Ngun: Diemthi.24h.com.vn THI TH I HC MN: HA HC (Thi gian lm bi: 90 pht; 50 cu trc nghim) H v tn .................................................................. S bo danh ..........................

. M thi 133 Cho khi lng nguyn t ca cc nguyn t (theo vC): C = 12; H = 1; O = 16; S = 32; Cu = 64; Fe = 56; Al = 27; N = 14; Ca = 40; Ba = 137; Na = 23; Mg = 24; Cl = 35,5; Zn = 65; K = 39; Ag = 108; Br = 80; Be = 9; P = 31; Se = 79. A. PHN CHUNG CHO TT C TH SINH (40 cu: T cu 1 n cu 40) Cu 1: Vi cng thc phn t C3H6Cl2 th c bao nhiu cht khi tc dng vi dung dch NaOH d, un nng, cho sn phm c phn ng vi Cu(OH)2 iu kin thch hp? A. 3. B. 1. C. 2. D. 4. Cu 2: Cho hi nc i qua than nng thu c 0,8 mol hn hp kh X gm CO, CO2 v H2. Cho ton b X phn ng ht vi CuO d, un nng thu c hn hp cht rn Y. Ha tan ht Y bng dung dch HNO3 long, d thu c 0,4 mol kh NO (sn phm kh duy nht). T khi ca X so vi H2 l A. 7,875. B. 10,0. C. 3,9375. D. 8,0. Cu 3: Trong cc cht sau: cumen, vinylbenzen, vinylaxetilen, axit fomic, phenol, axit acrylic, isopren. C bao nhiu hirocacbon c th lm mt mu nc brom? A. 6. B. 5. C. 4. D. 3. Cu 4: Hp cht hu c X c cng thc phn t C6H9O4Cl. Bit rng: X + NaOH d Mui ca axit X1 + X2 + X3 + NaCl (X2, X3 l cc ancol c cng s nguyn t C). Khi lng phn t (vC) ca X1 l im thi 24h Xem tra im thi tt nghip THPT thi tt nghip trung hc ph thng cc nm

thi p n tt nghip THPT Xem tra p n thi tt nghip THPT

Ngun: Diemthi.24h.com.vn A. 134. B. 90. C. 143. D. 112. Cu 5: Cho cn bng sau xy ra trong bnh kn c dung tch khng i: 2SO2 (k) + O2 (k) t n v v 2SO3 (k) ; H 0 Yu t no sau y lm cho cn bng trn dch chuyn theo chiu nghch v tc phn ng thun tng? A. Gim nhit ca h phn ng. B. Thm cht xc tc phn ng. C. Thm SO3 vo h phn ng. D. Tng p sut. Cu 6: Cho 18,75 gam Al2S3 vo 600 ml dung dch NaOH 2M, sau khi cc phn ng kt thc, khng c kh thot ra th s mol ca NaOH cn li l A. 0,20. B. 0,05. C. 0,75. D. 0,45. Cu 7: Thy phn mt loi cht bo thu c axit panmitic, axit linoleic v axit oleic. Ch s iot (s gam iot c th cng vo lin kt bi trong mch cacbon ca 100 gam cht bo) ca loi cht bo trn l A. 89,0. B. 54,0. C. 44,5. D. 53,3. Cu 8: Cho cc th nghim sau: (1) Sc O3 vo dung dch KI. (2) Nhit phn KMnO4. (3) Nhit phn NaHCO3. (4) Cho H2O2 vo dung dch KMnO4 trong H2SO4 long. (5) in phn NaOH nng chy. (6) Nhit phn KClO3 c xc tc MnO2. C bao nhiu th nghim to ra sn phm c O2? A. 4. B. 3. C. 5. D. 6. Cu 9: Thc hin phn ng nhit nhm (trong iu kin khng c khng kh) hn hp X gm Al v Fe3O4 sau mt thi im thi 24h Xem tra im thi tt nghip THPT thi tt nghip trung hc ph thng cc nm

thi p n tt nghip THPT Xem tra p n thi tt nghip THPT

Ngun: Diemthi.24h.com.vn gian thu c m gam hn hp Y. Chia Y thnh hai phn bng nhau. Phn 1 tc dng va vi 100 ml dung dch NaOH 0,5M. Phn 2 tc dng ht vi dung dch HNO3 c nng, d thu c 3,696 lt kh NO2 ( ktc, sn phm kh duy nht). Gi tr ca m l A. 4,83. B. 8,46. C. 9,66. D. 19,32. Cu 10: Ha tan Fe3O4 trong dung dch H2SO4 long, d thu c dung dch X. Dung dch X tc dng c vi bao nhiu cht trong cc cht sau: Br2, H2S, K2Cr2O7, NaNO3, BaCl2, NaOH, KI? A. 6. B. 7. C. 5. D. 4. Cu 11: Cho (x + 1,5y) mol Ba(OH)2 vo dung dch cha x mol NH4 , y mol 2 Ba v z mol HCO3 . Sau khi cc phn ng kt thc, un nng nh th dung dch thu c cha A. Ba(HCO3)2 v NH4HCO3. B. (NH4)2CO3. C. Ba(HCO3)2. D. Ba(OH)2. Cu 12: Oxi ha 26,6 gam hn hp X gm mt ancol n chc v mt anehit n chc, thu c mt axit hu c duy nht (hiu sut phn ng l 100%). Cho ton b lng axit ny tc dng vi 100 gam dung dch cha NaOH 4% v Na2CO3 26,5% th thu c dung dch ch cha mt mui ca axit hu c. Phn trm khi lng ca ancol trong X l A. 13,53%. B. 86,47%. C. 82,71%. D. 17,29%.

im thi 24h Xem tra im thi tt nghip THPT thi tt nghip trung hc ph thng cc nm

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Ngun: Diemthi.24h.com.vn Cu 13: Cho cc loi t sau: nilon-6, enang, visco, lapsan, olon, nilon-6,6. C bao nhiu t thuc loi t poliamit? A. 5. B. 3. C. 4. D. 2. Cu 14: Ha tr cao nht trong hp cht vi oxi ca nguyn t R gp 3 ln ha tr ca n trong hp cht kh vi hiro. Phn trm khi lng ca R trong hp cht kh vi hiro nhiu hn trong hp cht c ha tr cao nht vi oxi l 54,11%. Nguyn t R l A. Se. B. P. C. Cl. D. S.Trang 2/5 - M thi 133 Cu 15: Cho s phn ng: P + NH4ClO4 H3PO4 + Cl2 + N2 + H2O Sau khi lp phng trnh ha hc, ta c tng s nguyn t b oxi ha v tng s nguyn t b kh ln lt l A. 8 v 5. B. 10 v 18. C. 18 v 10. D. 5 v 8. Cu 16: Thy phn hon ton m gam tetrapeptit X mch h thu c hn hp Y gm 2 amino axit (no, phn t cha 1 nhm COOH v 1 nhm NH2) l ng ng k tip. t chy hon ton hn hp Y cn va 4,5 mol khng kh (cha 20% O2 v th tch, cn li l N2) thu c CO2, H2O v 82,88 lt kh N2 ( ktc). S cng thc cu to tha mn ca X l A. 8. B. 4. C. 12. D. 6. Cu 17: trng thi c bn: - Phn lp electron ngoi cng ca nguyn t nguyn t X l np2n+1 . - Tng s electron trn cc phn lp p ca nguyn t nguyn t Y l 7. - S ht mang in trong nguyn t nguyn t Z nhiu hn s ht mang in trong nguyn t nguyn t X l 20 ht. Nhn xt no sau y l sai? A. Nguyn t X v Y thuc 2 chu k k tip. B. S oxi ha cao nht ca X trong hp cht l +7. im thi 24h Xem tra im thi tt nghip THPT thi tt nghip trung hc ph thng cc nm thi p n tt nghip THPT Xem tra p n thi tt nghip THPT

Ngun: Diemthi.24h.com.vn C. Oxit v hiroxit ca Y c tnh lng tnh. D. m in gim dn theo th t X, Y, Z. Cu 18: Tin hnh in phn (vi in cc tr, hiu sut l 100%) dung dch X cha 0,02 mol CuCl2; 0,02 mol CuSO4 v 0,005 mol H2SO4 trong thi gian 32 pht 10 giy vi cng dng in khng i l 2,5 ampe th thu c 200 ml dung dch Y. Gi tr pH ca dung dch Y l A. 1,08. B. 1,00. C. 0,70. D. 1,78. Cu 19: Cho m gam hn hp kim loi gm Al, Mg, Zn phn ng ht vi dung dch H2SO4 long, d th thu c dung dch X cha 61,4 gam mui sunfat v 5m/67 gam kh H2. Gi tr ca m l A. 20,10. B. 13,40. C. 10,72. D. 17,42. Cu 20: Amin X khi tc dng vi dung dch HCl d thu c mui dng CnHm(NH3Cl)2. t chy 0,1 mol X bng mt lng oxi d, ri cho hn hp sau phn ng (gm CO2, H2O, N2 v O2 d) li chm qua nc vi trong d thy khi lng dung dch sau phn ng gim 7,8 gam so vi khi lng nc vi trong ban u v thu c 30 gam kt ta. S cng thc cu to tha mn iu kin trn ca X l A. 4. B. 2. C. 3. D. 1. Cu 21: Khi cho cng mt lng hp cht hu c X tc dng vi Na d v vi NaHCO3 d th s mol kh H2 thu c nhiu gp 2 ln s mol CO2. Cng thc no sau y l cng thc phn t ca X? A. C8H16O4. B. C7H16O4. C. C8H16O5. D. C6H14O5. Cu 22: Cho 39,6 gam hn hp gm K2CO3 v KHSO3 vo 147 gam dung dch H2SO4 20%, un nng n khi kt thc cc phn ng thu c dung dch X. Dung dch X cha cc cht tan l A. K2SO4, KHSO3. B. K2SO4, KHSO3, KHSO4. im thi 24h Xem tra im thi tt nghip THPT thi tt nghip trung hc ph thng cc nm thi p n tt nghip THPT Xem tra p n thi tt nghip THPT

Ngun: Diemthi.24h.com.vn C. K2SO4. D. K2SO4 v H2SO4. Cu 23: Cho cc pht biu sau: (1) t chy hon ton este X thu c s mol CO2 bng s mol H2O th X l este no, mch h, n chc. (2) Glucoz, mantoz, saccaroz u c c cu to dng mch h v dng mch vng. (3) X phng v cht git ra tng hp u khng to kt ta vi nc cng. (4) Phenol v anilin u d phn ng vi nc brom do nh hng ca gc hirocacbon n nhm chc. S pht biu ng l A. 2. B. 1. C. 4. D. 3. Cu 24: Cho 3,834 gam mt kim loi M vo 360 ml dung dch HCl, lm kh hn hp sau phn ng thu c 16,614 gam cht rn khan. Thm tip 240 ml dung dch HCl trn vo ri lm kh hn hp sau phn ng th thu c 18,957 gam cht rn khan. Bit cc phn ng xy ra hon ton, b qua s thy phn ca cc ion trong dung dch. Kim loi M l A. Mg. B. Be. C. Al. D. Ca. Cu 25: Chia m gam hn hp X gm mt ancol v mt axit thnh 3 phn bng nhau. Phn 1 tc dng ht vi Na d thu c 0,15 mol H2. t chy hon ton phn 2 thu c 0,9 mol CO2. un phn 3 vi dung dch H2SO4 c th thu c este Y c cng thc phn t C5H10O2 khng c kh nng tham gia phn ng trng bc. Gi tr ca m l A. 62,4. B. 72,0. C. 58,2 D. 20,8. Cu 26: Hn hp X gm SO2 v O2 c t khi so vi H2 bng 28. Nung nng hn hp X mt thi gian (c xc tc V2O5) thu c hn hp Y c t khi so vi X bng 16/13. Hiu sut ca phn ng tng hp SO3 l A. 60,0%. B. 50,0%. C. 62,5%. D. 75,0%. im thi 24h Xem tra im thi tt nghip THPT thi tt nghip trung hc ph thng cc nm

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Ngun: Diemthi.24h.com.vn Cu 27: Cho hn hp hai axit cacboxylic hai chc tc dng vi dung dch NaOH va thu c dung dch cha m gam hn hp mui. Cho ton b lng mui thu c tc dng ht vi NaOH d c mt CaO un nng thu c cht rn X v hn hp hirocacbon Y c t khi so vi H2 bng 18,5. Cho ton b cht rn X tc dng vi dung dch H2SO4 long, d thu c 0,4 mol CO2. Gi tr m l A. 33,8. B. 61,8. C. 25,0. D. 32,4. Cu 28: Cho cc hn hp bt, mi hn hp gm hai cht c s mol bng nhau: Ba v Al2O3; Cu v Fe3O4; NaCl v KHSO4; Fe(NO3)2 v AgNO3. S hn hp khi ha tan vo nc rt d ch thu c dung dch l A. 3. B. 4. C. 1. D. 2. Cu 29: Cho cc cht sau: Cr2O3, Al, CH3COONH4, (NH4)2CO3, Na2HPO3, H2NCH2COOH, KHCO3, Pb(OH)2. C bao nhiu cht l cht lng tnh?Trang 3/5 - M thi 133 A. 8. B. 6. C. 7. D. 5. Cu 30: Cho cc pht biu sau: (1) Vi cng thc phn t C2H2O3 c hai hp cht hu c mch h c th tham gia phn ng trng bc. (2) Cng thc phn t C3H5Cl c 4 ng phn cu to. (3) Vi cng thc phn t C4H10O2 c 3 ancol ng phn c th ha tan Cu(OH)2. (4) Tinh bt v xenluloz l ng phn ca nhau. S pht biu ng l A. 3. B. 2. C. 1. D. 4. Cu 31: Trong cc cht sau: CuSO4, S, SO2, H2S, Fe2(SO4)3, SO3. C bao nhiu cht c th to ra H2SO4 bng mt phn ng? A. 2. B. 5. C. 6. D. 4. im thi 24h Xem tra im thi tt nghip THPT thi tt nghip trung hc ph thng cc nm thi p n tt nghip THPT Xem tra p n thi tt nghip THPT

Ngun: Diemthi.24h.com.vn Cu 32: t chy hon ton m gam hn hp T gm 3 ancol thu c x mol CO2 v y mol H2O. Mt khc cho m/2 gam hn hp T tc dng vi Na d thu c z mol H2. Mi lin h gia m, x, y, z l A. m = 12x + y + 64z. B. m = 24x + 2y + 64z. C. m = 12x + 2y +32z. D. m = 12x + 2y + 64z. Cu 33: Cho cc cht: ancol etylic, axit axetic, phenol, etylamin, trimetylamin, tristearin. C bao nhiu cht c th to lin kt hiro gia cc phn t ca n? A. 4. B. 6. C. 3. D. 5. Cu 34: t chy hon ton m gam qung pirit st (cha 80% FeS2 v khi lng, cn li l tp cht tr) bng mt lng oxi d. Ly ton b lng SO2 thu c cho hp th ht vo 100 ml dung dch cha Ba(OH)2 1,5M v NaOH 1M th thu c 26,04 gam kt ta. Gi tr ln nht ca m l A. 13,44. B. 18,00. C. 16,80. D. 21,00. Cu 35: Cho 28,8 gam hn hp X gm propinal, glucoz, fructoz tc dng vi lng d dung dch AgNO3 trong NH3 th thu c 103,6 gam cht rn. Phn trm khi lng ca propinal trong X l A. 37,5%. B. 40,0%. C. 42,5%. D. 85,6%. Cu 36: Thc hin phn ng tch 15,9 gam hn hp gm butan v pentan (c t l mol tng ng l 3 : 2) iu kin thch hp thu c hn hp X gm cc hirocacbon mch h v hiro c t khi so vi H2 bng 15. X phn ng ti a vi bao nhiu gam brom trong CCl4? A. 40,0 gam. B. 44,8 gam. C. 56,0 gam. D. 84,8 gam. Cu 37: Cho m kg mt loi qung apatit (cha 93% khi lng Ca3(PO4)2, cn li l tp cht tr khng cha photpho)

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Ngun: Diemthi.24h.com.vn tc dng va vi dung dch H2SO4 c sn xut supephotphat n. dinh dng ca supephotphat thu c sau khi lm kh hn hp sau phn ng l A. 26,83%. B. 42,60%. C. 53,62%. D. 34,20%. Cu 38: un nng hn hp tt c cc ancol c cng thc phn t C2H6O, C3H8O vi dung dch H2SO4 c iu kin thch hp, thu c hn hp X ch gm ete v anken. X cha ti a bao nhiu hp cht? A. 6. B. 3. C. 8. D. 5. Cu 39: Ha tan hn hp X gm CuSO4 v Fe2(SO4)3 vo nc c dung dch Y. Cho Fe d vo dung dch Y n khi cc phn ng kt thc thu c dung dch Z c khi lng bng khi lng dung dch Y (b qua s thy phn ca cc ion trong dung dch v s bay hi ca nc). Phn trm khi lng ca CuSO4 trong X l A. 26,32%. B. 73,68%. C. 63,20%. D. 5,40%. Cu 40: Khi thy phn pentapeptit X (Gly-Ala-Val-Ala-Gly) th thu c ti a bao nhiu sn phm cha gc glyxyl m dung dch ca n c phn ng mu biure? A. 9. B. 5. C. 4. D. 2. B. PHN RING: Th sinh ch c chn lm 1 trong 2 phn (Phn I hoc Phn II) Phn I. Theo chng trnh Chun (10 cu: T cu 41 n cu 50) Cu 41: t chy hon ton mt ete c to bi 2 ancol n chc X, Y (Y mch nhnh) ri cho sn phm chy hp th ht vo nc vi trong d th thu c 20 gam kt ta v khi lng dung dch sau phn ng gim 6,88 gam so vi khi lng nc vi trong ban u. Khi lng phn t ca X (vC) l A. 74. B. 46. C. 32. D. 58. Cu 42: t chy hon ton m gam hn hp X gm hai ancol hai chc thuc cng dy ng ng, thu c 39,6 gam im thi 24h Xem tra im thi tt nghip THPT thi tt nghip trung hc ph thng cc nm thi p n tt nghip THPT Xem tra p n thi tt nghip THPT

Ngun: Diemthi.24h.com.vn CO2 v 18,9 gam H2O. Nu khi cho m gam X tc dng va vi Na th thu c bao nhiu gam cht rn? A. 24,3 gam. B. 24,6 gam. C. 25,9 gam. D. 32,9 gam. Cu 43: Cht no trong cc cht sau y m phn t lun c 9 lin kt xch ma? A. C3H8O3. B. C3H6. C. C2H4O2. D. C2H7N. Cu 44: Ha cht thng c dng khc ch ln thy tinh l A. CaF2 v dung dch H2SO4 c. B. dung dch H2SO4 c. C. NaOH nng chy. D.Na3AlF6. Cu 45: Hn hp X gm axit oxalic, axetilen, propanial v vinyl fomat (trong s mol ca axit oxalic v axetilen bng nhau). t chy hon ton m gam hn hp X cn dng va 1,125 mol O2, thu c H2O v 55 gam CO2. Nu cho m gam hn hp X tc dng vi dung dch NaHCO3 d th thu c ti a bao nhiu lt CO2 ( ktc)? A. 2,8 lt. B. 5,6 lt. C. 8,6 lt. D. 11,2 lt.Trang 4/5 - M thi 133 Cu 46: Trong cc cht sau: tristearin, benzyl fomat, etyl clorua, tinh bt, anbumin, cao su buna. S cht km bn trong c mi trng axit v baz l A. 3. B. 2. C. 5. D. 4. Cu 47: Nhm kim loi no sau y m iu ch chng th ch c th dng phng php in phn nng chy? A. Zn, Cu, Cr, Fe. B. Fe, Al, Ca, Cu. C. Na, Al, Ca, Mg. D. Na, Zn, Mg, Al. Cu 48: Pht biu no sau y sai? A. Trong y khoa, ozon c dng cha su rng. B. Kh sunfur va c tnh oxi ha va c tnh kh. C. Lu hunh tc dng c vi thy ngn nhit thng. D. H2S ch th hin tnh kh khi tham gia phn ng ha hc.

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Ngun: Diemthi.24h.com.vn Cu 49: Nung m gam hn hp X gm bt st v lu hunh thu c hn hp Y gm FeS, Fe, S. Chia Y thnh 2 phn bng nhau. Cho phn 1 tc dng vi dung dch H2SO4 long, d thy thot ra 2,8 lt hn hp kh ( ktc). Cho phn 2 tc dng ht vi lng d dung dch HNO3 c, nng thy thot ra 16,464 lt kh ch c NO2 ( ktc, sn phm kh duy nht). Gi tr m l A. 14,00. B. 17,84. C. 8,92. D. 7,00. Cu50: Cho s chuyn ha: 222 000 3 0HOOX Pd/PbCO ,t 1500 C 4 xt,t xt t, CH X Y Z T M Bit X, Y, Z, T, M l cc hp cht hu c. Cc cht Z, M ln lt l A. CH3CHO v CH3COOC2H3. B. CH3CHO v C2H3COOC2H3. C. C2H2 v CH3COOH. D. C2H5OH v CH3COOC2H3. Phn II. Theo chng trnh Nng cao (10 cu: T cu 51 n cu 60) Cu 51: Nhn xt no sau y l sai v enzim? A. Hot ng xc tc ca enzim c tnh chn lc cao. B. Cc enzim hu ht c bn cht l protein. C. Tc phn ng nh xc tc enzim thng rt ln. D. L polieste ca axit photphoric v pentoz. Cu 52: Nhn xt no sau y l sai? im thi 24h Xem tra im thi tt nghip THPT thi tt nghip trung hc ph thng cc nm thi p n tt nghip THPT Xem tra p n thi tt nghip THPT

Ngun: Diemthi.24h.com.vn A. Trong pin in ha, anot l cc m cn catot l cc dng. B. Sut in ng ca pin in ha lun c gi tr dng. C. in cc hiro lun c th in cc bng 0,00 V. D. Khi pin in ha hot ng, cation cu mui chuyn dch v cc dng. Cu 53: Cho dy axit sau: HClO, HClO2, HClO3, HClO4. Theo chiu t tri sang phi th A. tnh axit gim, bn phn t tng, tnh oxi ha tng. B. tnh axit tng, bn phn t gim, tnh oxi ha tng. C. tnh axit tng, bn phn t gim, tnh oxi ha gim. D. tnh axit tng, bn phn t tng, tnh oxi ha gim. Cu 54: Cho cc cht: H2S, Na2CO3, Cu, KI, Ag, SO2, Mg. C bao nhiu cht tc dng c vi dung dch Fe2(SO4)3 d cho sn phm c FeSO4? A. 4. B. 5. C. 2. D. 3. Cu 55: Nhn xt no sau y l sai? A. Khi tch H2CrO4 v H2Cr2O7 ra khi dung dch th chng s b phn hy thnh CrO3. B. Cc oxit v hiroxit ca crom u l cht lng tnh. C. Cho dung dch H2SO4 vo dung dch K2CrO4 th dung dch thu c c mu da cam. D. Cho CrCl3 vo dung dch cha NaOH d v Br2 thu c dung dch c mu vng. Cu 56: Cht no trong cc cht sau m trong phn t khng c lin kt 1, 4 glicozit ? A. Xenluloz. B. Amiloz. C. Mantoz. D. Amilopectin. Cu 57: Cho 16,75 gam hn hp X gm FeCl3, CuCl2 vo dung dch H2S d, sau khi phn ng xy ra hon ton thu c 9,92 gam cht rn (b qua s thy phn ca cc ion kim loi). T hn hp X c th iu ch c ti a bao nhiu gam kim loi? A. 9,23 gam. B. 7,52 gam. C. 6,97 gam. D. 5,07 gam.

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Ngun: Diemthi.24h.com.vn Cu 58: Thy phn hon ton 0,15 mol mt este X cn dng va 100 gam dung dch NaOH 18%, thu c mt ancol v 36,9 gam hn hp mui ca hai axit cacboxylic n chc. Cng thc phn t ca hai axit l A. HCOOH v C2H5COOH. B. C2H5COOH v C3H7COOH. C. HCOOH v C3H7COOH. D. CH3COOH v C2H5COOH. Cu 59: t chy hon ton hn hp hai ancol no, mch h X, Y (phn t Y nhiu hn phn t X mt nguyn t cacbon) cn dng va 1,05 mol O2, thu c 0,75 mol CO2 v 18,9 gam H2O. C bao nhiu cp X, Y tha mn iu kin trn? A. 4. B. 3. C. 2. D. 1. Cu 60: thu c 500 ml dung dch c pH bng 5 cn phi ha tan bao nhiu gam NH4Cl vo nc, bit hng s phn li 250C ca NH4 l Ka = 10-9,24 ?Trang 5/5 - M thi 133 A. 3,32 gam. B. 4,64 gam. C. 2,32 gam. D. 2,14 gam. n -----------------------------------------------\ ----------- HT ----------

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