S GIO DC V O TO HI PHNG CHNH THC

K THI TUYN SINH VO LP 10 THPT CHUYN Nm hc 2012-2013 THI MN HA HC Thi gian lm bi 120 pht ( khng k thi gian giao ) Lu : thi gm trang, th sinh lm bi vo t giy thi

Th sinh s dng khi lng mol ca cc nguyn t trong khi lm bi:

Na = 23; Mg=24 ; Al = 27 ; K =39 ; Fe = 56 ; Cu = 64 ; Ba = 137 ; Ca = 40 ; C = 12 H=1 ; O = 16 ; N = 14; S = 32 ; He =4 ; Cl =35,5 ; Br = 80

Bi 1.(2,0 im) 1. Cho cc cht rn: BaO, CaCO3, Al, CuS, Al2O3 v NaNO3. Xc nh cc cht ha tan c trong dung dch HCl d, dung dch NaOH d. Vit cc phng trnh phn ng xy ra ( nu c). 2. t chy hon ton 2,75 gam hp cht A c cng thc CxH2xOzNtClt to ra 1,792 lt (ktc) kh CO2. Tm cng thc phn t ca A. Bit t khi ca A so vi O2 bng 4,297. Bi 2.(2,0 im) 1. Cho 17,92 lt kh (ktc) hn hp X gm CH3CH2CH3 , CHC CH=CH2; CHC CH3, CH2=CH2 v H2 c t l s mol tng ng l 1:1:3:2:9 qua xc tc Ni nung nng. Sau mt thi gian thu c hn hp kh Y c t khi so vi H2 bng 14,5. Dn hn hp kh Y i chm qua bnh cha dung dch Br2 d, sau khi cc phn ng kt thc thy khi lng bnh tng m gam v thot ra 6,72 lt kh ( ktc) hn hp kh Z c t khi so vi He bng 4,5833. Xc nh gi tr m v s mol Br2 tham gia phn ng. 2. Xc nh mt b ha cht v c A, B, C, D, E, F, G, H, I, K, L, M, N v vit phng trnh ha hc ph hp vi cc phn ng sau: mui (A) + axit (B) mui (C) + mui (D) + nc (1) mui (D) + mui (E) + nc mui (C) + hidroxit (F) + oxit (G) (2) mui (A) + oxit (G) + nc hidroxit (F) + mui (H) (3) mui (H) + mui (I) mui (K) + mui (C) + oxit (G) + nc (4) t0 mui (L) + axit (B) c (5) mui (M) + oxit (G) + oxit (N) + nc Bi 3.(2,0 im) 1. Cho kh CO qua 69,9 gam hn hp X gm Fe2O3 v oxit kim loi MaOb nung nng thu c 3,36 lt ( ktc) kh CO2 v hn hp cht rn Y gm Fe, FeO, Fe3O4, Fe2O3 v MaOb. ha tan hon ton hn hp Y cn va 1,3 lt dung dch HCl 1M thu c 1,12 lt (ktc) kh H 2 v dung dch Z. Cho t t dung dch NaOH vo dung dch Z ti d thu c kt ta T. Lc kt ta T ngoi khng kh n khi lng khng i thu c 32,1 gam baz duy nht. Xc nh cng thc ca oxit MaOb. 2. Cho hn hp lng gm 3 cht: ru etylic, axit axetic v etyl axetat. Trnh by phng php ha hc chng minh s c mt ca cc cht c trong hn hp. Bi 4.(2,0 im) Cho 11,3 gam hn hp X gm Na,Mg,Al vo 240 gam dung dch H2SO4 24,5% thu c dung dch Y v 11,2 lt (ktc) kh H 2. Cho t t V ml dung dch Ba(OH)2 0,5M vo dung dch Y n khi thu c khi lng kt ta Z cc i bng 156,3 gam th dng li. Nung kt ta Z n khi lng khng i thu c m gam cht rn T. 1. Vit cc phng trnh phn ng ha hc xy ra. 2. Tnh thnh phn phn trm khi lng mi kim loi trong hn hp X. 3. Xc nh gi tr V v m. Bi 5.(2,0 im) Cho 4,6 gam hn hp X gm cc axit HCOOH, CH3COOH, CH2=CHCOOH v (COOH)2 tc dng vi dung dch NaOH va . C cn dung dch sau phn ng thu c 6,47 gam mui khan. Mt khc, t chy hon ton 4,6 gam hn hp X ri cho ton b sn phm chy hp th ht vo bnh ng dung dch Ba(OH)2 d thu c m gam kt ta v khi lng dung dch gim 19,62 gam so vi khi lng dung dch ban u. 1. Vit cc phng trnh phn ng ha hc xy ra. 2. Tnh khi lng m gam kt ta thu c.