CHUYN :

BI TP V PHN NG NHIT LUYN

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Nguyn tc: Dng CO, H2 kh oxt kim loi sau Al to Kim loi + CO2 , H2O CO + O ( trong oxt) t CO2 H2 + O ( trong oxt) t H2O Nhn xt: nO = n H 2 + nCO ; nO = noxit - nkim loi A. T LUN Cu 1.Hn hp A gm Al2O3, MgO, CuO, FeO. Cho kh CO d i qua A nung nng c cht rn B. Ho tan B vo dung dch NaOH d, thu c dung dch C v cht rn D. Cho dung dchHCl d vo dung dchC. Ho tan cht rn D vo dung dchHNO3(l)(phn ng to kh NO). Cc cht trong B, C, D l nhng cht no , vit cc ptp xy ra. Cu 6. Ho tan hon ton hn hp Al, Cu, Ag bng dung dchHNO3 long d thu c kh NO duy nht v dung dch A. C cn dung dchA ri nht phn hon ton hn hp mui khan th thu c hn hp cht rn B. Nung nng B ri cho mt lung kh CO d i qua n phn ng hon ton c hn hp cht rn D. Cho D tc dng vi dung dchHCl d th D ch tan mt phn. Vit cc ptp xy ra. Cu 17.Thi mt lung kh CO d i qua ng s ng hn hp Fe3O4 v CuO nung nng n phn ng hon ton, ta thu c 2,32 gam hn hp kim loi. Kh thot ra cho vo bnh ng nc vi trong d thy c 5 gam kt ta trng. Xc nh khi lng hn hp 2 oxit kim loi. Cu 14.Kh 32 gam Fe2O3 bng kh CO d nhit cao, sn phm kh thu c cho vo bnh nc vi trong d thu c a gam kt ta.Xc nh a. Cu 2.Nung nng 20,3 gam hn hp A gm Al2O3, CuO, FeO ri cho 1 lung kh CO d i qua n khi phn ng xy ra hon ton, thu c 17,1 gam cht rn v hn hp kh B.Mt khc 20,3 gam A tc dng va vi 350 ml dung dchHCl 2M thu c dung dch D. Cho dung dch NaOH d vo dung dch D thu c kt ta, lc ly kt ta em nung trong khng kh n khi lng khng i th thu c m gam cht rn. 1. Tnh khi lng mi cht trong 20,3 gam hn hp A v tnh m. S. mAl2O3 =5,1g;CuO=8g, FeO=7,2g 2.Sc ton b hn hp kh B vo V(l) dung dch Ba(OH)2 1M thu c 19,7 gam kt ta. Tnh V.s V=1,5l Cu 3.Cho mt lung CO i qua ng s ng 0,04 mol hn hp A gm FeO v Fe2O3 t nng. Sau khi kt thc th nghim thu c cht rn B gm 4 cht nng 4,784 gam. Kh i ra khi ng s cho hp th vo dung dch Ba(OH)2 d, th thu c 9,062 gam kt ta. Mt khc ho tan cht rn B bng dung dch HCl d thy thot ra 0,6272(l) H2(ktc). 1. Tnh %m cc oxit trong hn hpA .s%mFeO=13%;%mFe2O3=87% 2. Tnh %m cc cht trong B, bit trong B s mol Fe3O4 = 1/3 tng s mol FeO v Fe2O3. Cu 4.Mt hn hpX gm Fe, FeO, Fe2O3. Ly 0,4 gam X cho tc dng vi dung dch HCl d th thu c 56 ml kh H2(ktc). em kh 1 gam hn hpX bng H2 nhit cao th thu c 0,2115 gam H2O. 1. Tnh %m mi cht trong hn hpX. 2. Tnh V dung dchHNO3 0,5M phi dng ho tan ht 1 gam hn hpX trn. Cho bit phn ng ch to ra kh NO duy nht. Cu 5. Khi dng CO kh Fe2O3 nhit cao, ta thu c kh CO2 v hn hp cc cht rn X. Ho tan X trong dung dchHCl d, thu c 4,48(l) kh (ktc) v dung dchY. Cho dung dchNaOH d vo dung dchY, thu c 45 gam cht kt ta mu lc nht. 1. Hn hp X c my cht? 2. Khi lng Fe trong X? 3. Tnh th tch CO dng 2000C v 0,8 atm. Cu 7. Cho 4,72 gam hn hp gm Fe, FeO, Fe2O3 tc dng vi CO d nhit cao. Phn ng xong thu c 3,92 gam Fe. Nu ngm cng lng hn hp trn trong dung dchCuSO4 d phn ng xong thu c 4,96 gam cht rn. Xc nh khi lng mi cht trong hn hp ban u. S.mFe=1,68g;mFeO=1,44g;mFe2O3=1,6g. Cu 8. C 100 ml dung dch hn hp axit H2SO4 0,8M v HCl 1,2M; thm vo 10 gam hn hp bt Fe, Mg, Zn. Sau khi phn ng xong, ly 1/2 lng kh sinh ra cho i qua ng s ng a gam CuO nung nng. Sau khi phn ng hon ton, trong ng s cn 14,08 gam hn hp cht rn A. Cho A di dng bt tc dng vi dung dchAgNO3 th sau khi phn ng xong thu c cht rn B, trong c 25,23% Ag. 1. Tnh a. 2. Tnh th tch dung dchHNO3 2M cn dng ho tan ht B(phn ng ch to kh NO).
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Cu 9. Kh ht m gam Fe3O4 bng kh CO nhit cao thu c hn hp A gm FeO v Fe. A tan va trong 0,3(l) dung dch H2SO4 1M cho ra 4,48(l) kh(ktc). Tnh m(khi lng Fe3O4) dng v th tch kh CO phn ng vi Fe3O4. Cu 10. Mt hn hp X gm Fe2O3, FeO, MgO c khi lng l 4,24 gam trong c 1,2 gam MgO. Khi cho X phn ng vi CO d nhit cao(phn ng hon ton), ta thu c cht rn A v hn hp CO + CO2. Hn hp ny khi qua nc vi trong d cho ra 5 gam kt ta. Xc nh khi lng FeO, Fe2O3 trong hn hpX. Cu 11. Kh 39,2 gam hn hpA gm Fe2O3 v FeO bng kh CO nhit cao thu c hn hp B gm FeO v Fe. B tan va trong 2,5(l) trong dung dchH2SO4 0,2M cho ra 4,48(l) kh(ktc). Tnh khi lng Fe2O3 v khi lng FeO trong hn hpA. Cu 12. Nung 24 gam hn hp gm Fe2O3 v CuO trong 1 lung kh H2 d. Phn ng hon ton. Cho hn hp kh to ra sau phn ng i qua mt bnh ng H2SO4 c. Khi lng ca bnh tng 7,2 gam. Tnh khi lng Fe v Cu thu c sau phn ng. Cu 13 Cho kh CO qua ng ng a gam hn hp gm CuO, Fe3O4, FeO, Al2O3 nung nng. Kh thot ra c cho vo nc vi trong d thy c 30 gam kt ta trng. Sau phn ng, cht rn cn li trong ng s c khi lng 202 gam. a c gi tr l bao nhiu. Cu 15.Kh hon ton 0,25 mol Fe3O4 bng H2 nhit cao. Sn phm hi cho hp th vo 18 gam dung dchH2SO4 80%. Nng H2SO4 sau khi hp th hi nc l bao nhiu? Cu 19.Thi t t V(l) hn hp kh(CO, H2) i qua 1 ng s ng 16,8 gam hn hp 3 oxit CuO, Fe3O4, Al2O3 nhit cao. Sau phn ng, ta thu c hn hp kh v hi nng hn hn hp (CO, H2) ban u l 0,32 gam. 1. V(ktc)? 2. Cht rn cn li trong ng s c khi lng? Cu 20.Thi rt chm 1,12(l)(ktc) kh CO qua mt ng s ng hn hp gm Al2O3, CuO, Fe3O4, Fe2O3 c khi lng l 12 gam(d) ang c nung nng, hn hp kh v hi thot ra khi ng s c hp th hon ton vo dung dchCa(OH)2 d, ta thy c 2,5 gam kt ta trng. Khi lng cht rn cn li trong ng s l: Cu 21.Cho 4,48(l) CO(ktc) tc dng vi FeO nhit cao. Sau phn ng thu c cht rn A c khi lng nh hn 1,6 gam so vi khi lng FeO ban u. Xc nh khi lng Fe thu c v tnh %V ca hn hp CO v CO2 thu c. Cu 22.16 gam hn hpA gm MgO v CuO. Khi cho A tc dng vi H2 d nhit cao, cn li mt cht rn B. B tan va trong 1(l) dung dchH2SO4 0,2M. Tnh %m ca cc cht trong hn hpA. Cu 23. Kh 6,4 gam CuO bng H2 nhit cao. Hn hp kh v hi thu c cho qua H2SO4 m c th khi lng ca H2SO4 tng 0,9 gam. Tnh % CuO b kh bi kh H2 v th tch H2(ktc) dng, bit rng hiu sut phn ng kh ny l 80%. Cu 24. Kh 1,6 gam Fe2O3(cho ra Fe) bng kh CO ly d nhit cao. Hn hp kh CO v CO2 khi qua nc vi trong d cho 3 gam kt ta. Tnh %Fe2O3 b kh v V(ktc) CO dng. Cu 25. C 2,88 gam hn hpA gm Fe, FeO, Fe2O3. Ho tan hon ton hn hpA bng dung dchH2SO4 long thu c 0,224(l) H2(ktc). Mt khc ly 5,76 gam hn hpA kh bng H2 n khi hon ton thu c 1,44 gam H2O. Phn trm khi lng tng cht trong hn hpA l: Cu 26.Cho mt lung CO i qua ng s ng m gam Fe2O3 nung nng. Sau mt thi gian thu c 13,92g hn hp X gm Fe, FeO, Fe3O4 v Fe2O3. Ho tan ht X bng HNO3 c nng c 5,824 lt NO2 (ktc). 1. Vit cc phn ng xy ra. 2. nh m. Cu 27. X l hn hp gm CuO v Fe2O3 nung 4,5 gam X vi C trong iu kin khng c khng kh cho n khi cc phn ng xy ra hon ton thu c 1,344 lt (ktc). Hn hp Y gm CO v CO2. Cho t khi ca Y i vi oxi l 1. 1. Vit cc phng trnh phn ng xy ra. 2. Tnh % khi lng cc cht trong X. Cu 28.Cho mt lung CO i qua ng s ng m gam Fe2O3 nung nng sau mt thi gian thu c 5,22g hn hp X gm Fe, FeO, Fe3O4 v Fe2O3 d. Ho tan ht X bng HNO3 thu c 1,68 lt (ktc) hn hp Y gm NO v NO2. Bit t khi ca Y so vi hidro l 21,8. 1. Tm m. 2. Nu ho tan ht X bng H2SO4 c nng thu c V lt SO2 (ktc). nh V1. 3. ho tan ht X cn 150ml dung dch HCl 1M thu c V2 lt H2 (ktc). nh V2. 2

Cu 29.Cho mt lung CO i qua ng s ng m gam Fe2O3 nung nng. Sau mt thi gian thu c 10,44g cht rn X gm Fe, FeO, Fe2O3 v Fe3O4. Ho tan ht X bng HNO3 c nng thu c 4,368 lt NO2 (ktc). 1. Tnh m. 2. Nu ho tan ht X bng 150ml dung dch HCl 2M (va ) thy bay raV lt H2(kc). nh V. Cu 30.X l hn hp gm CuO v FeO. Nung 14g X vi cacbon trong iu kin khng c khng kh cho n khi cc phn ng xy ra hon ton thu c 3,29 lt (ktc) hn hp Y gm CO v CO2. Dn Y qua nc vi trong d thy xut hin 1,75g kt ta. Tnh % khi lng cc oxit trong X. Cu 31.Mt oxit kim loi c cng thc MxOy, trong M chim 72,41% theo khi lng. Kh hon ton oxit ny bng kh CO thu c 16,8 gam kim loi M. Ho tan hon ton lng M bng HNO3 c, nng thu c mui ca M ho tr III v 0,9 mol kh NO2. Cng thc ca oxit trn l: Cu 32.Kh mt oxit st bng CO nhit cao, phn ng xong ngi ta thu c 0,84 gam Fe v 448 ml CO2(ktc). Xc nh cng thc ca oxit st. Cu 33.Cho V(l) kh CO qua ng s ng 5,8 gam oxit st nng mt thi gian th thu c hn hp kh X v cht rn Y. Cho Y tc dng vi axit HNO3 long c dung dch Z v 0,784(l) kh NO. Xc nh cng thc ca oxit st. Cu 34.Cho m gam FexOy vo 1 bnh kn cha 4,48(l) CO(ktc). Nung bnh 1 thi gian cho n khi oxit st b kh hon ton thnh 1 oxit st khc. 1. Xc nh cng thc ca 2 oxit st. Bit %Fe(theo khi lng) trong FexOy l 70% v trong oxit st thu c l 77,78%. 2. Tnh m, bit rng t khi hi ca hn hp CO v CO2 thu c sau phn ng so vi H2 l 18. Cu 35.Ho tan hon ton 12 gam hn hp gm st v 1 oxit st vo dung dchHCl d th thu c 4,982(l) kh 27,30C, 1 atm. Nu hn hp trn dng H2 d kh th thu c 0,2 gam nc. 1. Vit cc ptp xy ra v tnh %m mi cht trong hn hp ban u. 2. Xc nh cng thc ca oxit st. Cu 36.Kh hon ton 4,06 gam 1 oxit kim loi bng CO nhit cao thu c kim loi. Dn ton b kh sinh ra vo bnh ng dung dchCa(OH)2 d thy to thnh 7 gam kt ta. Nu ly lng kim loi sinh ra ho tan ht vo dung dchHCl d th thu c 1,176(l) H2(ktc). 1. Xc nh cng thc ca oxit kim loi. 2. Cho 4,06 gam oxit kim loi trn tc dng hon ton vi 500 ml dung dchH2SO4 c, nng, d thu c dung dchX v c kh SO2 thot ra. Tnh CM ca mui trong dung dch X(coi th tch dung dch thay i khng ng k). Cu 37.Hn hp A gm 2 oxit st. Kh hon ton 15,68 gam hn hpA bng CO th thy khi lng hn hp gim i 4,48(g). 1. Xc nh CT ca cc oxit st. Bit s mol ca 2 oxit trong A bng nhau. 2. Tnh th tch dung dch NaOH 1M cn ly t nht hp th hon ton lng kh sinh ra do phn ng trn. Cu 38.R l kim loi ho tr II. em ho tan a gam oxit ca kim loi R vo 48 gam dung dchH2SO4 6,125% (long) thnh dung dchA, trong nng H2SO4 ch cn 0,98%. Bit rng a gam oxit trn phn ng hon ton vi 2,8(l) CO c kim loi R v kh B. Nu ly 0,7(l) kh B cho qua dung dchCa(OH)2 d th thu c 0,625 gam kt ta(cc phn ng xy ra hon ton, cc th tch kh o ktc, mui sunfat ca kim loi R tan hon ton). 1. Tnh a v tm kim loi R. 2. Cho 0,54 gam bt Al vo 20 gam dung dchA. Sau khi phn ng kt thc thu c m gam cht rn. Tnh m. Cu 39.Nung 16,2 gam hn hpA gm MgO, Al2O3, MO trong 1 ng s ri cho lung H2 i qua. iu kin th nghim, H2 ch kh MO vi H = 80%, lng hi nc to ra ch c hp th 90% bi 15,3 gam dung dchH2SO4 90%, kt qu thu c dung dchH2SO4 86,34%. Cht rn cn li trong ng s c ho tan trong mt lng va dung dch axit khng c tnh oxi ho(v d HCl) thu c dung dchB v cn li 2,56 gam kim loi M khng tan. Ly 1/10 dung dchB cho tc dng vi dung dchNaOH d, ly kt ta nung nhit cao n khi lng khng i th thu c 0,28 gam mt oxit. Xc nh kim loi M v tnh % khi lng cc cht trong A. Cu 40. Kh 2,4 gam hn hp gm CuO v mt oxit st(c s mol bng nhau) bng H2. Sau phn ng thu c 1,76 gam cht rn, em ho tan cht bng dung dchHCl thy bay ra 0,448(l) kh(ktc). Xc nh cng thc ca oxit st. 3

Cu 41. Ho tan hon ton a gam mt oxi st bng H2SO4 c, nng thy thot ra kh SO2 duy nht. Trong th nghim khc, sau khi kh hon ton cng a gam oxit st bng CO nhit cao ri ho tan lng st to thnh bng H2SO4 c, nng th thu c lng kh SO2 nhiu gp 9 ln lng kh SO2 th nghim ni trn. Vit cc phng trnh phn ng trong hai th nghim trn v xc nh cng thc ca oxit st. Cu 42. Kh 3,48 gam mt oxit ca kim loi M cn dng 1,344 lt H2 (ktc). Ton b lng kim loi M thu c cho tc dng vi dung dch HCl d cho 1,008 lt H2 (ktc). Tm kim loi M v oxit ca M. Cu 43. Hn hp A c khi lng 8,14 gam gm CuO, Al2O3 v mt oxit ca st. Cho H2 d qua A nung nng, sau khi phn ng xong thu c 1,44 gam H2O. Ha tan hon ton A cn dng 170ml dung dch H2SO4 long 1M, c dung dch B. Cho B tc dng vi dung dch NaOH d, lc ly kt ta em nung trong khng kh n khi lng khng i, c 5,2 gam cht rn.Xc nh cng thc ca oxit st v tnh khi lng tng oxit trong A. Cu 44. Khi kh 2,32 gam mt oxit st A bng lng H2 d thnh Fe thu c 0,72 gam nc. Xc nh cng thc phn t ca A v hon thnh cc phn ng (1) v (2): Cu 45. kh 4,06 g mt oxit kim loi thnh kim loi phi dng 1,568 lt H2 (ktc). Ho tan ht lng kim loi to thnh trn bng dung dch H2SO4 long thu c 1,176 lt H2 (ktc). Tm cng thc oxit kim loi. Cu 47. Nung hn hp A gm Al v Fe2O3 c hn hp B. Chia hn hp B thnh hai phn bng nhau. Phn 1: Ho tan trong d2 H2SO4 d thu c 2,24(l) kh(ktc). Phn 2: Ho tan trong d2 KOH d th khi lng cht rn khng tan l 8,8(g). Bit cc p xy ra hon ton. Xc nh khi lng cc cht trong hn hp A v B. Cu 48. Nung nng hn hp bt gm Al v Fe3O4 trong iu kin khng c khng kh phn ng xy ra hon ton. Thu c hn hpA. Nu cho A tc dng vi d2KOH d th thu c 0,672(l) kh(ktc). Nu cho A tc dng vi d2H2SO4 , to, d th thu c 100ml d2B v 1,428(l) SO2 duy nht (ktc). 1. Xc nh cc cht trong A v tnh %m mi cht trong hn hp ban u. 2. thu c kt ta nh nht trong d2B ngi ta phi dng 500ml d2KOH 0,5M. Tnh s mol ca H2SO4 c trong d2B. Cu 49. Hn hp A gm Al v Fe2O3. Thc hin p nhit nhm hon ton hn hp A thu c hn hp B. Chia hn hp B thnh 2 phn. Phn1: Cho tc dng vi d2 NaOH d thu c 4,48(l) H2(ktc), trong phn 1 khi lng Fe bng 0,4705 ln khi lng c phn. Phn 2: Cho tc dng vi d2 HCl d thu c 17,92(l) H2(ktc). 1. B gm nhng cht no? Tnh khi lng mi phn. Bit cc phn ng xy ra hon ton. 2. Tnh khi lng mi cht trong hn hp A. Cu 50.Hn hp A gm 0,56(g) Fe v 16(g) Fe2O3. Trn A vi m(mol) bt Al ri nung nhit cao(khng c khng kh) thu c hn hp D.Nu cho D tan trong d2H2SO4(l), d th thu c a(l) kh, nhng cho D tc dng vi d2NaOH d thu c 0,25a(l) kh trong cng k. 1. Xc nh thnh phn cc cht trong D. 2. m c gi tr trong khong no? Nu p nhit nhm ch to ra Fe. Cu 51.Nung m(g) hn hp A gm bt Al v Fe3O4 (ch c phn ng kh thnh Fe) sau mt thi gian thu c hn hp cht rn B. ho tan ht B cn V(ml) H2SO4 0,7M (long). Sau p thu c d2C v 9,846(l) kh 1,5 atm v 270C. Cho d2NaOH vo d2C n d thu c kt ta D. Nung kt ta D trong k khng c khng kh n khi lng khng i thu c 44(g) cht rn E. Cho 50(g) hn hp X gm CO v CO2 qua ng s ng E, nung nng . Sau khi E p ht thu c hn hp kh Y c mY=1,208.mX. 1. Xc nh cc cht trong B, C, D, E, Y. 2. Tnh %m cc cht trong B, tnh m v V. Cu 53.Trn 6,48 gam Al vi 1,6 gam Fe2O3. Thc hin phn ng nhit nhm thu c cht rn A. Khi cho A tc dng vi dung dchNaOH d, c 1,344(l) kh(ktc) thot ra. Tnh hiu sut ca phn ng nhit nhm. Cu 54.Mt hn hp gm Al v Fe2O3 c khi lng l 26,8 gam. Tin hnh phn ng nhit nhm(phn ng hon ton) thu c cht rn A. Chia A lm 2 phn bng nhau. Phn 1: Cho tc dng vi dung dchNaOH cho ra kh H2. Phn 2: Cho tc dng vi dung dchHCl d thu c 5,6(l) kh(ktc). Tnh khi lng Al v Fe2O3 trong hn hp ban u.
A (1) (2) Fe2 ( SO4 ) 3 FeSO4

Cu 55.Mt hn hp X gm Al v Fe2O3. Thc hin phn ng nhit nhm hon ton thu c cht rn A. Cho A tc dng vi dung dch NaOH d thu c 3,36(l) kh(ktc), cn li cht rn B. Cho B tc dng vi H2SO4 long d, thu c 8,96(l) kh(ktc). Tnh khi lng mi cht trong hn hpX Cu 56.Tin hnh phn ng nhit nhm vi Fe2O3 trong iu kin khng c khng kh. Chia hn hp sau phn ng( trn u)thnh 2 phn. Phn 2 c khi lng nhiu hn phn 1 l 134 gam. Cho phn 1 tc dng vi dung dchNaOH d thu c 16,8(l) H2(ktc). Phn 2 ho tan bng dung dchHCl d thy c 84(l) kh H2(ktc) thot ra. Cc phn ng xy ra hon ton. Tnh khi lng Fe to thnh sau phn ng nhit nhm. Cu 57.Hn hp M gm Fe3O4, CuO, Al, khi lng hn hpM l: 5,54 gam. Sau khi thc hin phn ng nhit nhm hon ton, thu c cht rn A. Ho tan A trong dung dchHCl d th thu c H2 thot ra ti a l 1,344(l)(ktc). Nu ho tan A trong dung dch NaOH d th sau phn ng thu c 2,96 gam cht rn. Tnh %m cc cht trong hn hpA. Cu 58. Hn hp A gm Al v mt oxit st. Chia hn hp A thnh 2 phn bng nhau. Phn 1: Cho tc dng vi dung dchH2SO4 long thu c 0,672(l) kh(ktc). Phn 2: Thc hin phn ng nhit nhm hon ton, thu c hn hpB, cho B tc dng vi dung dchNaOH d thu c 134,4 ml kh(ktc) sau cho tip dung dchH2SO4 long, d vo thu c 0,4032(l) H2(ktc). Xc nh cng thc ca oxit st. Cu 59.Ho tan hon ton 1 t oxit st bng dung dch H 2SO4 c, nng ta thu c 2,24(l) SO2(ktc), phn dung dch em c cn c 120 gam mui khan. 1. Xc nh cng thc ca oxit st. 2. Trn 10,8 gam bt Al vi 34,8 gam bt oxit st trn ri tin hnh phn ng nhit nhm. Ho tan hon ton hn hp cht rn sau phn ng bng dung dch H 2SO4 20%(d = 1,14 gam/ml) th thu c 10,752(l) H2(ktc).Tnh hiu sut ca phn ng nhit nhm. Tnh th tch ti thiu H2SO4 dng. Cu 60.Mt hn hp gm Al v mt oxit st dng bt, c chia thnh 2 phn bng nhau. ho tan ht phn 1 cn 200 ml dung dchHCl 0,675M, thu c 0,84(l) H2(ktc). Nung phn 2 nhit cao. Sau khi phn ng hon ton, ly sn phm cho tc dng vi dung dch NaOH d thy cn 1,12 gam cht rn khng tan. 1. Xc nh cng thc ca oxit st. 2. Tnh khi lng ca cc cht trong hn hp ban u. Cu 61. Hn hp A c khi lng 8,14 gam gm CuO, Al 2O3 v mt oxit ca st. Cho H 2 d qua A nung nng, sau khi phn ng xong thu c 1,44 gam H2O. Ho tan hon ton A cn dng 170 ml dung dch H2SO4long 1M, c dung dch B.Cho B tc dng vi dung dch NaOH d, lc ly kt ta em nung trong khng kh n khi lng khng i, c 5,2 gam cht rn.Xc nh cng thc ca oxit st v khi lng tng oxit trong A. (HBK HN 2001-2002) B.TRC NGHIM Cu 1. Thi t t hn hp kh CO, H2 qua hn hp CaO, Fe3O4, Al2O3, ZnO, Na2O, MgO nhit cao ti d. Sau khi phn ng xy ra hon ton thu c hn hp X gm: A.3 kim loi v 3 oxt kim loi. B.2 kim loi v 4 oxt kim loi C. 4 klim oi v 2oxt kim loi. D.5 kim loi. Cu 32. Cho kim loi M tc dng vi dung dchH2SO4 long ly kh H2 kh oxit ca kim loi N (cc phn ng u xy ra). M v N ln lt l nhng kim loi no sau y: A. Cu,Fe B. Ag,Cu C. Cu,Ag D. Fe,Cu Cu 33. Cho kim loi X tc dng vi dung dchHCl ly kh H2. Nu dng kh ny kh oxit kim loi Y. X v Y c th ln lt l kim loi no sau y: A. Fe,Mg B. Fe,Ca C. Cu,Fe D. Tt c u sai Cu 26. Cho kh CO(d) i qua ng s nung nng ng hn hp X gm Al2O3, MgO, Fe3O4, CuO thu c cht rn Y. Cho Y vo dung dch NaOH(d), khuy k thy cn li phn khng tan Z. Gi s cc phn ng xy ra hon ton. Phn khng tan Z gm: A. Mg, Fe, Cu, Al. B. Mg, Fe, Cu. C. MgO, Fe3O4, Cu. D. MgO, Fe, Cu. Cu 92. (A-07): Cho lung kh H2 d qua hn hp cc oxit CuO, Fe 2O3, ZnO, MgO nung nng nhit cao. Sau phn ng, hn hp cht rn cn li l: A. Cu, Fe, ZnO, MgO. B. Cu, Fe, Zn, Mg. C. Cu, Fe, Zn, MgO. D. Cu, FeO, ZnO, MgO. Cu 2. Thc hin phn ng nhit nhm hon ton hn hp X gm Al v Fe3O4 (trong k khng c kk) ri chia cht rn sau phn ng thnh 2 phn bng nhau: 5

- Phn 1: Tc dng vi dung dch NaOH(d) thu c 6,72 lt kh(ktc). - Phn 2: Tc dng vi dung dch HCl(d) thu c 26,88 lt kh(ktc). Khi lng ca hn hp X l: A. 96,6g. B. 193,2g. C. 96,9g. D. 185,4g. Cu 3. Cho V lt hn hp kh (ktc) gm CO v H2 p vi 1lng d hn hp rn gm CuO v Fe3O4 nung nng. Sau khi cc p xy ra hon ton, khi lng hn hp rn gim 0,32g. Gi tr ca V l: A. 0,224. B. 0,448. C. 0,112. D. 0,560. Cu 4. Nung nng m gam hn hp v Fe2O3(trong k khng c kk) n p hon ton, thu c hn hp rn Y. Chia Y thnh 2 phn bng nhau: - Phn 1: Tc dng vi dung dch H2SO4 long(d), sinh ra 3,08 lt kh H2(ktc); - Phn 2: Tc dng vi dung dch NaOH(d), sinh ra 0,84 lt kh H2(ktc). Gi tr ca m l: A. 29,43. B. 29,40. C. 22,75. D. 21,40. Cu 5. Hn hp A c khi lng 17,86g gm CuO, Al2O3 v FeO. Cho H2 d i qua A nung nng, sau khi p xong thu c 3,6g H2O.Mt khc, ha tan hon ton A bng dung dch HCl(d), c dung dch B. C cn dung dch B thu c 33,81g mui khan. Khi lng Al2O3 trong hn hp ban u l: A. 3,06g. B. 1,53g. C. 3,46g. D. 1,86g. Cu 6. Trn 0,81g bt Al vi 3,2g Fe2O3 v 8g CuO ri tin hnh p nhit nhm thu c hn hp A. Ha tan hon ton A trong dung dch HNO3 V lt(ktc) hn hp kh X gm NO v NO2 c t l s mol tng ng l 1:3. Gi tr ca V l:A. 1,120. B. 0,896. C. 1,344. D. 0,672. Cu 7. Nung 5g hn hp X gm Ca, CuO, Fe2O3, Al2O3 trong bnh chn khng thu c cht rn Y. Cho Y t/d ht vi axt HNO3(va ) thu c dung dch Z cha 4 mui v 0,336 lt NO(sp kh duy nht, ktc). % khi lng Ca trong hn hp X l: A. 18%. B. 20%. C. 15%. D. 10%. Cu 8. Hn hp X gm FeO, Fe3O4 v Fe2O3. kh hon ton 3,04g hn hp X cn va 0,1g H2. Nu ha tan ht 3,04g hn hp X bng dung dch H2SO4 c, nng th th tch kh SO2(sp kh duy nht,ktc) thu c l: A. 0,224. B. 0,336. C. 0,448. D. 0,896. Cu 9. Cho 0,3mol FexOy tham gia p nhit nhm hon ton thy to ra 0,4mol Al2O3. Cng thc ca oxt st l:A. Fe2O3. B. FeO. C. Fe3O4. D. Khng xc nh c. Cu 10. Kh hon ton m gam hn hp X gm FeO v Fe2O3 bng H2(d), thu c 9g H2O v 22,4g cht rn. % s mol ca FeO trong hn hp X l: A. 66,67. B. 20,56. C. 26,67. D. 40,67. Cu 11. Cho dng kh CO i qua ng s ng m gam Fe2O3 nung nng 1thi gian thu c 13,42g hn hp X gm Fe, FeO, Fe2O3, Fe3O4. Ha tan hon ton X bng HNO3 c, nng (d) c 5,824 lt kh NO2(sp kh duy nht, ktc). Gi tr ca m l: A. 4,00. B. 8,00. C.16,0. D. 15,5. Cu 12. Thi lung kh CO qua ng s ng m gam hn hp gm CuO, Fe2O3, FeO, Al2O3 nung nng.Sau 1thi gian thu c 215g cht rn v kh X. Dn kh X vo dung dch nc vi trong d thy c 15g kt ta.Gi tr ca m l: A. 217,4. B. 249. C. 219,8. D. 230. Cu 13. Kh hon ton 4,06g 1oxt kim loi bng kh CO nhit cao thnh kim loi. Dn ton b kh sinh ra vo bnh ng dung dch Ca(OH)2 (d) to thnh 7,00g kt ta. Nu ly lng kim loi sinh ra ha tan ht vo dung dch HCl(d) th thu c 1,176 lt kh H2(ktc). Cng thc ca oxt kim loi l: A. FeO. B. CrO. C. Fe2O3. D. Fe3O4. Cu 14. Trn 5,4g bt Al vi 14g Fe2O3 ri tin hnh p nhit nhm (khng c kk, Fe2O3 b kh v Fe). Sau 1thi gian lm ngui hn hp v ha tan bng dung dch NaOH(d), cho n khi cc p hon ton thu c 1,68 lt kh(ktc). Hiu sut ca p nhit nhm l: A. 66,67%. B. 92,68%. C. 75%. D. 85,71%. Cu 15. Ha tan ht 4,0g oxt FexOy cn dng 52,14ml dung dch HCl 10%(D=1,05g/ml). kh ha hon ton 4,0g oxt st ny cn t nht th tch kh CO(ktc) l: A. 1,68lt. B. 1,545lt. C. 1,24lt. D. 0,056lt. Cu 16. 5,6g bt Fe trong kk 1thi gian thu c 7,2g hn hp X gm cc oxt st v st d. Thm 10,8g bt Al vo X ri thc hin p nhit nhm hon ton c hn hp Y. Th tch kh thot ra(ktc) khi ha tan Y bng dung dch HCl(d) l: A. 13.44lt. B. 11,20lt. C. 6,72lt. D. 8,96lt.

Cu 17. Cho hn hp kh CO v H2 i qua hn hp bt gm cc oxt: Al2O3, ZnO, CuO, Fe2O3, Ag2O t nng, sau 1thi gian thu c ch rn khan c khi lng gim 4,8g so vi ban u. Ha tan ton b lng cht rn ny bng dung dch HNO3 long(d) sinh ra V lt kh NO(sp kh duy nht, ktc). Gi tr ca V l: A. 4,48. B. 6,72. C. 5,60. D. 2,24. Cu 18. un nng hn hp gm Al v 16g Fe2O3(trong k khng c kk) n p xy ra hon ton, thu c hn hp rn X. Cho X t/d va vi V ml dung dch NaOH 1M sinh ra 3,36 lt H2(ktc). Gi tr ca V l: A. 100. B. 200. C. 300. D. 150. Cu 19. Cho t t V lt hn hp kh CO, H2 i qua ng s ng 16,8g hn hp 3oxt: CuO, Fe2O3, Al2O3. Sau p thu c hn hp kh v hi nng hn hn hp CO, H2 ban u 0,32g. Gi tr ca V v khi lng cht rn cn li trong ng s sau khi nung nng ln lt l: A. 4,48 lt v 13,6g. B. 0,448 lt v 16,48g. C. 0,336lt v 16,56g. D. 0,112lt v 16g. Cu 20. Kh m gam Fe3O4 bng kh H2 thu c hn hp X gm Fe v FeO. Hn hp X t/d va ht vi 3 lt dung dch H2SO4 0,2M (long).Gi tr ca m l: A. 46,4. B. 23,2. C. 11,6. D. 34,8. Cu 21. Cho 18,0g hn hp X gm Fe, FeO, Fe2O3, Fe3O4 p va vi 300ml dung dch H2SO4 1M thu c 1,12 lt kh(ktc). Nu kh hon ton 18,0g hn hp trn bng CO(d) ri cho cht rn to thnh p ht vi dung dch HNO3(d) th th tch kh NO(sp kh duy nht, ktc) thu c l: A. 6,72lt. B. 5,60lt. C. 4,48lt. D. 7,84lt. Cu 22.Dn kh CO(d) i qua hn hp gm 0,1mol Fe3O4; 0,1mol CuO v 0,15mol MgO n khi cc p xy ra hon ton.Cho ton b cht rn thu c vo dung dch H2SO4 long(d) thu c V lt kh(ktc). Gi tr ca V l: A. 13,44. B. 10,08. C. 6,72. D. 5,60. Cu 23. Ha tan hon ton 7,40g hn hp X gm FeO, Fe3O4, Fe2O3 bng dung dch H2SO4 long(d) sinh ra 17,8 gam mui sunfat khan. Nu cng cho hn hp X trn p vi lng d kh CO nhit cao n p hon ton ri dn ton b kh thu c vo dung dch nc vi trong d th khi lng kt ta to thnh l: A. 15,0g. B. 24,0g. C. 13,0g. D. 18,0g. Cu 24.Thi mt lung kh CO i qua hn hp Fe v Fe2O3 nung nng c kh B v cht rn D. Cho B qua nc vi trong d thy to ra 6,00g kt ta. Ha tan D bng H2SO4 c, nng(d) thy to ra 0,18 mol kh SO2(sp kh duy nht) v dung dch cha 24,0g mui. Phn trm s mol ca Fe trong hn hp ban u l: A. 45,00%. B. 80,00%. C. 75,00%. D. 66,67%. Cu 25. Cho lung kh CO i t t qua ng s ng m gam hn hp gm CuO, Fe2O3, MgO v FeO nung nng. Sau mt thi gian cn li 14,4g cht rn. Kh thot ra khi ng s c hp th vo dung dch Ca(OH)2(d) c 16,0g kt ta. Gi tr ca m l: A. 18,67. B. 19,26. C. 19,60. D. 16,70. Cu 28. Thi rt chm 2,24 lt(ktc) mt hn hp kh gm CO v H2 qua 1 ng s ng hn hp Al2O3, CuO, Fe3O4, Fe2O3 c khi lng 24,0g (d) nung nng. Sau khi p hon ton thu c cht rn c khi lng l: A. 20,6g. B. 21,7g. C. 18,8g. D. 22,4g. Cu 29. Nung hn hp gm 15,2g Cr2O3 v m gam Al nhit cao. Sau khi cc p xy ra hon ton, thu c 23,3g hn hp rn X. Cho ton b X phn ng vi axt HCl(d) thot ra V lt kh H2(ktc). Gi tr ca V l: A. 3,36. B. 7,84. C. 4,48. D. 10,08. Cu 31. Khi kh 5 gam oxit ca mt kim loi thu c 3,995 gam kim loi. Khi oxi ho 1,270 gam kim loi ny to thnh 1,590 gam oxit tng ng. Kim loi ny l: A. Zn B. Fe C. Al D. Cu Cu 34. kh 6,4 gam 1 oxit kim loi cn 2,688(l) kh H2(ktc). Nu ly lng kim loi cho tc dng vi dung dchHCl d th thu c 1,792(l) kh(ktc). Kim loi l: A. Mg B. Al C. Fe D.Cr Cu 35. Cho kh CO kh hon ton mt lng hn hp gm FeO, Fe 2O3, Fe3O4 gii phng ra 6,72 lt CO 2 (ktc). Tnh th tch CO (ktc) tham gia p? A. 4,48 lt. B. 6,72 lt. C. 8,96 lt. D. 2,24 lt. Cu 36. Dng kh CO (va ) kh 1,2g hn hp CuO v Fe 2O3 thu c 0,88g hn hp hai kim loi. Tnh th tch CO2 (ktc) thu c sau p? A. 15,568 lt. B. 0,448 lt. C. 4,48 lt. D. Kt qu khc. Cu 38. Dn kh CO (ktc) vo a gam hn hp 2 oxit Fe2O3 v CuO un nng nhit cao p xy ra hon ton thu c 2g hn hp kim loi v 0,56 lt CO2 (ktc). Tnh a? A. 24g. B. 2,4g. C. 4,2g. D. Kt qu khc. 7

Cu 39. Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn hp rn gm CuO, Fe 2O3 ( nhit cao). Sau khi cc phn ng xy ra hon ton, thu c kh X. Dn ton b kh X trn vo lng d dung dch Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l: A. 1,120. B. 0,896. C. 0,448. D. 0,224. Cu 40. Thi mt lung kh CO i qua ng s ng m gam hn hp Fe 3O4 v CuO nung nng thu c 2,32 gam hn hp rn. Ton b kh thot ra cho hp th ht vo bnh ng dung dch Ca(OH) 2 d thu c 5 gam kt ta. Gi tr ca m l: A.3,22 gam. B.3,12 gam. C.4,0 gam. D.4,2 gam. Cu 43. Nung 3,2g hn hp gm CuO v Fe2O3 vi cacbon trong iu kin khng c khng kh v phn ng xy ra hon ton thu c 0,672 lt (ktc) hn hp kh CO v CO 2 c t khi so vi hiro l 19,33. Thnh phn% theo khi lng ca CuO v Fe2O3 trong hn hp u l: A. 50% v 50%. B. 66,66% v 33,34%. C. 40% v 60%. D. 65% v 35%. Cu 47. Cho t t mt lung kh CO i qua ng s ng m gam hn hp X gm Fe, FeO, Fe 2O3 v Fe3O4 un nng th thu c 64g Fe. Kh i ra sau phn ng cho tc dng vi dung dich Ca(OH)2 d th thu c 40g kt ta. Cc phn ng xy ra hon ton. Gi tri ca m l: A. 68g B. 70,4g C. 72g D. 86g Cu 48. Kh m gam hn hp gm cc oxit CuO, FeO, Fe 3O4 v Fe2O3 bng kh CO nhit cao, thu c 40 gam hn hp cht rn B v 13,2 gam kh CO2 Gi tri ca m l: A. 36,2 gam B. 44,8 gam C. 22,4 gam D. 8,4 gam Cu 49. Thi rt chm 2,24 lt hn hp kh (ktc) gm CO/H 2 qua mt ng s ng hn hp bt Al2O3, CuO, Fe3O4, Fe2O3 c khi lng 24 gam nung nng. Hn hp kh v hi thot ra khi ng s c hp th hon ton bi dung dich Ca(OH)2 d thu c 5 gam kt ta trng. Khi lng cht rn cn li trong ng s l: A. 22,4 B. 20,8 C. 16,8 D. 11,2 Cu 50. Kh hon ton 31,9 gam hn hp Fe 2O3 v FeO bng H2 nhit cao, to thnh 9 gam H 2O. Khi lng st iu ch c t hn hp trn l: A. 23,9 B. 19,2 C. 23,6 D. 30,581 Cu 51. Kh hon ton 4,64 gam hn hp cc oxit ca sut bng CO nhit cao. Kh sinh ra sau phn ng c dn vo bnh ng nc vi trong d thu c 8 gam kt ta. Khi lng st thu c l: A. 3.36 B. 3,63 C .6,33 D. 33,6 Cu 52.Thi 8,96 lt CO2 (ktc) qua 16 gam FexOy nung nng. Dn ton b lng kh sau phn ng qua dung dch Ca(OH)2 d, thy to ra 30 gam kt ta. Khi lng st thu c l: A. 9,2 B. 6,4 C. 9,6 D.11,2 Cu 52. Cho CO qua 1,6 gam Fe2O3 t nng (gi s ch xy ra phn ng kh Fe2O3 thnh Fe). Kh thu c cho qua nc vi d thu c 3 gam kt ta. Phn trm theo khi lng Fe2O3 b kh v th tch kh CO (ktc) phn ng l : A. 100% v 6,72 lt B. 80% v 0,672 lt C.16,0gam v 0,672 lt D. 100% v 44,8 lt Cu 53.Kh hon ton 17.6 gam hn hp X gm Fe, FeO, Fe2O3 cn 2,24 lt CO (ktc). Khi lng Fe thu c sau phn ng. A. 5,60 gam B. 6.72 gam C 16,0 gam D. 11,20 gam Cu 54. Thi mt lung kh CO i qua ng s ng m gam hn hp gm Fe 3O4 v cho nung nng thu c 2,32 gam hn hp cht rn. Ton b kh thot ra cho hp th ht vo bnh ng dung dich Ca(OH) 2 d thu c 5 gam kt ta. Gi tri ca m l: A. 3,22 gam B. 3,12 gam C. 4,0 gam D. 4,2 gam Cu 55. Cho kh CO i qua ng s ng 16 gam Fe2O3 un nng, sau phn ng thu c hn hp X gm Fe, Fe2O3 Fe3O4. Ho tan X bng lng d H2SO4 c nng d thu c dung dich Y. C cn Y th lng mui khan thu c l: A. 20 gam B. 32 gam C. 40 gam D. 48 gam Cu 56. kh hon ton hn hp CuO, FeO cn 4,48 lt H2 (ktc). Nu cng kh lng hn hp trn bng CO ri cho ton b sn phm i qua dung dich nc vi trong d th lng kt ta sinh ra l: A. 10,0 gam B. 20,0 gam C. 15,0 gam D. 7,8 gam Cu 57. Cho mt lung hn hp kh gm CO v H2 thiu i qua 3,92 gam hn hp X gm Fe2O3 v Fe3O4 nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh A v cht rn B. Cho A qua bnh 1 ng H2SO4 c, ri qua bnh 2 ng nc vi trong d.Kt qu bnh 1 tng thm 0,54 gam v bnh 2 to ra 4 gam kt ta. Tnh khi lng cht rn B. A. 2,8 gam B. 8,2 gam . C. 3,0 gam D. 2,96 gam 8

Cu 58. Cho 16,8 lt hn hp X gm CO v CO2(ktc) c khi lng l 27g,dn hn hp X qua than nng thu c V lt kh Y.Dn kh Y qua ng ng 160g CuO(nung nng)th thu c m gam rn. a) S mol CO v CO2 ln lt l: A. 0,0375 v 0,0375 B. 0,25 v 0,5 C. 0,5 v 0,25 D. 0,375 v 0,375 b) V c gi tr l : A.1,68 B. 16,8 C. 25,2 D. 2,8 c)Gi tr ca m l : A. 70 B.72 C.142 D.Kt qu khc Cu 59. Nung 4g hn hp X gm CuO v FeO vi cacbon d trong iu kin khng c khng kh v phn ng xy ra hon ton thu c 1,12 lt (ktc) hn hp kh Y gm CO v CO 2 v cht rn Z.Dn Y qua bnh ng nc vi trong d th thu c 0,5g kt ta. a) Khi lng ca Z l: A. 3,12g B. 3,21g C.3g D. 3,6g b)Khi lng CuO v FeO ln lt l : A. 0,4g v 3,6g B. 3,6g v 0,4g C. 0,8g v 3,2g D. 1,2g v 2,8g Cu 61. Cho mt lung kh CO i qua ng s ng m(g) Fe 2O3 nung nng,mt thi gian thu c 13,92g cht rn X gm Fe,Fe3O4,FeO v Fe2O3.Cho X tc dng vi dung dch HNO 3 c nng thu c 5,824 lt NO2 (ktc). a) Th tch kh CO dng (ktc). A. 3.2 lt B. 2,912 lt C. 2,6 lt D. 2,5 lt b) m c gi tr l : A. 16 B. 15 C. 14 D. 17 Cu 62. Cho mt lung kh CO i qua ng ng m(g) Fe2O3 nung nng.Sau mt thi gian thu c 44,46g hn hp X gm Fe3O4,FeO,Fe,Fe2O3 d.Cho X tc dng ht vi dung dch HNO3 lang thu c 3,136 lt NO(ktc) duy nht. a)Th tch CO dng (ktc) l: A. 4,5lt B. 4,704 lt C. 5,04 lt D. 36,36 lt b) m c gi tr l :A. 45 B. 47 C. 47,82 D. 47,46 lt Cu 63. Cho mt lung kh CO i qua ng ng 10g Fe 2O3 nung nng.Sau mt thi gian thu c m(g) hn hp X gm 3 oxit st.Cho X tc dng ht vi dung dch HNO 3 0,5M (va ) thu c dung dch Y v 1,12 lt NO (ktc) duy nht. a)Th tch CO dng (ktc) l: A. 1,68 B. 2,24 C. 1,12 D. 3,36 b) m c gi tr l: A. 7,5g B. 8,8 C. 9 D. 7 c) Th tch dung dch HNO3 dng l: A. 0,75 lt B. 0,85 lt C. 0,95 lt D. 1 lt Cu 64. Cho lung kh CO i qua ng s ng m(g) Fe 2O3 nung nng.Sau mt thi gian thu c 6,96g hn hp rn X,cho X tc dng ht vi dung dch HNO 3 0,1M va thu c dung dch Y v 2,24 lt hn hp kh Z gm NO v NO2 c t khi so vi hidro l 21,8. a) Hp th ht kh sau khi nung vo nc vi trong d th thu c kt ta c khi lng l: A. 5,5g B. 6g C. 6,5g D. 7g b) m c gi tr l : A. 8g B. 7,5g C. 7g D. 8,5g c) Th tch dung dch HNO3 dng A. 4 lt B.1 lt C. 1,5 lt D. 2 lt d)Nng mol/lt ca dung dch Y l: A. 0,1 B. 0,06 C. 0,025 D. 0,05 e) C cn dung dch Y th thu c bao nhiu gam mui? A. 24g B. 24,2g C. 25g D.30g Dng cho cu 66,67: Dn t t V lt hn hp kh X (ktc) gm CO v H 2 qua ng s cha 16,8 gam hn hp CuO, Fe3O4 v Al2O3 nung nng n khi X phn ng ht, thu c hn hp kh v hi nng hn khi lng ca X l 0,32 gam. Cu 66. Gi tr ca V l:A. 0,112. B. 0,224. C. 0,448. D. 0,896. Cu 67. S gam cht rn cn li trong ng s l: A.12,12. B. 16,48. C. 17,12. D. 20,48. Cu 68. Dn mt lung kh CO d qua ng s ng Fe 3O4 v CuO nung nng n khi phn ng hon ton thu c 2,32 gam hn hp kim loi. Kh thot ra khi bnh c dn qua dung dch nc vi trong d thu c 5 gam kt ta. Tng s gam 2 oxit ban u l: A. 6,24. B. 5,32. C. 4,56. D. 3,12. 9

Cu 70. Hn hp A gm Fe2O3; Fe3O4; FeO vi s mol bng nhau. Ly x gam A cho vo mt ng s, nung nng ri cho 1 lung kh CO i qua, ton b kh CO 2 sinh ra c hp th ht vo dung dch Ba(OH) 2 d thu c y gam kt ta. Cht rn cn li trong ng s c khi lng 19,200 gam gm Fe, FeO v Fe 3O4, Fe2O3. Cho hn hp ny tc dng ht vi dung dch HNO3 thu c 2,24lt kh NO duy nht (ktc). 1.Gi tr ca x v y tng ng l: A. 20,880 v 20,685. B. 20,880 v 1,970. C. 18,826 v 1,970. D. 18,826 v 20,685. 2.S mol HNO3 tham gia phn ng l: A. 1,05. B. 0,91. C. 0,63. D. 1,26. Cu 72. Cho hn hp A gm 0,1 mol Fe v 0,2 mol Fe2O3 vo trong mt bnh kn dung tch khng i 11,2 lt cha CO (ktc). Nung nng bnh 1 thi gian, sau lm lnh ti 0 oC. Hn hp kh trong bnh lc ny c t khi so vi H2 l 15,6. 1.So vi trc th nghim th sau th nghim p sut trong bnh A. Tng. B. Gim C. Khng i. D. Mi u gim, sau tng. 2.S gam cht rn cn li trong bnh sau khi nung l. A. 20,4. B. 35,5. C. 28,0. D. 36,0. 3.Nu phn ng xy ra v hiu sut 100% th s gam cht rn sau khi nung l: A. 28,0. B. 29,6. C. 36,0. D. 34,8. Cu 75. (Kh): Hn hp A gm CuO v MO theo t l mol tng ng l 1: 2 (M l kim loi ha tr khng i). Cho 1 lung H2 d i qua 2,4 gam A nung nng thu c hn hp cht rn B. ho tan ht B cn 40 ml dung dch HNO3 2,5M v thu c V lt kh NO duy nht (ktc). Hiu sut cc phn ng t 100%. 1. Kim loi M l: A. Ca. B. Mg. C. Zn. D. Pb. 2.Gi tr ca V l: A. 0,336. B. 0,448. C. 0,224. D. 0,672. Cu 77. Cho kh CO qua ng cha 15,2g hn hp gm CuO v FeO nung nng. Sau mt thi gian thu c hn hp kh B v 13,6g cht rn C. Cho B tc dng vi dung dch Ca(OH) 2 d thu c m gam kt ta. Gi tr ca m l:A. 15,0. B. 10,0. C. 20,0. D. 25,0. Cu 78. Kh hon ton mt oxit ca kim loi M cn dng 1,344 lt H 2(ktc). Ton b lng kim loi M sinh ra cho tc dng vi dung dch HCl d thu c 1,008 lt H2 (ktc). Cng thc oxit l A. Fe3O4. B. Fe2O3. C. FeO. D. ZnO Dng cho cu 79,80: Kh hon ton 32,20 gam hn hp gm CuO, Fe 2O3 v ZnO bng CO nhit cao thu c 25,00 gam hn hp X gm 3 kim loi. Cho X tc dng va vi dung dch HNO 3 th thu c V lt kh NO duy nht (ktc) v dung dch cha m gam mui (khng cha NH4NO3). Cu 79. Gi tr ca m l:A. 52,90. B. 38,95. C. 42,42. D. 80.80. Cu 80: Gi tr ca V l: A. 20,16. B. 60,48. C. 6,72. D. 4,48. Cu 81. Chia 47,2 gam hn hp gm CuO, Fe2O3 v Fe3O4 thnh 2 phn bng nhau. Phn 1 kh hon ton bng CO d nhit cao thu c 17,2 gam 2 kim loi. Phn 2 cho tc dng va vi dung dch H 2SO4 long, thu c m gam mui. Gi tr ca m l: A. 124,0. B. 49,2. C. 55,6. D. 62,0. Cu 82. Cho H2 d qua 8,14 gam hn hp A gm CuO, Al2O3 v FexOy nung nng. Sau khi phn ng xong, thu c 1,44g H2O v a gam cht rn. Gi tr ca a l: A. 6,70. B. 6,86. C. 6,78. D. 6,80. Dng cho cu 83,84: Chia 48,2 gam hn hp gm CuO, Fe2O3 v ZnO thnh 2 phn bng nhau. Phn 1 cho tc dng vi dung dch H2SO4 long, d ri ly dung dch thu c cho tc dng vi dung dch NaOH th thu c lng kt ta ln nht l 30,4 gam. Phn 2 nung nng ri dn kh CO i qua n kh phn ng hon ton thu c m gam hn hp 3 kim loi. Cu 83. Gi tr ca m l:A. 18,5. B. 12,9. C. 42,6. D. 24,8. Cu 84. S lt kh CO (ktc) tham gia phn ng l: A. 15,68. B. 3,92. C. 6,72. D. 7,84. Dng cho cu 85,86: Cho 44,56 gam hn hp A gm FeO, Fe2O3 v Fe3O4 tc dng hon ton vi CO d (nung nng) thu c a gam cht rn. Dn kh thot ra vo dung dch nc vi trong d thu c 72,00 gam kt ta. Nu cng cho lng A nh trn tc dng va vi Al (nung nng chy) th thu c m gam cht rn. Bit cc phn ng kh st oxit ch to thnh kim loi. Cu 85. Gi tr ca a l: A. 21,52, B. 33,04. C. 32,48. D. 34,16. Cu 86. Gi tr ca m l:A. 73,72. B. 57,52. C. 51,01. D. 71,56. Cu 87. Kh hon ton 18,0 gam mt oxit kim loi M cn 5,04 lt kh CO (ktc). Cng thc ca oxit l: 10

A. Fe2O3. B. FeO. C. ZnO. D. CuO. Dng cho cu 88,89,90: Kh hon ton 69,6 gam hn hp A gm FeO, Fe 2O3, Fe3O4 v CuO nhit cao thnh kim loi cn 24,64 lt kh CO (ktc) v thu c x gam cht rn. Cng cho 69,6 gam A tc dng vi dung dch HCl va thu c dung dch B cha y gam mui. Cho B tc dng vi dung dch NaOH d thy to thnh z gam kt ta. Cu 88. Gi tr ca x l:A. 52,0. B. 34,4. C. 42,0. D. 28,8. Cu 89. Gi tr ca y l:A 147,7. B. 130,1. C. 112,5. D. 208,2. Cu 90. Gi tr ca z l:A. 70,7. B. 89,4. C. 88,3. D. 87,2. Cu 91. Ho tan hon ton 20,0 gam mt oxit kim loi bng dung dch H 2SO4 long thu c 50,0 gam mui. Kh hon ton lng oxit thnh kim loi nhit cao cn V lt kh CO (ktc). Gi tr ca V l: A. 2,80. B. 5,60. C. 6,72. D. 8,40. Cu 95. Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn hp rn gm CuO, Fe 2O3 ( nhit cao). Sau khi cc phn ng xy ra hon ton, thu c kh X. Dn ton b kh X trn vo lng d dung dch Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l: A. 0,896. B. 1,120. C. 0,224. D. 0,448. Cu 97. Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit st n khi phn ng xy ra hon ton.Hn hp kh thu c sau phn ng c t khi so vi hiro bng 20. Cng thc ca oxit st v phn trm th tch ca kh CO2 trong hn hp kh sau phn ng. A. Fe2O3; 65%. B. Fe3O4; 75%. C. FeO; 75%. D. Fe2O3; 75%. Cu 98. (H A -2008). Nung nng m gam Al v Fe2O3 trong mi trng khng c khng kh n khi phn ng xy ra hon ton thu c hn hp rn Y. Chia Y thnh hai phn bng nhau: Phn I tc dng vi dung dch H2SO4 long d thu c 3,08 lt H2 (ktc). Phn II tc dng vi dung dch NaOH d sinh ra 0,84 lt kh H2 (ktc). Gi tr ca m l: A. 21,4 B. 29,4 C. 29,43 D. 22,75 Cu 99. (H A -2008). Cho V lt hn hp kh ( ktc) gm CO v H 2 phn ng vi mt lng d hn hp rn gm CuO v Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr ca V l: A. 0,448. B. 0,112. C. 0,224. D. 0,560. Cu 100. (H A -2009). Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al 2O3 nung nng n khi phn ng hon ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l: A. 0,8 gam. B. 8,3 gam. C. 2,0 gam. D. 4,0 gam. Cu 101. (H B-2009). Nung nng m gam Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy ra hon ton thu c cht rn X. Cho X tc dng vi dung dch NaOH d thu c dung dch Y, cht rn Z v 3,36 lt H2 (ktc). Sc kh CO2 d vo dung dch Y thu c 39 gam kt ta. Gi tr ca m l: A. 48,3 B. 57,0 C. 45,6 D. 36,7 Cu 102. (H B -2010). Hn hp X gm CuO v Fe2O3. Ho tan hon ton 44 gam X bng dung dch HCl (d), sau phn ng thu c dung dch cha 85,25 gam mui. Mt khc, nu kh hon ton 22 gam X bng CO (d), cho hn hp kh thu c sau phn ng li t t qua dung dch Ba(OH)2 (d) th thu c m gam kt ta. Gi tr ca m l : A. 76,755. B. 73,875. C. 147,750. D. 78,875. Cu 103.Cho 3,04 gam hn hp X gm FeO, Fe3O4, Fe2O3. kh hon ton hn hp X th cn 0,1 gam hiro. Mt khc, ho tan hn hp X trong H2SO4 c, nng th th tch kh SO2 (l sn phm kh duy nht ktc) l : A. 112 ml. B. 224 ml. C. 336 ml. D. 448 ml. Cu 104.(CA -2011). Nung hn hp gm 10,8 gam Al v 16,0 gam Fe2O3 (trong iu kin khng c khng kh),sau khi phn ng xy ra hon ton thu c cht rn Y. Khi lng kim loi trong Y l A. 5,6 gam. B. 22,4 gam. C. 11,2 gam. D. 16,6 gam. Cu 105.(H B -2011). Cho hi nc i qua than nng , thu c 15,68 lt hn hp kh X (ktc) gm CO, CO2 v H2. Cho ton b X tc dng ht vi CuO (d) nung nng, thu c hn hp cht rn Y. Ho tan ton b Y bng dung dch HNO3 (long, d) c 8,96 lt NO (sn phm kh duy nht, ktc). Phn trm th tch kh CO trong X l: A. 18,42%. B. 57,15%. C. 14,28%. D. 28,57%. Cu 106.(H B -2011). Thc hin phn ng nhit nhm hn hp gm m gam Al v 4,56 gam Cr2O3 (trong iu kin khng c O2), sau khi phn ng kt thc, thu c hn hp X. Cho ton b X vo mt lng d dung dch HCl (long, nng), sau khi cc phn ng xy ra hon ton, thu c 2,016 lt H2 (ktc). Cn nu 11

cho ton b X vo mt lng d dung dch NaOH (c, nng), sau khi cc phn ng kt thc th s mol NaOH phn ng l: A. 0,16 mol. B. 0,14 mol. C. 0,06 mol. D. 0,08 mol. Cu 107.(H A -2012).Dn lung kh CO i qua hn hp gm CuO v Fe2O3 nung nng, sau mt thi gian thu c cht rn X v kh Y. Cho Y hp th hon ton vo dung dch Ba(OH)2 d, thu c 29,55 gam kt ta. Cht rn X phn ng vi dung dch HNO3 d thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l: A. 2,24. B. 4,48. C. 6,72. D. 3,36. Cu 108.(H B -2012). Hn hp X gm Fe3O4 v Al c t l mol tng ng 1 : 3. Thc hin phn ng nhit nhm X (khng c khng kh) n khi phn ng xy ra hon ton thu c hn hp gm A. Al, Fe, Fe3O4 v Al2O3. B. Al2O3, Fe v Fe3O4. C. Al2O3 v Fe. D. Al, Fe v Al2O3.

C.MT S BI TP V PHN NG NHIT NHM. 1) Mt s ch khi gii bi tp: - Phn ng nhit nhm: 2nAl + 3M2On t nAl2O3 + 6M (Hn hp X) (Hn hp Y) - Thng gp: + 2Al + Fe2O3 t Al2O3 + 2Fe + 2yAl + 3FexOy t Al2O3 + 3xFe + (6x 4y)Al + 3xFe2O3 t 6FexOy + (3x 2y)Al2O3 - Nu phn ng xy ra hon ton, ty theo tnh cht ca hn hp Y to thnh bin lun. V d: + Hn hp Y cha 2 kim loi Al d ; oxit kim loi ht + Hn hp Y tc dng vi dung dch baz kim (NaOH,) gii phng H2 c Al d + Hn hp Y tc dng vi dung dch axit c kh bay ra th c kh nng hn hp Y cha (Al2O3 + Fe) hoc (Al2O3 + Fe + Al d) hoc (Al2O3 + Fe + oxit kim loi d) - Nu phn ng xy ra khng hon ton, hn hp Y gm Al2O3, Fe, Al d v Fe2O3 d - Thng s dng: + nh lut bo ton khi lng: mhn hpX = mhn hpY + nh lut bo ton nguyn t (mol nguyn t): nAl (X) = nAl (Y) ; nFe (X) = nFe (Y) ; nO (X) = nO (Y)
0
0

Ch : Nu yu cu tnh hiu sut phn ng ta gii trng hp phn ng xy ra khng hon ton. 2) Mt s v d minh ha: V d 1: Nung nng m gam hn hp Al v Fe2O3 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton , thu c hn hp rn Y. Chia Y thnh hai phn bng nhau: Phn 1: tc dng vi dung dch H2SO4 long (d) sinh ra 3,08 lt kh H2 ( ktc) Phn 2: tc dng vi dung dch NaOH (d) sinh ra 0,84 lt kh H2 ( ktc) Gi tr ca m l: A. 22,75 gam B. 21,40 gam C. 29,40 gam D. 29,43 gam

12

Hng dn: nH2(1) = 0,1375 mol ; nH2(2) = 0,0375 mol - Hn hp rn Y tc dng vi NaOH gii phng H2 Al d v v phn ng xy ra hon ton nn thnh phn hn hp rn Y gm: Al2O3, Fe v Al d - Gi nFe = x mol ; nAl d = y mol c trong 1/2 hn hp Y - T ta c h phng trnh:

nFe = 0,05 mol 2 - Theo lbt khi lng: m = (0,05.102 + 0,1.56 + 0,025.27).2 = 22,75 gam p n A - Theo lbt nguyn t i vi O v Fe: n Al 2 O3 = nFe 2 O3 = V d 2: Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y, cht rn Z v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt ta. Gi tr ca m l: A. 45,6 gam B. 57,0 gam C. 48,3 gam D. 36,7 gam Hng dn: nH2 = 0,15 mol ; nAl(OH)3 = 0,5 mol - T suy ra thnh phn hn hp rn X gm: Fe, Al2O3 (x mol) v Al d (y mol) - Cc phn ng xy ra l: 2Al + 2NaOH + 2H2O 2NaAlO2 + 3H2 Al2O3 + 2NaOH 2NaAlO2 +H2O CO2 + NaAlO2 Al(OH)3 + NaHCO3 - nH2 = 0,15 mol y = 0,1 mol - Theo lbt nguyn t i vi Al: 2x + y = 0,5 x = 0,2 mol
0,2.3 = 0,15mol mol - Theo lbt nguyn t i vi O: nO ( Fe2 O3 ) = nO ( Al 2 O3 ) nFe3O4 = 4

2 x + 3 y = 0,275 1,5 y = 0,0375

x = 0,1 y = 0,025

- Theo lbt nguyn t i vi Fe: nFe = 3nF3O4 = 3.0,15 = 0,45 mol - Theo lbt khi lng: m = 0,45.56 + 0,2.102 + 0,1.27 = 48,3 gam p n C V d 3: Thc hin phn ng nhit nhm hn hp X gm Al v mt oxit st FexOy (trong iu kin khng c khng kh) thu c 92,35 gam cht rn Y. Ha tan Y trong dung dch NaOH (d) thy c 8,4 lt kh H2 ( ktc) thot ra v cn li phn khng tan Z. Ha tan 1/2 lng Z bng dung dch H2SO4 c, nng (d) thy c 13,44 lt kh SO2 ( ktc) thot ra. Bit cc phn ng xy ra hon ton. Khi lng Al2O3 trong Y v cng thc oxit st ln lt l: A. 40,8 gam v Fe3O4 B. 45,9 gam v Fe2O3 C. 40,8 gam v Fe2O3 D.45,9 gam v Fe3O4 Hng dn: nH2 = 0,375 mol ; nSO2(c Z) = 2.0,6 = 1,2 mol - T suy ra thnh phn cht rn Y gm: Fe, Al2O3, Al d v phn khng tan Z l Fe - nH2 = 0,375 mol nAl d = 0,25 mol - nSO2 = 1,2 mol nFe =
1,2.2 = 0,8mol 3

- mAl2O3 = 92,35 0,8.56 0,25.27 = 40,8 gam (1) nAl2O3 = 0,4 mol - Theo lbt nguyn t i vi O nO ( Fe2 O3 ) = 0,4.3 = 1,2 mol x nFe 0,8 2 = = - Ta c: = cng thc oxit st l Fe2O3 (2) y nO 1,2 3 - T (1) ; (2) p n C V d 4: Trn 5,4 gam bt Al vi 17,4 gam bt Fe3O4 ri tin hnh phn ng nhit nhm (trong iu kin khng c khng kh). Gi s ch xy ra phn ng kh Fe3O4 thnh Fe. Ha tan hon ton cht rn sau phn ng bng dung dch H2SO4 long (d) thu c 5,376 lt kh H2 ( ktc). Hiu sut phn ng nhit nhm v 13

s mol H2SO4 phn ng l: A. 75 % v 0,54 mol B.80 % v 0,52 mol

0

C.75 % v 0,52 mol

D. 80 % v 0,54 mol

Hng dn: nAl = 0,2 mol ; nFe3O4 = 0,075 mol ; nH2 = 0,24 mol - Phn ng xy ra khng hon ton: 8Al + 3Fe3O4 t 4Al2O3 + 9Fe x
3 x 8

0,5x

9 x (mol) 8

nAl 2 O3 = 0.5 x 8 - Hn hp cht rn gm: nFe = x 9 3 n = ( 0 , 075 x) Fe O 8 3 4d

- Ta c phng trnh: nH2SO4phn ng =
0,16 9 .100% = 80% (1) x .2 + (0,2 x).3 = 0,24.2 x = 0,16 mol Hphn ng = 0,2 8

- nH+phn ng = 2.nFe + 3.nAl + 6.nAl2O3 + 8.nFe3O4 = 0,36 + 0,12 + 0,48 + 0,12 = 1,08 mol
1,08 = 0,54mol (2) 2

- T (1) ; (2) p n D Cu 1: Mt hn hp M gm Fe3O4, CuO v Al c khi lng 5,54 gam. Sau khi thc hn phn ng nhit nhm xong (hiu sut 100%) th thu c cht rn A. - Nu ho tan A trong dung dch HCl d th lng H2 sinh ra ti a 1,344 lt kh (ktc). - Nu ho tan A trong NaOH d th khi phn ng xong cn 2,96 gam cht rn. Tnh thnh phn % cc cht trong hn hp A. Cu 2: a. Ly 26,8 gam hn hp gm Al v Fe 2O3 thc hin hon ton phn ng nhit nhm, thu c cht rn A, cho cht rn ny ho tan hon ton trong dung dch HCl d thy thot ra 11,2 lt kh H 2 (ktc). Hy xc nh thnh phn % cc cht trong hn hp. b. Tin hnh phn ng nhit nhm vi Fe2O3 trong iu kin khng c khng kh. Chia hn hp sau phn ng ( trn u) thnh hai phn, phn 2 c khi lng nhiu hn phn 1 l 134 gam. Cho phn 1 tc dng vi NaOH d c 16,8 lt kh H 2 bay ra. Phn 2 ho tan bng dung dch HCl thy c 84 lt kh H 2 bay ra. Phn ng xy ra hiu sut 100%, th tch cc kh o ktc. Tnh khi lng st to thnh trong phn ng nhit nhm. Cu 3: C mt hn hp Al v Fe xOy. Sau phn ng nhit nhm thu c 92,35 gam cht rn. Ho tan cht rn trong dung dch NaOH d thy c 8,4 lt kh bay ra v cn li phn khng tan D. Ho tan 1/4 lng cht D bng H2SO4 c, nng phi dng 60 gam dung dch H2SO4 98%. Gi s ch to 1 mui st III. Tnh khi lng Al2O3 to thnh v cong thc FexOy. Cu 4: Cho hn hp A dng bt gm Al v oxit st t. Nung A nhit cao phn ng xy ra hon ton thu c hn hp B. Nghin nh hn hp B chia thnh hai phn: - Phn t (I) tc dng vi dung dch NaOH d thu 1,176 lt H 2 (ktc). Tch ring cht khng tan em ho tan trong dung dch HCl d thu c 1,008 lt kh (ktc). - Phn nhiu (II) cho tc dng vi dung dch HCl d thu c 6,552 lt kh (ktc). Tnh khi lng hn hp A v thnh phn % khi lng cc cht trong hn hp A. Cu 5: Trn u 83 gam hn hp bt Al, Fe2O3 v CuO ri tin hnh phn ng nhit nhm. Gi s lc ch xy ra 2 phn ng kh oxit thnh kim loi. Chia hn hp thnh hai phn c khi lng chnh lch nhau 66,4g. Ly phn c khi lng ln ho tan bng dung dch H 2SO4 d thu c 23,3856 lt H2 (ktc), dung dch X v cht rn. Ly 1/10 dung dch X tc dng vi 200ml dung dch KMnO 4 0,018M (Bit rng trong mi trng H+, Mn+7 b kh thnh Mn+2). Ho tan phn c khi lng nh vo dung dch NaOH d thy cn li 4,736g cht rn khng tan.Bit rng s mol CuO bng s mol Fe 2O3. Tnh % mi oxit kim loi b kh theo n. 14

Cu 6: Ly 93,9g Fe3O4 trn vi Al dc hn hp X. Nung hn hp trong mi trng khng c khng kh. Sau khi phn ng xy ra hon ton, ta c hn hp Y. Chia Y thnh haiphanf c khi lng khc nhau. Phn 1 tc dng vi dung dch NaOH d cho 0,672 lt kh H 2 (ktc). Phn 2 tc dng dng vi dung dch HCl d cho 18,816 lt kh H2 (ktc). Tinh khi lng cc cht trong hn hp u. Hiu sut phn ng 100%. Cu 7: Khi nung hn hp A gm Al, Fe2O3 c hn hp B (hiu sut 100%). Chia hn hp B lm hai phn bng nhau. Ho tan phn 1 trong H 2SO4 long d, thu c 1,12 lt kh (ktc). Phn cn li ho tan trong dung dch NaOH d th khi lng cht khng tan l 4,4g. a.Vit cc ptp. b.Xc nh khi lng cc cht trong cc hn hp A, B. Cu 8: Tin hnh phn ng nhit nhm vi hn hp A gm bt Al v Fe 2O3 trong iu kin khng c khng kh . Sau phn ng thu c hn hp cht rn B, Chia B lm hai phn bng nhau. Phn 1: Cho tc dng vi dung dch NaOH d, thu c 1,68 lt H2 (27,3oC, 2,2 atm). Phn 2: Cho tc dng vi dung dch HCl 1M va , thu c 12,32 lt H 2 (ktc) v dung dch D, cho dung dch tc dng vi dung dch NaOH d trong khng kh, lc kt ta ri em nung cho n khi khi lng khng thay i th thu c cht rn E. Cc phn ng xy ra u c hiu sut 100%. a.Vit ptp. b.Tnh % khi lng cc cht trong hn hp B. c.Tnh th tch dung dch HCl. d.Tinh khi lng E. Cu 9: Nung m gam hn hp A gm bt Al v Fe 3O4 mt thi gian thu c cht rn B. ho tan ht B cn V ml dung dch H2SO4 0,7M. Sau phn ng thu c dung dch C v 9,846 lt (1,5 atm, 27 oC). Cho dung dch NaOH vo dung dch C n d thu c kt ta D. Nung D trong chn khng cho n khi lng khng i thu c 44g cht rn E.Cho 50g hn hp X gm CO v CO 2 qua ng s ng E nung nng. Sau khi E phn ng ht thu c hn hp kh Y c khi lng gp 1,208 ln khi lng ca X. a.Tnh % khi lng cc cht trong B. b.Tnh m, V Cu 10: Sau phn ng nhit nhm ca hn hp X gm bt Al vi Fe xOy thu c 9,39 gam cht rn Y. Cho ton b Y thu c vi dung dch NaOH d thy c 336 ml kh bay ra (ktc) v phn khng tan Z. ho tan 1/3 lng cht Z cn 12,4 ml dung dch HNO3 65,3% (d = 1,4 g/ml) v thy c mu nu bay ra. a.Xc nh cng thc ca FexOy. b.Tnh thnh phn % v khi lng ca Al trong hn hp X ban u. Cho bit cc phn ng xy ra hon ton. (HcVin Ngn Hng Tp HCM 2001-2002) Cu 11: Cho hn hp A c khi lng m gam gm bt Al v oxit Fe xOy. Tin hnh phn ng nhit nhm hn hp A trong iu kin khng c khng kh, c hn hp B. Nghin nh, trn u B ri chia thnh hai phn. Phn 1 c khi lng 14,49 gam c ho tan trong dung dch HNO 3 un nng, c dung dch C v 3,696 lt kh NO duy nht (ktc). Cho phn hai tc dng vi lng d dung dch NaOH un nng thy gii phng 0,336 lt kh H2 (ktc) v cn li 2,52 gam cht rn. Cc phn ng u xy ra hon ton. 1. Vit cc phng trnh phn ng xy ra. 2.Tnh m. Cu 12: Tin hnh phn ng nhit nhm m gam hn hp A gm Al v FexOy thu c hn hp cht rn B. Cho B tc dng vi dung dch NaOH d thu c dung dch C, phn khng tan D v 0,672 lt kh H 2.Cho t t dung dch HCl v dung dch C n khi thu c lng kt ta ln nht ri lc ly kt ta, nung n khi lng khng i c 5,1 gam cht rn.Phn khng tan D cho tc dng vi dung dch H 2SO4 c nng. Sau phn ng ch thu c dung dch E cha mt mui st duy nht v 2,688 lt kh SO2. Cc th tch kh o ktc, hiu sut cc phn ng bng 100%. 1. Xc nh cng thc phn t ca oxit st v tnh m. 2. Nu cho 200 ml dung dch HCl 1M tc dng vi dung dch C n khi phn ng kt thc thu c 6,24 gam kt ta th th s gam NaOH trong dung dch NaOH lc u l bao nhiu? (HGTVT 01-02) Cu 13.Hn hp A gm bt Al v 1 oxit st c chia thnh 3 phn bng nhau. Phn 1: Cho tc dng vi dung dchBa(OH)2 d thu c 2,016(l) kh(ktc). Phn 2 v phn 3 thc hin phn ng nhit nhm. Sn phm thu c sau phn ng nhit nhm vi phn 2 em ho tan trong dung dchNaOH d th thu c cht rn C v khng c kh thot ra. Cho C phn ng ht vi dung dchAgNO3 1M th cn 120 ml, sau phn ng thu c 17,76 gam cht rn v dung dch ch c Fe(NO3)2. 15

Sn phm thu c phn 3 sau khi thc hin phn ng nhit nhm, cho vo bnh c 2(l) dung dchH 2SO4 0,095M thu c dung dchD v mt phn Fe khng tan. 1. Xc nh cng thc ca oxit st v tnh khi lng cc cht sau phn ng nhit nhm mi phn. 2. Tnh nng mol/l ca cc cht trong D, khi lng Fe khng tan. Coi V cc cht rn khng ng k, th tch dung dch khng thay i trong qu trnh phn ng. Bit cc phn ng xy ra hon ton. Trc nghim. Cu 1: Trn 12,15 gam Alvi 72 gam Fe2O3 ri tin hnh phn ng nhit nhm trong iu kin khng co khng kh, kt thc phn ng khi lng cht rn thu c l: A. 92,25g B. 84,15 gam C. 97,65 gam D. 77,4 gam Cu 2 : Trn 8,1 gam Al vi bt Fe2O3v CuO ri t nng tin hnh phn ng nhit nhm mt thi gian, thu c hn hp X. Ha tan hon ton X trong dung dich HNO3 un nng thu c V lt kh NO( sn phm kh duy nht). Gi tr ca V l: A. 2,24 lt B. 6,72 lt C. 0,224 lt D. 0,672 lt Cu 3 : Trn 0,54 gam bt Al vi bt Fe2O3 v CuO ri tin hnh phn ng nhit Al thu c hn hp X. Ha tan hon ton X trong dung dch HNO3 thu c hn hp kh NO v NO2 c t l s mol tng ng l 1: 3. Th tch kh NO l: A. 2,24 lt B. 0,224 lt C.6,72 lt D. 6,72 lt Cu 4 : Thc hin phn ng nhit Al 0,35 mol Al vi 0,3 mol Fe2O3 thu c 0,2 mol Fe. Hiu sut phn ng l:A. 57,14% B. 83,33% D. 68,25% D. 66,67% Cu 5 : Hn hp A gm 0,56gam Fe, 16 gamFe2O3v x mol Al ri nung nhit cao khng c khng kh c hn hp D. Nu cho D tan trong H2SO4 long d c V lt kh nhng nu cho D tc dng vi NAOH d th thu c 0,25V lt kh. Gi tr ca X l: A. 0,1233 B. 0,2466 C. 0,12 D. 0.3699 Cu 6 : Trn 5,4 gam bt Al vi 17,4g bt Fe3O4 ri tin hnh phn ng nhit Al(gi s ch xy ra phn ng kh Fe3O4 thnh Fe) .Ha tan hon ton hn hp cht rn sau phn ng bng dung dch H2SO4 long, d th thu c 5,376 lt H2(ktc). Hiu sut phn ng l: A. 62,5 % B. 20% C. 60% D. 80% Cu 7 : Sau khi thc hin phn ng nhit Al vi Fe3O4 thu c cht rn A v nhn thy khi lng nhm tng 0,96 gam. Cho A tc dng vi dung dch NaOH d thu c 0,762 lt (ktc), (gi s phn ng u xy ra vi hiu sut 100%). Khi lng A l: A, 1,08 g B. 1,62 g C. 2,1 g D. 5,1 g Cu 8*: Trn 16,2 gam bt Al vi 69,9 gam bt Fe3O4 thu c hn hp X. Thc hin phn ng nhit nhm hn hp X trong iu hin khng c khng kh thu c hn hp Y. Cho Y tc dng vi dng vi dung dch HCl d thu c 17,64 lt kh H2 (ktc)Hiu sut ca phn ng nhit nhm l: A. 20% B. 30% C. 40% D. 50% Cu 9 : Thc hin phn ng nhit nhm 92,35 gam hn hp X gm Al v oxit st FexOy thu c cht rn Y. Ha tan Y trong dung dch NaOH d thy c 8,4 lt kh thot ra v cn li cht rn khng tan Z. ha tan lng Z ht 60 gam dung dch H2SO498%( c nng), gi s ch to mui Fe (III). Khi lng Al2O3 trong hn hp l: A. 2, 04 gam B. 40,8 gam C. 20,4 gam D. 4,08 gam Cu 10:khi nung hn hpX gm Al v Fe2O3 thu c hn hp Y. Chia Y thnh hai phn bng nhau: -phn 1 tan trong dung dch NaOH d, khng c kh thot ra v cn li 4,4 gam cht rn khng tan .-phn 2trong dung dch H2SO4long d thu c 1,12 lt kh(ktc) A. 5,6 gam B. 11,2 gam C. 16 gam D. 8 gam Cu 11: Tin hnh phn ng nhit nhm vi Fe3O4 trong iu kin khng c khng kh, cho bit phn ng xy ra hon ton v Fe3O4 ch b kh thnh Fe. Chia hn hp sau phn ng thnh hai phn bng nhau. Cho phn 1 tc dng ht vi dung dch NaOH( d) thu c2,52 ltH2(ktc). Ha tan ht phn 2 vo dung dch HNO3c nng(d) thy c 11,76 lt kh bay ra (ktc). Khi lng e sinh ra sau phn ng nhit nhm l: A.8,4 g B5,6 g C. 11,2 g D. 16,8 g Cu 12: Ly 20 g hn hp bt Al v Fe2O3 ngm trong dung dch NaOH(d), phn ng xong ngi ta thu c 3, 36l kh hidro (ktc). Khi lng Fe2O3 ban u l: A. 13,7 gam B. 17,3 gam C. 18 gam D. 15,95gam Cu 13: Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c khng kh) n khi phn ng 16

xy ra hon ton, thu c hn hp rn Y. Chia Y thnh hai phn bng nhau: - Phn 1 tc dng vi dung dch H2SO4 long (d), sinh ra 3,08 lt kh H2 ( ktc); - Phn 2 tc dng vi dung dch NaOH (d), sinh ra 0,84 lt kh H2 ( ktc). Gi tr ca m l: A. 22,75 B. 21,40. C. 29,40. D. 29,43. Cu 14: Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y, cht rn Z v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt ta. Gi tr ca m l: A. 36,7. B. 48,3. C. 45,6. D. 57,0. Cu 15: Trn 5,4 gam Al vi 4,8 gam Fe 2O3 ri nung nng thc hin phn ng nhit nhm. Sau phn ng ta thu c m (g) hn hp cht rn. Gi tr ca m l: A. 2,24 B. 4,08 C. 10,2 D. 0,224 Cu 16: Trn 10,8 gam bt nhm vi 34,8g bt Fe3O4 ri tin hnh phn ng nhit nhm thu c hn hp A. ha tan ht A bng HCl thu c 10,752 lt H2(ktc). Hiu sut phn ng nhit nhm v th tch dung dch HCl 2M cn dng l? A. 80% v 1,08lt B. 20% v 10,8lt C. 60% v 10,8lt D. 40% v 1,08lt Cu 17: Nung hn hp A gm Al, Fe2O3 c hn hp B (hiu sut 100%). Ha tan ht B bng HCl d c 2,24 lt kh (ktc), cng lng B ny nu cho phn ng vi dung dch NaOH d thy cn 8,8g rn C. Khi lng cc cht trong A l? A. mAl=2,7g, mFe2O3=1,12g B. mAl=5,4g, mFe2O3=1,12g C. mAl=2,7g, mFe2O3=11,2g D. mAl=5,4g, mFe2O3=11,2g Cu 18: Hn hp A gm 0,56g Fe v 16g Fe2O3 m (mol) Al ri nung nhit cao khng c khng kh c hn hp D. Nu cho D tan trong H2SO4 long c v(lt) kh nhng nu cho D tc dng vi NaOH d th thu c 0,25V lt kh. Ga tr ca m l? A. 0,1233 B. 0,2466 C. 0,12 D. 0,3699 Cu 19: C 26,8g hn hp bt nhm v Fe2O3. Tin hnh nhit nhm cho ti hon ton ri ha tan ht hn hp sau phn ng bng dung dch HCl c 11,2 lt H2(ktc). Khi lng cc cht trong hn hp ban u l? A. mAl=10,8g;m Fe2 O3 =1,6g B. mAl=1,08g;m Fe2 O3 =16g C. mAl=1,08g;m Fe2 O3 =16g D. mAl=10,8g;m Fe2 O3 =16g Cu 20: Hn hp X gm Al v Fe2O3. Ly 85,6gam X em nung nng thc hin phn ng nhit nhm, sau mt thi gian thu c m gam cht rn Y. Chia Y lm 2 phn bng nhau: Phn 1: Ha tan trong dung dch NaOH d thy thot ra 3,36lt kh (ktc) v cn li m1 gam cht khng tan. Phn 2: Ha tan ht trong dung dch HCl thy thoat ra 10,08 lt kh (ktc). Phn trm khi lng Fe trong Y l? A. 18% B. 39,25% C. 19,6% D. 40% Cu 21: Hn hp X gm Al v Fe2O3. Ly 85,6gam X em nung nng thc hin phn ng nhit nhm, sau mt thi gian thu c m gam cht rn Y. Chia Y lm 2 phn bng nhau: Phn 1: Ha tan trong dung dch NaOH d thy thot ra 3,36lt kh (ktc) v cn li m1 gam cht khng tan. Phn 2: Ha tan ht trong dung dch HCl thy thoat ra 10,08 lt kh (ktc). Thnh phn cht rn Y gm cc cht l? A. Al, Fe2O3, Fe, Al2O3 B. Al, Fe, Al2O3 C. Fe, Al2O3 D. C A, C ng. Cu 21: iu ch c 78 gam Cr t Cr2O3(d)bng phng php nhit nhm vi hiu sut ca phn ng l 90% th khi lng ca bt nhm cn dng ti thiu l: A.81 gam B.54gam C. 40,5 gam D.45 gam Cu 21: Nung hn hp bt gm 15,2g Cr2O3 v m(g) Al nhit cao. Sau khi phn ng hon ton thu c 23,3g hn hp rn X. Cho ton b hn hp X phn ng vi axit HCl d, thot ra V(l) H 2 (ktc). Gi tr ca V l: A. 4,48 B. 3,36. C. 7,84. D.10,08. Cu 21: Khi cho 41,4 g hn hp X gm Fe 2O3, Cr2O3, Al2O3, tc dng vi dung dch NaOH c d, sau phn ng thu c cht rn c khi lng 16g. kh hon ton 41,4g X bng phn ng nhit Al phi dng 10,8g Al. Thnh phn % theo khi lng ca Cr2O3 trong hn hp X l: A. 50,67%. B.20,33%. C.66,67%. D.36,71%. Cu 22.(HB-2012).Nung nng 46,6 gam hn hp gm Al v Cr2O3 (trong iu kin khng c khng kh) nkhi phn ng xy ra hon ton. Chia hn hp thu c sau phn ng thnh hai phn bng nhau. Phn mt phn ng va vi 300 ml dung dch NaOH 1M (long). ha tan ht phn hai cn va 17

dung dch cha a mol HCl. Gi tr ca a l: A. 0,9. B. 1,3.

C. 0,5.

D. 1,5.

18