S GD va T ong Thap

Trng THPT Tam Nong

E KIEM TRA CHAT LNG HKI 2008-2009 MON: HOA HOC (KHOI 10) GV RA E: NGUYEN VAN TUAN THI GIAN LAM BAI: 45 PHUT NGAY THI: ././2008

A. Muc ch va yeu cau:

- Hs biet: Tnh c so p, n , e cua nguyen t. Viet c cau hnh e cua nhng nguyen t nhieu e va xac nh c v tr, tnh chat cua nguyen t cac nguyen to. Tnh c so e toi a trong 1 lp va phan lp. Biet c hoa tr cao nhat cua cac nguyen to khi tao hp chat vi O, H va viet cong thc oxit, hiroxit va hp chat kh vi hiro. - Hs hieu: + Cach viet cau hnh e cua cac nguyen t nhieu electron, xac nh c so e lp ngoai cung. + Biet c s bien oi tnh kim loai, tnh phi kim cua cac nguyen to trong chu k va trong 1 nhom A. + Cach tnh so oxi hoa cua cac nguyen to trong cac phan t va cac ion. + Lap c phng trnh phan ng oxi hoa kh. + Viet c nhng cong thc e va cong thc cau tao cua cac phan t dang n chat va hp chat. - Van dung: - T cau hnh e suy ra v tr va cau tao cua nguyen t va suy ra tnh chat cua nguyen t nguyen to. - Can bang phan ng oxi hoa kh bang phng phap thang bang electron khi biet so oxi hoa cua cac nguyen to trong phan ng.

B. Cau truc e kiem tra HKI:

B.1. Phan chung: Cau 1: (2) Thanh phan nguyen t va Hat nhan nguyen t Cau 2: (2) Cau tao vo nguyen t va cau hnh electron nguyen t Cau 3: (1) Bang tuan hoan va s bien oi tuan hoan cau hnh e cac

nguyen to hoa hoc Cau 4: (2) S bien oi tuan hoan cac nguyen to hoa hoc Cau 5: (1) Lien ket hoa hoc, hoa tr va so oxi hoa B.2. Phan Rieng: C ban: (2 ) Lap phng trnh hoa hoc cua phan ng oxi - hoa kh Nang cao: (2 ) Lap phng trnh hoa hoc cua phan ng oxi hoa kh C. e cng on tap HKI:
E CNG ON TAP KHOI 10 MON: HOA (HKI: 2008-2009)

Chng I: I. Ly Thuyet: Thanh phan nguyen t va Hat nhan nguyen tCau tao vo nguyen t va cau hnh electron nguyen t 1) Trong nguyen t gom co nhng hat c ban nao? Nhng hat o co ien tch va khoi lng la bao nhieu? 2) Cach viet ky hieu hoa hoc cua 1 nguyen t.

3)Cach tnh so p, n, e da vao ky hieu hoa hoc cua nguyen t va tnh gia tr A . 4)Th t mc nang lng cua cac phan lp electron c viet nh the nao? 4)So electron toi a trong 1 phan lp va trong 1 lp. 5)Viet cau hnh electron cua 20 nguyen to au tien trong bang tuan hoan. II. Bai Tap: 1) Hay tnh so p, n, e cua cac nguyen t co ky hieu hoa hoc 24 35 Mg ; 17 Cl . sau ay: 12 2) Cho 1 nguyen t S co cac hat: p=16, n=16. Nguyen t S c ky hieu nh the nao? 65 63 Cu va 29 Cu . NTK TB cua Cu la 63,54. 3) ong co hai ong v ben: 29 Tnh thanh phan phan tram so nguyen t cua moi ong v. 4) Cho biet so e toi a cua cac phan lp s, p, d , f la bao nhieu? 5)Lp th N co toi a bao nhieu electron? 6)Hay viet cau hnh e cua cac nguyen t co so hieu nguyen t lan lt bang: 11, 15, 17, 19. 7)Nguyen t A cocau hnh e phan lp ngoai cung la: 3s 1. Hay viet cau hnh e ay u cua A. Chng II: I. Ly Thuyet:Bang tuan hoan va s bien oi tuan hoan cau hnh e cac nguyen to hoa hoc-S bien oi tuan hoan cac nguyen to hoa hoc 1) Nhng nguyen tac sap xep cac nguyen to vao bang tuan hoan. 2)Chu k la g? Nhom nguyen to la g? ac iem cua chu k va nhom nguyen to (nhom A) 3)ac iem cua electron lp ngoai cung cho ta biet ieu g? 4)S bien thien tnh chat cua cac nguyen to trong 1 chu k va 1 nhom A 5)Tm hoa tr cao nhat cua cac nguyen to khi tao hp chat vi Oxi va hiro. 6)Viet cong thc oxit va hiroxit tng ng. 7)So sanh tnh axit, baz cua cac oxit va hiroxit trong cung 1 chu k va cung 1 nhom A 8)Tm v tr cua cac nguyen to trong bang tuan hoan khi biet cau hnh e hay so th t nguyen to 9)T v tr suy ra cau tao va tnh chat cua 1 nguyen t nao o II. Bai Tap: 1) Cho 2 nguyen t P(z=15) va S(z=16).

-Tm hoa tr cao nhat cua P vi O va H. Hoa tr cao nhat cua S vi O va H. -Viet cong thc oxit va hiroxit tng ng cua 2 nguyen to tren ( neu co) - Tm v tr va cau tao cua 2 nguyen to tren trong bang tuan hoan -Hai nguyen to tren co tnh chat g: KL, PK hay kh hiem? 2) Nguyen t A co cau hnh e la: 1s2 2s2 2p6 3s2 3p4 -Cho biet v tr cua A trong bang tuan hoan. - Cho biet cau tao cua A va tm hoa tr cao nhat cua A vi H va O ( neu co) - Viet cong thc oxit va hiroxit tng ng cua A (neu co). 3) Hp chat kh cua 1 nguyen to R vi H la RH 4. Hp chat cua no vi O co 53,3%O ve khoi lng. Tm NTK cua R. Chng III: I. Ly Thuyet:Lien ket hoa hoc, hoa tr va so oxi hoa 1) The nao la ion, ion dng , ion am? Viet phng trnh hnh thanh ion cua chung 2) Lien ket CHT va LK ion la g? Tnh chat chung cua hp chat co lien ket CHT va hp chat co LK ion? 3) Viet cong thc electron cua nhng phan t co LK CHT 4) Xac nh hoa tr cua cac nguyen to trong hp chat ion va hp chat CHT? 5) Cac quy tac xac nh so oxi hoa. 6) da vao cac quy tac xac nh so oxh tnh so oxi hoa cua cac nguyen to trong phan t n chat, phan t hp chat, ion n nguyen t, ion a nguyen t. II. Bai Tap: 1) Viet phng trnh hnh thanh ion cua cac nguyen t: Na(z=11); Mg(z=12); S(z=16); Cl(z=17) 2) Cho cac ion: 11 Na + ; 16 S 2 . Viet cau hnh e cua cac ion va tnh so p, n, e cua cac ion. 3)Hay viet cong thc electron va cong thc cau tao cua cac phan t: H2O; H2S; CH4; NH3; N2; CO2; HCl; C2H4. 4) Tnh so oxi hoa cua cac nguyen to trong cac ion va phan t sau ay: NO2; NO3-; HNO3; H2SO4; KMnO4; HClO4; K2Cr2O7; KClO3; NH4+, SO42-; Fe2+. Chng IV: I. Ly Thuyet: Phan ng oxi hoa- kh 1) Cac khai niem: chat oxh, chat kh, qt oxh, qt kh la g? 2) Lap phng trnh hoa hoc cua phan ng oxh kh bang phng phap thang bang electron. II. Bai Tap:

*** Cho cac phng trnh phan ng: a) Cu + HNO3(loang) Cu(NO3)2 + NO + H2O t C b) NH3 + CuO Cu + N2 + H2O t C c) MnO2 + HCl MnCl2 + Cl2 + H2O t C d) P + HNO3 (ac) H3PO4 + NO2 + H2O lanh e) Mg + HNO3 (loang) Mg(NO3)2 + NH4NO3 + H2O t C g) SO2 + Br2 + H2O H2SO4 + HBr - Hay xac nh chat oxi hoa va chat kh cua cac phng trnh phan ng tren - Hay can bang cac ptp tren bang phng phap thang bang electron.
o o o o

D. Ma tran e kiem tra:

NOI DUNG BIET Cb Nc Cb HIEU Nc VAN DUNG Cb Nc
0,5(c.1 b) 0,5(c.1 b)

TONG Cb Nc 2 2

Thanh phan nguyen t 0,5(c.1 0,5(c.1 1(c.1a) 1(c.1a) b) b) va Hat nhan nguyen t Cau tao vo nguyen t 0,5(c.2 0,5(c.2 va cau hnh 1(c.2b) 1(c.2b) a) a) electron nguyen t Bang tuan hoan va s bien oi 0,5(c.3 0,5(c.3 0,5(c.3 0,5(c.3 tuan hoan a) a) b) b) cau hnh e cac nguyen to hoa hoc S bien oi tuan hoan 0,5(c.4 0,5(c.4 1(c.4b) 1(c.4b) cac nguyen b) b) to hoa hoc Lien ket hoa hoc, 0,5(c.5 0,5(c.5 hoa tr va a) a) so oxi hoa Phan rieng (c ban): P 1 1 oxh-kh Phan rieng (NC): P oxh1 1 kh Tong: 4 4 4 4 E. Noi dung e:

0,5(c.2 c)

0,5(c.2 c)

0,5(c.4 a) 0,5(c.5 b)

0,5(c.4 a) 0,5(c.5 b)

2 2 2 2 10 10

E.1. PHAN CHUNG: (8 iem) Cau I: (2iem) Cho cac nguyen t co k hieu hoa hoc la: 24 19 12 Mg , 9 F . Hay tm so proton, electron va ntron cua cac nguyen t tren. Cau II: (2 iem) Cho nguyen t A (Z=11): a) Viet cau hnh electron cua nguyen t A. b) Nguyen t A la kim loai, phi kim hay kh hiem? Tai sao? c) Tnh so electron tren tng lp cua nguyen t A.

Cau III: (1 iem)Cau hnh electron phan lp ngoai cung cua nguyen t B la : 2p3. a) Hay cho biet v tr cua nguyen t B trong bang tuan hoan. b) Tm hoa tr cao nhat cua nguyen t B vi Oxi va cong thc oxit tng ng. Cau IV: (2 iem) Cho day cac nguyen to: Al(Z=13) , Na(Z=11), Mg(Z=12). a) Hay sap xep theo chieu tang tnh kim loai cua cac nguyen to tren. b) Viet cong thc oxit tng ng cua cac nguyen to tren. Cau V: (1 iem) Cho cac phan t : CO2 , NH3. a) Tnh so oxi hoa cua N va C trong cac phan t tren. b) Viet cong thc electron cua cac phan t tren. B. PHAN RIENG: (2 iem) Cau VI: BAN C BAN (2 iem) Cho m gam Cu vao dung dch HNO3 (loang) d thu c Cu(NO3)2 , H2O va 6720 ml kh NO (ktc). a) Can bang phng trnh phan ng tren bang phng phap thang bang electron. b) Hay cho biet gia tr m bang bao nhieu ? Cau VII: BAN NANG CAO (2 iem) Cau VIIa: (1 iem) Hay can bang phng trnh phan ng sau ay bang phng phap thang bang electron: FeS 2 + O2 t C SO2 + Fe2O3 . Cau VIIb: (1 iem) Cho m gam Cu vao dung dch HNO3 (loang) d thu c Cu(NO3)2 , H2O va 6720 ml kh NO (ktc). Tnh gia tr m. (Cho: Cu=64; H=1; O=16; N=14; )
0

D. ap an: D.1: Phan chung: Cau hoi Cau I: 2 a)

19 9 24 12

ap an
Mg : co p=12, e=12

iem tng phan 0,5 0,5 0,5 0,5 1 0,5 0,5

Cau II: 2

: co p=9, e=9 24 Mg : b) 12 n=12 19 n= 19-9=10 9F : a) Cau hnh electron cua A(z=11): 1s2 2s2 2p6 3s1. b) A la kim loai (do co 1e lp ngoai cung) c) lp K( th 1): co 2 e lp L (th 2) : co 8 e lp M (th 3): co 1e
F

Cau III: a) V tr cua B o th 7, chu k 2, nhom VA. 1 b) Hoa tr cao nhat cua B vi Oxi la: 5 Cong thc oxit cao nhat cua B vi oxi la: N 2O5. Cau a) chieu tang tnh kim loai theo th t la: Al < Mg IV: < Na 2 b) Cong thc oxit tng ng la: Na2O, MgO, Al2O3. Cau V: a) so oxi hoa cua N trong NH3 la: -3 1 so oxi hoa cua C trong CO2 la: +4 b) Cong thc electron cua NH3 la:

0,5 0,25 0,25 0,5 1,5 0,25 0,25 0,25 0,25

H N H H
Cau VI 2

O C O

Cong thc electron cua CO2 la: a) Can bang ptp sau ay bang phng phap thang bang electron: +5 0 +2 Cuo + H N O3 (loang) Cu (NO3)2 + N O + H2O. Qua trnh Oxi hoa:
Cu Cu + 2e
+5 +2 0 2+

0,25 0,5 0,25 0,25 0,25

x3

Qua trnh kh: x2 N +3e N at he so vao ta co ptp la: +5 0 +2 3Cuo + 8 H N O3 (loang) 3 Cu (NO3)2 + 2 N O + 4 H2O. b) VNO= 6,7 lt nNO =
6, 72 = 0,3 mol 22, 4
+5 0 +2

ptp: 3Cuo + 8 H N O3 (loang) 3 Cu (NO3)2 + 2 N O + 4 H2O. (mol) 0,45 mol. 0,3 mol nCu= nNO = 1,5 x0,3 = 0, 45 mol => mCu=n.M=0,45 x 64= 28,8 gam. Cau VII Cau VII a: Can bang phng trnh phan ng sau 2 bang phng phap thang bang electron: +2 1 0 +4 +3 Fe S 2 + O 2 S O2 + Fe 2 O3 . 2 Fe+3 + 4S+4 + 22 e Qua trnh Oxh: 2 FeS2 x 2 0 Qua trnh kh: O 2 + 4 e 2 O-2 x 11 at he so vao phng trnh ta co: 4 FeS2 + 11 O2 8 SO2 + 2 Fe2O3 .
3 2

0,25 0,25

0,25 0,5

0,25 0,25

Cau VII b: VNO= 6720ml= 6,7 lt nNO =

6, 72 = 0,3 mol 22, 4
+5 0 +2

0,25 0,25 0,25

ptp: 3Cuo + 8 H N O3 (loang) 3 Cu (NO3)2 + 2 N O + 4 H2O. (mol) 0,45 mol. 0,3 mol nCu= nNO = 1,5 x0,3 = 0, 45 mol => mCu=n.M=0,45 x 64= 28,8 gam.
3 2

GV ra e Duyet cua To Trng (ky ten)

(a ky)

Nguyen Th Hong Nng Nguyen Van Tuan

S GD va T ong Thap Trng THPT Tam Nong E KIEM TRA CHAT LNG HKI

-------------------------

Nam hoc: 2008-2009 Mon: Hoa Hoc Khoi: 10 Thi gian: 45 Phut (khong ke thi gian

phat e) A. PHAN CHUNG: (8 iem) Cau I: (2iem) Cho cac nguyen t co k hieu hoa hoc la: 24 19 12 Mg , 9 F . Hay tm so proton, electron va ntron cua cac nguyen t tren. Cau II: (2 iem) Cho nguyen t A (Z=11): a) Viet cau hnh electron cua nguyen t A. b) Nguyen t A la kim loai, phi kim hay kh hiem? Tai sao? c) Tnh so electron tren tng lp cua nguyen t A. Cau III: (1 iem)Cau hnh electron phan lp ngoai cung cua nguyen t B la : 2p3. a) Hay cho biet v tr cua nguyen t B trong bang tuan hoan. b) Tm hoa tr cao nhat cua nguyen t B vi Oxi va cong thc oxit tng ng. Cau IV: (2 iem) Cho day cac nguyen to: Al(Z=13) , Na(Z=11), Mg(Z=12). a) Hay sap xep theo chieu tang tnh kim loai cua cac nguyen to tren. b) Viet cong thc oxit tng ng cua cac nguyen to tren. Cau V: (1 iem) Cho cac phan t : CO2 , NH3. a) Tnh so oxi hoa cua N va C trong cac phan t tren. b) Viet cong thc electron cua cac phan t tren. B. PHAN RIENG: (2 iem) Cau VI: BAN C BAN (2 iem) Cho m gam Cu vao dung dch HNO3 (loang) d thu c Cu(NO3)2 , H2O va 6720 ml kh NO (ktc). a) Can bang phng trnh phan ng tren bang phng phap thang bang electron. b) Hay cho biet gia tr m bang bao nhieu ? Cau VII: BAN NANG CAO (2 iem) Cau VIIa: (1 iem) Hay can bang phng trnh phan ng sau ay bang phng phap thang bang electron: FeS 2 + O2 t C SO2 + Fe2O3 . Cau VIIb: (1 iem) Cho m gam Cu vao dung dch HNO3 (loang) d thu c Cu(NO3)2 , H2O va 6720 ml kh NO (ktc). Tnh gia tr m.
0

(Cho: Cu=64; H=1; O=16; N=14; ) -----------------------Het-----------------------