HOA HOC 11: Bai tap ANKEN

Trng THPT Tan Chau

PHN I: BI TP T LUN DNG 1: NG PHN DANH PHP - PTHH Bi 1:Vit CTCT v gi tn cc ng phn ca: C4H8 v C5H10 Bi 2:Nhng hp cht no trong s cc hp cht sau y c ng phn cis-trans a/2-brom-3-clobut-2-en b/1-brom-1-clo-2-metylprop-1-en c/CH3CH=CH2 d/CH3CH=CHCl Bi 3:Vit phn ng trng hp ca cc cht cho di y: a/CH2=CH2 b/CH2=C(CH3)2 c/CH2=CHCl d/CF2=CF2 e/CH(CH3)=CH(CH3) f/CH(CH2Br)=CH(CH2Br) g/CH2=CH(CH=CH2) Bi 4:Vit phng trnh biu din bin ha sau: a/hecxan butan etilen etylclorua etilen PE b/C3H7OH C3H6 C3H8 C2H4 C2H4(OH)2 c/ vi vi sng canxicacbua axetilen etilen etanol H 2 SO4 H 2 / Ni d/C2H5OH A (B) +Cl2, askt HCl (C) Bi 5:Hon thnh cc phng trnh phn ng v gi tn cc sn phm to thnh: a/CH2=CH2+HBr .. b/CH2=CH2+.. CH3CH2-OH H 2 SO4 . c/CH3-CH=CH2+HI . d/CH3-CH2-CH2-CH2-OH 1800 C
H 2 SO4 H 2 SO4 .. e/CH3-CH(OH)-CH2-CH3 f/(CH3)3C-OH 1800 C 1800 C Bi 9:a/Mun iu ch n-pentan CH3(CH2)3CH3 ta c th hiro ha nhng anken no? Vit CTCT ca chng b/Vit phng trnh phn ng iu ch cc hp cht sau y t nhng anken thch hp 1/CH3CHBr-CHBrCH3 2/CH3CHBr-CBr(CH3)2 3/CH3CHBr-CH(CH3)2

DNG 2: XC NH CTPT V CNG THC CU TO Bi 7:Khi t mt th tch hirocacbon A cn 6 th tch Oxi v sinh ra 4 th tch CO 2, A c th lm mt mu nc Brom v kt hp vi hiro to ra mt hirocacbon no mch nhnh. Xc nh CTCT ca A v vit cc phng trnh phn ngs: C4H8 Bi 10:Cho hai hrocacbon A v B u th kh. A c cng thc C 2xHy; B c cng thc CxH2x (tr s x trong hai cng thc bng nhau). Lp CTPT ca A v B; bit rng t khi ca A i vi khng kh bng 2 v t khi ca B i vi A l 0,482. Vit CTCT cc ng phn ca A v B v gi tn chng? B:C2H4; A:C4H10 Bi 11: hiro ha hon ton 0,7 g mt olfin cn dng 246,4 cm 3 hiro ( 27,30C v 1 atm). Xc nh CTPT v CTCT bit rng olfin c cu to mch thng? s:C5H10 Bi 15:t chy hon ton 0,25 mol kh A thu c 33g CO2 v 13,4g H2O a/Tm CTPT v CTCT ca A bit rng iu kin chun khi lng ring ca A l 1,875g/l b/Tm lng dung dch KMnO4 40% c th b mt mu va bi lng cht A trn? s:C3H6 Bi 16:C mt ng ng ca etilen 0,21 hirocacbon kt hp c vi 0,8g brom. Xc nh CTCT ca hirocacbon v cho bit nu thay brom bng clo th phi dng ht bao nhiu cm3 clo (kc) Bi 17:Mt hn hp X gm hai lfin ng ng k tip nhau c th tch 17,92 lt (o 0 0C v 2,5 atm) sc qua bnh ng KMnO4 d khi lng bnh tng 70g a/Vit cc phng trnh phn ng xy ra? b/Xc nh CTPT , CTCT ca hai lfin ? c/t chy hon ton th tch trn ca hn hp X ri cho sn phm vo 5 lt dung dch NaOH 1,8M s thu c mui g ? bao nhiu gam? s:C2H4; C3H6; 84g NaHCO3; 424g Na2CO3 Bi 18:A v B l hai anken k tip nhau trong dy ng ng. Cho 13,44 lt hn hp trn qua mt bnh ng dung dch brom d thy bnh tng thm 28g a/Xc nh CTPT vit CTCT ca hai anken (c th c) b/Cho hn hp hai anken tc dng vi HCl th thu c ti a 3 sn phm. Xc nh CTCT ca hai anken v gi tn ca chng s:propen; buten-2
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Bi 19:Cho 3,36 lt hn hp gm mt ankan v mt anken i qua nc brom thy c 8g brom tham gia phn ng. Khi lng ca 6,72 lt hn hp l 13 gam a/Xc nh CTPT ca hai hirocacbon b/t chy 3,36 lt hn hp th thu c bao nhiu lt kh CO2 v bao nhiu gam nc s:a/c 3 cp: C7H14 v CH4; C5H10 v C2H6; C3H6 v C3H8 b/10,08g CO2 v 9,9g H2O Bi 20:Mt hn hp mtan v olfin A c th tch l 10,8 lt (kc) cho qua mt bnh ng dung dch brom d thu c mt kh, em t chy hon ton thu c 5,5g CO2. Bnh ng brom tng 10g a/Tnh thnh phn % th tch cc kh trong hn hp u? b/Tm CTPT ca A c/Tnh lng cht to thnh trong dung dch brom khi cho hn hp i qua ? s:25,93% CH4; 74,07% A; b/ C2H4 c/67,14g Bi 21:Xc nh CTPT v CTCT ca tt c cc ng phn ca cc anken X, Y, Z, T bit rng: a/10,5 g X phn ng va vi 150 g dung dch Br2 40% b/Hir ha hon ton 1,4 gam Y cn dng va 492,8 cm3 H2 (o 27,30C v 1atm) c/1,05 gam Z phn ng va vi dung dch KMnO4 cho 1,9 gam ancol 2 chc d/12,6 gam T phn ng va vi 75,84gam dung dch KMnO4 25% s:X:C2H4; Y:C5H10; Z:C3H6; T:C5H10 Bi 22:Cho 0,74g hn hp A gm mtan v mt anken li t t qua bnh nc brom d thy khi lng bnh tng thm 0,42g ng thi th tch hn hp kh A gim 1/3 a/Xc nh CTPT anken? b/Tnh t khi ca hn hp A i vi khng kh s:a/C3H6 b/0,85 Bi 23:t chy 8,96 lt hn hp X gm hai olfin A v B ng ng k tip th thy khi lng CO 2 ln hn khi lng H2O l 39 gam a/Xc nh CTPT ca A v B b/Tnh % theo th tch hn hp X s:A:C3H6(25%); B:C4H8(75%) Bi 24:2,36 gam hn hp 2 ankan A v B l ng ng k tip nhau c t chy hon ton thu c 3,96g H2O a/Tm CTPT v CTCT ca A v B b/Cho 31,36 lt hn hp (kc) gm A v B v etilen i qua bnh cha dung dch nc brom d thy tng khi lng ca bnh l 7,84g. t chy sn phm sau khi sau khi qua bnh brom dn kh sinh ra qua dung dch Ca(OH)2 thu c 120g mui trung tnh v 140,94g mui axit 1/Tnh thnh phn % th tch ca hn hp u 2/Tnh t khi hi ca hn hp ban u i vi nit? s:A:C2H6(30%); B:C3H8(50%);1,307 Bi 25:t chy hon ton 2,24lt kh C 2H4 (kc) ri hp th ton b sn phm vo dung dch cha 11,1 gam Ca(OH)2. Hi sau khi hp th khi lng phn dung dch tng hay gim bao nhiu gam? s:tng 2,4 gam Bi 26:t chy hon 1 hirocacbon A sinh ra 16,8 lt CO 2 (kc) v 13,5 gam H2O. 1g kh A c cng th tch vi 0,761 gam Oxi trong cng iu kin a/Xc nh CTPT v CTCT ca A bit A c cu to mch h b/Cho 1 lt hn hp gm hirocacbon trn v hiro qua bt Ni nung nng. Hn hp kh sn phm sau khi dn qua bnh cha dung dch brom d th cn li mt hirocacbon duy nht ng thi bnh cha dung dch nng thm 0,21g. Tnh thnh phn % ca hn hp hai cht u? s:C3H6(55,6%) H2(44,4%) Bi 27:Hn hp A v B l hai anken c khi lng 12,6g trn theo t l 1:1 v s mol tc dng va vi 32g brom Nu trn hn hp trn theo t l 1:1 v khi lng th 16,8g hn hp tc dng va vi 0,6g H 2 . Tm CTPT ca A v B bit MA<MB ? s:A:C3H6; B:C6H12

DNG 3: BI TP V PHN NG CRCKINH Bi 1: Nhit phn metan thu c hn hp X gm C2H2 ; CH4 ; H2. T khi ca X so vi H2 bng 5. Tm hiu sut ca qa trnh nhit phn. Bi 2 : Crackinh C4H10 thu c hn hp gm 5 hirocacbon c KLPT trung bnh bng 36,25. Xc nh hiu sut ca phn ng crackinh. Bi 3 : Crackinh C4H10 thu c hn hp ch gm 5 hirocacbon c t khi hi so vi H2 l 16,325. Xc nh hiu sut ca phn ng crackinh.
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Bi 4: Crackinh mt ankan thu c hn hp kh c t khi hi so vi H2 bng 19,565. Bit hiu sut ca phn ng Crackinh l 84%. Xc nh ankan cho. Bi 5: Khi crackinh ton b mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12 . Xc nh CTPT ca X Bi 6: Crakinh hon ton mt ankan khng phn nhnh X thu c hn hp kh Y c t khi hi i vi H2 l 18. Xc nh CTCT ca X. Bi 7: Craking 40 lt butan thu c 56 lt hn hp A gm H2, CH4 ,C2H4 ,C2H6 ,C3H6 , C4H8 v mt phn butan cha b craking (cc th tch kh o cng iu kin nhit v p sut). Xc nh hiu sut phn ng to hn hp A. Bi 8: Crackinh 560 lt C4H10 thu c 1010 lt hn hp kh X khc nhau. Bit th tch cc kh u o (ktc). Tm th tch C4H10 cha b cracking v hiu sut ca phn ng cracking. Bi 9: Crackinh 5,8 gam C4H10 c hn hp kh X. Tm khi lng nc thu c khi t chy hon ton hn hp X. Bi 10: Craking m gam butan thu c hp A gm H2, CH4, C2H4, C2H6, C3H6, C4H8 v mt phn butan cha b craking. t chy hon ton A thu c 9 gam H2O v 17,6 gam CO2. Xc nh gi tr ca m. Bi 11: Khi tin hnh craking 22,4 lt kh C 4H10 (ktc) thu c hn hp A gm CH 4, C2H6, C2H4, C3H6, C4H8, H2 v C4H10 d. t chy hon ton A thu c x gam CO2 v y gam H2O. Xc nh cc gi tr ca x v y. DNG 4: XC NH % CC CHT V CC GI TR KHC Bi 6:Cho etilen vo bnh cha brom lng to ra 1,2-ibrometan 1/Tnh th tch etilen (kc) tc dng vi brom bit rng sau khi cn li thy bnh brom tng thm 14g 2/Tnh khi lng brom c th kt hp vi 3,36 lt etilen (kc) s:11,2 lt; 24g Bi 8:Cho 3 lt hn hp etan v etilen (kc) sc vo dung dch brom ngi ta thu c 4,7g 1,2-ibrometan a/Vit phng trnh phn ng xy ra b/Tnh thnh phn hn hp theo khi lng v theo th tch gi thit rng phn ng xy ra hon ton Bi 12:Cho 2,24 lt hn hp kh A (kc) gm etan, propan, propilen sc qua dung dch Brom d thy khi lng bnh tng thm 2,1g .Nu t chy kh cn li s thu c mt lng CO2 v 3,24g H2O a/Tnh thnh phn % th tch mi kh b/Dn lng CO2 ni trn vo bnh ng 200ml dung dch KOH 2,6M. Hy xc nh nng mol/lt cc cht trong dung dch sau phn ng? s:C2H6(20%); C3H8(30%); K2CO3 0,65M; KOH1,3M Bi 13:Ngi ta mun iu ch 21 g etilen: a/Tnh khi lng ancol etylic nguyn cht phi dng nu hiu sut 100% b/Tnh th tch etan (kc) phi dng nu hiu sut l 80%?s:34,5g; 21 lt Bi 14:Sau khi tch hiro hn hp etan v propan to thnh hn hp etilen v propilen. Khi lng phn t trung bnh ca hn hp etilen v propilen nh hn khi lng phn t trung bnh ca hn hp u l 6,55%. Hy xc nh thnh phn % theo th tch ca hn hp u? s:C2H6(96,18%); C3H8(3,82%) PHN ANKEN Cu 1 : Anken l : A. Hidro cacbon khng no, mch h, c 1 lin kt i trong phn t. B. Hidro cacbon khng no, mch h. C. Hidro cacbon khng no, mch h, c 1 lin kt trong phn t. D. A v C Cu 2 : Mtan c tp cht C2H4. loi tp cht c th dng : A. H2O B. Nc brom. C. dung dch KMnO4 D. B v C Cu 3 : phn bit 4 kh : CH4, C2H4 , CO2, SO2. Cc thuc th v th t dng l : A. Qu tm, nc brm. B. Nc brm, qy tm. C. Nc vi trong, dd KMnO4 D. C A, B, C.
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Cu 4 : Cht hu c A c cng thc C4H8. S ng phn ng vi CTPT ca A (k c ng phn cis-trans) l : A. 4 B. 5 C. 6 D. 7 Cu 5 : Anken C5H10 c s ng phn (k c ng phn cis-trans) l : A. 4 B. 5 C. 6 D. 7 Cu 6 : Trong cc cht : propen (I) ; 2-metyl but-2-en (II) ; 3,4-dimetyl hexen-3 (III) ; 3-clo propen-1 (IV) ; 1,2-diclo eten (V), cht no c ng phn hnh hc : A. III, V B. II, IV C. I, II, III, IV D. I, V Cu 7 : Etilen iu ch trong phng th nghim thng ln cc cht SO2, CO2. Chn 1 trong cc cht sau loi b tp cht : A. dung dch brom d B. dung dch NaOH d C. dung dch Na2CO3 d D. dung dch KMnO4 d Cu 8 : Khi cng HCl vo propen, sn phm chnh thu c l : A. 1-clo propan B. 2-clo propan C. 3-clo propen-1 D. Tt c sai Cu 9 : Cht X : CH3-CHBr-CH(CH3)2 c iu ch t anken no sau y c hiu sut cao nht : A. CH3-CH=C(CH3)2 B. CH2=CH-CH(CH3)2 C. CH3-CH2-C(CH3)=CH2 D. A, B, C c hiu sut nh nhau Cu 10 : Mun iu ch n-pentan c th thc hin phn ng hidro ho nhng anken no ? A. CH3-CH2-C(CH3)=CH2 B. CH2=CH-CH2-CH2-CH3 C. CH3-CH=CH-CH2-CH3 D. B v C Cu 11 : 4 cht, Y, Y, Z, T u l cht kh iu kin thng. Khi phn hu mi cht thnh C v H2 th th tch H2 u bng 3 ln th tch hidrocacbon ban u. X, Y, Z, T ln lt l : A. C2H6 ; C2H4 ; C3H6 B. CH4 ; C2H4 ; C3H8 C. C2H6 ; C3H6 ; C4H6 D. C3H6 ; C4H6 ; C6H6 Cu 12. Phng php no sau y l tt nht phn bit kh CH4 v kh C2H4 ? A. Da vo t l v th tch kh O2 tham gia phn ng chy. B. S thay i mu ca dung dch nc brom. C. So snh khi lng ring. D. Phn tch thnh phn nh lng ca cc hp cht. Cu 13. t chy s mol nh nhau ca 2 hirocacbon mch h thu c s mol CO 2 nh nhau, cn t l s mol H2O v CO2 ca chng tng ng l; 1: 1,5. CTPT ca chng l: A. C2H6 v C2H4 B. C3H8 v C3H6 C. C4H10 v C4H8 D. C5H12 v C5H10 a Cu 14. t chy hn hp gm mt ankan v mt anken thu c a mol H 2O v b mol CO2. T s T = c b gi tr l: A. T = 1 B. T = 2 C. T < 2 D. T > 1 Cu 15 : Trong phn t anken, hai nguyn t cacbon mang ni i trng thi A. lai ho sp B.lai ho sp2 C.lai ho sp3 D.khng lai ho. Cu 16 : Hai nhm nguyn t lin kt vi nhau bi lin kt i C = C khng quay t do c quanh trc lin kt, do b cn tr bi A. lin kt n. B. lin kt i. C. lin kt . D. lin kt Cu 17 : phn t etilen : A. hai nguyn t C v hai nguyn t H v tr trans vi nhau nm trn mt mt phng, hai nguyn t H cn li nm trn mt phng khc. B. hai nguyn t C v hai nguyn t H v tr cis vi nhau nm trn mt mt phng, hai nguyn t H cn li nm trn mt mt phng khc. C. hai nguyn t C v bn nguyn t H u cng nm trn mt mt phng. D. hai nguyn t C nm trn mt mt phng, cn bn nguyn t H li nm trn mt mt phng khc. Cu 18 : C bao nhiu ng phn anken cng c cng thc phn t C5H10 ? A. 2 B. 3 C. 5 D. 6 Cu 19 : Anken sau y c ng phn hnh hc : A. pent-1-en. B.pent-2-en. C. 2-metylbut-2-en. D.3-metylbut-1-en. Cu 20. Hirocacbon c cng thc phn t C4H8 c s ng phn l : A. 3 B. 4 C.5 D.6 Cu 21. S ng phn anken c cng thc phn t l C5H10 m c ni i C = C gia mch l : A. 1 B.2 C.3 D.4
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Cu 22. Ch ra ni dung sai : A. Cc anken u nh hn nc. B. Anken v du m ho tan tt ln nhau. C. Anken l nhng cht c mu. D. Lin kt i C = C l trung tm phn ng gy ra nhng phn ng c trng cho anken. Cu 23. Olefin c tnh cht : A. Lm mt mu brom trong nc, khng lm mt mu brom trong CCl4. B. Lm mt mu brom trong CCl4, khng lm mt mu brom trong nc. C. Lm mt mu brom trong H2O, cng nh trong CCl4. D. Khng lm mt mu brom trong H2O, cng nh trong CCl4. Cu 24. S ng phn mch h (k c ng phn cis trans ) ng vi cng thc C4H8 l : A. 4 B. 5 C. 6 D. 7 Cu 25. Mt hidrocacbon c cng thc :CH2=C(C2H5)-CH3 c tn theo danh php h thng l: A. 2-etyl prop-1-en B. 3-metyl but-2-en C. 2-metyl but-1-en D. 2-metyl but-2-en Cu 26. Xt cc loi phn ng sau :(1) chy (2) th (3) cng (4) trng hp . Loi phn ng no ch xy ra vi etilen m khng xy ra vi etan? A. (1) v (2) B. (2) v (3) C. (3) v (4) D. (1) v (4) Cu 27. C cc cht n-butan, propen, vinylclorua, but-2-en. S cht c th trng hp c l : A. 1 cht B. 2 cht C. 3 cht D. 4 cht Cu 28. Mt hidrocacbon mch h A cng vi HCl thu c sn phm chnh c CTCT l : CH3-CH(Cl)-CH(Cl)-CH3 . Tn gi ca A l: a.pent -2-en b.3-metyl but-1-en c.3-metyl but-2-en d.tt c u sai . Cu 29. Mt hn hp X gm hai anken (ktc) hidrat ha cho hn hp Ych gm hai ru .X l : A. Etilen v propilen B. Etilen v but-1-en C. Etilen v but -2-en D. Propilen v but-2-en Cu 30. Anken no c ng phn cis-trans ? 1. 2,3-dimetyl pent-2-en 2. 2,3-dimetyl pent-1-en 3. 3,4-dimetyl pent-2-en 4. 3,4-dimetyl pent -1-en A. 1 v 3 B. 1 v 4 C. A D. C Cu 31. Ba anken ng ng k tip c tng khi lng l 126 . Ba anken l : A. C2H4 ,C3H6, C4H10 B. C3H6, C4H8, C5H10 C. C2H4, C3H6, C4H8 D. C3H6, C3H8, C4H8. Cu 32.Cht c ph ln cho khng dnh c cng thc l: A. CF2=CF2 b.-(CH2-CH2)C. CCl2-CCl2 d.-(CF2-CF2)-n Cu 33. Cho hidrocacbon X tc dng vi Cl 2 c sn phm hu c duy nht C 2H4Cl2. Hidrocabon Y tc dng vi clo c hn hp hai sn phm c cng cng thc C2H4Cl2 .CTPTca X v Y tng ng l : A. C2H4v C2H6 B. C2H4 v C2H2 C. C2H2 v C2H6 D. C2H2 v C2H4 Cu 34.Chn ng sn phm A ca phn ng sau: 3CH2=CH-CH3+2KMnO4 +2H2O 3A + 2MnO2 +2KOH A. C3H6(OH)2 B. C3H7OH C. C3H6OH D. a v c u ng Cu 35: Cho anken c tn gi sau: 2,3,3 trimetylpent 1 en. CTPT ca anken l: A. C8H14 B. C7H14 C. C8H18 D. C8H16 Cu 36: Cho anken c tn gi sau: 2 metylbut 2 en. CTCT ca anken l: A. (CH3)2 CHCH=CH2 B. CH3CH = C(CH3)2 C. CH3CH = CHCH2CH3 dCH3CH=CHCH2CH2CH3 Cu 37: Anken A c CTPT l C4H8 c bao nhiu ng phn cu to? A. 2 B. 3 C. 4 D. 5 Cu 38: iu kin anken c ng phn cis trans l: A. anken phi c phn t lng ln B. anken phi c nhnh C. anken phi c nhm th khc nhau D. mi nguyn t C ni i ca anken phi lin kt vi 2 nguyn t hoc hai nhm nguyn t khc nhau. Cu 39: Anken c s ng phn nhiu hn ankan l do: A. Anken c cha lin kt i trong phn t C. Anken c ng phn cis trans
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B. Anken c cu to phc tp hn D. Anken c cha lin kt pi trong phn t. Cu 40:Mt anken c CTCT sau:CH3 CH = C CH CH3 C2H5 CH3 Tn gi theo IUPAC ca anken l: A. 3 etyl-4-metylpent 2-en C. 2-metyl-3etylpent-3-en B. 4-metyl-3-etylpent-2-en D. 3-propylpent -3-en Cu 41: Cu no sau y khng ng khi ni v tnh cht vt l ca anken? A. Nh hn nc C. L nhng cht khng mu B. Tan nhiu trong nc D. Cc anken t C2 n C4 l nhng cht kh. Cu 42: Hn hp kh no sau y khng lm mt mu nc brom? A. CO,CO2,C2H4 B. CH4, C3H8, CO C. C2H6, SO2, N2 D. C3H6, SO3, CH4 Cu 43: Cho bit sn phm chnh ca phn ng sau: CH2 = CH CH2CH3 + HCl ? A. CH3CHClCH2CH3 B. CH2=CHCH2CH2Cl C. CH2ClCH2CH2CH3 D. CH2=CHCHClCH3 Cu 44: Phn ng no sau y c dng iu ch etilen trong phng th nghim? H 2 SO4 dd t 0 , xt CH2 = CH2 + H2O C. CH3CH3 A. CH3CH2OH CH2 = CH2 + H2 >1700 C
t , Pd B. CHCH + H2 D. CH3CH2CH2CH3 CH3 CH3 + CH2 = CH2 CH2 = CH2 Cu 45. Cho hp cht sau (hp cht X) CH 3 CH3CHC = CHCH2CH 3 C2H 5 Tn ca X l A. 4,5-imetylhept-3-en. C. 3,4-imetylhept-4-en. B. 2-etyl-3-metylhex-3-en. D. 5-etyl-4-metylhex-3-en Cu 46. Cht no di y khng c ng phn hnh hc? A. DCH = CHD C. (CH3)2C = C(Br)CH3 B. CH3 CH = CH CH2Cl D. FClC = CBrI Cu 47. Cho 2,3-imetylbut-2-en tc dng vi HBr. Sn phm ca phn ng l A. 2-brom-3,3-imetylbutan C. 2,2-imetylbutan B. 2-brom-2,3-imetylbutan D. 3-brom-2,2-imetylbutan Cu 48. Cho etilen tc dng vi dung dch H2SO4 m c nhit thng. Sn phm hu c thu c l A. CH3CH2OH. C. CH3CH2SO3H. B. CH3CH2OSO3H. D. CH2 = CHSO4H. Cu 49. Cho etilen tc dng vi dung dch H2SO4 long un nng, sn phm chnh l A. CH3CH2OH. C. CH3CH2SO3H. B. CH3CH2SO4H. D. CH2=CHSO4H. Cu 50. Khi cho lung kh etilen vo dung dch brom (mu nu ) th xy ra hin tng g ? A. Khng thay i g. B. To kt ta . C. Si bt kh. D. Dung dch mt mu nu . Cu 51. Qu trnh cng hp lin tip nhiu phn t nh khc hoc tng t nhau to thnh phn t rt ln l phn ng A. trng ngng. B. th. D. trng hp. C. oxi ho kh. Cu 52: 2,8g anken X lm mt mu va dung dch cha 8g Br2. X tc dng vi H2O cho 1 sn phm duy nht. A. But-1-en B. But-2-en C. pent-2-en D. hex-3-en Cu 53. Cho 2,24 lt anken li qua bnh ng dung dch brom th thy khi lng bnh tng 5,6 g. Anken c cng thc phn t l A. C2H4. B. C3H6 C. C4H8. D. C4H10. Cu 54. Cho 1,12 g anken cng hp va vi brom thu c 4,32 g sn phm cng hp. Cng thc phn t ca anken l A. C3H6. B. C4H8. C. C5H10. D. C5H12. Cu 55. Tin hnh phn ng tch nc 4,6 g ancol etylic trong H2SO4 un nng 170C thu c 1,792 lt kh etilen (ktc). Hiu sut ca phn ng l A. 60%. B. 70%. C. 80%. D. 90%. Cu 56: t 2,8g cht A cn 6,72 lt O2 (ktc) cho CO2 v H2O c th tch bng nhau (cng iu kin). 2,8g A phn ng va vi brom tao ra 9,2g sn phm. CTPT ca A l :
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A. C3H6 B. C4H8 C. C5H10 D. C A, B, C Cu 57: Cho 2,24 lt (ktc) hn hp 2 anken lin tip qua bnh ng brom d thy khi lng bnh tng 3,5g. Cng thc phn t ca 2 anken l : A. C3H6 v C4H8 B. C4H8 v C5H10 C. C2H4 v C3H6 D. Tt c u sai Cu 58. Mt hirocacbon chy hon ton trong O2 sinh ra 8,8g CO2 v 3,6g H2O. Cng thc ho hc ca hirocacbon A. CH4 B. C2H2 C. C2H4 D. C6H6 Cu 59. Khi t chy hon ton 2 hirocacbon lin tip trong dy ng ng thu c 16,8 l CO 2 (ktc) v 13,5g H2O. Hai hirocacbon thuc dy ng ng no? A. Ankan B. Anken C. Ankin D. Aren Cu 60. t chy hon ton 2 hirocacbon mch h trong cng dy ng ng thu c 1,12 lt CO 2 (ktc) v 0,9g H2O. Hai hirocacbon thuc dy ng ng no? A . Ankan B . Anken C . Ankin D . Aren Cu 61. Cho hn hp 2 anken c s mol bng nhau i qua dung dch nc brom thy lm mt mu va 200g dung dch Br2 nng 16%. S mol mi anken l: A . 0,05 B . 0,1 C . 0,2 D . 0,15 Cu 62. t chy hon ton hn hp 2 hirocacbon mch h trong cng dy ng ng thu c 11,2 lt CO2 (ktc) v 9g H2O. Hai hirocacbon thuc dy ng ng no? A. Ankan B. Anken C. Ankin D. Aren Cu 63. Cho hn hp 2 anken li qua bnh ng nc Br 2 d thy khi lng bnh nc Br2 tng 8g. Tng s mol ca 2 anken l: A. 0,1 B. 0,05 C. 0,025 D. 0,005 Cu 64. t chy hon ton m gam hn hp gm CH 4, C3H6, C4H10 thu c 17,6g CO2 v 10,8g H2O. m c gi tr l: A. 2g B. 4g C. 6g D. 8g Cu 65. t chy hon ton 0,1 mol hn hp CH4, C4H10 v C2H4 thu c 0,14 mol CO2 v 0,23 mol H2O. Hi s mol ca ankan v anken trong hn hp l bao nhiu? A. 0,09 mol ankan v 0,01 mol anken B. 0,01 mol ankan v 0,09 mol anken C. 0,08 mol ankan v 0,02 mol anken D. 0,02 mol ankan v 0,08 mol anken Cu 66. Mt hn hp gm mt ankan v mt anken c cng s nguyn t C trong phn t v c cng s mol. m gam hn hp ny lm mt mu va 80g dung dch 20% brom trong CCl 4. t chy hon ton m gam hn hp thu c 0,6 mol CO2. Ankan v anken c CTPT l: A. C2H6, C2H4 B. C3H8, C3H6 C. C4H10, C4H8 D. C5H12, C5H10 Cu 67. t chy hon ton hn hp gm 1 ankan v 1 anken. Cho sn phm chy i qua ng 1 ng P 2O5 d v ng 2 ng KOH rn, d thy khi lng ng 1 tng 4,14g; ng 2 tng 6,16g. S mol ankan trong hn hp l: A. 0,06 mol B. 0,09 mol C. 0,18 mol D. 0,03 mol Cu 68. Crckinh 11,6g C4H10 thu c hn hp kh X gm 7 cht kh l: C 4H8, C3H6, C2H4, C2H6, CH4, H2 v C4H10 d. t chy hon ton X cn V lt khng kh ktC. Gi tr ca V l: A. 136 lt B. 145,6 lt C. 112,6 lt D. 224 lt Cu 69. Hn hp kh X gm 1 ankan v mt anken. Cho 1680 ml X li chm qua dung dch Br 2 thy lm mt mu va dung dch cha 4g Br2 v cn li 1120 ml kh. Mt khc nu t chy hon ton 1680 ml X ri cho sn phm chy i vo bnh ng dung dch Ca(OH) 2 d thu c 12,5g kt tA. CTPT cc hirocacbon l: A. CH4, C2H4 B. CH4, C3H6 C. C2H6, C2H4 D. C3H8, C3H6 Cu 70. Hn hp gm mt ankan v mt anken c cng s nguyn t C trong phn t v c cng s mol. Ly m gam hn hp ny lm mt mu va 80g dung dch Br 2 20% trong dung mi CCl4. t chy hon ton m gam hn hp thu c 0,6 mol CO2. CTPT ca ankan v anken l: A. C2H6 v C2H4 B. C3H8 v C3H6 C. C4H10 v C4H8 D. C5H12 v C5H10 Cu 71. Cho 14g hn hp gm 2 anken l ng ng k tip i qua dung dch Br 2 lm mt mu va dung dch cha 64g Br2. 1) CTPT ca cc anken l: A. C2H4, C3H6 B. C3H6, C4H8 C. C4H8, C5H10 D. C5H10, C6H12 2) T l s mol ca 2 anken trong hn hp l: A. 1 : 2 B. 2 : 1 C. 2: 3 D. 1: 1
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Cu 72. Chia hn hp 3 anken: C3H6, C4H8, C5H10 thnh 2 phn bng nhau. t chy phn 1 sinh ra 6,72 lt CO2 ktC. Hiro ho phn 2 ri t chy sn phm. Dn sn phm chy vo bnh ng dung dch Ca(OH) 2 th khi lng kt ta l: A . 29g B . 31g C. 30g D. 32g Cu 73. t chy hon ton 4 hirocabon trong cng mt dy ng dng thu c 10,56g CO 2 v 4,32g H2O. Cc hirocabon ny thuc dy ng dng no? A . Ankan B . Anken C . Ankin D . Aren Cu 74. t chy hn hp gm 3 anken thu c 4,4g CO2. Nu dn ton b sn phm chy vo bnh ng nc vi trong d th khi lng bnh s tng thm l: A . 4,8g B . 5,2g C . 6,2g D . Khng xc nh c Cu75. Mt hn hp gm 1 ankan v 1 anken c t l s mol 1: 1. S nguyn t C ca ankan gp 2 ln s nguyn t C ca anken. Ly a gam hn hp th lm mt mu va dung dch cha 0,1 mol Br 2. t chy hon ton a gam hn hp thu c 0,6 mol CO2. CTPT ca chng l: A . C2H4 v C4H10 B . C3H6 v C6H14 C . C4H8 v C8H18 D . C5H10 v C10H22 Cu 76. t chy hon ton hn hp gm C3H6 v C3H8 c t l s mol l 1:1 thu c 1,2 mol CO 2 v 1,4 mol H2O. Khi lng H2O sinh ra khi t chy C3H8 l: A . 1,44g B . 10,4g C . 14,4g D . 41,4g Cu 77. Cho hn hp 3 anken i qua bnh ng nc brom d, thy khi lng Br 2 tham gia phn ng l 16g. Tng s mol ca 3 anken l: A . 0,1 B . 0,05 C . 0,075 D . 0,025 Cu 78. t chy hon ton 8,96 lt (ktc) hn hp hai anken l ng ng lin tip thu c mg H 2O v (m + 39)g CO2. Hai anken l: A . C2H4 v C3H6 B . C4H8 v C5H10 C . C4H8 v C3H6 D . C6H12 v C5H10 Cu 79. t chy hon ton 0,4 mol hn hp gm 2 anken ng ng lin tip, thu c lng CO 2 nhiu hn lng H2O l 39g. CTPT ca cc anken l: A . C2H4 v C3H6 B . C3H6 v C4H8 C . C4H8 v C5H10 D . C5H10 v C6H12 Cu 80. Cho 10,2 g hn hp A gm CH 4 v 2 anken ng ng lin tip li qua dung dch Br 2 d thy khi lng bnh tng7g, ng thi th tch hn hp A gim i mt na. 1. CTPT cc anken l: A . C2H4 , C3H6 B . C3H6 , C4H8 C . C4H8 , C5H10 D . C5H10 , C6H12 2. Phn trm th tch ca anken c khi lng mol ln hn l: A . 35% B . 30% C . 15% D . 25% Cu 81. Khi crckinh butan thu c hn hp A gm: CH4, C3H6, C2H4, C2H6, C4H8, H2, C4H10 d. t chy hon ton hn hp A ny thu c 8,96 lt CO2 v 13,44 lt CO2 (ktc) v 10,8g H2O. 1. S mol C4H10 mang crckinh l: A . 0,12 B . 0,02 C . 0,2 D . 0,21 2. Tng s mol CO2 v H2O thu c l: A . 1mol B . 1,2mol C . 1,4mol D . 1,6mol Cu 82.Th tch ca m gam O2 gp 2,25 ln th tch hi ca m gam hidrocacbon X cng iu kin. Diclo ha X ch thu c hai sn phm ng phn.Tn ca X l : A. Neo-pentan B. Propen C. propen D. Iso pentan Cu 83. Trng hp 5,6 lt C2H4 (ktc) nu hiu sut phn ng t 90% th khi lng polime thu c l : A. 7,3g b.6,3g C. 4.3g d.5,3g Cu 84. Mt loi polime c phn t khi l 50000 .H s trng hp ca loi polietilen xp x l : A. 920 B. 1230 D.1529 D. 1786 Cu 85. Mt hn hp gm hai anken c th tch 11,2 lt (ktc ) k tip nhau trong dy ng ng .Khi cho hn hp i qua dung dch brom th thy khi lng bnh brom tng ln 15,4 g . CTPT ca hai anken l : A. C2H4, C3H6 B.C3H6,C4H8 C.C4H8 vC5H10 D. C5H10,C6H12 Cu 86: t chy han ton 4,48 lt C3H6 ( ktc) ri cho sn phm chy i qua bnh ng dung dch nc vi trong c d thy khi lng bnh tng m(g). Gi tr ca m l: A. 37,2 B. 24,8 C. 12,4 D. 26,4 Cu 87: t chy han ton 1 lt hidrocacbon A sinh ra 3 lt CO 2 v 3 lt hi H2O ( cng iu kin). Bit A lm mt mu dung dch thuc tm. Cng thc cu to ca A l: A. CH2 = CHCH3 B. CHC CH3 C. Xiclopropan D. CH3CH2CH3 Cu 88: T khi hi ca hn hp kh gm C 2H6 v C3H6 i vi hidro l 18,6. Thnh phn % th tch ca mi cht trong hn hp l:
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A. 50%; 50% B. 40%; 60% C. 45%; 55% D. 20%; 80% Cu 89. t chy hon ton hn hp gm C3H6 v C3H8 c t l s mol l 1:1 thu c 1,2 mol CO 2 v 1,4 mol H2O. Khi lng H2O sinh ra khi t chy C3H8 l: A . 1,44g B . 10,4g C . 14,4g D . 41,4g Cu 90. Cho hn hp 3 anken i qua bnh ng nc brom d, thy khi lng Br 2 tham gia phn ng l 16g. Tng s mol ca 3 anken l: A . 0,1 B . 0,05 C . 0,075 D . 0,025

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