HA HC HU C 12 THI I HC, CAO NG T NM 2007 N 2012 ESTER - LIPIT Cu 1.

. (H B-2009) Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO 3 trong NH3. Th tch ca 3,7g hi cht X bng th tch ca 1,6 g kh oxi (cng iu kin v nhit v p sut). Khi t chy hon ton 1 g X th th tch CO2 thu c vt qu 0,7 lt (ktc). CTCT ca X l: A. O=CH-CH2-CH2OH. B. HOOC-CHO. C. HCOOC2H5. D. CH3COOCH3. Cu 2. (HB-2012) Thy phn este X mch h c cng thc phn t C4H6O2, sn phm thu c c kh nng trng bc. S este X tha mn tnh cht trn l A. 5 B. 6 C. 3 D. 4 Cu 3. (H B-2009) Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. CTCT ca X v Y tng ng l: A. HO-CH(CH3)-CHO v HOOC-CH2-CHO. B. HO-CH2-CHO v HO-CH2-CH2-CHO. C. HCOOCH3 v HCOOCH2-CH3 D. HO-CH2-CH2-CHO v HO-CH2-CH2-CH2-CHO. Cu 4. (HA-2010) Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%, thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l A. C2H5COOH v C3H7COOH. B. HCOOH v C2H5COOH. C. HCOOH v CH3COOH. D. CH3COOH v C2H5COOH. Cu 5. (H B-2009) Cho hn hp X gm 2 cht hu c no n chc tc dng va u vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH) 2 (d) th thy khi lng bnh tng 6,82 g. Cng thc ca hai hp cht hu c trong X l A. CH3COOH v CH3COOC2H5. B. HCOOH v HCOOC2H5. C. C2H5COOH v C2H5COOCH3. D. HCOOH v HCOOC3H7. Cu 6. (C-2011) x phng ho hon ton 52,8 gam hn hp hai este no, n chc , mch h l ng phn ca nhau cn va 600 ml dung dch KOH 1M. Bit c hai este ny u khng tham gia phn ng trng bc. Cng thc ca hai este l A. C2H5COOCH3 v CH3COOC2H5 B. HCOOC4H9 v CH3COOC3H7 C. C2H5COOC2H5 v C3H7COOCH3 D. CH3COOC2H5 v HCOOC3H7 Cu 7. (H A-2008) Cho s chuyn ha sau: t0 C3H4O2 + NaOH X+Y t0 X + H2SO4 long Z+T Bit Y v Z u c phn ng trng gng. Hai cht Y, Z tng ng l: A. HCHO, CH3CHO. B. CH3CHO, HCOOH. C. HCOONa, CH3CHO. D. HCHO, HCOOH. Cu 8. (C A-2009) Hai hp cht hu c X, Y c cng CTPT C3H6O2. C X v Y u tc dng c vi Na; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. CTCT ca X v Y ln lt l A. C2H5COOH v CH3CH(OH)CHO. B. HCOOC2H5 v HOCH2CH2CHO. C. HCOOC2H5 v HOCH2COCH3. D. C2H5COOH v HCOOC2H5. Cu 9. (HB-2010) Thuy phn este Z trong mi trng axit thu c hai cht hu c X va Y (M X < MY). Bng mt phan ng co th chuyn hoa X thanh Y. Cht Z khng th la A. metyl axetat B. etyl axetat C. metyl propionat D. vinyl axetat Cu 10. (C A-2008) Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S cht trong dy tham gia phn ng trng gng l: A. 4 B. 5 C. 3 D. 6 Cu 11. (HA-2011) t chy hon ton 0,11 gam mt este X ( to nn t mt axit cacboxylic n chc v mt ancol n chc) thu c 0,22 gam CO2 v 0,09 gam H2O. S este ng phn ca X l: A. 5 B. 4 C. 2 D. 6 Cu 12. (HB-2011) Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X tha mn cc tnh cht trn l: A. 5 B. 4 C. 2 D. 6 Cu 13. (C A-2008) Mt hn hp X gm 2 cht hu c n chc. Cho X phn ng va vi 500 ml dung dch KOH 1M. Sau phn ng, thu c hn hp Y gm 2 mui ca 2 axit cacboxylic v mt ancol. Cho ton b lng ancol thu c trn tc dng vi Na (d), sinh ra 3,36 lt H2 (ktc). Hn hp X gm A. mt axit v mt este. B. mt este v mt ancol.C. hai este. D. mt axit v mt ancol.
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Cu 14. (H A-2008) Este X c cc c im sau: - t chy hon ton X to thnh CO2 v H2O c s mol bng nhau; - Thy phn X trong mi trng acid c cht Y (tham gia phn ng trng gng) v cht Z (c s nguyn t carbon bng mt na s nguyn t carbon trong X). Pht biu khng ng l: A. Cht Y tan v hn trong nc. B. Cht X thuc loi este no n chc. C. un Z vi dung dch H2SO4 1700C thu c anken. D. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O. Cu 15. (C A-2009) Cho m g hn hp hai cht hu c n chc, mch h tc dng va vi dung dch cha 11,2 g KOH, thu c mui ca mt axit cacboxylic v mt ancol X. Cho ton b X tc dng ht vi Na thu c 3,36 lt kh H 2 (ktc). Hai cht hu c l: A. mt este n mt ancol B. hai axit. C. mt este v mt axit. D. hai este. Cu 16. (C A-2008) Este n chc X c t khi hi so vi metan l 6,25. Cho 20 g X tc dng vi 300 ml dung dch KOH 1M (un nng). C cn dung dch sau phn ng thu c 28 g cht rn khan. CTCT ca X l: A. CH2=CH-CH2-COO-CH3.B. CH2=CH-COO-CH2-CH3. C. CH3-COO-CH=CH-CH3. D. CH3-CH2-COO-CH=CH2. Cu 17. (HA-2012) Cho cc pht biu sau: (a) Cht bo c gi chung l triglixerit hay triaxylglixerol. (b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong dung mi hu c. (c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch. (d) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5, (C17H35COO)3C3H5. S pht biu ng l A. 1 B. 2 C. 4 D. 3 Cu 18. (C-2011) Este X no, n chc, mch h, khng c phn ng trng bc. t chy 0,1 mol X ri cho sn phm chy hp th hon ton vo dung dch nc vi trong c cha 0,22 mol Ca(OH) 2 th vn thu c kt ta. Thu phn X bng dung dch NaOH thu c 2 cht hu c c s nguyn t cacbon trong phn t bng nhau. Phn trm khi lng ca oxi trong X l: A. 43,24% B. 36,36% C. 37,21% D. 53,33% Cu 19. (C-2012) Cho cc phn ng sau t0 X + 2NaOH 2Y + H2O (1)
t0 Y + HCl (long) Z + NaCl (2) Bit X l cht hu c c cng thc phn t C6H10O5. Khi cho 0,1 mol Z tc dng ht vi Na (d) th s mol H2 thu c l: A. 0,05 B. 0,15 C. 0,10 D. 0,20 Cu 20. (HA-2011) Cho dy cc cht: phenylamoni clorua, benzyl clorua, isopropyl clorua, m-crezol, ancol benzylic, natri phenolat, anlyl clorua. S cht trong dy tc dng c vi dung dch NaOH long, un nng l A. 4 B. 3 C. 6 D. 5 Cu 21. (C A-2007) Khi t chy hon ton 4,4 g cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO2 (ktc) v 3,6 g H2O. Nu cho 4,4g cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 g mui ca acid hu c Y v cht hu c Z. Tn ca X l: A. isopropyl axetat. B. etyl axetat. C. etyl propionat. D. metyl propionat. Cu 22. (HB-2010) Hp cht hu c mch h X c cng thc phn t C6H10O4. Thy phn X to ra hai ancol n chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l A. CH3OCO-COOC3H7. B. CH3OCO-CH2-COOC2H5. C. CH3OCO-CH2-CH2-COOC2H5. D. C2H5OCO-COOCH3. Cu 23. (HB-2012) Este X l hp cht thm c cng thc phn t l C9H10O2. Cho X tc dng vi dung dch NaOH, to ra hai mui u c phn t khi ln hn 80. Cng thc cu to thu gn ca X l A. CH3COOCH2C6H5. B. C2H5COOC6H5. C. C6H5COOC2H5. D. HCOOC6H4C2H5. Cu 24. (HA-2011) Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th lng NaOH phn ng l 10 gam. Gi tr ca m l: A. 14,5. B. 15,5. C. 17,5. D. 16,5 Cu 25. (C A-2009) Cho 20 g mt este X (c phn t khi l 100 vC) tc dng vi 300 ml dung dch NaOH 1M. Sau phn ng, c cn dung dch thu c 23,2 g cht rn khan. CTCT ca X l: A. CH3COOCH=CHCH3 B. CH2=CHCOOC2H5

C. CH2=CHCH2COOCH3 D. C2H5COOCH=CH2 Cu 26. (H B-2008) Khi t chy hon ton mt este no n chc th s mol CO 2 sinh ra bng s mol O2 phn ng. Tn gi ca este l: A. metyl fomiat B. etyl axetat C. metyl axetat D. n-propyl axetat Cu 27. (HA-2011) Cho axit salixylic (axit o-hiroxibenzoic) phn ng vi anhirit axetic, thu c axit axetylsalixylic (o-CH3COO-C6H4-COOH) dng lm thuc cm (aspirin). phn ng hon ton vi 43,2 gam axit axetylsalixylic cn va V lt dung dch KOH 1M. Gi tr ca V l A. 0,96. B. 0,48. C. 0,72 D. 0,24. Cu 28. (C A-2009) S hp cht l ng phn cu to, c cng CTPT C 4H8O2, tc dng c vi dung dch NaOH nhng khng tc dng c vi Na l: A. 3 B. 1 C. 4 D. 2 Cu 29. (CA-2008) X phng ha hon ton 22,2g hn hp gm 2 este HCOOC 2H5 v CH3COOCH3 bng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l: A. 150 ml B. 200 ml C. 400 ml D. 300 ml Cu 30. (H A-2009) X phng ha mt hp cht c CTPT C10H14O6 trong dung dch NaOH (d), thu c glixerol v hn hp gm 3 mui (khng c ng phn hnh hc). Cng thc ca 3 mui l: A. CH2=CH-COONa, CH3-CH2-COONa, HCOONa.B. CH2=CH-COONa, CHC-COONa, HCOONa. C. HCOONa, CH3-COONa, CH3-CH=CH-COONa. D. CHC-COONa, CH3-CH2-COONa, HCOONa. Cu 31. (HB-2011) Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X, thu c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l: A. 25% B. 72,08% C. 75% D. 27,92% Cu 32. (C-2012) Ha hi hon ton 4,4 gam mt este X mch h, thu c th tch hi bng th tch ca 1,6 gam kh oxi (o cng iu kin). Mt khc, thy phn hon ton 11 gam X bng dung dch NaOH d, thu c 10,25 gam mui. Cng thc ca X l: A. CH3COOC2H5. B. HCOOC3H7. C. C2H5COOCH3. D. C2H5COOC2H5. Cu 33. (HA-2010) Cho hn hp X gm ancol metylic v hai axit cacboxylic (no, n chc, k tip nhau trong dy ng ng) tc dng ht vi Na, gii phng ra 6,72 lt kh H2 (ktc). Nu un nng hn hp X (c H2SO4 c lm xc tc) th cc cht trong hn hp phn ng va vi nhau to thnh 25 gam hn hp este (gi thit phn ng este ho t hiu sut 100%). Hai axit trong hn hp X l A. HCOOH v CH3COOH. B. C3H7COOH v C4H9COOH. C. CH3COOH v C2H5COOH. D. C2H5COOH v C3H7COOH. Cu 34. (H A-2009) Cho cc hp cht hu c: C2H2, C2H4, CH2O, CH2O2 (mch h), C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu giy qu tm m, S cht tc dng c vi dung dch AgNO 3 trong NH3 to ra kt ta l: A. 5 B. 3 C. 4 D. 2 Cu 35. (C-2011) Cng thc ca triolein l: A. (CH3[CH2]14COO)3C3H5 B. (CH3[CH2]7CH=CH[CH2]7COO)3C3H5 C. (CH3[CH2]16COO)3C3H5 D. (CH3[CH2]7CH=CH[CH2]5COO)3C3H5 Cu 36. (H A-2008) Pht biu ng l: A. Phn ng thy phn este trong mi trng axit l phn ng thun nghch. B. Phn ng gia axit v ru khi c H2SO4 l phn ng mt chiu. C. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v ancol. D. Khi thy phn cht bo lun thu c C2H4(OH)2. Cu 37. (HB-2011) Triolein khng tc dng vi cht (hoc dung dch) no sau y? A. H2O (xc tc H2SO4 long, un nng) B. Dung dch NaOH (un nng) C. H2 (xc tc Ni, un nng D. Cu(OH)2 ( iu kin thng) Cu 38. (HA-2010) Hn hp M gm ancol no, n chc X v axit cacboxylic n chc Y, u mch h v c cng s nguyn t C, tng s mol ca hai cht l 0,5 mol (s mol ca Y ln hn s mol ca X). Nu t chy hon ton M th thu c 33,6 lt kh CO2 (ktc) v 25,2 gam H2O. Mt khc, nu un nng M vi H2SO4 c thc hin phn ng este ho (hiu sut l 80%) th s gam este thu c l A. 34,20. B. 18,24 C. 27,36. D. 22,80. Cu 39. (HB-2011) Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l: A. 2 B. 5 C. 4 D. 3 Cu 40. (C A-2007) Poli (vinyl axetat) l polime c iu ch bng phn ng trng hp A. C2H5-COO-CH=CH2 B. CH2=CH-COO-C2H5 C. CH3-COO-CH=CH2 D. CH2=CH-COO-CH3
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Cu 41. (HB-2012) S trieste khi thy phn u thu c sn phm gm glixerol, axit CH 3COOH v axit C2H5COOH l A. 4 B. 9 C. 2 D. 6 Cu 42. (H A-2009) X phng ha hon ton 1,99g hn hp hai este bng dung dch NaOH thu c 2,05g mui ca mt axit cacboxylic v 0,94 g hn hp 2 ancol l ng ng k tip nhau. Cng thc ca 2 este l: A. CH3COOC2H5 v CH3COOC3H7. B. CH3COOCH3 v CH3COOC2H5. C. HCOOCH3 v HCOOC2H5. D. C2H5COOCH3 v C2H5COOC2H5. Cu 43. (C A-2007) S hp cht n chc, ng phn cu to ca nhau c cng CTPT C 4H8O2, u tc dng c vi NaOH l A. 4 B. 5 C. 6 D. 3 Cu 44. (C-2011) Hp cht hu c X c cng thc phn t l C 4H8O3. X c kh nng tham gia phn ng vi Na, vi dung dch NaOH v phn ng trng bc. Sn phm thu phn ca X trong mi trng kim c kh nng ho tan Cu(OH) 2 to thnh dung dch mu xanh lam. Cng thc cu to ca X c th l: A. CH3CH(OH)CH(OH)CHO B. HCOOCH2CH2CH2OH C. HCOOCH2CH(OH)CH3 D. CH3COOCH2CH2OH. Cu 45. (H A-2009) X phng ha hon ton 66,6 g hn hp hai este HCOOC 2H5 v CH3COOCH3 bng dung dch NaOH, thu c hn hp X gm 2 ancol. un nng hn hp X vi H2SO4 1400C, sau khi phn ng xy ra hon ton thu c m g nc. Gi tr ca m l A. 18,00 B. 8,10 C. 16,20 D. 4,05 Cu 46. (H A-2008) S ng phn este ng vi CTPT C4H8O2 l: A. 2 B. 6 C. 5 D. 4 Cu 47. (HB-2012) t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O 2, thu c 23,52 lt kh CO2 v 18,9 gam H2O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH 1M, c cn dung dch sau phn ng th thu c 27,9 gam cht rn khan, trong c a mol mui Y v b mol mui Z (M Y < MZ). Cc th tch kh u o iu kin tiu chun. T l a : b l A. 3 : 2 B. 4 : 3 C. 2 : 3 D. 3 : 5 Cu 48. (H A-2009) Cht hu c X c CTPT C5H8O2. Cho 5 g X tc dng va ht vi dung dch NaOH, thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 g mt mui. Cng thc ca X l: A. HCOOCH=CHCH2CH3 B. CH3COOC(CH3)=CH2 C. HCOOCH2CH=CHCH3 D. HCOOC(CH3)=CHCH3 Cu 49. (H B-2008) Hp cht hu c no, a chc X c CTPT C7H12O4. Cho 0,1 mol X tc dng va vi 100 g dung dch NaOH 8% thu c cht hu c Y v 17,8 g hn hp mui. CTCT thu gn ca X l: A. CH3OOC-(CH2)2-COOC2H5 B. CH3COO-(CH2)2-OOCC2H5 C. CH3COO-(CH2)2-COOC2H5 D. CH3OOC-(CH2)2-COOC3H7 Cu 50. (C-2012) Cho s phn ng:
+ NaOH + NaOH 3 3 Z Este X (C4HnO2) Y C2H3O2Na. t0 t0 t0 + AgNO / NH

Cng thc cu to ca X tha mn s cho l A. HCOOCH2CH2CH3. B. CH3COOCH2CH3. C. CH2=CHCOOCH3. D. CH3COOCH=CH2 Cu 51. (C-2012) Cho cc este : etyl fomat (1), vinyl axetat (2), triolein (3), metyl acrylat (4), phenyl axetat (5). Dy gm cc este u phn ng c vi dung dch NaOH (un nng) sinh ra ancol l: A. (2), (3), (5). B. (3), (4), (5). C. (1), (3), (4). D. (1), (2), (3). Cu 52. (HA-2010) t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin). Cho m gam X tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Gi tr ca m l A. 8,88 B. 7,2 C. 6,66 D. 10,56 Cu 53. (H A-2009) Cho dy chuyn ha sau: +X + NaOH(d)/t 0 Phenol phenyl axetat Y (hp cht thm) Hai cht X, Y trong s trn ln lt l: A. anhidric axetic, phenol. B. axit axetic, natri phenolat. C. axit axetic, phenol. D. anhidrit axetic, natri phenolat. Cu 54. (C A-2009) Pht biu no sau y sai ? A. Sn phm ca phn ng x phng ha cht bo l axit bo v glixerol. B. S nguyn t hidro trong phn t este n v a chc lun l mt s chn.
4

C. Trong cng nghip c th chuyn ha cht bo lng thnh cht bo rn. D. Nhit si ca este thp hn hn so vi ancol c cng phn t khi. Cu 55. (C A-2007) un 12 g axit axetic vi 13,8 g etanol (c H2SO4 lm xc tc) n khi phn ng t trang thi cn bng, thu c 11 g este. Hiu sut ca phn ng este ha l: A. 50% B. 55% C. 62,5% D. 75% Cu 56. (HB-2011) Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l: A. 30 gam B. 31,45 gam C. 31 gam D. 32,36 gam Cu 57. (H B-2009) Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va 3,976 lt kh O2 (ktc), thu c 6,38 g CO2. Mt khc, X tc dng vi dung dch NaOH, thu c mt mui v hai ancol l ng ng k tip. CTPT ca hai este trong X l A. C3H6O2 v C4H8O2. B. C2H4O2 v C5H10O2. C. C2H4O2 v C3H6O2. D. C3H4O2 v C4H6O2. Cu 58. (C A-2007) Ester X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x phng ha to ra mt andehid v mt mui ca axit hu c. C bao nhiu CTCT ph hp vi X ? A. 5 B. 2 C. 3 D. 4 Cu 59. (C A-2008) un nng 6,0 g CH3COOH vi 6,0 g C2H5OH (c H2SO4 xc tc, hiu sut phn ng este ha bng 50%). Khi lng este to thnh l: A. 8,8 g B. 5,2 g C. 4,4 g D. 6,0 g Cu 60. (C A-2008) Hai cht hu c X v Y u c khi lng phn t bng 60 vC. X c kh nng tham gia phn ng vi: Na, NaOH, Na2CO3. Y phn ng vi NaOH (un nng) nhng khng phn ng vi Na. CTCT ca X, Y ln lt l: A. HCOOCH3, CH3COOH. B. (CH3)2CHOH, HCOOCH3. C. CH3COOH, HCOOCH3. D. CH3COOH, CH3COOCH3. Cu 61. (HA-2011) t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH)2 (d). Sau phn ng thu c 18 gam kt ta v dung dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban u thay i nh th no? A. Gim 7,74 gam. B. Tng 2,70 gam. C. Tng 7,92 gam. D. Gim 7,38 g CACBOHIDRAT Cu 62. (HB-2008) Cho cc cht: ru etylic, glixerol, gluco, dimetyl eter v axit formic. S cht tc dng vi Cu(OH)2 l: A. 1 B. 3 C. 4 D. 2 Cu 63. (HA-2011) Xenluloz trinitrat c iu ch t phn ng gia axit nitric vi xenluloz (hiu sut phn ng 60% tnh theo xenluloz). Nu dng 2 tn xenluloz th khi lng xenluloz trinitrat iu ch c l A. 2,97 tn B. 3,67 tn C. 1,10 tn D. 2,20 tn Cu 64. (HA-2008) Lng gluco cn dng to ra 1,82 g sorbitol vi hiu sut 80% l A. 1,82 g B. 1,8 g C. 1,44 g D. 2,25 g Cu 65. (HB-2009) Pht biu no sau y khng ng ? A. Khi gluco dng vng th tt c cc nhm OH u to eter vi CH 3OH. B. Gluco tn ti dng mch h v dng mch vng. C. dng mch h, gluco c 5 nhm OH k nhau. D. Gluco tc dng c vi nc brom. Cu 66. (HA-2008) Tinh bt, xenlulo, saccaro, manto u c kh nng tham gia phn ng A. ha tan Cu(OH)2 B. trng ngng C. trng gng D. thy phn Cu 67. (HB-2012) iu ch 53,46 kg xenluloz trinitrat (hiu sut 60%) cn dng t nht V lt axit nitric 94,5% (D = 1,5 g/ml) phn ng vi xenluloz d. Gi tr ca V l A. 36 B. 40 C. 24 D. 60 Cu 68. (HB-2008) Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ancol 46 0 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml) A. 6,0 kg B. 5,0 kg C. 4,5 kg D. 5,4 kg Cu 69. (C-2012) Pht biu no sau y l ng? A. Ancol etylic tc dng c vi dung dch NaOH. B. Axit bo l nhng axit cacboxylic a chc. C. Este isoamyl axetat c mi chui chn. D. Etylen glicol l ancol no, n chc, mch h. Cu 70. (HB-2011) Cho cc pht biu sau v cacbohirat: (a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc. (b) Tinh bt v xenluloz u l polisaccarit
5

(c) Trong dung dch, glucoz v saccaroz u ha tan Cu(OH) 2, to phc mu xanh lam. (d) Khi thy phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit, ch thu c mt loi monosaccarit duy nht. (e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO 3 trong NH3 thu c Ag. (g) Glucoz v saccaroz u tc dng vi H 2 (xc tc Ni, un nng) to sobitol. S pht biu ng l: A. 4 B. 5 C. 3 D. 6 Cu 71. (HA-2007) chng minh phn t glucoz c nhiu nhm hidroxyl, ngi ta cho dung dch glucoz phn ng vi A. AgNO3 trong dung dch NH3, un nng. B. Cu(OH)2 nhit thng. C. Cu(OH)2 trong NaOH, un nng. D. kim loi Na. Cu 72. (HA-2011) Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut ton b qu trnh l 90%, Hp th ton b lng CO2, sinh ra khi ln men m gam tinh bt vo nc vi trong , thu c 330 gam kt ta v dung dch X. Bit khi lng X gim i so vi khi lng nc vi trong ban u l 132 gam. Gi tr ca m l: A. 486 B. 324 C. 405 D. 297 Cu 73. (HA-2008) Gluxit (carbohidrat)ch cha 2 gc gluco trong phn t l A. manto B. xenlulo C. saccaro D. tinh bt Cu 74. (HA-2007) Cho mg tinh bt ln men thnh ancol etylic vi hiu sut 81%. Ton b lng CO 2 sinh ra c hp th hon ton vo dung dch Ca(OH)2, thu c 550 g kt ta v dung dch X. un k dung dch X thu thm c 100 g kt ta. Gi tr ca m l: A. 750 B. 550 C. 650 D. 810 Cu 75. (HA-2012) Cho s phn ng : xuctac Y (a) X + H2O (b) Y + AgNO3 + NH3 + H2O
xuctac E+Z (c) Y anh sang X+G (d) Z + H2O chat diepluc

t0

amoni gluconat + Ag + NH4NO3

X, Y, Z ln lt l: A. Xenluloz, saccaroz, cacbon ioxit. B. Xenluloz, fructoz, cacbon ioxit. C. Tinh bt, glucoz, etanol. D. Tinh bt, glucoz, cacbon dioxit. Cu 76. (HB-2009) Cho mt s tnh cht: c dng si (1); tan trong nc (2); tan trong nc Svayde (3); phn ng vi HNO3 (xt H2SO4 ) (4); tham gia phn ng trng bc (5); b thy phn trong dung dch axit un nng (6). Cc tnh cht ca xenlulo l: A. 3, 4, 5, 6. B. 1, 2, 3, 4. C. 1, 3, 4, 6. D. 2, 3, 4, 5. Cu 77. (C-2012) Ln men 90 kg glucoz thu c V lt ancol etylic (D = 0,8 g/ml) vi hiu sut ca qu trnh ln men l 80%. Gi tr ca V l: A. 57,5 B. 46,0 C. 23,0 D. 71,9 Cu 78. (HA-2009) Cacbohidrat nht thit phi cha nhm chc A. ancol B. andehit C. xeton D. amin Cu 79. (C-2011) Cho cc cht : saccaroz, glucoz , frutoz, etyl format , axit fomic v anehit axetic. Trong cc cht trn, s cht va c kh nng tham gia phn ng trng bc va c kh nng phn ng vi Cu(OH) 2 iu kin thng l : A. 4 B. 5 C. 2 D. 3 Cu 80. (HB-2009) Xenluloz trinitrat c iu ch t xenlulo v HNO 3 c xt H2SO4 , t0, cn dng dung dch cha m kg HNO3 (hiu sut phn ng t 90%). Gi tr ca m l: A. 42 B. 30 C. 21 D. 10 Cu 81. (HA-2010) T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic (hiu sut 80%). Oxi ho 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X. trung ho hn hp X cn 720 ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l A. 20%. B. 10%. C. 90% D. 80%. Cu 82. (HB-2009) Pht biu no sau y l ng? A. xenlulo c cu trc mch phn nhnh. B. Saccaro lm mt mu nc brom. C. Gluco b kh bi dung dch AgNO3/NH3. D. Amilopectin c cu trc mch phn nhnh. Cu 83. (C-2008) Cho dy cc cht: gluco, xenlulo, saccaro, tinh bt, manto. S cht trong dy tham gia phn ng trng gng l: A. 3 B. 4 C. 2 D. 5 Cu 84. (HA-2012) Cho cc pht biu sau:
6

(a) t chy hon ton este no, n chc, mch h lun thu c s mol CO2 bng s mol H2O. (b) Trong hp cht hu c nht thit phi c cacbon v hiro. (c) Nhng hp cht hu c c thnh phn nguyn t ging nhau, thnh phn phn t hn km nhau mt hay nhiu nhm CH2 l ng ng ca nhau. (d) Dung dch glucoz b kh bi AgNO3 trong NH3 to ra Ag. (e) Saccaraz ch c cu to mch vng. S pht biu ng l A. 4. B. 5. C. 3. D. 2. Cu 85. (HA-2010) Mt phn t saccaroz c: A. mt gc -glucoz v mt gc -fructoz. B. mt gc -glucoz v mt gc -fructoz. C. mt gc -glucoz v mt gc -fructoz. D. hai gc -glucoz. Cu 86. (HB-2007) Pht biu khng ng l A. Thy phn (xt H+,t0) saccaro cng nh manto u cho cng mt monosaccarit. B. Dung dch fructo ha tan c Cu(OH)2. C. sn phm thy phn xenlulo (xt H+,t0) c th tham gia phn ng trng gng. D. Dung dch manto tc dng vi Cu(OH)2 khi un nng cho kt ta Cu2O. Cu 87. (HB-2008) Th tch dung dch HNO3 67,5% (khi lng ring 1,5 g/ml) cn dng tc dng vi xenlulo to thnh 89,1 kg xenlulo trinitrat l (bit khi lng HNO3 hao ht 20%) A. 81 lt B. 55 lt C. 49 lt D. 70 lit Cu 88. (HB-2011) Cho cc pht biu sau: (a) C th dng nc brom phn bit glucoz v fructoz (b) Trong mi trng axit, glucoz v fructoz c th chuyn ha ln nhau (c) C th phn bit glucoz v fructoz bng phn ng vi dung dch AgNO 3 trong NH3 (d) Trong dung dch, glucoz v fructoz u ha tan Cu(OH) 2 nhit thng cho dung dch mu xanh lam (e)Trong dung dch, fructoz tn ti ch yu dng mch h (f) Trong dung dch, glucoz tn ti ch yu dng mch vng 6 cnh (dng v ) S pht biu ng l A. 2 B. 5 C. 4 D. 3 Cu 89. (HB-2008) Cho cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (manto). S cht trong dy tham gia phn ng trng gng l: A. 5 B. 3 C. 4 D. 6 Cu 90. (C-2009) Cho cc chuyn ha sau: X + H2O Y + H2

xt, t0 Y

t0

sorbitol

Y + 2 AgNO3 + 3 NH3 + H2O Y

t0

amoni gluconat + 2 Ag + 2 NH4NO3

xt

E+Z

Z + H2O chat diep luc X + G X, Y v Z ln lt l A. xenlulo, fructo v kh carbonic. B. xenlulo, gluco v kh carbonic. C. tinh bt, gluco v kh carbonic. D. tinh bt, gluco v ancol etylic. Cu 91. (HB-2011) Thy phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c dung dch X (hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt lng d dung dch AgNO3 trong NH3 th lng Ag thu c l A. 0,090 mol B. 0,095 mol C. 0,12 mol D. 0,06 mol Cu 92. Cho cc pht biu sau: (1) Fructoz v glucoz u c kh nng tham gia phn ng trng bc; (2) Saccaroz v tinh bt u khng b thy phn khi c axit H 2SO4 (long) lm xc tc; (3) Tinh bt c to thnh trong cy xanh nh qu trnh quang hp; (4) Xenluloz v saccaroz u thuc loi disaccarit; Pht biu ng l : A. (1) v (3). B. (2) v (4). C. (1) v (2). D. (3) v (4).

as

Cu 93. (CA-2008) T 16,2 tn xenlulo ngi ta sn xut c m g tn xenlulo trinitrat (bit hiu sut phn ng tnh theo xenlulo l 90%). Gi tr ca m l A. 26,73 B. 25,46 C. 33,00 D. 29,70 Cu 94. (HB-2010) Cac dung dich phan ng c vi Cu(OH) 2 nhit thng la A. fructoz, axit acrylic, ancol etylic. B. glixerol, axit axetic, glucoz C. anhit axetic, saccaroz, axit axetic D. long trng trng, fructoz, axeton Cu 95. (HA-2009) Dy gm cc dung dch u tham gia phn ng trng bc l: A. gluco, glixerol, manto, axit fomic. B. fructo, manto, glixerol, andehit axetic. C. gluco, manto, axit fomic, andehit axetic. D. gluco, fructo, manto, saccaro. Cu 96. (HA-2009) Ln men m g gluco vi hiu sut 90%, lng kh CO 2 sinh ra hp th ht vo dung dch nc vi trong, thu c 10 g kt ta. Khi lng dung dch sau phn ng gim 3,4 g so vi khi lng dung dch nc vi trong ban u. Gi tr ca m l: A. 20,0 B. 13,5 C. 30,0 D. 15,0 Cu 97. (C-2007) Cho 50 ml dung dch gluco cha r nng tc dng vi lng d AgNO 3 trung dung dch NH3, un nng thu c 2,16 g Ag. Nng mol ca dung dch gluco dng l A. 0,02M B. 0,1M C. 0,2M D. 0,01M Cu 98. (C-2007) Ch dng Cu(OH)2 c th phn bit c tt c dung dch ring bit sau: A. gluco, lng trng trng, glixerol, ancol etylic. B. saccaro, glixerol, andehit axetic, ancol etylic. C. lng trng trng, gluco, fructo, glixerol. D. gluco, manto, glixerol, andehit axetic. Cu 99. (HB-2010) Cht X c cc c im sau: phn t c nhiu nhm -OH, c v ngt, ha tan Cu(OH) 2 nhit thng, phn t c lin kt glicozit, lam mt mau nc brom. Cht X la A. glucoz B. mantoz C. Saccaroz D. xenluloz Cu 100. (C-2008) Cho s chuyn ha sau (mi mi tn l 1 phng trnh phn ng). Tinh bt X Y Z metyl axetat. Cc cht Y, Z trong s trn ln lt l: A. C2H5OH, CH3COOH. B. CH3COOH, CH3OH. C. C2H4, CH3COOH. D. CH3COOH, C2H5OH. Cu 101. (C-2011) Ln men dung dch cha 300 gam glucoz thu c 92 gam ancol etylic. Hiu sut qu trnh ln men to thnh ancol etylic l: A. 40% B. 80% C. 54% D. 60% Cu 102. (HB-2012) Thy phn hn hp gm 0,01 mol saccaroz v 0,02 mol mantoz trong mi trng axit, vi hiu sut u l 60% theo mi cht, thu c dung dch X. Trung ha dung dch X, thu c dung dch Y, sau cho ton b Y tc dng vi lng d dung dch AgNO3 trong NH3, thu c m gam Ag. Gi tr ca m l A. 9,504. B. 6,480. C. 7,776. D. 8,208. Cu 103. (C-2009) Len men hon ton m g gluco thnh ancol etylic. Ton b kh CO 2 sinh ra trong qu trnh ny c hp th ht vo dung dch Ca(OH)2 (d) to ra 40 g kt ta. Nu hiu sut ton qu trnh trn l 75% th gi tr ca m l: A. 30 B. 60 C. 58 D. 48 AMIN - AMINO AXIT - PROTEIN Cu 104. (HA-2009) Hp cht X mch h c CTPT l C4H9NO2. Cho 10,3 g X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m g mui khan. Gi tr ca m l A. 9,4 B. 9,6 C. 10,8 D. 8,2 Cu 105. (C-2011) Hai cht no sau y u tc dng uc vi dung dch NaOH long? A. CH3NH3Cl v H2NCH2COONa. B. CH3NH3Cl v CH3NH2. C. ClH3NCH2COOC2H5. v H2NCH2COOC2H5. D. CH3NH2 v H2NCH2COOH. Cu 106. (C-2012) Thy phn hon ton m gam ipeptit Gly-Ala (mch h) bng dung dch KOH va , thu c dung dch X. C cn ton b dung dch X thu c 2,4 gam mui khan. Gi tr ca m l: A. 1,64 B. 1,46 C. 1,22 D. 1,36 Cu 107. (C-2012) Cho 14, 55 gam mui H2NCH2COONa tc dng hon ton vi dung dch HCl d, thu c dung dch X. C cn ton b dung dch X, thu c bao nhiu gam mui khan? A. 16,73 gam B. 20,03 gam C. 8,78 gam D. 25,50 gam Cu 108. (C-2007) trung ha 25 g dung dch ca mt amin n chc X nng 12,4% cn dng 100 ml dung dch HCl 1M. CTPT ca X l: A. C3H5N B. CH5N C. C2H7N D. C3H7N

Cu 109. (HB-2012) Cho dy cc cht sau: toluen, phenyl fomat, fructoz, glyxylvalin (Gly-Val), etylen glicol, triolein. S cht b thu phn trong mi trng axit l A. 4 B. 5 C. 3 D. 6 Cu 110. (HA-2010) Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l A. 0,70. B. 0,55. C. 0,65 D. 0,50. Cu 111. (HA-2007) Amino axit cha mt nhm amin bc nht trong phn t. t chy hon ton mt lng X thu c CO2 v N2 theo t l th tch l 4:1. X c CTCT l A. H2N-(CH2)3-COOH. B. H2N-(CH2)4-COOH. C. H2N-CH2-COOH. D. H2N-CH2-CH2-COOH. Cu 112. (HA-2011) Thy phn hon ton 60 gam hn hp hai ipetit thu c 63,6 gam hn hp X gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho 1/10 hn hp X tc dng vi dung dch HCl (d), c cn cn thn dung dch, th lng mui khan thu c l : A. 7,09 gam. B. 16,30 gam C. 8,15 gam D. 7,82 g Cu 113. (HA-2009) Pht biu no sau y l ng? A. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh. B. Anilin tc dng vi axit nitr khi un nng, thu c mui diazoni. C. Benzen lm mt mu nc brom nhit thng. D. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam. Cu 114. (HA-2007)t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO 2, 0,56 lt N2(cc kh o ktc) v 3,15 g H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2N-CH2-COONa. CTCT thu gn ca X l A. H2N-CH2-COOC2H5. B. H2N-CH2-COOCH3. C. H2N-CH2-COOC3H7 D. H2N-CH2-CH2-COOH. Cu 115. (HB-2010) Thuy phn hoan toan 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) va 1 mol Phenylalanin (Phe). Thuy phn khng hoan toan X thu c ipeptit Val-Phe va tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X co cng thc la A. Gly-Phe-Gly-Ala-Val B. Val-Phe-Gly-Ala-Gly C. Gly-Ala-Val-Phe-Gly. D. Gly-Ala-Val-Val-Ph Cu 116. (HA-2012) Dung dch cht no sau y lm qu tm chuyn thnh mu hng? A. Axit aminoaxetic. B. axit -aminoglutaric C. Axit -aminopropionic D. Axit , -iaminocaproic Cu 117. (HA-2011) Thnh phn % khi lng ca nit trong hp cht hu c C xHyN l 23,73%. S ng phn amin bc mt tha mn cc d kin trn l A. 4 B. 1 C. 2 D. 3 Cu 118. (C-2012) Pht biu no sau y l ng? A. Amino axit thuc loi hp cht hu c tp chc. B. Cc amino axit thin nhin hu ht l cc -amino axit. C. nhit thng, cc amino axit u l nhng cht lng. D. Axit glutamic l thnh phn chnh ca bt ngt. Cu 119. (HA-2011) Khi ni v peptit v protein, pht biu no sau y l sai ? A. Thy phn hon ton protein n gin thu c cc a-amino axit. B. Lin kt ca nhm CO vi nhm NH gia hai n v a-amino axit c gi l lin kt peptit. C. Tt c cc protein u tan trong nc to thnh dung dch keo. D. Protein c phn ng mu biure vi Cu(OH)2. Cu 120. (HA-2010) Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l A. 8 v 1,0. B. 7 v 1,0 C. 7 v 1,5. D. 8 v 1,5. Cu 121. (HB-2011) Ancol v amin no sau y cng bc? A. (C6H5)2NH v C6H5CH2OH B. (CH3)3COH v (CH3)3CNH2 C. (CH3)2CHOH v (CH3)2CHNH2 D. C6H5NHCH3 v C6H5CH(OH)CH3 Cu 122. (HB-2010) ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO 2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 30. B. 60 C. 45. D. 120 Cu 123. (HA-2010) t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp gm kh cacbonic, kh nit v hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc dng vi axit nitr nhit thng, gii phng kh nit. Cht X l A. CH3-CH2-NH-CH3. B. CH3-CH2-CH2-NH2. C. CH2=CH-CH2-NH2. D. CH2=CH-NH-CH3.
9

Cu 124. (HA-2010) Pht biu ng l: A. Khi thy phn n cng cc protein n gin s cho hn hp cc -aminoaxit. B. Enzim amilaza xc tc cho phn ng thy phn xenluloz thnh mantoz. C. Axit nucleic l polieste ca axit photphoric v glucoz. D. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc mu xanh m. Cu 125. (HB-2010) Trung ha hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l A. H2NCH2CH2NH2. B. H2NCH2CH2CH2NH2. C. H2NCH2CH2CH2CH2NH2. D. CH3CH2CH2NH2. Cu 126. (HB-2007) C 3 cht lng: benzen, anilin, stiren ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch NaOH. B. giy qu tm. C. dung dch phenolphtalein. D. nc brom. Cu 127. (HA-2012) Hn hp X gm 2 amino axit no (ch c nhm chc -COOH v -NH 2 trong phn t), trong t l mO : mN = 80 : 21. tc dng va vi 3,83 gam hn hp X cn 30 ml dung dch HCl 1M. Mt khc, t chy hon ton 3,83 gam hn hp X cn 3,192 lt O2 (ktc). Dn ton b sn phm chy (CO2, H2O v N2) vo nc vi trong d th khi lng kt ta thu c l A. 13 gam. B. 10 gam. C. 15 gam. D. 20 gam Cu 128. (HA-2010) C bao nhiu tripeptit (mch h) khc loi m khi thy phn hon ton u thu c 3 aminoaxit: glyxin, alanin v phenylalanin? A. 3 B. 4 C. 9 D. 6 Cu 129. un nng m gam hn hp gm a mol tetrapeptit mch h X v 2a mol tripeptit mch h Y vi 600 ml dung dch NaOH 1M (va ). Sau khi cc phn ng kt thc, c cn dung dch thu c 72,48 gam mui khan ca cc amino axit u c mt nhm -COOH v mt nhm -NH2 trong phn t. Gi tr ca m l A. 44,48. B. 54,30. C. 66,00. D. 51,72. Cu 130. ( H A - 2 0 1 0 ) Hn hp kh X gm imetylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 550 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t ca hai hirocacbon l A. CH4 v C2H6. B. C3H6 v C4H8. C. C2H6 v C3H8. D. C2H4 v C3H6. Cu 131. (C-2012) Cho 20 gam hn hp gm hai amin no, n chc, mch h tc dng va vi V ml dung dch HCl 1M, thu c dung dch cha 31,68 gam hn hp mui. Gi tr ca V l: A. 100. B. 320. C. 50. D. 200. Cu 132. (HB-2010) t chay hoan toan 0,1 mol mt amin no, mach h X bng oxi va u thu c 0,5 mol hn hp Y gm khi va hi. Cho 4,6g X tac dung vi dung dich HCl (d), s mol HCl phan ng la A. 0,1 B. 0,4 C. 0,3 D. 0,2 Cu 133. (HB-2010) Hai hp cht hu c X v Y c cng cng thc phn t l C 3H7NO2, u l cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l A. vinylamoni fomat v amoni acrylat. B. amoni acrylat v axit 2-aminopropionic. C. axit 2-aminopropionic v axit 3-aminopropionic. D. axit 2-aminopropionic v amoni acrylat. Cu 134. (C-2012) Pht biu no sau y l sai? A. Tripeptit Gly-Ala-Gly c phn ng mu biure vi Cu(OH) 2. B. Trong phn t dipeptit mch h c hai lin kt peptit. C. Tt c cc peptit u c kh nng tham gia phn ng thy phn. D. Protein n gin c to thnh t cc gc -amino axit. Cu 135. (HB-2008) un nng cht H2N-CH2-CO-NH-CH(CH3)-CO-NH-CH3-COOH trong dung dch HCl (d) sau khi phn ng kt thc thu c sn phm l A. H2N-CH2-COOH, H2N-CH(CH3)-COOH. B. H2N-CH2-COOH, H2N-CH2-CH2-COOH. C. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl-. D. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl-. Cu 136. (HB-2012) Cho 21 gam hn hp gm glyxin v axit axetic tc dng va vi dung dch KOH, thu c dung dch X cha 32,4 gam mui. Cho X tc dng vi dung dch HCl d, thu c dung dch cha m gam mui. Gi tr ca m l A. 44,65. B. 22,35. C. 50,65. D. 33,50. Cu 137. (HB-2007) Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l A. anilin, metyl amin, amoniac. B. amoni clorur, metyl amin, natri hidroxit. C. anilin, amoniac, natri hidroxit. D. metyl amin, amoniac, natri axetat.
10

Cu 138. (HA-2010) Cho s chuyn ho:

+ H 2 du ( Ni ;t C + NaOH du ;t C + HCl Triolein X Y Z . Tn ca Z l
0 0

A. axit stearic B. axit oleic. C. axit linoleic. D. axit panmitic. Cu 139. (C-2012) S nhm amino v s nhm cacboxyl c trong mt phn t axit glutamic tng ng l A. 2 v 1. B. 2 v 2. C. 1 v 2. D. 1 v 1. Cu 140. (HA-2007) -amino axit cha mt nhm -NH2. Cho 10,3 g X tc dng vi axit HCl (d), thu c 13,95 g mui khan. CTCT thu gn ca X l: A. CH3CH2CH(NH2)COOH. B. H2NCH2COOH. C. CH3CH(NH2)COOH. D. H2NCH2CH2COOH. Cu 141. (HA-2010) Trong s cc cht: C3H8, C3H7Cl, C3H8O v C3H9N; cht c nhiu ng phn cu to nht l A. C3H7Cl B. C3H9N C. C3H8 D. C3H8O Cu 142. (HA-2007) Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO 2, 1,4 lt N2 (th tch cc kh o ktc) v a0,125 g H2O. CTPT ca X l A. C3H9N B. C2H7N. C. C3H7N. D. C4H9N. Cu 143. (C-2011) Cho cc dung dch : C6H5NH2 (amilin), CH3NH2, NaOH, C2H5OH v H2NCH2COOH. Trong cc dung dch trn, s dung dch c th lm i mu phenolphtalein l: A. 5 B. 4 C. 3 D. 2 Cu 144. (C-2007) Hp cht X c CTPT trng vi CTGN, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%, cn li l oxi. Khi cho 4,45 g X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 g mui khan. CTCT thu gn ca X l: A. H2N-(CH2)2-COOH. B. H2N-CH2-COOCH3. C. CH2=CHCOONH4. D. H2NCOOCH2CH3. Cu 145. (C-2009) Thy phn 1250 g protein X thu c 425 g alanin. Nu phn t khi ca X bng 100 000 u th s mc xch alanin c trong phn t X l A. 382 B. 479 C. 328 D. 453 Cu 146. (HB-2011) Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc hirocacbon), phn trm khi lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ha thnh anehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l: A. 2,67 B. 5,34 C. 3,56 D. 4,45 Cu 147. (HA-2012) Hn hp M gm mt anken v hai amin no, n chc, mch h X v Y l ng ng k tip (M X < MY). t chy hon ton mt lng M cn dng 4,536 lt O2 (ktc) thu c H2O, N2 v 2,24 lt CO2 (ktc). Cht Y l: A. butylamin. B. etylamin. C. etylmetylamin. D. propylamin. Cu 148. (HB-2011) Cho ba dung dch c cng nng mol : (1) H2NCH2COOH, (2) CH3COOH, (3) CH3CH2NH2. Dy xp theo th t pH tng dn l: A. (1), (2), (3) B. (2), (1), (3) C. (2) , (3) , (1) D. (3), (1), (2) Cu 149. (C-2011) Pht biu no sau y l ng? A. Amino axit l hp cht c tnh lng tnh. B. Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng axit. C. Trong mt phn t tetrapeptit mch h c 4 lin kt peptit. D. Trong mi trng kim, ipetit mch h tc dng c vi Cu(OH) 2 cho hp cht mu tm. Cu 150. (HA-2008) C cc dung dch ring bit sau: C6H5NH3Cl, H2NCH2CH2CH(NH2)COOH, ClH3NCH2COOH, H2NCH2COONa, HOOCCH2CH2CH(NH2)COOH. S lng cc dung dch c pH < 7 l A. 4 B. 5 C. 2 D. 3 Cu 151. (C-2009) Cho 1,82 g cht hu c n chc mch h X c CTPT C3H9O2N tc dng va vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 g mui khan. CTCT thu gn ca X l A. HCOONH3CH2CH3 B. HCOONH2(CH3)2 C. CH3CH2COONH4 D. CH3COONH3CH3 Cu 152. (HA-2011) Dung dch no sau y lm qu tm i thnh mu xanh? A. Dung dch alanin B. Dung dch lysin. C. Dung dch valin D. Dung dch glyxin Cu 153. (HB-2012) Cho axit cacboxylic X phn ng vi cht Y thu c mt mui c cng thc phn t C 3H9O2N (sn phm duy nht). S cp cht X v Y tha mn iu kin trn l A. 3 B. 2 C. 1 D. 4 Cu 154. (HB-2008) Cho 8,9 g cht hu c X c CTPT C3H7O2N phn ng vi 100 ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 g cht rn. CTCT thu gn ca X l A. H2NCH2COOCH3. B. HCOOH3NCH=CH2. C. H2NCH2CH2COOH. D. CH2=CHCOONH4.

11

Cu 155. (HA-2012) Cho dy cc cht: C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH (3), (C2H5)2NH (4), NH3 (5) (C6H5- l gc phenyl). Dy cc cht sp xp theo th t lc baz gim dn l : A. (4), (2), (3), (1), (5). B. (4), (1), (5), (2), (3). C. (4), (2), (5), (1), (3). D. (3), (1), (5), (2), (4). Cu 156. (C-2011) Amino axit X c dng H2NRCOOH (R l gc hirocacbon). Cho 0,1 mol X phn ng ht vi dung dch HCl (d) thu c dung dch cha 11,15 gam mui. Tn gi ca X l: A. phenylalanin B. glyxin C. alanin D. valin Cu 157. (HB-2008) Cho hp cht hu c X c CTPT C2H8O3N2 tc dng vi dung dch NaOH, thu c cht hu c Y v cc cht v c. Khi lng phn t (theo n v carbon) ca Y l A. 68 B. 45 C. 46 D. 85 Cu 158. (HA-2009) Thuc th dng phn bit Gly-Ala-Gly vi Gly-Ala l A. dung dch NaOH. B. dung dch NaCl. C. Cu(OH)2 trong mi trng kim. D. dung dch HCl. Cu 159. (HB-2011) Pht biu khng ng l: A. Protein l nhng polopeptit cao phn t c phn t khi t vi chc nghn n vi chc triu. B. ipeptit glyxylalanin (mch h) c 2 lin kt peptit. C. Metylamin tan trong nc cho dung dch c mi trng baz D. Etylamin tc dng vi axit nitr nhit thng to ra etanol. Cu 160. (HB-2007) Mt trong nhng im khc nhau ca protit so vi lipit v gluco l A. protit lun cha chc hidroxyl. B. protit c khi lng phn t ln hn. C. protit lun l cht hu c no. D. protit lun cha nit. Cu 161. (HA-2011) Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32 gam Ala-Ala v 27,72 gam Ala-Ala-Ala. Gi tr ca m l A. 66,44. B. 111,74. C. 90,6. D. 81,54 Cu 162. (HB-2007) Cho cc cht: etyl axetat, anilin, ancol etylic, axit acrylic, phenol, phenylamoni clorur, ancol benzylic, p-crezol. Trong cc cht ny, s cht tc dung c vi dung dch NaOH l: A. 6 B. 3 C. 4 D. 5 Cu 163. (HB-2007) Cho cc loi hp cht: amino axit (X), mui amoni ca axit carboxylic (Y), amin (Z), ester ca amino axit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi dung dch HCl l A. X, Y, Z. B. X, Y, T. C. X, Y, Z, T. D. Y, Z, T. Cu 164. (HA-2012) Pht biu no sau y l ng A. Tt c cc peptit u c phn ng mu biure. B. Mui phenylamoni clorua khng tan trong nc. C. iu kin thng, metylamin v imetylamin l nhng cht kh c mi khai. D. H2N-CH2-CH2-CO-NH-CH2-COOH l mt ipeptit. Cu 165. (HA-2008) Pht biu khng ng l: A. Amino axit l hp cht hu c tp chc, phn t ng thi cha nhm amino v nhm carboxyl. B. Amino axit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt. C. Hp cht H2NCH2COOH3NCH3 l ester ca glyxin. D. Trong dung dch, H2NCH2COOH cn tn ti dng ion lng cc H3N+CH2COO-. Cu 166. (HB-2011) Hn hp X gm O2 v O3 c t khi so vi H2 l 22 . Hn hp kh Y gm metylamin v etylamin c t khi so vi H2 l 17,833. t chy hon ton V1 lt Y cn va V2 lt X (bit sn phm chy gm CO2, H2O v N2, cc cht kh khi o cng iu kin nhit , p sut). T l V1 : V2 l: A. 5 : 3 B. 1 : 2 C. 1 : 2 D. 3 : 5 POLIME - VT LIU POLIME Cu 167. Dy gm cc cht c dng tng hp caosu buna-S l A. CH2=CH-CH=CH2; CH3-CH=CH2. B. CH2=CH-CH=CH2; C6H5-CH=CH2. C. CH2=C(CH3)-CH=CH2; C6H5-CH=CH2. D. CH2=CH-CH=CH2; lu hunh. Cu 168. (HA-2011) Cho s phn ng: CHCH X; X polime Y; X + CH2=CH-CH=CH2 polime Z Y v Z ln lt dng ch to vt liu polime no sau y? A. T nitron v cao su buna-S. B. T nilon-6,6 v cao su cloropren. C. T olon v caosu buna-N. D. T capron v cao su buna. Cu 169. (C-2012) Pht biu no sau y l sai? A. Lc baz ca anilin yu hn lc baz ca metylamin.
12

B. Cao su buna-N thuc loi cao su thin nhin. C. Cht bo cn c gi l triglixerit hoc triaxylglixerol. D. Poli(metyl metacrylat) c dng ch to thy tinh hu c. Cu 170. (HA-2012) Hp cht X c cng thc C8H14O4. T X thc hin cc phn ng (theo ng t l mol): t0 (a) X + 2NaOH X1 + X2 + H2O (b) X1 + H2SO4 X3 + Na2SO4 (c) nX3 + nX4 nilon-6,6 + 2nH2O (d) 2X2 + X3 X5 + 2H2O Phn t khi ca X5 l A. 202. B. 198. C. 174. D. 216. Cu 171. (HA-2007) Nilon-6,6 l mt loi A. t axetat B. t poliamit C. t poliester D. t visco Cu 172. (HB-2012) Cho cc cht: caprolactam (1), isopropylbenzen (2), acrilonitrin (3), glyxin (4), vinyl axetat (5). Cc cht c kh nng tham gia phn ng trng hp to polime l A. (3), (4) v (5). B. (1), (2) v (3). C. (1), (3) v (5). D. (1), (2) v (5). Cu 173. (HB-2012) Cc polime thuc loi t nhn to l A. t nilon-6,6 v t capron. B. t visco v t xeluloz axetat. C. t visco v t nilon-6,6. D. t tm v t vinilon. Cu 174. (HB-2007) Cc ng phn ng vi CT C8H10O (u l dn xut ca benzen) c tnh tch nc thu c sn phm c th trng hp to polimer, khng tc dng vi dung dch NaOH. S lng ng phn tha tnh cht trn l A. 1 B. 2 C. 3 D. 4 Cu 175. (HA-2007) Poli(vinyl axetat) l polimer c iu ch bng phn ng trng hp A. C2H5-COO-CH=CH2 B. CH2=CH-COOCH3 C. CH2=CH-COOC2H5 D. CH3-COO-CH=CH2 Cu 176. (C-2011) Cho cc polime : (1) polietilen , (2) poli(metyl metacrylat), (3) polibutaien, (4) polistiren, (5) poli(vinyl axetat) v (6) t nilon-6,6. Trong cc polime trn, cc polime c th b thu phn trong dung dch axit v dung dch kim l: A. (2), (5), (6). B. (1), (2), (5). C. (1), (4), (5). D. (2), (3), (6). Cu 177. (HA-2012) Loi t no sau y c iu ch bng phn ng trng hp? A. T nilon-6,6. B. T visco. C. T nitron. D. T xenluloz axetat. Cu 178. Pht biu no sau y l ng? A. Si bng, t tm thuc loi polime thin nhin. B. T nilon-6,6 c iu ch t hexametyleniamin v axit axetic. C. T visco, t xenluloz axetat u thuc loi t tng hp. D. Polietilen v poli (vinyl clorua) l sn phm ca phn ng trng ngng. Cu 179. (HA-2011) Sn phm hu c ca phn ng no sau y khng dng ch to t tng hp? A. Trng ngng axit e-aminocaproic. B. Trng hp metyl metacrylat. C. Trng hp vinyl xianua. D. Trng ngng hexametyleniamin vi axit aipic. Cu 180. (HB-2011) Cho cc t sau: t xenluloz axetat, t capron, t nitron, t visco, t nilon-6,6. C bao nhiu t thuc loi t poliamit? A. 2 B. 4 C. 3 D. 1

01. C; 02. A; 03. B; 04. C; 05. A; 06. A; 07. B; 08. A; 09. C; 10. C; 11. B; 12. B; 13. A; 14. C; 15. A; 16. D; 17. D; 18. B; 19. C; 20. D; 21. D; 22. B; 23. B; 24. D; 25. D; 26. A; 27. C; 28. D; 29. D; 30. A; 31. A; 32. A; 33. C; 34. C; 35. B; 36. A; 37. D; 38. B; 39. C; 40. C; 41. A; 42. B; 43. C; 44. B; 45. B; 46. A; 47. B; 48. D; 49. A; 50. D; 51. C; 52. A; 53. D; 54. A; 55. C; 56. C; 57. A; 58. D; 59. C; 60. C; 61. D; 62. B; 63. D; 64. D; 65. A; 66. D; 67. B; 68. C; 69. C; 70. A; 71. B; 72. C; 73. A; 74. A; 75. D; 76. C; 77. B; 78. A; 79. D; 80. C; 81. C; 82. D; 83. C; 84. D; 85. C; 86. A; 87. D; 88. D; 89. C; 90. C; 91. B; 92. A; 93. A; 94. B; 95. C; 96. D; 97. C; 98. A; 99. B; 100. A; 101. D; 102. A; 103. D; 104. A; 105. C; 106. B; 107. D; 108. B; 109. C; 110. C; 111. C; 112. D; 113. A; 114. B; 115. C; 116. B; 117. C; 118. A; 119. C; 120. B; 121. D; 122. D; 123. B; 124. A; 125. B; 126. D; 127. A; 128. D; 129. D; 130. D; 131. B; 132. D; 133. B; 134. B; 135. D; 136. A; 137. D; 138. A; 139. C; 140. A; 141. B; 142. A; 143. D; 144. B; 145. A; 146. A; 147. B; 148. B; 149. A; 150. D; 151. D; 152. B; 153. D; 154. A; 155. C; 156. B; 157. B; 158. C; 159. B; 160. D; 161. D; 162. D; 163. B; 164. C; 165. C; 166. C; 167. B; 168. C; 169. B; 170. A; 171. B; 172. C; 173. B; 174. B;
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175. D; 176. A; 177. C; 178. A; 179. B; 180. A;

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