S GD-T BC NINH

TRNG THPT CHUYN BN

( thi c 04 trang)

THI TH I HC, NM 2008-2009

Mn thi: HO HC 12
Thi gian lm bi: 90 pht
M thi 519

H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cho bit khi lng nguyn t(tnh theo vC) ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; F = 19; Na = 23; Mg = 24; Al = 27; Si = 28; P = 31; S = 32; Cl = 35,5; K
= 39; Ca = 40; Cr = 52; Fe = 56; Ni = 58; Cu = 64; Zn = 65; Ag = 108; Ba = 137, I = 127;
Hc sinh khng c s dng bng tun hon cc nguyn t ho hc
Cu 1: Cho cc cht l O2, SO2, H2O2, CO2 ZnS, S, H2SO4, FeCl2. Cc cht va c tnh kh, va c tnh oxi ha l
A. H2O2, S, SO2, CO2.
B. FeCl2, S, SO2, H2O2.
C. SO2, ZnS, FeCl2.
D. CO2, Fe2O3, O2, H2SO4.
Cu 2: So snh nhit si ca cc cht sau: ancol etylic (1); etyl clorua (2); ietyl ete (3); axit axetic (4).
A. 4 > 3 > 2 > 1.
B. 4 > 1 > 2 > 3.
C. 4 > 1 > 3 > 2.
D. 1 > 2 > 3 > 4.
Cu 3: Kh no tha mn tt c cc tnh cht: to kt ta vi dung dch AgNO3, lm mt mu dung dch KMnO4,
khng tn ti trong mt hn hp vi SO2, tc dng c vi nc clo.
A. CO2
B. NH3
C. C2H2
D. H2S
Cu 4: Cho s sau:
HCl
HCl
/ etanol(t0 )
KOH / etanol(t0 )
NaOH, H 2 O(t0 ) E
(CH3)2CH-CH2CH2Cl KOH
A B C D

E c cng thc cu to l
A. (CH3)2C(OH)-CH2CH3.
B. (CH3)2CH-CH(OH)CH3.
C. (CH3)2C=CHCH3.
D. (CH3)2CH-CH2CH2OH.
Cu 5: Mt cht hu c X c cng thc n gin l C4H4O tc dng va vi dung dch KOH 11,666%. Sau phn
ng thu c dung dch Y. C cn Y th phn hi ch c H 2O vi khi lng 86,6 gam, cn li cht rn Z c khi
lng l 23 gam. Cng thc cu to thu gn ca X c th l
A. HCOOC6H4C2H5.
B. HCOOC6H4CH3.
C. CH3COOC6H5.
D. HCOOC4H4OH.
Cu 6: T toluen mun iu ch o-nitrobenzoic ngi ta thc hin theo s sau:
0
) A
+ Y (xt, t 0 )
C6H5CH3 +X(xt,t

o-O2NC6H4COOH
X, Y ln lt l
A. KMnO4 v HNO3.
B. KMnO4 v NaNO2. C. HNO3 v H2SO4.
D. HNO3 v KMnO4.
Cu 7: Mt hp cht X (c MX < 170). t chy hon ton 0,486 gam X sinh ra 405,2 ml CO2 ( ktc) v 0,27 gam
H2O. X tc dng vi dung dch NaHCO3 v vi Na u sinh ra cht kh vi s mol bng ng s mol X tham gia
phn ng. Cng thc cu to ca X l
A. HOOC-C5H10-COOH.
B. HOC4H6O2-COOH.
C. HO-C5H8O2COOH.
D. HOC3H4COOH.
Cu 8: Cho 300 ml dung dch cha NaHCO3 x mol/l, v Na2CO3 y mol/l. Thm t t dung dch HCl z mol/l vo
dung dch trn n khi bt u c kh bay ra th dng li, thy ht t ml. Mi quan h gia x, y, z, t l
A. t.z=300y.
B. t.z=300x.y.
C. t.z=150xy.
D. t.z=100xy.
Cu 9: Cho m gam hn hp bt Zn v Fe vo lng d dung dch CuSO4. Sau khi kt thc cc phn ng, lc b
phn dung dch thu c m gam bt rn. Thnh phn phn trm theo khi lng ca Zn trong hn hp bt ban u l
A. 85,30%.
B. 82,20%.
C. 12,67%.
D. 90,27%.
Cu 10: Cho 4 dung dch mui l: AlCl3, FeCl3, FeCl2, ZnCl2. Ch dng mt dung dch no sau y nhn bit c
c 4 dung dch trn
A. dung dch NaOH.
B. dung dch NH3.
C. dung dch AgNO3.
D. dung dch H2S.
Cu 11: Cho cc cht sau: propyl clorua; anlyl clorua; phenyl clorua. S cht tc dng c vi dung dch NaOH
long khi un nng l
A. 1.
B. 2.
C. 0.
D. 3.

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Cu 12: Mt hn hp gm axetilen, propilen v metan. t chy hon ton 11 gam hn hp thu c 12,6 gam
H2O. Mt khc 5,6 lt ( ktc) hn hp lm mt mu va dung dch cha 50 gam Br 2. Thnh phn phn trm th
tch ca cc kh C2H2; C3H6; CH4 trong hn hp u ln lt l
A. 50%; 25%; 25%.
B. 40%; 40%; 20%.
C. 25%; 25%; 50%.
D. 25%; 50%; 25%.
Cu 13: Khi lm lnh 500ml dung dch CuSO4 25% ( d = 1,2 g/ml) th c 50g CuSO4. 5H2O kt tinh li. Lc b
mui kt tinh ri dn 11,2 lt kh H2S (ktc) qua nc lc. Nng phn trm ca CuSO4 cn li trong dung dch sau
phn ng l
A. 7,32%.
B. 8,14%.
C. 6,98%.
D. 8,44%.
Cu 14: Trong thnh phn kh thi ca mt nh my c cc kh c gy nhim mi trng khng kh: SO 2, Cl2,
NO2. loi cc kh c trn nh my dng:
A. P2O5.
B. dung dch H2SO4 c.
C. dung dch Ca(OH)2.
D. dung dch KMnO4.
Cu 15: Cho 4 phn ng:
1 (1) Fe + 2HCl FeCl2 + H2
2 (2) 2NaOH + (NH4)2SO4 Na2SO4 + 2NH3 + 2H2O
3 (3) BaCl2 + Na2CO3 BaCO3 + 2NaCl
4 (4) 2NH3 + 2H2O + FeSO4 Fe(OH)2 + (NH4)2SO4
Cc phn ng thuc loi phn ng axit - baz l
A. (1), (2).
B. (2), (4).
C. (3), (4).
D. (2), (3).
Cu 16: Dy gm cc cht no sau y d b nhit phn
A. NaOH, H2SiO3, CaCO3, NH4NO2, Cu(NO3)2.
B. NaHCO3, MgCO3, BaSO4, KNO3, (NH4)2CO3.
C. NaHCO3, Na2CO3, Ca(HCO3)2, CaCO3, NH4NO3.
D. NaHCO3, NH4HCO3, Ca(HCO3)2, AgNO3, NH4Cl.
du,t0
+ CuOdu,t0
Cu 17: Cho dy bin ha sau: Xiclo propan +Br2 X1 +NaOH
X2
X3
Khi cho 0,1 mol cht X tc dng vi AgNO3 d trong dung dch NH3, un nng th thu c khi lng Ag l
A. 43,2 gam
B. 21,6 gam
C. 10,8 gam
D. 32,4 gam
Cu 18: Cho CO d i qua m gam hn hp gm Fe v Fe2O3 nhit cao sau phn ng ngi ta thu c 11,2
gam Fe. Nu cho m gam hn hp trn vo dung dch CuSO4 d, phn ng xong ngi tan nhn thy cht rn thu
c c khi lng tng thm 0,8 gam. Gi tr ca m l
A. 12,5 g.
B. 24,2 g.
C. 13,6 g.
D. 18 g.
Cu 19: Cng thc n gin nht ca cht A l (C 3H4O3) v cht B l (C2H3O3). Bit A l axit no a chc, cn B l
mt axit no cha ng thi nhm chc OH, A v B u mch h. Cng thc cu to ca A v B l
A. C3H5(COOH)3 v HOOC-CH(OH)-CH2-CH(OH)-COOH.
B. C3H7(COOH)3 v HOOC-[CH(OH)]2-COOH.
C. C4H7(COOH)3 v HOOC-[CH(OH)]2-COOH.
D. C3H5(COOH)3 v HOOC-[CH(OH)]2-COOH.
Cu 20: Theo danh php IUPAC ancol (CH3)2C=CHCH2OH c tn gi l
A. pent-2-en-1-ol.
B. 2-metylbut-2-en-4-ol.
C. 3-metylbut-2-en-1-ol.
D. ancol iso-pent-2-en-1-ylic.
Cu 21: Cho phn ng oxi ha kh sau: KMnO4 + Na2SO3 + NaHSO4 K2SO4 + MnSO4 + Na2SO4+ H2O
Tng h s cn bng ca cc cht trong phn ng l
A. 23.
B. 47.
C. 31.
D. 27.
Cu 22: Nh mt git dung dch H2SO4 2M ln mt mu giy trng. Hin tng s quan st c l
A. Khi h nng, ch giy c git axit H2SO4 s chuyn thnh mu en.
B. Khng c hin tng g xy ra.
C. Khi h nng, ch giy c git axit H2SO4 s bc chy.
D. Ch giy c git axit H2SO4 s chuyn thnh mu en.
Cu 23: C 1 gam hp kim Cu-Al c x l bng lng d dung dch NaOH, ra sch cht rn cn li ri ho tan
bng dung dch HNO3, sau lm bay hi dung dch ri nung n khi lng khng i, thu c lng cht rn l
0,4 gam. Phn trm theo khi lng ca cc kim loi Cu-Al trong hp kim v th tch kh NO thot ra ktc l:
A. 68% , 32% v 0,224 lt.
B. 65% , 35% v 0,075 lt.
C. 32% , 68% v 0,224 lt.
D. 32% , 68% v 0,075 lt.
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Cu 24: kh hon ton 45 gam hn hp gm CuO, FeO, Fe 3O4, Fe2O3, Fe v MgO cn dng va 8,4 lt kh
CO (ktc). Khi lng cht rn thu c sau phn ng l
A. 38 g.
B. 39 g.
C. 24 g.
D. 42 g.
Cu 25: Mt hn hp X gm FeO, Fe3O4, Fe2O3. Ly m1 gam hn hp X cho vo ng s chu nhit, nung nng ri
thi mt lung kh CO i qua. Ton b kh sau phn ng c dn t t vo dung dch Ba(OH) 2 d thu c 19,7
gam kt ta trng. Cht rn cn li trong ng s c khi lng l 19,20 gam gm Fe , FeO v Fe3O4. Xc nh m1.
A. 23,2 gam.
B. 20,8 gam
C. 22,0 gam
D. 23,6 gam
Cu 26: phn bit dung dch ca 3 cht: h tinh bt, saccaroz, glucoz ng ring bit trong 3 l mt nhn. Ta
cn dng thuc th l
A. dung dch AgNO3.
B. Cu(OH)2.
C. Cu(OH)2/OH-, t0.
D. dung dch I2.
Cu 27: Khi ho tan Al bng dung dch HCl nu thm vi git mui Hg(NO3)2 th hin tng xy ra l
A. Al phn ng ng thi vi cc dung dch HCl, Hg(NO3)2.
B. Qu trnh ho tan xy ra nhanh hn, kh thot ra mnh hn.
C. Al y Hg ra khi mui ri tc dng vi dung dch HCl.
D. Al tc dng vi dung dch HCl trc ri y Hg ra khi mui.
Cu 28: Qu trnh tng hp poli(metyl metacrylat) c hiu sut phn ng este ho v trng hp ln lt l 60% v
80%. Vy mun tng hp 120 kg poli(metyl metacrylat) th khi lng ca axit v ancol tng ng cn dng l
A. 6 kg v 40 kg.
B. 171 v 82kg.
C. 175 kg v 80 kg.
D. 215 kg v 80 kg.
3+
2+
Cu 29: Cho mt pin in ho c to bi cc cp oxi ho-kh Cr /Cr v Fe /Fe. Phn ng xy ra cc dng
ca pin in ho ( iu kin chun) l
A. Fe2+ + 2e Fe.
B. Cr3+ + 3e Cr.
C. Cr Cr3+ + 3e.
D. Fe Fe2+ + 2e.
Cu 30: trung ha 500ml dung dch X cha hn hp HCl 0,1M v H2SO4 0,3M cn bao nhiu ml dung dch hn
hp gm NaOH 0,3M v Ba(OH)2 0,2M?
A. 500ml.
B. 750ml.
C. 250ml.
D. 125ml.
Cu 31: A l mt amino axit trong phn t ngoi cc nhm cacboxyl v amino khng c nhm chc no khc. 0,1
mol A phn ng va ht vi 100ml dung dch HCl 1M to ra 18,35 gam mui. Mt khc khi cho 22,05 gam A tc
dng vi NaOH d to ra 28,65 gam mui khan. Cng thc phn t A l
A. H2NC4H7(COOH)2..
B. H2NC3H3(COOH)2.
C. H2NC2H3(COOH)2.
D. H2NC3H5(COOH)2.
Cu 32: Cho m g hn hp X gm 3 kim loi Al, K v Mg. Chia hn hp thnh ba phn bng nhau. Phn 1 cho ha
tan vo nc c V1 lt kh H2. Phn 2 ha tan vo dung dch NaOH c V2 lt kh H2.Phn 3 ha tan vo dung
dch HCl d thu c V3 lt kh H2. Cc kh u o cng iu kin . So snh th tch cc kh thot ra trong cc th
nghim trn.
A. V1<V2 < V3
B. V1 V2<V3
C. V1=V2<V3
D. V1 =V3 >V2
Cu 33: Cho cc cht lng sau: axit axetic; glixerol; triolein. phn bit cc cht lng ny c th ch cn dng
A. dung dch NaOH.
B. nc Br2.
C. nc v qu tm.
D. nc v dung dch NaOH.
Cu 34: Cho 0,01 mol mt hp cht ca st tc dng ht vi H 2SO4 c nng (d), thot ra 0,112 lt ( ktc) kh SO 2
(l sn phm kh duy nht). Cng thc ca hp cht st l
A. FeCO3.
B. FeS2.
C. FeS.
D. FeO .
Cu 35: t chy hon ton hn hp A gm 2 ankin X, Y. Hp th ton b sn phm chy vo 4,5 lt dung dch
Ca(OH)2 0,02M thu c kt ta v khi lng dung dch tng 3,78 gam. Cho dung dch Ba(OH) 2 va vo dung
dch thu thm kt ta. Tng khi lng kt ta 2 ln l 18,85 gam. Bit rng s mol X bng 60% tng s mol ca X
v Y c trong hn hp A . Cc phn ng xy ra hon ton. Cng thc ca X, Y ln lt l
A. C3H4 v C4H6.
B. C2H2 v C4H6.
C. C2H2 v C3H4.
D. C4H6 v C2H2.
Cu 36: Thnh phn chnh ca supepht pht kp l
A. Ca(H2PO4)2
B. Ca(H2PO4)2. CaSO4 C. NH4H2PO4
D. Ca3(PO4)2.CaF2
Cu 37: T etilen v benzen s phn ng dng t nht c th iu ch c polibutaien; polistiren; poli(butaienstiren) l
A. 6.
B. 8.
C. 5.
D. 7.
Cu 38: Cho m gam Al tc dng va ht vi dung dch HNO 3 thu c 8,96 lt (ktc) hn hp hai kh NO v NO 2
c t khi so vi H2 l 16,5. Tnh m
A. 10,8 g
B. 6,75g
C. 9,45g
D. 8,10g
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Cu 39: X l hp cht hu c mch h n chc c cha oxi. t chy hon ton 1 mol X cn 4 mol O 2 thu c
CO2 v hi nc vi th tch bng nhau (o cng iu kin). S cng thc cu to c th c ca X l
A. 4.
B. 5.
C. 2.
D. 3.
Cu 40: Hn hp X cha glixerol v 2 ancol no, n chc k tip nhau trong dy ng ng. Cho 8,75 gam X tc
dng vi Na thu c 2,52 lt H2 ( ktc). Mt khc 14 gam X tc dng va vi 3,92 gam Cu(OH) 2. Cng thc
phn t ca 2 ancol l
A. C3H7OH v C4H9OH.
B. C2H5OH v C3H7OH.
C. CH3OH v C2H5OH.
D. C4H9OH v C5H11OH.
Cu 41: C hn hp cc cht Al, Fe, Al2O3. Nu ngm 24 gam hn hp ny trong dung dch NaOH d, thu c
6,72 lt kh H2 (ktc) v mt cht rn. Lc ly cht rn, ho tan va lng cht rn ny cn dng 200 ml dung
dch HCl 1,5M. Phn trm theo khi lng ca cc cht trong hn hp ban u ln lt l
A. 34,78%; 33,54% v 31,68%.
B. 35,0%; 22,5% v 42,5%.
C. 30,3%; 35,6% v 34,1%.
D. 23,33%; 28,125% v 48,545%.
Cu 42: Chn cu sai trong s cc cu sau y
A. Cc kim loi Na, Ba, K, Al u c cu to mng tinh th lp phng tm khi.
B. Dng dung dch Na2CO3, Ca(OH)2, Na3PO4 lm mm nc cng.
C. CrO3 l mt oxit axit, mui cromat v icromat c tnh oxi ho mnh.
D. Phng php in phn c th iu ch c hu ht cc kim loi t Li, Na, Fe, Cu, Ag.
Cu 43: Phn ng tng hp glucoz trong cy xanh cn c cung cp nng lng
,clorofin
6CO2 + 6H2O as
H = 2813kJ.
C6H12O6 + 6O2
2
Trong mt pht, mi cm l xanh nhn c khong nng lng 2,09 J nng lng Mt tri, nhng ch 10% c
s dng vo phn ng tng hp glucoz. Vi mt ngy nng (t 6 gi n 17 gi), din tch l xanh l 1m 2 th khi
lng glucoz tng hp c l
A. 80,70g.
B. 93,20g.
C. 88,27g.
D. 78,78g.
Cu 44: 1 mol amino axit A tc dng va vi 1 mol HCl. 0,5 mol A tc dng va vi 1 mol NaOH. Khi
lng phn t ca A l 147u. Cng thc phn t A l
A. C7H10N4O2.
B. C4H7N2O4.
C. C5H11NO4.
D. C5H9NO4.
Cu 45: Mt trong cc tc dng ca mui it l c tc dng phng bnh bu c. Thnh phn ca mui it l:
A. NaCl c trn thm mt lng nh KI
B. NaCl c trn thm mt lng nh I2
C. NaCl c trn thm mt lng nh HI
D. NaCl c trn thm mt lng nh HIO3
Cu 46: Phn ng no khng th hin tnh kh ca glucoz?
A. Phn ng trng gng glucoz.
B. Cho glucoz cng H2 (Ni, t0).
C. Cho glucoz tc dng vi Cu(OH)2 to ra Cu2O.
D. Cho glucoz tc dng vi nc brm.
Cu 47: Caroten c cng thc phn t C40H56. Khi hiro ho hon ton caroten thu c hirocacbon no c cng
thc C40H78. S lin kt v s vng trong caroten ln lt l
A. 12 v 1.
B. 11 v 1.
C. 12 v 2.
D. 11 v 2.
Cu 48: Ho tan hon ton 9,75 gam Zn bng dung dch HNO3 long, ton b lng kh NO (sn phm kh duy
nht sinh ra c oxi ho hon ton bi oxi thnh NO 2 ri sc vo nc cng vi dng kh oxi chuyn ht thnh
HNO3. Tng th tch kh oxi (ktc) phn ng l
A. 0,56 lt.
B. 3,92 lt.
C. 1,68 lt.
D. 1,12 lt.
Cu 49: X l mt dn xut ca benzen c cng thc phn t C7H9NO2. Cho 1 mol X tc dng va vi NaOH, c
cn dung dch thu c mt mui khan c khi lng l 144 gam. Cng thc cu to thu gn ca X l
A. C6H5COONH4.
B. HCOOH3NC6H5.
C. HCOOC6H4NO2.
D. HCOOC6H4NH2.
Cu 50: A l hn hp kh gm N2 v H2 c t khi so vi oxi bng 0,225. Dn A vo bnh c Ni un nng, phn ng
tng hp amoniac xy ra th thu c hn hp kh B c t khi so vi oxi bng 0,25. Hiu sut ca qu trnh tng hp
NH3 l
A. 30%.
B. 25%
C. 15%.
D. 20%.
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