TRNG HSP H NI TRNG THPT CHUYN M : 251

THI TH I HC LN TH V NM 2013 MN HA HC Thi gian lm bi: 90 pht

I. PHN CHUNG CHO TT C TH SINH: (40 cu, t cu 1 n cu 40) Cu 1: t chy hon ton m gam mt ancol a chc X to ra 0,3 mol CO2 v 0,4 mol H2O. X khng c kh nng tc dng vi Cu(OH)2 to ra dung dch mu xanh lam. Cho m gam X tc dng vi Na (d) thu c V lt kh H2 ( ktc). Gi tr ca V l A. 1,12 lt. B. 3,36 lt. C. 2,24 lt. D. 4,48 lt. Cu 2: t chy cc ancol trong cng mt dy ng ng th t l mol CO2: H2O tng dn khi s nguyn t cacbon tng. Cc ancol cng thuc mt dy ng ng A. no, n chc. B. khng no. C. no, mch h. D. no, a chc. Cu 3: t chy hon ton hhn hp gm hai hyrocacbon mch h thu c CO2 v H2O c s mol bng nhau. Thnh phn % v s mol ca hai cht trong hn hp bng: A. 40 v 60. B. 50 v 50. C. 25 v 75. D. phng n khc. Cu 4: Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC: mH: mO = 21: 2 : 4. Hp cht X c cng thc phn t trng vi cng thc n gin nht. S ng phn cu to thuc loi hp cht thm ng vi cng thc phn t ca X l A. 5. B. 6. C. 4. D. 3. Cu 5: in phn 200 ml dung dch cha AgNO3 2M v HNO3 trong vng 4 gi 3 giy vi cng d dng in 0,201 ampe th thu c 3,078 gam Ag catot. Hiu sut in phn l A. 90%. B. 95%. C. 80%. D. 75%. Cu 6: Cho glixerin trileat (hay triolein) ln lt vo mi ng nghim cha ring bit: Na, Cu(OH)2, CH3OH, dung dch Br2, dung dch NaOH.Trong iu kin thch hp, s phn ng xy ra l A. 4. B. 3. C. 5. D. 2. Cu 7: Cht hu c X c cng thc phn t C4H11O3N c kh nng phn ng vi c dung dch axit v dung dch kim. Khi cho X tc dng vi dung dch NaOH d ri c cn th phn rn thu c ch cha cht v c. S cng thc cu to ph hp vi tnh cht trn ca X l A. 2. B. 3. C. 5. D. 4. Cu 8: Cho dung dch Fe(NO3)2 ln lt tc dng vi cc dung dch Na2S, H2SO4 long, H2S, H2SO4 c, NH3, AgNO3, Na2CO3, Br2. S trng hp xy ra phn ng l A. 5. B. 7. C. 8. D. 6. Cu 9: Trong s cc pht biu sau v phenol (C6H5OH) (1) Phenol tan t trong nc nhng tan nhiu trong dung dch HCl. (2) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm. (3) Phenol dng sn xut keo dn, cht dit nm mc. (4) Phenol tham gia phn ng th brom v th nitro d hn benzen. S pht biu ng l A. 1. B. 4. C. 2. D. 3. Cu 10: C 4 dung dch mui ring bit: CuCl2, ZnCl2, FeCl2, AlCl3. phn bit cc dung dch trn ch cn dng thm mt thuc th l A. NH3. B. NaOH. C. H2S. D. AgNO3. Cu 11: Cho s chuyn ha: Glucoz X Y CH3COOH. Hai cht hu c X, Y ln lt l A. CH3CHO v CH3CH2OH. B. CH3CH2OH v CH2=CH2. B. CH3CH2OH v CH3CHO. D. CH3CH(OH)COOH v CH3CHO. Cu 12: Cho cc cn bng sau: (1) 2SO2 (k) + O2 (k) 2SO3 (k). (2) N2 (k) + 3H2 (k) 2NH3 (k). (3) CO2 (k) + H2 (k) CO (k) + H2O (k). (3) 2HI (k) H2 (k) + I2 (k). Khi thay i p sut, nhm gm cc cn bng ha hc u khng b dch chuyn l A. (1) v (2). B. (1) v (3). C. (3) v (4). D. (2) v (4). Cu 13: Cho cc pht biu sau: (1) Trong nhm halogen, tnh phi kim v m in gim dn t flo n iot. (2) Cc halogen u c cc trng thi oxi ha 1, 0, +1, +3, + 5, +7. (3) Trong dy axit khng cha oxi ca halogen t HF n HI tnh axit v tnh kh u tng dn. (4) Cc axit HX (X l halogen) thng c iu ch bng cch cho mui NaX (rn) tc dng vi H2SO4 (c), un nng.

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(5) Cho cc dung dch dch mui NaX (X l halogen) tc dng vi dung dch AgNO3 u thu c kt ta AgX. S nhn xt ng l A. 5. B. 3. C. 4. D. 2. Cu 14: Cho 200 ml dung dch X cha ng thi HCl 1,025 M v HNO3 1,05 M vo 300 ml dung dch Y cha ng thi Ba(OH)2 0,5M v NaOH 0,4M thu c 500 ml dung dch Z. pH ca dung dch Z l A. 12,4. B. 12. C. 11. D. 13. Cu 15: Dn 0,336 lt C2H2 ( ktc) vo dung dch KMnO4 0,2M thy to thnh cht rn mu nu en. Th tch dung dch KMnO4 ti thiu cn dng hp th ht lng kh C2H2 trn l A. 20 ml. B. 40 ml. C. 400 ml. D. 200 ml. Cu 16: Cht hu c X c cng thc phn t C2H3Cl3. Cho X tc dng vi dung dch NaOH, un nng thu c cht hu c Y. T X v Y ngi ta iu ch phenyl axetat theo s sau: X Y Z T phenyl axetat Cc cht X v T trong s trn l A. 1, 1, 2 tricloetan v phenol. B. 1, 1, 1 tricloetan v anhirit axetic. C. 1, 1, 2 tricloetan v anhirit axetic. D. 1, 1, 1 tricloetan v axit axetic. Cu 17: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c, c xc tc axit sunfuric c. c 59,4 kg xenluloz trinitrat cn dng dung dch cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l A. 42 kg. B. 20 kg. C. 60 kg. D. 84 kg. Cu 18: Cho dy gm cc cht v ion sau: Zn, S, FeO, SO2, N2, HCl, Cu2+, Cl . S cht v ion c c tnh oxi ha v tnh kh l A. 5. B. 4. C. 6. D. 7. Cu 19: Dy gm cc cht iu ch trc tip (bng mt phn ng) to ra anehit axetic l A. C2H5OH, C2H4, C2H2. B. CH3COOH, C2H2, C2H4. C. C2H5OH, C2H2, CH3COOC2H5. D. HCOOC2H3, C2H2, CH3COOH. Cu 20: Hn hp X gm 0,15 mol C2H2; 0,1mol C2H4; 0,1mol C4H4 (vinylaxetilen) v 0,4 mol H2. un nng X vi xc tc Ni, sau mt thi gian thu c hn hp Y c t khi so vi hiro l 12,7. Dn Y qua dung dch nc brom d, s gam brom tham gia phn ng l A. 40 gam. B. 56 gam. C. 72 gam. D. 104 gam. Cu 21: Hiro ha hon ton hirocacbon X cng thc phn t C5H10 thu c sn phm l isopentan. S cng thc cu to c th c ca X l A. 6. B. 5. C. 7. D. 4. Cu 22: S anken c cp ng phn cis tran ca C5H10 l A. 3. B. 4. C. 1. D. 2. Cu 23: in phn mt dung dch cha 0,1 mol HCl; 0,2 mol FeCl3; 0,1 mol CuCl2 vi hai in cc tr n khi catot thu c 3,2 gam Cu th anot thu c th tch kh ( ktc) l A. 4,48 lt. B. 3,36 lt. C. 2,24 lt. D. 1,12 lt. Cu 24: Nguyn t X c cu hnh electron l 1s22s22p63s23p64s23d6. Ion to t X c cu hnh electron l A. 1s22s22p63s23p63d5. B. 1s22s22p63s23p63d6. C. 1s22s22p63s23p64s23d5. D. p s khc. Cu 25: X v Y l hai nguyn t thuc cng mt nhm v hai chu k k tip nhau. Bit ZX < ZY v ZX + ZY = 32. Kt lun no sau y khng ng i vi X v Y? A. Nguyn t ca X v Y u c 2e lp ngoi cng. B. Bn knh nguyn t v bn knh ion ca Y u ln hn X. C. Chng u c oxit cao nht v hp cht kh vi hiro. D. Chng u l kim loi mnh v u c ha tr II. Cu 26: Nguyn t nguyn t X c tng s cc ht p, n, e l 58, trong ht nhn s ht p v n hn nhau 1. S hiu nguyn t ca X l A. 19. B. 20. C. 18. D. 21 Cu 27: Thy phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%, thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l A. C2H5COOH v C3H7COOH. B. CH3COOH v C2H5COOH. C. HCOOH v CH3COOH. D. HCOOH v C2H5COOH. Cu 28: Hp cht trong phn t c lin kt ion l A. HF. B. NH3. C. H2O. D. NH4NO3. Cu 29: Cho m gam hn hp gm hai ancol no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c hn hp rn Z v hn hp hi Y (t khi ca Y so vi hiro l 13,75). Cho Y phn ng vi mt lng d AgNO3 trong dung dch NH3un nng, sinh ra 64,8 gam Ag. Gi tr ca m l A. 7,8. B. 8,8. C. 7,4. D. 9,2.

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Cu 30: Cho cc hp cht ha hc sau: etanol (1), phenol (2), nc (3), axit axetic (4), axit clohiric (5), axit fomic (6), axit oxalic (7) v propanol (8). Dy sp xp theo chiu hot ng ca nguyn t hiro tng dn l A. 8, 1, 3, 2, 7, 4, 6, 5. B. 8, 1, 3, 2, 4, 6, 7, 5. C. 8, 1, 2, 3, 4, 6, 7, 5. D. 3, 8, 1, 2, 4, 6, 7, 5. Cu 31: m in ca Al l 1,61 v Cl l 3,16. Nhn xt no sau y v lin kt gia nhm v clo trong phn t AlCl3 l ng? A. lin kt cng ha tr khng phn cc. B. lin kt ion. C. lin kt cng ha tr phn cc. D. lin kt cho nhn. Cu 32: Thy phn este X mch h c cng thc phn t C4H6O2, sn phm thu c c kh nng trng bc. S este X tha mn tnh cht trn l A. 4. B. 3. C. 6. D. 5. Cu 33: Hn hp X gm FeS2 v Cu2S. Ha tan hn hp X trong dung dch HNO3 va thu c dung dch Y ch cha hai mui sunfat v gii phng kh NO. Thnh phn % v s mol ca hai cht tng ng trong hn hp X l A. 75 v 25. B. 66,67 v 33,33. C. 40 v 60. D. 50 v 50. Cu 34: Thy phn 5,13 gam mantoz vi hiu sut H%, thu c dung dch X. Cho dung dch X tc dng vi dung dch AgNO3 trong NH3(d), thu c 4,374 gam Ag kt ta. Gi tr ca H l A. 35. B. 67,5. C. 30. D. 65,7. Cu 35: Cho cn bng ha hc sau: N2 (k) + 3H2 (k) 2NH3 (k) H < 0. Cn bng s dch chuyn v bn phi khi: A. tng nhit v gim p sut ca h. B. tng nhit v tng p sut ca h. C. gim nhit v gim p sut ca h. D. gim nhit v tng p sut ca h. Cu 36: Cp cht no sau y m trong phn t mi cht u cha c 3 loi lin kt ion, cng ha tr v cho nhn? A. NH4NO3 v Al2O3. B. (NH4)2SO4 v KNO3. C. NH4Cl v NaOH. D. Na2SO4 v HNO3. Cu 37: Thnh phn % khi lng ca nit trong hp cht hu c CxHyN l 19,18%. S ng phn amin bc mt tha mn cc d kin trn l A. 4. B. 3. C. 1. D. 8. Cu 38: pH ca dung dch CH3COONa 0,1 M (Kb ca CH3COO l 5,71.10 10) l A. 8,88. B. 4,76. C. 5,12. D. 10,24. Cu 39: Nhit phn hon ton hn hp X gm KNO3 v Fe(NO3)2 thu c hn hp kh Y. Dn t t hn hp kh Y vo nc thy cc kh c hp th hon ton. Thnh phn % v s mol ca hai cht tng ng trong hn hp X l A. 20 v 80. B. 25 v 75. C. 33,33 v 66,67. D. 50 v 50. Cu 40: Khi nhn xt v cc mui cacbonat trung ha, nhn xt no sau y l ng? A. Tt c cc mui cacbonat u tan trong nc. B. Tt c cc mui cacbonat u b nhit phn to ra oxit kim loi v cacbon ioxit. C. Tt c cc mui cacbonat u b nhit phn, tr mui cacbonat ca kim loi kim. D. Tt c cc mui cacbonat u khng tan trong nc. II. PHN RING [10 cu] A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Khi nung m gam Cu ngoi khng kh thu c cht rn A. Cho A tc dng vi dung dch H2SO4 c, nng, d thu c dung dch B v gii phng kh SO2. C cn dung dch B thu c 30 gam tinh th CuSO4.5H2O. Gi tr ca m l A. 6,72 gam. B. 6,4 gam. C. 7,68 gam. D. 8 gam. Cu 42: Mt cc nc c cha cc ion: Na+ (0,05 mol), Mg2+ (0,02 mol), Ca2+ (0,04 mol), Cl (0,02 mol), HCO3 (0,13 mol) v SO42 (0,01 mol). Nc trong cc cha: A. cng vnh cu. B. l nc mm. C. cng ton phn. D. cng tm thi. Cu 43: Ha tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO3 c, nng thu c 1,344 lt kh NO2 (sn phm kh duy nht, ktc) v dung dch Y. Sc t t kh NH3 (d) vo dung dch Y, sau khi phn ng xy ra hon ton thu c m gam kt ta. Phn trm v khi lng ca Cu trong hn hp X v gi tr ca m ln lt l A. 21,95% v 2,25. B. 78,05% v 2,25. C. 21,95% v 0,78. D. 78,05% v 0,78. Cu 44: Dung dch X cha ng thi hai cht tan Na2CO3 1M v KHCO3 0,5M; dung dch Y cha HCl 1M. Rt t t 200 ml dung dch X vo cc cha 250 ml dung dch Y, khuy k. Th tch kh thot ra ktc l A. 1,12 lt. B. 3,36 lt. C. 2,8 lt. D. 3,92 lt. Cu 45: oxi ha hon ton 0,01 mol CrCl3 thnh K2CrO4 bng Cl2 khi c mt KOH, lng ti thiu Cl2 v KOH tng ng l A. 0,015 v 0,08 (mol). B. 0,03 v 0,04 (mol). C. 0,015 v 0,04 (mol). D. 0,03 v 0,08 (mol). Cu 46: Khi ni v peptit v protein, pht biu no sau y l sai? A. Tt c cc protein u tan trong nc to thnh dung dch keo. B. Protein c phn ng mu biure vi Cu(OH)2. C. Lin kt ca nhm CO vi nhm NH gia hai n v - amino axit c gi l lin kt peptit.

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D. Thy phn hon ton protein n gin thu c cc - amino axit. Cu 47: Cho cc dung dch: C6H5NH2 (anilin), CH3NH2, NaOH, H2NCH2COOH v C2H5OH. Trong cc dung dch trn, s dung dch c th lm i mu phenolphtalein l A. 4. B. 2. C. 5. D. 3. Cu 48: Cho cc t sau: t xenluloz axetat, t capron, t nitron, t visco, t nilon 6,6. C bao nhiu t thuc loi t poliamit? A. 1. B. 3. C. 2. D. 4. Cu 49: Hn hp M gm mt anken v hai amin no, n chc, mch h X v Y l ng ng k tip (MX < MY). t chy hon ton mt lng M cn dng 4,536 lt O2 (ktc) thu c H2O, N2 v 2,24 lt CO2 (ktc). Cht X l A. propylamin. B. etylamin. C. metylamin. D. butylamin. Cu 50: Tnh cht no sau y khng ng vi cht hu c: H2N CH(COOH)2 ? A. phn ng vi NaOH v HCl. B. phn ng vi ancol. C. khng lm i mu qu tm. D. tham gia phn ng trng ngng. B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Hai cht no sau y u tc dng c vi dung dch NaOH long? A. CH3NH3Cl v CH3NH2. B. ClH3NCH2COOC2H5 v H2NCH2COOC2H5. C. CH3NH3Cl v H2NCH2COONa. D. CH3NH2 v H2NCH2COOH. Cu 52: Cho 200 ml dung dch Al2(SO4)3 tc dng vi dung dch NaOH 1M ngi ta nhn thy khi dng 180 ml dung dch NaOH hay dng 340 ml dung dch NaOH trn th vn thu c khi lng kt ta bng nhau. Nng mol/l ca dung dch Al2(SO4)3 ban u l A. 0,375 M. B. 0,25 M. C. 0,125 M. D. 0,5 M. Cu 53: Cho bit E0 Mg2+/Mg = 2,37 V; E0Zn2+/ Zn = 0,76 V; E0Pb2+/ Pb = 0,13 V; E0Cu2+/ Cu = + 0,34 V. Pin in ha c sut in ng chun bng 1,1 V c cu to bi hai cp oxi ha kh A. Pb2+ / Pb v Cu2+ / Cu. B. Zn2+ / Zn v Cu2+ / Cu. C. Mg2+ / Mg v Zn2+ / Zn. D. Zn2+ / Zn v Pb2+ / Pb. Cu 54: Trong phng php thy luyn dng iu ch Ag t qung cha Ag2S, cn dng thm A. dung dch NaCN v Zn. B. dung dch HNO3 c v Zn. C. dung dch H2SO4 c v Zn. D. dung dch HCl c v Zn. Cu 55: Cht X c cng thc phn t C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l A. metyl aminoaxetat. B. axit amino propionic. C. axit amino propionic. D. amino acrylat. Cu 56: Pht biu khng ng l A. ipeptit glyxylalanin (mch h) c 2 lin kt peptit. B. Etylamin tc dng vi axit nitrow nhit thng to ra etanol. C. Protein l nhng polipeptit cao phn t c phn t khi t vi chc nghn n vi triu. D. Metylamin tan trong nc cho dung dch c mi trng baz. Cu 57: Cho m gam Fe phn ng vi H2SO4 thu c kh A v 11,04 gam mui. T l mol gia Fe v H2SO4 trong phn ng trn l 3:8. Gi tr ca m l: A. 3,2256 gam. B. 3,36 gam. C. 4,24 gam. D. 33,6 gam. Cu 58: Ln men dung dch cha 300 gam glucoz thu c 92 gam ancol etylic. Hiu sut qu trnh ln men to thnh ancol etylic l A. 54%. B. 40%. C. 80%. D. 60%. Cu 59: Qung giu st nht nhng him c trong t nhin l A. hmatit. B. manhtit. C. xirit. D. pirit. Cu 60: Cho cc loi t: bng, t capron, t xenluloz axetat, t tm, t nitron, nilon 6,6. S t tng hp l A. 2. B. 3. C. 4. D. 5. --------------------HT---------------------

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P N M 251 1C, 2C, 3D, 4A, 5B, 6D, 7D, 8B, 9D, 10A, 11C, 12C, 13D, 14B, 15D, 16B, 17A, 18A, 19A, 20C, 21C, 22C, 23B, 24D, 25C, 26A, 27D, 28D, 29A, 30B, 31C, 32D, 33B, 34A, 35D, 36B, 37A, 38A, 39C, 40C, 41C, 42D, 43D, 44B, 45A, 46A, 47B, 48C, 49C, 50C, 51B, 52B, 53B, 54A, 55D, 56A, 57B, 58D, 59B, 60B.

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