AMIN

DNG 1: TNH KHI LNG AMIN (MUI) TRONG PHN NG VI AXT HOC VI BROM * Cn nh 2 phng trnh: + Vi HCl: RNH2 + HCl RNH3Cl (1) R+16 R+52,5 Tng 36,5g +Vi Brom: C6H5NH2 + 3Br2 C6H2Br3NH2 + 3HBr kt ta trng 93 330 Xg Yg *PP: 1) p dng nh lut bo ton khi lng khi lng: mamin + maxit = mmui 2) Tnh mol ca cht bi cho ri t vo ptrnh suy ra s mol ca cht bi hi => tnh m 3) p dng nh lut tng gim khi lng C6H5NH2 + HCl C6H5NH3Cl 93 Tng 36,5 Ag m = = B mMui = A + B 1. Cho 5,9 gam Propylamin (C3H7NH2) tc dng va vi axit HCl. Khi lng mui (C 3H7NH3Cl) thu c l (Cho H = 1, C = 12, N = 14) A. 8,15 gam. B. 9,65 gam. C. 8,10 gam. D. 9,55 gam. 2. Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A. 7,65 gam. B. 8,15 gam. C. 8,10 gam. D. 0,85 gam. 3. Cho anilin tc dng 2000ml dd Br2 0,3M. Khi lng kt ta thu c l A.66.5g B.66g C.33g D.44g 4. Cho 0,1 mol anilin (C6H5NH2) tc dng va vi axit HCl. Khi lng mui phenylamoniclorua ( C6H5NH3Cl) thu c l A. 25,900 gam . B. 6,475gam. C. 19,425gam. D. 12,950gam 5. Cho m gam Anilin tc dng ht vi dung dch Br2 thu c 9,9 gam kt ta. Gi tr m dng l A. 0,93 gam B. 2,79 gam C. 1,86 gam D. 3,72 gam 6. Th tch nc brom 5 % (d = 1,3g/ml) cn dng iu ch 3,96 gam kt ta 2,4,6 tribrom anilin l A. 164,1ml. B. 49,23ml. C 88,61 ml. D. s khc . 7. Cho 20g hn hpX gm ba amin no n chc l ng ng k tip nhau tc dng va vi dung dch HCl 1M, c cn dung dch thu c 31,68g mui. Xc nh th tch HCl dng ? A 16ml B 32ml C 160ml D 320ml DNG 2: XC NH CU TO AMIN N CHC DA VO PHN NG CHY * i vi p t chy nh: + t CTTQ ca amin no n chc hoc amin n chc l: CxHyN nCO2 x p dng CT: = y 2nH 2O + Amin no n chc: 2 CnH2n+3N + (6n+3)/2 O2 2nCO2 + (2n+3)H2O+ N2 nCO 2 2n 2 S mol amin = ( nH2O n CO2) v = n =? 3 2n + 3 nH O
2

+Amin khng no n chc c 1 lk i (CnH2n+1N) 2 CnH2n+1N + (6n+1)/2 O2 2nCO2 + (2n+1)H2O + N2 nCO 2n 2 S mol amin = 2 ( nH2O n CO2) v = n 2n + 1 H 2O + Amin thm: 2CnH2n 5 N + (6n-5)/2 O2 2nCO2 + (2n-5)H2O +N2 1. t chy mt ng ng ca metylamin, ngi ta thy t l th tch cc kh v hi V CO2:VH2O sinh ra bng 2:3 Cng thc phn t ca amin l: A. C3H9N B. CH5N C. C2H7N D. C4H11N

2. t chy hon ton m (g) hn hp 3 amin thu c 3,36lt CO 2; 1,12lt N2(ktc) v 5,4g H2O. Gi tr ca m l: A.3,6 B.3,8 C.4 D.3,1 3. t chy hon ton m gam mt amin n chc thu c 0,2 mol CO 2 v 0,35 mol H2O. Cng thc phn t ca amin l A. C4H7N B. C2H7N C. C4H14N D. C2H5N CO2 6 4. t chy hon ton mt amin n chc b 1 thu c CO 2 v H2O theo t l = . Vy CT amin l: A. H2O 7 C3H7N B. C4H9N C. CH5N D. C2H7N CO2 8 5. t chy hon ton mt amin n chc cha no thu c CO 2 v H2O theo t l = . Vy CT amin H2O 9 l: A. C3H6N B. C4H9N C. C4H8N D. C3H7N 6. t chy hon ton 10,4 gam hai amin no, n chc, ng ng lin tip nhau, thu c 11,2 lt kh CO 2 (ktc). Hai amin c cng thc phn t l A. CH4N v C2H7N B. C2H5N v C3H9N C. C2H7N v C3H7N D. C2H7N v C3H9N 7. Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l (cho H = 1, O = 16) A. C2H7N. B. C4H9N. C. C3H7N. D. C3H9N. 8. t chy mt amin no n chc mch thng ta thu c CO2 v H2O c t l mol nCO2 : nH2O = 8 : 11 . CTCT ca X l :A. (C2H5)2NH B. CH3(CH2)3NH2 C. CH3NHCH2CH2CH3 D. C 3 9. t chy mt amin n chc no (h) thu c t l s mol CO 2 : H2O l 2 : 5. Amin cho c tn gi no di y? A. imetylamin. B. Metylamin. C. Trimetylamin. D. Izopropylamin 10. t chy hon ton 5,9 gam mt amin no h n chc X thu c 6,72 lt CO 2, . Cng thc ca X l A. C3H6O. B. C3H5NO3. C. C3H9N. D. C3H7NO2. 11. t chy hon ton 6,2 gam mt amin no h n chc, cn 10,08 lt O2 ktc. CTPT l A. C4H11N. B. CH5N. C. C3H9N. D. C5H13N. 12. t chy hon ton amin no n chc X, thu c 16,8 lt CO 2 ; 2,8 lt N2 (ktc) v 20,25 g H2O. Cng thc phn t ca X l A. C4H9N. B. C3H7N. C. C2H7N. D. C3H9N. 13. C hai amin bc mt: A (ng ng ca anilin) v B (ng ng ca metylamin). t chy hon ton 3,21g amin A sinh ra 336ml kh N2 (ktc). Khi t chy hon ton amin B cho VH 2O : VCO2 = 3 : 2 . Cng thc phn t ca hai amin l: A. CH3C6H4NH2 v CH3CH2CH2NH2 B. C2H5C6H4NH2 v CH3CH2CH2NH2 C. CH3C6H4NH2 v CH3CH2CH2CH2NH2 D. C2H5C6H4NH2 v CH3CH2CH2CH2NH2 14. t chy hon ton a mol amin no, n chc thu c 13,2g CO2 v 8,1g H2O.Gi tr ca a l: A.0,05 B.0,1 C.0,07 D.0,2 15. t chy hon ton amin no, n chc bc mt ,mch h thu c t l mol CO 2 v H2O l 4:7 .Tn gi ca amin l: A.etyl amin B. imetyl amin C.etyl metyl amin D.propyl amin

16. t chy hon ton 10,4 gam hai amin no, n chc, ng ng lin tip nhau, thu c 11,2 lt kh CO2 (ktc). Hai amin c cng thc phn t l A. CH4N v C2H7N B. C2H5N v C3H9N. C. C2H7N v C3H7N D. C2H7N v C3H9N

17. t chy hon ton hn hp 2 amin no n chc ng ng lin tip nhau, thu c nH 2O : nCO2 = 2 :1 . Hai amin c Cng thc phn t l: A. C3H7NH2 v C4H9NH2 B. CH3NH2 v C2H5NH2 C. C2H5NH2 v C3H7NH2 D. C4H9NH2 v C5H11NH2 DNG 3: XC NH CU TO AMIN N CHC DA VO PHN NG TO MUI * Phn ng to mui: t CTTQ ca amin no n chc CnH2n+1NH2 hoc amin n chc l: R-NH2 V n chc nn ta lun c nHCl = nNH2 + Vi HCl: RNH2 + HCl RNH3Cl (1)

p dng CT:

= n = a => MR =a -16 => CTPT HCl (hoc M = = A M = A - 14 => CTPT) 1. trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l (Cho H = 1; C = 12; N = 14) A. C3H7N. B. C2H7N. C. C3H5N. D. CH5N. 2. trung ha 20 gam dung dch ca mt amin n chc X nng 22,5% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l (Cho H = 1; C = 12; N = 14) A. C2H7N B. CH5N C. C3H5N D. C3H7N 3. Trung ha 3,1 gam mt amin n chc cn 100 ml dung dch HCl 1M. Cng thc phn t ca X l A. C2H5N B. CH5N C. C3H9N D. C3H7N 4.Cho 0,4 mol amin no, n chc X tc dng vi dd HCl va thu c 32,6g mui.CTPT ca X l: A.CH3NH2 B.C2H5NH2 C.C3H7NH2 D.C4H9NH2 5. Trung ha 11,8 gam mt amin n chc cn 200 ml dung dch HCl 1M. Cng thc phn t ca X l A. C2H5N B. CH5N C. C3H9N D. C3H7N 6. Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l A. 5. B. 8. C. 7. D. 4. 7. Cho 20 hn hp 3 amin n chc no, ng ng lin tip nhau tc dng vi dung dch HCl 1M va , sau c cn dung dch thu c 31,68 gam hn hp mui. Bit t l mol ca cc amin theo th t t amin nh n amin ln l 1:10:5 th ba amin c Cng thc phn t l: A. CH3NH2, C2H5NH2, C3H7NH2 B. C2H5NH2, C3H7NH2, C4H9NH2 C. C3H7NH2, C4H9NH2, C5H11NH2 D. Tt c u sai.

M RNH 2

mRNH 2

Dng 4: AMIN TAC DUNG VI DUNG DCH MUOI (tng t amoniac) 3RNH2 + 3H2O + FeCl3 Fe(OH)3 + 3RNH3+Cl1. Cho 9,3 gam mt amin no n chc bc 1 tc dng vi dung dch FeCl3 d thu c 10,7 gam kt ta. Cng thc ca amin trn l: A. C2H5N B. CH5N C. C3H9N D. C3H7N 2. Cho hn hp 2 amin n chc bc I c t khi hi so vi hiro l 19 (bit c mt amin c s mol bng 0,15) tc dng vi dung dch FeCl3 d thu c kt ta A. em nung A n khi lng khng i thu c 8 gam cht rn. Cng thc ca 2 amin l A. CH3NH2 v C2H5NH2 B. CH3NH2 v C2H3NH2 C. C2H5NH2 v C2H3NH2 D. CH3NH2 v CH3NHCH3 3. Cho m gam hn hp hai amin n chc bc I c t khi hi so vi hiro l 30 tc dng vi FeCl 2 d thu c kt ta X. ly kt ta nung trong khng kh n khi lng khng i c 18,0 gam cht rn. Vy gi tr ca m l A. 30,0 gam B. 15,0 gam C. 40,5 gam D. 27,0 gam 4. Cho 17,4 gam hn hp 2 amin n chc bc I c t khi so vi khng kh bng 2. Tc dng vi dung dch FeCl 3 d thu c kt ta, em nung kt ta n khi lng khng i c m gam cht rn. Gi tr ca m l A. 16,0 gam B. 10,7 gam C. 24,0 gam D. 8,0 gam

AMINOAXIT
DNG 1: TNH KHI LNG CA AMINO AXIT TRONG PHN NG VI AXT HOC BAZ * Phi vit c 2 phng trnh c dng: + Vi axt HCl: H2N R COOH + HCl ClH3N R COOH R + 61 R+ 97,5 tng 36,5 + Vi baz NaOH: H2N R COOH+ NaOH H2N R COONa+ H2O R + 61 R+ 83 tng 22 DNG 2: TM CTCT CA AMINO AXT DA VO P TO MUI

*T/ dng vi NaOH:. Ptpu: (H2N)a R (COOH)b + bNaOH (H2N)a R (COONa)b + bH2O n NaOH = b = s nhm chc axit ( COOH) na min * T/d vi HCl Ptpu: (H2N)a R (COOH)b + aHCl (ClH3N)a R (COOH)b n HCl = a = s nhm chc baz (NH2) n a min 1. Mt - amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl. Cho 10,68 gam X tc dng vi HCl d thu c 15,06 gam mui. Tn gi ca X l A. axit glutamic. B. valin. C. alanin. D. Glixin 2. 0,1 mol aminoaxit X phn ng va vi 0,2 mol HCl hoc 0,1 mol NaOH. Cng thc ca X c dng l. A. (H2N)2R(COOH)2. B. H2NRCOOH. C. H2NR(COOH)2. D. (H2N)2RCOOH 3. X l mt - amioaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 23,4 gam X tc dng vi HCl d thu c 30,7 gam mui. Cng thc cu to thu gn ca X l cng thc no? A. CH3-CH(NH2)-COOH B. H2N-CH2-COOH C.CH2-CH(CH3)CH(NH2)COOH D.CH2=C(CH3)CH(NH2)COOH 4. X l mt aminoaxit no ch cha 1 nhm - NH 2 v 1 nhm COOH. Cho 0,89 gam X tc dng vi HCl va to r a 1,255 gam mui. Cng thc cu to ca X l cng thc no sau y? A. H2N- CH2-COOH B. CH3- CH(NH2)-COOH.C. CH3-CH(NH2)-CH2-COOH. D. C3H7-CH(NH2)-COOH 5. X l mt - amioaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 15,1 gam X tc dng vi HCl d thu c 18,75 gam mui. Cng thc cu to ca X l cng thc no? A. C6H5- CH(NH2)-COOH B. CH3- CH(NH2)-COOH C. CH3-CH(NH2)-CH2-COOH D. C3H7CH(NH2)CH2COOH 6. X l mt amino axit. Khi cho 0,01 mol X tc dng vi HCl th dng ht 80 ml dung dch HCl 0,125 M v thu c 1,835 g mui khan. Cn khi cho 0,01 mol X tc dng vi dung dch NaOH th cn 25 gam dung dch NaOH 3,2%. Cng thc no sau y l ca X ? A. C7H12-(NH)-COOH C3H5-COOH B. C3H6-(NH)-COOH C. NH2-C3H5-(COOH)2 D. (NH2)2-

7. Cho 4,41g mt aminoaxit X tc dng vi dung dch NaOH d cho ra 5,73g mui. Mt khc cng lng X nh trn nu cho tc dng vi dung dch HCl d thu c 5,505 g mui clorua. X CTCT ca X. A. HOOC-CH2CH2CH(NH2)COOH B. CH3CH(NH2)COOH C. HOOCCH2CH(NH2)CH2COOH D.C A,B 8. 0,1 mol aminoaxit A phn ng va vi 0,2 mol HCl, sn phm to thnh p va ht vi 0,3 mol NaOH. Gi tr n, m ln lt l: A. (H2N)2R(COOH)3. B. H2NRCOOH. C. H2NR(COOH)2. D. (H2N)2RCOOH 9. Cho 1 mol aminoaxit X tc dng vi dung dch NaOH d m1 g mui Y. Mt khc cng 1 mol X nh trn nu cho tc dng vi dung dch HCl d thu c m2 g mui Z. Bit m1 - m2 = 7,5. X CTPT ca X. A. C5H9O4N B. C4H10O2N2 C. C5H11O4N D. C5H8O4N2

10. Cho 14,7 gam mt amino axit X (c 1 nhm NH 2) tc dng vi NaOH d thu c 19,1 gam mui. Mt khc cng lng amino axit trn phn ng vi HCl d to 18,35 gam mui. Cng thc cu to ca X c th l A. NH2-CH2-COOH B. CH3-CH(NH2)COOH C. NH2-(CH2)6 -COOH D. HOOC-CH2-CH2-CH(NH2)COOH 11. X l mt amin aamino axit cha 1 nhmCOOH v 1 nhm NH2. Cho 8,9g X tc dng vi dung A. CH c COOH B. CH3 mui CHkhan. CH COOH 2 dch HCl. Sau 2 cn dung dch th thu c 12,55g Cng thc ng ca X l

NH2 C. CH3 CH COOH NH2 NH2

NH2

D. CH2 CH2 COOH

12. Amino axit X cha 1 nhmCOOH v 2 nhm NH2. Cho 0,1 mol X tc dng ht vi 270ml dung dch NaOH 0,5M c cn thu c 15,4g cht rn. Cng thc phn t c th c ca X l A. C4H10N2O2 B. C5H12N2O2 C. C5H10NO2 D. C3H9NO4 13. X l mt a amino axit cha 1 nhm COOH v 1 nhm NH 2. Cho 8,9g X tc dng vi 200ml dung dch HCl 1M. Thu c dung dch Y. phn ng ht vi cc cht trong dung dch Y cn dng 300ml dung dch NaOH 1M. CTCT ca X l.

A. CH3 - CH2 COOH NH2

B. CH3 CH2 CH COOH CH3 D. CH3 C NH2 NH2 COOH

C.

CH2(NH2) - CH2 COOH

DNG 3: T CHY AMINOAXIT t CTTQ CxHyOzNt m m m m m x: y: z :t = C : H : O : N = nCO2 : 2.nH2O : O : 2.nN2 12 1 16 14 16 Hay x: y: z :t = %C % H %O % N : : : 12 1 16 14

1. Mt amino axit (X) c cng thc tng qut NH 2RCOOH. t chy hon ton a mol X thu c 6,729 (l) CO2 (ktc) v 6,75 g H2O. CTCT ca X l : A. CH2NH2COOH B v C B. CH2NH2CH2COOH C. CH3CH(NH2)COOH D. C

2. Este X c to bi ancol metylic v - amino axit A. T khi hi ca X so vi H 2 l 51,5. Amino axit A l A. Axit - aminocaproic B. Alanin C. Glyxin D. Axit glutamic 3. Hp cht X c 40,45%C, 7,86%H, 15,73%N v cn li l oxi. Khi lng mol phn t ca X nh hn 100 gam. Bit X tc dng c vi hiro nguyn t. Cng thc cu to ca X l A. CH3CH(NH2)COOH B. CH3-CH2-CH2-CH2NO2 C. H2NCH2CH2COOH D. CH3-CH2-CH2-NO2 4. Phn tch nh lng hp cht hu c X ta thy t l khi lng gia 4 nguyn t C, H, O, N l m C : mH : mO : mN = 4,8 : 1 : 6,4 : 2,8. T khi hi ca X so vi He bng 18,75. Cng thc phn t ca X l A. C2H5O2N. B. C3H7O2N. C. C4H10O4N2. D. C2H8O2N2

THI I HC
Cu 1 (Cu 29-DH-10-A): Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l : A. 0,70. B. 0,50. C. 0,65. D. 0,55. Cu 2 (Cu 40-DH-10-A): C bao nhiu tripeptit (mch h) khc loi m khi thy phn hon ton u thu c 3 aminoaxit: glyxin, alanin v phenylalanin? A. 6. B. 9. C. 4. D. 3. Cu 3 (Cu 41-DH-10-A): Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l A. 7 v 1,0. B. 8 v 1,5. C. 8 v 1,0. D. 7 v 1,5.

Cu 4 (Cu 16-DH-10-B): Hai hp cht hu c X v Y c cng cng thc phn t l C3H7NO2, u l cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l A. amoni acrylat v axit 2-aminopropionic. B. axit 2-aminopropionic v amoni acrylat. C. vinylamoni fomat v amoni acrylat. D. axit 2-aminopropionic v axit 3-aminopropionic. Cu 5 (Cu 19-DH-10-B): Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung dch Y cha (m+30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha (m+36,5) gam mui. Gi tr ca m l A. 171,0. B. 112,2. C. 123,8. D. 165,6. Cu 6 (Cu 23-DH-10-B): ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 45. B. 120. C. 30. D. 60. Cu 7 (Cu 47-DH-10-B): Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l A. Gly-Ala-Val-Val-Phe. B. Gly-Phe-Gly-Ala-Val. C. Val-Phe-Gly-Ala-Gly. D. Gly-Ala-Val-Phe-Gly. Cu 8 (Cu 6-CD-10-A): Dung dch no sau y lm qu tm chuyn mu xanh? A. Glyxin. B. Etylamin. C. Anilin. D. Phenylamoni clorua. Cu 9 (Cu 10-CD-10-A): ng vi cng thc phn t C2H7O2N c bao nhiu cht va phn ng c vi dung dch NaOH, va phn ng c vi dung dch HCl? A. 2. B. 3. C. 1. D. 4. Cu 10 (Cu 48-DH-10-B): Nu thu phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu c ti a bao nhiu ipeptit khc nhau? A. 3. B. 1. C. 2. D. 4. Cu 11 (Cu 14-DH-09-A): Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l A. C5H9O4N. B. C4H10O2N2. C. C5H11O2N. D. C4H8O4N2. Cu 12 (Cu 20-DH-09-A): Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l A. dung dch NaOH. B. dung dch NaCl. C. Cu(OH)2 trong mi trng kim. D. dung dch HCl. Cu 13 (Cu 48-DH-09-A): Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l A. 10,8. B. 9,4. C. 8,2. D. 9,6. Cu 14 (Cu 15-DH-09-B): Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. (H2N)2C3H5COOH. B. H2NC2C2H3(COOH)2. C. H2NC3H6COOH. D. H2NC3H5(COOH)2. Cu 15 (Cu 22-DH-09-B): S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l A. 2 B. 3 C. 4 D. 1 Cu 16 (Cu 24-DH-09-B): Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2 . Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z ; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l A. CH3OH v CH3NH2 B. C2H5OH v N2 C. CH3OH v NH3 D. CH3NH2 v NH3 Cu 17 (Cu 48-DH-09-B): Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l A. 29,75 B. 27,75 C. 26,25 D. 24,25 Cu 18 (Cu 18-CD-09-A): Cht X c cng thc phn t C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l : A. metyl aminoaxetat. B. axit -aminopropionic. C. axit -aminopropionic. D. amoni acrylat.

Cu 19 (Cu 50-CD-09-A): Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vC th s mt xch alanin c trong phn t X l A. 453. B. 382. C. 328. D. 479. Cu 20 (Cu 58-CD-09-A): Cho tng cht H2NCH2COOH, CH3COOH, CH3COOCH3 ln lt tc dng vi dung dch NaOH (to) v vi dung dch HCl (to). S phn ng xy ra l: A. 3. B. 6. C. 4. D. 5.