1

CHUYN 6

OXI LU HUNH

PHN I: L THUYT
1. OXI
TAC DUNG HAU HET MOI KIM LOAI (tr Au va Pt), can co t
0
tao oxit
2Mg + O
2

o
t
2MgO Magie oxit
3Fe + 2O
2

o
t
Fe
3
O
4
Oxit sat t (FeO, Fe
2
O
3
)
TAC DUNG TRC TIEP CAC PHI KIM (tr halogen), can co t
0
tao ra oxit
S + O
2

o
t
SO
2

C + O
2

o
t
CO
2

TAC DUNG H
2
(no theo t le 2 :1 ve so mol), t
0
2H
2
+ O
2

o
t
2H
2
O
TAC DUNG VI CAC HP CHAT CO TNH KH
2SO
2
+ O
2
V
2
O
5
, 450
0
C

2SO
3

CH
4
+ 2O
2

o
t
CO
2
+ 2H
2
O
2. OZON la dang thu hnh cua oxi va co tnh oxhoa manh hn O
2
rat nhieu
O
3
+ 2KI + H
2
O I
2
+ 2KOH + O
2
(oxi khong co)
Do tao ra KOH nen O
3
la m xanh qu tam dd KI (dung trong nhan biet ozon)
2Ag + O
3
Ag
2
O + O
2
(oxi khong co phan ng)
3. LU HUYNH

TAC DUNG VI NHIEU KIM LOAI
Fe + S
0

o
t
FeS
-2
sat II sunfua
Hg + S HgS
-2
thuy ngan sunfua, phan ng xay ra t
0
thng
TAC DUNG HIDRO
H
2
+ S
o
t
H
2
S
-2
hidrosunfua

TAC DUNG PHI KIM (tr Nit va Iod)
S + O
2

o
t
SO
2

4. HIDROSUNFUA (H
2
S)
TAC DUNG OXI cothe tao S hoac SO
2
tuy lng oxi va cach tien hanh phan ng.
2H
2
S + 3O
2
0
t
2H
2
O + 2SO
2
(d oxi, ot chay)
2H
2
S + O
2
thap t t
0
2H
2
O + 2S+ (Dung dch H
2
S trong khong kh hoac lam lanh ngon la H
2
S ang chay)
TAC DUNG VI CLO co the tao S hay H
2
SO
4
tuy ieu kien pha n ng
H
2
S + 4Cl
2
+ 4H
2
O 8HCl + H
2
SO
4
H
2
S + Cl
2
2 HCl + S
DUNG DCH H
2
S CO TNH AXIT YEU : Khi tac dung dung dch kiem co the tao muoi axit hoac muoi
trung hoa
H
2
S + NaOH
1 : 1
NaHS + H
2
O
H
2
S + 2NaOH
2 :: 1
Na
2
S + 2H
2
O
5. LU HUYNH (IV) OXIT
SO
2
LA CHAT KH (
4 +
S - 2e
6 +
S ) Khi gap chat oxi hoa manh nh O
2
, Cl
2
, Br
2
: kh SO
2
ong vai tro la
chat kh.
2
4 +
S O
2
+ O
2
V
2
O
5
450
0
2SO
3
O S
4 +
2
+ Cl
2
+ 2H
2
O 2HCl + H
2 O S
6 +
4
2
SO
2
LA CHAT OXI HOA (
4 +
S + 4e
0
S ) Khi tac dung chat kh manh
O S
4 +
2
+ 2H
2
S 2H
2
O + 3
0
S
O S
4 +
2
+ Mg MgO + S
Ngoai ra SO
2
la mot oxit axit
SO
2
+ NaOH
1 : 1
NaHSO
3
(
2
nSO
nNaOH
> 2 )
SO
2
+ 2 NaOH
2 : 1
Na
2
SO
3
+ H
2
O (
2
nSO
nNaOH
s 1)
Neu 1<
2
nSO
nNaOH
< 2 th tao ra ca hai muoi

mol y SO Na
mol x NaHSO
:
:
3 2
3

6. LU HUYNH (VI) OXIT
TAC DUNG VI H
2
O tao axit sunfuric
SO
3
+ H
2
O H
2
SO
4
+ Q
SO
3
tan vo han trong H
2
SO
4
tao oleum : H
2
SO
4
.nSO
3
TAC DUNG BAZ tao muoi
SO
3
+ 2 NaOH Na
2
SO
4
+ H
2
O
7. AXT SUNFURIC H
2
SO
4
trang thai loang la mot axit manh, trang thai ac la mot chat oxihoa
manh.
dang loang la axt manh lam o qu tm, tac dung kim loai(trc H) giai pho ng H
2,
tac

dung baz, oxit
baz va nhieu muoi.
dang ac la mot chat oxihoa manh
TAC DUNG KIM)
2Fe + 6 H
2
SO
4



0
t

Fe
2
(SO
4
)
3
+ 3SO
2
+ 6H
2
O
Cu + 2 H
2
SO
4
0
t

CuSO
4
+ SO
2+
2H
2
O
Al, Fe, Cr khong tac dung vi H
2
SO
4
ac nguoi, v kim loai b thu ong hoa.
TAC DUNG VI CAC PHI KIM
2H
2
SO
4()
+ C

0
t

CO
2
+ 2SO
2
+ 2H
2
O
2H
2
SO
4()
+ S

0
t

3SO
2
+ 2H
2
O
TAC DUNG MOT SO HP CHAT CO TNH KH

FeO + H
2
SO
4

()
0
t
Fe
2
(SO
4
)
3
+ SO
2
+ 4H
2
O
2HBr + H
2
SO
4 ()


0
t
Br
2
+ SO
2
+ 2H
2
O


PHN II: BI TP
DNG 1: CHUI PHN NG
Phng php: Da vo tnh cht ha hc vit cc PTP:
BI TP P DNG
Cu 1: Hon thnh cc phng trnh phn ng sau:
a. SSO
2
SH
2
S H
2
SO
4
SO
2
Na
2
SO
3
SO
2
SO
3
H
2
SO
4
FeSO
4
Fe(OH)
2
FeSO
4

b. H
2
SO
4
SO
2
H
2
SO
4
Fe
2
(SO
4
)
3
Fe(OH)
3
Fe
2
(SO
4
)
3
K
2
SO
4
BaSO
4
.
Cu 2 : Vit cc phng trnh phn ng thc hin cc bin ha sau :
FeS SO
2
SO
3
H
2
SO
4
CuSO
4
BaSO
4


S H
2
S SO
2

Cu 3: Hon thnh chui phn ng sau :
S H
2
S SO
2
KHSO
3
K
2
SO
3
SO
2
CaSO
3

Cu 4: Hon thnh cc phng trnh phn ng theo s :
3
Hidrosunfua lu hunh kh sunfuraxir sunfuric lu hunh ioxit canxi sunfit kh
sunfurlu hunh hidrosunfua axit sunfuric.
DNG 2: NHN BIT
Phng php: MUOI SUNFUA VA NHAN BIET GOC SUNFUA (S
2-
) hau nh cac muoi sunfua ie u
khong tan, ch co muoi cua kim loai kiem va kie m tho tan (Na
2
S, K
2
S, CaS, BaS). Mot so muoi khong tan
va co mau ac trng CuS en, PbS en, CdS vang, SnS o gach, MnS hong.
e nhan biet S
2-
dung dung dch Pb(NO
3
)
2

MUOI SUNFAT VA NHAN BIET GOC SUNFAT (SO
4
2-
)
Phan ln muoi sunfat tan, ch co BaSO
4
, PbSO
4
khong tan co mau trang, CaSO
4
t tan co mau trang.
Nhan biet goc sunfat du ng dung dch cha SO
4
2-
BI TP P DNG
Cu 1: Nhn bit cc dung dch mt nhn:
a. H
2
SO
4
, HCl, NaOH, Na
2
SO
4
, HNO
3
. b. K
2
SO
3
, K
2
SO
4
, K
2
S, KNO
3
.
Cu 2: Ch dng mt thuc th hy nhn bit cc dung dch: Na
2
S, Na
2
SO
3
, BaCl
2
, NaCl.
Cu 3: Ch dng mt thuc th hy nhn bit cc dung dch: H
2
SO
4
, BaCl
2
, NaCl, Na
2
SO
3
, Na
2
S.
Cu 4: Trnh by phng php phn bit 4 cht rn : NaCl, Na
2
CO
3
, BaSO
4
, BaCO
3
vi iu kin ch dng thm
dung dch HCl long.
DNG 3: BT VIT PTP V IU CH CHT
Phng php: Da vo tnh cht ha hc
BI TP P DNG
Cu 1: Vit 2 phng trnh chng minh:
a. SO
2
ng vai tr l cht oxi ha. SO
2
ng vai tr l cht kh.
b. H
2
S l cht kh. H
2
SO
4
c l cht oxi ha.
c. S l cht kh. S l cht oxi ha.
d. Ozon c tnh oxi ha mnh hn oxi.
Cu 2: T FeS
2
, NaCl, O
2
v H
2
O. Vit cc pt phn ng iu ch: Fe
2
(SO
4
)
3
, Na
2
SO
4
, nc iaven, Na
2
SO
3
,
Fe(OH)
3
.
Cu 3: T KCl, Cu, Fe, S v H
2
O. Vit cc phng trnh iu ch FeCl
2
, CuCl
2
, H
2
S, CuSO
4
, FeSO
4
, Fe
2
(SO
4
)
3
.
DNG 4: XC NH CHT
Phng php: Nm mt s cng thc tnh s mol:
n = m/M n = C
M
. V
n
Kh
= v/ 22,4
- Tnh t l theo PTP
BI TP P DNG
Cu 1: Cho 3,36 lt O
2
(ktc) phn ng hon ton vi mt kim loi ha tr (III) thu c 10,2g oxit. Xc nh tn
kim loi.
Cu 2: t chy hon ton 0,84g mt kim loi ha tr (II) ht vi 0,168 lt kh O
2
(ktc). Xc nh tn kim loi.
Cu 3: t chy hon ton 2,88g mt kim loi ht vi oxi thu c 4,8g oxit. Xc nh tn kim loi.
Cu 4: Cho 2,8g mt kim loi ha tr (III) tc dng ht vi dung dch axit sunfuric c nng thu c 1,68 lt kh
SO
2
ktc. Xc nh tn kim loi.
Cu 5: Cho 12,15g mt kim loi tc dng ht vi 1000ml dung dch axit sunfuric 1,35M. Xc nh tn kim loi.
Cu 6: Ha tan hon ton 1,44g kim loi ha tr (II) bng 250ml dung dch H
2
SO
4
0,3M. Sau phn ng phi
dng ht 60ml dung dch NaOH 0,5M trung ha lng axit cn d. Xc nh tn kim loi.
Cu 7: 6,3 gam mt kim loi X c ha tr khng i tc dng hon ton vi 0,15 mol O
2
. Cht rn thu c sau
phn ng em ha tan vo dung dch HCl ( d) thy thot ra 1,12 lt kh H
2
ktc. Xc nh kim loi X.
Cu 8: Cho 1,2 gam kim loi X ha tr II vo 150ml dung dch H
2
SO
4
long 0,3M, X tan ht, sau ta cn
thm 60ml dung dch KOH 0,5M trung ha axit d. Xc nh kim loi X.
DNG 5: BT CHT D, CHT P HT
Phng php: p dng cc cng thc tng t DNG 3
- So snh s mol cc cht tham gia P, cht cn d l sn phm sau P.
4
BI TP P DNG
Cu 1: Nung hn hp gm 3,2g S v 4,2g Fe trong bnh kn n phn ng hon ton. Tnh khi lng cc cht
sau p.ng ?
Cu 2: Nung hn hp gm 3,2g S v 1,3g Zn trong bnh kn n phn ng hon ton. Tnh khi lng cc cht
sau png ?
Cu 4: Nung 5,6 g bt st v 13g km vi mt lng d lu hunh. Sn phm cu phn ng cho tan hon ton
trong dung dch axit clohidric. Kh sinh ra dn vo dung dch Pb(NO
3
)
2
.
a. Vit cc phng trnh phn ng xy ra?
b. Tnh th tch dung dch Pb(NO
3
)
2
(D = 1,1g/ml) cn hp th hon ton lng kh sinh ra.
Cu 5: Cho 8,96 lt kh (ktc) H
2
S vo mt bnh ng 85,2g Cl
2
ri vo bnh ng mt lt nc phn ng xy
ra hon ton.
a. Trong bnh cn kh g? Bao nhiu mol?
b. Tnh khi lng H
2
SO
4
sinh ra.
DNG 6: XC NH MUI TO THNH T P H
2
S v SO
2
VI BAZ TAN
Phng php: So snh t l s mol
- Nu
2
nSO
nNaOH
> 2 thi SO
2
+ NaOH
1 : 1
NaHSO
3

- Nu
2
nSO
nNaOH
s 1 thi SO
2
+ 2 NaOH
2 : 1
Na
2
SO
3
+ H
2
O
- Ne u 1<
2
nSO
nNaOH
< 2 th tao ra ca hai muoi

mol y SO Na
mol x NaHSO
:
:
3 2
3

- H
2
S + KOH tng t SO
2
+ NaOH
BI TP P DNG
Cu 1. Dn ton b 2,24 lt kh H
2
S vo 100 ml dung dch KOH 1,6M. Tnh khi lng mui sau phn ng ?
Cu 2: Cho 150 g dung dch H
2
S 3,4% tc dng vi 250 ml dd NaOH 1M. Tnh khi lng mui to thnh sau
phn ng.
Cu 3: Dn 4,48 lt kh SO
2
(ktc) vo 300 ml dung dch NaOH 1M. Tnh khi lng mui to thnh sau phn
ng?
Cu 4: Dn kh sunfur c khi lng 6,4g vo 250g dung dch KOH 12%. Tnh khi lng mui to thnh sau
phn ng?
Cu 6. Hp th hon ton 2,24 lt kh SO
2
( ktc ) vo 100 ml dung dch Ca(OH)
2
0,8M thu c m gam kt ta.
Tnh m ?
Cu 7. Hp th hon ton 3,36 lt kh SO
2
( ktc ) vo 125 ml dung dch Ba(OH)
2
1M thu c m gam kt ta.
Tnh m ?
Cu 8. Hp th hon ton V lt kh SO
2
( ktc ) vo 200 ml dung dch Ca(OH)
2
1M thu c 12 gam kt ta.
Tnh V ?
Cu 9. Hp th hon ton V lt kh SO
2
( ktc ) vo 300 ml dung dch Ba(OH)
2
0,8M thu c 21,7 gam kt ta.
Tnh V ?

DNG 7: TON V H
2
SO
4

Phng php: Tnh theo PTP
- CNG THC TNH NHANH GII BI TP TRC NGHIM H
2
SO
4
Cng thc 1 :
o Tnh khi lng mui sunfat thu c khi ha tan ht 1 hoc hn hp kim loi (trc hiro)
bng H
2
SO
4
(long) to H
2
:
m

= m
hh
+ 96.n
2
H

Cng thc 2 :
o Tm kim loi khi cho m (gam) kim loi(trc hiro) tc dng H
2
SO
4
(long) gii phng H
2
:

5
o M =
2
. 2
.
H
n
a m

(a= s oxi ha thp ca kim loi = s e kim loi nhng = ha tr thp ca kim loi )
Cng thc 3:
o c im ca phn ng :
- Kim loi (tr Au ,Pt) + H
2
SO
4
c (nng) Mui sunfat + Sn phm kh + H
2
O
(Al , Fe khng phn ng vi H
2
SO
4
c ngui )

0
M
n
M
+
+ ne ( n = 1,2,3 )

Cng thc 4:
o Khi lng mui sunfat (m) thu c khi cho 1 hoc hn hp cc kim loai tc dng H
2
SO
4

(c,nng) to mt hoc hn hp cc sn phm kh :
m

= m
hhkl
+ 96.n
2
SO
; m

= m
hhkl
+ 96.3.n
S
; m

= m
hhkl
+ 96.4.n
S H
2

Cng thc 5 :
o Tm kim loi khi cho m (gam) kim loi tc dng H
2
SO
4
(c,nng) to mt hoc hn hp cc
sn phm kh :

M =
2
. 2
.
SO
n
a m
; M =
S
n
a m
. 6
.
; M =
S H
n
a m
2
. 8
.

Cng thc 6 :
o Tnh khi lng m (gam) mui sunfat thu c khi ha tan ht m(gam) 1 hoc hn hp oxit
kim loi bng H
2
SO
4
(long) :
m

= m
oxit
+ 80.
4 2
SO H
n
Cng thc 7 :
o Khi lng m (gam)mui thu c khi ha tan ht m
hh
(gam) Fe ,FeO , Fe
2
O
3
,Fe
3
O
4
(khng
nht thit phi 4 cht v phi c oxit st) bng H
2
SO
4
(c,nng) to mt hoc hn hp
cc sn phm kh :
m = ) . 16 (
160
400
2
SO hh
n m + ; m = ) . 64 (
160
400
2
S H hh
n m + ;
m = ) . 48 (
160
400
S hh
n m +
o Khi nung m(gam) Fe ngoi khng kh , cho m
hh
(gam) hn hp cc cht thu c vo H
2
SO
4

(c,nng) to mt hoc hn hp cc sn phm kh :
m = ) . 16 (
80
56
2
SO hh
n m + ; m = ) . 64 (
80
56
2
S H hh
n m + ;
m = ) . 48 (
80
56
S hh
n m +

BI TP P DNG
Cu 1-Ha tan ht 11,1 gam hn hp 3 kim loi trong dung dch H
2
SO
4
long d thu c dung dch A v 8,96
lt kh (ktc) .C cn dung dch A thu c m gam mui khan . m c gi tr l :
A . 59,1 gam B. 35,1 gam C. 49,5 gam D. 30,3 gam
Cu 2-Ha tan ht 20,608 gam mt kim loi M bng dung dch H
2
SO
4
long d thu c dung dch A v V lt
kh (ktc) . C cn dung dch A thu c 70,0672 gam mui khan . M l :
A . Na B. Mg C. Fe D. Ca
Cu 3-Cho 13,33 gam hn hp Al,Cu,Mg tc dng vi dung dch H
2
SO
4
long d thu c dung dch A , 7,728
lt kh (ktc) v 6,4 gam cht rn khng tan . C cn dung dch A thu c bao nhiu gam mui khan ?
A . 40,05 gam B. 42,25 gam C. 25,35 gam D. 46,65 gam
Cu 4-Ha tan ht hn hp X gm 0,12 mol Fe v 0,24 mol kim loi M trong dung dch H
2
SO
4
long d thu
c dung dch A v 10,752 lt kh (ktc) C cn dung dch A thu c 59,28 gam mui khan . Ml :
A . Na B. Mg C. Ca D. Al
Cu 5-Cho 15,82 gam hn hp Al,Fe,Cu tc dng ht vi dung dch H
2
SO
4
c nng thu c dung dch A v
9,632 lt SO
2
(ktc) . C cn dung dch A s thu c s gam mui khan l :
A. 57,1 B. 60,3 C.58,81 D.54,81
6
Cu 6-Cho 13,248 gam mt kim loi M tc dng vi dung dch H
2
SO
4
c nng d thu c V lt kh H
2
S
(ktc) v dung dch A .C cn dung dch A . C cn dung dch A thu c 66,24 gam mui khan . V c gi tr
l :
A . 2,4640 lt B. 4,2112 lt C. 4,7488 lt D. 3,0912 lt
Cu 7-Ha tan ht m gam hn hp 3 kim loi bng H
2
SO
4
c nng d thu c 11,782 lt SO
2
(ktc) v dung
dch A . C cn dung dch A thu c 71,06 gam mui khan . m c gi tr l :
A. 20,57 B. 60,35 C.58,81 D.54,81
Cu 8-Ha tan hn hp A gm 16,8 gam Fe ; 2,7 gam Al v 5,4 gam Ag tc dng vi H
2
SO
4
c nng ch thot
ra kh SO
2
. S mol H
2
SO
4
tham gia phn ng l :
A. 1,25 mol B. 1,20 mol C.1,45 mol D.1,85 mol
Cu 9-Cho 7,40 gam hn hp kim loi Ag , Al , Mg tan ht trong dung dch H
2
SO
4
c nng d thu c hn
hp sn phm kh gm 0,015 mol S v 0,0125 mol H
2
S v dung dch A . C cn dung dch A thu c bao
nhiu gam mui khan ?
A . 12,65 gam B. 15,62 gam C. 16,52 gam D. 15,26 gam
Cu 10-Ha tan hon ton 49,6 gam hn hp X gm Fe , FeO , Fe
2
O
3
v Fe
3
O
4
dung dch H
2
SO
4
c nng thu
c dung dch Y v 8,96 lt kh SO
2
(ktc) . C cn dung dch Y thu c m gam mui khan . m c gi tr l :
A . 145 gam B. 140 gam C. 150 gam D. 155 gam
Cu 11-Ha tan 6,76 gam hn hp ba oxit Fe
3
O
4
, Al
2
O
3
, v CuO bng 100ml dung dch H
2
SO
4
1,3 M va ,
thu c dung dch Y c ha tan cc mui . C cn dung dch Y thu c m gam hn hp cc mui khan . m c
gi tr l :
A . 15,47 gam B. 16,35 gam C. 17,16 gam D. 19,5 gam
Cu 12-Cho m gam hn hp A gm 3 oxit kim loi MgO , ZnO , Fe
2
O
3
ha tan va trong 300 ml dung dch
H
2
SO
4
0,1 M , thu c dung dch Y . C cn dung dch Y thu c 5,21 gam hn hp cc mui sunfat khan .
Ga tr ca m l :
A . 2,85 gam B.2,30 gam C. 2,35 gam D. 2,81 gam
Cu 13-Cho 2,81 gam hn hp gm 3 oxit MgO , ZnO , Fe
2
O
3
ha tan va trong 300 ml dung dch H
2
SO
4

long , thu c dung dch Y . C cn dung dch Y thu c 5,21 gam hn hp cc mui sunfat khan . Nng
mol/l ca dung dch H
2
SO
4
:
A . 0,5 M B. 0,1 M C. 0,3 M D. 0,4 M
Cu 14-Cho hn hp X gm 5,4 gam Al , 4,8 gam Mg v 13 gam Zn tc dng vi dung dch H
2
SO
4
c , nng
d thu c 0,175 mol mt sn phm kh duy nht l X . X l :
A . SO
2
B. S C. H
2
S D. H
2

Cu 15-Cho 9 gam hn hp Al v Mg c t l s mol Al: Mg = 4:3 tc dng vi tc dng vi H
2
SO
4
c nng
va (cha 0,5625 mol H
2
SO
4
) thu c 1 sn phm kh duy nht X . X l :
A . SO
2
B. S C. H
2
S D. H
2

Cu 16-Ha tan ht 1,360 gam hn hp 2 kim loi X,Y trong dung dch H
2
SO
4
long , thu c 0,672 lt kh
(ktc) v m gam mui . Ga tr ca m l :
A. 2,44 gam B. 4,42 gam C. 24.4 gam D. 4,24 gam
Cu 17-Ha tan hon ton 19,2 gam kim loi M trong dung dch H
2
SO
4
c nng d thu c kh mi xc .
Cho kh ny hp th hon ton trong 1 lt dung dch NaOH 0,6 M , sau phn ng em c cn dung dch thu
c 37,8 gam cht rn , kim loi M l :
A. Cu B. Ca C. Fe D. Mg
Cu 18-Oxi ha hon ton 14,30 gam hn hp bt cc kim loi Mg , Al , Zn bng oxi d thu c 22,3 gam
hn hp oxit . Cho lng oxit ny tc dng ht vi dung dch HCl th lng mui to ra l :
A. 48,.90 gam B. 36,60 gam C. 32,050 gam D. 49,80 gam
Cu 19-Cho 5,6 gam Fe tc dng vi dung dch H
2
SO
4
c nng thu c 0,84 lt kh (ktc) gm mt sn phm
kh duy nht . Sn phm kh duy nht l :
A . SO
2
B. S C. H
2
S D. H
2

Cu 20-Nung m gam bt st ngoi khng kh sau mt thi gian thu c hn hp X gm 4 cht c khi lng
75,2 gam . Cho X tc dng vi H
2
SO
4
c nng , d thu c 6,72 lt kh SO
2
duy nht (ktc) . Ga tr m l :
A. 56 gam B. 5,6 gam C. 52 gam D. 11,2 gam
Cu 21-Ha tan hon ton 2,81 gam hn hp Fe
2
O
3
, MgO , ZnO trong 500 ml dung dch H
2
SO
4
0,1 M (va
) . Sau phn ng , khi lng hn hp mui khan khi c cn l :
A. 3,81 gam B. 4,81 gam C. 5,81 gam D. 6,81 gam
Cu 22-Cho 55,2 gam hn hp X gm 2 oxit kim loi FeO v Al
2
O
3
tan va trong 700ml dung dch H
2
SO
4

2M . C cn dung dch sau phn ng thu c m gam mui khan . Ga tr ca m l :
A. 98,8 gam B. 167,2 gam C. 136,8 gam D. 219,2 gam
Cu 23-Cho 2,54 gam hn hp Y gm 3 oxit FeO , MgO , Al
2
O
3
tan va trong 300 ml dung dch H
2
SO
4

0,2M . C cn dung dch sau phn ng thu c m gam mui khan . Ga tr ca m l :
A. 7,34 gam B. 5,82 gam C. 4,94 gam D. 6,34 gam
7
Cu 24-Cho 38,3 gam hn hp 4 oxit kim loi Fe
2
O
3
, MgO , ZnO v Al
2
O
3
tan va trong 800 ml dung dch
H
2
SO
4
1M . C cn dung dch th thu c a gam mui khan . Ga tr ca a l :
A. 68,1 gam B. 86,2 gam C. 102,3 gam D. 93,3 gam
Cu 25-Ha tan ht 4,20 gam hn hp 3 kim loi X,Y,Z bng dung dch H
2
SO
4
c , nng thu c 0,025 mol
S (sn phm kh duy nht ) . C cn dung dch thu c sau phn ng thu c m gam mui khan . Ga tr ca
m l :
A. 14,10 gam B. 11,40 gam C. 6,60 gam D. 1,410 gam
Cu 26-Ha tan hon ton 11,90 gam hn hp 3 kim loi X,Y,Z bng dung dch H
2
SO
4
c , nng thu c
7,616 lt kh SO
2
(ktc) , 0,640 gam S v dung dch X .C cn dung dch X thu c m gam mui khan . Ga
tr ca m l :
A. 50,30 gam B. 30,50 gam C. 35,00 gam D. 30,05 gam
Cu 27-Cho 1,26 gam hn hp Mg v Al c t l mol tng ng l 3:2 tc dng vi H
2
SO
4
c ,nng va
thu c 0,015 mol mt sn phm kh c cha lu hunh . Sn phm kh l :
A . SO
2
B. S C. H
2
S D. H
2
Cu 28-Ha tan hon ton a gam Fe
x
O
y
bng dung dch H
2
SO
4
bng dung dch H
2
SO
4
m c nng va ,
c cha 0,075 mol H
2
SO
4
thu c b gam mt mui c 168 ml kh SO
2
(ktc) duy nht thot ra . Cng thc
ca Fe
x
O
y
v gi tr ca a , b l :
A . Fe
3
O
4
; 3,48 ; 9 B. Fe
2
O
3
; 2,45 ; 7 C. FeO ; 3,45 ; 5 D. Fe
2
O
3
; 2,48 ; 5
Cu 29-Khi ha tan mt oxit kim loi ha tr II bng mt lng va dung dch H
2
SO
4
9,8% th thu c
dung dch mui c nng 14,8% . Cng thc phn t ca oxit kim loi l :
A . CaO B. CuO C. MgO D. BaO
Cu 30-Ha tan 9,6 gam mt kim loi M trong dung dch H
2
SO
4
c nng d thu c 3,36 lt kh SO
2
(ktc)
v thu c dung dch A . C cn dung dch A thu c mui sunfat khan . Kim loi M v khi lng mui
sunfat khan l :
A . Mg ; 21gam B. Fe ; 23 gam C. Cu ; 24 gam D. Zn ; 27 gam
Cu 31-Cho 29 gam hn hp Mg,Zn,Fe tc dng ht vi dung dch H
2
SO
4
long thy thot ra V lt kh (ktc) .
C cn dung dch sau phn ng thu c 86,6 gam mui khan . Ga tr ca V l :
A . 6,72 lt B. 13,44 lt C. 22,4 lt D. 4,48 lt
Cu 32-Ha tan m gam hn hp X gm FeO , Fe
2
O
3
, Fe
3
O
4
bng H
2
SO
4
c nng , d thu c 11,2 lt kh
SO
2
duy nht (ktc) v dung dch X . C cn dung dch X thu c 95 gam mui khan . . Ga tr ca m l :
A. 20 gam B. 30 gam C. 40 gam D. 50 gam
Cu 33-Ha tan hon ton 20,88 gam mt oxit st bng dung dch H
2
SO
4
c nng , d thu c V lt kh SO
2

(ktc) v dung dch X . C cn
dung dch X thu c 58 gam mui khan . Ga tr ca V l :
A . 3,248 lt B. 13,45 lt C. 22,40 lt D. 4,48 lt
Cu 34-Ha tan 30 gam hn hp X gm FeO , Fe
2
O
3
, Fe
3
O
4
bng H
2
SO
4
c nng , d thu c 11,2 lt kh
SO
2
duy nht (ktc) v dung dch X . C cn dung dch X thu c m gam mui khan . . Ga tr ca m l :
A . 56 gam B. 95 gam C. 52 gam D. 112 gam
Cu 35-Ha tan hon ton 11,9 gam Al , Zn vo dung dch H
2
SO
4
c nng , thu c dung dch X ; 7,616 lt
kh SO
2
(ktc) v 0,64 gam S . Tng khi lng mui trong X l :
A. 50,3 gam B. 49,8 gam C. 47,15 gam D. 45,26 gam