THPT Phong Chu Lm Thao Ph Th.

Mi chi tit lin h thy Trung 0983173532

GI GII CHI TIT THI TUYN SINH I HC KHI A NM 2013 Mn thi : HA, khi A - M : 374 Cho bit nguyn t khi ca cc nguyn t : H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; P = 31; Ca = 40; Cr = 52, Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag=108; Ba = 137. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1 : Hn hp X gm 3,92 gam Fe, 16 gam Fe 2O3 v m gam Al. Nung X nhit cao trong iu kin khng c khng kh, thu c hn hp cht rn Y. Chia Y thnh hai phn bng nhau. Phn mt tc dng vi dung dch H2SO4 long (d), thu c 4a mol kh H2. Phn hai phn ng vi dung dch NaOH d, thu c a mol kh H2. Bit cc phn ng u xy ra hon ton. Gi tr ca m l A. 5,40 B. 3,51 C. 7,02 D. 4,05 . HD gii : Khi nung X : 2Al + Fe2O3 2Fe + Al2O3 3,92 Fe : 0,1 + = 0,135 56.2 T mol Fe2O3 = 0,1 Rn Y mi phn : Al : m 0,1 du 2.27 bt e : 3nAl(d) + 2nFe = 2.4a (1) v : 3nAl(d) = 2.a (2) Thay (2) vo (1) a = 0,045 T (2) m = 7,02 Cu 2: Trong iu kin thch hp, xy ra cc phn ng sau (a) 2H2SO4 + C 2SO2 + CO2 + 2H2O (b) H2SO4 + Fe(OH)2 FeSO4 + 2H2O (c) 4H2SO4 + 2FeO Fe2(SO4)3 + SO2 + 4H2O (d) 6H2SO4 + 2Fe Fe2(SO4)3 + 3SO2 + 6H2O Trong cc phn ng trn, phn ng xy ra vi dung dch H2SO4 long l A. (a) B. (c) C. (b) D. (d) Cu 3: Trong mt bnh kn cha 0,35 mol C2H2; 0,65 mol H2 v mt t bt Ni. Nung nng bnh mt thi gian, thu c hn hp kh X c t khi so vi H2 bng 8. Sc X vo lng d dung dch AgNO3 trong NH3 n phn ng hon ton, thu c hn hp kh Y v 24 gam kt ta. Hn hp kh Y phn ng va vi bao nhiu mol Br2 trong dung dch? A. 0,10 mol. B. 0,20 mol. C. 0,25 mol. D. 0,15 mol . HD gii : p dng LBT khi lng mX = m(C2H2) + m(H2) = 10,4 g nX = 0,65 mol . mol (C2H2 d) = mol (C2Ag2) = 0,1 mol (C2H2 p) = 0,35 0,1 = 0,25 mol(H2 d) = mol (H2 b) 0,35 = 0,3 mol (H2 p) = 0,35 . Gi x, y ln lt l mol p C2H2 to C2H4 v C2H6 , nn : x + y = 0,25 v x + 2y = 0,35 y = 0,1 , x = 0,15 . Cu 4: iu kin thch hp xy ra cc phn ng sau: (a) 2C + Ca CaC2 (b) C + 2H2 CH4 (c) C + CO2 2CO (d) 3C + 4Al Al4C3 Trong cc phn ng trn, tnh kh ca cacbon th hin phn ng A. (c) B. (b) C. (a) D. (d)

Trang 1

THPT Phong Chu Lm Thao Ph Th.

Mi chi tit lin h thy Trung 0983173532

Cu 5: Ln men m gam glucoz to thnh ancol etylic (hiu sut phn ng bng 90%). Hp th hon ton lng kh CO2 sinh ra vo dung dch Ca(OH)2 d, thu c 15 gam kt ta. Gi tr ca m l A. 15,0 B. 18,5 C. 45,0 D. 7,5. HD gii : Ca ( OH ) 2 Glucozo C6H12O6 2CaCO3 2CO2 + n CaCO 3 100 = 15 g m(Glu) = .180. 2 90 Cu 6: Hn hp X gm Ba v Al. Cho m gam X vo nc d, sau khi cc phn ng xy ra hon ton, thu c 8,96 lt kh H2 (ktc). Mt khc, ha tan hon ton m gam X bng dung dch NaOH, thu c 15,68 lt kh H2 (ktc). Gi tr ca m l A. 29,9 B. 24,5 C. 19,1 D. 16,4. HD gii Tc vi H2O : Ba tan ht (x mol), Al tan 1 phn 4x = 0,4 x = 0,1 mol . Tc dng NaOH c Ba v Al u ht (y mol) x + 1,5y = 0,7 y = 0,4 Cu 7: Khi lng Ag thu c khi cho 0,1 mol CH3CHO phn ng hon ton vi lng d dung dch AgNO3 trong NH3, un nng l A. 10,8 gam B. 43,2 gam C. 16,2 gam D. 21,6 gam HD gii P : CH3CHO 2Ag mol(Ag) = 2 mol(CH3CHO) Cu 8: Cho bt Fe vo dung dch gm AgNO3 v Cu(NO3)2. Sau khi cc phn ng xy ra hon ton, thu c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X v hai kim loi trong Y ln lt l: A. Cu(NO3)2; Fe(NO3)2 v Cu; Fe B. Cu(NO3)2; Fe(NO3)2 v Ag; Cu C. Fe(NO3)2; Fe(NO3)3 v Cu; Ag D. Cu(NO3)2; AgNO3 v Cu; Ag. HD gii : Lut p Ag+ p trc ; Cu2+ p sau . X gm 2 mui ; Y gm 2 kim loi Fe ht , Ag+ ht . Cu 9: Cho 100 ml dung dch amino axit X nng 0,4M tc dng va vi 80 ml dung dch NaOH 0,5M, thu c dung dch cha 5 gam mui. Cng thc ca X l A. NH2C3H6COOH B. NH2C3H5(COOH)2 C. (NH2)2C4H7COOH D. NH2C2H4COOH . HD gii : mol (X) = mol NaOH p va X c 1 chc COOH . Mui (H2N)nRCOONa : 0,04 R + 67 + 16n = 5/0,04 R + 16n = 58 Chn : n = 1 R = 42 (C3H6) Cu 10: Cho 1,37 gam Ba vo 1 lt dung dch CuSO4 0,01 M. Sau khi cc phn ng xy ra hon ton, khi lng kt ta thu c l A. 3,31 gam B. 2,33 gam C. 1,71 gam D. 0,98 gam. HD gii : Khi Ba tc dng vi H2O to ra dd : Ba2+ + 2OH- . Dung dch CuSO4 Cu2+ + SO42- . Kt ta to ra : BaSO4 (0,01) v Cu(OH)2 (0,01)

Trang 2

THPT Phong Chu Lm Thao Ph Th.

Mi chi tit lin h thy Trung 0983173532

Cu 11: Khi c chiu sng, hirocacbon no sau y tham gia phn ng th vi clo theo t l mol 1 : 1, thu c ba dn xut monoclo l ng phn cu to ca nhau? A. isopentan. B. pentan. C. neopentan. D. butan. HD gii : 1 2 3 4 isopentan CH3 CH CH2 CH3 : c 4 v tr th khc nhau 4 dn xut . | CH3 1 2 3 trng 2 trng 1 pentan : CH3 CH2 CH2 CH2 CH3 : c 3 v tr th khc nhau 3 dn xut . CH 3 | neopentan : 1 CH 3 C CH3 2 : c 2 v th khc nhau 2 dn xut . | CH 3 1 2 trng 2 trng 1 c 2 v tr th khc nhau 2 dn xut . butan : CH3 CH2 CH2 CH3 Cu 12: Oxi ha hon ton 3,1 gam photpho trong kh oxi d. Cho ton b sn phm vo 200 ml dung dch NaOH 1M n khi phn ng xy ra hon ton, thu c dung dch X. Khi lng mui trong X l A. 14,2 gam B. 11,1 gam C. 16,4 gam D. 12,0 gam HD gii n Lp t s NaOH = 2 P to mui nc th 2 ca axit H3PO4 l HPO42- : Na2HPO4 = mol (P) nP Cu 13: Cho X l hexapeptit, Ala-Gly-Ala-Val-Gly-Val v Y l tetrapeptit Gly-Ala-Gly-Glu. Thy phn hon ton m gam hn hp gm X v Y thu c 4 amino axit, trong c 30 gam glyxin v 28,48 gam alanin. Gi tr ca m l A. 77,6 B. 83,2 C. 87,4 D. 73,4 HD gii : Hexapeptit : x ; tetrapeptit : y mol (glyxin) = 2x + 2y = 0,4 v mol(alanin) = 2x + y = 0,32 x = 0,12 ; y = 0,08 . mX = (89.2 + 75.2 + 117.2 5.18).0,12 = 56,64 mY = (75.2 + 89 + 147 3.18).0,08 = 26,56 Cu 14: trng thi c bn, cu hnh electron ca nguyn t Na( Z = 11) l A. 1s22s22p53s2 B. 1s22s22p43s1 C. 1s22s22p63s2 D. 1s22s22p63s1 Cu 15: Hn hp X cha ba axit cacboxylic u n chc, mch h, gm mt axit no v hai axit khng no u c mt lin kt i (C=C). Cho m gam X tc dng va vi 150 ml dung dch NaOH 2M, thu c 25,56 gam hn hp mui. t chy ho n ton m gam X, hp th ton b sn phm chy bng dung dch NaOH d, khi lng dung dch tng thm 40,08 gam. Tng khi lng ca hai axit cacboxylic khng no trong m gam X l A. 15,36 gam B. 9,96 gam C. 18,96 gam D. 12,06 gam HD gii : mmui = maxit + 22nNaOH m = 18,96 Khi lng dd tng = m(CO2) + m(H2O) = 40,08 44x + 18y = 40,08 Ta c : m = mC + mH + mO 12x + 2y + 32.mol(NaOH) = 18,96 x = 0,69 ; y = 0,54 mol axit ko no = mol(CO2) mol(H2O) = 0,15 mol axit no = 0,15
Trang 3

THPT Phong Chu Lm Thao Ph Th.

Mi chi tit lin h thy Trung 0983173532

C n H 2 n O 2 : 0,15 bt C 0,15n + 0,15m = 0,69 n + m = 4,6 (m 2 , n 1 ) C m H 2 m 2O 2 : 0,15 Chn n = 1 m = 3,6 khi lng axit ko no = (14m + 30).0,15

Cu 16: Dung dch axit axetic phn ng c vi tt c cc cht trong dy no sau y? A. Na, NaCl, CuO B. Na, CuO, HCl C. NaOH, Na, CaCO3 D. NaOH, Cu, NaCl HD gii A. Loi NaCl B. Loi HCl D. Loi Cu v NaCl Cu 17: Tn thay th (theo IUPAC) ca (CH3)3C-CH2-CH(CH3)2 l A. 2,2,4-trimetylpentan B. 2,2,4,4-tetrametylbutan C. 2,4,4,4-tetrametylbutan D. 2,4,4-trimetylpentan. HD gii : CH3 1 2| 3 4 5 CH3 - C CH2 CH CH3 | | CH3 CH3 Cu 18: T nilon-6,6 l sn phm trng ngng ca A. etylen glicol v hexametyleniamin B. axit aipic v glixerol C. axit aipic v etylen glicol. D. axit aipic v hexametyleniamin . HD gii : T nilon-6,6 (c 2 con s 6) c to t mi cht c 6C . A.etylen glicol C2H4(OH)2 c 2C ; loi A. B. glixerol C3H5(OH)3 ; loi B . C. Tng . Cu 19 : Hn hp X gm Na, Ba, Na2O v BaO. Ha tan hon ton 21,9 gam X vo n c, thu c 1,12 lt kh H2 (ktc) v dung dch Y, trong c 20,52 gam Ba(OH)2. Hp th hon ton 6,72 lt kh CO2 (ktc) vo Y, thu c m gam kt ta. Gi tr ca m l A. 23,64 B. 15,76 C. 21,92 D. 39,40 HG gii : Na : x (mol) Qui i X v Ba : y(mol) O : z(mol) - Ta c : mX = mNa + mBa + mO = 21,9 - bt e : x + 2y = 2(mol H2) + 2z - y = mol Ba(OH)2 = 0,12 x = 0,14 ; z = 0,14 . a + b = n CO 2 HCO 3 : a (mol) n x + 2y Lp t l OH = = 1,27 phn to ra 2 mui 2 n CO 2 n CO 2 CO 3 : b(mol) a + 2b = n OH a = 0,22 ; b = 0,08 m(BaCO3) = 0,08.197 = 15,76 Cu 20: Hp cht X c thnh phn gm C, H, O cha vng benzen. Cho 6,9 gam X vo 360 ml dung dch NaOH 0,5 M (d 20% so vi lng cn phn ng) n phn ng hon ton, thu c dung dch Y. C cn Y thu c m gam cht rn khan. Mt khc, t chy hon ton 6,9 gam X cn
Trang 4

THPT Phong Chu Lm Thao Ph Th.

Mi chi tit lin h thy Trung 0983173532

va 7,84 lt O2 (ktc), thu c 15,4 gam CO2. Bit X c cng thc phn t trng vi cng thc n gin nht. Gi tr ca m l A. 13,2 B. 12,3 C. 11,1 D. 11,4. HG gii : bt khi lng : m(X) + m(O2) = m(CO2) + m(H2O) m(H2O) = 2,7 g . m 2m H 2 O m O C : H : O = nC : nH : nO = CO 2 : = 0,35 : 0,3 : 0,15 = 7 : 6 : 3 : 44 18 16 CTPT X l C7H6O3 . 2 .7 6 + 2 = = 5 = Vng benzen ( +v = 4) + . 2 Vy X c th l : HO C6H4 COOH hoc HO C6H4 OCOH . 6,9 0,36.0,5 : .100 = 0,05 : 0,15 = 1 : 3 X l HO C6H4 OCOH mol(X) : mol (NaOH p) = 138 120 P : HOC6H4OCOH + 3NaOH NaOC6H4ONa + HCOONa + 2H2O m(X) + m(NaOH ly d 20%) = m(rn) + m(H2O) m(rn) = 12,3 g Cu 21: Bit X l axit cacboxylic n chc, Y l ancol no, c hai cht u mch h, c c ng s nguyn t cacbon. t chy hon ton 0,4 mol hn hp gm X v Y (trong s mol ca X ln hn s mol ca Y) cn va 30,24 lt kh O2, thu c 26,88 lt kh CO2 v 19,8 gam H2O. Bit th tch cc kh o iu kin tiu chun. Khi lng Y trong 0,4 mol hn hp trn l A. 17,7 gam B. 9,0 gam C. 11,4 gam D. 19,0 gam HD gii : n S C = CO 2 = 3 ancol no C3H8Ox (a mol) v axit ko no l C3H4O2 (b mol) 0,4 2n H 2 O bt H : 8a + 4b = (1) = 5,5 .0,4 0,4 Ta c : a + b = 0,4 (2) T (1) v (2) a = 0,15 ; b = 0,25 bt khi lng : m(X,Y) + m(O2) = m(CO2) + m(H2O) m(X,Y) = 44.1,2 + 18.1,1 32.1,35 = 29,4 g . m(Y) = m(X,Y) m(X) = 11,4 g Cu 22: Tin hnh cc th nghim sau (a) Sc kh etilen vo dung dch KMnO4 long. (b) Cho hi ancol etylic i qua bt CuO nung nng. (c) Sc kh etilen vo dung dch Br2 trong CCl4. (d) Cho dung dch glucoz vo dung dch AgNO3, trong NH3 d, un nng. (e) Cho Fe2O3 vo dung dch H2SO4 c, nng. Trong cc th nghim trn, s th nghim c xy ra phn ng oxi ha - kh l A. 5. B. 2 C. 3 D. 4 . HD gii : (a) C2H4 + K Mn O4 + H2O C2H4(OH)2 + Mn O2 + KOH . (b) CH3CH2OH + Cu O CH3CHO + Cu + H2O (c) C2H4 + Br2 C2H4 Br2 (d) C6H12O6 + Ag NO 3 /NH3 Ag (e) Fe2O3 + H2SO4 c, nng Fe2(SO4)3 + H2O Cu 23: Cho s cc phn ng:
Trang 5
+1
0 0 1

+7

+4

+2

THPT Phong Chu Lm Thao 0 Ph Th.

X + NaOH (dung dch) Y + Z; 15000C T Q + H2 ; Trong s trn, X v Z ln lt l A. HCOOCH=CH2 v HCHO C. CH3COOCH=CH2 v CH3CHO HD gii :
0

Mi chi tit lin h thy Trung 0983173532 0

Y + NaOH (r0n) Q + H2O t , xt

t , CaO

T + P;

Z.

B. CH3COOC2H5 v CH3CHO D. CH3COOCH=CH2 v HCHO

C T 1500 Q + H2 T (CH4) ; Q (C2H2) v Y l CH3COONa CH CH + H2O CH3CHO (Z) Vy X l : CH3COO CH=CH2 + NaOH CH3COONa + CH3CHO . Cu 24: ng vi cng thc phn t C4H10O c bao nhiu ancol l ng phn cu to ca nhau? A. 3 B. 5 C. 4 D. 2. HD gii : S ng phn ancol C4H10O = 24-2 = 22 = 4 p . Cu 25: Cho m gam Fe vo bnh cha dung dch gm H2SO4 v HNO3, thu c dung dch X v 1,12 lt kh NO. Thm tip dung dch H2SO4 d vo bnh thu c 0,448 lt kh NO v dung dch Y. Bit trong c hai trng hp NO l sn phn kh duy nht, o iu kin tiu chun. Dung dch Y ha tan va ht 2,08 gam Cu (khng to thnh sn phm kh ca N+5). Bit cc phn ng u xy ra hon ton. Gi tr ca m l A. 2,40 B. 4,20 C. 4,06 D. 3,92 . HD gii : Dung dch Y ha tan va ht Cu Fe Fe2+ . m m m 2,08 bt e : 2 Fe + 2 Cu = 3n NO 2 + 2 = 3(0,05 + 0,02) m = 4,06 g 56 64 56 64 Cu 26: Lin kt ha hc gia cc nguyn t trong phn t HCl thuc loi lin kt A. cng ha tr khng cc B. ion C. cng ha tr c cc D. hiro. HD gii: HCl c hnh thnh bi 2 phi kim khc nhau Cu 27: Thc hin cc th nghim sau (a) Cho dung dch HCl vo dung dch Fe(NO3)2 (b) Cho FeS vo dung dch HCl. (c) Cho Si vo dung dch NaOH c. (d) Cho dung dch AgNO3 vo dung dch NaF. (e) Cho Si vo bnh cha kh F2. (f) Sc kh SO2vo dung dch H2S. Trong cc th nghim trn, s th nghim xy ra phn ng l A. 6 B. 5 C. 4 D. 3. HD gii : (a) H+ + Fe2+ + NO3- Fe3+ + NO + H2O (b) FeS + HCl FeCl2 + H2S (c) Si + NaOH + H2O Na2SiO3 + H2 (d) AgF ko kt ta p ko xy ra . (e) Si + F2 SiF4 . (f) SO2 + H2S S + H2O Cu 28: Ha tan hon ton m gam Al bng dung dch HNO3 long, thu c 5,376 lt (ktc) hn hp kh X gm N2, N2O v dung dch cha 8m gam mui. T khi ca X so vi H2 bng 18. Gi tr ca m l A. 17,28 B. 19,44 C. 18,90 D. 21,60 . HG gii :

Trang 6

THPT Phong Chu Lm Thao Ph Th.

Mi chi tit lin h thy Trung 0983173532

44 36(1) N 2 36 0,24 mol X mol N2 = mol N2O = 0,12 36 28(1) N 2O bt e : 3mol Al = 10mol N2 + 8mol N2O + 8mol NH4NO3 . m Ta c : m(NH4NO3) = 8m mAl(NO3)3 = 8m .213 27 m 8m .213 m 27 3 = 10.0,12 + 8.0,12 + 8 m = 21,6 g . 27 80 Cu 29: Cho hn hp X gm 0,01 mol Al v a mol Fe vo dung dch AgNO3 n khi phn ng hon ton, thu c m gam cht rn Y v dung dch Z cha 3 cation kim loi. Cho Z phn ng vi dung dch NaOH d trong iu kin khng c khng kh, thu c 1,97 gam kt ta T. Nung T trong khng kh n khi lng khng i, thu c 1,6 gam cht rn ch cha mt cht duy nht. Gi tr ca m l A. 8,64 B. 3,24 C. 6,48 D. 9,72. HD gii : NaOH d ko c kt ta Al(OH)3 ; AgOH ko bn Ag2O ; C khi lng kt ta v khi lng rn 3 cation kim loi l Al3+ , Fe3+ , Fe2+ Tc dng vi NaOH d :
mol Ag = 3mol Al + 2mol (x) Fe2+ + 3mol (y)Fe3+ . Ta c : 1,97 = mFe(OH)2 + mFeOH)3 90x + 107y = 1,97 (1) x y V 1,6 g = mFe2O3 160( + ) = 1,6 (2) 2 2 T (1) v (2) x = y = 0,01 Vy : mAg = 108(3.0,01 + 2.0,01 + 3.0,01) = 8,84 g

Cu 30: Cht no sau y khng to kt ta khi cho vo dung dch AgNO3? A. HCl B. K3PO4 C. KBr D. HNO3 . HD gii: Ag+ to c kt ta vi Cl- , PO43- v Br- . C th : AgCl trng ; AgBr vng ; Ag3PO4 vng . Cu 31: Phenol phn ng c vi dung dch no sau y? A. NaCl. B. KOH. C. NaHCO3. D. HCl. HD gii : Phenol l axit yu < H2CO3 < HCl Phenol ko p vi HCl v mui axit mch hn n . Cu 32: Cho cc cn bng ha hc sau: 2HI (k). N2O4 (k). (a) H2 (k) + I2 (k) (b) 2NO2 (k) 2NH3 (k). 2SO3 (k). (c) 3H2 (k) + N2 (k) (d) 2SO2 (k) + O2 (k) nhit khng i, khi thay i p sut chung ca mi h cn bng, cn bng ha hc n o trn khng b chuyn dch? A. (a). B. (c). C. (b). D. (d). HD gii : p sut thay i (tng hoc gim) + Cn bng chuyn dch khi h s cn bng cc phn t kh trong p khc nhau . + Cn bng ko chuyn dch khi h s cn bng cc phn t trong p bng nhau . Cu 33: Kim loi st tc dng vi dung dch no sau y to ra mui st(II)? A. CuSO4. B. HNO3 c, nng, d.
Trang 7

THPT Phong Chu Lm Thao Ph Th.

Mi chi tit lin h thy Trung 0983173532

C. MgSO4. D. H2SO4 c, nng, d. HD gii : HNO3 v H2SO4 c, nng, d u to mui Fe3+ . MgSO4 ko c p (v Fe ng sau Mg trong dy in ha) Cu 34: Ha tan hon ton 1,805 gam hn hp gm Fe v kim loi X vo bng dung dch HCl, thu c 1,064 lt kh H2. Mt khc, ha tan hon ton 1,805 gam hn hp trn bng dung dch HNO3 long (d), thu c 0,896 lt kh NO (sn phm kh duy nht). Bit c c th tch kh u o iu kin tiu chun. Kim loi X l A. Al. B.Cr. C. Mg. D. Zn. HG gii : T p n X tc dng c vi HCl mol e 2 th nghim khc nhau Loi B (v Cr v Al c s oxi ha bin i nh nhau) bt e (TN1) : 2mol (x)Fe + n mol(y) = 2mol H2 2x + ny = 2.0,0475 (1) (2) bt e (TN2) : 3x + ny = 3.0,04 T (1) v (2) x = 0,025 ; ny = 0,045 . 0,405.n Ta c : 1,805 = mFe + mX mX = 0,405 g X = = 9n (chn n = 3) . 0,045 Cu 35: Cc cht trong dy no sau y u to kt ta khi cho tc dng vi dung dch AgNO3 trong NH3 d, un nng? A. vinylaxetilen, glucoz, anehit axetic . B. glucoz, imetylaxetilen, anehit axetic. C. vinylaxetilen, glucoz, imetylaxetilen . D. vinylaxetilen, glucoz, axit propionic. HD gii : Cht tham p vi dung dch AgNO3/NH3 to kt ta th phi c : nhm HCO v C C u mch . B v C loi imetylaxetilen ; D loi axit propionic Cu 36: Tin hnh in phn dung dch cha m gam hn hp CuSO4 v NaCl (hiu sut 100%, in cc tr, mng ngn xp), n khi nc bt u b in phn c hai in cc th ngng in phn, thu c dung dch X v 6,72 lt kh (ktc) anot. Dung dch X ha tan ti a 20,4 gam Al2O3. Gi tr ca m l A. 25,6. B. 23,5 C. 51,1. D. 50,4. HD gii : Dung dch X ha tan c Al2O3 X c OH- hoc H+ . Ti catot : Cu2+ + 2e Cu 0,1 0,6 0,4 2HOH + 2e H2 + 2OH- . 0,4 0,4 2OH- + Al2O3 2AlO2- + H2O 0,4 0,2 . Ti anot : 2Cl- Cl2 + 2e 0,6 0,3 0,6 Ti anot H2O ko in phn . Vy : m = mCuSO4 + mNaCl = 51,1 g Cu 37: Cht no sau y khi un nng vi dung dch NaOH thu c sn phm c anehit? A. CH3-COO-C(CH3)=CH2. B. CH3-COO-CH=CH-CH3. C. CH2=CH-COO-CH2-CH3. D. CH3-COO-CH2-CH=CH2. HD gii :
Trang 8

THPT Phong Chu Lm Thao Ph Th.

Mi chi tit lin h thy Trung 0983173532

Este c dng R COO CH=CH2 Cu 38: Dung dch no sau y lm phenolphtalein i mu? A. glyxin. B. metylamin. C. axit axetic. D. alanin. HD gii : Cht c tnh bazo lm phenolphtalein i mu sang hng . glyxin v alanin trung tnh (v c 1 nhm COOH v 1 nhm NH 2) Cu 39: Cho 0,1 mol tristearin ((C17H35COO)3C3H5) tc dng hon ton vi dung dch NaOH d, un nng, thu c m gam glixerol. Gi tr ca m l A. 27,6. B. 4,6. C. 14,4. D. 9,2. HD gii : tristearin ((C17H35COO)3C3H5) C3H5(OH)3 . Cu 40: Dy cc cht u tc dng c vi dung dch Ba(HCO3)2 l: A. HNO3, Ca(OH)2 v Na2SO4. B. HNO3, Ca(OH)2 v KNO3. C. HNO3, NaCl v Na2SO4. D. NaCl, Na2SO4 v Ca(OH)2. II. PHN RING (10 cu) Th sinh ch c lm mt trong hai phn (Phn A hoc Phn B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Cho X v Y l hai axit cacboxylic mch h, c cng s nguyn t cacbon, trong X n chc, Y hai chc. Chia hn hp X v Y thnh hai phn bng nhau. Phn mt tc dng ht vi Na, thu c 4,48 lt kh H2 (ktc). t chy hon ton phn hai, thu c 13,44 lt kh CO2 (ktc). Phn trm khi lng ca Y trong hn hp l A. 28,57% B. 57,14% C. 85,71% D. 42,86% . HD gii X l : RCOOH (x mol) v Y l R(COOH)2 (y mol) c cng s cacbon l n . bt H nhm chc COOH : x + 2y = 2.0,2 = 0,4 Ta c : n H 2 < n X , Y < 2n H 2 0,2 < x + y < 0,4 (1) bt C : nx + ny = mol CO2 = 0,6 n(x + y) = 0,6 x + y =
Thay (2) vo (1) : 1,5 < n < 3 n = 2 x = 0,2 ; y = 0,1 . X : CH 3COOH : 0,2(mol) Vy Y : (COOH )2 : 0,1(mol)

0,6 (2) n

Cu 42: t chy hon ton hn hp X gm 0,07 mol mt ancol a chc v 0,03 mol mt ancol khng no, c mt lin kt i, mch h, thu c 0,23 mol kh CO2 v m gam H2O. Gi tr ca m l A. 5,40 B. 2,34 C. 8,40 D. 2,70 . HD gii : Ancol khng no,c mt lin kt i c : mol (H2O) mol CO2 = 0 Ancol no c : mol (H2O) mol (CO2) = mol ancol mol H2O = 0,07 + 0,23 = 0,3 m(H2O) = 0,3.18 = 5,4 Cu 43: Dy cc cht u c kh nng tham gia phn ng thy phn trong dung dch H 2SO4 un nng l: A. fructoz, saccaroz v tinh bt B. saccaroz, tinh bt v xenluloz C. glucoz, saccaroz v fructoz D. glucoz, tinh bt v xenluloz HD gii : monosaccarit : glucozo v fructozo ko tham gia p thy phn . Cu 44: Cho cc cp oxi ha kh c sp xp theo th t tng dn tnh oxi ha ca cc ion kim loi: Al3+/Al; Fe2+/Fe, Sn2+/Sn; Cu2+/Cu. Tin hnh cc th nghim sau: (a) Cho st vo dung dch ng(II) sunfat. (b) Cho ng vo dung dch nhm sunfat.
Trang 9

THPT Phong Chu Lm Thao Ph Th.

Mi chi tit lin h thy Trung 0983173532

(c) Cho thic vo dung dch ng(II) sunfat. (d) Cho thic vo dung dch st(II) sunfat. Trong cc th nghim trn, nhng th nghim c xy ra phn ng l : A. (b) v (c) B. (a) v (c) C. (a) v (b) D. (b) v (d) HD gii: Cht kh mnh + Oxi ha mnh kh yu + oxi ha yu . Tnh kh Al > Fe > Sn > Cu (b) Tnh kh Cu < Al ko p (d) Tnh kh Sn < Fe ko p Cu 45: Cho cc pht biu sau: (a) Trong bng tun hon cc nguyn t ha hc, crom thuc chu k 4, nhm VIB. (b) Cc oxit ca crom u l oxit baz. (c) Trong cc hp cht, s oxi ha cao nht ca crom l +6 (d) Trong cc phn ng ha hc, hp cht crom(III) ch ng vai tr cht oxi ha. (e) Khi phn ng vi kh Cl2 d, crom to ra hp cht crom(III). Trong cc pht biu trn, nhng pht biu ng l: A. (a), (b) v (e) B. (a), (c) v (e) C. (b), (d) v (e) D. (b), (c) v (e) HD gii : Cr (Z = 24) c cu hnh e lp ngoi cng l : 3d44s2 crom thuc chu k 4, nhm VIB (loi C,D) . CrO3 + H2O axit H2CrO4 hoc H2Cr2O7 (loi A) . Cu 46: Th nghim vi dung dch HNO3 thng sinh ra kh c NO2. hn ch kh NO2 thot ra t ng nghim, ngi ta nt ng nghim bng: (a) bng kh. (b) bng c tm nc. (c) bng c tm nc vi. (d) bng c tm gim n. Trong 4 bin php trn, bin php c hiu qu nht l A. (d) B. (c) C. (a) D. (b) HD gii: loi b kh NO2 th NO2 phi c p xy ra nhanh 2Ca(OH)2 + 4NO2 Ca(NO2)2 + Ca(NO3)2 + 2H2O Cu 47: Hn hp X gm H2, C2H4 v C3H6 c t khi so vi H2 l 9,25. Cho 22,4 lt X (ktc) vo bnh kn c sn mt t bt Ni. un nng bnh mt thi gian, thu c hn hp kh Y c t khi so vi H2 bng 10. Tng s mol H2 phn ng l A. 0,070 mol B. 0,015 mol C. 0,075 mol D. 0,050 mol HD gii : Gi x l mol H2 p bt khi lng : mX = mY 9,25.1 = 10(1 x) x = 0,075 Cu 48: Trong cc dung dch CH3-CH2-NH2, H2N-CH2-COOH, H2N-CH2-CH(NH2)-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, s dung dch lm xanh qu tm l A.4 B.1 C. 2 D.3 HD gii dung dch lm xanh qu tm phi c tnh bazo CH3-CH2-NH2, H2N-CH2-CH(NH2)-COOH Cu 49: Cho phng trnh phn ng aAl +bHNO3 cAl(NO3)3 + dNO + eH2O. T l a : b l A. 1 : 3 B. 2 : 3 C. 2 : 5 D. 1 : 4. HD gii : Al +4HNO3 Al(NO3)3 + NO + 2H2O
Trang 10

THPT Phong Chu Lm Thao Ph Th.

Mi chi tit lin h thy Trung 0983173532

Cu 50: Cho 25,5 gam hn hp X gm CuO v Al2O3 tan hon ton trong dung dch H2SO4 long, thu c dung dch cha 57,9 gam mui. Phn trm khi lng ca Al2O3 trong X l A. 40% B. 60% C. 20% D. 80% . HD gii : CuSO 4 : x CuO : x (mol) 80x + 102 y = 25,5 2 SO 4 H 57,9(g ) 25,5 g Al2O3 : y(mol) Al2 (SO 4 )3 : y 160x + 342 y = 57,9
x = 0,255 ; y = 0,05

Trang 11