Bi 1: t chy hon ton 4,4g sunfua ca kim loi M (cng thc MS) trong oxi d.

Cht rn sau phn ng em ho tan trong mt lng va dung dch HNO3 37,8% thy nng phn trm ca mui trong dung dch thu c l 41,72%. Khi lm lnh dung dch ny th thot ra 8,08g mui rn. Lc tch mui rn thy nng phn trm ca mui trong dung dch l 34,7%. Xc nh cng thc mui rn. 0 Bi 2: Mt hn hp X gm 2 oxit AOx v AOx+1 chim th tch l 56 lt (273 C, 1atm). Hn hp X cn nng 84g. 1. Xc nh CTPT ca 2 oxit trn v thnh phn hn hp bit rng A l mt nguyn t thuc nhm 6, phn nhm chnh. 2. Ly 84g hn hp X cho vo mt bnh c th tch V=1 lt. Thm vo 16g O2 v mt t V2O5 xc tc. Nung bnh cho n khi t n cn bng th p sut P2 sau phn 0 ng bng 1,2 ln p sut P1 (lc cha thm O2), P1 v P2 u o 273 C. Tnh hng 0 s cn bng ca phn ng 273 C. 3. Phi thm vo hn hp c c trong cu 2 (sau phn ng vi O2) bao nhiu mol 0 O2 khi n cn bng mi ta c 1 mol AOx+1, nhit vn l 273 C. Cho S=32, Se=79. Bi 3: Cho st phn ng va ht vi axit sunfuric thu c kh A v 8,28g mui. Tnh s gam Fe phn ng, bit rng s mol st bng 37,5% s mol axit sunfuric phn ng. (Bit: Cl=35,5; Br=80; S=32; O=16; K=39; Fe=56, Mkhng kh=28,8). Bi 4: Nung chy mt gam mu cha MnO, Cr2O3 v tp cht tr vi lng d cht oxi ho mnh Na2O2 thu c hn hp cha Na2MnO4 v Na2CrO4. Sau khi phn ng kt thc, ngui hn hp, ho tan hn hp vo nc v lm phn hu ht lng Na2O2. Thm vo lng d dung dch H2SO4, thu c dung dch cha cc ion 2MnO4 , Cr2O7 v kt ta MnO2. Lc ra kt ta thu c kt ta MnO2 v dung dch B. Thm vo B 50ml dung dch FeSO4 0,1M, lng FeSO4 cn li tc dng va vi 18,4ml dung dch KMnO4 0,01M. Thm vo kt ta MnO2 10ml dung dch FeSO4 0,1M (d) v lng d dung dch H2SO4 dng lm mi trng ho tan hon ton lng kt ta MnO2. Lng FeSO4 cn d li phn ng va ht vi 8,24ml dung dch KMnO4 0,01M trong mi trng H2SO4. 1. Vit phng trnh phn ng xy ra. 2. Tnh % theo khi lng ca MnO v Cr2O3 trong mu. Bi 5: 1. Ho tan hn hp X (Na, Mg, Al) vo nc, thu c 8,96 lt kh (ktc), 5,1g cht rn khng tan Y v dung dch Z. Cho ton b Y vo dung dch HCl d thu c 0,25 mol H2. Tnh khi lng tng cht trong hn hp X. 2. Cho 3,87 gam hn hp A (Mg v Al) v 250ml dung dch B gm HCl 1M v H2SO4 0,5M thu c dung dch C v 4,365 lt H2 (ktc). Tnh khi lng mui to thnh. Bi 6: X l hn hp gm Fe v Cu. Ho tan hon ton m gam X bng V lt dung dch H2SO4 98% (d=1,84g/ml) thu c dung dch A. Pha long dung dch A ri in phn 2+ vi in cc tr bng dng in I=9,65A n khi ht Cu th mt 9 pht 20 giy (Hp=100%), sau khi in phn thu c dung dch B, dung dch B phn ng va ht vi 100ml dung dch KMnO4 0,04M. 1. Vit phng trnh phn ng. 2. Tnh m. 3. Tnh V, bit lng axit phn ng vi hn hp X ch bng 10% lng axit trong dung dch u. Bi 7: Cho 50g dung dch MX (M l kim loi kim, X l halogen) 35,6% tc dng vi 10g dung dch AgNO3 thu c kt ta. Lc kt ta, c dung dch nc lc. Bit

nng MX trong dung dch sau th nghim gim 1,2 ln so vi nng ban u. 1. Xc nh cng thc mui MX. 2. Trong phng th nghim, khng kh b nhim mt lng X2 rt c, hy tm cch loi n (vit phng trnh phn ng). Bi 8: Ho tan hon tan Fe trong dung dch H2SO4 c nng thu c dung dch A. Chia A thnh hai phn bng nhau: Phn 1: cho phn ng vi 700ml dung dch KMnO4 0,1M trong mi trng axit H2SO4 (va ). Thm tip dung dch HCl vo dung dch sau phn ng thy c 0,56 lt kh thot ra ktc. Phn 2: em c cn th thu c 65,6g mui. Tnh khi lng Fe dng. Bi 9: t chy hon ton 12g mt mui sunfua ca kim loi M ho tr II thu c rn A v kh B. Ho tan A bng mt lng va dung dch H2SO4 24,5% thu c dung dch mui nng 33,33%, lm lnh dung dch ny thy tch ra 15,625g tinh th T, phn dung dch bo ho c nng l 22,54%. 1. Xc nh kim loi M v cng thc ca tinh th T. 0 2. un nng kh B vi nc trong ng hn kn 150 C thy thot ra cht rn mu vng. Vit phng trnh phn ng. Bi 10: Cho m gam mui halogen ca mt kim loi kim phn ng vi 50ml H2SO4 c, nng ly d. Sau khi phn ng xy ra hon ton thu c kh A c mi v hn hp sn phm B. Trung ho B bng 250 ml dung dch NaOH 2M ri lm bay hi nc cn thn th c 199,6g hn hp D (kh). Nung D n khi lng khng i thu c hn hp mui E c khi lng 98g. Nu cho dung dch BaCl2 vo B th thu c kt ta F c khi lng gp 1,4265 ln khi lng mui E. Dn kh A vo dung dch Pb(NO3)2 thu c 23,9g kt ta mu en. 1. Tnh nng % dung dch H2SO4 (D=1,715g/ml) v m gam mui. 2. Xc nh kim loi kim, halogen v vit cc phng trnh phn ng. Bi 11: Cho hn hp X gm hai cht rn FeCO3 v FeS2. Cho X cng mt lng O2 vo mt bnh kn c th tch V (l). t nng bnh cho phn ng xy ra (gi thit kh nng phn ng ca 2 mui l nh nhau, sn phm phn ng l Fe2O3, sau phn ng a v iu kin ban u thu c cht rn Y v hn hp kh Z. p sut trong bnh lc ny l P. ho tan cht rn Y cn 200ml dung dch HCl 0,3M, thu c hn hp kh M v sn phm E cn li, nu a M vo bnh kn th tch V (l) cng iu kin vi Z th p sut trong bnh lc ny l P. Thm dung dch NaOH d vo sn phm E c cht rn F, lc ly F v lm kh ngoi khng kh cn c 3,85g (khng nung). 1. Vit phn ng xy ra. 2. Tnh % khi lng cc mui trong hn hp. Bi 12: Cho 4,9g hn hp gm Mg v Zn vo mt cc cha 400ml dung dch H2SO4 0,5M (long). Sau phn ng thu c dung dch A. Cho vo dung dch A 0,5 lt dung dch hn hp gm Ba(OH)2 0,04M v NaOH 0,76M, khuy u cho phn ng hon ton ri lc ly kt ta v nung n khi lng khng i th thu c 11,47g cht rn. Tnh khi lng mi kim loi trong hn hp ban u. Bi 13: Ho tan 13,2g hn hp X gm hai kim loi c cng ho tr vo 400ml dung dch HCl 1,5M, kt thc phn ng thu c 31,7g hn hp mui khan. 1. Tnh th tch kh sinh ra. Chng minh kim loi cn d. 2. Xc nh hai kim loi, tnh thnh phn phn trm v khi lng ca hn hp X bit rng t l s mol phn ng gia hai kim loi l 1:2. Bi 14: Hp cht A to bi kim loi M c ho tr khng i v X (nm chu k 3, nhm VIA). Ly 13g A chia lm hai phn khng bng nhau:

Phn 1: tc dng vi O2 to kh B. Phn 2: tc dng vi dung dch HCl d to kh C. Trn B v C thu 7,68g kt ta vng v cn li cht kh no m khi gp nc clo to dung dch D. Cho D tc dng vi AgNO3 d to c 22,96g kt ta. 1. Vit cu hnh electron y ca X. Gi tn v nu tnh cht ho hc c bn ca X. X c nhng s oxi ho no? Trong hp cht no? Gii thch ti sao X c nhng s oxi ho . 2. Xc nh cng thc phn t A. Bi 15: C 100ml dung dch X cha H2SO4 v HCl the t l mol 1:1. trung ho 100ml dung dch X cn 400ml dung dch NaOH 5% (d=1,2g/ml). 1. Tnh nng mol ca mi axit trong dung dch X. 2. Nu nng % ca NaCl trong dung dch thu c sau phn ng l 1,95%, hy tnh khi lng ring ca dung dch X v nng % ca mi axit trong dung dch X. Bi 16: Cho 7,02g hn hp gm Al v hai kim loi kim th thuc hai chu k k tip vo dung dch HCl d thu c 6,496 lt kh (ktc). Nu ly ring lng Al trong hn hp em cho vo dung dch NaOH d th thu c V lt kh (ktc). Bit 3,136< V >3,584, cc phn ng u xy ra hon ton. 1. Tm hai kim loi kim th. 2. Cho V=3,36 lt, tnh khi lng mi kim li trong hn hp ban u. Cho ZHe=2, ZLi=3, ZBe=4, ZB=5, ZC=6, ZN=7, ZO=8, ZF=9, ZNe=10, ZNa=11, ZMg=12, ZAl=13, ZCa=20, ZSr=38, ZBa=56, MBe=9, MMg=24, MAl=27, MCa=40, MSr=88, MBa=137. Bi 17: Theo l thuyt khong pyrit c cng thc FeS2, trong thc t mt phn ion 22S2 c thay th bi S v cng thc tng qut ca pyrit l FeS2-x. Nh vy c th coi pyrit nh l hn hp FeS2, FeS. Khi x l mt mu khong vi Br2 trong KOH d th xy ra phn ng: FeS2 + Br2 + KOH Fe(OH)3 + KBr + K2SO4 + H2O FeS + Br2 + KOH Fe(OH)3 + KBr + K2SO4 + H2O Sau khi lc c cht rn A v dung dch B: Nung cht rn A n khi lng khng i thu c 0,2g Fe 2O3. Cho d dung dch BaCl2 vo dung dch B thu c 1,1087g kt ta BaSO4. 1. Xc nh cng thc tng qut ca pyrit. 2. Cn bng cc phn ng trn bng phng php ion electron. 3. Tnh lng Br2 dng oxi ho mu khong trn. Bi 18: Nung nng hn hp gm 5,6g bt Fe vi 4g bt S trong bnh kn mt thi gian, c hn hp rn A gm FeS, FeS2, Fe v S d. Cho A tan ht trong dung dch H2SO4 c, d, kt thc phn ng thu c bao nhiu lt kh (ktc). Bi 19: Ho tan hn hp A gm Mg, Cu vo 1 lng va dung dch H2SO4 c nng thu c 1,12 lt kh SO2 (kc) v dung dch B. Cho dung dch B tc dng vi dung dch NaOH d thu c kt ta C. Nung C n khi lng khng i ta thu c 0 hn hp rn E. Cho E tc dng vi lng d H2 (c t ) th thu c 2,72g hn hp rn F. 1. Vit phng trnh phn ng xy ra. 2. Tnh khi lng mi cht trong hn hp A. (Cho Mg=24, Cu=64, O=16). Bi 20: C hai kim loi A v B. Khi lng nguyn t u gm hai s hng a v b (a, b 0 v a>b). Khi lng nguyn t ca A l ab v khi lng nguyn t ca B l ba. Hiu s hai khi lng nguyn t nh hn 10. Tng s hai khi lng nguyn t nm trong khong t 100 n 140. Hy xc nh hai kim loi A, B.

Bi 21: Nung m gam mt mui cacbonat kim loi ho tr II mt thi gian thu c p gam cht rn A v x lt kh B bay ra. Ho tan cht rn A bng mt lng va dung dch HCl thu c dung dch C v y lt kh B bay ra. in phn hon ton dung dch C thu c q gam kim loi catot v z lt kh E anot. 1. Vit cc phng trnh phn ng xy ra. 2. Lp cc biu thc tnh x, y, z theo m, p, q. 3. Cho m=9,3g v q=4,8g. Tnh th tch kh E. Cho kh E tc dng vi 2 lt kh H2 ri ly sn phm phn ng ho tan vo 40g nc thu c dung dch F. Ly 8,73g dung dch F cho tc dng vi AgNO3 d thy to thnh 2,87g kt ta. Tnh hiu sut phn ng gia kh E v H2. Cc th tch u o ktc. Bi 22: Ho tan 5,91g hn hp NaX v KBr vo 100ml dung dch hn hp Cu(NO3)2 0,1M v AgNO3 cha bit nng , thu c kt ta A v dung dch B. Trong dung dch B, nng % ca NaNO3 v KNO3 tng ng theo t l 3,4 : 3,03. Cho ming km vo dung dch B, sau khi phn ng xong ly ming km ra khi dung dch, thy khi lng tng 1,1225g. 1. Tnh lng kt ta A. 2. Tnh CM ca AgNO3 trong dung dch hn hp. Bi 23: T cc nguyn t O, Na, S to ra c cc mui A, B u c 2 nguyn t Na trong phn t. Trong mt th nghim ho hc ngi ta cho m1 gam mui A bin i 0 thnh m2 mui B v 6,16 lt kh Z ti 27,3 C, 1atm. Bit rng hai khi lng khc nhau 16g. 1. Vit phng trnh phn ng xy ra vi cng thc c th ca A, B. 2. Tnh m1, m2. Bi 24: Hn hp X gm Al v kim loi M, trong s mol ca M ln hn s mol ca Al. Ho tan hon ton 1,08g hn hp X bng 100ml dung dch HCl thu c 1,176 lt kh (ktc) v dung dch Y. Khi cho dung dch Y tc dng vi dung dch AgNO3 d thu c 17,9375g kt ta. 1. Tnh nng mol/lt ca dung dch HCl dng, bit M c ho tr II trong mui to thnh. 2. Xc nh M v phn trm khi lng mi kim loi trong hn hp X. Bi 25: Ho tan 0,88g hn hp A gm 1 kim loi M ho tr II v oxit ca M vo dung dch HCl va thu c 200ml dung dch B cha 2,22g mui. 1. Xc nh kim loi M, bit rng tng s ht trong nguyn t M ln hn 40. 2. Tnh % khi lng mi cht trong hn hp A. 3. Tnh CM ca dung dch HCl dng. 0 Bi 26: un nng n 200 C hn hp 4 mui A, B, C, D ca natri, mi th 1 mol s thy c kh E khng chy c thot ra v 1 hn hp mi c hnh thnh c khi lng gim i 12,5% cha 1,33a mol A, 1,67a mol C v a mol D. Nu tng nhit 0 0 n 400 C hn hp ch cn li A v D, nu tng n 600 C th ch cn li A. Thnh phn phn trm khi lng ca natri trong mui nh t A l 39,316%. 1. Tm cc cht A, B, C, D, E. Vit phng trnh phn ng. 0 2. Xc nh thnh phn % theo s mol ca hn hp 400 C. 3. Xp theo th t mnh dn ca axit tng ng vi cc mui ny. Bi 27: Hp cht M to nn t 7 nguyn t ca 2 nguyn t A, B (bit A c 1e c thn v MA>MB) c khi lng phn t 144. Bit A, B khng cng chu k, khng cng phn nhm chnh. Tm CTPT, CTCT ca M. Cho 17,6g hn hp gm M v RB2 tc dng ht vi nc c 7,84 lt kh (ktc). Tnh thnh phn phn trm th tch mi kh trong hn hp. Bit R l kim loi c b 4 s

lng t ca e sau cng c tng i s = 3,5. Hy vit CTCT RB2. Bi 28: Hn hp A gm KClO3, Ca(ClO3)2, Ca(ClO)2, CaCl2 v KCl cn nng 83,68g. Nhit phn hon ton A thu c cht rn B gm CaCl2 v KCl cng vi mt lng oxi va oxi ho SO2 to thnh SO3 iu ch 191,1g dung dch H2SO4 80%. Cho B tc dng vi 360ml dung dch K2CO3 0,5M (va ) thu kt ta C v dung dch D. Lng KCl trong D nhiu gp ln KCl trong A. 1. Tnh khi lng kt ta C. 2. Tnh % khi lng KClO3 trong A. Bi 29: Ho tan 7,18g mt thanh st cha tp cht l Fe2O3 vo mt lng rt d dung dch H2SO4 long ri thm nc ct vo thu c 500ml dung dch. Ly 25ml dung dch cho tc dng vi dung dch KMnO4th phi dng ht 12,5ml dung dch KMnO4 0,096M. 1. Xc nh hm lng (% khi lng) Fe tinh khit trong thanh st. 2. Nu ly cng mt lng thanh st nh trn v hm lng st tinh khit nh trn nhng cha tp cht l FeO v lm li th nghim nh trn th th tch dung dch KMnO4 0,096M cn dng l bao nhiu? Bi 30: Hn hp X gm Fe v mt kim loi R c ho tr khng i. Ho tan hon 0 ton 3,3g X trong dung dch HCl d thu c 2,9568 lt kh 27,3 C, 1atm. Mc khc cng ho tan hon tn 3,3g X trng dung dch HNO31M ly d 10% thu c 896ml hn hp kh Y gm N2O, NO (ktc) c t khi so vi hn hp NO, C2H6 l 1,35 v mt dung dch Z. 1. Xc nh R v tnh % cc kim loi trong X. 2. Cho dung dch Z tc dng vi 400ml NaOH thy xut hin 4,77g kt ta. Tnh nng mol ca dung dch NaOH, bit Fe(OH)3 kt ta hon ton. Bi 31: Ho tan 10,65g gm mt oxit ca kim loi kim v mt oxit kim loi kim th bng dung dch HCl ta thu c dung dch B. C cn dung dch B v in phn 0 nng chy hon ton hn hp mui th thu c anot 3,696 lt kh C ( 27,3 C, 1atm) v hn hp kim loi D catot. 1. Tnh kh lng ca D. 2. Ly m gam D cho tc dng ht vi nc ta c dung dch E v V lt kh ( ktc). Cho t t bt Al vo dung dch E cho ti ngng thot kh, thy ht p gam Al v c V1 lt kh thot ra ( ktc). a. So snh V1 v V. b. Tnh p theo m. 3. Nu ly hn hp kim loi D ri luyn thm 1,37g Ba th thu c mt hp kim trong Ba chim 23,077% v s mol. Hi hn hp u l oxit ca cc kim loi kim, kim th no? Bi 32: 1. em in phn 200ml dung dch NaCl (D=1,1g/ml) vi in cc bng than c mng ngn xp v dung dch lun lun c khuy u. Khi catot thot ra 0 22,4 lt kh o iu kin 20 C, 1atm th ngng in phn. Hp cht cha trong dung dch sau khi kt thc in phn l cht g? Xc nh C% ca n. 2. Hn hp A gm 3 mui NaCl, NaBr, NaI: 5,76g A tc dng vi lng d dung dch brom, c cn thu c 5,29g mui khan. Ho tan 5,76g A vo nc ri cho mt lng kh clo sc qua dung dch. Sau mt thi gian c cn th thu c 3,955g mui khan, trong c 0,05 mol ion clorua. a. Vit cc phng trnh phn ng. b. Tnh thnh phn phn trm khi lng mi mui trong A. Bi 33: Hn hp X gm hai kim loi M v N (N ng sau M trng dy in ho v chim 60% v khi lng). Cho 25g X tc dng vi dung dch HNO3, sau khi phn

ng xy ra hon ton thu c kh NO v 16,6g cht rn khng tan. Lc b cht rn, c cn dung dch, thu c m1 gam cht rn khan. Nhit phn hon ton m1 gam cht rn ny trong chn khng thu c m2 gam mt oxit kim loi v 7,56 lt (kc) hn hp kh NO2 v O2trong oxi chim 1/9 th tch hn hp. 1. Vit phng trnh phn ng dng tng qut, xc nh M. 2. Tnh m1 v m2. Bi 34: 1. Mt dung dch c axit ho bng H2SO4, cha 0,543g mt mui trong thnh phn c natri, clo v oxi. Cho thm vo dung dch KI cho n khi iot ngng thot ra, khi lng iot l 3,05g. a. Xc nh cng thc mui. b. Nhit phn hon ton mui th khi lng mui gim bao nhiu %? 2. Khi un nng 22,12g KMnO4, thu c 21,16g hn hp rn. Tm th tch clo cc i (ktc) c th thu c khi cho hn hp rn tc dng vi axit clohiric 36,5% (D=1,18g/ml) v th tch dung dch axit cn cho phn ng. Bi 35: Cho 5g hn hp Fe, Cu cha 40% Fe vo mt lng dung dch HNO3 1M, khuy u cho phn ng xy ra hon ton th thu c mt phn rn nng 3,32g, dung dch B v kh NO. Tnh lng mui to thnh trong dung dch B. Bi 36: Cho 12,5g hn hp gm Mg v Zn vo 100ml dung dch A cha HCl 1M v H2SO4 0,6M. 1. Hy cho bit kim loi c tan ht khng? 2. Cho 100ml dung dch B gm KOH 1M v NaOH 0,8M vo 100ml dung dch A, c cn dung dch sau phn ng thu c rn C khan. Tnh khi lng rn C. Bi 37: Cho 200ml dung dch A gm: MgCl2 0,3M, AlCl3 0,45M v HCl 0,55M tc dng hon ton vi V lt dung dch B gm: NaOH 0,02M v Ba(OH)2 0,01M. Tnh th tch V thu c kt ta ln nht v kt ta nh nht. Tnh khi lng kt ta . Bi 38: Cho mt lung kh 8,064 lt CO thiu i qua hn hp X gm 0,1 mol Fe2O3 v 0,1 mol Fe3O4 un nng, sau khi phn ng kt thc thu c phn rn A v kh CO2. Ly phn rn A cho tc dng vi 500ml dung dch HCl d thu c 3,60192 lt H2 v dung dch B. Dung dch B lm mt mu hon ton dung dch cha 8,4372g KMnO4. 1. Xc nh s mol mi cht trong A, bit rng trong A s mol Fe3O4 bng vi s mol ca FeO. 2. Dn mt lung kh Cl2 d vo dung dch B c dung dch Y. Cho ton b dung dch Y tc dng ht vi nc baryt thu c kt ta Z, em nung kt ta Z n khi lng khng i c cht rn G. Tnh khi lng G. 3. Tnh nng mol/lt ca dung dch HCl ni trn bit dng d 15%. 0 Cho bit cc cht kh u o 54,6 C v 0,5atm. Bi 39: Cho 10,24g hn hp X gm 3 kim loi Cu, Mg, Fe dng bt tc dng vi 150ml dung dch 2 axit HCl 2M v H2SO4 2M (long ) phn ng lm gii phng ra 3,584 lt H2 (ktc) th ht bt kh thot ra. em lc, ra thu c dung dch A v cht rn B. Ho tan ht B trong H2SO4 c un nng gii phng ra V lt SO2 (ktc). Thm vo dung dch A 125ml NaOH 25% c d=1,28g/ml. Khuy u hn hp, lc, ra kt ta, nung n nhit cao trong khng kh n khi c khi lng khng i, thu c 9,6g cht rn C. 1. Vit cc phng trnh phn ng xy ra v tnh % theo khi lng ca mi kim loi trong hn hp. 2. Tnh th tch V ca kh SO2 ktc. 3. Cho 2,56g hn hp X tc dng vi 500ml dung dch AgNO 3 0,17M. Khuy k hn

hp phn ng xy ra hon ton, thu c dung dch v cht rn E. Tnh khi lng ca E. Bi 40: Cho 5 lt H2 v 3,36 lt Cl2 (ktc) tc dng vi nhau ri ho tan sn phm vo 192,7g nc ta thu c dung dch A. Ly 50g dung dch A cho tc dng vi dung dch AgNO3 d thu c 7,175g kt ta. 1. Tnh hiu sut ca phn ng gia H2 v Cl2. 2. Cho 1,3g hn hp 2 kim loi Mg, Fe vo 100ml dung dch A, phn ng xong c cn th thu c 3,9625g cht rn B. Xc nh thnh phn cht rn B. Bi 41: Ho tan ht 11,2g hn hp A gm hai kim loi: M (ho tr x) v M (ho tr y) trong dch HCl (dung dch B) ri sau c cn dung dch thu c 39,6g mui khan. 1. Tnh th tch kh sinh ra ktc. 2. Cho 22,4g hn hp A tc dng 500ml dung dch B thy thot ra 16,8 lt kh H2 (ktc), c cn dung dch thu c cht rn C. Tnh khi lng cht rn C v nng mol dung dch B. Bi 42: Cho m gam hn hp X gm FeO, Fe2O3, Fe3O4 tan trong H2SO4 long, va c 500ml dung dch Y trong sut. Chia Y lm hai phn bng nhau: Phn 1: c cn thu c 31,6g hn hp mui khan. Phn 2: cho mt lung Cl2 d i qua cho n phn ng hon ton ri c cn c 33,375g hn hp mui khan. 1. Vit cc phng trnh phn ng xy ra. 2. nh m. Bi 43: Cho a gam hn hp hai kim loai Cu, Fe (trong Fe chim 30% v khi lng) vo 50ml dung dch HNO3 63% (d=1,38g/ml), khuy u hn hp n khi phn ng xy ra hon ton, c cht rn A cn nng 0,75a gam, dung dch B v 0 7,3248 lt hn hn hp kh NO2 v NO ( 54,5 C v 1atm). Hi c cn dung dch B thu c bao nhiu gam mui? Bi 44: Ho tan hon ton hn hp X gm 0,24g FeS2 v 0,264g FeS vo lng d H2SO4 c nng thu c dung dch A v kh B. Hp th ht kh B bng mt lng va dung dch KMnO4 thu c dung dch D khng mu trong sut c pH=2. 1. Vit cc phng trnh phn ng v tnh th tch dung dch D. 2. Nu em ho tan lng hn hp X trn vo dung dch HNO3 long th thu c dung dch Z v (V) lt kh NO ktc. Dung dch Z va tc dng vi dung dch NaOH cho kt ta mu nu , va tc dng vi dung dch BaCl2. Hy tnh (V). Bi 45: 1. Ho tan a gam hn hp A gm Fe v kim loi M (ho tr khng i) trong dung dch HCl d th c 1,008 lt kh ktc v dung dch cha 4,575g mui khan. Tnh a. 2. Khi ho tan ht cng lng hn hp A nh trn trng dung dch cha hn hp HNO3 c v H2SO4 nhit thch hp th thu c 1,8816 lt (ktc) hn hp hai kh c t khi hi so vi H2 l 25,25. Xc nh M. Bi 46: Cho 9,69g hn hp A gm clorua vi v K2Cr2O7 tc dng ht vi HCl c d, un nng thu c kh B. Cho kh B vo dung dch NaOH nhit thng. Sau khi phn ng xong nh t t 600ml dung dch HCl 0,2M vo thy trung ho va ht NaOH d, c cn dung dch thu c 15g mui khan. Cho kh B sc vo dung dch cha 11,528g hn hp X gm 2 mui CaBr2 v CaI2 n khi phn ng hon ton, c cn dung dch thu c 7,73g mui khan Y. 1. Tnh khi lng mi cht trong A. 2. Tnh khi lng mi cht trong X. Bi 47: Hn hp A gm hai kim loi X, Y c ho tr khng i v khng c kim loi

no ho tr I. Ly 7,68g hn hp A chia thnh hai phn bng nhau. Phn 1 nung trong kh O2 d oxi ho hon ton, thu c 6g hn hp rn B gm 2 oxit. Phn 2 ho tan hon ton trong dung dch cha HCl v H2SO4 long, thu c V lt kh H2 (ktc) v dung dch C. C cn dung dch C thu c p gam mui khan. 1. Tnh V. 2. Gi tr ca p nm trong khong no? 3. Xc nh kim loi X, Y. Bit s mol ca hn hp A ng vi mi phn ni trn l 0,1 mol v khi lng nguyn t ca X, Y u ln hn 20 vC. Bi 48: t 5,6g mt hn hp gm FeS2 v Cu2S bng mt lng oxi ly d, thu c 1,344 lt kh SO2 (ktc) v cht rn A ch gm 2 oxit. Chuyn ton b SO2 thu c thnh dung dch H2SO4 long (dung dch B). Cho A vo B, khuy u phn ng xy ra hon ton, thu c cht rn C mu v dung dch D. Thm t t dung dch KMnO4 0,1M vo dung dch D cho n khi dung dch KMnO4 khng cn mt mu na, thu c kt ta E. 1. Tnh s gam cht rn C. 2. Tnh th tch ti a dung dch KMnO4 cn dng. 3. Tnh s gam kt ta E thu c. Bi 49: Cho 2,626g hn hp A gm (NH4)2CO3 v Na2CO3 v 200ml dung dch hn hp B gm: Ba(OH)2 0,1M v NaOH 0,1M, un nng nh, ta thu c dung dch D, kt ta E v kh F. Tnh khi lng kt ta E, th tch kh F (ktc) v khi lng mi mui trong A. Gi thit rng khi lng dung dch D gim i 4,382g so vi khi lng hn hp A v dung dch B. Bi 50: Cho m1 gam hn hp gm Mg, Al vo m2 gam dung dch HNO3 24%. Sauk hi cc kim loi tan ht c 8,96 lt ( ktc) hn hp kh X gm NO, N2O, N2 bay ra ( ktc) v dung dch A. Thm mt lng va O2vo X, sau phn ng thu c hn hp kh Y. Dn Y t t qua dung dch NaOH d c 4,48 lt hn hp kh Z i ra ( ktc). T khi ca Z i vi H2 bng 20. Nu cho dung dch NaOH vo A c lng kt ta ln nht thu c 62,2g kt ta. Tnh m1, m2. Bit lng HNO3 ly d 20% so vi lng cn thit.