I HC QUC GIA H NI

THI TUYN SINH SAU I HC NM 2012 T I

MN THI: C S L THUYT HA HC V CU TO CHT
Cu 1:
Cho cn bng: N2O4(k)

2NO2(k)

Kp,303K = 0,124

( Khng mu) ( mu nu )
1. Cho 0,125 mol N2O4 vo bnh chn khng v gi nhit 303K. Hi dung tch bnh phn
ng phi bng bao nhiu (lit) khi cn bng c 80% lng N2O4 ban u chuyn thnh NO2.?
2. Xt du ca i lng Go, So, Ho ca phn ng thun nhit ni trn.
3. Nu tng nhit v gi th tch ca bnh phn ng th mu sc v p sut trong bnh thay i
th no? V sao?
Cu 2:
Bit 25oC, TAgCH3COO= 2.10-3 v pKa= 4,75.
1. Tnh tan ca bc axetat (mol/l) trong nc v pH ca dung dch bo ha bc axetat, coi Ag+
thy phn khng dng k.
2. Ngi ta cho 0, mol AgCH3COO vo 1 lit nc. Cn phi a pH ca dung dch n gi tr
no ha tan ht lng mui trn.
Cu 3:
Xt phn ng (1) 25oC: H3AsO4 + 3I- + 2H+

H3AsO3 + I3- + H2O (1)

1. Xc nh chiu ca phn ng iu kin tiu chun.

2. Xc nh chiu ca phn ng pH = 2, nng ca cc cht vn bng 1M.
3. Nu ch thay i pH ca dung dch, xc nh pH ca dung dch m ti phn ng (1) i
chiu.
4. Tnh hng s cn bng ca phn ng (1).
Cho: EoH3AsO4/H3AsO3 = 0,559V, EoI3-/I- = 0,536V
Cu 4:
1. Da vo s xen ph ca cc obital nguyn t, hy m t cu to ca phn t CO v N2.
2. Cc kh CO v N2 c tnh cht vt l tng i ging nhau u c nng lng lin kt ln,
nhng nng lng lien kt ca CO (1070 kJ/mol) ln hn N2 (946 kJ/mol). Hy gii thch.

Cu 5:
1. Da vo quy tc Huckel v tnh thm, hy cho bit cc h e vng sau y, th h no bn, ti
sao?
C3H3, C3H3+, C4H4, C5H5, C5H5-, C6H6, C7H7, C7H7+, C8H8, C8H82-.
2. p dng m hnh hp th 1 chiu, hy tnh nng lng ra kJ/mol ca 6 e khng nh c trong
phn t hexatrien vi chiu di L = 8,4 Angtron, bit 6e chim 3 mc nng lng thp nht.
Tnh s song (cm-1) ca bc x hp th ng vi bc chuyn dch e t t mc nng lng b
chim cao nht n mc nng lng cha b chim thp nht.
Cu 6:
Bc kim loi tn ti th rn, tinh th lp phng tm din.
1. Hy v mng c s.
2. C bao nhiu nguyn t mng c s.
3. Khi lng ring ca Ag l 10,5 gam/cm3. Hy xc nh chiu di ca mng c s theo
Angtron.
4. Tnh bn knh nguyn t Ag trong tinh th.
Cho: ZC = 6, ZO = 8, h = 6,625.10-34J.s; me = 9,1.10-31 kg; NA = 6,02.1023; c = 3.108 m/s; MAg =
108
------HT-----(Cn b coi thi khng gii thch g thm)