S GD - T H TNH

TRNG THPT L QUNG CH

( thi c 04 trang)

THI KHO ST CHT LNG LN II NM 2013

Mn: HO HC; Khi A, B
Thi gian lm bi: 90 pht, khng k thi gian pht
Kha ngy 30,31/03/2013

H, tn th sinh:..................................................................................................................................................
S bo danh:..........................................................................................................................................................

MT 132

- Th sinh khng s dng bng HTTH cc nguyn t ha hc

- Cho bit nguyn t khi ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52;
Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137.
Cu 1: Phenol phn ng c vi bao nhiu cht trong s cc cht sau: NaOH, HCl, Br2, (CH3CO)2O,
CH3COOH, Na, NaHCO3, CH3COCl.
A. 4.
B. 6.
C. 5.
D. 7.
Cu 2: - Cho a gam Fe ( d) vo V1 lit Cu(NO3)2 1M thu c m gam rn.
- Cho a gam Fe (d) vo V2 lit AgNO3 1M, sau phn ng thu c m gam rn.
Mi lin h V1 v V2 l:
A. V1 = 2V2
B. V1 = 10V2
C. V1 = V2
D. 10V1 = V2
Cu 3: Cho 8,04 gam hn hp hi gm CH 3CHO v C2H2 tc dng hon ton vi dung dch AgNO 3/NH3
thu c 55,2 gam kt ta. Cho kt ta ny vo dung dch HCl d, sau khi kt thc phn ng cn li m
gam cht khng tan. Gi tr ca m l:
A. 61,78.
B. 41,69.
C. 55,2.
D. 21,6.
Cu 4: Do tc dng dit khun, c bit l vi khun gy thi ra nn dung dch ca hp cht X c
dng ngm xc ng vt, thuc da, ty u X l:
A. Ancol metylic.
B. Ancol etylic.
C. Anehit fomic.
D. Anehit axetic.
Cu 5: Cht hu c X c 1 nhm amino, 1 chc este. Hm lng N c trong X l 15,73%. X phng ho
m gam X thu c hi ancol Z, cho Z qua CuO d thu c andehit Y ( phn ng hon ton), cho Y
phn ng hon ton AgNO3/NH3d thu c 16,2 gam Ag . gi tr m l.
A.7,725.
B. 3,3375.
C. 6,675.
D. 5,625.
Cu 6: Hai cht c dng lm mm nc cng vnh cu l:
A. Na2CO3, HCl.
B. NaCl, Ca(OH)2. C. Na2CO3, Ca(OH)2. D. Na2CO3, Na3PO4.
Cu 7: Hn hp X gm Al, Fe2O3 c khi lng 21,67 gam. Tin hnh phn ng nhit nhm hn hp X
trong iu kin khng c khng kh. Ha tan hon ton hn hp cht rn sau phn ng bng dung dch
NaOH d thu c 2,016 lt H2 (ktc) v 12,4 gam cht rn khng tan. Hiu sut ca phn ng nhit
nhm l:
A. 80%.
B. 75%.
C. 60%.
D. 71,43%.
Cu 8: Hin tng no xy ra trong th nghim sau: Cho 0,1 mol Na vo 100 ml dung dch cha CuSO 4
1M v H2SO4 1M (long).
A. Ch c kh bay ln.
B. C kh bay ln v c kt ta mu xanh.
C. Ch c kt ta.
D. C kh bay ln v c kt ta mu xanh sau kt ta li tan.
Cu 9: Cho 3,76 gam hn hp X gm Mg v MgO c t l mol tng ng l 14:1 tc dng ht vi dung
dch HNO3 th thu c 0,448 lt mt kh duy nht (o ktc) v dung dch Y. C cn cn thn dung dch
Y thu c 23 gam cht rn khan T. Xc nh s mol HNO3 phn ng ?
A. 0,28.
B. 0,34.
C. 0,36.
D. 0,32.
Cu 10: Trong cc cht Xiclopropan, xiclohexan, benzene, stiren, axit axetic, axit acrylic, andehit axetic,
Andehit acrylic, axeton, etyl axetat, vinyl axetat, imetyl ete s cht c kh nng lm mt mu nc brom
l.
A. 5.
B. 7.
C. 6.
D. 4.
Cu 11: Oxi ha anehit X n chc bng O2 (xc tc thch hp) vi hiu sut phn ng l 75% thu c
hn hp Y gm axit cacboxylic tng ng v anehit d. Trung ha axit trong hn hp Y cn 100 ml
dung dch NaOH 0,75M ri c cn dung dch sau phn ng thu c 5,1 gam cht rn khan. Nu cho hn
hp Y tc dng hon ton vi dung dch AgNO3 trong NH3 d, un nng th thu c khi lng Ag l

A. 27,0 gam.
B. 21,6 gam.
C. 5,4 gam.
D. 10,8 gam.
Cu 12: in phn (in cc tr) dung dch NaCl v CuSO4 (t l mol tng ng l 3:1) n khi catot
xut hin bt kh th dng li .sn phm kh thu c Anot l
A. kh Cl2.
B. kh H2 v kh O2. C. kh Cl2v H2.
D. kh Cl2v O2.
Cu 13: Nhit phn hon ton m gam hn hp X gm KNO3 v Fe(NO3)2 . Hn hp kh thu c em
dn vo bnh cha 2 lit H2O th khng thy kh thot ra khi bnh . Dung dich thu c c g tr pH=1 v
ch cha mt cht tan duy nht, coi th tch dung dch khng thay i . gi tr m l
A. 28,1.
B. 23,05.
C.46,1.
D. 38,2.
Cu 14: Nhn nh no sau y khng ng:
A. Hn hp Fe3O4 v Cu c th tan ht trong dung dch HCl.
B. Hn hp Al2O3 v K2O c th tan ht trong nc.
C. Hn hp CuS v FeS c th tan ht trong dung dch HCl d.
D. Hn hp Al v BaO c th tan ht trong nc.
Cu 15: Cho a gam hn hp X gm Fe2O3 v Cu tc dng vi 240 ml dung dch H 2SO4 long 0,5M. Sau
khi phn ng xy ra hon ton, lc thu c 4,48 gam hn hp rn Y dung dch Z. Cho hn hp rn Y tc
dng vi kh CO d thu c 3,52 gam hn hp rn A cha b gam Fe. Cc phn ng xy ra hon ton.
Gi tr ca a v b ln lt l:
A. 10,88 gam v 2,24 gam.
B. 23,68 gam v 1,68 gam.
C. 13,44 gam v 1,68 gam.
D. 13,44 gam v 2,24 gam.
Cu 16: Cho cc dung dch long sau (c cng nng mol): (1) CH 3COONa; (2) ClCH2COONa; (3)
CH3CH2COONa v (4) NaCl. Th t pH tng dn ca cc dung dch trn l:
A. (4)<(3)<(2)<(1). B. (4)<(2)<(3)<(1). C. (1)<(2)<(3)<(4). D. (4)<(2)<(1)<(3).
Cu 17: Nh t t 500 ml dung dch H 2SO4 1M long d vo bnh X cha m gam hn hp gm Fe 3O4 v
Cu (c trn theo t l nol 1:2) khuy u thy hn hp tan dn v cn li 3,84 gam cht rn. Cho tip
dung dch cha NaNO3 t t vo bnh X (sau phn ng ca hn hp X vi H 2SO4) khuy u cho n khi
kh va ngng thot ra thu c V lt kh NO (sn phm kh duy nht). Tnh m v V:
A. 21,6 gam; 2,24 lt.
B. 21,6 gam; 0,896 lt.
C. 10,8 gam; 0,896 lt.
D. 10,8 gam; 1,344 lt.
Cu 18: t chy ht 9,984 gam kim loi M (c ho tr II khng i ) trong hn hp kh Cl2 v O2. Sau
phn ng thu c 20,73 gam cht rn v th tch hn hp kh phn ng l 3,4272 lit (ktc). Kim loi
M l.
A. Ca.
B. Mg.
C. Zn.
D. Cu.
Cu 19: Nhit si ca cc cht CH3Cl, CH3OH, HCOOH, CH4 tng theo th t l:
A. CH3Cl < CH4< CH3OH < HCOOH.
B. CH4 < CH3Cl < CH3OH < HCOOH.
C. CH3Cl < CH3OH < CH4 < HCOOH.
D. CH4 < CH3OH < HCOOH < CH3Cl.
Cu 20: Cht hu c E c cng thc cu to l HCOOCH=CH 2. un nng m gam E sau ly ton b
cc sn phm sinh ra thc hin phn ng trng gng thu c tng khi lng Ag l 108g Ag. Hiro
ha m gam E bng H2 xc tc Ni,t0 va thu c E. t chy ton b lng E ri dn sn phm vo
bnh ng dung dch NaOH d th khi lng bnh tng thm bao nhiu gam?
A. 55,8g.
B. 46,5g.
C. 42g.
D. 48,2g.
Cu 21: Hn hp A gm CH4, C2H4, C3H4. Nu cho 26,8 gam hn hp X tc dng vi dung dch
AgNO3/NH3 d th thu c 29,4 gam kt ta. Nu cho 8,4 lt hn hp X (ktc) tc dng vi dung dch
Brom th thy c 54 gam brom phn ng. Phn trm th tch ca CH4 trong hn hp X l:
A. 40%.
B. 25%.
C. 35%.
D. 30%.
Cu 22: Cho tng cht: C, Fe, BaCl2, Fe3O4, FeCO3, FeS, H2S, HI, AgNO3, HCl, Na2CO3, NaNO3, FeSO4
ln lt tc dng vi H2SO4 c, nng. S phn ng thuc loi oxi ha kh l:
A. 9.
B. 6.
C. 7.
D. 8.
Cu 23: t chy hon ton 2,24 lt (ktc) hn hp kh gm: CH4, C2H4, C2H6, C3H8 thu c 6,16 gam
CO2 v 4,14 gam H2O. S mol C2H4 trong hn hp trn l:
A. 0,08 mol.
B. 0,09 mol.
C. 0,01 mol.
D. 0,03 mol.
Cu 24: Cho hn hp Fe3O4 v Cu vo dung dch HCl d. Sau khi phn ng xy ra hon ton thu c
dung dch X v cht rn Y. Nh vy trong X cha:
A. HCl, FeCl2, FeCl3.
B. HCl, FeCl3, CuCl2.
C. HCl, CuCl2, FeCl2.
D. HCl, CuCl2.

Cu 25: t chy hon ton m gam mt cacbohirat cn 13,44 lt kh O2 (ktc) sau em hp th hon
ton sn phm chy trong 200 ml dung dch cha ng thi NaOH 1,75M v Ba(OH)2 1M thu c kt
ta c khi lng l:
A. 39,4 gam.
B. 9,85 gam.
C. 19,7 gam.
D. 29,55 gam.
Cu 26: C bao nhiu cht c th phn ng vi axit fomic trong s cc cht sau: KOH, NH3, CaO, Mg,
Cu, Na2CO3, Na2SO4, CH3OH, C6H5OH, dd Br2, AgNO3/NH3?
A. 8.
B. 9.
C. 7.
D. 6.
3+
2+
+
2Cu 27: Dung dch Y gm Al ; Fe ; 0,05 mol Na ; 0,1 mol SO4 ; 0,015 mol Cl-. Cho V lt dung dch
NaOH 1M vo dung dch Y thu c kt ta ln nht th gi tr ca V l:
A. 0,30.
B. 0,25.
C. 0,40.
D. 0,35.
Cu 28: Cho x gam P2O5 tc dng ht vi 388 ml dung dch NaOH. C cn dung dch sau phn ng thu
c 3x gam cht rn. Gi tr ca x l:
A. 14,2.
B. 12,78.
C. 11,36.
D. 17,04.
Cu 29: Hn hp kh X gm SO2 v O2 c t khi so vi H2 l 24. Cho hn hp X (ktc) i qua bnh cha
V2O5 nung nng. Hn hp thu c sau phn ng c t khi so vi H2 l 30. Hiu sut ca phn ng gia
SO2 v O2 l:
A. 20%.
B. 60%.
C. 40%.
D. 80%.
Cu 30: t chy hon ton m gam hn hp X gm ancol etylic, axetanehit, metyl fomat thu c 0,1
mol CO2 v 0,13 mol H2O. Cho m gam X trn vo mt lng d dung dch AgNO3/NH3 thu c a gam
kt ta. Gi tr ca a l:
A. 4,32.
B. 1,08.
C. 10,08.
D. 2.16.
Cu 31: Xt phn ng thun nghch sau:
SO2(k) + NO2(k) SO3(k) + NO(k).
Cho 0,11 mol SO2; 0,1 mol NO2; 0,07 mol SO3 vo bnh kn dung tch 1 lt. Khi t trng thi cn
bng th cn li 0,02 mol NO2. Vy hng s cn bng KC l:
A. 23,00.
B. 20,00.
C. 18,00.
D. 0,05.
Cu 32: X l mt pentapeptit mch h. Thy phn hon ton X ch thu c 1 aminoaxit no Y, mch h,
c mt nhm amino v mt nhm cacboxyl (tng % khi lng ca O v N trong Y l 51,685%). Khi
thy phn ht m gam X trong mi trng axit thu c 30,2 gam tetrapeptit; 30,03 gam tripeptit; 25,6
gam ipeptit v 88,11 gam Y. Gi tr ca m l:
A. 156,66.
B. 167,85.
C. 141,74.
D. 186,90.
Cu 33: Tng s proton trong ht nhn nguyn t X v Y l 25. Y thuc nhm VIIA. dng n gin
n cht X tc dng vi Y. khng nh no sau y ng?
A. X l kim loi, Y l phi kim.
B. trng thi c bn X c 2 electron c thn.
B. Cng thc oxit cao nht ca X l XO3. C. Cng thc oxit cao nht ca X l Y2O.
Cu 34: Cho phn ng CO(k) + H2O(k) CO2 (k) + H2 (k) + H <0
Trong cc yu t (1) Tng nhit , (2) thm lng CO, (3) thm mt lng H 2, (4) gim p sut chung
ca h, (5) dung cht xc tc. S yu t lm thay i cn bng l.
A. 2.
B. 4.
C. 3.
D. 5.
Cu 35: Ho tan ht m gam Al2(SO4)3 vo nc c dung dch X. Cho 360 ml dung dch NaOH 1M vo
dung dch X, thu c 2a gam kt ta. Mt khc, nu cho 400 ml dung dch NaOH 1M vo dung dch th
thu c a gam kt ta. Cc phn ng xy ra hon ton, gi tr ca m l:
A. 20,52.
B. 19,55.
C. 15,39.
D. 18,81.
Cu 36: Cc nguyn t thuc nhm IA, theo chiu tng dn ca in tch ht nhn th:
A. Bn knh nguyn t tng dn.
B. Nng lng ion ho tng dn.
C. Tnh kh gim dn.
D. m in tng dn.
Cu 37: Cho hn hp X gm 2 amin n chc l ng ng k tip nhau tc dng va vi dung dch
HCl thu c 14,2 gam hn hp mui. Cho hn hp mui vo dung dch AgNO3 d thu c 28,7
gam kt ta. Hy cho bit cng thc phn t ca cc cht trong hn hp X l:
A. C2H7N, C3H9N
B. C3H9N, C4H11N
C. CH5N, C2H7N
D. C4H11N, C5H13N
Cu 38: Dy gm cc kim loi u tc dng vi dung dch Fe(NO3)3 l:
A. Cu,Ag,Au,Mg.
B. Fe,Mg,Cu,Ag,Al. C. Fe,Zn,Cu,Al,Mg. D. Au,Cu,Al,Mg,Zn.
Cu 39: Fructoz v saccaroz u c:
A. phn ng trng bc.
B. 5 nhm hiroxyl trong phn t.
C. phn ng kh brom trong dung dch nc.
D. phn ng ha tan Cu(OH)2 nhit thng.

Cu 40: Cho m gam anilin tc dng vi 150ml dung dch HCl 1M thu c hn hp X c cha 0,05 mol
anilin. Hn hp X ny tc dng va vi V ml dung dich NaOH 1M. Gi tr ca m v V ln lt l:
A. 9,3 v 300.
B. 18,6 v 150.
C.18,6 v 300.
D. 9,3 v 150.
Cu 41: Dy gm cc kim loi u tc dng vi nc nhit thng to ra cc mi trng kim l:
A. Li, K, Ca.
B. Zn, Na, Ba.
C. Fe, K, Ba.
D. Be, Na, Ca.
Cu 42: Cho Na tc dng vi 100ml dd AlCl 3 thu c 5,6 lt H2(ktc) v kt ta . Lc kt ta ri em
nung n khi lng khng i thu c 5,1 gam cht rn. Nng mol/l ca dd AlCl3 l:
A. 1,5M.
B. 2,5M.
C. 2,0M.
D. 1,0M.
Cu 43: Cho cc hp cht: amoniac; p nitroanilin; p aminotoluen; metylamin; imetylamin. Dy no
trong cc dy sau c sp xp theo th t tng dn tnh baz?
A. p O2N-C6H4-NH2 < C6H5-NH2 < p CH3-C6H4-NH2 < NH3 < (CH3)2NH < CH3-NH2
B. C6H5-NH2 < p O2N-C6H4-NH2 < p CH3-C6H4-NH2 < NH3 < CH3-NH2 < (CH3)2NH
C. (CH3)2NH < CH3-NH2 < NH3 < p CH3-C6H4-NH2 < C6H5-NH2 < p O2N-C6H4-NH2
D. p O2N-C6H4-NH2 < C6H5-NH2 < p CH3-C6H4-NH2 < NH3 < CH3-NH2 < (CH3)2NH
Cu 44: Cho dung dich NH3 d ln lt vo tng dung dch FeCl 3, AgNO3, NaCl, Cu(NO3)2. S trng
hp thu c kt ta sau phan ng la:
A. 1.
B. 4.
C. 3.
D. 2.
Cu 45: Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na 2O v Al2O3; Cu v
FeCl3; BaCl2 v CuSO4; Ba v NaHCO3. S hn hp c th tan hon ton trong nc (d) ch to ra dung
dch l:
A. 4.
B. 1.
C. 3.
D. 2
Cu 46: t chy hon ton hn hp gm 2 este no h n chc cn 5,68 g kh oxi v thu c 3,248 lt
kh CO2 (ktc). Cho hn hp este trn tc dng va vi KOH thu c 2 ru l ng ng k tip v
3,92 g mui ca mt axit hu c. Cng thc cu to ca 2 este l :
A. HCOOCH3 v HCOOC2H5.
B. C3H7COOCH3 v CH3COOC2H5.
C. CH3COOCH3 v CH3COOC2H5.
D. C2H5COOCH3 v C2H5COOC2H5.
Cu 47: Thc th cn dng phn bit ancol etylic nguyn cht v cn 960 l
A. HCl.
B. Cu(OH)2.
C. Na.
D. CuSO4.
Cu 48: Cho 7,68g hn hp gm FeO, Fe 3O4 v Fe2O3 tc dng va ht vi 260ml dung dch HCl 1M thu
c dung dch X. Cho X tc dng vi dung dch NaOH d, lc kt ta, nung trong khng kh n khi
lng khng i thu c m gam cht rn, gi tr ca m l:
A. 8g.
B. 12g.
C. 16g.
D. 24g.

Cu 49: Trong dy bin ha: C2H6

C2H5Cl
C2H5OH
CH3CHO
CH3COOH
CH3COOC2H5 C2H5OH C2H5OC2H5. S phn ng oxi ha- kh trn dy bin ha trn l
A. 3.
B. 4.
C. 5.
D. 2.
Cu 50: Trong phng th nghim, hirohalogenua (HX) c iu ch t phn ng sau:
NaX(rn) + H2SO4 (c, nng) NaHSO4 (hoc Na2SO4) + HX (kh).
Hy cho bit phng php trn c th dng iu ch c hirohalogenua no sau y ?
A. HBr v HI.
B. HF v HCl.
C. HCl, HBr v HI.
D. HF, HCl, HBr, HI.
------------------------ HT---------------------(Cn b coi thi khng gii thch g thm)