Cu 1: (3 im)

THI TUYN SINH VO LP 10 CHUYN TRNG CHUYN H LONG MN: HO HC (Nm hc 2005 2006, thi gian lm bi 120 pht)

1. Cho cc cht: CaCO3; AgNO3; ZnSO4; Cr(OH)3; MnO2 nhng cht no c th phn ng vi dd HCl ? Vit PTHH. 2. t qung pirit ta thu c kh A, nhit phn mui kali clorat ta thu c kh B, khi lm mt nc ru etylic ta thu c kh C, khi cho axit clohiric tc dng vi mui st ta thu c kh D c mi trng thi. Bit rng A v C u tc dng vi dd Brom. Kh B tc dng vi kh D trong cc iu kin khc nhau ta thu c cc sn phm khc nhau: Trng hp th nht cho ta kh A; trng hp th hai cho ta cht kt ta mu vng C. Hy vit PT phn ng xy ra. Xc nh A, B, C, D, G Cu 2: (2 im) 1. Trn cc bao b phn bn NPK thng k hiu bng nhng ch s nh 25.12.12 hoc 15.10.10. K hiu ny cho ta bit iu g ? T k hiu ny c th tnh c t l hm lng cc nguyn t N, P, K hay khng ? p dng tnh vi trng hp phn bn NPK c k hiu 20.10.10 2. Bng phng php ho hc hy nhn bit cc gi ng cc oxit mt nhn sau: Fe2O3; CuO; MgO; Na2O Cu 3: (1,5 im) C cc cht hu c A, B, D trong CTPT u cha C, H, O Bit A tc dng vi B cho ta cht D c CTPT l C4H8O2, khi oxi ho A di tc dng ca men gim cho ta B A, B u tc dng vi kim loi natri; B tc dng vi dd natri hiroxit nhit thng, cn D tc dng vi dd natri hiroxit khi un nng. Tm CTPT, CTCT ca A, B, D v vit cc PTHH. Cu 4: (1,5 im) Ho tan 4,2g hn hp gm Fe v kim loi R (ha tr II) vo dd HCl thu c 2,24 lt H2 (ktc), Nu khi ha tan 5,5g kim loi R th dng khng ht 500ml dd HCl 1M. Xc nh kim loi R v tnh % khi lng mi kim loi trong hn hp. Cu 5: (2,0 im) Cho 100ml dd A gm axit hu c RCOOH v mui kim loi (ho tr I) d tan trong nc ca axit tc dng vi 60ml dd Ba(OH)2 0,25M, sau phn ng thu c dd B. trung ho Ba(OH)2 d trong B cn cho thm 3,65g dd HCl 15%. Mt khc, khi cho 100ml dd A tc dng vi H2SO4 d, un nng thu c hi axit hu c trn c th tch ng bng th tch ca 1,6g oxi o cng iu kin. Tnh nng mol ca cc cht trong A.

 THI TUYN SINH VO LP 10 CHUYN (TNH NGH AN) MN: HO HC (Nm hc 2003 2004, thi gian lm bi: 150 pht) Cu 1: (3,75 im) Hon thnh cc phng trnh phn ng sau: ACl3 + H2SO4 --> A(kt ta) + B C + KOH --> D + H2O D + HCl + --> C + B + NaOH --> C (kt ta) + Na2SO4 D + H2SO4 --> B + Cu 2: (1,5 im) 1. Vit cc phng trnh phn ng to te khi cho hn hp cc ru CH3OH, C2H5OH qua ng nung nng c H2SO4 c xc tc. 2. T cc cht axit HCl, CaOCl2, NaCl, H2O, KMnO4 v cc iu kin cn thit cho sn, hy vit cc phng trnh phn ng iu ch kh clo khc nhau. Cu 3: (1,5 im) Khi phn tch mt hn hp kh c thnh phn % theo khi lng nh sau: 8% SO2; 9,5% O2 v 82,5% N2. Tnh thnh phn % theo th tch ca hn hp kh . Cu 4: (2,25 im) Hirocacbon CxH2x+2 th kh c th tch 224ml (o ktc) c t chy hon ton. Sn phm sinh ra cho ho tan trong dd Ca(OH)2 (ly d) thu c 1g kt ta. 1. Xc nh CTPT ca hirocacbon 2. Trnh by cch nhn bit hirocacbon ny bng phng php ho hc (c phng trnh phn ng minh ho) Cu 5: (3,5 im) Th nghim 1: Cho mt lng kim loi Mg vo 200ml dd X cha AgNO3 0,15M v Cu(NO3)2 0,01M. Phn ng kt thc thu c 5g cht rn v dd Y Th nghim 2: Cho 0,78g mt kim loi T (ng trc Cu trong dy hot ng ho hc ca kim loi, c ho tr II trong hp cht) cng vo 200ml dd X. Phn ng kt thc thu c 2,592g cht rn v dd Z. 1. Tnh khi lng kim loi M dng 2. Xc mh kim loi T 3. tnh nng Cm ca cc cht trong dd X v Z, coi th tch ca dd khng thay i v th tch ca cht rn l khng ng k. cho bit AgNO3 tham gia phn ng xong th Cu(NO3)2 s tham gia phn ng

Cu 1 : 1 . Mt hn hp gm hai xit : CuO v Fe2O3 . Ch dung thm HCl v bt Al , hy trnh by 3 cch iu ch Cu tinh khit . 2. Ngi ta nhn thy khi t chy cc ng ng ca 1 loai ru th t l s mol CO2: H2O tng dn khi s nguyn t cacbon tng . Hi chng nm dy ng ng no ? ( ru no , ru khng no, rou thm ) Cu 2 : 1 . Dn t t V lit kh CO2 dktc vo 300 ml dung dch cha ng thi Ba(OH)2 0,5M v NaOH 1 M th thu c 19,7g kt ta trng . Tnh th tch V . 2 . Hn hp kh A gm H2 v mt hidrocacbon X mch h c t khi so vi H2 bng 3 .un nng A vi xc tc Ni n khi phn ng xy ra hon ton thu c hn hp B c t khi so vi H2 l 4,5 . Tm cng thc v gi tn X bit X nm trong cc dy ng ng hc . Cu 3: 1.Cho cc dung dch sau : H2SO4 , Na2SO4 , MgSO4 , KCl , BaCl2 . Ch dung thm mt thuc th , nu cch phn bit cc dung dch trn . 2. Ba cht ng phn A , B, C thnh phn cha C, H,O phn t khi 60dvd. Xc nh cng thc phn t , cng thc cu to v vit cc phng trnh phn ng bit rng : tc dng c vi Na c A v C , tc dng vi NaOH c A v B , tham gia phn ng trng gng c B v C . Cu 4 : Ha tan 1,42 g mt hn hp bt gm Mg, Al , Cu trong dung dch HCl va thu c dung dch A v 0,64 g cht rn khng tan . Cho dung dch A tc dng vi 90 ml dung dch NaOH 1M sau nung kt ta ti khi lng khng i thu dc 0,91 g cht rn B . 1 Vit cc PTPU 2. Tnh thnh phn phn trm theo khi lng ca cc kim loi trong hn hp u . Cu 5 : Mt ru n chc X mch h tc dng vi HBr d thu dc cht hu c Y thnh phn cha C , H , Br trong Br chim 69,56% v khi lng.Phn t khi ca Y nh hn 260 dvc . Nu un nng ru X vi H2SO4 c 170 C th n tch H2O to thnh hai hidrocacbon c cc ni i cc v tr hok k nhau . 1 .Xc nh cng thc phn t v CTCT ca X . 2 . Vit phng trnh phn ng tch nc ti hai hidrocacbon ca X v cho bit cht no l sn phm chnh ? Gii thch .

thi tuyn sinh vo khi THPT chuyn HSPHN nm 2008

 THI CHUYN PTNK TPHCM NM 2008 - 2009

Cu 1: Vit cc pt ho hc ca phn ng xy ra, nu c, trong cc qu trnh sau( nu khng c p ghi r khng phn ng) a) Nung hh gm bt Fe v S trong mi trng khng c oxi B) Sc kh clo vo dd NaOH c ngui c) un si k dung dch canxi hidrocacbonat bo ho d) un nhm oxit trong dung dch NaOH Cu 2: Xc nh X v hon thnh cc pt p sau( ch dc thm H2O nu cn) (a)XH3 + MnO2 -> Mn3O4 + XO (b)Ag + HNO3 -> AgNO3 + XO XO + O2 -> XO2 (d) KNO2 + KI + H2SO4 -> I2 + XO + K2SO4 (e)XO2 + C -> CO2 + XO (f) XO + XH3 -> X2 Cu 3: X, Y, Z l 3 ho cht dc dng ph bin lm phn ha hc. Chng l cc phn bn n cung cp 3 thnh phn chnh: m, ln, kali cho cy trng. Ba ho cht trn u tan trong nc. Bit rng: + Dung dch nc ca X cho kt ta mu trng vi dung dch natri cacbonnat d + Khi cho d dung dch natri hidroxit vo dung dch nc ca Y v un si, nhn thy c mi khai bay ra, nhng cho dung dch axit clohidric vo dd Y th khng thy hin tng g xy ra. Dung dch Y cng to kt ta trng vi dung dch bi clorua + Dung dch nc' ca Z to kt ta trng vi dung dch bc nitrat, nhng khng to kt ta vi dung dch bi clorua Xc nh X, Y, Z v vit cc pt m t cc TN trn Cu 4: Dung dch A cha ng thi 2 mui bc nitrat v ng (II) nitrat vi nng mol cu mui ng gp 4 ln nng mol ca mui bc a) Nhng 1 thanh km vo 250 ml dung dch A. Sau 1 tg ly ra ra sch v cn nng thy m thanh km tng 1,51 . Bit rng lc ny dung dch sau p cha 3 mui. Tnh C M ca mui km trong dd sau p B) Nu gi thanh km y trong A 1 thi gian lu th thy sau p dd thu dc ch cha 1 mui duy nht vi nng l 0,54 M. Tnh nng mol cc cht trong dd A ban u c) Trong th nghim cu B), khi lng thanh km thay i bao nhiu so vi khi lng ca thanh km ban u Trong c bi chp nhn lng kim loi sinh ra bm ht vo thanh km v V dd khng thay i trong qu trnh p. Cu 5: Cho chui chuyn ho sau H2O, Al2O3 A ---------------------> B(C2H6O) Al2O3 + ZnO B ---------------------> C(C4H6) A, 600 C C --------------------------> D(C6H10) Pt, 300 C D --------------------> E(C6H6) HNO3, H2SO4 E -----------------------------> F (C6H5NO2) Fe + HCl F ---------------> G (C6H8NCl) NaOH G -------------> H(C6H7N) X CTCT ca cc cht trn v vit li di dng cc pt phn ng. Bit 1 mol D p vi 1 mol Br2 v E khng p vi dd brm

Cu 6: Mt hn hp kh gm hidrocacbon CnH2n v hidro c th tch chung l 3,360 l (dktc) dc cho qua xc tc platin 200 C. Sau mt tg p , th tch hn hp kh l 2,464 l (dktc) tng ng vi lng CnH2n phn ng dc l 80%. Nu cho hn hp kh ban u p vi dung dch nc' brm th m dung dch tng 2,1 g XD thnh phn phn trm v V cc cht trong hh kh u v tm CT ca CnH2n