9.3.

Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son

BI TP AMIN
A. BI TP AMIN I. L THUYT 1. nh ngha CTTQ a. nh ngha Cu 1: Pht biu no sau y l ng? A. Khi thay H trong hirocacbon bng nhm NH2 ta thu c amin B. Amino axit l hp cht hu c a chc c 2 nhm NH 2 v COOH C. Khi thay H trong phn t NH3 bng gc hirocacbon ta thu c amin. D. Khi thay H trong phn t H2O bng gc hirocacbon ta thu c ancol. Cu 2: Pht biu no sau y khng ng? A. Amin c cu to bng cch thay th H ca amoniac bng 1 hay nhiu gc hirocacbon. B. Bc ca amin l bc ca nguyn t cacbon lin kt vi nhm amin. C. Ty thuc vo gc hirocacbon c th phn bit thnh amin thnh amin no, cha no v thm. D. Amin c t 2 nguyn t cacbon trong phn t bt u xut hin ng phn. Cu 3: Pht biu no sau y ng? A. Amin l hp cht m phn t c nit trong thnh phn. B. Amin l hp cht c mt hay nhiu nhm NH2 trong phn t. C. Amin no, n chc, mch h c cng thc chung l CnH2n + 3N (n 1) D. A v C ng. Cu 4: Cho cc cht c cu to nh sau: (1) CH3 - CH2 - NH2; (2) CH3 - NH - CH3; (3) CH3 - CO - NH2 ; (4) NH2 - CO - NH2; (5) NH2 - CH2 - COOH (6) C6H5 - NH2; (7) C6H5NH3Cl; (8) C6H5 - NH - CH3; (9) CH2 = CH - NH2. Cht no l amin ? A. (1); (2); (6); (7); (8) B. (1); (3); (4); (5); (6); (9) C. (3); (4); (5) D. (1); (2); (6); (8); (9). Cu 5: Cng thc chung ca amin thm (cha 1 vng benzen) n chc bc nht l A. CnH2n 7NH2 (n 6) B. CnH2n + 1NH2 (n6) C. C6H5NHCnH2n+1 (n6) D. CnH2n 3NH2 (n6) Cu 6: Chn cu ng a. Cng thc tng qut ca amin mch h c dng l A. CnH2n+3N. B. CnH2n+2+kNk. C. CnH2n+2-2a+kNk. D. CnH2n+1N. b. Cng thc tng qut ca amin no, mch h c dng l A. CnH2n+3N. B. CnH2n+2+kNk. C. CnH2n+2-2a+kNk. D. CnH2n+1N. b. S ng phn bc ca amin Cu 1: Khng nh no sau y khng ng? A. Amin C3H9N c 4 ng phn cu to. B. Amin c CTPT C4H11N c 3 ng phn mch khng phn nhnh. C. C 5 amin cha vng benzen c cng cng thc phn t C7H9N D. C 5 amin bc 2 c cng cng thc phn t C5H13N Cu 2: ng vi cng thc phn t C 4H11N, c x ng phn amin bc nht, y ng phn amin bc hai v z ng phn amin bc ba. Cc gi tr x, y v z ln lt bng: A. 4, 3 v 1 C. 3, 3 v 0 B. 4, 2 v 1 D. 3, 2 v 1 Cu 3: S ng phn cu to ca amin ng vi cng thc phn t C 4H11N tc dng vi dung dch hn hp HCl v NaNO 2 sinh ra cht kh l: A. 7 B. 8 C. 4 D. 5 Cu 4: Cho cc cht C4H10O, C4H9Cl, C4H10, C4H11N. S ng phn cu to ca cc cht gim theo th t l A. C4H11N, C4H10O, C4H9Cl, C4H10 B. C4H10O, C4H11N, C4H10, C4H9Cl C. C4H10O, C4H9Cl, C4H11N, C4H10 D. C4H10O, C4H9Cl, C4H10, C4H11N. Cu 5: Khng nh no sau y khng ng? A. Bc ca amin phu thuc vao s nguyn t H trong NH3 a c thay bng gc hidrocacbon. B. Cho cc cht: 1. CH3NH2; 2. CH3NHCH3; 3. (CH3)(C2H5)2N; 4. (CH3)(C2H5)NH; 5.(CH3)2CHNH2. Amin bc 2 l 2, 4. C. 2 cht C6H5CHOHCH3 v C6H5NHCH3 c cng bc D. Cc amin: etylmetylamin (1) ; etylimetylamin (2) ; isopropylamin (3) c sp xp theo th t bc amin tng dn l (2), (3),(1). c. Danh php Cu 1: Khng nh no sau y khng ng? A. Amin c CTCT (CH3)2CHNH2 c tn thng l izo-propylamin B. Amin c CTCT (CH3)2CH NH CH3 c tn thay th l N-metylpropan -2-amin C. Amin c CTCT CH3[CH2]3N(CH3)2 c tn thay th l N,N- imetylbutan-1-amin D. Amin c CTCT (CH3)2(C2H5)N c tn gi l imetyletylamin Cu 2: Khng nh no sau y khng ng? A. Amin tn gi etyl izo-propyl amin c CTCT l (CH3)2CH(C2H5)NH B. N,N- Etylmetylpropan-1-amin c CTCT l (CH3)(C2H5)(CH3CH2CH2)N

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 2 C. Amin bc 2 c CTPT l C3H7N c tn gi l etylmetylamin hoc Nmetyletanamin. D. Amin c CTCT C6H5-CH2-NH2 c tn gi l phenylamin. Cu 3: Tn gi ca amin no sau y l ng? A. 2-etylpropan-1-amin B. N-n-propyletanamin C. butan-3-amin D. N,N-imetylpropan-2-amin Cu 4: Cho amin c cu to: CH3-CH(CH3)-NH2 . Chn tn gi khng ng? A. Prop-1-ylamin B. Propan-2-amin C. isoproylamin D. Prop-2-ylamin Cu 5: Tn gi cc amin no sau y l khng ng? A. CH3-NH-CH3 imetylamin B. CH3-CH2-CH2NH2 n-propylamin C. CH3CH(CH3)-NH2 isopropylamin D. C6H5NH2 alanin Cu 6: Hp cht c CTCT: m-CH3-C6H4-NH2 c tn theo danh php thng thng l A. 1-amino-3-metyl benzen. B. m-toludin. C. m-metylanilin. D. C B, C u ng. Cu 7: Hp cht c CTCT nh sau CH3CH(OH)CH2CH(NH2)CH(CHO)CH3. Tn hp cht theo danh php IUPAC l A. 3-amino-5-hiroxi-2-metylhexanal. B. 5-hiroxi-2-metyl-3-aminohexanal. C. 5-oxo-4-aminohexanol-2. D. 4-amino-5-oxohexanol. Lu : Theo quy tc ca IUPAC mc u tin ca cc nhm chc gim theo dy sau: COOH>-SO3H>-COOR>-COCl>-CONH2>-CHO>-O->-OH>-NH2>-OR>-R. 2. Tnh cht vt l - ng dng iu ch Cu 1: Gii php thc t no sau y khng hp l ? A. Tng hp cht mu cng nghip bng phn ng ca amin thm vi dung dch hn hp NaNO 2 v HCl nhit thp. B. To cht mu bng phn ng gia amin no v HNO2 nhit cao. C. Kh mi tanh ca c bng gim n. D. Ra l ng anilin bng axit mnh. Cu 2: iu ch anilin bng cch kh nitrobenzen th dng cht kh l A. kh H2 B. NH3 C. Cacbon D. Fe + dung dch HCl Cu 3: ng dng no sau y khng phi ca amin? A. Cng ngh nhum. B. Cng nghip dc C. Cng ngh tng hp hu c. D. Cng ngh giy. Cu 4: Trong s cc cht sau: C 2H6 ; C2H5Cl ; C2H5NH2 ; CH3COOC2H5 ; CH3COOH ; CH3CHO ; CH3OCH3 cht no to c lin kt H lin phn t? A. C2H6 B. CH3COOCH3 C. CH3CHO ; C2H5Cl D. CH3COOH ; C2H5NH2. Cu 5: Metylamin d tan trong H2O do nguyn nhn no sau y ? A. Do nguyn t N cn cp electron t do d nhn H + ca H2O. B. Do metylamin c lin kt H lin phn t. C. Do phn t metylamin phn cc mnh. D. Do phn t metylamin to c lin kt H vi H2O. Cu 6: Khng nh no sau y khng ng? A. Trong cc cht: CH3Cl, CH3OH, CH3OCH3, CH3NH2 th CH3OH l cht lng iu kin thng. B. Nhit si ca ancol cao hn so vi hirocacbon c phn t khi tng ng do c lin kt H gia cc phn t ancol. C. Phenol l cht rn kt tinh iu kin thng. D. Metylamin l cht lng iu kin thng ,c mi khai, tng t nh amoniac. Cu 7: Khi cho anilin vo ng nghim cha nc, hin tng quan st c l A. Anilin tan trong nc to dung dch trong sut. B. Anilin khng tan to thnh lp di y ng nghim. C. Anilin khng tan ni ln trn lp nc. D. Anilin t tan trong nc to dung dch b c, lu c s tch lp. Cu 8: un hn hp brometan d v dung dch amoniac trong etanol 100 0C (phng php Hoffman) ngi ta thu c sn phm g? A. Cc loi mui clorua B. Trietylamin C. ietylamin D. Tt c cc sn phm trn Cu 9: Pht biu no sau y v tnh cht vt l ca amin l khng ng? A. Metyl amin, imetyl amin, etyl amin l cht kh, d tan trong nc B. Cc amin kh c mi tng t aminiac, c C. Anilin l cht lng kh tan trong nc, mu en D. tan trong nc ca amin gim dn khi s nguyn t cacbon trong phn t tng Cu 10: Hp cht no sau y c nhit si cao nht? A. n butylamin. B. Tert butylamin C. Metyl n propylamin D. imetyl etylamin Cu 11: Hy cho bit s sp xp no sau y ng vi chiu tng dn v nhit si ca cc cht? A. ancol metylic < axit fomic < metylamin < ancol etylic B. ancol metylic < ancol etylic < metylamin < axit fomic C. metylamin < ancol metylic < ancol etylic < axit fomic D. axit fomic < metylamin < ancol metylic < ancol etylic Cu 12: Cho ba hp cht butylamin (1), ancol butylic (2) v pentan (3). Th t gim dn nhit si l: A. (1) > (2) > (3). B. (1) > (3) > (2). C. (2) > (1) > (3). D. (3) > (2) > (1). Cu 13: Cho cc cht CH3NH2, C2H5NH2, CH3CH2CH2NH2. Theo chiu tng dn phn t khi Nhn xt no sau y ng? A. Nhit si tng dn, tan trong nc tng dn B. Nhit si gim dn, tan trong nc tng dn C. Nhit si tng dn, tan trong nc gim dn D. Nhit si gim dn, tan trong nc gim dn

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 3 Cu 14: Cho cc cht sau: Ancol etylic (1), etylamim (2), metylamim (3), axit axetic (4). Dy sp sp theo chiu c nhit si tng dn l dy no ? A. (2) < (3) < (4) < (1) B. (2) < (3) < (4) < (1) C. (3) < (2) < (1) < (4) D. (1) < (3) < (2) < (4) Cu 15: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l A. C4H10, C3H7NH2, C3H7F, C3H7OH, CH3CH2COOH B. C4H10, C3H7Cl, C3H7NH2, C3H7OH, CH3CH2COOH C. Benzen, toluen, phenol, CH3COOH D. (CH3)3N, CH3CH2OH, CH3CH2CH2NH2, HCOOH 3. Tnh cht ho hc a. So snh tnh baz ca cc amin Cu 1: Nguyn nhn Amin c tnh baz l A. C kh nng nhng proton. B. Trn N cn mt i electron t do c kh nng nhn H+. C. Xut pht t amoniac. D. Phn ng c vi dung dch axit. Cu 2: Tnh baz ca metylamin mnh hn anilin v A. Nhm metyl lm tng mt electron ca nguyn t nit, nhm phenyl lm gim mt electron ca nguyn t nit. B. Nhm metyl lm tng mt electron ca nguyn t nit. C. Nhm metyl lm gim mt electron ca nguyn t nit, nhm phenyl lm tng mt electron ca nguyn t Nit. D. Phn t khi ca metylamin nh hn. Cu 3: Khng nh no sau y lun ng? A. Tnh baz ca amin tng dn theo th t: bc I < bc II < bc III. B. Tnh baz ca anilin l do nhm NH2 nh hng ln gc C6H5. C. V c tnh baz nn anilin lm i mu cht ch th mu. D. Do nh hng ca nhm C6H5 lm gim mt e trn Nit nn anilin c tnh baz yu. Cu 4. iu nao sau y sai? A. Cc amin u c tnh baz. B. Tnh baz ca cc amin u mnh hn NH3. C. Anilin c tnh baz rt yu. D. Amin co tinh baz do N co cp electron cha chia. Cu 5. Cc gii thch v quan h cu trc, tnh cht no sau y khng hp l? A. Do c cp electron t do trn nguyn t N m amin c tnh baz. B. Do nhm NH2- y e nn anilin d tham gia vo phn ng th vo nhn thm hn v u tin v tr o- v p-. C. Tnh baz ca amin cng mnh khi mt electron trn nguyn t N cng ln. D. Vi amin R-NH2, gc R ht electron lm tng mnh ca tnh baz v ngc li. Cu 6. Phn ng no di y khng th hin tnh baz ca amin? A. CH3NH2 + H2O CH3NH3+ + OHB. C6H5NH2 + HCl C6H5NH3Cl 3+ + C. Fe + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH3 D. CH3NH2 + HNO2 CH3OH + N2 + H2O Cu 7: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l A. anilin, metylamin, amoniac. B. anilin, amoniac, natri hiroxit. C. amoni clorua, metylamin, natri hiroxit. D. metylamin, amoniac, natri axetat. Cu 8: Chn cu ng khi ni v s i mu ca cc cht khi gp qu tm? A. Phenol trong nc lm qu tm ha . B. Anilin trong nc lm qu tm ha xanh. C. Etylamin trong nc lm cho qu tm chuyn thnh mu xanh. D. dung dch Natriphenolat khng lm qu tm i mu. Cu 9: Cho cc cht sau: phenol, anilin, phenyl amoni clorua, amoni clorua, natriphenolat, axit axetic, natri axetat, natri etylat; natri clorua; natri cacbonat. S cht c kh nng lm qu tm m chuyn mu l A. 6 B. 8 C. 5 D. 7 Cu 10: Trong cc cht di y, cht no c lc baz mnh nht ? A. NH3 B. C6H5CH2NH2 C. C6H5NH2 D. (CH3)2NH Cu 11: Trong cc cht di y, cht no c lc baz yu nht ? A. C6H5NH2 B. C6H5CH2NH2 C. (C6H5)2NH D. NH3 Cu 12: Trong cc cht di y, cht no c tnh baz mnh nht ? A. C6H5NH2. B. (C6H5)2NH C. p-CH3-C6H4-NH2. D. C6H5-CH2-NH2 Cu 13: Cht no c lc baz mnh nht ? A. CH3NH2 B. (CH3)2CH NH2 C. CH3NH CH3 D. (CH3)3N Cu 14: Cht no c lc baz yu nht ? A. CH3NH2 B. (CH3)2CH NH2 C. CH3NH CH3 D. (CH3)3N Cu 15: Hp cht no di y c tnh baz mnh nht: A. CH3 C6H4 NH2 B. O2N C6H4 NH2 C. CH3 O C6H4 NH2 D. Cl C6H4 NH2 Cu 16: Cht no di y c tnh baz mnh nht? A. NH3 B. CH3CONH2 C. CH3CH2CH2OH D. CH3CH2NH2 Cu 17: Amin no sau y c tnh baz mnh nht? A. CH3CH=CH-NH2. B. CH3CH2CH2NH2. C. CH3CC-NH2. D. CH3CH2NH2.

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 4 Cu 18: Trong cc cht: p.O 2N-C6H4-OH, m.CH3-C6H4-OH, p.NH2-C6H4-CHO, m.CH3-C6H4-NH2. Cht c lc axit mnh nht v cht c lc baz mnh nht tng ng l A. p.O2N-C6H4-OH v p.NH2-C6H4-CHO B. p.O2N-C6H4-OH v m.CH3-C6H4-NH2 C. m.CH3-C6H4-OH v p.NH2-C6H4-CHO D. m.CH3-C6H4-OH v m.CH3-C6H4-NH2 Cu 19: Trt t tng dn mnh tnh baz ca dy no di y khng ng? A. C6H5NH2< NH3 C. NH3<CH3NH2<CH3CH2NH2 B. CH3CH2NH2 < CH3NHCH3 D. p-CH3C6H4NH2<p-O2NC6H4NH2 Cu 20: Hy sp xp cc cht sau y theo trt t tng dn tnh baz : (1) amoniac ; (2) anilin ; (3) etylamin ; (4) ietylamin; (5) Kalihiroxit. A. (2)<(1)<(3)<(4)<(5). B. (1)<(5)<(2)<(3)<(4). C. (1)<(2)<(4)<(3)<(5). D. (2)<(5)<(4)<(3)< (1). Cu 21: C 4 ha cht : metylamin (1), phenylamin (2), iphenylamin (3), imetylamin (4). Th t tng dn lc baz l A. (3) < (2) < (1) < (4). B. (2) < (3) < (1) < (4). C. (1) < (3) < (2) < (4). D. (4) < (1) < (2) < (3). Cu 22: Dy sp xp ng theo th t tng dn tnh baz: A. Anilin < iphenylamin < xiclohexylamin. B. Anilin < xiclohexylamin < iphenylamin C. iphenylamin < Anilin < xiclohexylamin. D. Xiclohexylamin < iphenylamin < Anilin. Cu 23: Hy sp xp cc cht sau y theo th t tng dn tnh baz: (1) metylamin; (2) amoniac; (3) etylamin; (4) anilin; (5) n propylamin. A. (4)<(5)<(2)<(3)<(1) B. (4)<(2)<(1)<(3)<(5) C.(2)<(1)<(3)<(4)<(5) D. (2)<(5)<(4)<(3)<(1) Cu 24: Cho cc cht sau: p-NO2C6H4NH2 (1), p-ClC6H5NH2 (2), p-CH3C6H5NH2 (3). Tnh baz tng dn theo dy no ? A. (1) < (2) < (3) B. (2) < (1) < (3) C. (1) < (3) < (2) D. (3) < (2) < (1) Cu 25: Chiu tng dn tnh baz ca dy cht sau C6H5OH, C6H5NH2, NH2CH3, NaOH l A. C6H5NH2, C6H5OH, NH2CH3, NaOH B. NH2CH3,C6H5OH, C6H5NH2, NaOH C. C6H5OH, NH2CH3, C6H5NH2, NaOH D. C6H5OH, C6H5NH2, NH2CH3, NaOH Cu 26: Cho cc cht sau: 1. p- CH3C6H4NH2 2. m-CH3C6H4NH2 3. C6H5NHCH3 4. C6H5NH2 Xp cc cht sau theo chiu tng dn tnh baz A. 1 < 2 < 4 < 3 B. 4 < 2 < 1 < 3 C. 4 < 3 < 2 < 1 D. 4 < 3 < 1 < 2 Cu 27: Dy no sau y c sp xp theo chiu tng tnh baz A. C2H5ONa, NaOH, NH3, C6H5NH2, CH3C6H4NH2, CH3NH2 B. C6H5NH2,CH3C6H4NH2, NH3,CH3NH2, C2H5ONa, NaOH. C. NH3, C6H5NH2, CH3C6H4NH2, CH3NH2, C2H5ONa, NaOH D. C6H5NH2,CH3C6H4NH2, NH3,CH3NH2, NaOH, C2H5ONa. Cu 28: Cho cc cht imetylamin (1), Metylamin (2), Amoniac (3), Anilin (4), p-metylanilin (5), p-nitroanilin (6). Tnh baz tng dn theo th t l: A. (1), (2), (3), (4), (5), (6) B. (6), (4), (5), (3), (2), (1) C. (6), (5), (4), (3), (2), (1) D. (3), (2), (1), (4), (5), (6) Cu 29: Cho cc cht: natri hiroxit (1), imetylamin (2), etylamin (3),natri etylat (4),p-metylanilin (5), amoniac (6), anilin (7), p-nitroanilin (8), natri metylat (9) , metylamin (10). Th t gim dn lc baz l: A. (4), (9), (1), (2), (3), (10), (5), (6), (7), (8). B. (4), (9), (1), (2), (3), (10), (6), (5), (7), (8). C. (1), (4), (9), (2), (3), (10), (6), (5), (8), (7). D. (9), (4), (1), (2), (3), (10), (6), (5), (7), (8). Cu 30: Gi tr pH tng dn ca cc dung dch c cng nng mol/l no sau y l ng?(xt 25 0C) A. NaOH, CH3NH2,NH3, Ba(OH)2, C6H5OH B. Ba(OH)2, NaOH, CH3NH2, C6H5OH C. NH3, CH3NH2, C6H5NH2, NaOH, Ba(OH)2 D. C6H5NH2, CH3NH2, NaOH, Ba(OH)2 Cu 31: Cho cc dung dch sau c cng pH: HCl; NH4Cl; C6H5NH3Cl. Th t tng dn nng mol/lt ca cc dung dch l A. HCl < NH4Cl < C6H5NH3Cl B. HCl < C6H5NH3Cl < NH4Cl C. C6H5NH3Cl < NH4Cl < HCl D. NH4Cl < HCl < C6H5NH3Cl Cu 32: Cho cc dung dch sau: NaOH, NH 3, CH3NH2 v NH4Cl. Hy cho bit s sp xp no sau y ng vi chiu tng dn pH ca cc dung dch bit rng cc dung dch c cng nng mol/l. A. NaOH < CH3NH2 < NH3 < NH4Cl B. CH3NH2 < NH4Cl < NH3 < NaOH C. NH3 < CH3NH2 < NaOH < NH4Cl D. NH4Cl < NH3 < CH3NH2 < NaOH Cu 33: So snh no sau y l ng? A. Trt t tng dn lc baz: C3H7NH2 < CH3NHC2H5 < (CH3)3N. B. Trt t tng dn lc axit: CH2ClCH2COOH < CH3CHClCOOH < CH3CHFCOOH. C. Trt t tng dn lc baz: CH3NH2 < NH3 < C6H5NH2. D. Trt t tng dn lc axit: HCOOH < CH3COOH < CH3CH2COOH. b. Tnh cht ho hc Cu 1: Anilin (C6H5NH2) v phenol (C6H5OH) u c phn ng vi

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 5 A. dung dch NaCl. B. dung dch HCl. C. nc Br2. D. dung dch NaOH. Cu 2: Dung dch etylamin khng tc dng vi cht no sau y? A. axit HCl B. dd CuCl2 C. dd HNO3 D. dd NaOH Cu 3: Anilin tc dng c vi nhng cht no sau y? (1) dd HCl; (2) dd H2SO4; (3) dd NaOH ; (4) dd brom; (5) dd CH3 CH2 OH; (6) dd CH3COOC2H5 A. (1) , (2) , (3) B. (4) , (5) , (6) C. (3) , (4) , (5) D. (1) , (2) , (4). Cu 4: Cht khng phn ng vi dung dch NaOH l A. C6H5NH3Cl. B. C6H5CH2OH. C. p-CH3C6H4OH. D. C6H5OH. Cu 5: Phenol v anilin u lm mt mu nc brom cn toluen th khng, iu ny chng t A. nhm OH v NH2 y e mnh hn nhm CH3 B. nhm OH v NH2 y e yu hn nhm CH3. C. kh nng y e ca nhm OH>-CH3>-NH2 D. nhm CH3 ht e mnh hn nhm OH v NH2. Cu 6: Khi t chy ng ng ca metylamin, t l th tch k = V CO2 : VH2O (hi) bin i nh th no theo s lng nguyn t cacbon trong phn t ? A. 0,4 < K < 1 B. 0,25 < K < 1 C. 0,75 < K < 1 D. 1 < K < 1,5. Cu 7: Nguyn nhn no sau y lm anilin tc dng c vi dung dch nc brom ? A. Do nhn thm benzen c h thng lin kt bn vng. B. Do nhn thm benzen ht electron. C. Do nhn thm benzen y electron. D. Do nhm NH2 y electron lm tng mt electron cc v tr o- v p-. Cu 8: Bn ng nghim ng cc hn hp sau: (1) benzen + phenol; (2) anilin + dung dch HCl d; (3) anilin + dung dch NaOH; (4) anilin + H2O ng nghim no s s tch lp cc cht lng? A. (3), (4) B. (4) C. (1), (2), (3) D. (1), (4) Cu 9: Khi cho metylamin v anilin ln lt tc dng vi HBr v dung dch FeCl2 s thu c kt qu no di y? A. C metylamin v anilin u tc dng vi c HBr v FeCl2. B. Metylamin ch tc dng vi HBr cn anilin tc dng c vi c HBr v FeCl2. C.. Metylamin tc dng c vi c HBr v FeCl2 cn anilin ch tc dng vi HBr. D. C metylamin v anilin u ch tc dng vi HBr m khng tc dng vi FeCl2 Cu 10: Khi nh vi git dd C2H5NH2 vo dd FeCl3 sau phn ng thy A. dd trong sut khng mu B. dd mu vng nu C. c kt ta mu gch D. c kt ta mu nu Cu 11: Hp cht hu c B thnh phn cha: C, H, N c cc tnh cht sau: iu kin thng l cht lng khng mu, rt c, t tan trong nc, d tc dng vi dung dch HCl v d lm mt mu dung dch Br 2 to kt ta trng. Cng thc phn t ca B c th l A. C4H9N B. C6H7N C. C7H11N D. C2H7N Cu 12: Cho dung dch etylamin tc dng va vi cht X thy c kh bay ra v dung dch sau phn ng c mi ancol. X l A. HNO2 B. CH3I C. CH3OH D. HNO3. Cu 13: Cho kh CO2, dd KHSO4 vo 2 ng nghim cha dung dch C 6H5ONa. Cho dd NaOH, dd HCl vo 2 ng nghim cha dung dch phenylamoni clorua. Hin tng dd b vn c s xy ra : A. 2 ng nghim. B. C 4 ng nghim C. 3 ng nghim D. 1 ng nghim Cu 14: Cho vi git anilin vo nc, sau thm dung dich HCl (d) vo, ri li nh tip dung dch NaOH vo, s xy ra hin tng: A. Lc u dung dich b vn c, sau trong sut v cui cng b vn c li. B. Lc u dung dich trong sut, sau b vn c v cui cng tr li trong sut. C. Dung dch trong sut. D. Dung dch b vn c hon ton. Cu 15: Th nghim no sau y khng thu c kt ta sau khi phn ng kt thc? A. Cho dung dch CH3NH3 n d vo dung dch Al(NO3)3 B. Nh dung dch NH3 n d vo dung dch ZnCl2 C. Cho kh CO2 li vo dung dch Na[Al(OH)4] (hoc NaAlO2) cho n d D. Nh dung dch NH3 n d vo dung dch AlCl3 Cu 16: u khng nh no sau y lun lun ng? A. Phn t khi ca mt amin n chc lun l s l. B. Phn t khi ca mt amin n chc lun l s chn. C. t chy ht a mol amin bt k lun thu c ti thiu a/2 mol N 2 (phn ng chy ch cho N2) D. A v C ng. Cu 17: Trong s cac phat biu sau v anilin? (1) Anilin tan it trong nc nhng tan nhiu trong dung dich NaOH. (2) Anilin co tinh baz, dung dich anilin khng lam i mau quy tim. (3) Anilin dung san xut phm nhum, dc phm, polime. (4) Anilin tham gia phan ng th brom vo nhn thm d hn benzen. Cac phat biu ung la A. (1), (2), (3) B. (1), (2), (4) C. (1), (3), (4) D. (2), (3), (4) Cu 18: Trong s cc cu sau: a) Cc cht: amoniac, etylamin, hiro, ancol metylic u kh c ng (II) oxit khi nung nng.

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 6 b) Propen v xiclopropan khi cng brom u cho cng mt sn phm. c) Cc cht rn: km hiroxit, bc oxit, bc clorua u tan c trong dung dch amoniac m c. d) Khi cho dung dch natri stearat vo dung dch canxi hirocacbonat c kt ta to thnh. e) Stiren v toluen u c kh nng lm mt mu dung dch thuc tm. S cu ng l A. 3. B. 5. C. 4. D. 2. Cu 19: Pht biu no sau y ng? A. Etylamin phn ng vi axit nitr nhit thng sinh ra bt kh. B. Anilin tc dng vi axit nitr khi un nng thu c mui iazoni. C. Benzen lm mt mu nc brom nhit thng. D. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam. Cu 20: Nhn nh no sau y khng ng? A. Phenylamin c tnh baz yu hn NH3 B. Nh c tnh baz, anilin tc dng c vi dung dich Brom. C. Anilin khng tc dng c vi dung dich NaOH. D. Tt c cc amin u c kh nng nhn proton. Cu 21: Pht biu no sau y khng ng? A. Phenol phn ng vi dung dch NaOH, ly mui thu c cho tc dng vi dung dch HCl li thu c phenol. B. Dung dch natri phenolat phn ng vi kh CO 2, ly kt ta thu c tc dng vi dung dch NaOH li thu c natri phenolat. C. Axit axetic phn ng vi NaOH, ly mui thu c cho tc dng vi CO 2 li thu c axit axetic. D. Anilin phn ng vi dung dch HCl, ly mui thu c cho tc dng vi dung dch NaOH li thu c anilin. Cu 22: Nhn xt no di y khng ng? A. Anilin c tnh baz, phenol c tnh axit B. Phenol v anilin d tham gia phn ng th vo nhn thm do nh hng ca vng benzen ln nhm OH hoc NH 2. C. Anilin v phenol u d tham gia phn ng th vi dd Br2 to kt ta trng D. Anilin v phenol u tham gia phn ng cng H2 vo nhn thm Cu 23: Hin tng no sau y khng ng? A. Nhng qu tm vo metyl amin thy qu tm chuyn sang mu xanh B. Phn ng gia kh metyl amin v kh HCl xut hin khi trng C. Nh vi git dd Br2 v dd anilin thy xut hin kt ta trng D. Thm vi git phenolphtalein vo dd etyl amin thy xut hin mu xanh Cu 24: Pht biu no sau y khng ng? A. Anilin c iu ch trc tip t nitrobenzen. B. Trong phn ng este ho axit cacboxylic ng vai tr axit cn ancol ng vai tr baz. C. Gc phenyl (-C6H5) v nhm chc amino (-NH2) trong phn t anilin c nh hng qua li vi nhau D. Anilin c tnh baz yu hn NaOH nn b NaOH y ra khi mui Cu 25: Hp cht hu c X mch h cha cc nguyn t C, H, N trong c 23,72% khi lng N. X tc dng vi HCl theo t l mol 1:1. Chn cu pht biu sai? A. X l hp cht amin. B. Cu to ca X l amin no, n chc C. Nu cng thc X l CxHyNz th z = 1 D. Nu cng thc X l CxHyNz th : 12x - y = 45 Cu 26: Metylamin khng c tnh cht no sau y: A. Tc dng vi dung dch FeCl3 to kt ta. B. Tc dng vi cc axit to mui d tan trong nc. C. L cht kh c mi khai tng t ammoniac. D. C tnh baz yu hn so vi ammoniac. Cu 27: Cho dy cc cht: etyl axetat, anilin, ancol etylic, axit acrylic, phenol, phenylamoni clorua, ancol benzylic, p-crezol, cumen. S cht trong dy tc dng c vi dung dch NaOH l A. 5. B. 4. C. 3. D. 6. Cu 28: Cho cc hp cht sau: C 2H5OH, C6H5ONa, CH3OCH3, C6H5OH, C6H5NH3Cl, CH3COOCH3, C6H5CH2OH, HOC6H4CH3. S cht tc dng vi dung dch NaOH l A. 4. B. 6. C. 3. D. 5. Cu 29: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2(anilin), C6H5OH (phenol), C6H6 (benzen), CH3CHO. S cht trong dy lm mt mu dung dch brom l A. 6 B. 5 C. 7 D. 8 Cu 30: Co 12 c h t : Anilin; Phenol; Axetanehit; Stiren; Toluen; Axit metacrylic; Vinyl axetat; Isopren; Benzen; Ancol isoamylic; Isopentan; Axeton. S cht c kha nng lm mt mu nc brom l A. 8. B. 6. C. 5. D. 7. Cu 31: C 5 l ng ha cht, trong c 3 dung dch CH 3NH2, C6H5ONa, C2H5NH3Cl v 2 cht lng C6H6, C6H5NH2. Nu cho dung dch HCl vo ln lt vo 5 l trn th s phn ng xy ra l: A. 2. B. 3. C. 4. D. 5.

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 7 Cu 32: Cho cc cht sau: C2H5OH, C6H5OH, C6H5NH2, dung dch C6H5ONa, dung dch NaOH, dung dch CH3COOH, dung dch HCl. Cho tng cp cht tc dng vi nhau iu kin thch hp, s cp cht c phn ng xy ra l A. 8 B. 12 C. 9 D. 10 Cu 33: Cho cc cht: phenol, ancol metylic, axit fomic, natri phenolat v natri hiroxit. Trong iu kin thch hp s cp cht c th tc dng c vi nhau l: A. 3. B. 5. C. 4. D. 2. Cu 34: Cho anilin tc dng vi cc cht sau: dung dch Br 2, CH3I, dung dch HCl, dung dch NaOH, HNO 2. S phn ng xy ra l: A. 5 B. 3 C. 6. D. 4 Cu 35: Cho cc cht sau: axit axetic; phenol; ancol etylic; v anilin ln lt tc dng vi; dung dch NaOH; dung dch NaHCO3; dung dch brom; HCl. S phng trnh phn ng xy ra l: A. 6 B. 8 C. 7 D. 5 Cu 36: Cho dung dich metylamin d ln lt vo tng dung dch FeCl 3, AgNO3, NaCl, Cu(NO3)2. S trng hp thu c kt ta sau phan ng la: A. 1 B. 2 C. 3 D. 4 Cu 37: Dy cht u tc dng vi CH3COOH l A. CH3OCH3, NaOH, CH3NH2, C6H5OH B. CH3CH2OH, NaHCO3, CH3NH2, C6H5ONa C. CH3CH2OH,NaHSO4,CH3NH2,C6H5ONa D. CH3CH2OH, CaCO3, C6H5NH2; C6H5OH Cu 38: Trong s cc hp cht thm sau: C6H5OH ; C6H5NH2 ; C6H5CHO ; C6H5COOH , C6H5CH3 , C6H5OCH3 ; C6H5Cl. Tng s cht nh hng nhm th mi vo v tr meta l: A. 2 B. 3 C. 4 D. 5 Cu 39: Trong s cc cht: clobenzen, toluen, nitrobenzen, anilin, phenol, axit benzoic, benzanehit, naphtalen, p-xilen, cumen, p-crezol, s cht tham gia phn ng th nhn thm d hn so vi benzen l A. 7. B. 9. C. 8. D. 6. Cu 40: Cho mi cht CH3I (X), HCl (Y), nc brom (Z), NaNO 2/HCl (T) tc dng vi anilin. Cc cht phn ng c vi anilin l A. X,Y, Z v T B. Y,Z v T C. Y v Z D. Z Cu 41: Dung dch metylamin c th tc dng vi cht no sau y: Na 2CO3, FeCl3, H2SO4 long, CH3COOH, C6H5ONa, qu tm A. FeCl3, H2SO4long, CH3COOH, qu tm B. Na2CO3, FeCl3, H2SO4 long, C6H5ONa C. FeCl3, qu tm D. Na2CO3, H2SO4 long, qu tm Cu 42: Cho cc phn ng: C6H5NH3Cl + (CH3)2NH (CH3)2NH2Cl + C6H5NH2 (I); (CH3)2NH2Cl + NH3 NH4Cl + (CH3)2NH (II) Trong phn ng t xy ra l A. (I). B. (II). C. (I), (II). D. khng c. Cu 43: Phn ng no di y l ng? + 5 C A. C2H5NH2+ HNO2 + HCl C2H5N2+Cl-+ 2H2O B. C6H5NH2+ HNO2 + HCl 0 C6H5N2 Cl +2 H2O 5 C C. C6H5NH2+ HNO2 + HCl C6H5N2+Cl-+ 2H2O D. C6H5NH2+ HNO2 + HCl 0 C6H5OH + N2 + H2O Cu 44: Phng trnh ha hc no sau y khng ng? A. 2CH3NH2 + H2SO4 (CH3NH3)2SO4 B. FeCl3 + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH3Cl C. C6H5NH2 + 2Br2 3,5-Br2-C6H3NH2 + 2HBr D. C6H5NO2 + 3Fe +7HCl C6H5NH3Cl + 3FeCl2 + 2H2O Cu 45: Phng trnh ha hc no sau y khng ng? A. 2CH3NH2 + H2SO4 (CH3NH3)2SO4 B. CH3NH2 + O2 CO2 + N2 + H2O C. C6H5NH2 + 3Br2 2,4,6-Br3C6H2NH3Br + 2HBr D. C6H5NO2 + 3Fe +6HCl C6H5NH2 + 3FeCl2 + 2H2O Cu 46: A + HCl RNH3Cl. Trong A (CxHyNt) c %N = 31,11%. CTCT ca A l A. CH3 - CH2 - CH2 - NH2 B. CH3 - NH - CH3 C. C2H5NH2 v CH3 - NH - CH3 D. C2H5NH2 4. Nhn bit Cu 1: C th nhn bit l ng dung dch CH3NH2 bng cch no trong cc cch sau? A. Nhn bit bng mi. B. Thm vi git dung dch H2SO4. C. Thm vi git dung dch Na2CO3. D. a a thy tinh nhng vo dung dch HCl c ln pha trn ming l ng dung dch CH 3NH2 c. Cu 2: phn bit anilin v etylamin ng trong 2 l ring bit ta dng thuc th no? A. Dung dch Br2. B. Dung dch HCl. C. Dung dch NaOH. D. Dung dch AgNO3. Cu 3: Phng php no sau y phn bit hai kh NH3v CH3NH2 ? A. Da vo mi ca kh. C. Th bng dung dch HCl c. B. Th bng qu tm m. D. t chy ri cho sn phm qua dd Ca(OH)2
0
0

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 8 Cu 4: Hoa cht c th dung phn bit phenol v anilin la A. dung dch Br2. B. H2O. C. dung dch HCl. D. NaCl. Cu 5: Ba cht lng: C2H5OH, CH3COOH, CH3NH2 ng trong ba l ring bit. Thuc th dng phn bit ba cht trn l A. qu tm. B. kim loi Na. C. dung dch Br2. D. dung dch NaOH. Cu 6: phn bit phenol, anilin, benzen bng phng phap hoa hoc, ta cn dung cac hoa cht la: A. Dung dich Brm, Na B. Qui tim C. Kim loai Na D. Qui tim, Na. Cu 7: Hy chn thuc th thch hp phn bit 3 cht kh sau: imetyl amin, metylamin, trimetyl amin. A. Dung dch HCl. B. Dung dch FeCl3. C. Dung dch HNO2 D. C B v C. Cu 8: nhn bit dung dch cc cht: glucoz, etylamin, anilin, glixerol, ta c th tin hnh theo trnh t no di y? A. Dng dung dch AgNO3/NH3, qu tm, nc brom B. Dng dung dch AgNO3/NH3, Cu(OH)2 lc nh C. Dng qu tm, Na kim loi, nc brom D. Dng phnolphtalein, Cu(OH)2 lc nh Cu 9: C 4 cht ng trong 4 l mt nhn: phenol, anilin, benzen, styren. Th t nhm thuc th no sau y c th nhn bit 4 cht trn? A. Qu tm, dd Br2 B. dd Br2, dd NaOH C. dd Br2, dd HCl D. B, C Cu 10: C 4 dd ring bit mt nhn: anilin, metyl amin, axit axetic, anehit axetic (axetanehit). Th t thuc th no sau y nhn bit c 4 dd trn? A. dd HCl, dd Br2 B. Qu tm, dd AgNO3/NH3,to C. Qu tm, dd Br2 D. B, C Cu 11: nhn bit cc cht: CH3NH2, C6H5NH2, C6H5OH, CH3COOH trong cc bnh mt nhn ring bit, ngi ta dng A. dd HCl v qu tm B. Qu tm v dd Br2 C. dd NaOH v dd Br2 D. Tt c ng Cu 12: phn bit cc cht: anilin, dung dch metylamin, phenol (lng), benzen ta c th dng thuc th theo th t sau: A. Qu tm, dd HCl, dd NaOH. B. dd brom, qu tm, dd HCl. C. Qu tm, dd NaOH, dd HCl. D. A, B, C u ng. Cu 13: C 4 l mt nhn ng 4 cht: metanol, glyxerol, dd glucoz, anilin. C th dng 2 cht no trong s cc cht sau nhn bit cc cht trn? 1. dd KOH 2. Na kim loi 3. Cu(OH) 2/OH- 4. dd Br2 5. dd AgNO3/NH3, t0C A. 2, 5 B. 1,4 C. 3,4 D. 4,5 Cu 14: C cc ddNH3, C6H5NH2, NaOH, HCl. Thuc th duy nht phn bit cc dd trn l. A. qu tm B. dd Br2 C. dd NaCl D. dd HCHO Cu 15: C 4 dung dch, mi dung dch cha 1 trong 4 cht: CH4O, CH5N, CH2O, CH2O2. Dng cht no nhn bit chng? A. Giy qu, dd AgNO3 /NH3 B. Giy qu, dd FeCl3 C. Giy qu, dd AgNO3 /NH3, Na D. Giy qu, dd AgNO3 /NH3, Br2 Cu 16: Cho cc cht sau: C2H5OH, C6H6, C6H5NH2, C6H5ONa. Chn mt thuc th nhn bit cc cht l A. dung dch NaOH. B. dung dch BaCl2. C. dung dch HCl. D. dung dch Ca(OH)2. Cu 17: C 2 dd NaAlO2, C6H5ONa v 2 cht lng C6H6, C6H5NH2, ng trong cc l ring bit, mt nhn. Nu ch dng dd HCl lm thuc th th nhn bit c cc cht: A. NaAlO2 B. C6H5NH2 C. NaAlO2, C6H5ONa D. C 4 cht trn. Cu 18: Trnh by cch phn bit cc dung dch sau bng mt thuc th: axit axetic, etyl amin, anilin, Na 2CO3 v BaCl2. A. Qu tm B. dung dch brom C. dung dch NaOH D. dung dch HCl Cu 19: C 3 cht lng l C2H5OH, C6H6, C6H5NH2 v 3 dung dch l NH 4HCO3, NaAlO2, C6H5ONa. Ch dng dung dch cht no di y c th nhn bit c tt c cc cht trn? A. NaOH. B. BaCl2. C. Qu tm. D. HCl. Cu 20: Cho cc cht lng: anilin, benzen, ancol etylic v cc dung dch (CH 3COO)2Ba, CH3COONa. Ho cht no sau y c th s dng nhn bit c 3 cht lng v 2 dung dch trn? A. Dung dch H2SO4 B. Dung dch NaOH C. Dung dch HCl D. Dung dch brom Cu 21: Khng th dng thuc th trong dy no sau y phn bit cht lng: phenol, anilin, benzen? A. Dd Brm B. dd HCl v dd NaOH C. dd HCl v dd brm D. dd NaOH v dd brm Cu 22: Cp cht no sau y khng th phn bit c bng dung dch brom A. Stiren v toluen B. Glucoz v Fructoz C. Phenol v anilin D. axit acrylic v phenol Cu 23: C cc cht ng trong cc l b mt nhn l: ancol etylic, anilin, phenol, etylenglycol v mantoz. Dng nhng thuc th no sau y khng th nhn bit c ht? A. CuCl2, dung dch NaOH B. CuCl2, dung dch HCl C. Cu(OH)2/OH-, dd HCl, t0 D. Cu(OH)2/OH-, dd HNO3, t0 Cu 24: lm sch kh CH3NH2 c ln cc kh CH4, C2H2, H2, ngi ta dng A. dd HCl v dd NaOH B. dd Br2 v dd NaOH C. dd HNO3 v dd Br2 D. dd HCl v dd K2CO3 Cu 25: ti to anilin ngi ta cho phenyl amoniclorua tc dng vi cht no sau y ? A. Kh CO2. B. Dung dch NaCl. C. Dung dch NaOH. D. Dung dch HCl. Cu 26: tinh ch anilin t hn hp: phenol, anilin, benzen cch thc hin no sau y l ng? A. Ha tan dd HCl d, chit ly phn tan. Thm NaOH d v chit ly anilin tinh khit. B. Ha tan dd Brm d, lc ly kt ta, dehalogen ha thu c anilin. C. Ha tan NaOH d v chit ly phn tan v thi CO2 vo sau n d thu c anilin tinh khit.

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 9 D. Dng NaOH tch phenol, sau dng brm tch anilin ra khi benzen. Cu 27: tch ring hn hp gm ba cht lng: C6H6, C6H5OH v C6H5NH2 ngi ta c th tin hnh theo trnh t sau: A. Dng dung dch HCl, lc, chit, sc kh CO2 B. Dng dung dch NaOH, lc nh, chit, sc kh CO2. C. Dng dung dch NaOH, lc nh, chit, dung dung dch HCl, chit, dng dung dch NaOH D. Dng dung dch brom, lc nh, chit, dng dung dch NaOH, kh CO 2 5. Chui phn ng + HNO3, H2SO4 + Fe, HCl + NaOH Cu 1: Cho chui phn ng sau: C6H6 Y Z. Tn gi ca Z l: X A. Anilin. B. Nitrobenzen. C. Phenylclorua. D. Phenol. o + Fe, HCl + NaOH a c , t Cu 2: Cho chui phn ng sau: 1-brom-2-nitrobenzen X Y. cht Y l: A. o-aminophenol. B. m-nitrophenol. C. nitrophenol. D. brom-2-amonibenzen. Cu 3: Cho s phn ng: X C6H6 Y anilin. X v Y tng ng l: A. Xiclohexan, C6H5-CH3 B. C2H2, C6H5-NO2. C. CH4, C6H5-NO2 D. C2H2, C6H5-CH3. HNO3 (1mol ), H 2 SO4 Fe , HCl NaOH Cu 4: Cho s phn ng: C6H6 A B C. Cht B l A. Nitrobenzen B. anilin C. Natri phenolat D. Mt loi mui clorua t0 HNO 3, H 2 SO 4 t0 Fe , HCl , du B C Cu 5: Theo s phn ng sau: CH4 A D. Cht A, B, C, D ln lt l : C 1:1 A. C2H2, C6H6, C6H5NO2, C6H5NH2 B. C2H2, C6H6, C6H5NO2, C6H5NH3Cl C. C2H4, C6H6, C6H5NH2, C6H5NH3Cl D. C6H6, C6H5NO2, C6H5NH2,C6H5NH3Cl Cu 6: Cho s : (X) (Y) (Z) M (trng). Cc cht X, Y, Z ph hp s trn l ? A. X (C6H6), Y (C6H5NO2), Z (C6H5NH2) B. X (C6H5CH(CH3)2), Y (C6H5OH), Z (C6H5NH2) C. X (C6H5NO2), Y (C6H5NH2), Z (C6H5OH) D. C A v C Cu 7: Cho s : C6H6 X Y Z m-HO-C6H4-NH2 Cc cht X, Y, Z tng ng l: A. C6H5Cl, m-Cl-C6H4-NO2, m-HO-C6H4-NO2 B. C6H5NO2, m-Cl-C6H4-NO2, m-HO-C6H4-NO2 C. C6H5Cl, C6H5OH, m-HO-C6H4-NO2 D. C6H5NO2, C6H5NH2, m-HO-C6H4-NO2 Cu 8: T C2H2 v cc cht v c cn thit khc, c th iu ch 2,4,6-triamino phenol (X) bng s phn ng no sau y: A. C2H2 C6H6 C6H3(NO2)3 C6H3(NH2)3 C6H2(NH2)3Br X B. C2H2 C6H6 C6H5Br C6H5OH C6H2(NO2)3OH X C. C2H2 C6H6 C6H5NO2 NH2C6H2Br3 X D. C2H2 C6H6 C6H5NH2 NH2C6H2Br3 X
Zn / HCl 3 2 X Y Z . X, Y, Z l cc hp cht hu c, thnh Cu 9: Cho chui chuyn ha sau C7 H 8 H 2 SO4 dd HNO dd(1:1) HNO

phn ch yu ca Z l A. o-Crezol, p-Crezol

B. Axit o-phtalic, Axit p-phtalic

+ Cl 2, as 1:1

C. o- Metylanilin, p-Metylanilin
+NaOH, to

D. o-Crezol, m-Crezol
T.

Cu 10: Cho s phn ng sau: Toluen

+CuO,

to

+ dd AgNO3/NH 3

Bit X, Y, Z, T l cc hp cht hu c v l nhng sn phm chnh. Cng thc cu to ng ca T l cht no sau y? A. p-HOOC-C6H4-COONH4. B. C6H5-COONH4. C. C6H5-COOH. D. CH3-C6H4-COONH4. II. BI TP 1. Bi tp amin lin quan n tnh baz Cu 1: Khi cho 13,95g anilin tc dng hon ton vi 0,2 lit dd HCl 1M. Khi lng mui thu c l A. 25,9g B. 20,25g C. 19,425g D. 27,15g Cu 2: Cho lng d anilin phn ng hon ton vi 0,05 mol H2SO4 long, khi lng mui thu c l A. 7,1g B. 14,2g C. 19,1g D. 28,4g Cu 3: Cho 4,5 gam etylamin tc dng va vi axit HCl. Khi lng mui thu c l A. 7,65 gam. B. 8,15 gam. C. 8,10 gam. D. 0,85 gam. Cu 4: Cho 11,25 gam C2H5NH2 tc dng vi 200 ml dung dch HCl x(M). Sau khi phn ng xong thu c dung dch c cha 22,2 gam cht tan. Gi tr ca x l A. 1,3M B. 1,25M C. 1,36M D. 1,5M Cu 5: Cho 11,8 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 19,1 gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l A. 3 B. 4 C. 5 D. 6 Cu 6: Trung ha 50 ml dung dch metylamin cn 30 ml dung dch HCl 0,1M. Gi s th tch khng thay i. CM ca metylamin l: A. 0,06 B. 0,05 C. 0,04 D. 0,01 Cu 7: trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100 ml dung dch HCl 1M. Cng thc phn t ca X l A. C3H5N. B. C2H7N. C. CH5N. D. C3H7N.

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 10 Cu 8: Trung ha hon ton 9,62 gam mt amin bc 1 bng dung dch HCl thu c 19,11g mui. Amin c cng thc l A. H2NCH2CH2NH2 B. CH3CH2NH2 C. H2NCH2CH2CH2CH2NH2 D. H2NCH2CH2CH2NH2 Cu 9: Cho 18,6 gam mt ankylamin tc dng vi dung dch FeCl 3 (d), thu c 21,4 gam kt ta. Cng thc cu to thu gn ca ankylamin l: A. CH3NH2. B. C4H9NH2. C. C2H5NH2. D. C3H7NH2. Cu 10: Hp cht hu c X mch h cha C, H v N trong N chim 16,09% v khi lng. X tc dng c vi HCl theo t l s mol 1:1. Cng thc ca X l A. C3H7NH2 B. C4H9NH2 C. C2H5NH2 D. C5H11NH2 Cu 11: Trung ho 0,9 gam 1 amin n chc X cn va vi 200 ml dung dch H 2SO4 c pH =1. Pht biu khng chnh xc v X l: A. X l cht kh B. Tn gi X l etyl amin C. Dung dch trong nc ca X lm qu tm ha xanh D. X tc dng c vi dung dch FeCl3 cho kt ta Fe(OH)3 Cu 12: Hp cht X cha vng benzen, c cng thc phn t C xHyN. Khi cho X tc dng vi dung dch HCl thu c mui Y c cng thc dng RNH3Cl (R l gc hirocacbon). Phn trm khi lng ca nit trong X l 13,084%. S ng phn cu to ca X tha mn cc iu kin trn l A. 3. B. 4. C. 5. D. 6. Cu 13: A l hp cht hu c mch vng cha C, H, N trong N chim 15,054% theo khi lng. A tc dng vi HCl to ra mui c dng RNH3Cl. Cho 9,3g A tc dng ht vi nc brom d thu c a gam kt ta. gi tr ca a l A. 33 B. 30 C. 39 D. 36 Cu 14: Cho 3,04g hn hp A gm 2 amin no n chc tc dng va vi 400 ml dd HCl 0,2M thu c a gam mui. Tm th tch N2 (ktc) sinh ra khi t chy ht hn hp A trn A. 0,224 lit B. 0,448 lit C. 0,672 lit D. 0,896 lit Cu 15: Cho 29,8 gam hn hp 2 amin n chc k tip tc dng ht vi dung dch HCl, lm kh dung dch thu c 51,7 gam mui khan. Cng thc phn t 2 amin l A. C2H5N v C3H7N B. CH5N v C2H7N C. C3H9N v C4H11N D. C2H7N v C3H9N Cu 16: Mt hn hp gm 2 amin n chc no k tip nhau trong dy ng ng. Ly 21,4g hn hp cho vo 250ml dung dch FeCl3 (c d) thu c mt kt ta c khi lng bng khi lng hn hp trn. Cng thc phn t ca 2 amin trn l: A. CH3NH2 v C2H5NH2 B. C2H5NH2 v C3H7NH2 C. C3H7NH2 v C4H9NH2 D. C4H9NH2 v C5H11NH2 Cu 17: kt ta ht 400ml dung dch hn hp HCl 0,5M v FeCl 3 0,8M cn bao nhiu gam hn hp gm metylamin v etylamin c t khi so vi H2 l 17,25? A. 41,4 gam B. 40,02 gam C. 51,75 gam D. Khng iu kin tnh. Cu 18: X v Y l 2 amin n chc mch h ln lt c phn trm khi lng Nit l 31,11% v 23,73%. Cho m gam hn hp gm X v Y c t l s mol n X:nY=1:3 tc dng vi dung dch HCl va thu c dung dch cha 44,16 gam mui. m c gi tr l: A. 22,2 gam B. 22,14 gam C. 33,3 gam D. 26,64 gam Cu 19: X l amin no n chc mch h v Y l amin no 2 ln amin mch h c cng s cacbon. Trung ha hn hp gm a mol X v b mol Y cn dung dch cha 0,5 mol HCl v to ra 43,15 gam hn hp mui. Trung ha hn hp gm b mol X v a mol Y cn dung dch cha 0,4 mol HCl v to ra p gam hn hp mui. p c gi tr l : A. 40,9 gam B. 38 gam C. 48,95 gam D. 32,525 gam Cu 20: Cho 1,52g hn hp hai amin n chc no X, Y (c trn vi s mol bng nhau) tc dng va vi 200ml dung dch HCl, thu c 2,98g mui. Kt lun no sau y khng chinh xac? A. Tn gi 2 amin l metylamin v etylamin B. Nng dung dch HCl bng 0,2 (M). C. S mol mi cht l 0,02 mol D. Cng thc ca amin l CH5N v C2H7N Cu 21: Dung dch X cha 2 axit HCl v H 2SO4 c pH = 2. trung ho hon ton 0,59 gam hn hp Y gm 2 amin no, n chc mch h, bc 1 (c s nguyn t C 4) phi dng ht 1 lt dung dch X. CTPT ca 2 amin l A. C2H5-NH2 v CH3NH2. B. C2H5-NH2 v C3H7-NH2. C. C2H5-NH2 v C4H9-NH2 . D. C3H7-NH2 v C4H9-NH2 . Cu 22: Cho 24,9 gam hn hp X gm 2 amin no n chc mch h ng ng k tip tc dng vi dung dch FeCl 3 d thu c 21,4 gam kt ta. Cng thc v % khi lng ca 2 amin l : A. C2H7N( 27,11%) v C3H9N (72,89%) B. C2H7N( 36,14%) v C3H9N (63,86%) C. CH5N( 18,67%) v C2H7N (81,33%) D. CH5N( 31,12%) v C2H7N (68,88%) Cu 23: Cho 9,85 gam hn hp 2 amin n chc no, bc 1 tc dng va vi dung dch HCl thu c 18,975 gam mui. Cng thc cu to ca 2 amin ln lt l A. CH3NH2 v C2H5NH2. B. C3H7NH2 v C4H9NH2 C. CH3NH2 v C3H5NH2. D. C2H5NH2 v C3H7NH2. Cu 24: Cho hn hp X gm hai amin n chc, no, bc 1 A v B. Ly 2,28g hn hp trn tc dng ht vi dung dch HCl th thu c 4,47g mui. S mol ca hai amin trong hn hp bng nhau. Tn ca A, B ln lt l: A. Metylamin v etylamin. B. Etylamin v propylamin. C. Metylamin v propylamin. D. Metylamin v isopropylamin.

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 11 Cu 25: Cho 20 gam hn hp 3 amin no, mch h, n chc, ng ng k tip nhau tc dng va vi dd HCl 1M, c cn dd thu c 31,68 gam hn hp mui. Bit khi lng phn t cc amin u nh hn 80. CTPT ca cc amin? A. CH3NH2, C2H5NH2 v C3H7NH2 B. C2H3NH2, C3H5NH2 v C4H7NH2 C. C2H5NH2, C3H7NH2 v C4H9NH2 D. C3H7NH2, C4H9NH2 v C5H11NH2 Cu 26: Cho 10 gam hn hp 3 amin no, mch h, n chc, ng ng k tip nhau tc dng va vi dd HCl 1M, c cn dd thu c 15,84 gam hn hp mui. Nu 3 amin trn c t l mol 1:10:5 theo th t phn t khi tng dn th cng thc phn t ca cc amin? A. CH5N, C2H7N v C3H7NH2 B. C2H7N, C3H9N v C4H11N C. C3H9N, C4H11N v C5H11N D. C3H7N, C4H9N v C5H11N Cu 27: Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Th tch dung dch HCl dng l bao nhiu? A. 100ml B. 50ml C. 200ml D. 320ml Cu 28: Cho 9 g hn hp X gm 3 amin: n-propylamin, etylmetylamin,trimetyl amin tc dng va vi V ml dung dch HCl 1M. Gi tr ca V l: A. 100ml. B. 150 ml. C. 200 ml. D. Kt qu khc. Cu 29: Cho 20 gam hn hp 3 amin no n chc l ng ng k tip c t l mol tng ng l 1: 10 : 5, tc dng va vi dung dch HCl thu c 31,68 gam hn hp mui. Tng s ng phn ca 3 amin trn l A. 7 B. 14 C. 28 D. 16 2. Bi tp amin lin quan n phn ng chy Cu 1: t chy hon ton m gam metylamin (CH3NH2), sinh ra 2,24 lt kh N2 ( ktc). Gi tr ca m l A. 3,1 gam. B. 6,2 gam. C. 5,4 gam. D. 2,6 gam. Cu 2: t chy hon ton 7,4g mt amin thu c 6,72 lt kh CO2 (kc) v 9g H2O. CTPT ca amin l: A. C2H5N. B. C3H9N. C. C3H10N2. D. C3H8N2. Cu 3: Khi t chy hon ton mt amin n chc X, thu c 16,80 lit CO 2, 2,80 lit N2 (cc kh o ktc) v 20,25g H 2O. CTPT ca X l A. C4H9N B. C3H7N C. C2H7N D. C3H9N Cu 4: t chy hon ton 6,2g mt amin no, n chc phi dng ht 10,08 lt kh oxi (ktc). CTPT ca amin l A. C2H5NH2 B. CH3NH2 C. C4H9NH2 D. C3H7NH2 Cu 5: t chy mt hn hp amin A cn V lt O2(ktc) thu c N2 v 31,68 gam CO2 v 7,56 gam H2O. Gi tr V l: A. 25,536 B. 20,16 C. 20,832 D. 26,88 Cu 6: t chy hon ton mt amin n chc, no, bc 2 thu c CO 2 v H2O vi t l mol tng ng l 2: 3. Tn gi ca amin l A. etylmetylamin. B. ietylamin. C. imetylamin. D. metylisopropylamin. Cu 7: t chy hon ton mt amin no, mch h, bc mt X bng oxi va , sau phn ng c hn hp Y gm kh v hi, trong VCO2 ; VH2O = 1 : 2. Cho 1,8g X tc dng vi dung dch HCl d. Sau phn ng lm bay hi dung dch c m gam mui khan.Gi tr ca m l: A. 3,99 g B. 2,895g C. 3,26g D. 5,085g Cu 8: t chy hon ton mt amin n chc, bc mt thu c CO2 v nc theo t l mol 6:7. Amin c tn gi l g? A. Propylamin B. Phenylamin C. isopropylamin D. Propenylamin Cu 9: t chy hon ton mt amin no, n chc, mch h thu c t l khi lng ca CO 2 so vi nc l 44 : 27. Cng thc phn t ca amin l A. C3H7N B. C3H9N C. C4H9N D. C4H11N Cu 10: t chy hon ton mt amin khng no n chc trong phn t c mt lin kt i gc hirocacbon thu c n CO2 ; nH2O = 8:9. Cng thc phn t ca amin l A. C4H9N B. C4H11N C. C3H7N D. C2H5N n Cu 11: t chy mt amin no n chc mch h X ta thu c CO 2 v H2O c t l mol CO2 : nH2O = 8:11. Bit rng khi cho X tc dng vi dung dch HCl to mui c cng thc dng RNH 3Cl. S ng phn ca X tha mn iu kin trn l: A. 1. B. 2. C. 3. D. 4. Cu 12: t chy hon ton hn hp gm 1 amin no n chc mch h X v 1 amin khng no n chc mch h Y c 1 ni i C=C c cng s nguyn t C vi X cn 55,44 lt O 2(ktc) thu c hn hp kh v hi trong nCO2 : nH2O =10:13 v 5,6 lt N2 (ktc). Khi lng ca hn hp amin ban u l: A. 35,9 gam B. 21,9 gam C. 29 gam D. 28,9 gam Cu 13: t chy hon ton 1,18g amin n chc X bng 1 lng khng kh va , dn ton b lng hn hp kh sau phn ng vo bnh ng Ca(OH)2 d, c 6g kt ta v c 9,632 lt kh (ktc) duy nht thot ra khi bnh. Tm CTPT ca X A. C4H11N B. C2H7N C. C3H7N D. CH5N Cu 14: t chy hon ton mt amin thm X thu c 0,07 mol CO2, 0,99g H2O v 336ml N2(ktc). trung ho 0,1 mol X cn 600ml dd HCl 0,5M. Bit X l amin bc 1. X c cng thc: A. CH3- C6H2(NH2)3 B. C6H3(NH2)3 C. CH3-NH-C6H3(NH2)2 D. NH2- C6H2(NH2)3

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 12 Cu 15: t chy 0,10 mol mt amin X (no, n chc, mch h) thu c thu c 6,72 lt kh CO 2 ( ktc). Ho tan X trn vo 100 ml H2O c dung dch Y. Nng phn trm cht tan trong dung dch Y l A. 5,57% B. 5,90% C. 5,91% D. 5,75% Cu 16: t chy hon ton 5,4g mt amin X n chc trong lng va khng kh. Dn sn phm kh qua bnh ng nc vi trong d thu c 24g kt ta v c 41,664 lt (ktc) mt cht kh duy nht thot ra. X tc dng vi HNO 2 to ra kh N2. X l: A. imetylamin B. metylamin C. anilin D. etylamin Cu 17: Trong bnh kn cha 35 ml hn hp gm H2, mt amin n chc v 40 ml O2. Bt tia la in t chy hon ton hn hp, ri a hn hp thu c v iu kin ban u. Th tch cc cht to thnh bng 20 ml gm 50% l CO 2, 25% l N2, 25% l O2. CTPT ca amin l A. CH5N B. C2H7N C. C3H6N D. C3H5N Cu 18: Ly 15,660 (g) amin n chc, mch h X (X c khng qu 4 lin kt trong phn t) trn vi 168 lt khng kh (ktc). Bt tia la in t chy hon ton X, hn hp sau phn ng c a v 0 0C, 1 atm ngng t ht hi nc th c th tch l 156,912 lt. Xc nh s ng phn ca X? A. 2 B. 17 C. 16 D. 8 Cu 19: t chy hon ton m gam mt amin n chc X bng lng khng kh va thu c 1,76 gam CO 2; 1,26 gam H2O v V lt N2 (ktc). Gi thit khng kh ch gm N2 v O2 trong oxi chim 20% v th tch khng kh. Cng thc phn t ca X v gi tr ca V ln lt l: A. X l C2H5NH2; V = 6,944 lt. B. X l C3H7NH2; V = 6,944 lt. C. X l C3H7NH2; V = 6,72 lt. D. X l C2H5NH2; V = 6,72 lt. Cu 20: t chy hon ton m gam mt amin bng lng va khng kh (khng kh cha 20%O 2 v 80%N2 theo th tch), thu c 1,76 gam CO2, 0,99 gam H2O v 6,16 lit N2 ktc. Cng thc phn t ca X l. A. C4H7N. B. C4H11N2. C. C4H9N. D. C4H11N. Cu 21: t chy hon ton m gam amin A bng lng khng kh va thu c 17,6g CO 2 v 12,6g nc v 69,44 lt kh nit (kc). Gi thit khng kh gm 80% nit v 20% oxi v th tch. Gi tr m v s ng phn ca A l: A. 9g v 3 ng phn. B. 9g v 2 ng phn. C. 93 g v 3 ng phn. D. 93g v 4 ng phn. Cu 22: t chy hon ton 2 amin no, n chc, mch h ng ng k tip thu c 4,4g CO 2 v 3,6g H2O. CTPT ca 2 amin l A. Metylamin v etylamin B. Etylamin v propylamin C. propylamin v butylamin D. Etylmetylamin v imetylamin Cu 23: t chy hon ton a mol hn hp X gm 2 amin no n chc mch h thu c 5,6 (l) CO 2 (ktc) v 7,2 g H2O. Gi tr ca a l A. 0 ,05 mol B. 0,1 mol C. 0,15 mol D. 0,2 mol Cu 24: t chy hon ton m gam hn hp 2 amin no, n chc, mch h thu c 11,2 lt CO 2 (kc) v 17,1g H2O. Gi tr ca m l: A. 12,1g. B. 14,7g. C. 8,9g. D. 10,68g. Cu 25: t chy hon ton hn hp 2 amin khng no c 1 lin kt i, n chc c khi lng phn t hn km nhau 14, thu c 15,68 lt CO2 (kc) v 15,3g H2O. CTPT 2 amin l: A. C2H5N v C3H7N. B. C3H7N v C4H9N. C. C2H3N v C3H5N. D. C3H9N v C4H11N. Cu 26: t chy ht 6,72 lt hn hp kh (ktc) X gm 2 amin n chc bc mt A v B l ng ng k tip. Cho hn hp kh v hi sau khi t chy ln lt qua bnh 1 ng H 2SO4 c, bnh 2 ng KOH d, thy khi lng bnh 2 tng 21,12 gam. Tn gi ca 2 amin l A. metylamin v etylamin. B. n-propylamin v n-butylamin. C. etylamin v n-propylamin. D. iso-propylamin v iso-butylamin. Cu 27: t chy hon ton 2 amin no, n chc ng ng lin tip, thu c hn hp sn phm v hi nc vi t l: V(CO2) : V(H2O) = 8 : 17. Cng thc ca 2 amin l A. C2H5NH2 v C3H7NH2 B. C3H7NH2 v C4H9NH2 C. CH3NH2 v C2H5NH2 D. C4H9NH2 v C5H11NH2 Cu 28: t chy hn hp gm 2 amin no n chc mch h ng ng k tip thu c N 2, CO2 v hi H2O c t l V(CO2) : V(H2O) = 176 : 251. Thnh phn % v khi lng cc amin trong hn hp ln lt l A. 42,73% v 57,27% B. 44,70% v 55,30% C. 43,27% v 56,73% D. 41,32% v 58,68% Cu 29: Cho 13,35 gam hn hp X gm 2 amin no n chc mch h ng ng k tip tc dng vi dung dch HCl va thu c dung dch cha 22,475 gam mui. Nu t chy hon ton 13,35 gam hn hp X th trong sn phm chy c V(CO2) : V(H2O)bng A. 8/13 B. 5/8 C. 11/17 D. 26/41 Cu 30: C 2 amin bc 1: (A) l ng ng ca anilin, (B) l ng ng ca metylamin. t chy hon ton 3,21g (A) thu c 336 ml N2 (ktc). Khi t chy hon ton (B) cho hn hp kh, trong V(CO2) : V(H2O) = 2 : 3. CTCT ca (A),(B) l A. CH3C6H4NH2 v CH3CH2CH2NH2 B. C2H5C6H4NH2 v CH3CH2CH2NH2

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 13 C. CH3C6H4NH2 v CH3CH2CH2CH2NH2 D. C2H5C6H4NH2 v CH3CH2CH2CH2NH2 Cu 31: Mt hn hp X gm 2 amin no A, B c cng s nguyn t C. Phn t B c nhiu hn A mt nguyn t N. Ly 13,44 lt hn hp X ( 273oC, 1atm) em t chy hon ton thu c 26,4 gam CO 2 v 4,48 lit N2 (ktc). Bit rng c hai u l amin bc 1. CTCT ca A v B v s mol ca chng l: A. 0,2 mol CH3NH2 v 0,1 mol NH2CH2NH2. B. 0,2 mol CH3CH2NH2 v 0,1 mol NH2CH2CH2NH2. C. 0,1 mol CH3CH2NH2 v 0,2 mol NH2CH2CH2NH2. D. 0,2 mol CH3CH2NH2 v 0,1 mol NH2CH2NHCH3. Cu 32: Cho 42,8g mt hn hp X gm 2 amin no A, B, n chc ng ng k tip. Chia X lm 2 phn bng nhau . Phn 1 tc dng va vi 0,3 lt dd H 2SO4 1 M. Phn 2 t chy hon ton thu c V lt N 2. CTPT, s mol mi amin v V ln lt c gi tr l A. 0,4 mol CH3-NH2, 0,2 mol C2H5-NH2, 3,36 lt N2 B. 0,8 mol C2H5-NH2, 0,4 mol C3H7- NH2, 11,2 lt N2 C. 0,6 mol C2H5-NH2, 0,3 mol C3H7-NH2, 8,96 lt N2 D. 0,8 mol CH3-NH2, 0,4 mol C2H5-NH2, 6,72 lt N2 Cu 33: X l dung dch anilin trong benzen. t chy hon ton 17,1 gam X cn 34,16 lt O 2(ktc). % s mol anilin trong X l A. 54,39% B. 50,% C. 39,54% D. 53,94% Cu 34: t chy hon ton 100ml hn hp gm imetylamin v 2 hirocacbon l ng ng k tip thu c 140ml CO 2 v 250ml hi nc (cc kh o cng iu kin). CTPT ca 2 hirocacbon? A. C2H4 v C3H6 B. C2H2 v C3H4 C. CH4 v C2H6 D. C2H6 v C3H8 Cu 35: t chy hon ton 100ml hn hp gm imetylamin v 2 hirocacbon ng ng k tip thu c 140ml CO 2 v 250ml hi nc (cc th tch o cng iu kin). Thnh phn % th tch ca ba cht trong hn hp theo tng phn t khi ln lt bng bao nhiu? A. 20%; 20% v 60% B. 25%; 25% v 50% C. 30%; 30% v 40% D. 60%; 20% v 20% Cu 36: Hn hp kh X gm etylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 550 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t ca hai hirocacbon l A. CH4 v C2H6. B. C2H4 v C3H6. C. C2H6 v C3H8. D. C3H6 v C4H8. 3. Mt s dng khc Cu 1: Cho m gam anilin phn ng hon ton vi dd brom d, sau phn ng thu c m + 35,55 gam kt ta trng. Tnh m? A. 49,50 g B. 20,95 g C. 74,25 g D. 13,95 g Cu 2: Th tch nc brom 3% (d = 1,3g/ml) cn dng iu ch 4,4 gam kt ta 2,4,6 tribrom anilin l A. 164,1ml. B. 49,23ml. C. 146,1ml. D. 16,41ml. Cu 3: Khi lng anilin thu c khi kh 246g nitrobenzen (hiu sut H=80%) l: A. 186g B. 148,8g C. 232,5g D. 260,3g Cu 4. Cho nc brom d vo anilin thu c 16,5 gam kt ta. Gi s H = 100%. Khi lng anilin trong dung dch l: A. 4,5 B. 9,30 C. 46,5 D. 4,65 Cu 5: Ngi ta iu ch anilin bng cch nitro ha 500 g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu? Bit hiu sut phn ng mi giai on l 78%, 80%, 97,5%. A. 346,7 g B. 362,7 g C. 463,4 g D. 358,7 g Cu 6: T Canxi cacbua c th iu ch anilin theo s phn ng:
C,600 C Fe+ HCl NaOH 2 3 2 4 CaC2 C2H2 C6H6 C6H5NO2 C6H5NH3Cl C6H5NH2 hs= 80% hs= 75% hs= 60% hs=80% hs= 95% H O
0

HNO /H SO

(hs=hiu sut). T 1 tn Canxi cacbua cha 80% CaC2 c th iu ch c bao nhiu kg anilin theo s trn ? A. 106,02 kg B. 101,78 kg C. 162,85 kg D. 130,28 kg Cu 7: Cho 1,87 g hn hp anilin v phenol tc dng va vi 20g dung dich Brom 48%. Khi lng kt ta thu c l: A. 6,61g B. 11,745g C. 3,305g D. 1,75g Cu 8: Mt hn hp gm ancol etylic, phenol, anilin co khi lng 23,3 gam. Nu cho hn hp tac dung vi Na d, thy thoat ra 2,24 lit khi (kc). Cung lng hn hp o, nu cho tac dung vi dung dich NaOH thy cn va ung 100 ml dung dich NaOH 1M. Khi lng mi cht trong hn hp ln lt la: A. 4,6g; 9,4g va 9,3g B. 9,4g; 4,6 g va 9,3g C. 6,2g; 9,1g va 8 g D. 9,3g; 4,6g va 9,4g. Cu 9: Cho mt hn hp X cha NH3, C6H5NH2 v C6H5OH. Hn hp X tc dng va vi 0,02 mol NaOH hoc 0,01 mol HCl. Nu cho hn hp phn ng ht vi Br 2 th cn va vi 0,075 mol Br2. Lng cc cht NH 3, C6H5NH2 v C6H5OH trong hn hp X ln lt l A. 0,005 mol; 0,005 mol v 0,02 mol. B. 0,01 mol; 0,005 mol v 0,02 mol. C. 0,005 mol; 0,02 mol v 0,005 mol. D. 0,01 mol; 0,05 mol v 0,02 mol. Cu 10: Mt amin n chc c cha 31,111%N v khi lng. Cng thc phn t v s ng phn ca amin tng ng l A. CH5N; 1 ng phn. B. C2H7N; 2 ng phn. C. C3H9N; 4 ng phn. D. C4H11N; 8 ng phn.

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 14 Cu 11: Phn tch nh lng 0,15 gam hp cht hu c X thy t l khi lng cc nguyn t C:H:O:N = 4,8:1:6,4:2,8. Nu phn tch nh lng m gam cht X th t l khi lng cc nguyn t C:H:O:N l bao nhiu? A. 4 : 1 : 6 : 2 B. 2,4 : 0,5 : 3,2 : 1,4 C. 1,2 : 1 : 1,6 : 2,8 D. 1,2 : 1,5 : 1,6 : 0,7 Cu 12: Mt amin c cng thc thc nghim l: (C2H7N)n. S ng phn ca amin ny l: A. 1. B. 2. C. 3. D. 4. Cu 13: Ba cht A, B, C (CxHyNz) c thnh phn % v khi lng N trong A, B, C ln lt l 45,16%; 23, 73%; 15, 05%; A, B, C tc dng vi axit u cho mi amoni dng R NH3Cl cng thc ca A, B, C ln lt l: A. CH3NH2, C3H7NH2, C4H9NH2 B. CH3NH2, C3H7NH2, C6H5NH2 C. CH3NH2, C4H9NH2, C6H5NH2 D. CH3NH2, C6H5NH2, C2H5NH2 Cu 14: Amin RNH2 c iu ch theo phn ng: NH3+RI RNH2+HI Trong RI , Iot chim 81,41%. t 0,15 mol RNH2 cn bao nhiu lt O2 (ktc)? A. 7,56 lt B. 12,6 lt C. 17,64 lt D. 15,96 lt Cu 15: Cho 26 gam hn hp 2 amin no n chc mch h bc mt c s mol bng nhau tc dng ht vi axit nitr nhit thng thu c 11,2 lt N2 (ktc). Kt lun no sau y l sai? A. 2 amin trn l 2 ng ng k tip. B. Tng khi lng 2 ancol sinh ra l 26,5 gam C. Nu t chy hon ton 26 gam hn hp X thu c 55 gam CO2. D. Cho amin c phn t khi nh tc dng vi CH3I theo t l mol 1:1 thu c amin bc hai c % khi lng N l 19,178%. Cu 16: X l 1 amin no mch h 2 ln amin (c 2 chc amin u bc 1) c khi lng phn t bng khi lng phn t ca 1 este n chc c phn trm khi lng oxi l 36,36%. X c bao nhiu ng phn cu to? A. 6 B. 7 C. 8 D. 9 B. BI TP MUI IAZONI MUI NITRAT AMIN MUI CACBONAT AMIN I. L THUYT Cu 1: Cht no sau y khi phn ng vi dung dch hn hp HCl v HNO2 0-50C to ra mui iazoni ? A. C2H5NH2. B. C6H5NH2. C. CH3NHC6H5. D. (CH3)3N. Cu 2: Mt hp cht hu c X c Cng thc phn t C 2H7NO2, X tc dng c vi dung dch NaOH v dung dch HCl. X c th c cng thc cu to: A. H2NCH2COOH B. CH3COONH4 C. HCOOH3NCH3 D. B v C ng Cu 3: C cc cht sau: HCOONH 4; CH3CHO; phenol; glixerol; CH2=CH-CHO; axit HCOOH; axit CH3COOH. S cht c phn ng trng bc l: A. 6 B. 3 C. 5 D. 4 Cu 4: S ng phn c CTPT C3H9O2N tc dng vi NaOH c mui B v kh C (lm xanh qu tm m) l: A. 2. B. 4. C. 5. D. 6. Cu 5: Cho chui phn ng sau: +CH 3 I +HCl A + NaOH Axit propanoic; Y imetylamin. CTCT ca A l: X + Y + H2O; X A. CH3COONH3CH2CH3. B. C2H5COONH3CH3. C. HCOONH3CH2CH2CH3. D. Tt c u ng. Cu 6: Cho hn hp X gm cc cht c cng thc phn t C 3H9O2N tc dng vi dung dch NaOH c, nng thu c hn hp Y gm n kh v hi. Gi tr ca n l A. 4 B. 3 C. 2 D. 5 Cu 7: Hp cht hu c A c cng thc phn t C 3H9O2N. Cho A phn ng vi dung dch NaOH, un nng thu c mui B v kh C lm xanh giy qu tm m. Nung B vi vi ti xt th thu c hidrocacbon n gin nht. Cng thc cu to ca A l: A. C2H5COONH4 B. CH3COONH3CH3 C. HCOONH3C2H5 D. HCOONH(CH3)2 Cu 8: Cht hu c X c cng thc phn t l C 3H9O2N. X tc dng vi NaOH un nng thu c mui Y c phn t khi nh hn phn t khi ca X. X khng th l cht no ? A. CH3CH2COONH4. B. CH3COONH3CH3. C. HCOONH2(CH3)2. D. HCOONH3CH2CH3. Cu 9: Hp cht A c cng thc phn t C 4H11O2N. Khi cho A vo dung dch NaOH long, un nh thy kh B bay ra lm xanh giy qu m. Axit ho dung dch cn li sau phn ng bng dung dch H 2SO4 long ri chng ct c axit hu c C c M =74. Tn ca A, B, C ln lt l A. Metylamoni axetat, metylamin, axit axetic. B. Metylamoni propionat, metylamin, axit propionic. C. Amoni propionat, amoniac, axit propionic. D. Etylamoni axetat, etylamin, axit propionic. Cu 10: Cho cht hu c X c cng thc phn t C 2H8O3N2 tc dng vi dung dch NaOH, thu c cht hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l A. 85. B. 68. C. 45. D. 46. Cu 11: Mui X (C2H8O3N2) tc dng ht vi dung dch NaOH un nng thu c dung dch A (ch cha mui v c), cht hu c B lm xanh qu tm m. X c th l mui no sau y: A. C2H5NH3NO3. B. CH2(NH3)2CO3. C. NH2CH2NH3HCO3. D. Tt c u ng.

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 15 Cu 12: Mt hp cht hu c X c CTPT C 3H10O3N2. Cho X phn ng vi NaOH d, c cn dung dch sau phn ng thu c cht rn Y (ch c cc hp cht v c) v phn hi Z (ch c mt hp cht hu c no, n chc mch khng phn nhnh). Cng thc cu to ca X l A. HCOONH3CH2CH2NO2 B. HO-CH2-CH2-COONH4 C. CH3-CH2-CH2-NH3NO3 D. H2N-CH(OH)CH(NH2)COOH Cu 13: S hp cht ng vi cng thc phn t C 4H11NO3 u tc dng c vi dung dch NaOH v dung dch HCl (khi tc dng vi dung dch NaOH d ch to ra mt mui v c duy nht) l: A. 6 B. 5 C. 3 D. 4 Cu 14: X c cng thc C4H14O3N2. Khi cho X tc dng vi dung dch NaOH th thu c hn hp Y gm 2 kh iu kin thng v u c kh nng lm xanh qu tm m. S CTCT ph hp ca X l A. 3 B. 2 C. 4 D. 5 Cu 15: Mt amin X bc 1 c CTPT l C 7H10N2. Nu em phn ng vi axit HNO 2 xong thu c sn phm Y. 1 mol Y tc dng ti a vi 1mol NaOH. S ng phn cu to ca X l: A. 1. B. 2. C. 3. D. 4. Cu 16: Mt hp cht A thuc loi cht thm c CTPT C 6H7ON, c th phn ng vi NaOH v HCl. S ng phn c th c ca A tha mn cc iu kin trn l: A. 1. B. 2. C. 3. D. 4. II. BI TP Cu 1: Mui iazoni C6H5N2+Cl- c sinh ra khi cho C6H5NH2 (anilin) phn ng vi NaNO2 trong dung dch HCl nhit thp t 0-50C. iu ch c 14,05 gam C6H5N2+Cl- (vi hiu sut phn ng t 100%) th lng C6H5NH2 v NaNO2 cn dng va l: A. 0,1 mol v 0,1 mol. B. 0,1 mol v 0,2 mol. C. 0,1 mol v 0,3 mol. D. 0,1 mol v 0,4 mol. Cu 2: Ly a mol anilin cho vo hn hp hai axit HCl v HNO 2 0-50C. Sau khi phn ng xong c 28,10g mui benzeniazoni clorua. Tnh khi lng NaNO2 ti thiu dng iu ch lng mui trn, bit H = 100% ? A. 13,80 g B. 27,60 g C. 6,90 g D. 25,86g. Cu 3: 900C tan ca anilin l 6,4 gam. Nu cho 212,8 gam dung dch anilin bo ha nhit trn tc dng vi dung dch HCl d th s gam mui thu c l: A. 20,15 gam B. 19,45 gam C. 17,82 gam D. 16,28 gam Cu 4: Hai cht hu c A, B c cng thc CH 5NO2 v C2H7NO2. Hn hp X gm A v B cho tc dng vi NaOH d to ra 2,72 gam mt mui duy nht v bay ra mt hn hp kh c M = 27,5. Hn hp X c khi lng A. 1,47 gam B. 2,94 gam C. 4,42 gam D. 3,32 gam Cu 5: Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z (ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z i vi H 2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l: A. 16,5 B. 14,3 C. 8,9 D. 15,7 Cu 6: Hp cht X c cng thc C2H7NO2 c phn ng trng gng, khi phn ng vi dung dch NaOH long to ra dung dch Y v kh Z, khi cho Z tc dng vi dung dch hn hp gm NaNO 2 v HCl to ra kh P. Cho 11,55 gam X tc dng vi dung dch NaOH va , c cn dung dch thu c s gam cht rn khan l: A. 14,32 g B. 9,52 g C. 8,75 g D. 10,2 g Cu 7: A c cng thc phn t l C 2H7O2N. Cho 7,7 gam A tc dng vi 200 ml dung dch NaOH 1M thu c dung dch X v kh Y, t khi ca Y so vi H2 nh hn 10. C cn dung dch X thu c m gam cht rn. Gi tr ca m l A. 12,2 gam. B. 14,6 gam. C. 18,45 gam. D. 10,7 gam. Cu 8: A c cng thc phn t l C 2H7O2N. Cho 7,7 gam A tc dng vi 200 ml dung dch NaOH 1M thu c dung dch X v kh Y, t khi ca Y so vi H2 ln hn 10. C cn dung dch X thu c m gam cht rn. Gi tr ca m l A. 12,2 gam. B. 14,6 gam. C. 18,45 gam. D. 10,8 gam. Cu 9: t chy hon ton 1 mol cht hu c X cha thu c 2 mol CO 2, 11,2 lt N2 ktc v 63 gam H2O. T khi hi ca X so vi He = 19,25. Bit X d phn ng vi dung dch HCl v NaOH. X c CTCT l A. HCOONH3CH3(1). B. (1) hoc (3). C. CH3CH2COONH4(2). D. CH3COONH4(3). Cu 10: Ly 9,1 gam hp cht X c cng thc phn t l C 3H9O2N tc dng vi dung dch NaOH d, un nng, thu c 2,24 lt (ktc) kh Y (lm xanh giy qu tm m). t chy hon ton lng kh Y ni trn, thu c 8,8 gam CO 2. X, Y ln lt l A. CH3COONH3CH3; CH3NH2 B. HCOONH3C2H3; C2H3NH2 C. CH2=CHCOONH4; NH3 D. HCOONH3C2H5; C2H5NH2 Cu 11: Hn hp A cha 2 cht hu c c cng cng thc phn t C 3H9O2N thy phn hon ton hn hp A bng lng va dung dch NaOH thu c hn hp X gm 2 mui v hn hp Y gm 2 amin. Bit phn t khi trung bnh X bng 73,6 vc, phn t khi trung bnh Y c gi tr A. 38,4. B. 36,4. C. 42,4. D. 39,4. Cu 12: Cht X lng tnh, c cng thc phn t C 3H9O2N. Cho 18,2 gam X tc dng va vi dung dch NaOH, sau phn ng c cn dung dch thu c 16,4 gam mui khan. Tn gi ca X l:

9.3.Chuyn 9-Bi tp Amin-GV: Thy gio lng Su tm v bin son 16 A. amoni propionat. B. metylamoni propionat. C. metylamoni axetat. D. amoni axetat. Cu 13: Cho hai hp cht hu c X, Y c cng thc phn t l C 3H9NO2. Cho hn hp X v Y phn ng vi dung dch NaOH thu c mui ca hai axit hu c thuc ng ng k tip v hai cht hu c Z v T. Tng khi lng phn t ca Z v T l A. 74 B. 44 C. 78 D. 76 Cu 14: Hn hp gm hai hp cht hu c A v B c cng cng thc phn t C 4H11O2N. Cho hn hp tc dng vi 600 ml dung dch NaOH 0,1M thot ra hn hp hai kh u lm xanh mu giy qu c th tch 1,12 lt v c t khi hi i vi H 2 l 19,7 v dung dch A. C cn dung dch A thu c m gam rn khan. Gi tr ca m l: A. 4,78 B. 7,48 C. 8,56 D. 5,68 Cu 15: X l mt dn xut ca benzen c cng thc phn t C7H9NO2. Cho 1 mol X tc dng va vi NaOH, c cn dung dch thu c mt mui khan c khi lng l 144 gam. Cng thc cu to thu gn ca X l A. C6H5COONH4. B. HCOOH3NC6H5. C. HCOOC6H4NO2. D. HCOOC6H4NH2. Cu 16: Mui X c cng thc phn t l CH 6O3N2. un nng X vi NaOH thu c 2,24 lt kh Y (Y l hp cht cha C, H, N v c kh nng lm xanh giy qu tm m). Tnh khi lng mui thu c? A. 8,2 gam B. 8,5 gam C. 6,8 gam D. 8,3 gam Cu 17: Cho 14,1 gam cht X c cng thc CH 6N2O3 tc dng vi 200 ml dung dch NaOH 1M, un nng. Sau khi phn ng kt thc thu c dung dch Y v cht kh Z lm xanh giy qu tm m. C cn dung dch Y thu c cht rn khan c khi lng l A. 12,75 gam B. 21,8 gam C. 14,75 gam D. 30,0 gam Cu 18: Cho 0,1 mol hp cht ha c c cng thc phn t CH 6O3N2 tc dng vi dung dch cha 0,2 mol NaOH un nng, sau khi phn ng xy ra hon ton thu c cht kh lm xanh giy qu tm m v dung dch Y. C cn dung dch Y thu c m gam rn khan. Gi tr ca m l A. 21,8 B. 15 C. 12,5 D. 8,5 Cu 19: Cho 0,1 mol cht X c cng thc phn t C 2H8O3N2 tc dng vi dung dch cha 0,2 mol NaOH un nng thu c kh lm xanh qu m v dung dch Y. C cn dung dch Y thu c m gam cht rn khan. Gi tr ca m l A. 5,7. B. 21,8. C. 15. D. 12,5. Cu 20: Cng thc phn t cua mt hp cht hu c X la C 2H8O3N2. un nong 10,8 gam X vi dung dich NaOH va u, thu c dung dich Y. Khi c can Y thu c phn bay hi co cha mt cht hu c Z co 2 nguyn t cacbon trong phn t va con lai a gam cht rn. Gia tri cua a la A. 8,5 B. 6,8 C. 9,8 D. 8,2 Cu 21: Mt mui X c cng thc C3H10O3N2. Ly 14,64 gam X cho phn ng ht vi 150 ml dung dch KOH 1M. C cn dung dch sau phn ng thu c phn hi v cht rn. Trong phn hi c cha cht hu c Y (bc 1). Trong cht rn ch cha mt hp cht v c. Cng thc phn t ca Y l: A. C3H7NH2 B. CH3OH C. C4H9NH2 D. C2H5OH Cu 22: Mt mui X c CTPT C3H10O3N2. Ly 19,52 gam X cho phn ng vi 200 ml dung dch KOH 1M. C cn dung dch sau phn ng thu c cht rn v phn hi. Trong phn hi c cht hu c Y n chc bc I v phn rn ch l hn hp cc cht v c c khi lng m gam. Gi tr ca m l: A. 18,4 gam B. 13,28 gam C. 21,8 gam D. 19,8 gam Cu 23: Cho 7,32 gam A (C3H10O3N2) phn ng ht vi 150ml dd KOH 0,5M. C cn dd sau phn ng th c phn hi v phn cht rn, trong phn hi c 1 cht hu c bc 3, trong phn rn ch l cht v c. Khi lng cht rn l: A. 6,90 g. B. 6,06 g. C. 11,52 g. D. 9,42 g. Cu 24: Cho 12,4 gam cht A c CTPT C3H12N2O3 un nng vi 2 lt dd NaOH 0,15 M. Sau phn ng hon ton thu c cht kh B lm xanh qu m v dung dch C. C cn C ri nung n khi lng khng i thu c bao nhiu gam cht rn ? A. 14,6 B. 17,4 C. 24,4 D. 16,2 Cu 25: Hp cht thm X c cng thc phn t C 6H8N2O3. Cho 28,08 gam X tc dng vi 200 ml dung dch KOH 2M sau phn ng thu c dung dch Y. C cn dung dch Y c m gam cht rn khan. Gi tr ca m l: A. 21,5 gam B. 38,8 gam C. 30,5 gam D. 18,1 gam