GII CHI TIT MT S CU 608

Cu 7.
iu kin tc dng c vi H
2
O l s [O] > +4 p n B
Cu 13.
Ta c:
2+
Ba
n = 0,012 mol;
OH
n

= 0,168 mol

H
n
+
= 0,1 mol;
2
4
SO
n

= 0,02 mol
Th t cc phn ng: H
+
+ OH

H
2
O (1)
Ba
2+
+ SO
4
2-
BaSO
4
(2)
Al
3+
+ 3OH

Al(OH)
3
(3)
C th c phn ng: Al(OH)
3
+ OH

AlO
2

+ 2H
2
O (4)
(1), (2)
-
3
OH
Al(OH)
n
3,732 - 233 . 0,012
n = = 0,012 mol
78
+

V
-
OH
n
n
3
= +
-
3+
OH
Al
n + n
0,012 + 0,068
z = n = = = 0,02 mol
4 4
+

t = 0,12 (nh LBTT:
+ -
dt dt
n n = ) p n B
Cu 17.
A, B c n
Ag
= 0,025 . 4 = 0,1 mol m
Ag
= 10,8 8,64 A, B sai
Gi a, b (mol) ln lt l s mol mi anehit, ta c:

hh
n = a + b = 0,025
a = 0,01 mol
8,64
b = 0,015 mol n = 2a + 4b =
108

Kim tra C ta c: m
hh
= 77 . 0,01 + 58 . 0,015 = 1,57 1,64 C sai p n D
Cu 18.
Theo : CTTQ i din cho hn hp X:
4
x
C H (v cc cht trong hn hp X u c 4 nguyn t H)
12x + 4 = 17 . 2 x = 2,5
Ta c: m =
2 2
CO H O
4
m +m = 44 . 0,05 . 2,5 + 18 . 0,05 . = 7,3 gam
2
p n D
*Cn nh:
2
CO
n = n
t
. s C;
2
H O
n = n
t
. s
H
2

Cu 19.
4,385 gam hn hp X
o
o
2
C, t
2
3 t
hhY/H
4
2 4 2
O (het) 0,896 hh Y(dktc)
KClO
d = 16
KMnO
m g ran (K MnO , MnO , KCl)

%KMnO
4
(theo m) = ?
*Gi :
KClO
3

o
t
KCl +
2
3
O
2
(1)
x
3
x
2

2KMnO
4

o
t
K
2
MnO
4
+ MnO
2
+ O
2
(2)
y
y
2

Phn ng t than:
C +
1
2
O
2
CO (3)
C + O
2
CO
2
(4)
p vi Al
3+
= 0,068 mol
T cc d kin ca hn hp Y
2
CO
CO
n = 0,01
n = 0,03

T (3), (4)
2
O
n
sinh (1), (2)
=
2
O
n
p (3), (4)
=
1
2
. 0,03 + 0,01 = 0,025
Vy ta c h phng trnh:
3 y
x = 0,01 x + = 0,025
2 2
y = 0,02
122,5x + 158y = 4,385

%KMnO
4
=
158 . 0,02
0, 7206 72, 06%
4,385
= = p n C
Cu 20.
C
nng

2
H O hoi
15,68 lt hn hp X
o
CuO du
2
t
2
CO
CO
H

rn Y
3
HNO du

%CO (theo th tch) = ? 8,96 lt NO (ktc)
*Gi :
Cc phn ng: C + H
2
O
o
t
CO + H
2
(1)
x x
C + 2H
2
O
o
t
CO
2
+ 2H
2
(2)
y 2y
2
2
CO: x mol
hhY CO : y mol
H : x + 2y mol

n
hhX
= x + y + (x + 2y) = 2x + 3y = 0,7 (a)
Khi cho hn hp X phn ng vi CuO d ta c:
n
Cu

sinh ra
=
2
hh(H ,CO)
n = 2(x + y) mol
Cho cht rn Y phn ng vi HNO
3
ta c:
2
CO H Cu NO
2n + 2n = 2n = 3n 2.2(x + y) = 3.0,4 x + y = 0,3 (b)
T (a) v (b) ta c h phng trnh:
2x + 3y = 0,7 x = 0,2
x + y = 0,3 y = 0,1

%CO (theo V) =
0, 2
0, 2857 28, 57%
0, 7
= = p n B
Cu 22.
1,82 gam hh X
2 4 3 2
30ml dd H SO 0,5M, HNO 2M +0,1mol O
H=100%
Cu
a mol NO
Ag

hh kh Y
2
+ H O
150ml dd pH = z
z = ?
*Gi :
T d kin hn hp X
Cu: 0,02mol
Ag: 0,005mol

Ta c
+
H
n = 0,09 mol;
3
NO
n

= 0,06 mol
Do
-
+
3
NO
H
n
n
<
4 1
H
+
ht trc, tc NO
3

lun cn d
Thy n
Cu
.2 + n
Ag
.1 <
+
H
n
3.
4
Cu, Ag: ht
n
Cu
.2 + n
Ag
.1 = 3n
NO
n
NO
= 0,015 mol
D dng thy hn hp Y gm
2
2
NO : 0,015 mol
O : 0,0925 mol

nn ta c:

3 2
HNO NO
n = n = 0,015 mol

+ -1
0,015
[H ] = = 0,1 = 10
0,15
pH = 1 p n A
Cu 24.
Ta c:
OH
n

= 0,612;
3
Al(OH)
8,424
n = = 0,108
78

V BaCl
2
d nn ta c: 0,4 . x . 3 =
33, 552
233
y = 0,12 (1)
Do
-
3
OH
Al(OH)
n
n
3
+
= nn ta c:
-
3+
OH
Al
n + n
0,612 + 0,108
n 0,4(x . 1 + y . 2) =
4 4
+
= (2)
(1), (2)
x = 0,21
x 7
=
y = 0,12 y 4

p n C
Cu 25.
T
2
hh X/H
d = 22 hn hp X
2
n[O]
3
O : a mol
= 11a mol
O : 3a mol

T
2
hh Y/H
d = 17,833 hn hp Y
5
2 7
CH N: 2x mol
C H N: x mol

Phn ng chy: CH
5
N +
9
2
[O] CO
2
+
5
2
H
2
O +
1
2
N
2
(1)
2x 9x
C
2
H
7
N +
15
2
[O] 2CO
2
+
7
2
H
2
O +
1
2
N
2
(2)
x
15
2
x
(1), (2)
[O] p.u
n = 9x +
15
2
x = 16,5x
Vy 16,5x = 11a x =
11.a
16,5

Theo c:
1 hh Y
2 hh X
11a
3.
V V 3x 2a 1 16,5
= = = = =
V V 4a 4a 4a 2
p n D
Cu 27.
D thy ch c (b), (c) ng p n C
Cu 31.
Ta c
2
CO
n = 0,25 mol;
2
H O
n = 0,35 mol
2 2
CO H O
n n < X, Y u n, no
n
hh(X, Y)
=
2 2
H O CO
n - n = 0,1 mol
S C trung bnh n
X
= n
Y
= 0,05 mol
Ta c hn hp 3 ete
2 5 2
3 7 2
2 5 3 7
(C H ) O a mol
(C H ) O b mol
C H -O-C H c mol

2 5
C H OH pu
n = 2a + c;
3 7
C H OH pu
n = 2b + c
Ta c
hh ete
hh ete
m =74a + 102b + 88c = 1,25 mol
0,42
n = a + b + c = = 0,015 mol
28

37.(2a + c) + 51(2b + c) = 1,25 2a + c = 0,02
(2a + c) + (2b + c) = 0,03 2b + c = 0,01





Vy: H
p
ca C
2
H
5
OH =
0, 02
0, 4 40%
0, 05
= =
H
p
ca C
3
H
7
OH =
0, 01
0, 2 20%
0, 05
= = p n C
Cu 33.
Ta c
2
CO
n = 0,1 mol;
OH
n

= 0,1.x mol;
2
3
CO
n

= 0,02 mol

3
BaCO
11,82
n = = 0,06 mol
197

T B, C, D 1 < x < 2 1 <
2
OH
CO
n
n

< 2
dung dch Y
( ) 2-
3
2-
3
CO
3
= 0,02 + 0,1x - 0,1 = n
HC
CO
O
: n

;

0,02 + (0,1x - 0,1) = 0,06 x = 1,4 p n B
*Cn nh: CO
2
+ dd OH
-

Nu 1 <
2
OH
CO
n
n

< 2 th sn phm thu c c
2
3
CO
n

, HNO
3
-
v
2- -
2
3
- 2-
2
3 3
CO
CO OH
CO
HCO CO
n = n - n
n = n - n

Theo c:

2
hh X
H O
m = 86x + 74(y + z) = 3,08
x = 0,01
n = x . 3 + (y + z) . 3 = 0,12 y + z = 0,03

%CH
3
COOCH=CH
2
(theo mol) =
x 0,01
= = 0,25 = 25%
x + y + z 0,01 + 0,03

p n A
Cu 38. Chn A
Cu 41.
Cc ng phn ca C
5
H
10
phn ng vi dung dch Br
2
:
*Anken: CH
2
=CH-CH
2
-CH
2
-CH
3
; CH
3
-CH=CH-CH
2
-CH
3

CH
2
=C-CH
2
-CH
3
; CH
3
-C=CH-CH
3
; CH
3
-CH-CH=CH
2

CH
3
CH
3
CH
3

*Xicloankan:
CH
2
CH
2
CH
2

CH
2
-CH-CH
2
-CH
3
; CH
3
-CH-CH-CH
3
; CH
2
- C-CH
3

CH
2
p n A
Cu 42.
Ta c
hhX hhY
X Y
Y
X
n .M = n .M
n = 1 mol
n = 2 mol

Vy
2
H Y
1
n = n = 0,5 mol
2
V = 11,2 lt p n C
Cu 46.
m gam Zn
2 4 3
500ml d.d Fe (SO ) 0,24M
H = 100%
khi lng dung dch tng thm 9,6 gam
Gi tr ca m = ?
Phng trnh phn ng: Zn + Fe
2
(SO
4
)
3
ZnSO
4
+ 2FeSO
4
(1)
Zn + FeSO
4
Fe + ZnSO
4
(2)
Theo c m
mui tng
= 9,6 gam m
kim loi gim
= 9,6 gam
(1) c m
kim loi gim
= 65.n
p
; n
p
=
2 4 3
Fe (SO )
n = 0,12
(2) c m
kim loi gim
= 9.n
p
; n
p
= n
Zn p

Ta c: 65 . 0,12 + 9 . x = 9,6 x = 0,2

Zn
n = 0,12 + 0,2 = 0,32 m = 0,32 . 65 = 20,8 gam p n B
Cu 50.
Cc pht biu sai: (b), (e) p n B
Cu 58.
Ta c n
Ag+

b
= 0,08 mol; n
Zn
= 0,09 mol
Ta thy
+
Zn
Ag
. 1 < . 2 n n Zn cn d, Ag
+
: ht
Theo LBTT c
+
Zn pu'
Ag
. 1 = . 2 n n 0,08 . 1 = n
Zn p.
. 2 n
Zn p
= 0,04
Zn cn d trong Z l 0,05 mol
Theo c: m
rn X
+ m
rn Z
= m
Cu b
+ m
Zn cn d
+ m
Ag
7,76 + 10,53 = m + 65 . 0,05 + 108 . 0,08 m = 6,4
p n B