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CHT HA DO VT L

GVHD: TS. Nguyn Th L Thanh Danh sch thnh vin nhm 5: 1/ Thi Sn 2/ V Ngc i Trang 3/ Trng Thu Thy 4/ L Minh Duy

V0904537 V0904692 V0904661 V0904105

Mc lc
1 2 3 4 5 3 6 4 Gii thiu v cht ha do Phn loi cht ha do Cc thuyt ha do c in nh hng ca cht ha do La chn cht ha do Mt s cht ha do v ng dng

1. Tng quan CHD Khi nim: Cht ho do (plasticizers) l cht c tc dng lm tng mm do ca mch polymer

Hm lng: 0,5 - 10% tnh theo t l 100% cao su. Trng hp c bit c th dng vi lng t 10 50%

Phn loi cht ha do

Cht ha do Ha do vt l Ha do ha hc

- Khng lm thay i bn cht ha hc, trng lng phn t cao su.

- Len li vo l hng gia cc Mch phn t -> lm yu lc lin kt gia cc mch phn t. -B o thi ra bn ngoi trong qu trnh s dng.

- Lm thay i bn cht ha hc, trng lng phn t cao su. -Phn ng vi cc mc xch trong mch -> ct t mch -> lm gim trng lng phn t.

Cht ha do vt l

Plasticizers are imbedded in the structure of polyvinyl chloride (PVC)

Cht ha do vt l

Chc nng ca cht ha do

Gim nhit gia cng Tng bm dnh CHD Cao su sng Tng phn tn ph gia vo cao su Tng tnh mm do

Chc nng ca cht ha do

Chc nng ca cht ha do

Chc nng ca cht ha do

Chc nng ca cht ha do

Chc nng ca cht ha do

Chc nng ca cht ha do

Khng co cht hoa deo deo Williams 4.16 Coumarone AX (long st) 3.52 Coumarone BHF (chay 65oC) 3.65 Coumarone HBF (nong chay 125oC) 3.63 Nha thng (cellophane) 3.44 Hc in g thng 3.85

Lu hoa tt nht bn keo t (kg/cm2)

8 phut

11 phut

11 phut

11 phut

15 phut

11 phut

232

252

252

280

255

243

Modul 300% (kg/cm2)

192

98

116

132

106

98

bn xe rach (kg/cm2)

43.5

53.5

48

60

54

48

2. Phn loi cht ha do vt l

Theo ngun gc
ng vt v thc vt Dn xut t than Dn xut t du m
Hc n th v nha ri ng

Tng hp

Cht du

Cht trn

Cht dnh v nha

2.1. CHD ngun gc ng vt v thc vt

Cc cht du trong ng, thc vt
nht thp Gim tnh nng c l ca CS lu ha Tng tr cho cht to xp

Cht trn : cc acid bo v dn xut

D dng phn tn cht n Tng tr lu ha Mt s acid bo tan nhiu trong CS

Cc cht nha: nha thng v dn xut

To dnh cho CS Hi lm chm lu ha Du th truyn cho CS tnh d b lo ha

Du ht cao su

Tri cao su lc cn xanh

Khi gi rng xung

2.2. CHD ngun gc t than

Cht du: Du anthracene
- Cht lng hi vng, ng mu nu khi tip xc oxy. - t dng lm CHD v c tnh ph hy

Cht nha: Nha p-coumarone indene

- Chu c acid, baze, nc v nhit nng. - Tnh khng dn in cao v h s tn hao nh - Tan c trong nhiu dung mi hu c

Hc n than v du hc (brais)
- Ci thin c x rch nhit cao ca CSLH. - H thp c l tnh ca CS sau lu ha

2.3. CHD ngun gc t du m

CHD ngun gc du m

DU

SP

CC LOI NHA

ASPHALTE BITUME

Paraffinic

Naphthenic

Cu trc phng hng chim u th

Aromatic

Cu trc phng hng

2.3.1 Du Paraffin
-c s dng ph bin v r nht di dng nn. -c sn xut t cht thi du kh. -Thnh phn:

2.3.1 Du Paraffin
-Ch c chc nng to trn trong CS, khng c tc dng ha do. -L loi du khng c c tnh

Nhc im: -Phn tn vo CS kh khn -C l tnh ni chung u b h thp. -Khng th dng c trong mt s loi CS.

2.4 CHD tng hp

Ester -Phthalate -Phosphate -Sebacate, adipate, azelate, . -Ester ca acid bo: Ricinoleate, oleate, -Ester khc Cht dnh v nha

Dn xut chloride -Diphenyl chloride ha -Paraffin chloride ..

2.4.1 CHD Ester

Ester c cng dng tng qut: CHD este c cng dng c bit CHD kh chy CHD dng cho CS chu nhit cao, du, m, dung mi

CHD polyme dn xut t acid sebasic

CHD polyme dn xut t acid adipic

CHD ester c cng dng c bit

Adipate:

-Tt c adipate u l nhng cht ha do tt -Tng cng cho CS cc tnh cht u vit nhit thp. -D bay hi, nn dng phi hp vi 1 CHD polymer khc Phthalate: Ngoi cng dng tng qut th cn dng tng cng un cong tt nhit thp cho CS

2.4.2 Cht dnh v nha

Cc abietate: cu trc este, tnh nng ging nha Nha loi PF Polymer c phn t khi nh

Polyme butylene
Copolymer butadiene-acrylonitrile

2.4.2 Cht dnh v nha

Polymer c phn t khi nh Copolymer butadiene -acrylonitrile -D dng trong x l b. -Hp th S trong QTLH, nn lm chm lu ha

Polyme butylene

- a phn tn thp. -D dng nhi trn v khuch tn cht n .

-Tng tnh keo dnh CS sng.

-Gim bt tnh co rt CSLH

-Ch dng trong trng hp dc bit

3. Cc thuyt c in v ha do

a/ Thuyt gel: - Xem polymer c cu trc hnh t ong, khng gian ba chiu, cht ha do gim cng ca polymer bng cch gim s kt t ca cc phn t polymer

3. Cc thuyt c in v ha do

b/ Thuyt bi trn: - Xem cht ha do gm 2 phn: phn gn vi cao su c tc dng nh mt dung mi, phn cn li s tc dng nh cht bi trn

3. Cc thuyt c in v ha do

b/ Thuyt bi trn: - Ha do lin quan n vic in y vo cc khong trng ln trong mng li phn t, hnh thnh cc b mt trt.

- Tnh c cc ca nn polymer v cht ha do l tiu ch cn thit la chn cht ha do thch hp.

4. So snh cc cht ha do

5. La chn cht ha do
Mch phn t di, c tnh linh ng

Tng hp tt vi cao su

Khng c, r tin, khng chy, .

Cht ha do

Tg thp

TLPT khng qu nh, nhit si tng i cao

6.1 Tn thng mi mt s CHD

6.2 ng dng

CHD Phthalates : Khng nc, khng du tt. ng dng: lm tm thm tri sn, ph tng oto,

CHD Adipates: Dng cho CS chu nhit thp nn c ng dng trong bao b thc phm

6.2 ng dng

CHD Trimellitates : ng dng trong cc VL chu c nhit cao

TEHTM : Tri-2-ethylhexyltrimelitate Tri-n-octyl trimellitate Trimelliate of C8-C10 linear alcohols,

Ti liu tham kho

1. Cao su thin nhin Nguyn Hu Tr Cng ty Kim an

2. Bi ging Cng ngh Cao su TS. Nguyn Th L Thanh, Khoa CNVL trng HBK TPHCM. 3. Plasticizers of POLYNT Specially Sollutions.

4. The Function And Selection of Ester Plasticizers

Mt s n pha ch

MT V XE TI NNG

NR 70 SBR 10 BR 20 ZnO / Stearic acid N220 (ISAF) 50 Du aromactic 3 DPAA 2 MQ 2 ZMBI 1 S 1.5 TBBS 1

Mt s n pha ch
MT V XE DU LCH

SBR 1500 35 SBR 1712 65 ZnO 2 Stearic acid 1 N242 (ISAF HS) 85 Du aromatic 25 Sp paraffin 2 TMQ 1.4 S 2

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