TRNG I HC KHTN Trng THPT Chuyn KHTN

BI KIM TRA KIN THC LP 12 NM HC 2012 -2013 MN HA HC - Thi gian lm bi: 90 pht

M thi: 147 147c 15,68 lt kh Cu 1: t chy hon ton m gam hn hp X gm hai ancol n chc, cng dy ng ng, thu CO2 (ktc) v 17,1 gam nc. Mt khc, thc hin phn ng este ho m gam X vi 15,6 gam axit axetic, thu c a gam este. Bit hiu sut phn ng este ho ca hai ancol u bng 60%. Gi tr ca a l A. 25,79. B. 15,48. C. 24,80. D. 14,88. Cu 2: Hai cht c dng lm mm nc cng vnh cu l: A. Na2CO3 v HCl. B. NaCl v Ca(OH)2. C. Na2CO3 v Ca(OH)2. D. Na2CO3 v Na3PO4. Cu 3: t chy hon ton 0,1 mol este X thu c 0,3 mol kh CO2 v 0,3 mol H2O. Nu cho 0,1 mol X tc dng ht vi NaOH th thu c 8,2 gam mui. X l A. HCOOCH3 B. HCOOC2H5 C. CH3COOCH3 D. CH3COOC2H5 Cu 4: Este X (c KLPT MX = 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l A. 29,75 B. 27,75 C. 26,25 D. 24,25 Cu 5: Cho cc phng trnh phn ng: Fe + A FeCl2 + Cht A no sau y chn khng ng? A. HCl. B. Cl2. C. CuCl2. D. FeCl3. Cu 6: Trong cng nghip, amoniac c iu ch t nit v hiro bng phng php tng hp: N2(k) + 3H2(k) 2NH3 (k) Phn ng theo chiu thun l phn ng to nhit. V l thuyt, cn bng trn s dch chuyn v pha to thnh amoniac nu A. gim nhit v gim p sut. B. gim nhit v tng p sut. C. tng nhit v tng p sut. D. tng nhit v gim p sut. Cu 7: un nng xenluloz vi hn hp HNO3 v H2SO4 c, thu c cht d chy, n mnh khng c khi nn c dng lm thuc sng khng khi. Sn phm l A. trinitroxenluloz. B. trinitratxenluloz. C. initroxenluloz. D. mononitroxenluloz. Cu 8: Do c tc dng dit khun, c bit l vi khun gy thi ra nn dung dch ca hp cht X c dng ngm xc ng vt, thuc da, ty u X l A. ancol metylic. B. ancol etylic. C. anehit fomic. D. anehit axetic. Cu 9: Trong cc cht HF, HCl, HBr v HI th A. HF l axit mnh nht. B. HF c bo qun v vn chuyn trong cc l thu tinh. C. HCl tan v hn trong nc. D. HI l axit mnh nht. Cu 10: Cho 21 gam hn hp gm glyxin v axit axetic tc dng va vi dung dch KOH, thu c dung dch X cha 32,4 gam mui. Cho X tc dng vi dung dch HCl d, thu c dung dch cha m gam mui. Gi tr ca m l A. 44,65. B. 50,65. C. 22,35. D. 33,50. Cu 11: Cho hn hp X gm ancol metylic, etylen glicol v glixerol. t chy hon ton m gam X thu c 6,72 lt kh CO2 (ktc). Cng m gam X trn cho tc dng vi Na d thu c ti a V lt kh H2 (ktc). Gi tr ca V l A. 3,36. B. 11,20. C. 5,60. D. 6,72. Cu 12: Ho tan hon ton 0,3 mol hn hp gm Al v Al4C3 vo dung dch KOH (d), thu c a mol hn hp kh v dung dch X. Sc kh CO2 (d) vo dung dch X, lng kt ta thu c l 46,8 gam. Gi tr ca a l A. 0,55. B. 0,60. C. 0,40. D. 0,45. Cu 13: Chia m gam hn hp gm Na2O v Al2O3 thnh 2 phn u nhau: Phn 1: Ho tan trong nc d thu c 1,02 gam cht rn khng tan. Phn 2: Ho tan ht trong dung dch HCl 1M th cn va 140ml dung dch HCl. Khi lng hn hp ban u m c gi tr bng A. 2,26 gam. B. 2,66 gam. C. 5,32 gam. D. 7,00 gam. Cu 14: Ho tan ht 7,2 gam hn hp A gm 2 mui cacbonat ca 2 kim loi k tip nhau phn nhm IIA bng dung dch H2SO4 long, thu c kh B. Cho ton b kh B hp th ht bi dung dch Ba(OH)2 d thu c 15,76 gam kt ta. Hai kim loi ban u l A. Be v Mg. B. Mg v Ca. C. Ca v Sr. D. Sr v Ba. Cu 15: Nung nng mt hn hp gm CaCO3 v MgO ti khi lng khng i, th s gam cht rn cn li ch bng 2/3 s gam hn hp trc khi nung. Vy % theo khi lng ca CaCO3 trong hn hp ban u l A. 75,76%. B. 24,24 %. C. 66,67 %. D. 33,33 %. Su tm: http://vuphan62hn.violet.vn/ Kim tra kin thc lp 12-ln 1 nm hc 2012-2013 - Page 1/4

Cu 16: Cho cc cht sau: C6H5 NH2 (A); Cl C6H4 NH2 (B); O2N C6H4 NH2 (C); CH3 C6H4 NH2 (D). Cht c tnh baz mnh nht l A. A. B. B. C. C. D. D. Cu 17: Cng thc ho hc ca clorua vi l A. CaCl2. B. CaOCl2. C. CaO2Cl. D. Ca(ClO)2. Cu 18: C hai hirocacbon A, B u l cht kh iu kin thng, khng phi l ng phn ca nhau. Khi t chy hon ton mi cht u to ra s mol nc gp 3 ln s mol mi cht chy. A v B tho mn s chuyn ho sau: A X Y B Cao su buna Trong X, Y c cng s lng nguyn t C trong phn t . Vy Y l A. vinylaxetilen. B. etanol. C. n butan . D. vinyl clorua. Cu 19: Hy cho bit nhn nh no ng trong s cc nhn nh di y? A. Nguyn t clo c tnh phi kim mnh hn nguyn t oxi. B. Oxi phn ng trc tip c vi clo khi t nng. C. Clo c m in tng ng m in ca oxi. D. iu kin thng oxi km hot ng ho hc hn clo. Cu 20: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l A. H2NC4H8COOH. B. H2NC3H6COOH. C. H2NC2H4COOH. D. H2NCH2COOH. Cu 21: Oxi ho 4,48 lt C2H4 ( ktc) bng O2 (xc tc PdCl2, CuCl2), thu c cht X n chc. Ton b lng cht X trn cho tc dng vi HCN (d) th c 7,1 gam CH3CH(CN)OH (xianohirin). Hiu sut qu trnh to CH3CH(CN)OH t C2H4 l A. 70%. B. 50%. C. 60%. D. 80%. Cu 22: Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y, cht rn Z v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt ta. Gi tr ca m l A. 48,3. B. 57,0. C. 45,6. D. 36,7. Cu 23: Hirocacbon X c khi lng mol bng 100 gam. Cho X tc dng vi clo to ra hn hp 3 dn xut monoclo l ng phn ca nhau. C bao nhiu cht X tho mn iu kin trn? A. 2 cht. B. 3 cht. C. 4 cht. D. 5 cht. Cu 24: Ho tan 7,02 gam hn hp gm mantoz v glucoz vo nc ri cho tc dng ht vi dung dch AgNO3 trong NH3 thu c 6,48 gam Ag. Phn trm theo khi lng ca glucoz trong hn hp ban u l A. 76,92%. B. 51,28%. C. 25,64%. D. 55,56%. Cu 25: Cho AgNO3 vo tng dung dch NaF, NaCl, NaBr, NaI th mui halogen to c kt ta l A. NaCl. B. NaCl v NaBr. C. NaCl, NaBr v NaI. D. tt c 4 mui cho. Cu 26: Dung dch NaHCO3 trong nc A. cho mi trng kim (pH > 7). B. cho mi trng axit (pH < 7). C. khng lm i mu qu tm. D. khng b thu phn bi nc. Cu 27: t chy hon ton 0,3 gam hp cht A c t khi hi so vi hiro bng 30, sn phm to ra ch gm 224 ml kh CO2 (ktc) v 0,18 gam H2O. Cht A va phn ng c vi NaOH, va c phn ng trng gng. Vy A l A. axit axetic. B. HOCH2CHO. C. HCOOCH3. D. HOOC CHO. Cu 28: Hp cht A c cng thc tng qut (CxH4Ox)n thuc loi axit no a chc, mch h. Gi tr ca x l n tng ng l A. 4 v 1. B. 3 v 2. C. 2 v 2. D. 2 v 3. Cu 29: Thm rt t t dung dch cha 0,3 mol HCl vo 400 ml dung dch Na2CO3 0,5M n khi kt thc phn ng thu c dung dch X v kh Y. Thm tip nc vi trong d vo dung dch X, sau phn ng khi lng kt ta thu c l A. 5 gam. B. 8 gam. C. 10 gam. D. 15 gam. Cu 30: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ancol etylic 460 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml) A. 4,5 kg. B. 6,0 kg. C. 5,0 kg. D. 5,4 kg. Cu 31: Cho m gam hn hp hi X gm hai ancol (n chc, bc I, l ng ng k tip) phn ng vi CuO d, thu c hn hp hi Y gm nc v anehit. T khi hi ca Y so vi kh hiro bng 14,5. Cho ton b Y phn ng hon ton vi lng d dung dch AgNO3 trong NH3, thu c 97,2 gam Ag. Gi tr ca m l A. 14,0. B. 10,1. C. 18,9. D. 14,7. Cu 32: t chy hon ton 4,64 gam mt hirocacbon X (cht kh iu kin thng) ri em ton b sn phm chy hp th ht vo bnh ng dung dch Ba(OH)2. Sau cc phn ng thu c 39,4 gam kt ta v khi lng phn dung dch gim bt 19,912 gam. Cng thc phn t ca X l Su tm: http://vuphan62hn.violet.vn/ Kim tra kin thc lp 12-ln 1 nm hc 2012-2013 - Page 2/4
,600 0

A. CH4. B. C4H10. C. C2H4. D. C3H4. Cu 33: Hn hp X gm 0,15 mol vinylaxetilen v 0,6 mol H2. Nung nng hn hp X (xc tc Ni) mt thi gian, thu c hn hp Y c t khi so vi H2 bng 10. Dn hn hp Y qua dung dch brom d, sau khi phn ng xy ra hon ton, khi lng brom tham gia phn ng l A. 0 gam. B. 24 gam. C. 8 gam. D. 16 gam. Cu 34: t chy hon ton hn hp gm FeS2 v Ag2S vi nhng s mol bng nhau thu c 3,36 lt SO2 (ktc) v cht rn B. Cho B vo cc ng lng d dung dch axit HCl. S gam cht rn khng tan trong dung dch axit HCl l A. 14,35 gam. B. 7,175 gam. C. 10,8 gam. D. 5,4 gam. Cu 35: un nng hn hp gm glixin v alanin thu c tripeptit mch h, trong t l gc ca glixin v alanin l 2:1. Hy cho bit c bao nhiu tripeptit c to ra? A. 2 cht. B. 3 cht. C. 4 cht. D. 5 cht. Cu 36: Phng trnh phn ng no ng trong cc phng trnh sau? A. 5Fe2+ + MnO4 + 4H2O 5Fe3+ + Mn2+ + 8OH B. 5Fe2+ + MnO4 + 8H+ 5Fe3+ + Mn2+ + 4H2O C. 3Fe2+ + MnO4 + 4H+ 3Fe3+ + MnO2 + 2H2O D. 3Fe2+ + MnO4 + 2H2O 3Fe3+ + MnO2 + 4OH Cu 37: Polivinyl clorua, polimetacrilat metyl c tnh cht no sau y ging nhau? Kh tan trong etanol, trong nc (1); Khng bay hi (2); Khng c im nng chy r rt (3). A. (1) v (2). B. (1) v (3). C. (2) v (3). D. (1), (2) v (3). Cu 38: Axit stearic c cng thc phn t l A. C15H31COOH. B. C17H31COOH. C. C17H33COOH. D. C17H35COOH. Cu 39: Cho cc phng trnh phn ng sau: CH3 CH = CH2 + Cl2 CH3 CHCl CH2Cl (1); CH3 CH = CH2 + HClO CH3 CH(OCl) CH3 (2); CH3 CH = CH2 + H2O CH3 CH2 CH2OH (3); CH3 CH = CH2 + BrI CH3 CHBr CH2I (4); Phn ng vit ng theo qui tc Maccopnhicop l A. (1). B. (2), (3). C. (2), (3), (4). D. (2). Cu 40: Thu phn hon ton m gam ipeptit Gly Ala (mch h) bng dung dch KOH va , thu c dung dch X. C cn ton b dung dch X thu c 2,4 gam mui khan. Gi tr ca m l A. 1,46. B. 1,36. C. 1,64. D. 1,22. Cu 41: Cht no sau y va tc dng c vi dung dch NaOH, va tc dng c vi nc Br2 ? A. CH3CH2COOH. B. CH3COOCH3. C. CH2=CHCOOH. D. CH3CH2CH2OH. Cu 42: Cho cc cht C2H2 (A); HCHO (B) v HCOOH (C). Cht c th tc dng vi dung dch AgNO3/NH3 to ra kt ta l A. (A). B. (B). C. (B) v (C). D. (A), (B) v (C). Cu 43: Hp th hon ton 0,336 lt kh CO2 (ktc) vo 200ml dung dch gm NaOH 0,1M v KOH 0,1M thu c dung dch X. C cn ton b dung dch X thu c bao nhiu gam cht rn khan? A. 2,58 gam. B. 2,22 gam. C. 2,31 gam. D. 2,44 gam. Cu 44: C bao nhiu ng phn axit (k c ng phn cis tran) ng vi cng thc phn t C4H6O2 ? A. 2 cht. B. 3 cht. C. 4 cht. D. 5 cht. Cu 45: Cho mt hn hp gm Cu, Fe, Ag, Mg. Dng dung dch no sau y c th tch ring c Ag ra khi hn hp? A. HNO3 c, nng. B. H2SO4 c, nng. C. Dung dch HCl. D. Dung dch Fe(NO3)3. Cu 46: Cho mi cht sau: Na2O, ZnO, Al2O3, CrO3 vo dung dch NaOH, c phn ng xy ra i vi A. Na2O, Al2O3. B. ZnO v Al2O3. C. CrO3. D. tt c cc oxit. Cu 47: c im ca n mn ho hc l A. khng ph thuc nhit v khng pht sinh dng in. B. ph thuc nhit v pht sinh dng in. C. ph thuc nhit v khng pht sinh dng in. D. Ph thuc nhit v c th c hoc khng pht sinh dng in. Cu 48: nhn bit cc hp cht n chc c cng cng thc phn t C2H4O2 c th dng A. dung dch HCl. B. dung dch NaOH. C. dung dch NH3. D. dung dch AgNO3/NH3. Cu 49: Trong cc loi phn bn ho hc sau, loi no c hm lng P2O5 cao nht? A. Supe phot pht n. B. Supe phot phat kp. C. Phn ln t nhin. D. Phn ln nung chy. Cu 50: t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n chc, mch h v mt ancol n chc (c s nguyn t cacbon trong phn t khc nhau) thu c 0,3 mol CO2 v 0,4 mol H2O. Thc hin phn ng este ho 7,6 gam hn hp trn vi hiu sut 80% thu c m gam este. Gi tr ca m l A. 8,16. B. 6,12. C. 2,04. D. 4,08. Su tm: http://vuphan62hn.violet.vn/ Kim tra kin thc lp 12-ln 1 nm hc 2012-2013 - Page 3/4

P N M 147 1D, 2D, 3C, 4C, 5B, 6B, 7B, 8C, 9D, 10A, 11A, 12B, 13C, 14B, 15A, 16D, 17B, 18B, 19D, 20D, 21B, 22A, 23C, 24B, 25C, 26A, 27C, 28B, 29C, 30A, 31D, 32D, 33B, 34C, 35B, 36B, 37D, 38D, 39D, 40A, 41C, 42D, 43C, 44D, 45D, 46D, 47C, 48D, 49B, 50D.

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