Bi 1:

C7H14, l Hidrocabon khng no k=1 (xc nh t cng thc tng qut CnH2n+2-2k), CTCT c 01 vng hoc 01 ni i C=C a) Da vo sn phm ca p oxi ha (khi b oxi ha khnghon ton th ni i s t to thnh axit cacboxylic hoc xeton), th suy ra A l mch thng: CH3-CH2-C(CH3)=CH-CH2-CH3 PTP:

5CH3-CH2-C0(CH3)=C-1H-CH2-CH3 + 6KMn+7O4+ 9H2SO4 5CH3-CH2-C+2O-CH3 + 5CH3-CH2-C+3OOH + 6Mn+2SO4 + 3K2SO4 + 9H2O

Cht oxi ha: KMnO4 (c th l Mn+7) Cht kh: A (c th l C0 v C-1) b) Phn p oxi ha khng hon ton to CO2 B c ni i C=C u mch, kt hp vi B mch thng B l: CH3-(CH2)4-CH=CH2 PTP (trong trng hp dng HCl long, axit xem nh mi trng)

3CH3-(CH2)4-C-1H=C-2H2 + 5K2Cr2+6 O7 + 40HCl 3CH3-(CH2)4-C+3OOH + 3C+4O2 + 10Cr+3Cl3 + 10KCl + 23H2O

Cht oxi ha: K2Cr2O7 (c th l Cr+6) Cht kh: B (c th l C-1 v C-2)

Bi 12: - Th nht: E khng lm nht mu nc Brom, suy ra E l Xiclobutan (t vng 4 cnh tr ln khng phn ng vi nc Brom) - Th hai: B v C l ng phn hnh hc ca nhau nn B v C c th l: cis-But-2-en hoc trans-but-2-en. Tuy nhin, B c nhit si cao hn C nn B l: cis-But-2-en C l trans-but-2-en (V hai hp cht l ng phn ca nhau th ng phn th ng phn cis c nhit si cao hn ng phn trans); 0 - Th ba: A, B v C c cng sn phm khi phn ng vi H2 (Ni\t ) suy ra A l: But 1- en; - Th t: A, B, C, D v F lm nht mu nc Brom, suy ra D v F c th l: iso propen hoc metyl xiclopropan Tm lai: A l: But 1- en B l: cis-But-2-en C l: trans-but-2-en D l: iso propen (hoc metyl xiclopropan ) E l: Xiclobutan F l: metyl xiclopropan (hoc iso propen)