1. BI TP L THUYT Bi 1: Cho 4 dung dch mui: CuSO4, K2SO4, NaCl, KNO3.

Dung dch no sau khi in phn cho ra mt dung dch axit (in cc tr). A. CuSO4 B. K2SO4 C. NaCl D. KNO3 Bi 2: Cho 4 dung dch mui: CuSO4, ZnCl2, NaCl, KNO3. Dung dch no sau khi in phn cho ra mt dung dch bazo (in cc tr). A. CuSO4 B. ZnCl2 C. NaCl D. KNO3 Bi 3: in phn dung dch cha H2SO4 trong thi gian ngn, pH ca dung dch bin i nh th no khi ngng in phn. A. Gim mnh B. Tng nh C. Gn nh khng i D.Tng mnh. Bi 4: in phn dung dch NaCl, in cc tr, khng c vch ngn. Sn phm thu c gm A. H2, Cl2, NaOH B. H2, Cl2, NaOH, nc Javen C. H2, Cl2, nc Javen D. H2, nc Javen. Bi 5: Khi in phn dung dch mui A th gi tr pH khu vc gn catot tng ln. Mui A l: A. NaCl B. CuCl2 C. ZnSO4 D. NaNO3 Bi 6: Ion no sau y b in phn trng thi dung dch: SO42-, Cl-, NO3-, Cu2+, Fe3+, Ca2+, H+ A. SO42-, Cl-; Ca2+, H+ B. SO42-, NO3-, Ca2+, H+ C. SO42-, NO3-, Cu2+, H+ D. Cu2+, Fe3+, Cl-, H+ Bi 7: Trong qu trnh in phn, cc mui X (X: Cl-, Br-) di chuyn v: A. Cc dng v b oxi ha B. Cc m v b oxi ha C. Cc dng v b kh D. Cc m v b kh + + + Bi 8: Cho dung dch cha cc ion: Na , K , Cu , Cl , SO42-, NO32-. Cc ion no khng b in phn khi trng thi dung dch: A. Na+, K+, Cl-, SO42B. K+, Cu+, Cl-, NO32+ 2+ 2+ C. Na , Cu , Cl , SO4 D. Na , K+, SO42-, NO322. IN PHN DUNG DCH Bi 1: Khi lng Cu catot thu c khi in phn dung dch CuSO4 (in cc tr) sau 30 pht vi cng dng in l 0.5A. A. 0.3 gam B. 0.45 gam C. 1.29 gam D. 0.4 gam Bi 2: Tin hnh in phn 400 ml dung dch CuSO4 0.5M vi cng dng in 1.34A trong vng 24 pht. Hiu sut phn ng in phn l 100%. Khi lng kim loi bm vo catot v th tch kh ( ktc) thot ra anot l: A. 0.64 gam Cu v 0.224 lt O2 B. 0.64 gam Cu v 0.112 lt O2 C. 0.32 gam Cu v 0.224 lt O2 D. 0.32gam Cu v 0.112 lt O2 Bi 3: Nu mun in phn hon ton (mt mu xanh) 400 ml dung dch CuSO4 0.5M vi cng dng in I = 1.34A (hiu sut in phn l 100%) th cn bao nhiu thi gian. A. 6 gi B. 7 gi C. 8 gi D. 9 gi Bi 4: in phn dung dch mui CuSO4 d trong thi gian 1930 giy, thu c 1.92 gam Cu catot. Cng dng in trong qu trnh in phn l gi tr no di y: A. 3A B. 4.5A C. 1.5A D. 6A Bi 5: in phn dung dch Cu(NO3)2 vi cng dng in 9.56A n khi bt u c kh thot ra catot th ngng li, thi gian in phn l 40 pht. Khi lng Cu sinh ra catot l: A. 7.68 gam B. 8.67 gam C. 7.86 gam D. 8.76 gam Bi 6: Tin hnh in phn 400 ml dung dch Cu(NO3)2 0.1M vi cng dng in 9.56A trong vng 100 giy. Hiu sut phn ng in phn l 100%. Khi lng kim loi bm vo catot v th tch kh ( ktc) thot ra anot l: A. 3.2 gam Cu v 0.56 lt O2 B. 3.2 gam Cu v 0.448 lt O2 C. 2.56 gam Cu v 0.56 lt O2 D. 2.56 gam Cu v 0.56 lt O2

Chuyn in phn

Bi 7: in phn 500 ml dung dch AgNO3 vi in cc tr cho n khi catot bt u c kh thot ra th ngng in phn. trung ha dung dch sau in phn cn 800 ml dung dch NaOH 1M. 1. Tnh nng mol/l ca dung dch AgNO3 ban u. A. 1.6M B. 0.8M C. 2.4M D. 3.2M 1. Tnh thi gian in phn, bit cng dng in I=20A. A. 1930 giy B. 3860 giy C. 9650 giy D. 7720 giy Bi 8: in phn 2 lt dung dch CuSO4 vi in cc tr v dng in mt chiu c cng I=10A cho n khi catot bt u c kh thot ra th ngng li, thy phi mt 32 pht 10 giy. 1. Tnh nng mol/l ca dung dch CuSO4 ban u. A. 0.075M B. 0.1M C. 0.025M D. 0.05M 1. Tnh pH ca dung dch sau in phn. Gi s th tch dung dch khng thay i. A. 4 B. 3 C. 1 D. 2 Bi 9: in phn 100 ml dung dch NaCl vi in cc tr, mng ngn xp, cng dng in mt chiu l 1.93A. Tnh thi gian in phn thu c dung dch c pH = 12, th tch dung dch c xem nh khng ng k, hiu sut phn ng in phn l 100%. A. 100 giy B. 50 giy C. 150 giy D. 200 giy Bi 10: Cho dng in mt chiu 10A qua 400 cm3 dung dch H2SO4 0.5M (in cc tr). Tnh thi gian in phn thu c dung dch H2SO4 0.6M A. 71410 giy B. 74110 giy C. 47110 giy D. 14710 giy Bi 11: in phn vi in cc tr 500 ml dung dch Fe(NO3)2 n khi bt u c bt kh thot ra catot th ngng li. yn dung dch cho n khi khi lng ca catot khng i, thy khi lng catot tng 14 gam so vi lc cha in phn. Tnh nng mol/l ca dung dch Fe(NO3)2 trc khi in phn. A. 0.5M B. 1M C. 1.5M D. 2M 3. Bi ton in phn hn hp Bi 1: Khi in phn (c mng ngn) dung dch hn hp HCl, NaCl, CuCl2 trong dung dch c 1 t qu tm. Tin hnh in phn dung dch cho n khi nc b in phn c hai in cc th mu qu bin i nh th no. A. Tm xanh B. xanh tm C. Xanh tm D. tm xanh Bi 2: Tin hnh in phn hon ton dung dch X ( catot bt u thot ra H2) cha hn hp AgNO3 v Cu(NO3)2 thu c 56 gam hn hp kim loi catot v 4.48 lt kh anot ( ktc). Tnh s mol mi mui trong X. A. 0.1 mol AgNO3 v 0.1 mol Cu(NO3)2 B. 0.2 mol AgNO3 v 0.1 mol Cu(NO3)2 C. 0.4 mol AgNO3 v 0.2 mol Cu(NO3)2 D. 0.3 mol AgNO3 v 0.3 mol Cu(NO3)2 Bi 3: in phn dung dch hn hp cha Ag2SO4 v CuSO4 mt thi gian thy khi lng catot tng ln 4.96 gam v kh thot ra anot c th tch l 0.336 lt ( ktc). Khi lng kim loi bm catot ln lt l: A. 4.32 g v 0.64 g B. 3.32 g v 1.64 g C. 4.12 g v 0.84 g D. Kt qu khc. Bi 4: in phn 100ml dung dch cha AgNO3 0.1M v Cu(NO3)2 0.1M vi cng dng in I l 1.93A. Tnh thi gian in phn (vi hiu sut 100%) 1. in phn ht Ag (t1) 2. in phn ht Ag v Cu (t2) A. t1=500s, t2=1000s B. t1=1000s, t2=1500s C. t1=500s, t2=1200s D. t1=500s, t2=1500s Bi 5: in phn 100 ml dung dch Cu(NO3)2 0.2M v AgNO3 0.1M vi cng dng in I = 3.86A. Tnh thi gian in phn c mt khi lng kim loi bm trn catot l 1.72 gam A. 250s B. 1000s C. 500s D. 750s 4: in phn cho Bi 1: in phn dung dch cha CuSO4 v KCl vi s mol nCuSO4 > .nKCl vi in cc tr. Bit rng qu trnh in phn gm 3 giai on. Hy cho bit kh thot ra mi giai on.

1. G1: Anot: Cl2 Katot: khng c kh; G2: Anot: O2 Katot: khng c kh; G3: Anot: O2 Katot: H2. 2. G1: Anot: Cl2 Katot: khng c kh; G2: Anot: Cl2 Katot: H2; G3: Anot: O2 Katot: H2. 3. G1: Anot: Cl2 Katot: khng c kh; G2: Anot: Cl2 Katot: khng c kh; G3: Anot: O2 Katot: H2. 4. G1: Anot: Cl2 Katot: H2; G2: Anot: Cl2 Katot: H2; G3: Anot: O2 Katot: H2. Bi 2 ( thi tuyn sinh i hc khi B nm 2007). in phn dung dch cha a mol CuSO4 v b mol NaCl (vi in cc tr, c mng ngn xp). dung dch sau in phn lm phenolphtalein chuyn sang mu hng th iu kin ca a v b l (bit ion SO42khng b in phn trong dung dch) A. b > 2a B. b = 2a C. b < 2a D. 2b = a Bi 3: in phn c mng ngn in cc tr 100 ml dung dch cha CuSO4, NaCl u c nng mol/l l 0.1M vi cng I = 0.5A sau mt thi gian thu c dung dch c pH = 2. Thi gian tin hnh in phn l: A. 193s B. 1930s C. 2123s D. 1737s 5: Bi ton xc nh tn nguyn t thng qua in phn Bi 1: in phn vi in cc tr dung dch mui clorua ca mt kim loi ha tr II vi cng dng in 3A. Sau 1930 giy, thy khi lng catot tng 1.92 gam. Kim loi trong mui clorua trn l kim loi no di y. A. Ni B. Zn C. Fe D. Cu Bi 2: in phn 100 ml dung dch cha 2.7 gam mui clorua ca kim loi X cho ti khi kh bt u xut hin catot th ngng in phn thu c 0.228 lt kh anot (o ktc). Kim loi l: A. Cu B. Zn C. Al D. Mg Bi 3: in phn 100 ml dung dch XSO4 0.2M vi cng dng in mt chiu I = 10A trong thi gian t, khi anot thot ra 224 ml kh ( ktc) th cng lc kim loi bm vo catot c 1.28gm. Xc nh tn kim loi X. A. Fe B. Zn C. Cu D. Mg Tnh thi gian t, bit hiu sut phn ng t 100% A. 579 giy B. 386 giy C. 193 giy D. 289.5 giy Tnh nng ca dung dch sau in phn, bit th tch dung dch thay i khng ng k. A. 0.15M B. 0.12M C. 0.1M D. 0.18M Bi 4: in phn 100 ml dung dch XSO4 0.2M vi cng dng in I = 9.65A sau 200 giy th dng li thy khi lng catot tng 0.64 gam. Xc nh tn kim loi X. A. Ni B. Zn C. Cu D. Fe Nu in phn dung dch ny n 500 giy th khi lng catot tng: A. 1.6 gam B. 0.8 gam C. 0.96 gam D. 1.28 gam Bi 5: in phn (c mng ngn) hon ton dung dch c cha 0.745 gam XCl, cng dng in mt chiu I = 9.65A. Khi nc bt u b in phn c hai in cc th mt 100 giy. Xc nh kim loi X. A. Li B. Na C. K D. Rb Gi s th tch dung dch sau in phn l 100 ml. Tnh pH ca dung dch sau in phn. A. 13 B. 12 C. 11 D. 10 6. IN PHN NNG CHY Bi 1: in phn nng chayr2.34 gam NaCl vi cng dng in mt chiu I = 9.65A. Tnh khi lng Na bm vo catot khi thi gian in phn l 200 giy. A. 0.23 gam B. 0.276 gam C. 0.345 gam D. 0.46 gam in phn ht lng NaCl ban u vi cng dng in khng i th thi gian in phn l: A. 500 giy B. 400 giy C. 300 giy D. 200 giy

Bi 2: in phn nng chy a gam mui G to bi kim loi M v halogen X ta thu c 0.96 gam kim loi M catot v 0.04 mol kh anot. Mt khc, ha tan a gam mui G vo nc sau cho tc dng vi dung dch AgNO3 d thu c 11.48 gam kt ta. Cho bit X l halogen no: A. Clo B. Brom C. Iot D. Khng d liu. Cho bit M l kim loi no: A. Na B. Mg C. Al D. Khng d liu. Bi 3: in phn nng chy hon ton 4 gam XOH, kim loi X bm vo catot cho tc dng ht vi nc thu c 1 lt dung dch A c pH bng 13. Cho bit X l kim loi g. A. K B. Li C. Na D. Rb Nu cng dng in l 193A th thi gian in phn l bao nhiu. A. 50 giy B. 40 giy C. 30 giy D. 60 giy