PHENOL

Cu 1. chng minh c s nh hng qua li ca nhm OH v nhm C6H5 trong phenol ta c th cho phenol tc dng vi : A. dd NaOH v dd Br2 B. Na v dd HNO3 C. Na v dd Br2 D. dd NaOH v dd HCl Cu 2. X l hp cht hu c thm c cng thc phn t C8H10O. X c th tc dng vi Na to ra kh H2, khi oxi ha X bng CuO nung nng to ra sn phm c kh nng tham gia phn ng trng bc. S cng thc cu to ca X tha mn iu kin trn A. 3. B. 6. C. 4 D. 5. Cu 3. Trong s cc dn xut ca benzen c cng thc phn t C8H10O, c bao nhiu ng phn (X) tha mn cc iu kin sau: xt (Y) H 2O (X) + NaOH -> khng phn ng ; (X) polime (Z) A. 3 B. 4 C. 2 D. 1 Cu 4. Cho cc cht sau: phenol, phenyl clorua, benzyl clorua, ancol benzylic, p-crezol, 2-nitrophenol. C bao nhiu cht c kh nng phn ng vi dung dch NaOH long, nng A. 4 B. 6 C. 3 D. 5 Cu 5. Mt hp cht hu c X c cha vng benzen c cng thc phn t l C xHyO2 , trong oxi chim 25,8% v khi lng. X tc dng c vi NaOH theo t l mol l 1: 1. Hy cho bit X c bao nhiu cng thc cu to ? A. 5 B. 3 C. 4 D. 6 + Br2 / Fe ,t 0 + NaOH dac / t 0 , p cao HCl Cu 6. Cho s chuyn ho sau: Toluen X Y + Z. Trong X, Y, Z u l hn hp ca cc cht hu c. Z c thnh phn chnh gm A. m-metylphenol v o-metylphenol. B. o-bromtoluen v p-bromtoluen. C. o-metylphenol v p-metylphenol. D. benzyl bromua v o-bromtoluen. Cu 7. Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H 2 ( ktc). Cng thc cu to thu gn ca X l A. HO-C6H4-COOH. B. CH3-C6H3(OH)2. C. HO-C6H4-COOCH3. D. HO-CH2-C6H4-OH. Cu 8. Cho s l: A. C6H5ONa, C6H5OH. B. C6H6(OH)6, C6H6Cl6. C. C6H4(OH)2, C6H4Cl2. D. C6H5OH, C6H5Cl. Cu 9. Cho s phn ng sau: C6H6 (benzen) C6H5CH(CH3)2 C6H5OH. Tnh khi lng benzen cn dng iu ch c 94 kg phenol. Bit hiu sut phn ng t 80%. A. 94,5 gam B. 88,6 gam C. 78,0 gam D. 97,5 gam Cu 10. Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21:2:4. Hp cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm ng vi cng thc phn t ca X l A. 5. B. 3. C. 4. D. 6. Cu 11. Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO 2 thu c nh hn 35,2 gam. Bit rng, 1 mol X ch tc dng c vi 1 mol NaOH. Cng thc cu to thu gn ca X l A. HOCH2C6H4COOH. B. trinitrophenolC2H5C6H4OH. C. C6H4(OH)2. D. HOC6H4CH2OH. Cu 12. Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit cao. Sau khi phn ng xy ra hon ton, thu c x mol hn hp kh gm: CO2, CO, N2 v H2. Gi tr ca x l A. 0,54. B. 0,60. C. 0,45. D. 0,36. Cu 13. Cng thc phn t C7H8O c s ng phn cha vng thm l: A. 4 B. 3 C. 5 D. 6 Cu 14. Cho 21,4g hn hp A (CnH2n+1-OH v C6H5-OH) tc dng vi Na d thot ra 3,36 lit kh ktc. Mt khc cho 21,4g A tc dng va vi dd Br2 thu c 33,1g kt ta, xc nh CT ancol. Bit khi b oxi ho thu c anehit A. C2H5-OH B. CH3-CH2-CH2OH C. CH3-CHOH-CH3 D. CH3OH. Cu 15. Cho cht hu c X c cng thc phn t C6H6O2. Bit X tc dng vi KOH theo t l mol 1 : 2. Vy s ng phn cu to ca X l bao nhiu? A. 1 B. 4 C. 3 D. 2 + Br2 / Fe ,t 0 + NaOH dac / t 0 , p cao + HCl Cu 16. Cho dy chuyn ha iu ch sau: Toluen X Y D. D l cht no: A. o-Metylphenol hoc p-metylphenol C. m-Metylphenol B. o-Clo toluen v p-clotoluen D. Benzyl clorua
C6H6 (benzen)
+ Cl2 (1:1) Fe,to

+ NaOH c, d

pcao, tcao

+ axit HCl

Z.

Hai cht hu c Y, Z ln lt

Cu 17. Cho cc cht sau: (1) metanol; (2) phenol; (3) nc; (4) 2,4,6-trinitrophenol. S sp xp no ng vi chiu tng dn linh ng ca nguyn t H trong nhm -OH? A. (1) < (3) < (4) < (2) B. (3) < (1) < (2) < (4) C. (3) < (1) < (4) < (2) D. (1) < (3) < (2) < (4) Cu 18. Hp cht X c cha vng benzen v c CTPT l C7H8O2. Khi cho X tc dng vi Na thu c s mol kh H2 ng bng s mol X. X tc dng vi NaOH theo t l mol 1 : 1. Hy cho bit X c th c bao nhiu cng thc cu to ? A. 2 B. 4 C. 3 D. 1 Cu 19. Hp cht X cha vng benzen v c cng thc phn t l C8H10O. Oxi ho X thu c anehit X1. Tch nc X thu c hirocacbon X2. Hy la chn cng thc cu to ng ca X. A. C6H5CH2CH2OH B. p-CH3-C6H4-CH2OH C. o-CH3-C6H4-CH2OH D. C6H5CH(OH)CH3 Cu 20. Cht hu c A cha vng thm c cng thc phn t l C 7H8O, khi cho A tc dng vi dung dch Brom th thu c dn xut cha 3 nguyn t brom. C bao nhiu cng thc cu to tho mn vi A. A. 2 B. 3 C. 4 D. 1 Cu 21. X l hp cht thm c cng thc phn t C7H8O. X tc dng c vi dung dch Br2 to kt ta trng. S cng thc cu to ca X tho mn l. A. 2 B. 3 C. 4 D. 5 (1) ( 2) X1 (C7H7Cl) X2 (C7H8O). Hy cho bit tn gi ca X2. Bit rng X1 l Cu 22. Cho s sau : toluen sn phm duy nht ca phn ng (1). A. m- Metyl phenol B. o-Metyl phenol C. ancol benzylic D. p- Metyl phenol Cu 23. Trong s cc pht biu sau v phenol (C6H5OH): (1) Phenol tan t trong nc nhng tan nhiu trong dung dch HCl. (2) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm. (3) Phenol dng sn xut keo dn, cht dit nm mc. (4) Phenol tham gia phn ng th brom v th nitro d hn benzen. Cc pht biu ng l: A. (2), (3), (4). B. (1), (2), (4). C. (1), (2), (3). D. (1), (3), (4). Cu 24. Cht X c cng thc phn t l C7H8O. X tc dng vi NaOH hy cho bit kt lun no sau y ng vi cu to ca X. A. X l axit B. X l ete C. X l phenol D. X l ancol thm. Cu 25. Cho s : A B B1 B2 phenol. A l cht no sau A. C2H4 B. CH2=CHCl. C. C2H2 D. C4H6 Cu 36. S ng phn thm c cng cng thc phn t C7H8O va tc dng c vi Na va tc dng c vi NaOH l bao nhiu? A. 4 B. 3 C. 1 D. 2 Cu 27. Cho cc cht: C6H5OH (X), CH3-C6H4-OH (Y), C6H5 -CH2OH (Z). Cp cc cht ng ng ca nhau l cp cht no A. X v Z B. Y v Z C. X, Y v Z D. X v Y Cu 28. X c cha vng benzen v c cng thc phn t l C8H10O. X tc dng vi NaOH v tc dng vi dung dch Br2 thu c kt ta Y c cng thc phn t l C8H7OBr3. Hy cho bit X c bao nhiu cng thc cu to ? A. 3 B. 4 C. 2 D. 1 (1) ( 2) ( 4) (5) (3) (6) Cu 29. Cho dy bin ho sau: Metan X1 X2 X3 X4 X5 axit picric
(7 ) X6

Cc cht X1 ; X4 ; X6 ln lt l : A. CH3Cl; C6H5ONa; C6H2(NO2)3OH B. C2H2; C6H5OH; C6H2(NO2)3ONa C. C2H2; C6H5ONa; C6H2(NO2)3ONa D. C2H2; C6H5ONa; C6H2(NO2)3OH Cu 30. Cht X c cng thc phn t l C8H10O. X tc dng vi Na v NaOH. Khi cho X tc dng vi brom (dd) th thu c kt ta Y c cng thc phn t l C8H9OBr. Hy cho bit X c bao nhiu cng thc cu to? A. 1 B. 4 C. 2 D. 3 Cu 31. Hp cht X c cng thc phn t l C9H12O. hirat ho X thu c hirocacbon Y. Hiro ho Y trong iu kin thch hp thu c p-etyl toluen. Hy cho bit X c bao nhiu cng thc cu to? A. 2 B. 3 C. 4 D. 1 Cu 32. Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung dch NaHCO3. Tn gi ca X l A. axit acrylic. B. metyl axetat. C. anilin. D. phenol. Cu 33. Cht X c cng thc phn t l C9H12O. hirat ho X thu c hirocacbon Y. Hiro ho Y trong iu kin thch hp thu c hirocacbon Z c cng thc phn t l C9H12. Oxi ho Z bng oxi sau thu phn thu c phenol v axeton. Hy cho bit X c bao nhiu cng thc cu to? A. 3 B. 1 C. 4 D. 2 Cu 34. Cho cc cht hu c sau. C6H5-OH (I), C6H5- CH2-OH (II), C6H5- CH2- CH2- OH (III), p- CH3- C6H4-OH (IV), o- CH3- C6H4-OH (V), p- CH3- O- CH2- C6H4-OH (VI) ancol thm l: A. (I),(II),(III) B. (III) ,(IV) (V) C. (II) ,(III) D. (III) ,(IV) (V), (VI)

Cu 35. Cho dy cc cht: phenylamoni clorua, benzyl clorua, isopropyl clorua, m-crezol, ancol benzylic, natri phenolat, anlyl clorua. S cht trong dy tc dng c vi dung dch NaOH long, un nng l. A. 4. B. 3. C. 5. D. 6. Cu 36. Hp cht hu c X cha vng benzen c cng thc phn t trng vi cng thc n gin nht. Trong X, t l khi lng cc nguyn t l mC : mH : mO = 21 : 2 : 8. Bit khi X phn ng hon ton vi Na th thu c s mol kh hiro bng s mol ca X phn ng. X c bao nhiu ng phn (cha vng benzen) tha mn cc tnh cht trn? A. 10.