10 HO THI TH H 2013 Cho bit khi lng nguyn t (theo vC) ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24;

4; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56; Cu = 64; Br = 80; Ag = 108; Ba = 137. A. PHN CHUNG CHO TT C TH SINH ( 40 cu: T cu 01 n cu 40) Cu 1: Cho 28g bt st vo dung dch AgNO3 d, gi s phn ng xy ra hon ton th khi st tc dng ht s thu c bao nhiu gam cht rn? A. 162g B. 216g C. 270g D. 108g Cu 2: C bao nhiu ipeptit c th to ra t hai axit amin l alanin (Ala) v glixin (Gli)? A. 5 B. 2 C. 4 D. 3 Cu 3: Cho cc dung dch c nh s th t nh sau: 1. KCl 2. Na 2CO3 3. CuSO4 4. CH3COONa 5. Al2(SO4)3 6. NH 4Cl 7. NaBr 8. K2S. Dung dch c pH < 7 l: A. 3, 5, 6 B. 6, 7 , 8 C. 2, 4, 6 D. 1, 2, 3 Cu 4: Trong cc cht p.O2N-C6H4-OH, m.CH3-C6H4-OH, p.NH2-C6H4-CHO, m.CH3-C6H4-NH2. Cht c lc axit mnh nht v cht c lc baz mnh nht tng ng l A. p.O2N-C6H4-OH v m.CH3-C6H4-NH2 B. m.CH3-C6H4-OH v m.CH3-C6H4-NH2 C. p.O2N-C6H4-OH v p.NH2-C6H4-CHO D. m.CH3-C6H4-OH v p.NH2-C6H4-CHO Cu 5: Nhn xt no di y khng ng ? A. CrO, Cr(OH)2 c tnh baz; Cr2O3, Cr(OH)3 c tnh lng tnh B. Hp cht Cr(II) c tnh kh c trng; Cr(III) va c tnh oxi ha, va c tnh kh; Cr(VI) c tnh oxi ha C. Cr(OH)2, Cr(OH)3 c th b nhit phn D. Cr2+, Cr3+ c tnh trung tnh; Cr(OH)4 c tnh baz Cu 6: Thi kh CO2 vo dung dch cha 0,02 mol Ba(OH)2. Gi tr khi lng kt ta bin thin trong khong no khi CO2 bin thin trong khong t 0,005 mol n 0,024 mol ? A. 0,985 gam n 3,94 gam B. 0 gam n 3,94 gam C. 0 gam n 0,985 gam D. 0,985 gam n 3,152 gam Cu 7:Dy gm cc cht sau y u tc dng vi dung dch NaOH? A. C6H5NH2 ,C6H5OH B. C6H5OH ,C2H5OH C. CH3COOC2H5 , NH2CH2COOH D. CH3COOH , C2H5OH Cu 8: Tng s ht trong ion M3+ l 37. V tr ca M trong bng tun ha l: A. chu k 3, nhm IIA B. chu k 4, nhm IA C. chu k 3, nhm IIIA D. chu k 3, nhm VIA Cu 9: To lipit t glixerin phn ng vi 2 axit bo RCOOH v R'COOH, ta thu c hn hp cc trieste. Tnh s trieste ny? A. 8 B. 4 C. 6 D. 5 Cu 10: Cho 0,3 mol FexOy tham gia phn ng nhit nhm thy to ra 0,4 mol Al 2O3. Cng thc oxit st l: A. FeO B. Fe2O3 C. Khng xc nh c v khng cho bit s mol Fe to ra. D. Fe3O4 Cu 11: Cho dy cc cht: Ca(HCO3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong dy c tnh cht lng tnh l: A. 2 B. 3 C. 4 D. 5 Cu 12: Cho 2,54g este (X) mch h bay hi trong 1 bnh kn dung tch 0,6 lt (lc u l chn khng). Khi este bay hi ht th p sut 136,50C l 425,6 mmHg.Thu phn 25,4 gam (X) cn 0,3 mol NaOH thu c 28,2 g mt mui duy nht. Xc nh tn gi (X) bit rng (X) pht xut t ru a chc. A. Glixerin triaxetat B. Etylenglicoliaxetat C. Glixerin tripropionat D. Glixerin triacrylat
2 Cu 13: nhn ra ion SO4 trong dung dch hn hp c ln cc ion CO 32, PO43 SO32 v HPO42, nn

dng thuc th l dung dch cht no di y ? A. H2SO4 c d

B. Ba(OH)2
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 10 HO THI TH H 2013 C. Ca(NO3)2 D. BaCl2 / H2SO4 long d Cu 14: Cho m gam bt st vo dung dch hn hp cha 0,16 mol Cu(NO 3)2 v 0,4 mol HCl, lc u cho phn ng xy ra hon ton. Sau phn ng thu c hn hp kim loi c khi lng bng 0,7m gam v V lt kh (ktc). Gi tr ca V v m ln lt l A. 1,12 lt v 18,20 gam B. 4,48 lt v 21,55 gam C. 2,24 lt v 33,07 gam D. 4,48 lt v 33,07 gam Cu 15: Cho cc hp cht sau: 1. CH3-CH(NH2)-COOH 2. HO-CH2-COOH 3. CH2O v C6H5OH 4. C2H4(OH)2 v p-C6H4(COOH)2 5. (CH2)5(NH2)2 v (CH2)4(COOH)2 Cc trng hp no sau y c kh nng tham gia phn ng trng ngng? A. 3,5 B. 1, 2, 3, 4, 5 C. 1,2 D. 3,4 Cu 16: Cho 4,48 lt CO2 (ktc) hp th ht vo 500ml dung dch hn hp NaOH 0,1M v Ba(OH) 2 0,2M thu c m gam kt ta. Gi tr ng ca m l: A. 20,4g. B. 15,2g C. 9,85g D. 19,7g Cu 17: Hn hp (X) gm metanal v etanal. Khi oxi ha (hiu sut 100%) m (g) hn hp (X) thu c hn hp (Y) gm hai axit hu c tng ng, c t khi hi ca hn hp Y so vi hn hp X bng x .Gi tr x trong khong no? A. 1,62 < x < 1,53 B. 1,36 < x < 1,47 C. 1,45 < x < 1,53 D. 1,36 < x < 1,53 Cu 18: Aminoaxit Y cha 1 nhm COOH v 2 nhm - NH 2 cho 1 mol Y tc dng ht vi dung dch HCl v c cn th thu c 205g mui khan. Tm cng thc phn t ca Y. A. C6H14N2O2 B. C4H10N2O2 C. C5H10N2O2 D. C5H12N2O2 Cu 19: C 4 kim loi : Mg, Ba, Zn, Fe. Ch dng thm 1 cht th c th dng cht no trong s cc cht cho di y nhn bit kim loi ? A. dd Ca(OH)2 B. dd H2SO4 long C. dd NaOH D. khng nhn bit c. Cu 20: un nng phenol vi anehit fomic theo t l mol 1:1 trong mi trng axit ta thu c A. hn hp hai cht hu c tan vo nhau v khng c phn ng. B. polime c cu trc mch khng phn nhnh. C. polime c cu trc mng khng gian bn. D. polime c cu trc mch h phn nhnh. Cu 21: Cho hn hp gm FeO, CuO, Fe 3O4 c s mol 3 cht u bng nhau tc dng ht vi dung dch HNO3 thu c hn hp kh gm 0,09 mol NO2 v 0,05 mol NO. S mol ca mi cht l: A. 0,21 B. 0,12 C. 0.36 D. 0,24 Cu 22: Ho tan hon ton 1,4 gam bt Fe kim loi bng dung dch HNO 3 nng 2M ly d thu c V lt (ktc) hn hp kh NO v NO2 c t khi hi so vi hiro l 17. Gi tr ca V l A. 0,448 lt. B. 0,672 lt. C. 0,896 lt. D. 0,112 lt. Cu 23: Cho hn hp cha x mol Mg, y mol Fe vo dung dch cha z mol CuSO 4. Sau khi kt thc cc phn ng thu c cht rn gm 2 kim loi. Mun tho mn iu kin th: A. x < z < y B. z x C. x z < x +y D. z = x + y Cu 24: Trong cc qu trnh di y: 1) H2 + Br2 (t0) ; 2) NaBr + H2SO4 (c, t0 d) 3) PBr3 + H2O 4) Br2 + P + H2O Qu trnh no khng iu ch c HBr A. (3) v (4) B. (1) v (3). C. (2). D. (3) Cu 25: Cho 6,76 gam Oleum H2SO4 .nSO3 vo nc thnh 200ml dung dch. Ly 10 ml dung dch ny trung ho va vi 16 ml dung dch NaOH 0,5 M. Gi tr ca n l: A. 2 B. 1 C. 4 D. 3 Cu 26: Chia hn hp 2 kim loi c ho tr khng i lm 2 phn bng nhau. Phn 1 tan ht trong dung dch HCl to ra 1,792 lt H2 (ktc). Phn 2, nung trong oxi thu c 2,84 gam hn hp oxit. Khi lng hn hp 2 kim loi ban u l: A. 1,8 gam B. 2,4 gam C. 3,12 gam D. 2,2 gam
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 10 HO THI TH H 2013 Cu 27: C bn ng nghim ng cc hn hp sau: 1) Benzen + phenol 2) Anilin + dd H 2SO4 (ly d) 3) Anilin +dd NaOH 4)Anilin + nc. Hy cho bit trong ng nghim no c s tch lp A. 1, 2, 3 B. 1, 4 C. 3, 4 D. Ch c 4 Cu 28: Thu phn cc hp cht sau trong mi trng kim: 1. CH3ClCHCl 2. CH3COOCH=CH2 3. CH3COOCH2-CH=CH2 4. CH3CH2CHOHCl 5. CH3COOCH3. Sn phm to ra c phn ng trng gng l A. 1, 2, 4 B. 1, 2 C. 3, 5 D. 2 Cu 29: X l dung dch AlCl3 Y l dung dch NaOH 2M thm 150ml dung dch Y vo cc cha 100 ml dung dch X khuy u n khi phn ng hon ton thy trong cc c 7,8g kt ta. Thm tip vo cc 100ml dung dch Y khuy u ti khi kt thc phn ng thy trong cc c 10,92 g kt ta. Nng mol ca dung dch X bng: A. 3,2 M B. 2,0 M C. 1,6 M D. 1,0 M Cu 30: Hn hp X gm FeO, Fe3O4 v Fe2O3. kh hon ton 3,04 gam hn hp X cn va 0,1 gam H2. Ho tan ht 3,04 gam hn hp X bng dung dch H 2SO4 c, nng th th tch kh SO2 (sn phm kh duy nht) thu c ktc l A. 0,224 lt B. 0,336 lt C. 0,896 lt D. 0,448 lt Cu 31: C hin tng g xy ra khi cho t t n d dung dch FeCl3 v dung dch Na2CO3? A. Ch c kt ta nu B. C kt ta nu v si bt kh C. Ch c si bt kh D. C kt ta mu trng xanh v si bt kh Cu 32: phn bit 2 dung dch KI v KCl bng h tinh bt ngi ta phi dng thm 1 cht no sau y? p n no khng ng: A. FeCl3 B. O3 C. Khng cn dng cht no D. Cl2 hoc Br2 Cu 33: Hp cht X (C8H10)c cha vng benzen, X c th to ra 4 dn xut C8H9Cl. vy X l A. p-xilen B. Etylbenzen C. o-xilen D. m- xilen Cu 34: Thm NH3 n d vo dung dch hn hp cha 0,01 mol FeCl3 v 0,01 mol CuCl2. Khi cc phn ng xy ra hon ton, khi lng kt ta thu c bng : A. 0,90 gam B. 1,07 gam C. 2,05 gam D. 0,98 gam Cu 35: C 4 dung dch khng mu: glucoz, glixerol, h tinh bt v lng trng trng. Hy chn cht no trong s cc cht cho di y c th nhn bit c c 4 cht? A. Cu(OH)2 trong dung dch NaOH, nhit B. I2 C. AgNO3 trong dung dch NH3. D. HNO3 c nng, nhit Cu 36: Cho 2,24 lt NO2 (ktc) hp th ht vo 500ml dung dch NaOH 0,4M thu c dung dch X. Gi tr PH ca dung dch X l: A. PH < 7 B. PH > 7 C. PH = 7 D. C th PH > hoc PH < 7. Cu 37: C 4 hp cht hu c c cng thc phn t ln lt l: CH 2O, CH2O2, C2H2O3 v C3H4O3.S cht va tc dng vi Na, va tc dng vi dung dch NaOH, va c phn ng trng gng l A. 4 B. 3 C. 2 D. 1 Cu 38: in phn dung dch hn hp cha 0,1 mol FeCl3, 0,2 mol CuCl2 v 0,1 mol HCl (in cc tr, mng ngn xp). Khi catot bt u si bt kh th dng in phn. Ti thi im ny khi lng catot tng : A. 0,0 gam B. 5,6 gam C. 12,8 gam D. 18,4 gam Cu 39: Phn ng: FexOy + 2yHI xFeI2 + (y-x) I2 + y H2O khng phi l phn ng oxi ha kh nu: A. lun lun l phn ng oxi ho kh, khng ph thuc vo gi tr x,y B. x = 2; y = 3. C. x = 3; y = 4 D. x = y = 1 Cu 40: Hp cht X khng no mch h c cng thc phn t C 5H8O2, khi tham gia phn ng x phng ho thu c mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X (khng k ng phn hnh hc) A. 4 B. 3 C. 2 D. 5 B. PHN RING (Th sinh chn mt trong hai phn). I. Theo chng trnh chun (10 cu: t cu 41 n cu 50)
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 10 HO THI TH H 2013 Cu 41: Bnh 1 ng O2, bnh 2 ng O2 v O3 th tch nhit p sut ca 2 bnh u nh nhau. Khi lng kh bnh 2 nng hn bnh 1 l 1,6g tnh s mol O3 c trong bnh 2: A. Khng xc nh. B. 1/3 mol C. 0,1 mol D. 0,5 mol Cu 42: Mt hn hp X gm 1 ankan A v 1 ankin B c cng s nguyn t cacbon. Trn X vi H 2( va ) c hn hp Y. Khi cho Y qua Pt, xc tc th thu c kh Z c t khi i vi CO 2 bng 1 (phn ng cng H2 hon ton). Bit rng Vx = 6,72 lt v VH2 = 4.48 lit. Xc nh CTPT v s mol ca A, B trong hn hp X. Cc th tch kh c o ktc. A. C3H8,C3H4, 0,2 mol C3H8, 0,1 mol C3H4 B. C3H8,C3H4, 0,1 mol C3H8, 0,2 mol C3H4 C. C2H6,C2H2, 0,2 mol C2H6, 0,2 mol C2H2 D. C2H6,C2H2, 0,1 mol C2H6, 0,2 mol C2H2 Cu 43: Hn hp (X) gm 2 kim loi kim v 1 kim loi kim th tan hon ton vo nc, to ra dung dch (C) v gii phng 0,12 mol H2. Th tch dung dch H2SO4 2M cn thit trung ho dd (C) l: A. 1,2 ml B. 60 ml C. Kt qu khc D. 120 ml Cu 44: lm sch CO2 c ln hn hp HCl v hi nc. Cho hn hp ln lt i qua cc bnh: A. H2SO4 v KOH B. NaOH v H2SO4 C. Na2CO3 v P2O5 D. NaHCO3 v P2O5 Cu 45: Cho cc kim loi sau: Zn, Fe, Cu, Ag. Kim loi no va phn ng vi dung dch HCl, va phn ng vi dung dch FeCl2? A. Cu. B. Zn. C. Ag. D. Fe. Cu 46: t chy hon ton 0,25 mol hn hp hai este no, mch h, n chc l ng ng lin tip thu c 19,712 lit kh CO2 (ktc). X phng ha cng lng este trn bng dung dch NaOH to ra 17 gam mt mui duy nht. Cng thc ca hai este l : A. HCOOC2H5 v HCOOC3H7 B. HCOOC3H7 v HCOOC4H9 C. CH3COOC2H5 v HCOOC2H5 D. CH3COOCH3 v CH3COOC2H5 Cu 47: Phn ng no di y lm thay i cu to ca nhn thm ? as A. Stiren + Br2 B. Toluen + Cl2
as,50 C C. Benzen + Cl2 D. Toluen + KMnO4 + H2SO4 Cu 48: Nguyn t X c ho tr i vi H bng 2 v ho tr ti a i vi O bng 6. Bit X c 3 lp electron . Tnh Z ca X. A. 15 B. 16 C. 14 D. 10 Cu 49: Cho cc cht: benzen, toluen, stiren, propilen, axetilen. S cht lm mt mu thuc tm nhit thng l: A. 5 B. 3 C. 4 D. 2 Cu 50: Cho a gam hn hp Mg v Al vo 250 ml dung dch X cha 2 axit : HCl 1M v H 2SO4 0,5M c dung dch B v 4,368 lt H2 (ktc) th trong dung dch B s: A. Thiu axit B. Tt c u sai C. Dung dch mui D. D axit II. Theo chng trnh nng cao (10 cu: t cu 51 n cu 60). Cu 51: Khi ho tan Al bng dd HCl, nu thm vi git dung dch Hg2+ vo th qu trnh ho tan Al s: A. Xy ra nhanh hn B. Khng thay i C. Xy ra chm hn D. Tt c u sai Cu 52: Nguyn t oxi trng thi c bn c s obitan cha electron l A. 5 B. 6 C. 3 D. 4 Cu 53: Dung dch HCl v dung dch CH 3COOH c cng nng mol/lt. PH ca 2 dung dch l x v y. Quan h gia x v y l: (gi thit c 100 phn t CH3COOH th c 1 phn t in li) A. y = x + 2 B. y = 100x C. y = x 2 D. y = 2 x Cu 54: Cho cn bng H2 (K) + Cl2(K) 2HCl phn ng to nhit (H<0), phn ng chuyn dch theo chiu thun cn tng. A. Nng H2 hoc Cl2 B. Nhit C. p sut D. Cht xc tc. Cu 55: Khi thay i nhit ca dung dch cht in li th: A. in li thay i v hng s in li khng i B. in li v hng s in li u thay i C. in li khng i v hng s in li thay i D. in li v hng s in li u khng i Cu 56: Pht biu no di y l khng ng ? A. Trong phn ng oxi ha - kh t xy ra, th in cc chun ca cht kh ln hn th in cc chun ca cht oxi ha
o

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 10 HO THI TH H 2013 B. Kim loi trong cp oxi ha - kh c th in cc chun nh hn 0,00 V c th y c hiro ra khi dung dch axit C. Cation kim loi trong cp oxi ha - kh c th in cc chun ln hn c th oxi ha c kim loi trong cp c th in cc chun nh hn D. Sut in ng chun ca pin in ha bng th in cc chun ca cc dng tr th in cc chun ca cc m Cu 57: in phn 100 ml dung dch CuSO 4 0,2 M vi I = 9,65Ampe. Tnh khi lng Cu bm ln catt khi thi gian in phn t1 = 200 s, t2 = 500s ln lt l: A. 0,32g & 0,64g B. 0,64g & 1,28g C. 0,64g & 1,32g D. 0,32g & 1,28g Cu 58: Trong cng nghip, khi in phn dung dch NaCl c mng ngn thu c hn hp gm NaOH v NaCl khu vc catot. tch c NaCl khi NaOH ngi ta s dng phng php : A. chit B. kt tinh phn on C. chng ct D. lc, tch + 2+ Cu 59: Cho bit th in cc chun ca cc cp oxi ho kh: 2H /H2; Zn /Zn; Cu2+/Cu; Ag+/Ag ln lt l 0,00V; -0,76V; +0,34V; +0,80V. Sut in ng ca pin in ho no sau y ln nht? A. 2Ag + 2H+ B. Cu + 2Ag+ 2Ag+ + H2 Cu2+ + 2Ag C. Zn + 2H+ D. Zn + Cu2+ Zn2+ + H2 Zn2+ + Cu Cu 60: Hirat ho hon ton 1,56 gam mt ankin (A) thu c mt anehit (B). Trn (B) vi mt anehit n chc (C). Thm nc c mt 0,1 lit dd (D) cha (B) v (C) vi nng mol tng cng l 0,8M. Thm t t vo dd (D) vo dd cha Ag2O/NH3 d thu c 21,6g Ag kt ta. Xc nh CTCT v s mol ca (B) v (C) trong dung dch (D). A. (B): CH3-CHO 0,1 mol, (C): H-CHO 0,15 mol B. (B): CH3-CHO 0,08 mol,(C): H-CHO 0,05 mol C. (B): CH3-CHO 0,06 mol,(C): H-CHO 0,02 mol D. (B): CH3-CHO 0,1 mol, (C): C2H5CHO 0,2 mol ----------- HT ----------

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