GV Nguyen Phc Thuan 53/34/113, Bnh Li, P13, Q.

Bnh Thanh

: 0909449943

E 3:

TRNG CAO ANG S PHAM HA NOI - 1999

A. PHAN BAT BUOC: Cau I : (2,5 iem). 1) Cho kim loai bari (Ba) lan lt vao cac dung dch sau: CuSO4, (NH4)2SO4, NaHCO3, Al(NO3)3, FeCl2, NaOH. Neu hien tng xay ra va viet cac phng trnh phan ng. 2) T xenluloz va cac chat vo c can thiet khac, hay viet phng trnh phan ng ieu che cac chat sau: cao su buna, axit axetic, axit acrilic, glixerin, phenol. Cau II : (2,5 iem) Hoa tan het 4,68 gam hon hp muoi cacbonat cua hai kim loai A va B ke tiep nhau trong phan nhom chnh II bang 200 ml dung dch HCl 0,5M. Sau phan ng ta thu c dung dch C va 1,54 lt kh CO2 o 27,30C va ap suat 0,8 atm. 1) a> Cho biet ten cua hai nguyen to A va B. b> Tnh tong khoi lng muoi tao thanh trong dung dch C. 2) Tnh thanh phan % khoi lng moi muoi trong hon hp ban au. 3) Cho toan bo lng kh CO2 thu c tren hap thu het bi 200ml dung dch Ba(OH)2. Tnh nong o mol/l cua dung dch Ba(OH)2 e: a> Thu c 1,97 gam ket tua. b> Thu c lng ket tua ln nhat va lng ket tua nho nhat. Cau III : (2,5 iem) Cho 6,08 gam hon hp X gom CaC2, CaO va Ca tac dung het vi H2O th thu c 2,464 lt hon hp kh A 27,30C va 1 atm. T khoi hi cua A oi vi H2 bang 5,8. 1) Tnh thanh phan % theo khoi lng cua moi chat trong X. 2) un nong hon hp A co bot Ni lam xuc tac, sau mot thi gian th thu c hon hp kh B. chia B lam hai phan bang nhau. - Phan th nhat : Cho loi t t qua bnh ng dung dch Br2 d th thay con lai 448ml hon hp kh C ( ktc) co t khoi hi oi vi H2 bang 4,5. Hoi khoi lng bnh brom tang len bao nhieu gam? - Phan th hai : em tron vi 2,24 lt O2 ( ktc) vao trong bnh co dung tch 4 lt. Sau khi bat tia la ien e ot chay, gi bnh nhiet o 136,50C. Tnh ap suat bnh nhiet o o, biet dung tch cua bnh khong thay oi. B. PHAN RIENG CHO TNG LOAI OI TNG TH SINH: Cau IV : (2,5 iem) Dung cho th sinh thi theo chng trnh cha phan ban 1) Ch t quang pirit , khong kh va nc, hay viet cac phng trnh phan ng ieu che FeSO4 va Fe2(SO4)3 (co u chat xuc tac va phng tien can thiet). 2) Bang phng phap hoa hoc hay phan biet kh CO2 va SO2. 3) Tach hon hp cac kh sau: CH3NH2, CH4, C2H2 va C2H4. Cau V : (2,5 iem) Dung cho th sinh thi theo chng trnh phan ban 1) Viet phng trnh phan ng xay ra khi cho Cu kim loai lan lt vao cac dung dch sau: a> NaNO3 va H2SO4 b> HCl c> AgNO3

GV Nguyen Phc Thuan 53/34/113, Bnh Li, P13, Q. Bnh Thanh

: 0909449943

d> H2SO4 ac nong. 2) Bang phng phap hoa hoc hay phan biet cac dung dch sau: CuSO4, Cr2(SO4)3, FeSO4. 3) Viet phng trnh phan ng thc hien qua trnh bien hoa sau:
2 4 Buten-1 A B D o O

+ HCl

+ NaOH t

H SO ac 170

+ Br2

NaOH G. E + o