. C. 8,64. D. 10,8. Cu 32: Mt dung dch A cha: K +, Mg2+, Al3+ v SO42-. Cho 75 ml dung dch A tc dng lng d BaCl 2 to thnh 55,92g kt ta. Bit cc cation trong A c t l mol 1 : 2 : 1. C cn 75ml dung dch A c khi lng mui khan l: A. 28,44 gam B. 25,00 gam C. 23,04 gam D. 29,88 gam Cu 33: Ho tan ht hn hp rn gm CaC2, Al4C3 v Ca vo H2O thu c 3,36 lt hn hp kh X c t khi so vi hiro bng 10. Dn X qua Ni un nng thu c hn hp kh Y. Tip tc cho Y qua bnh ng nc brom d th c 0,784 lt hn hp kh Z (t khi hi so vi He bng 6,5). Cc kh o iu kin tiu chun. Khi lng bnh brom tng l A. 1,35 gam B. 2,09 gam C. 3,91 gam D. 3,45gam Cu 34: Dung dch CH3COOH c in li = 1%, nng C A, pH = a. Dung dch NH3 c in li = 0,1%, nng CB, pH = b. Cho b = a + 8.Quan h CA/CB? A. CA = CB +8 B. CA= 1/CB C. CB = 10CA D. CA = 8CB Cu 35: in phn c mng ngn 500 ml dung dch cha hn hp gm FeCl 3 0,1M v CuCl2 0,08 M (in cc tr, hiu sut in phn 100%) vi cng dng in 5A trong 45 pht 2 giy. Ti catot sau in phn thu c A. 1,568 lit kh B. 3,68 gam kim loi C. 3,12 gam kim loi D. 2,84 gam kim loi Cu 36: Cho cc cp phn ng sau: a. SO2 + O2 b. H2S + Cl2 + H2O c. SO2 + H2S d. SO2 + Br2 + H2O e. S + H2SO4 c nng f. S + F2 S phn ng to ra sn phm cha lu hunh mc oxi ha +6 l: A. 2 B.3 C.4 D.5 Cu 37: Oxi ho 25,6 gam CH3OH (c xc tc) thu c hn hp sn phm X. Chia X thnh hai phn bng nhau Phn 1 tc dng vi AgNO3 d trong NH3 un nng thu c m gam Ag. Phn 2 tc dng va vi 100ml dung dch KOH 1M. Hiu sut qu trnh oxi ho CH3OH l 75%. Gi tr ca m l A. 129,6. B. 64,8. C. 32,4. D. 108. Cu 38: Nung nng hn hp gm 5,6 gam Fe vi 4 gam bt S trong bnh kn mt thi gian c hn hp X gm FeS, FeS2, Fe v S d. Cho X tan ht trong dung dch H2SO4 c, nng d c V lt kh (ktc ). Gi tr ca V l A. 11,76 B. 8,96 C. 3,36 D. 11,65
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Ti liu n thi i hc nm 2012 -2013 Cu 39: Thc hin cc th nghim sau: (1) Sc kh C2H4 vo dung dch KMnO4. (2) Sc CO2 d vo dung dch NaAlO2 (3) Chiu sng vo hn hp kh (CH4; Cl2). (4) Sc kh H2S vo dung dch FeCl3. (5) Sc kh NH3 vo dung dch AlCl3. (6) Sc kh SO2 vo dung dch H2S. S th nghim c phn ng oxi ho- kh xy ra l A. 2,4,5,6. B. 1,2,4,5 C. 1,3,4,6. D. 1,2,3,4. Cu 40: Mt hn hp A gm Ba v Al. Cho m gam A tc dng vi nc d, thu c 1,344 lt kh, dung dch B. Cho 2m gam A tc dng vi dung dch Ba(OH) 2 d thu c 20,832 lt kh. (Cc phn ng u xy ra hon ton, cc th tch kh o iu kin tiu chun). Gi tr ca m l A. 12,21 B. 10,155 C. 12,855 D. 27,2 + 2Cu 41: Cho kim loi Ba (d) vo dung dch c cha cc ion: NH4 , HCO3 , SO4 , K+. S phng trnh phn ng (dng ion thu gn) ti a c th xy ra l A. 3 B. 6 C. 5 D. 4 Cu 42: Cho s bin i sau: (NH4)2Cr2O7 Cr2O3 Cr CrCl2 Cr(OH)2 Cr(OH)3 K2CrO4 K2Cr2O7 Cr2(SO4)3. Tng s phn ng thuc loi oxi ha - kh trong dy bin i trn l: A. 6 B. 7 C. 5 D. 4 Cu 43: Mui A c cng thc l C 3H10O3N2, ly 7,32 gam A phn ng ht vi 150ml dung dch KOH 0,5M. C cn dung dch sau phn ng th c phn hi v phn cht rn, trong phn hi c 1 cht hu c bc 3, trong phn rn ch l cht v c. Khi lng cht rn l: A. 6,06 g. B. 6,90 g. C. 11,52 g. D. 9,42 g. Cu 44: Cho -amino axit mch thng X c cng thc H2NR(COOH)2 phn ng va vi 0,1 mol NaOH to 9,55 gam mui. X l: A. axit 2-aminobutanioic B. axit 2-aminopropanioic C. axit 2-aminohexanioic D. axit 2-aminopentanioic Cu 45: Nung m gam hn hp X gm KClO 3 v KMnO4 thu c cht rn Y v O 2. Bit KClO3 phn hu hon ton, cn KMnO4 ch b phn hu mt phn. Trong Y c 0,894 gam KCl chim 8,132% theo khi lng. Trn lng O2 trn vi khng kh theo t l th tch VO2 : V KK =1:3 trong mt bnh kn ta thu c hn hp kh Z. Cho vo bnh 0,528 gam cacbon ri t chy ht cacbon, phn ng hon ton, thu c hn hp kh T gm 3 kh O2, N2, CO2, trong CO2 chim 22,92% th tch. Gi tr m (gam) l A. 12,91 B. 12,53 C. 12,70 D. 12,59 Cu 46: Tng s ng phn cu to chc axit v este ca hp cht c cng thc phn t C3H6O2 l A. 2. B. 1. C. 4. D. 3 Cu 47: Hn hp hai kim loi Mg v K vi t l s mol tng ng 1 : 3 tc dng vi dung dch HNO 3 d to sn phm duy nht do s kh N+5 l N2O th phng trnh ion thu gn c tng h s nguyn ti gin ca cc cht to thnh l : A. 68 B. 67 C. 62 D. 76 Cu 48: Hn hp X c 2 hirocacbon ng ng lin tip, c t khi hi so vi H 2 bng 15,8. Ly 6,32 gam X li vo 200 gam dung dch cha xc tc thch hp th thu c dung dch Z v thy thot ra 2,688 lt kh kh Y iu kin tiu chun c t khi hi so vi H2 bng 16,5. Bit rng dung dch Z cha anehit vi nng C%. Gi tr ca C% l: A. 1,305% B. 1,407% C. 1,208% D. 1,043% Cu 49: Cho qu tm vo ln lt cc dung dch: CH 3COOK, FeCl3, NH4NO3, K2S, Zn(NO3)2, Na2CO3. S dung dch lm i mu giy qu l A. 6 B. 5 C. 3 D. 4 Cu 50: Hn hp X gm axetilen 0,15 mol, vinylaxetilen 0,1 mol, etilen 0,1 mol v hiro 0,4 mol. Nung X vi xc tc niken mt thi gian thu c hn hp Y c t khi i vi hiro bng 12,7. Hn hp Y phn ng va vi dung dch cha a mol Br2. Ga tr ca a l: A. 0,35 B. 0,65 C. 0,45 D. 0,25 B S 26
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Ti liu n thi i hc nm 2012 -2013 Cu 1: Trung ho 20,9 gam hn hp phenol v p-crezol cn 100 ml dung dch NaOH 2M. Thnh phn trm khi lng ca phenol trong hn hp l A. 4,7%. B. 67,5%. C. 25,0%. D. 22,5%. Cu 2: Dy gm cc cht u c nhit si cao nht so vi cc ng phn ca n l: A. axit axetic, etanol, axeton. B. etyl axetat, etanol, axeton. C. axit axetic, etanol, ancol anlylic. D. etyl axetat, etanol, propanal. Cu 3: Cht no sau y khi tc dng vi dung dch Ba(OH)2 gii phng kh? A. Al. B. Cr2O3. C. Cr. D. Al2O3. Cu 4: Th t b kh catot khi in phn (bng cc in cc tr) dung dch cha cc ion Cu 2+, Fe3+, Ag+, Au3+ ln lt l: A. Au3+, Ag+, Cu2+, Fe3+. B. Au3+, Ag+, Fe3+, Cu2+. 3+ 3+ + 2+ C. Au , Fe , Ag , Cu . D. Fe3+, Cu2+, Ag+, Au3+. Cu 5: im ging nhau gia lin kt kim loi v lin kt ion l: A. u c to thnh nh cp electron dng chung. B. u c to thnh bng lc ht tnh in gia ion dng v cc electron t do. C. u c to thnh bng lc ht tnh in gia cc nguyn t v ion mang in tch tri du. D. u c to thnh bng lc ht tnh in gia cc tiu phn mang in tch tri du. Cu 6: Nguyn t no sau y c nng lng ion ho nh nht? A. K. B. Cs. C. Li. D. Na. Cu 7: Cho mt s c im sau y ni v nc cng tm thi v nc cng vnh cu: (1) To kt ta khi tc dng vi NaOH. (2) Lm hao tn x phng khi git ra. (3) To kt ta khi tc dng vi Na3PO4. (4) C cha cc cation Mg2+, Ca2+. Tt c nhng c im chung ca nc cng tm thi v vnh cu l: A. (1), (2), (3). B. (2), (3), (4). C. (1), (2), (4). D. (1), (2), (3), (4). Cu 8: un hn hp gm glixerol vi hn hp cc axit: panmitic, stearic, oleic (xc tc H2SO4 c) c th to ra bao nhiu loi este 3 chc A. 18. B. 12. C. 15. D. 9. Cu 9: Dy gm cc kim loi no sau y u c th tan c trong nc nhit thng? A. Ba, K, Na, Sr. B. K, Na, Fe, Al. C. Na, K, Mg, Ca. D. K, Na, Zn, Al. Cu 10: Cho 12,9 gam este X c cng thc C 4H6O2 tc dng vi 150 ml dung dch NaOH 1,25M. C cn dung dch sau phn ng c 15,6 gam cht rn khan. Tn gi X l A. metyl acrylat. B. etyl acrylat. C. vinyl axetat. D. anlyl axetat. Cu 11: Cho 15 gam fomalin tc dng hon ton vi lng d Cu(OH) 2 trong dung dch NaOH thu c 54,72 gam kt ta gch. Nng phn trm ca cht tan trong fomalin ni trn l A. 40%. B. 35%. C. 38%. D. 39%. Cu 12: iu ch 3,36 lt kh Cl2 (ktc) t cc cht NaCl, H2SO4, MnO2 th cn m gam NaCl. Gi tr ca m l A. 36,10. B. 17,55. C. 8,77. D. 37,50. Cu 13: Cho 37,82 gam cht hu c X c cng thc phn t l C 3H12O3N2 tc dng vi 350 ml dung dch KOH 2M un nng, sau khi phn ng xy ra hon ton thu c mt kh Y c kh nng lm xanh giy qu tm m v dung dch Z. C cn dung dch Z thu c khi lng cht rn khan l A. 47,26 gam. B. 43,78 gam. C. 42,09 gam. D. 47,13 gam. Cu 14: Cho cc cht metyl benzoat, natri phenolat, ancol benzylic, phenylamoniclorua, glixerol, protein. S cht tc dng c vi NaOH khi un nng l A. 5. B. 3. C. 2. D. 4. Cu 15: Cp cht no di y l ng ng ca nhau? A. Ancol etylic (C2H6O) v ancol anlylic (C3H6O). B. Ancol etylic (C2H6O) v etylenglicol (C2H6O2). C. Ancol metylic (CH4O) v ancol butylic (C4H10O). D. Phenol (C6H6O) v ancol benzylic (C7H8O). Cu 16: Cho cc cht sau: (1) CH 3COONa, (2) C2H6, (3) CaC2, (4) C4H10, (5) Al4C3. Dy cc cht iu ch c CH4 bng mt phn ng l: A. (1), (3), (5). B. (1), (2), (5). C. (1), (4), (5). D. (2), (4), (5). Cu 17: Trng hp no sau y khng thu c kt ta sau khi kt thc cc phn ng? A. Cho dung dch BaCl2 tc dng vi dung dch NaHSO4 (d).
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Ti liu n thi i hc nm 2012 -2013 B. Cho dung dch AlCl3 tc dng vi dung dch NH3 (d). C. Cho Ba tc dng vi dung dch H2SO4 (d). D. Cho Zn tc dng vi dung dch CrCl3 (d) Cu 18: Mt hp cht c cng thc phn t MX 2, trong M chim 46,67% v khi lng. Trong ht nhn M s ntron nhiu hn s proton l 4. Trong ht nhn X, s ntron bng s proton. Tng s proton trong phn t MX2 l 58. Hp cht MX2 l A. ZnSi2. B. CrCl2. C. FeS2. D. CuCl2. Cu 19: Hn hp kh X gm hai anken. Ly V lt kh X tc dng vi mt lng H 2 va (Ni, to), thu c hn hp Y gm hai ankan. t chy hon ton hn hp Y thu c H 2O v 13,2 gam CO2. Khi t chy hon ton V lt hn hp X thu c CO2 v m gam H2O. Gi tr ca m l A. 6,3. B. 3,6. C. 5,4. D. 2,7. Cu 20: Cu trc mt mt xch ca mt loi polime l -CO-[CH2]4-CO-NH-[CH2]6-NHPolime thuc loi no sau y? A. Cao su buna. B. T nilon-7. C. T nilon-6,6. D. T capron. Cu 21: Ho tan hon ton 6,94 gam hn hp FexOy v Al trong 100ml dung dch H2SO4 1,8M thu c 0,672 lt H2 (ktc). Bit lng axit ly d 20% so vi lng cn thit phn ng (gi s khng c phn ng kh Fe3+ thnh Fe2+). Cng thc ca FexOy l A. FeO. B. Fe2O3. C. Fe3O4. D. FeO3 Cu 22: Thc hin th nghim ho tan ht cng mt mu km trong cng mt dung dch HCl cc nhit khc nhau cho kt qu: - Khi thc hin phn ng 20oC, thi gian kt thc phn ng l 13,5 pht; - Khi thc hin phn ng 40oC, thi gian kt thc phn ng l 1,5 pht. Nu thc hin th nghim trn 55oC th thi gian l bao nhiu? A. 14,55 giy. B. 18,46 giy. C. 34,65 giy. D. 17,32 giy. Cu 23: Cho m gam hn hp gm CuO v Fe 2O3 tc dng vi CO, nung nng mt thi gian thu c hn hp rn X v hn hp kh Y. Cho Y phn ng vi dung dch Ba(OH)2 (d) thu c 29,55 gam kt ta. Cht rn X phn ng vi dung dch HNO3 (d) thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 1,12. B. 6,72. C. 3,36. D. 2,24. Cu 24: Kh 39,2 gam hn hp X gm Fe 2O3 v FeO bng kh CO thu c hn hp Y gm FeO v Fe. ho tan ht Y cn va 2,5 lt H2SO4 0,2M. Khi lng ca Fe2O3 v FeO trong hn hp X l: A. 16 gam Fe2O3; 23,2 gam FeO. B. 32 gam Fe2O3; 7,2 gam FeO. C. 18 gam Fe2O3; 21,2 gam FeO. D. 20 gam Fe2O3; 19,2 gam FeO. Cu 25: Ho tan ba mui no sau y vo nc c dung dch X gm: 0,35 mol Na +; 0,125 mol Mg2+; 0,25 mol Cl- v 0,175 mol SO42-? A. MgCl2, Na2SO4, NaCl. B. MgSO4, MgCl2, NaCl. C. MgSO4, Na2SO4, MgCl2. D. MgSO4, Na2SO4, NaCl. Cu 26: X l axit cacboxylic no, cng thc n gin nht l C2H3O2. Cng thc phn t ca X l A. C6H8O6. B. C4H6O4. C. C8H12O8. D. C2H3O2. Cu 27: Cho m gam mt lng kim loi M phn ng hon ton vi dung dch CuSO 4, sau phn ng thu c 3,555m gam Cu. Nu dng 0,02 mol M tc dng vi H 2SO4 (long, d) th thu c 0,672 lt kh (ktc). Kim loi M l A. Cr. B. Zn. C. Al. D. Fe. Cu 28: Trung ho 6,6 gam hn hp gm axit fomic v mt axit cacboxylic n chc X cn dung dch cha 0,1 mol NaOH. Mt khc, khi cho 6,6 gam hn hp trn tc dng vi mt lng d AgNO 3 trong NH3 th thu c 10,8 gam kt ta. Tn gi ca X l A. axit metacrylic. B. axit acrylic. C. axit etanoic. D. axit propanoic. Cu 29: Mt loi mui n c ln tp cht Na 2SO4, CaSO4, NaBr, v CaCl2. thu c mui n tinh khit (k c cch un nng) cn dng cc cht (hoc dung dch) no sau y? A. Dung dch BaCl2, Na2CO3, kh HCl, kh Cl2. B. Dung dch BaCl2, K2CO3, axit HCl, kh Cl2. C. H2O, BaCl2, K2CO3, H2SO4, Cl2. D. H2O, BaCl2, Na2CO3, Cl2. t cao Cu 30: Cho cc phn ng: X Y + Z Y Cl ; askt E + F + G
o

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Ti liu n thi i hc nm 2012 -2013 Bit X l mt ankan c t khi so vi khng kh nh hn 2,6; Y l ankan, Z l anken (s nguyn t C trong Y nhiu hn trong Z), E v F l sn phm th ca clo, E l sn phm u tin v F l sn phm khng u tin. Cc cng thc X, Y, Z, E, F v G ln lt l: A. C5H12, C3H8, C2H4, CH3-CH2-CH2-Cl, CH3-CHCl-CH3, HCl. B. C6H14, C4H10, C2H4, CH3-CHCl-CH2-CH3, CH2Cl-CH2-CH2-CH3, HCl. C. C4H10, C2H6, C2H4, CH2Cl-CH3, CH3-CH2-CH2-Cl, HCl. D. C5H12, C3H8, C2H4, CH3-CHCl-CH3, CH3-CH2-CH2-Cl, HCl. Cu 31: Cho 0,1 mol - amino axit X dng H2NRCOOH phn ng ht vi HCl thu c 11,15 gam mui. X l A. alanin. B. valin. C. glyxin. D. phenylalanin. Cu 32: nh hng ca nhm OH n nhn benzen v ngc li c chng minh bi phn ng ca phenol vi A. nc brom v dung dch NaOH. B. Na v nc brom. C. dung dch HNO3 v nc brom. D. nc brom v anehit fomic. Cu 33: un nng hp cht hu c X vi lng d dung dch AgNO 3 trong NH3 thu c hp cht Z. Cho Z tc dng vi dung dch H2SO4 long hoc vi dung dch NaOH un nng u c kh v c thot ra. S cht trong dy: HCHO, HCOOH, CH3CHO, CH3COOH, HCOONH4. CH3COOCH3 tho mn cc tnh cht nu trn l A. 3 cht. B. 1 cht. C. 4 cht. D. 2 cht. Cu 34: Dn kh thu c khi cho KMnO 4 tinh th phn ng vi dung dch HCl c vo nc to thnh dung dch X. Cho mu giy qu tm vo dung dch X th hin tng quan st thy l: A. Giy qu tm khng i mu. B. Giy qu tm chuyn sang mu xanh. C. Giy qu tm chuyn sang mu ri b mt mu. D. Giy qu tm chuyn sang mu xanh ri mt mu. Cu 35: Tn gi ca peptit: H2NCH2CONHCH(CH3)CONHCH2COOH l A. Gly-Ala-Gly. B. Gly-Gly-Ala. C. Ala-Ala-Gly. D. Gly-Gly-Gly. Cu 36: Nhit phn hon ton 18 gam mt mui nitrat kim loi thu c 8 gam oxit kim loi. Cng thc mui l A. Zn(NO3)2. B. Fe(NO3)3. C. Fe(NO3)2. D. Cu(NO3)2. Cu 37: Hon tan m gam hn hp rn gm Ca, CaC 2 vo mt lng d H2O, thu c hn hp kh c t khi so vi hiro l 5. trung ho dung dch sau phn ng, cn dng 600 ml dung dch HCl 0,5M. Gi tr ca m l A. 8,4. B. 7,2. C. 3,2. D. 4,0. Cu 38: Pht biu no sau y ng? A. Xenlulo v tinh bt l ng phn ca nhau. B. Saccaroz c tnh cht ca ancol a chc v anehit n chc. C. Glucoz v fructoz khi tc dng vi H2 (Ni, to) u to ra cng mt sn phm. D. Glucoz v fructoz u tc dng c vi nc brom. Cu 39: Cho 2 phn ng sau: FeSO4 + HNO3 + H2SO4 Fe2(SO4)3 + NO + H2O (1) Mn(OH)2 + Cl2 + KOH MnO2 + KCl + H2O (2) H s (nguyn ti gin) ca H2O phng trnh ho hc ca phn ng (1) v (2) ln lt l: A. 3 v 1. B. 4 v 2. C. 3 v 2. D. 4 v 1. Cu 40: Trn ln dung dch cha 0,06 mol Ba(OH) 2 vi dung dch cha 0,02 mol Al2(SO4)3. Sau khi cc phn ng kt thc khi lng kt ta thu c l A. 3,12 gam. B. 21,6 gam. C. 17,1 gam. D. 15,8 gam. Cu 41: iu ch 78 gam crom t Cr 2O3 bng phng php nhit nhm (hiu sut phn ng l 90%) th s gam bt nhm t nht cn dng l A. 40,5 gam. B. 54,0 gam. C. 81,0 gam. D. 45,0 gam. Cu 42: Cht X c cng thc phn t C4H4O v c cc tnh cht sau: - Tc dng vi AgNO3 trong dung dch NH3 to ra hai cht kt ta. - Tc dng vi Br2 (trong dung dch) theo t l mol ti a 1:3. Cng thc ca X l A. CH2=C=CH-CHO. B. CH C-CO-CH3. C. CH3-C C-CHO. D. CH C-CH2-CHO.
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Ti liu n thi i hc nm 2012 -2013 Cu 43: Khi ho tan 2,6 gam km bng HNO3(long, d) thu c 0,224 lt kh X duy nht (ktc) v dung dch Y ch cha mt mui. Kh X l A. NO2. B. N2. C. NO. D. N2O. Cu 44: Trn 10 ml dung dch HCl c pH = 3 vi V ml dung dch NaOH c pH = 10 thu c dung dch mi c pH = 5. Gi tr ca V l A. 90. B. 4. C. 25. D. 100 Cu 45: t chy x gam mt axit cacboxylic no, mch cacbon khng phn nhnh, thu c 0,06 mol CO 2 v 0,05 mol H2O. Gi tr ca x l A. 0,6. B. 1,46. C. 2,92. D. 0,73. Cu 46: Cho 6,03 gam hn hp gm etanal v axetilen tc dng hon ton vi lng d dung dch AgNO 3 trong NH3, thu c 41,4 gam kt ta. Cho ton b lng kt ta ny vo dung dch HCl d, sau khi xy ra phn ng hon ton cn li m gam cht rn khng tan. Gi tr ca m l A. 41,400 B. 30,135. C. 16,200. D. 46,335. Cu 47: T visco thuc loi polime A. trng hp. B. bn tng hp. C. tng hp. D. thin nhin. Cu 48: C nm ng nghim b mt nhn, mi ng ng mt trong cc dung dch HCl (1), dung dch NaOH (2), dung dch phenolphtalein (3), dung dch NaCl (4), dung dch NaHSO4 (5). Khng dng thm thuc th no khc, k c un nng, bng phng php ho hc c th nhn bit c cc dung dch: A. (2), (3), (4). B. (1), (2), (3). (4), (5). C. (1), (2), (3). D. (2), (3), (5). Cu 49: Cng thc cu to ca axit -aminoglutaric l A. NH2CH2CH2(NH2)CHCOOH. B. HOOCCH2CH2CH2(NH2)CHCOOH. C. HOOCCH2CH2(NH2)CHCOOH. D. HOOCCH2CH(NH2)CH2COOH. Cu 50: Trng hp no sau y khng xy ra phng trnh phn ng? A. Cho dung dch FeCl2 vo dung dch AgNO3. B. Cho dung dch Fe(NO3)3 vo dung dch AgNO3. C. Cho dung dch Fe(NO3)2 vo dung dch HCl. D. Cho dung dch Fe(NO3)2 vo dung dch AgNO3. B S 27 Cu 1: Cho 6,9 gam Na vo 100,0 ml dung dch HCl thu c dung dch X cha 14,59 gam cht tan. Cho dung dch X vo dung dch AgNO3 d, sau khi phn ng xy ra hon ton, em lng rn thu c ngoi khng kh n khi lng khng i c m gam rn. Gi tr ca m l : A. 38,65 B. 37,58 C. 40,76 D. 39,20 Cu 2: Mui X c cng thc phn t l CH6O3N2. un nng X vi NaOH thu c 2,24 lt kh Y (Y l hp cht cha C, H, N v c kh nng lm xanh giy qu tm m). Tnh khi lng mui thu c? A. 8,2 gam B. 8,5 gam C. 6,8 gam D. 8,3 gam Cu 3: Cho t t tng git ca dung dch cha b mol HCl vo dung dch cha a mol Na2CO3 thu c V lt CO2. Ngc li, cho t t tng git ca dung dch cha a mol Na2CO3 vo dung dch cha b mol HCl thu c 2V lt CO2. So snh a v b. A. a = 0,8b B. a = 0,35b C. a = 0,75b D. a = 0,5b Cu 4: Cho cc dung dch sau: NaHCO3 (X1) CuSO4 (X2) (NH4)2CO3 (X3) NaNO3 (X4) MgCl2 (X5) KCl (X6) Nhng dung dch khng to kt ta khi cho kim loi Ba vo l: A. X1, X3, X6 B. X1, X4, X5 C. X4, X6. D. X1, X4, X6 Cu 5: Hn hp X gm CH2=CH-CH2-OH v CH3-CH2-OH. Cho a gam hn hp X tc dng vi Na d thu c 2,24 lt H2 (ktc). Mt khc, a gam hn hp X lm mt mu va ht 100 gam dung dch Br2 20%. Vy gi tr ca a tng ng l: A. 12,7 gam B. 11,7 gam C. 9,7 gam D. 10,7 gam Fe(NO3)3 + NO2 + NO + H2O Cu 6: Cho phn ng sau: Fe3O4 + HNO3 Nu t l s mol gia NO v NO2 l 1 : 2 th h s cn bng ca HNO3 trong phng trnh ho hc l A. 30 B. 48 C. 38 D. 66
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Ti liu n thi i hc nm 2012 -2013 Cu 7: trung ho 28,8 gam hn hp gm axit axetic, ancol propylic v p-crezol cn 150 ml dung dch NaOH 2M. Mt khc ho tan hon ton 28,8 gam hn hp trn trong hexan ri cho Na d vo th thu c 4,48 lt H2 ( ktc). Lng p-crezol c trong hn hp l? A. 0,1 mol. B. 0,2 mol. C. 0,3 mol D. 0,4 mol - 22+ + Cu 8: Cho cc ion sau: Cl ; S ; Ca ; K . Th t tng dn bn knh ca cc ion trn l 2+ + 2- - 22+ + 2- - + 2+ 2+ + - 2A. Ca ; K ; S ; Cl B. Cl ; S ; Ca ; K . C. S ; Cl ; K ; Ca D. .Ca ; K ; Cl ; S . Cu 9: Trn ln 100 ml dung dch Ba(OH)2 1M vi 100 ml dung dch Al2(SO4)3 0,2M, khuy u cho phn ng xy ra hon ton thu c x gam kt ta v dung dch A. Sc CO2 d vo dung dch A, li thu c y gam kt ta. Gi tr ca x v y tng ng l A. 13,98 v 7,06. B. 23,3 v 7,06. C. 23,3 v 3,12. D. 13,98 v 3,12. Cu 10: Cho 6,72 gam Fe vo dung dch c 0,4 mol HNO3 (gi thit NO l sn phm kh duy nht). Sau khi phn ng hon ton, phn dung dch c s gam mui tan l A. 29,04 B. 24,2 C. 25,32 D. 21,6 Cu 11: Axit lactic (CH3-CH(OH)-COOH) c th tc dng c vi tt c cc cht trong dy no sau y ? A. Na, Na2CO3, K2SO4, CH3COOH. B. Na2O, NaHCO3, C2H5OH, HBr. C. CH3NH2, HCl, CaSO4. D. CH3OH, H2, NaOH, Br2. Cu 12: Nung nng m gam Cu vi oxi nhit cao c cht rn X. Ho tan X trong H 2SO4 long d th c 0,5m gam Cu. Cht rn X l A. Cu2O. B. Cu2O, CuO. C. Cu, Cu2O. D. CuO. Cu 13: Cho cc phn ng sau: a) FeS + H2SO4 (c, nng) b) MgO + HNO3 (c, nng) c) Fe + Fe2(SO4)3 d) C2H2 + H2 e) CH3CHO + AgNO3/NH3 g) Glixerol + Cu(OH)2 f) CH3COOCH3 + NaOH h) HCHO + Cu(OH)2

S phn ng thuc loi phn ng oxi ho - kh l A. 6 B. 4 C. 7 D. 5 Cu 14: Cho A l hp cht thm c cng thc phn t chnh l cng thc n gin nht. t chy hon ton 1,24 gam A ch thu c 1,568 lt CO2 (ktc) v 0,72 gam H2O. Cho a mol A tc dng vi Na d thu c a mol kh H2. Mt khc, a mol A tc dng vi a mol NaOH. S cng thc cu to c th ph hp vi A l A. 4 B. 6 C. 3 D. 5 Cu 15: Thu phn cc hp cht sau trong mi trng kim 1. CH3 - CHCl2 2. CH3 - COO - CH = CH - CH3. 3. CH3 - COO - CH2 - CH = CH2 4. CH3 - CH2 - CCl3. 5. (CH3 - COO)2CH2 Nhng cht sau khi thy phn cho sn phm c phn ng trng bc l A. 1, 2, 4, 5 B. 1, 2, 4 C. 1, 3, 5 D. 1, 2, 5 Cu 16: Tyrosin c cng thc p-HO-C6H4-CH2-CH(NH2)-COOH. Cho 0,1 mol Tyrosin tc dng va vi dd NaOH thu c hp cht hu c B. Lng HCl cn dng phn ng vi B l: A. 0,2 mol B. 0,4 mol C. 0,1 mol D. 0,3 mol Cu 17: Cho cc nhn xt sau: (1) Hp cht H2N-CH2-CH2-CO-NH-CH2-CO-NH-CH2-COOH cha 2 lin kt peptit (2) Phn t khi ca mt amino axit cha 1 nhm NH2 v 1 nhm COOH trong phn t lun l s l (3) Cc peptit u tc dng vi Cu(OH)2 trong mi trng kim to ra hp cht mu tm (4) Tripeptit l hp cht m phn t cha 3 lin kt peptit (5) Dung dch ca anilin khng lm xanh qu tm. S nhn xt ng l: A. 5 B. 3 C. 4 D. 2 Cu 18: iu ch este CH3COOC2H5 bng cch un C2H5OH vi CH3COOH c mt H2SO4 c, khi:
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Ti liu n thi i hc nm 2012 -2013 (1) Tng nng ancol (2) tng nng axit (3) chng ct ly dn este (4) Thm H2SO4 c (5) Tng nng ca c axit v ancol C my phng n gp phn lm cn bng dch chuyn v pha to thnh este A. 2 B. 5 C. 4 D. 3 Cu 19: Cho 12 gam Mg tc dng vi dung dch HNO 3 (va ) thu c dung dch A v V lt hn hp kh (ktc) gm N2O v N2 c t khi so vi H2 bng 18. C cn cn thn ton b dung dch A thu c 75 gam mui khan. Gi tr ca V l A. 2,480. B. 2.016. C. 2,240. D. 2,688. Cu 20: Pht biu no sau y l sai? A. Trong tinh th nguyn t, cc nguyn t lin kt vi nhau bng lin kt cng ho tr. B. Trong tinh th NaCl, xung quanh mi ion u c 6 ion ngc du gn nht. C. Tinh th nc , tinh th iot u thuc loi tinh th phn t. D. Tt c cc tinh th phn t u kh nng chy v kh bay hi. Cu 21: Cho cc pht biu sau (a) Khi t chy hon ton mt hirocacbon X bt k, nu thu c nCO2 = nH2O th l anken (b) Trong thnh phn hp cht hu c nht thit phi c cacbon. (c) Lin kt ho hc ch yu trong hp cht hu c l lin kt cng ho tr. (d) Nhng hp cht hu c khc nhau c cng phn t khi l ng phn ca nhau. (e) Phn ng hu c thng xy ra nhanh v khng theo mt hng nht nh. (g) Hp cht C9H14BrCl c vng benzen trong phn t. S pht biu ng l A. 5. B. 2. C. 3. D. 4. Cu 22: Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1) vo 30 ml dung dch gm H2SO4 0,5M v HNO3 2M, sau khi cc phn ng xy ra hon ton, thu c a mol kh NO (sn phm kh duy nht). Trn a mol NO trn vi 0,1 mol O2 thu c hn hp kh Y. Cho ton b Y tc dng vi H2O, thu c 150 ml dung dch c pH = z. Gi tr ca z l A. 4. B. 3. C. 1. D. 2. Cu 23: Thc hin cc th nghim sau: (a) Nung NH4NO3 rn. (b) un nng NaCl tinh th vi dung dch H2SO4 (c). (c) Sc kh Cl2 vo dung dch NaHCO3. (d) Sc kh CO2 vo dung dch Ca(OH)2 (d). (e) Sc kh SO2 vo dung dch KMnO4. (g) Cho dung dch KHSO4 vo dung dch NaHCO3. (h) Cho Na2SO3 vo dung dch H2SO4 (d), un nng. (i) Cho PbS vo dung dch HCl (long). S th nghim sinh ra cht kh l A. 4. B. 2. C. 6. D. 5. Cu 24: Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X, thu c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l A. 72,08%. B. 27,92%. C. 25%. D. 75%. Cu 25: Khi tin hnh phn ng th gia ankan B vi hi Br2 c chiu sng theo t l mol 1:1 ngi ta thu c hn hp X ch gm 2 sn phm phn ng (mt cht v c v mt cht hu c) th hi. T khi hi ca X so vi khng kh bng 4. Nu tin hnh phn ng th 3 nguyn t hidro trong phn t B bng Clo th c th thu c my ng phn? A. 2 B. 3 C.4 D. 1 Cu 26: Dy gm cc cht no sau y u c tnh lng tnh ? A. AlCl3, H2O, NaHCO3, Zn(OH)2, ZnO, H2NCH2COOH, CrO3 B. ZnCl2, AlCl3, NaAlO2, NaHCO3, H2NCH2COOH, Al2O3 C. H2O, Zn(OH)2, HOOC-COONa, H2NCH2COOH, NaHCO3 D. Al, NaHCO3, NaAlO2, ZnO, Be(OH)2 Cu 27: Cho mt lung kh CO i qua ng s ng m gam Fe2O3 nung nng. Sau mt thi gian thu c 10.44 gam cht rn X gm Fe, FeO, Fe2O3 v Fe3O4. Ha tan ht X trong dung dch HNO3 c, nng thu c 4.368 lt NO2 (sn phm kh duy nht ktc). Gi tr ca m l
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Ti liu n thi i hc nm 2012 -2013 A. 12 B. 24 C. 10.8 D. 16 Cu 28: in phn 2 lt dung dch hn hp gm NaCl v CuSO4 n khi H2O b in phn hai cc th dng li, ti catt thu 1.28 gam kim loi v ant thu 0.336 lt kh ( iu kin tiu chun). Coi th tch dung dch khng i th gi tr pH ca dung dch thu c bng: A. 12 B. 13 C. 2 D. 3 Cu 29: Hirat ho 3.36 lt C2H2 (iu kin tiu chun) thu c hn hp A (hiu sut phn ng 60%) . Cho hn hp sn phm A tc dng vi dung dch Ag2O/NH3 d thu c m gam cht rn. Gi tr ca m l A. 19,44 B. 33,84 C. 14,40 D. 48,24 Cu 30: Ho tan m gam hn hp gm Na2CO3 v KHCO3 vo nc c dung dch A. Cho t t dung dch HCl vo dung dch A thy c 4,48 lt kh bay ra (ktc) v dung dch B. Cho nc vi trong d vo dung dch B thu c 15 gam kt ta. Mt khc, tc dng ht vi cc cht c trong dung dch A cn 100 ml dung dch NaOH 1M. Tnh m ? A. 35,6 B.26,5 C.47,1 D. 36,5 Cu 31: Cho 2,1 gam hn hp gm 2 amin no, n chc, k tip nhau trong dy ng ng phn ng ht vi dung dch HCl (d) thu c 3,925 gam hn hp mui. Cng thc ca amin l A. C3H7NH2 v C4H9NH2 B. CH3NH2 v C2H5NH2 C. CH3NH2 v (CH3)3N D. C2H5NH2 v C3H7NH2 Cu 32: C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol ch bng phn ng cng 0 H2 ( xc tc Ni, t ) ? A. 2 B. 5 C.4 D. 3 Cu 33: Dy gm cc kim loi c cu to mng tinh th lp phng tm khi l A. Be, Mg, Ca B. Li, Na, K C. Na, K, Mg D. Li, Na, Ca Cu 34: Cho 1,56 gam hn hp gm Al v Al2O3 phn ng ht vi dung dch HCl (d), thu c V lt kh H2 (ktc) v dung dch X. Nh t t dung dch NH3 n d vo dung dch X c kt ta, lc ht lng kt ta, nung n khi lng khng i c 2,04 gam cht rn. Gi tr ca V l A. 0,448 B. 0,224 C. 1,344 D. 0,672 Cu 35: Cu hnh ca nguyn t hay ion no di y c biu din khng ng? 5 1 2+ 3 2 A. Cr (Z = 24) [Ar] 3d 4s B. Mn (Z = 25) [Ar] 3d 4s 3+ 5 10 1 C. Fe (Z = 26) [Ar] 3d D. Cu (Z = 29) [Ar] 3d 4s Cu 36: Cho 15,0 gam mt aminoaxit X c mt nhm amino v mt nhm cacboxyl tc dng vi dung dch NaOH thu c dung dch Y. C cn Y c 19,4 gam mui khan. X l A. H2NCH2COOH. B. H2NC2H4COOH. C. H2NC3H6COOH. D. H2NC4H8COOH Cu 37: Dy cc cht no sau y c th tham gia phn ng to polime ? A. Axit aipic; axit caproic; hexametilen iamin; etilenglicol B. popilen, anilin, axit metacrilic, cumen C. Phenol; xilen; alanin; valin; axit enantoic D. Caprolactam; axit terephtalic; glixerol; axit oxalic Cu 38: Cho kim loi M vo dung dch mui ca kim loi X thy c kt ta v kh bay ln. Cho kim loi X vo dung dch mui ca kim loi Y thy c kt ta. Mt khc, cho kim loi X vo dung dch mui ca kim loi Z, khng thy c hin tng g. Cho bit s sp xp no sau y ng vi chiu tng dn tnh kim loi ca X, Y, Z, M ? A. X < Y < M < Z B. Y < X < Z < M C. M < Z < X < Y D. Z < Y < X < M Cu 39: Hn hp X cha K2O, NH4Cl, KHCO3 v BaCl2 c s mol mi cht u bng 0,1 mo l. Cho hn hp X vo H2O (d), un nng, ri c cn phn dd thu c m gam cht rn khan. Gi tr ca m l: A. 7,45 B. 22,35 C. 11,175 D. 14,9 Cu 40: in phn dung dch cha a mol CuSO4, b mol NaCl (vi in cc tr, mng ngn xp). Dung dch thu c sau phn ng ho tan c Al2O3. Quan h gia a v b l A. a < 2b hoc a > 2b. B. a < b. C. b > 2a hoc b < 2a. D. b 2a. Cu 41: S hp cht l ng phn cu to, c cng cng thc phn t C4H8O2, tc dng c vi dung dch NaOH nhng khng tc dng c vi Na l
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Ti liu n thi i hc nm 2012 -2013 A. 2 B. 1 C. 3 D. 4 Cu 42: Ho tan 27,2 gam hn hp bt Fe v FeO trong dung dch axit sunfuric long, sau lm bay hi dung dch thu c 111,2 gam FeSO4.7H2O. Thnh phn % khi lng cc cht trong hn hp l A. 29,4% Fe v 70,6% FeO B. 24,9% Fe v 75,1% FeO C. 20,6% Fe v 79,4% FeO D. 26,0% Fe v 74,0% FeO + + 2+ 2+ Cu 43: Trong dung dch c cha cc cation K , Ag , Fe , Ba v mt anion X. Anion X l A. ClB. NO3C. SO42D. CO32Cu 44: Tn ca cc loi qung cha FeCO3 , Fe2O3, Fe3O4, FeS2. ln lt l A. Hematit; pirit ; manhetit ; xierit B. Xierit ;Manhetit; pirit ; Hematit C. Xierit ; Hematit; manhetit ; pirit D. Pirit ; Hematit; manhetit ; xierit Cu 45: Thi V lt (ktc) kh CO2 vo 300 ml dung dch Ca(OH)2 0,02M th thu c 0,2 gam kt ta. Gi tr ca V l: A. 44,8 ml hoc 89,6 ml B. 224 ml C. 44,8 ml hoc 224 ml D. 44,8 ml Cu 46: Nung 4,21 gam hn hp X gm Al, Mg, Fe trong oxi sau mt thi gian thu c 5,81 gam hn hp Y. Ha tan hon ton Y trong dung dch HNO3 d thu c 0,672 lt NO ( ktc v l sn phm kh duy nht). S mol HNO3 phn ng l: A. 0,36 mol B. 0,28 mol C. 0,32 mol D. 0,24 mol Cu 47: Trong t nhin oxi c ba ng v 16O, 17O, 18O; cacbon c hai ng v 12C, 13C. Hi c th c bao nhiu loi phn t kh cacbonic to thnh t cc ng v trn? A. 6. B. 9. C. 12. D. 18 Cu 48: Cho 17,88 gam hn hp X gm 2 axit cacboxylic l ng ng k tip nhau phn ng hon ton vi 200ml dung dch NaOH 1M v KOH 1M, thu c dung dch Y. C cn dung dch Y, thu c 32,22 gam hn hp cht rn khan. Cng thc ca 2 axit trong X l: A. C3H4O2 v C4H6O2 B. C2H4O2 v C3H6O2 C. C2H4O2 v C3H4O2 D. C3H6O2 v C4H8O2 + o Cu 49: Cho hn hp tt c cc ng phn mch h ca C4H8 tc dng vi H2O (H , t ) thu c ti a bao nhiu sn phm cng ? A. 4 B. 2 C. 6 D. 5 Cu 50: Nu thu phn khng hon ton pentapeptit: GlyAlaGlyAlaGly th thu c ti a bao nhiu ipeptit khc nhau? A. 1 B. 4 C. 2 D. 3 B S 28 Cu 1: Hp cht A c cng thc phn t C4H6Cl2O2. Cho 0,1 mol A tc dng va vi dung dch c cha 0,3 mol NaOH, thu c dung dch hn hp trong c hai cht hu c gm ancol etylic v cht hu c X, c cn dung dch sau phn ng thu c m gam cht rn khan. Khi lng m l: A. 9,6 gam B. 23,1 gam C. 11,4 gam D. 21,3 gam Cu 2: Nhn nh no sau y khng ng? A. Axeton khng lm mt mu dung dch KMnO4 iu kin thng. B. Cc xeton khi cho phn ng vi H2 u sinh ra ancol bc 2. C. Tr axetilen, cc ankin khi cng nc u cho sn phm chnh l xeton. D. Cc hp cht c cha nhm >C=O u phn ng vi dung dch Br2. Cu 3: Cho 70g hn hp phenol v cumen tc dung vi dung dch NaOH 16% va , sau phn ng thy tch ra hai lp cht lng phn cch, chit thy lp pha trn c th tch l 80 ml v c khi lng ring 0,86g/cm 3. % theo khi lng ca cumen trong hn hp l: A. 26,86% B. 98,29% C. 73,14% D. 56,8% Cu 4: Cho 27,3 gam hn hp A gm hai este no, n chc tc dng va vi dung dch KOH, thu c 30,8 gam hn hp hai mui ca 2 axit k tip v 16,1 gam mt ancol. Khi lng ca este c khi lng phn t nh c trong hn hp A l A. 21 gam. B. 22 gam. C. 17,6 gam. D. 18,5 gam.
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Ti liu n thi i hc nm 2012 -2013 Cu 5: Ch dng qu tm c th nhn bit c ti a bao nhiu dung dch trong cc dung dch sau: NaCl, NaHCO3, Na2CO3, NaHSO4, NaNO3, NaOH. A. 3 B. 2 C. 4 D. 6 Cu 6: Cho 13,62 gam trinitrotoluen (TNT) vo mt bnh ng bng thp c dung tch khng i 500ml (khng c khng kh) ri gy n. Sau phn ng nhit bnh l 1800 0C, p sut trong bnh l P atm, bit rng sn phm kh trong bnh sau n l hn hp CO, N2, H2. P c gi tr l: A. 224,38 B. 203,98 C. 152,98 D. 81,6 Cu 7: trung ho dung dch cha 0,9045 gam 1 axit hu c A cn 54,5 ml dung dch NaOH 0,2 M. Trong dung dch ancol B 94% (theo khi lng) t s mol ancol : nc l 86:14. Cng thc ca A v B l: A. C4H8(COOH)2, C2H5OH B. C6H4(COOH)2, CH3OH C. C4H8(COOH)2, CH3OH D. C6H4(COOH)2, C2H5OH. Cu 8: Cc cht kh sau: SO2, NO2, Cl2, N2O, H2S, CO2. Cc cht kh khi tc dng vi dung dch NaOH ( nhit thng) lun to ra 2 mui l: A. NO2, SO2 , CO2 B. CO2, Cl2, N2O C. SO2, CO2, H2S D. Cl2, NO2 Cu 9: Hp cht hu c X c cng thc phn t C 6H10O2, cho 9,12 gam X tc dng vi dung dch NaOH va thu c dung dch Y, cho dung dch Y tc dng vi dung dch AgNO 3 d trong NH3 un nng thu c 34,56 gam Ag. S ng phn cu to ca X l: A. 4. B. 5 C. 2. D. 3. Cu 10: Cho 11,36 gam hn hp gm Fe, FeO, Fe 2O3, Fe3O4 phn ng ht vi dung dch HNO 3 long d thu c 1,344 lt kh NO sn phm kh duy nht ( ktc) v dung dch X. Dung dch X c th ho tan c ti a 11,2 gam Fe. S mol ca HNO3 c trong dung dch ban u l: A. 0,94 mol. B. 0,64 mol. C. 0,86 mol. D. 0,78 mol. Cu 11: Cho cc cht v dung dch sau: toluen, stiren, etilen, xiclopropan, isopren, vinyl axetat, etyl acrylat, ivinyl oxalat, foocmon, axeton, dung dch glucoz, dung dch Fructoz, dung dch mantoz, dung dch saccaroz. S cht v dung dch c th lm mt mu dung dch Br2 l: A. 11. B. 10 C. 8 D. 9 Cu 12: Ha tan 14g hn hp Cu, Fe3O4 vo dung dch HCl, sau phn ng cn d 2,16g hn hp cht rn v dung dch X. Cho X tc dng vi AgNO3 d thu c bao nhiu gam kt ta: A. 45,92 B. 12,96 C. 58,88 D. 47,4 Cu 13: Ho tan ht m gam Al2(SO4)3 vo nc c dung dch X. Cho 360 ml dung dch NaOH 1M vo X, thu c 2a gam kt ta. Mc khc, nu cho 400 ml dung dch NaOH 1M vo X, cng thu c a gam kt ta. Cc phn ng xy ra hon ton, gi tr ca m l: A. 18,81 B. 15,39 C. 20,52 D. 19,665 Cu 14: Cho cc phn ng: to (1). O3 + dung dch KI (6). F2 + H2O to (2). MnO2 + HCl c (7). H2S + dung dch Cl2 to (3). KClO3 + HCl c (8). HF + SiO2 o t to (4). NH4HCO3 (9). NH4Cl + NaNO2 to (5). NH3(kh) + CuO (10). Cu2S + Cu2O S trng hp to ra n cht l: A. 5. B. 6. C. 7. D. 8. Cu 15: Ha tan 15,84 gam hn hp gm mt oxit kim loi kim v mt oxit kim loi kim th bng dung dch HCl d c dung dch X. C cn dung dch X, ly mui khan em in phn nng chy hon ton th thu c 6,048 lt kh (o ktc) anot v a (gam) hn hp kim loi catot. Gi tr ca a l: A. 7,2. B. 11,52. C. 3,33. D. 13,68. Cu 16: X l ipeptit Ala-Glu, Y l tripeptit Ala-Ala-Gly. un nng m (gam) hn hp cha X v Y c t l s mol ca X v Y tng ng l 1:2 vi dung dch NaOH va . Phn ng hon ton thu c dung dch T. C cn cn thn dung dch T thu c 56,4 gam cht rn khan. Gi tr ca m l: A. 45,6 B. 40,27. C. 39,12. D. 38,68. Cu 17: C cc nhn xt sau: (1) Cht bo thuc loi cht este.
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Ti liu n thi i hc nm 2012 -2013 (2) T nilon, t capron, t enang u iu ch bng phn ng trng ngng. (3) Vinyl axetat khng iu ch c trc tip t axit v ancol tng ng. (4) Nitro benzen phn ng vi HNO3 c (xc tc H2SO4 c) to thnh m-initrobenzen. (5) phenyl amoni clorua phn ng vi nc brom d to thnh (2,4,6-tribromphenyl) amoni clorua. Nhng cu ng l: A. 1, 3, 4. B. 2, 3, 4. C. Tt c. D. 1, 2, 4, 5. Cu 18: Mt loi phn Supephotphat kp c cha 72,68% mui canxi ihirophotphat cn li gm cc cht khng cha pht pho. dinh dng ca loi phn ln ny l: A. 60,68% B. 37,94% C. 30,34% D. 44,1% Cu 19: Pht biu no di y khng ng? A. Cht bo nh hn nc v khng tan trong nc B. M ng vt ch yu cu thnh t gc axit bo, no, tn ti trng thi rn C. Hiro ho du thc vt lng s to thnh cc m ng vt rn D. Nhc im ca cht git ra tng hp l gy nhim cho mi trng Cu 20: Cho cc cht sau: FeBr3, FeCl2, Fe3O4, AlBr3, MgI2, KBr, NaCl, CaF2, CaC2. Axit H2SO4 c nng c th oxi ha bao nhiu cht? A. 3 B. 6 C. 5 D. 7 Cu 21: Cho ankan X tc dng vi clo (as) thu c 26,5 gam hn hp cc dn xut clo (mono v iclo). Kh HCl bay ra c hp th hon ton bng nc sau trung ha bng dd NaOH thy tn ht 500 ml dd NaOH 1M. Xc nh CT ca X? A. C2H6 B. C4H10 C. C3H8 D. CH4 Cu 22: Cho cc cht: xiclobutan, metylxiclopropan, 1,2-imetylxiclopropan, -butilen, but-1-in, trans but-2en, butaien, vinyl axetilen, isobutilen, anlen. C bao nhiu cht trong s cc cht trn khi tc dng vi hiro c th to ra butan. A. 8 B. 9 C. 7 D. 6 Cu 23: Khi iu ch Na trong cng nghip ngi ta dng hn hp gm 2 phn NaCl v 3 phn CaCl 2 v khi lng vi mc ch: A. To ra nhiu cht in ly hn B. Tng nng ion ClC. Gim nhit nng chy D. To ra hn hp c khi lng ring nh ni ln trn Na nng chy Cu 24: Cho cc phn ng:
CH 2=CH2 + H2O C2H5OH + HBr (bk) CH3 -CH=CH 2 + Br 2(dd) toc
H

Cl 2 + KOH Mg(NO 3)2 Na 2O2 + H2O

toc

Fe3O4 + H2SO4 (loang) CH3 -CHO + H2 Trong cc phn ng trn c bao nhiu phn ng l oxh-kh, bao nhiu phn ng ni phn t: A. 7 4 B. 6 4 C. 5 4 D. 6 2 121 123 Cu 25: Sb cha 2 ng v chnh Sb v Sb, khi lng nguyn t trung bnh ca Sb l 121,75. % khi lng ca ng v 121 Sb trong Sb2O3 (MO=16) l: A. 52,2 B. 62,5 C. 26,1 D. 51,89 Cu 26: Cho H (Z=1), N (Z=7), O (Z=8). Trong phn t HNO 3, tng s cp electron lp ngoi cng khng tham gia lin kt ca 5 nguyn t l: A. 8. B. 9. C. 7. D. 6. Cu 27: Mt loi cao su buna-N c phn trm khi lng ca nit l 19,72%. T l mt xch butaien v vinyl xianua l: A. 1 : 2 B. 2 : 1 C. 1 : 3 D. 3 : 1 Cu 28: Cho cc cn bng sau: (1) 2NH3(k) N2(k) + 3H2(k) H > 0 (2) 2SO2(k) + O2(k) 2SO3(k) H < 0 (3) CaCO3(r) CaO(r) + CO2(k) H > 0 (4) H2(k) + I2(k) 2HI(k) H < 0 Trong cc cn bng trn cn bng no s chuyn dch theo chiu thun khi tng nhit v gim p sut:
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Ti liu n thi i hc nm 2012 -2013 A. 1, 3. B. 2, 4. C. 1, 2, 3 ,4. D. 1, 4. Cu 29: Cho cc dung dung dch sau: (1): natri cacbonat; (2): st (III) clorrua; (3): axit sunfuaric long; (4): axit axetic; (5): natri phenolat; (6): phenyl amoni clorua; (7): imetyl amoni clorua. Dung dch metylamin tc dng c vi dung dch: A. 3, 4, 6, 7 B. 2, 3, 4, 6 C. 2, 3, 4, 5 D. 1, 2, 4, 5 Cu 30: Cho mt ipeptit Y c cng thc phn t C6H12N2O3. S ng phn peptit ca Y (ch cha gc -amino axit) mch h l: A. 5. B. 4. C. 7. D. 6. Cu 31: Cho dung dch mui X vo cc dung dch Na2CO3 ; dung dch Na2S u thy c kt ta v c kh bay ln. Vy X l : A. AlCl3 B. FeCl3 C. FeCl2 D. CuCl2. Cu 32: C cc pht biu sau y: (1) Amiloz c cu trc mch phn nhnh. (2) Mantoz b kh ha bi dd AgNO3 trong NH3. (3) Xenluloz c cu trc mch phn nhnh. (4) Saccaroz lm mt mu nc brom. (5) Fructoz c phn ng trng bc. (6) Glucoz tc dng c vi dung dch thuc tm. (7) Trong dung dch, glucoz tn ti ch yu dng mch vng v mt phn nh dng mch h. S pht biu ng l: A. 6. B. 4. C. 5. D. 3. Cu 33: Gi thit trong tinh th cc nguyn t st l nhng hnh cu chim 74% th tch tinh th, phn cn li l cc khe rng gia cc qu cu, cho nguyn t khi ca Fe l 55,85 20 0C khi lng ring ca Fe l 7,87g/cm3. Bn knh nguyn t gn ng ca Fe l: A. 1,28 A0. B. 1,41A0. C. 1,67 A0. D. 1,97 A0. Cu 34: Cho 7,8 gam hn hp X gm 2 ancol n chc, bc I qua CuO d, nung nng (phn ng hon ton) sau phn ng thy khi lng cht rn gim 3,2 gam. Cho hn hp sn phm tc dng vi AgNO 3 d trong NH3, un nng thu c m gam Ag. Gi tr ca m l: A. 64,8 B. 43,2 C. 21,6 D. 86,4 Cu 35: Hn hp X gm NaBr v NaI. Cho hn hp X tan trong nc thu c dung dch Y. Nu cho brom d vo dung dch Y, sau phn ng hon ton, c cn thy khi lng mui khan thu c gim 7,05 gam. Nu sc kh clo d vo dung dch Y, phn ng hon ton, c cn dung dch thy khi lng mui khan gim 22,625 gam. Thnh phn % khi lng ca mt cht trong hn hp X l: A. 35,9% B. 47,8% C. 33,99% D. 64,3% Cu 36: Cho hi nc i qua than nung nng sau khi loi b hi nc d thu c 17,92 lt (ktc) hn hp kh X gm CO2, CO v H2. Hp th X vo dung dch Ba(OH)2 d thu c 35,46 gam kt ta v c V lt kh Y thot ra. Cho Y tc dng vi CuO d nung nng sau phn ng thy khi lng cht rn gim m gam. Gi tr ca m l: A. 12,8 gam B. 2,88 gam C. 9,92 gam D. 2,08 gam Cu 37: t chy hon ton mt hn hp X (glucoz, fructoz, metanal v etanoic) cn 3,36 lt O 2 (iu kin chun). Dn sn phm chy qua bnh ng dung dch Ca(OH) 2 d, sau phn ng hon ton thu c m gam kt ta. Gi tr ca m l A. 10,0 B. 12,0 C. 15,0 D. 20,5 Cu 38: C cc pht biu sau: (1) Lu hunh, photpho, C2H5OH u bc chy khi tip xc vi CrO3. (2) Ion Fe3+ c cu hnh electron vit gn l [Ar]3d5. (3) Bt nhm t bc chy khi tip xc vi kh clo. (4) Phn chua c cng thc l Na2SO4.Al2(SO4)3.24H2O. Cc pht biu ng l: A. (1), (2), (4) B. (1), (2). C. (1), (2), (3). D. (3), (4). Cu 39: in phn c mng ngn vi in cc tr 250 ml dung dch hn hp CuSO 4 aM v NaCl 1,5M, vi cng dng in 5A trong 96,5 pht. Dung dch to thnh b gim so vi ban u l 17,15g. Gi tr ca a l A. 0,5 M. B. 0,4 M. C. 0,474M. D. 0,6M. Cu 40: Nung hn hp gm 11,2 gam Fe; 6,4 gam Cu v 19,5 gam Zn vi mt lng d lu hunh n khi phn ng hon ton. Sn phm ca phn ng tc dng vi dung dch HCl d thu c kh B. Th tch dung dch Pb(NO3)2 20% (d = 1,1 g/ml) ti thiu cn dng hp th ht kh B l
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Ti liu n thi i hc nm 2012 -2013 A. 752,27 ml B. 902,73 ml C. 1053,18 ml D. 910,25 ml Cu 41: Cho cc cht sau: axetilen, axit oxalic, axit acrylic, fomanehit, phenyl fomat, vinyl axetilen, glucz, anehit axetic, metyl axetat, saccaroz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l A. 6 B. 8 C. 7 D. 5 Cu 42: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X cn 50 ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 19,04 lt kh CO 2 ( ktc) v 14,76 gam H2O. % s mol ca axit linoleic trong m gam hn hp X l: A. 31,25% B. 30% C. 62,5% D. 60% Cu 43: Dy cc kim loi c cu trc mng tinh th lp phng tm khi l: A. Na, K, Ba B. Ca, Sr, Ba C. Mg, Ca, Ba D. Na, K, Mg Cu 44: Xt phn ng: CO(kh) + H2O (kh) CO2(kh) + H2(kh). Trong iu kin ng nhit, khi tng p sut ca h th tc phn ng nghch nh th no? A. Gim. B. Tng. C. C th tng hoc gim D. Khng i. Cu 45: Hin tng ln lt xy ra khi cho t t n d dung dch NaOH vo dung dch CrCl 3, thm tip H2O2 d, ri cho dung dch BaCl2 vo l: A. To kt ta xanh lc ri tan, thnh dung dch da cam, sau c kt ta mu vng. B. To kt ta xanh lc ri tan, thnh dung dch mu vng, sau c kt ta da cam. C. To kt ta xanh lc ri tan, thnh dung dch mu vng, sau c kt ta mu vng. D. To kt ta trng ri tan, thnh dung dch mu xanh, sau c kt ta mu vng. Cu 46: Hn hp X gm hai anken c t khi so vi H2 bng 16,625. Ly hn hp Y cha 26,6 gam X v 2 gam H2. Cho Y vo bnh kn c dung tch V lt ( ktc) c cha Ni xc tc. Nung bnh mt thi gian sau a v 0 o C thy p sut trong bnh bng 7/9 at. Bit hiu sut phn ng hiro ho ca cc anken bng nhau v th tch ca bnh khng i. Hiu sut phn ng hiro ho l A. 40%. B. 50%. C. 75%. D. 77,77%. Cu 47: X c cng thc C4H14O3N2. Khi cho X tc dng vi dung dch NaOH th thu c hn hp Y gm 2 kh iu kin thng v u c kh nng lm xanh qu tm m. S CTCT ph hp ca X l: A. 5 B. 3 C. 4 D. 2 Cu 48: Co hai thi nghim sau: Thi nghim 1: Cho 6g ancol no h n chc X tac dung vi m gam Na, sau phan ng thu c 0,075 g H2. Thi nghim 2: Cho 6g ancol no h n chc X tac dung vi 2m gam Na, sau phan ng thu khng ti 0,1 g H2. X co cng thc la: A. CH3OH. B. C2H5OH. C. C3H7OH. D. C4H9OH. Cu 49: Ha tan m gam hh X gm CuCl 2 v FeCl3 trong nc c dung dch Y. Chia Y thnh 2 phn bng nhau. Phn 1 : cho kh H 2S d vo c 1,28g kt ta. Phn 2 : cho Na 2S d vo c 3,04g kt ta. Gi tr ca m l : A. 14,6 g B. 8,4 g C. 10,2 g D. 9,2 g Cu 50: xc nh hm lng ca FeCO3 trong qung xierit, ngi ta lm nh sau: Cn 0,600 gam mu qung, ch ho n theo mt quy trnh hp l, thu c dd FeSO 4 trong mi trng H2SO4 long. Chun dung dch thu c bng dung dch chun KMnO 4 0,025M th dng va ht 25,2 ml dung dch chun. Thnh phn phn trm theo khi lng ca FeCO3 trong qung l: A. 12,18% B. 60,9% C. 24,26% D. 36,54% B S 29 Cu 1: C hai bnh in phn mc ni tip: Bnh (1) cha 100ml dung dch CuSO 4 0,1M; Bnh (2) cha 100ml dung dch NaCl 0,1M tin hnh in phn c mng ngn cho ti khi bnh hai to ra dung dch c pH=13 th ngng in phn. Gi s th tch dung dch hai bnh khng i. Nng mol/l ca ion Cu 2+ trong dung dch bnh (1) sau in phn l: A. 0,04M. B. 0,10M. C. 0,05M. D. 0,08M. Cu 2: Khi t chy hon ton 6,44 gam mt ancol no X th thu c 9,24 gam khi CO 2. Mt khc khi cho 0,1 mol X tc dng vi kali cho 3,36 lt kh (o ktc). Cng thc cu to thu gn ca X l A. C3H7OH. B. C2H4(OH)2. C. C3H6OH. D. C3H5(OH)3.

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Ti liu n thi i hc nm 2012 -2013 Cu 3: Oxi ha m gam X gm CH3CHO, C2H3CHO, C2H5CHO bng oxi c xc tc sn phm thu c sau phn ng gm 3 axit c khi lng (m + 3,2) gam. Cho m gam X tc dng vi lng d dung dch AgNO 3/NH3 th thu c x gam kt ta. Gi tr ca x l A. 10,8. B. 43,2. C. 32,4. D. 21,6. Cu 4: Cho cc cht sau: CH3-CH2-CHO (1), CH2=CH-CHO (2), (CH3)2CH-CHO (3), CH2 =CH-CH2-OH (4). Nhng cht phn ng hon ton vi lng d H2 (Ni, t0C) cng to ra mt sn phm l: A. (2), (3), (4). B. (1), (3), (4). C. (1), (2), (4). D. (1), (2), (3). Cu 5: Cho 29,8 gam hn hp 2 amin n chc k tip tc dng ht vi dung dch HCl, lm kh dung dch thu c 51,7 gam mui khan. Cng thc phn t 2 amin l A. CH5N v C2H7N. B. C3H9N v C4H11N. C. C2H7N v C3H9N. D. C3H7N v C4H9N. Cu 6: Cho s sau: Tinh bt glucoz ancol etylic axit axetic iu ch 300 gam dung dch CH 3COOH 25% th phi cn m gam go (cha 80% tinh bt). Bit hiu sut ca mi phn ng t 75%. Gi tr ca m l A. 240 B. 150 C. 300 D. 135 Cu 7: Ho tan hon ton 74 gam hn hp X gm FeO, Fe 3O4, Fe2O3 bng dung dch H2SO4 long d sinh ra 178 gam mui sunfat. Nu cng cho 74 gam hn hp X trn phn ng vi lng d kh CO nhit cao. Sau phn ng, dn sn phm kh qua dung dch nc vi trong d th khi lng kt ta to thnh l m(g). Gi tr ca m l (cc phn ng xy ra hon ton) A. 130. B. 180. C. 240. D. 150. Cu 8: X, Y, Z, T l cc hp cht ca clo. Cho kh clo tc dng nc vi thu c X. Cho kh clo tc dng dung dch KOH long, ngui thu c cht Y v Z. Cho kh clo tc dng dung dch KOH c, nng c cht T v Z. Cc cht X, Y, Z, T ln lt l: A. CaCl2, KClO, KCl, KClO3. B. CaOCl2, KClO, KCl, KClO3. C. CaOCl2, KClO, KClO3, KCl. D. CaOCl2, KCl, KClO, KClO3. Cu 9: Cho s sau: Cu + dung dch mui X khng phn ng; Cu + dung dch mui Y khng phn ng. Cu + ddung dch mui X + dung dch mui Y phn ng Vi X, Y l mui ca natri. X, Y c th l A. NaNO3, NaHSO4. B. NaAlO2, NaNO3. C. NaNO3, NaHCO3. D. NaNO2, NaHSO3. Cu 10: Caroten (cht mu vng da cam c trong c c rt) c cng thc phn t C 40H56 c cha lin kt i v c vng. Khi hiro ho hon ton caroten thu c mt hirocacbon no c cng thc phn t C 40H78. S vong v s lin kt i trong phn t caroten l A. 1 vng v 11 ni i B. 2 vng v 11 ni i. C. 2 vng v 13 ni i D. 1 vng v 13 ni i to to to Cu 11: Cho s C2H2 X Y CH3COOH. Trong cc cht: C2H6, C2H4, CH3CHO, CH3COOCH=CH2. S cht ph hp vi cht X trong s trn l A. 2. B. 1. C. 4. D. 3. Cu 12: Ha tan hon ton hn hp 3 kim loi: Zn, Fe, Cu bng dung dch HNO 3 long, sau khi phn ng xy ra hon ton, thu c mt phn cht rn cha tan ht l Cu. Phn dung dch sau phn ng c cht tan l A. Zn(NO3)2, Fe(NO3)3, Cu(NO3)2. B. Zn(NO3)2, Fe(NO3)3. C. Zn(NO3)2, Fe(NO3)2. D. Zn(NO3)2, Fe(NO3)2, Cu(NO3)2. Cu 13: Nhng mt thanh magie vo dung dch c cha 0,8 mol Fe(NO 3)3 v 0,05 mol Cu(NO3)2. Sau mt thi gian, ly thanh kim loi ra, ra sch, cn li thy khi lng tng 11,6 gam so vi thanh kim loi ban u. Khi lng magie phn ng l A. 25,20 gam. B. 24,00 gam. C. 20,88 gam. D. 6,96 gam. Cu 14: t chy hon ton m gam hn hp gm hai este X 1, X2 l ng phn ca nhau cn dng 19,6 gam O 2, thu c 11,76 lit CO2 (ktc) v 9,45 gam H2O. Mt khc, nu cho m gam hn hp trn tc dng ht vi 200ml dung dch NaOH 1M ri c cn dung dch sau phn ng th cn li 13,95 gam cht rn khan. T l mol ca X 1, X2 l A. 1:2. B. 4:3. C. 2:3. D. 3:1. Cu 15: Cho t t 100 ml dung dch HCl 1,5 M vo 0,4 lt dung dch X gm Na 2CO3 v KHCO3 thu c 1,008 lt CO2 (ktc) v dung dch Y. Thm dung dch Ba(OH) 2 d vo dung dch Y thu c 29,55 gam kt ta. Nng mol/lit ca Na2CO3 v KHCO3 trong dung dch X ln lt l
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Ti liu n thi i hc nm 2012 -2013 A. 0,1125M v 0,225M. B. 0,0375 M v 0,05M. C. 0,2625M v 0,225M. D. 0,2625M v 0,1225M. Cu 16: Th tch dung dch HCl 0,3M cn trung ho 100ml dung dch hn hp NaOH 0,1M v Ba(OH) 2 0,1M l: A. 250 ml. B. 150 ml. C. 200 ml. D. 100 ml. Cu 17: Ha tan hon ton hn hp gm mt kim loi ha tr 1 v oxit kim loi ha tr 2 vo nc d. Sau khi phn ng xong c 500 ml dd X ch cha mt cht tan duy nht v 4,48 lt kh H 2. Tnh nng mol ca dung dch X: A. 0,2M B. 0,4 M C. 0,3M D. 0,25 M Cu 18: C 3 ng nghim ng 3 dung dch ring bit gm: Cu(NO 3)2; Pb(NO3)2; Zn(NO3)2 c nh s theo th t ng ln lt l 1, 2, 3. Nhng 3 l km (ging ht nhau) X, Y, Z vo 3 ng th khi lng mi l km s thay i nh th no? A. X gim, Y tng, Z khng i. B. X tng, Y tng, Z khng i. C. X tng, Y gim, Z khng i. D. X gim, Y gim, Z khng i. Cu 19: Dn V lt hn hp kh X cha C2H2, C2H4, H2 qua Niken nung nng thu c hn hp kh Y. Dn hn hp Y qua nc Br2 d thy khi lng bnh tng 3,2 gam v thu c hn hp kh Z. t chy hon ton hn hp kh Z thu c 4,48 lt kh CO2 (ktc) v 5,4 gam H2O. Khi lng hn hp X l A. 6,2 gam. B. 5,9 gam. C. 7,5 gam. D. 4,8 gam. Cu 20: Cho tng cht : C, Fe, BaCl2, Fe3O4, Fe2O3, FeCO3, Al2O3, H2S, HI, HCl, AgNO3, Na2SO3 ln lt phn ng vi H2SO4 c, nng. S phn ng thuc loi phn ng oxi ha kh l A. 6. B. 5. C. 7. D. 8. Cu 21: Cho cc cht ring bit: axit fomic, anehit axetic, ancol etylic, axit axetic. Th t cc ho cht dng lm thuc th phn bit cc cht trn l: A. qu tm, dung dch NaOH. B. qu tm, dung dch NaHCO3. C. dung dch AgNO3/NH3, dung dch NaOH. D. qu tm, dung dch AgNO3/NH3. Cu 22: Ha tan hon ton 3 gam hn hp X gm Mg, Zn, Fe trong dung dch HNO3 long d. Sau phn ng thu c dung dch Y cha 16,95g mui (khng c NH4NO3) v 1,68 lt kh Z (kc). Z c th l: A. NO2. B. NO. C. N2O. D. N2 Cu 23: Cho cc phn ng sau : to to (1) F2 + H2O (2) Ag + O3 o t to (3) KI + H2O + O3 (4) Nhit phn Cu(NO3) 2 to to (5) in phn dung dch H2SO4 (6) in phn dung dch CuCl 2 o o 0 t t (7) Nhit phn KClO3 (MnO2, t ) (8) in phn dung dch AgNO3 S phn ng m sn phm to ra c O2 l A. 5. B. 7. C. 6. D. 8. Cu 24: C hai bnh kn khng gin n ng y cc hn hp kh toC nh sau: - Bnh (1) cha H2 v Cl2 - Bnh (2) cha CO v O2 Sau khi un nng cc hn hp phn ng xy ra, a nhit v trng thi ban u th p sut trong A. bnh (1) tng, bnh (2) gim. B. bnh (1) gim, bnh (2) tng. C. bnh (1) khng i, bnh (2) tng. D. bnh (1) khng i, bnh (2) gim. Cu 25: Cho 10,0 gam hn hp X gm Mg v Zn vo 400 ml dung dch H2SO4 1,1M thu c kh H2. Cho ton b lng kh i qua CuO d thy khi lng cht rn gim 4,48 gam. Phn trm v khi lng ca Mg trong hn hp X l : A. 60%. B. 36%. C. 24%. D. 48%. Cu 26: Ly cng khi lng cc kim loi Mg, Fe, Al v Zn cho vo dung dch H 2SO4 c, nng, d. Th tch kh SO2 thu c (o cng iu kin) tng ng vi cc kim loi c sp xp theo chiu tng dn l: A. Zn < Fe < Mg < Al. B. Fe < Zn < Al < Mg. C. Zn < Fe < Al < Mg. D. Zn < Mg < Fe < Al. Cu 27: Hn hp kim loi u phn ng vi mui st (III) trong dung dch nhng khng y c st ra khi mui l A. Fe, Ni, Cu. B. Mg, Al, Zn. C. K, Ca, Al. D. Cu, Mg, Ni.
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Ti liu n thi i hc nm 2012 -2013 Cu 28: Cho 7,2 gam hn hp hai mui cacbonat ca hai kim loi k tip nhau trong nhm IIA. Ho tan ht hn hp hai mui trong dung dch HCl thu c kh B. B c hp th hon ton bi 450ml dung dch Ba(OH)2 0,2M thy xut hin 15,76 gam kt ta. hai kim loi l: A. Mg - Ca hoc Ca Sr. B. Be Mg. C. Be - Mg hoc Mg Ca. D. Mg Ca. Cu 29: Nhng thanh Zn, thanh Cu v thanh hp kim Zn-Cu ln lt vo ba cc 1, 2, 3 u cha dung dch HCl nng bng nhau. Tc thot kh H2 din ra nhanh nht cc A. 3. B. 1 v 3. C. 1. D. 2. Cu 30: Trong cng nghip hin nay, iu ch axetanehit ngi ta A. oxi ho etilen bng O2 c xc tc PbCl2 v CuCl2 ( t0C). B. oxi ho ancol etylic bng CuO ( t0C). C. cho axetilen hp nc to = 80oC v xc tc HgSO4. D. thu phn dn xut halogen ( CH3-CHCl2 ) trong dung dch NaOH. Cu 31: Amino axit mch khng phn nhnh X cha a nhm -COOH v b nhm -NH 2. Khi cho 1 mol X tc dng ht vi axit HCl thu c 169,5 gam mui. Cho 1 mol X tc dng ht vi dung dch NaOH thu c 177 gam mui.CTPT ca X l A. C3H7NO2. B. C4H7NO4. C. C4H6N2O2. D. C5H7NO2. Cu 32: Dy cc kim loi c th iu ch bng phng php nhit luyn trong cng nghip l: A. Na, Fe, Sn, Pb. B. Cu, Fe, Pb, Mg. C. Al, Fe, Cu, Ni. D. Ni, Zn, Fe, Cu. + Cu 33: X c tng s ht l 57, Y l nguyn t thuc chu k nh k cn lin tip vi X, cng nhm vi X. Vy Y l: A. ng. B. Liti. C. Natri. D. Magie. Cu 34: Cho 16,2 g hn hp este ca ancol metylic v hai axit cacboxylic no, n chc tc dng va vi dung dch NaOH 1M thu c dung dch A. C cn dd A thu c 17,8 g hn hp hai mui khan, th tch dung dch NaOH 1 M dng l A. 0,2 lt. B. 0,25 lt. C. 0,3 lt. D. 0,35 lt. Cu 35: C 4 dung dch khng mu ng trong 4 l mt nhn: NaCl, MgCl 2, AlCl3, FeCl2. C th dng kim loi no di y phn bit 4 dung dch trn (khng c s dng thm thuc th khc)? A. Al. B. Ag. C. Fe. D. Na. Cu 36: Hn hp X gm CH3COOH v C2H5OH. Cho m gam X tc dng ht vi Na thu c 3,36 lt H 2(ktc). Cho m gam X tc dng vi KHCO3 d thu c 2,24 lt CO2 (ktc). Nu un nng m gam X (xc tc H2SO4 c)vi hiu sut phn ng 60% th lng este thu c l A. 5,28 gam. B. 6,16 gam. C. 8,8 gam. D. 10,56 gam. Cu 37: Cho s chuyn ho sau: (1) C3H4O2 + NaOH (A) + (B) (2) (A) + H2SO4 long (C) + (D) (3) (C) + AgNO3 + NH3 + H2O (E) + Ag + NH4NO3 (4) (B) + AgNO3 + NH3 + H2O (F) + Ag + NH4NO3 Cc cht (B) v (C) (theo th t) c th l A. CH3CHO v HCOOH. B. CH3CHO v HCOONa. C. HCHO v HCOOH. D. HCHO v CH3CHO. Cu 38: Oxi ha 4,6 gam hn hp hai ancol no n chc mch h thnh anehit th dng ht 8 gam CuO. Cho ton b andehit tc dng vi dung dch AgNO3/NH3 d, un nng thu c 32,4 gam Ag (hiu sut phn ng l 100%). Cng thc ca hai ancol l: A. C3H7CH2OH v C4H9CH2OH. B. CH3OH v C2H5CH2OH C. C2H5OH v CH3CH2CH2OH. D. CH3OH v C2H5OH. Cu 39: Cho cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2. Dy gm cc dung dch u tc dng c vi dung dch Ba(HCO3)2 l: A. HNO3, NaCl, Na2SO4, Ca(OH)2. B. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2. C. NaCl, Na2SO4, Ca(OH)2, KHSO4. D. HNO3, Ca(OH)2, KHSO4, Na2SO4. + + Cu 40: Trn 400 ml dung dch X cha Na , K , x mol OH (tng s mol Na+ v K+ l 0,06 mol) vi 600 ml dung dch Y cha 0,01 mol SO42, 0,03 mol Cl, y mol H+. pH ca dung dch thu c sau phn ng l
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Ti liu n thi i hc nm 2012 -2013 A. 1,0. B. 12,0. C. 13,0. D. 2,0. Cu 41: Mt hp cht hu c X c CTPT C 3H10O3N2. Cho X phn ng vi NaOH d, c cn dung dch sau phn ng thu c cht rn Y (ch c cc hp cht v c) v phn hi Z (ch c mt hp cht hu c no, n chc mch khng phn nhnh). Cng thc cu to ca X l A. H2N-CH(OH)CH(NH2)COOH. B. HCOONH3CH2CH2NO2. C. HO-CH2-CH2-COONH4. D. CH3-CH2-CH2-NH3NO3. Cu 42: Chia hn hp gm Mg v MgO thnh 2 phn bng nhau: - Phn 1 cho tc dng ht vi dung dch HCl thu c 3,36 lt H 2(ktc), dung dch sau phn ng cha 42,75 gam mui - Phn 2 cho tc dng ht vi dung dch HNO 3 thu dc 0,448 lt kh X nguyn cht (ktc). C cn cn thn v lm kh dung dch sau phn ng thu c 67,6 gam mui. Cng thc phn t ca kh X l: A. NO2. B. N2. C. NO. D. N2O. Cu 43: Bradikinin c tc dng lm gim huyt p. l nonapeptit c cng thc vit tt l Arg Pro Pro Gly Phe Ser Pro Phe Arg. Khi thy phn khng hon ton peptit ny th s tripeptit c cha phenylalanin (Phe) ti a thu c l A. 4. B. 5. C. 6. D. 7. Cu 44: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l A. 40%. B. 20%. C. 25%. D. 50%. Cu 45: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch NaOH 0,5M, thu c mt mui v 448 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH) 2 (d) th khi lng bnh tng 8,68 gam. Cng thc ca hai hp cht hu c trong X l A. HCOOH v HCOOCH3. B. HCOOH v HCOOC2H5. C. CH3COOH v CH3COOC2H5. D. C2H5COOH v C2H5COOCH3. Cu 46: Trong cc polime sau: (1) poli(metyl metacrylat); (2) t capron; (3) nilon-6,6; (4) poli(etylenterephtalat); (5) poli(vinylclorua); (6) poli(vinyl axetat). Cc polime c th tng hp bng phn ng trng hp l: A. (2), (3), (4), (6). B. (1), (2), (4), (6). C. (1), (2), (5), (6). D. (1), (2), (3), (5). Cu 47: Thu phn cc cht sau trong mi trng kim: CH 3CHCl2 (1), CH3COOCH=CH-CH3 (2), CH3COOC(CH3)=CH2 (3), CH3CH2CCl3 (4), CH3COO-CH2-OOCCH3 (5), HCOOC2H5 (6). Nhm cc cht sau khi thu phn cho sn phm c kh nng tham gia phn ng trng gng l: A. (1), (2), (3), (6). B. (1), (4), (5), (6). C. (1), (2), (5), (3). D. (1), (2), (5), (6). Cu 48: Hp cht X l dn xut ca benzen c CTPT C 8H10O2. X tc dng vi NaOH theo t l mol 1:1. Mt khc cho X tc dng vi Na th s mol H 2 thu c ng bng s mol ca X phn ng. Nu tch mt phn t H2O t X th to ra sn phm c kh nng trng hp to polime. S CTCT ph hp ca X l A. 6. B. 2. C. 5. D. 7. Cu 49: Cho a mol Fe vo dung dch b mol HNO3 thu c kh NO v dung dch cha 2 mui Fe . Thit lp mi quan h gia a,b. A. 8a/3<b<4a. B. 2a< b <4a. C. 7a/3<b<4a. D. 3a< b<4a. Cu 50: C cc nguyn t ha hc: 9X; 13M; 15Y; 17R. Th t cc nguyn t c m in tng dn l A. M < X < Y < R. B. M < Y < R < X. C. Y < M < R < X. D. M < Y < X < R. B S 30 Cu 1: Khi in phn mt dung dch mui,gi tr pH khu vc gn mt in cc gim xung.Dung dch mui em in phn l : A. KCl B. CuSO4 C. K2SO4. D. CuCl2 Cu 2: Trong s cc cht sau: HCOOH, CH 3CHO, CH3CH2OH, CH3COOH cht va c kh nng tham gia phn ng trng bc, va c kh nng tc dng vi Na gii phng H2 l: A. CH3COOH. B. CH3CHO. C. HCOOH. D. CH3CH2OH. Cu 3: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l :
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Ti liu n thi i hc nm 2012 -2013 A. C4H8. B. C3H6. C. C3H8. D. C3H4. Cu 4: Thm t t tng git H2SO4 vo dung dch Ba(OH)2 n d th dn in ca h s bin i nh sau: A. lc u tng, sau gim. B. gim dn. C. lc u gim, sau tng. D. tng dn. Cu 5: T anehit no n chc A c th chuyn trc tip thnh ancol B v axit D tng ng iu ch este E t B v D. Hy xc nh t s d = ME / MA. A. 2 /1 B. 2/3 C. 3/2 D. 1/2 Cu 6: Trong cc loi phn bn sau: NH4Cl, (NH2)2CO, (NH4)2SO4, NH4NO3; loi c hm lng m cao nht l A. NH4NO3. B. NH4Cl. C. (NH2)2CO. D. (NH4)2SO4. Cu 7: Mt loi thu tinh cha 13,0% Na2O; 11,7% CaO v 75,3% SiO2 v khi lng. Thnh phn ca loi thu tinh ny biu din di dng cc oxit l A. Na2O.6CaO.SiO2. B. Na2O.CaO.6SiO2. C. 2Na2O.CaO.6SiO2. D. 2Na2O.6CaO.SiO2. Cu 8: Tch nc hn hp 2 ru thu c 2 anken. Ete ha hon ton hn hp 2 ru trn th thu c 3 ete, trong c 1 ete l C5H12O. Ete c khi lng phn t ln nht thu c l: A. 74 B. 88 C. 46 D. 130 Cu 9: Hp th hon ton 4,48 lt kh CO2 ( ktc) vo 100 ml dung dch hn hp gm NaOH 1,5 M v Ba(OH)2 1M, sinh ra m gam kt ta. Gi tr ca m l A. 19,70. B. 39,40. C. 11,82. D. 9,85. Cu 10: Cho 1,38 gam X c cng thc phn t C 2H6O5N2 ( l mui ca -amino axit vi HNO3 ) phn ng vi 150 ml dung dch NaOH 0,2 M . Sau phn ng c cn thu c m gam rn Y. Gi tr ca m l: A. 2,14 B. 2,22 C. 1,13 D. 1,01 Cu 11: Cho cc cht lng sau:axit axetic,glixerol,triolein. phn bit cc cht lng trn,c th ch cn dng: A. nc v qu tm B. nc v dd NaOH C. dd NaOH D. nc Br2 Cu 12: Chia dung dch X gm CuSO4 v Al(NO3)3 thnh 2 phn bng nhau. Phn 1 cho tc dng vi dung dch BaCl2 d thu c 6,99 gam kt ta. Phn 2 cho tc dng vi dung dch NaOH d, ri ly kt ta nung n khi lng khng i thu c m gam cht rn. Gi tr ca m l A. 12,6. B. 4,4. C. 3,2. D. 2,4. Cu 13: Hp cht hu c X cha cc nguyn t(C,H,Cl) c %Cl=84,53% v khi lng.X tc dng va vi dd NaOH thu c cht hu c Y.Khi lng phn t Y c gi tr A. 60 B. 98 C. 44 D. 82 Cu 14: thu c CO2 tinh khit t hn hp CO2 b ln kh HCl v hi nc ta cho hn hp qua ln lt cc bnh cha lng d A. dd NaHSO4, dd H2SO4 c. B. dd H2SO4 c, dd Na2CO3. C. dd Na2CO3, dd H2SO4 c. D. dd H2SO4 c, NaHCO3. Br (1:1) NaOH CuO HCO-CH2-CHO Cu 15: Cho s sau: C3H6 X Y CTCT ca X l: A. CH2Br-CH=CH2 B. CH3CH2CH2OH C. BrCH2CH2CH2Br D. CH3CH(Br)CH2Br Cu 16: Chn pht biu ng v O2 v O3? A. O2 v O3 c s proton v ntron trong phn t nh nhau. B. O2 v O3 l cc dng th hnh ca nguyn t oxi. C. O2 v O3 c tnh oxi ho manh nh nhau. D. C O2 v O3 u phn ng c vi cc cht Ag, KI, PbS nhit thng. Cu 17: Cho lung kh CO i qua ng s ng m(g) Fe 2O3 nhit cao mt thi gian ngi ta thu c 6,72(g) hn hp 4 cht rn khc nhau.em ha tan hn hp ny vo dung dch HNO 3 d to thnh 0,672(l) NO duy nht(ktc).Gi tr ca m l: A. 6,80(g) B. 6,72(g) C. 8,80(g) D. 7,44(g)
2

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Ti liu n thi i hc nm 2012 -2013 Cu 18: Cho V lt Cl2 (ktc) tc dng vi dd NaOH long, ngui d thu c m 1 gam tng khi lng 2 mui. Cho 2V lt kh Cl2 (ktc) tc dng vi dd NaOH c, nng d thu c m2 gam tng khi lng 2 mui. T l m1: m2 bng: A. 1:1. B. 2:3 C. 2:1 D. 1:2 Cu 19: Cho bit s hiu nguyn t ca cc nguyn t: Z H = 1, ZB = 5, ZC = 6, ZN = 7, ZO = 8, ZAl =13, ZP = 15, ZS = 16. Nhm no sau y cha ton cc cht khng tun theo qui tc bt t? A. BH3, NO2, PCl5. B. CO2 , C2H6, HNO3. C. CH4, CO2, Al2S3. D. CH4, H2O2, CS2. Cu 20: Cho 0,05 mol cht hu c X tc dng hon ton vi dd Br2,thu c cht hu c Y(cha 3 nguyn t).Khi lng dd Br2 tng ln 2,1 gam.Thy phn cht Y c cht Z khng c kh nng ha tan Cu(OH)2.Cht X l: A. axit fomic B. ancol etylic C. propen D. xiclo propan Cu 21: Cho a (mol) hp cht hu c X c cng thc phn t C 7H8O2 tc dng vi natri d thu c a (mol) kh H2(ktc). Mt khc, a (mol)X ni trn tc dng va vi a (mol) Ba(OH)2. Trong phn t X c th cha: A. 1 nhm OCH2OH lin kt vi nhn thm. B. 2 nhm OH lin kt trc tip vi nhn thm. C. 1 nhm cacboxyl COOH lin kt vi nhn thm. D. 1 nhm CH2OH v 1 nhm OH lin kt vi nhn thm. Cu 22: Cho 14,2 gam P2O5 vo 100 ml dung dch cha NaOH 1M v KOH 2M thu c dung dch X. Tng khi lng mui tan c mt trong X l: A. 28,6 gam B. 27,2 gam C. 29,4 gam D. 29,1 gam Cu 23: t chy hon ton a gam este X to bi ancol no,n chc,mch h v axit khng no(c mt lin kt i),n chc,mch h thu c 8,96 lt CO2 (kc) v 5,4 gam H2O.Gi tr ca a l: A. 5,6 gam B. 5,4 gam C. 8,6 gam D. 8,8 gam Cu 24: Np 2 kh N2 v H2 vo bnh kn thc hin phn ng: N2 + 3H2 2NH3. Sau mt thi gian, nng cc cht trong bnh nh sau:[N2] = 2M; [H2] = 3M; [NH3] = 2M. Nng mol/l ca N2 v H2 ban u ln lt l A. 4 v 8. B. 2 v 3. C. 2 v 4. D. 3 v 6. Cu 25: Trong cng nghip, andehit fomic c iu ch trc tip t A. ru metylic B. ru etylic C. metyl axetat D. axit fomic Cu 26: Cho 5,9 gam hirocacbon thm A ( c vng benzen ) bc hi trong bnh kn dung tch 5,6 lt ti nhit 136,50C th p sut trong bnh lc ny l 0,3 atm.S ng phn cu to tha mn A l: A. 6 B. 12 C. 8 D. 10 Cu 27: Xt cc loi hp cht hu c, mch h sau : Ru n chc no ( X), anehit n chc no (Y), ru n chc khng no 1 i i ( Z); andehit n chc, khng no 1 ni i ( T). ng vi cng thc tng qut CnH2nO ch c 2 cht sau : A. X, T B. Z, T C. X, Y D. Y, Z Cu 28: X phng ha 2,76 gam mt este X bng dung dch NaOH va ,thu c 4,44 gam hn hp 2 mui ca Na.Nung nng 2 mui ny trong O2 d,sau khi phn ng hon ton,thu c 3,18 gam Na 2CO3;2,464 lt kh CO2 (kc) v 0,9 gam nc.Cng thc n gin cng l CTPT ca X.Vy CTCT thu gn ca X l: A. C6H5COOCH3 B. HCOOC6H5 C. CH3COOC6H5 D. HCOOC6H4OH Cu 29: Dn t t n d kh H2S qua dung dch X cha NaCl, NH4Cl, CuCl2 v FeCl3 thu c kt ta Y gm A. CuS v FeS. B. CuS. C. CuS v S. D. Fe2S3 v CuS. Cu 30: S nguyn t m nguyn t c tng s 4 electron trn phn lp s l: A. 2. B. 7. C. 1. D. 6. Cu 31: t chy hon ton m gam mt amin X bng mt lng khng kh va thu c 17,6g CO 2,12,6 g H2O v 69,44 lt kh N2 (KTC).Gi thit khng kh ch gm (%VN2 =80 v %VO2=20).Gi tr m v s ng phn cu to ca amin X ln lt l: A. 9 v 6 B. 6 v 9 C. 9 v 2 D. 8 v 1 Cu 32: Ho tan hon ton mt lng kim loi ho tr II bng dung dch HCl 14,6% va c mt dung dch mui c nng 24,15%.Kim loi cho l: A. Fe B. Ba C. Zn D. Mg
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Ti liu n thi i hc nm 2012 -2013 Cu 33: Kh hon ton 4,06 gam mt oxit kim loi bng CO nhit cao thnh kim loi. Dn ton b kh sinh ra vo bnh ng dung dch Ca(OH)2 d thy to thnh 7 gam kt ta.Nu ly kim loi sinh ra ha tan ht vo dung dch HCl d th thu c 1,176 lt hiro.Vy lng mui kim loi thu c khi cho 34,8 gam oxit trn tc dng hon ton vi dung dch HCl d l A. 43,425 gam B. 70,6875 gam C. 67,80 gam D. 61,38 gam Cu 34: Hn hp X gm axit Y n chc v axit Z hai chc(Y,Z c cng s nguyn t cacbon).Chia X thnh 2 phn bng nhau. -Phn 1: tc dng vi Na d sinh ra 4,48 lt kh H2(kc) -Phn 2: t chy hon ton to 26,4 gam CO2 CTCT thu gn v % khi lng ca Z trong hn hp X l: A. HOOC-CH2-COOH :70,87% B. HOOC-CH2-COOH:54,88% C. HOOC-COOH :60,00% D. HOOC-COOH : 42,86% Cu 35: Nguyn t nguyn t R c tng s cc loi ht l 115. S ht mang in nhiu hn s ht khng mang in l 25. S khi ca R l: A. 70. B. 90. C. 80. D. 75. Cu 36: C th dng H2SO4 c lm kh tt c cc kh trong dy no sau y? A. CO2, N2, SO2, O2. B. CO2, N2, H2, O2. C. CO2, H2S, N2, O2. D. CO2, NH3, H2 , N2. Cu 37: iu khng nh no sau y lun ng: A. C mt kim loi duy nht nhit thng trng thi lng . B. Bn knh nguyn t kim loi lun ln hn bn knh nguyn t phi kim. C. Nguyn t kim loi no cng u c 1;2 hoc 3 electron lp ngoi cng . D. Cc kim loi u phn nhm chnh ca bng h thng tun hon.
(CH2)2COOH CH3 CH COOH H2N CH2 C N CH C N O H O H Cu 38: Thy phn peptit :

Sn phm no di y l khng th c A. Ala B. Ala-Glu C. Gly-Ala D. Glu-Gly Cu 39: Cho cc mnh : 1) cc nguyn t kim loi c th tham gia phn ng oxi ho - kh cng nh phn ng trao i. 2) cc kim loi khi tham gia phn ng ho hc lun ng vai tr l cht kh. 3) phn ng th(trong ho v c) lun l phn ng oxi ho - kh. 4) phn ng ho hp c th l phn ng oxi ho - kh hoc khng. 5) trong phn ng oxi ho - kh khng th c qu mt nguyn t th hin tnh oxi ho v mt nguyn t th hin tnh kh. Trong cc mnh trn th A. tt c ng. B. 1 v 5 sai. C. ch c 1 sai. D. ch c 5 sai. Cu 40: Cho glucoz ln men thnh ru (ancol) etylic. Dn kh CO 2 to thnh qua dung dch nc vi trong d, thu c 50 gam kt ta. Bit hiu sut ca qu trnh ln men l 80%. Khi lng glucoz cn dng ban u l A. 56,25 gam. B. 112,5 gam. C. 45,00 gam. D. 36,00 gam. Cu 41: Cho 14,948 gam hn hp KMnO4 v MnO2 (trong MnO2 chim 6,98% v khi lng) tc dng vi 150 ml HCl 36,8% (d = 1,19 g/ml). Lng kh clo thu c ( ktc) l: A. 2,016 lt B. 5,1968 lt C. 0,012 lt D. 4,928 lt Cu 42: Cho cc hp cht sau: 1) Glixerin 2) Glucoz 3) Fructoz 4) Saccaroz 5) Tinh bt 6) Xenluloz Nhng hp cht tc dng vi Cu(OH)2 cho dung dch mu xanh lam l: A. 1, 2, 3, 4, B. 1, 2, 5 C. 1, 2, 3, 4 D. 1, 2, 4, 6 Cu 43: Hn hp A gm hai cht k tip nhau trong dy ng ng ca axit fomic. t chy ht m gam hn hp A ri cho sn phm chy hp th ht vo lng d dung dch Ca(OH) 2 th thu c 23g kt ta. Cn khi cho m gam hn hp A tc dng ht vi NaHCO3 th thu c 2,016 lt CO2 (ktc). Khi lng mi axit trong hn hp A l
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Ti liu n thi i hc nm 2012 -2013 A. 2,96 gam; 3 gam B. 1,84 gam; 3 gam C. 2,3 gam; 2,96 gam D. 2,4 gam; 3,7 gam 0 Cu 44: un nng mt hn hp 2 ancol no n chc vi H2SO4 c 140 C thu c 21,6 gam nc v 72 gam hn hp 3 ete.Bit 3 ete thu c c s mol bng nhau v phn ng xy ra hon ton.CTPT ca 2 ru l: A. C3H7OH ; CH3OH B. C3H7OH ; C4H9OH C. CH3OH ; C2H5OH D. C2H5OH ; C3H7OH Cu 45: Nu hm lng mt kim loi trong mui cacbonat l 40% th hm lng kim loi ny trong mui photphat l: A. 45,00% B. 38,71% C. 60,00% D. 29,50% Cu 46: Cng thc ca amin cha 15,05% khi lng nit l: A. C6H8N2 B. C6H7N C. C2H8N2 D. C2H7N Cu 47: Cng thc chung ca axit cacboxylic no, x chc, mch h l? A. CnH2n+2Ox. B. CnH2nO2x. C. CnH2nO2. D. CnH2n+2-2xO2x. Cu 48: Nhng kim loi no sau y c th c iu ch t oxit, bng phng php nhit luyn nh cht kh CO A. Ba,Cu,Ca B. Fe,Cu,Ni C. Pb,Mg,Fe D. Fe,Ag,Al Cu 49: Cho 4,2g anehit A mch h phn ng vi lng d dung dch AgNO 3 trong NH3, ton b lng Ag thu c ha tan ht trong dung dch HNO 3 c nng d nhn c 3,792 lt NO 2 270C v 740mmHg. Cng thc cu to ca A l: A. CH3CH2CHO B. CH2=CHCH2CHO C. HOC-CH=CH-CHO D. CH2=CHCHO + Cu 50: Trong dung dch CH3COOH c cn bng:CH3COOH CH 3COO + H . in li ca CH3COOH s nh th no khi nh vi git dung dch NaOH vo? A. khng bin i B. tng C. gim D. khng xc nh c

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